Episodic mineralization of hydrothermal illite in the Soultz-sous-Forêts granite (Upper Rhine Graben, France)

Episodic and localized illite mineralization is documented in the hydrothermally altered Soultz-sous-Forêts granite (Upper Rhine Graben, France). Separated grain-size fractions of altered granite and argillite vein samples contain mixtures of 2M₁ and 1M trans-vacant illite varieties. The platy pseudohexagonal 2M₁ illite phases dominate the vein fillings, whereas the 1M illite occurs largely as a fibrous pore-filling variety, which is particularly abundant in the granite matrix. Multiple phases of fluid injections into the granite body have resulted in different illite assemblages, each sample containing a mixture of polytype generations formed during different crystal growth events. On the basis of mineralogical and K–Ar isotopic constraints, the ages of these vein-mineralizing events are determined by plotting the K–Ar values of the various grain-size fractions against polytype abundance and the fitted volume-weighted crystallite thickness distributions. The results suggest a Permian age for the formation of the studied argillite veins, characterized by successive injections of hydrothermal fluids. Secondary episodes of illite crystallization occurred during Jurassic and Cretaceous (or even younger times) in both the veins and the granite matrix. There are indications that the polytype structure and composition of illite were strongly influenced by variations in fluid chemistry and the degree of fluid–rock interaction as the granite was progressively sealed during post-Variscan, episodic hydrothermal activity.     

Lower and Middle Pleistocene human settlements recorded in fluvial deposits of the middle Loire River Basin,Centre Region,France

This paper records the findings from c. 80 prehistoric sites that have been discovered in the alluvial deposits of the rivers Creuse, Cher, and Loir, tributaries of the middle Loire River, over the period since 1981. These deposits comprise river terrace aggradations formed during successive glacial–interglacial cycles which have recorded climate and environment during Quaternary time. The systematic dating of these river deposits by Electron Spin Resonance (ESR) applied to optically bleached sedimentary quartz has resulted in the establishment of a chronological framework for the evolution of these rivers during Lower and Middle Pleistocene (between 1.7 Ma and 130 ka). Evidence for Early Palaeolithic (Mode 1) industries with an in situ context (workshops, soils) in the highest aggradations indicates that Hominins were present in the study area, near the geographical centre of France (47°N), around 1.1 Ma. Examination of the sites indicates that Human occupations were located along valley bottom sites during temperate episodes. Subsequently, after a gap of several hundred thousand years industries with handaxes appear in the Middle Loire Basin in the interval between 700 and 600 ka, and then continuously from 400 ka. These two phases of settlement produced industrial assemblages with clear differences in their responses to the supplies of raw materials and in the modes of making flakes.     

Vertical accretion of flood deposits and deeply stratified archaeological site formation in Central Maine,USA

Investigation of deeply stratified archaeological sites on the Piscataquis River in central Maine has revealed a continuous sequence of human occupation from ca. 10,000 yr B.P. to the near present. As an integrated aspect of the archaeological excavations, geomorphic features and surficial deposits were mapped from aerial photographs and field checked. Stratigraphic profiles were recorded from various locations and sediment column samples were collected and analyzed for grain size distribution in 1-cm vertical intervals from a 3-m deep excavation at the Sharrow site (ME 90-2D) to examine the flood deposits. Results include a general chronology of fluvial processes of the Piscataquis River since deglaciation and evidence of dominant vertical accretion of flood sediments on floodplain terraces throughout the Holocene epoch. This article defines an archaeologically significant but rarely recognized depositional regime characterized by a laterally controlled river channel and the exclusive vertical accretion of flood sediments. © 1994 John Wiley & Sons, Inc.     

Correlation of Plio-Pleistocene deposits of the Lower Rhine Basin (North-West Germany) and the Valle Ricca pits (Central Italy)

Biostratigraphic and palaeomagnetic research has been carried out on selected profiles in North-Western Germany and Central Italy in order to correlate Plio-Pleistocene sections.Around the Réunion subchronozone, vegetation in the Valle Ricca was dominated by a mountain forest type pointing to cool climatic conditions. In the Lower Rhine Basin vegetation had a slightly warmer character, but was also dominated strongly by a mountain type of forest vegetation, characteristic of cooler summers and higher precipitation than at present.Two warmer periods have been determined in the Central Italian profiles; the youngest around the Olduvai reversal, should correspond to the youngest Tiglian beds of the Lower Rhine Basin.Deposits older than the Réunion subzone have not been found in the Valle Ricca. In the Lower Rhine Basin, on the other hand, the Gauss-Matuyama boundary is located between the uppermost Pliocene, the Reuverian C and the Praetiglian.     

Hierarchical dynamic stratigraphy in various Quaternary gravel deposits,Rhine glacier area (SW Germany): implications for hydrostratigraphy

The approach of dynamic stratigraphy aims to understand genetic processes that form stratigraphic units in a hierarchy of spatial and temporal scales. This approach was used to investigate Quaternary gravel deposits in terms of their sedimentology and in order to characterize the various sedimentary units in terms of their hydrogeological properties. Facies analysis within 62 gravel pits, laboratory permeability measurements of field samples and geophysical surveys (3-D georadar, 2-D seismic reflection) led to the detection and classification of sedimentary heterogeneity according to the following six scales whereby each scale can be translated into defined hydrostratigraphic units. (1) Particles and pores (micro scale) that reflect depositional and diagenetic fluid dynamics as well as source material behaviour (e.g. grain-size, roundness, lithological composition). This was found to be important for the hydrogeochemistry of groundwater in gravel aquifers (e.g. higher sorption capacity of carbon-rich limestone particles for organic pollutants). (2) Strata (meso scale) contain the recognition of sorting, fabric, texture and stratinomic features, which can give an indication of transport and depositional dynamics. Five major lithofacies groups, for example, were distinguished within fluvial gravel-bed deposits. Their variable hydraulic properties led to their subdivision into 12 hydrofacies types. They form the smallest mappable hydrostratigraphic units, which may result in either preferred pathways for fluid flow or flow barriers. (3) Depositional elements (macro scale) enable reconstruction of sedimentary/geomorphic elements and their dynamics within a depositional system (e.g. gravel-bed braided river systems are dominated by gravel sheet, gravel dunes and scour pool depositional elements). Hydrostratigraphically, the architecture of depositional elements influences the hydraulic connectivity and local permeability structure/distribution within an aquifer body. Five types of depositional elements in fluvial gravel-bed deposits were distinguished and their geometries/dimensions quantified. (4) Facies bodies (mega scale) composed of a stack of depositional elements and strata recording distinct environmental systems and their dynamics (e.g. a coarse-grained prograding delta system). Hydrostratigraphically, facies bodies represent major compartments of an aquifer. Six major types of meltwater-controlled facies bodies were identified in the study area. (5) Genetic sequences (mega scale) reflect the shifts of depositional environments caused by allocyclic changes (e.g. glacial advance recorded by a coarsening upward sequence) or autocyclic changes of landscape shaping events. These sequences may form separate hydrostratigraphic units or aquifer storeys. (6) Basin fill (giga scale) comprising the lateral and vertical stacking of facies bodies and genetic sequences controlled by either long-term glacier dynamics or short term flood events. The regional distribution of permeable gravel units and, for example, less permeable diamicts builds the larger scale hydrostratigraphy.     

Rhone River flood deposits in Lake Le Bourget: a proxy for Holocene environmental changes in the NW Alps, France

The Holocene evolution of Rhone River clastic sediment supply in Lake Le Bourget is documented by sub-bottom seismic profiling and multidisciplinary analysis of well-dated sediment cores. Six high-amplitude reflectors within the lacustrine drape can be correlated to periods of enhanced inter- and underflow deposition in sediment cores. Based on the synthesis of major environmental changes in the NW Alps and on the age-depth model covering the past 7500 years in Lake Le Bourget, periods of enhanced Rhone River flood events in the lake can be related to abrupt climate changes and/or to increasing land use since c. 2700 cal. yr BP. For example, significant land use under rather stable climate conditions during the Roman Empire may be responsible for large flood deposits in the northern part of Lake Le Bourget between AD 966 and 1093. However, during the Little Ice Age (LIA), well-documented major environmental changes in the catchment area essentially resulted from climate change and formed basin-wide major flood deposits in Lake Le Bourget. Up to five 'LIA-like' Holocene cold periods developing enhanced Rhone River flooding activity in Lake Le Bourget are documented at c. 7200, 5200, 2800, 1600 and 200 cal. yr BP. These abrupt climate changes were associated in the NW Alps with Mont Blanc glacier advances, enhanced glaciofluvial regimes and high lake levels. Correlations with European lake level fluctuations and winter precipitation regimes inferred from glacier fluctuations in western Norway suggest that these five Holocene cooling events at 45°N were associated with enhanced westerlies, possibly resulting from a persistent negative mode of the North Atlantic Oscillation.     

First recorded evidence in the fossil record of snipe flies (Diptera: Rhagionidae) in Cretaceous amber, France

Novelaria, a new genus of rhagionid of late Albian age with three new species, is the first record of this family from Charentes amber (southwestern France). The new genus is probably closely related to the recent genus Chrysopilus. However its relationship with the other fossils in amber is discussed. A key for separation of the new species is provided and the diversity of the family during the Cretaceous is also briefly discussed.     

Historical mining and smelting in the Vosges Mountains (France) recorded in two ombrotrophic peat bogs

Two peat sequences were sampled in the vicinity of the main mining districts of the Vosges Mountains: Sainte-Marie-aux-Mines and Plancher-les-Mines. Lead isotopic compositions and excess lead fluxes were calculated for each of these radiocarbon-dated sequences. Geochemical records are in very good agreement with the mining history of the area, well known over the last millennium. Except for an anomaly corresponding to the Middle Bronze Age which has not yet been resolved, there is no clear geochemical evidence of local metal production in the Vosges before the 10th century as excess lead deposition archived between 500 BC and 500 AD is attributed to long-range transport of polluted particulate matter. The approach described here can be applied to other mining districts where archaeological evidence is scarce or even lacking, but where past exploitation is suspected.     

Baseline determination of the atmospheric Pb,Sr and Nd isotopic compositions in the Rhine valley,Vosges mountains (France) and the Central Swiss Alps

The Pb, Sr and Nd isotopic compositions of biomonitors (lichen, moss, bark) and soil litter from different regions in the Rhine valley, as well as of <0.45 μm particles separated out of ice of the Rhône and Oberaar glaciers and lichens from the Swiss Central Alps, have been determined in order to deduce the natural baseline of the atmospheric isotopic compositions of these regions, which are suggested to be close to the isotopic compositions of the corresponding basement rocks or soils at the same sites. ²⁰⁶Pb/²⁰⁷Pb and ⁸⁷Sr/⁸⁶Sr isotope ratios are positively correlated. Most polluted samples from traffic-rich urban environments have the least radiogenic Pb and Sr isotopic compositions with ²⁰⁶Pb/²⁰⁷Pb and ⁸⁷Sr/⁸⁶Sr ratios of 1.11 and 0.7094, respectively. These ratios are very different from those of the atmospheric baseline for the Vosges mountains and the Rhine valley (²⁰⁶Pb/²⁰⁷Pb: 1.158–1.167; ⁸⁷Sr/⁸⁶Sr: 0.719–0.725; ε_Nd: −7.5 to −10.1). However, this study indicates that the baseline of the atmospheric natural Pb and Sr isotopic compositions is affected by anthropogenic (traffic, industrial and urban) emissions even in remote areas. Lichen samples from below the Rhône and Oberaar glaciers reflect the baseline composition close to the Grimsel pass in the Central Swiss Alps (⁸⁷Sr/⁸⁶Sr: 0.714 − 0.716; ε_Nd: −3.6 to −8.1). The ¹⁴³Nd/¹⁴⁴Nd isotope ratios are highly variable (8ε units) and it is suggested that the variation of the ¹⁴³Nd/¹⁴⁴Nd is controlled by wet deposition and aerosols originating from the regional natural and industrial urban environments and from more distant regions like the Sahara in North Africa. The least anthropogenetically affected samples collected in remote areas have isotopic compositions closest to those of the corresponding granitoid basement rocks.     

P-T-t-deformation paths recorded by kinzigites during diapirism in the western Variscan belt (Golfe du Morbihan, southern Brittany, France)

Abstract The high-grade metamorphic rocks of southern Brittany underwent a complex tectonic evolution under various P-T conditions (high-P, high-T), related to stacking of nappes during Palaeozoic continentcontinent collision. The east to west thrusting observed in the whole belt is strongly perturbed by vertical movements attributed to the ascent of anatectic granites in the high-T area. The field reconstruction of subvertical, closed elliptical structures in gneisses and migmatites, associated with the subhorizontal, doubly radial pattern of stretching lineation in the mica schists, suggests the existence of an elliptical diapiric body buried at depth beneath the present erosion level. Deformation is associated with a complex P-T evolution partly recorded in aluminous gneisses (kinzigites, e.g. morbihanites). A chronology of successive episodes of mineral growth at different compositions is established by detailed studies of the mineral-microstructure relationships in X-Z sections, using the deformation-partitioning concept (low- and high-strain zones). Several thermometric and barometric calibrations are applied to mineral pairs either in contact or not in contact but in equivalent microstructiiral positions with respect to the deformation history. This methodology provides a continuous microstructural control of P-T variations through time and leads to three P-T-t-d paths constructed from numerous successive P-T estimations. Path 1 is a clockwise retrograde path preserved in low-strain zones, which records general exhumation movements after crustal thickening. Paths 2 and 3 are clockwise prograde/retrograde paths from high-strain zones; they are interpreted and discussed in the light of models of crustal anatexis and upward movement of magma (diapirism). Deformation and P-T effects induced by diapirism can be distinguished from the general deformation-metamorphic history of a belt, and would seem to be produced during a late stage of its history. The present microstructural-petrological approach to defining successive mineral equilibria in relation to progressive deformation steps provides a far more accurate evaluation of the metamorphic evolution than is possible by ‘standard’thermobarometry.     

Gravelly flood deposits of Irvine Creek, Ontario, Canada

In May 1974 a powerful flood flushed the Grand River basin, Ontario. The effects on the bedload were drastic in a narrow (30 m) and deep (40 m) rock walled and floored gorge near Elora, Ontario. Along Irvine Creek, the tributary occupying the gorge, the gravel cover was reworked in several types of bars, predominantly transverse and point bars. The bars formed very rapidly in response to essentially steady, non-uniform flow that developed during a brief period of high flood. Superimposed on major bars are several minor sedimentary features such as coarse transverse ribs, chute channels and bars, longitudinal ribs, imbrication clusters, backsets with well developed imbrication, that were formed under very high stream discharge. Structures like imbrication clusters, transverse ribs and small riffle bars require a ‘live bed’ situation to form, and they develop when stones come to a stop either because they cluster during transport, or because keystone effects occur along shallow channels. In Irvine Creek, very few sedimentary features were formed during waning and low flood stages: only some shadow deposits and a few Ostler lenses. The few fines that were available were lost downstream or filled in lower parts of gravel beds. This study confirms that in streams that experience strong seasonal fluctuations in discharge, bedforms that develop during high floods have a high probability of preservation. In gravelly deposits, foreset structures and plane beds are most commonly preserved, although they may be difficult to recognize in old deposits, which may appear massive, particularly if the gravel has been infilled with finer pebbles and sand. In the case of Irvine Creek, all deposits are organized, and lateral and vertical variations in textures, particularly imbrication and packing, are very useful in the recognition of sedimentary structures.     

Rossberg landslide history and flood chronology as recorded in Lake Lauerz sediments (Central Switzerland)

The southern slopes of Rossberg mountain, Central Switzerland, on which one of the largest historic landslides of the Alpine region was released in 1806 ad (Goldauer Bergsturz), are prone to large-scale mass wasting processes. This has led to numerous sliding events, which are well-recognizable in the modern topography but lack accurate dating. In order to provide new insights into the timing and the processes associated with past landslides as well as into the frequency of exceptional flood events, long sediment cores were retrieved from the subsurface of Lake Lauerz that lies in the pathway of these landslides and that records strong runoff events with typical flood layers. Analyses of the recovered cores display a sedimentologic succession with variable fingerprints of past landslides and flood events, depending on the coring location within the lake. The landslide signature can be calibrated using the 1806 ad event: An organic-rich peaty unit, which is found in two cores located close to the rockmass impact, points towards a sudden, gravity spreading-induced lateral displacement of the swampy plain where parts of the rock mass were accumulating. This rapid lateral mobilization of soft sediments, and not the rock masses, acted as ultimate trigger for the reported ~15 m-high impulse waves on the lake. In the more distal areas, the 1806 ad event led to the deposition of a thick, organic-rich redeposited layer. The 10 m-long core from the distal basin covers a radiocarbon-dated ~2,000 years sedimentation history and contains a highly similar event layer that was deposited in 810 ± 60 ad. This layer is most likely the product of a major historic landslide, known as Röthener Bergsturz, which, based on scarce historical reports, was commonly dated to 1222 ad. In the 2,000 years record, we identify three periods with enhanced occurrence of flood turbidites dated to 580–850 ad, 990–1420 ad, and 1630–1940 ad. Among the 54 detected flood layers, 6 probably mark exceptionally heavy rainfall events that are dated to ~610, ~1160, ~1290, ~1660, ~1850, and ~1876 ad, the latter being associated to one of the most intense rainfall events ever recorded instrumentally in the region.     

Characterization and correlation of Upper Jurassic (Oxfordian) bentonite deposits in the Paris Basin and the Subalpine Basin, France

Abstract Explosive volcanic activity is recorded in the Upper Jurassic of the Paris Basin and the Subalpine Basin of France by the identification of five bentonite horizons. These layers occur in Lower Oxfordian (cordatum ammonite zone) to Middle Oxfordian (plicatilis zone) clays and silty clays deposited in outer platform environments. In the Paris Basin, a thick bentonite (10–15 cm), identified in boreholes and in outcrop, is dominated by dioctahedral smectite (95%) with trace amounts of kaolinite, illite and chlorite. In contrast, five bentonites identified in the Subalpine Basin, where burial diagenesis and fluid circulation were more important, are composed of a mixture of kaolinite and regular or random illite/smectite mixed-layer clays in variable proportions, indicating a K-bentonite. In the Subalpine Basin, a 2–15 cm thick bentonite underlain by a layer affected by sulphate–carbonate mineralization can be correlated over 2000 km². Euhedral zircon, apatite and biotite crystals have been identified in all the bentonites. The geochemical composition of the bentonites in both basins is characterized by high concentrations of Hf, Nb, Pb, Ta, Th, Ti, U, Y, Zr and low concentrations of Cr, Cs and Rb. Biostratigraphical and geochemical data suggest that the thick bentonite in the Paris Basin correlates with the thickest bentonite in the Subalpine Basin, located 400 km to the south. These horizons indicate that significant explosive volcanic events occurred during the Middle Oxfordian and provide potential long-distance isochronous marker beds. Immobile element discrimination diagrams and rare-earth element characteristics indicate that the original ash compositions of the thickest bentonites correspond to a trachyandesitic source from a within-plate alkaline series that was probably related to North Atlantic rifting.     

High-resolution analysis of submarine lobes deposits: Seismic-scale outcrops of the Lauzanier area (SE Alps, France)

The Lauzanier area represents the northernmost extension of the Annot Sandstone series and contains deposits between 650 and 900 m-thick. This basin was active from upper Bartonian or lower Priabonian to early Rupelian. It is composed of two superposed units separated by a major unconformity. The sediment supply is due to channelled flows coming from the south. Flow processes include mass flow to turbidity currents. The size of the particles and the absence of fine-grained sediment suggest a transport over a short distance. The Lower Unit is made of coarse-grained tabular beds interpreted as non-channelled lobe deposits. The Upper Unit is made of massive conglomerates interpreted as the channelled part of lobes. These lobe deposits settle in a tectonically confined basin according to topographic compensation that occurs from bed scale to unit scale. The abrupt progradation between the lower and the upper unit seems related to a major tectonic uplift in the area. This uplift is also suggested by a change in the petrographic nature of the source and an abrupt coarsening of the transported clasts.This field example allows providing high resolution analysis for depositional sedimentary sequences of terminal lobe deposits in a coarse-grained turbidite system. The outcrop analysis shows the lateral evolution of deposits and the system progradation allows a longitudinal analysis of facies evolution by superposing on the same outcrops the channelled lobe system and the non-channelled lobe system. These results of high-resolution outcrop analysis can be extrapolated to results obtained on sedimentary lobes in recent deep-sea turbidite system that are either restricted to cores, or with a lesser resolution (seismic).     

Palaeoceanography of the Miocene (Tortonian) deposits of the Pre-Apulian zone,western Greece,as recorded by foraminifer and stable isotope records

An integrated faunal and geochemical dataset has been generated by the study of a late Miocene (early Tortonian) sedimentary section outcropping at Manassi, Levkas Island (eastern Mediterranean). Quantitative analysis of benthic foraminifers from the 25-m-thick section indicates changes of bottom palaeoecological conditions in this part of the eastern Mediterranean, during the analyzed time interval. Benthic foraminifer assemblages are typical of a bathyal environment and testify to relatively oxygenated conditions with low to moderate food supply alternating with periods with an increase in organic matter content. The long-term palaeoceanographic analyses indicate an anti-estuarine circulation model based on the benthic foraminifer and stable isotope results, which evolved in a strong estuarine circulation. The positive relationship existing between the plankton δ¹⁸O and δ¹³C, in most of the record, agrees well with the hypothesis of a variable contribution of runoff. In three stratigraphic levels, samples record heavy bottom water δ¹⁸O and δ¹³C values and light surface δ¹⁸O values, representing a wet, warm, estuarine climate with a stratified water column. In two stratigraphic levels, samples have depleted δ¹³C and δ¹⁸O values for both surface and bottom waters. These two samples represent wet, warm climates with some ocean mixing and stratification. The stable isotope signal of foraminifer tests from the Manassi section was influenced by the global temperature changes, but the local factors also played an important role. The palaeoenvironments derived from stable isotope analysis in this study are interpreted as responses to the local tectonic instability together with monsoon intensities that enhanced continental runoff, characteristic for the time interval studied in the study area. Due to the limited data available from this study, no correlations with the precessional, obliquity, or eccentricity cycles can be made.     

Variability of the metal content of flood deposits

Fresh flood deposits were sampled in the flood-plains of two river systems, the River Meuse, with a catchment area of 33,000 km² and the River Geul, with a catchment area of 3,000 km². As a result of industrial and mining activities, both rivers have a history of severe metal pollution, especially with zinc, lead, and cadmium. The flood deposits of both rivers are heterogeneous mixtures of contaminated bottom sediments (with relatively long residence times in the river) and clean sediments derived from soil erosion on agricultural cropland (with very short residence times). An additional source of sediment is formed by erosion of older, locally highly contaminated streambank deposits. These older sediments are polluted as a result of solid waste disposal containing metalliferous ore and tailings in the sand fraction. This is especially the case in the River Geul, which drains an old zinc and lead mining area. The metal content of the Meuse sediments, however, originates largely from liquid industrial wastes and occurs mainly in the clay fraction. For this reason, the positive correlation between textural composition, organic matter content, and heavy metal concentration, which is often reported, was not observed, and normalization of the metal content was not possible. Nevertheless, a clear decrease of contamination was noticed along the River Geul; this trend was absent along the River Meuse. An attempt has been made to model the longitudinal decay pattern for each of the investigated havey metals.     

Barite deposits of the “Montagne Noire”, Southern France

Several small barite deposits of Devonian age are known in the Monts de Cabrières region, Montagne Noire (southern France). A field and laboratory investigation of these stratabound deposits showed their possible diagenetic origin and a limited economic value.

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Zusammenfassung De petits gisements de barytine du Dévonien dans les Monts de Cabrières (Montagne Noire, France) ont été étudié en détail sur le terrain et au laboratoire. Les observations ont apporté des critères pour une explication génétique de ces gisements «stratiformes». Ils indiquent que les concentrations minérales se sont effectuées par un processus de sécrétion au cours de la diagenèse. L'importance économique de ces gisements est limitée.

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...es ist zwar nicht sinnlos, aber doch etwas unlogisch, wenn man von vornherein nicht versucht, eine Lagerstätte in ihre Umgebung auf die wahrscheinlichste Art einzugliedern, sondern sie unbedingt einem ganz fremden, zunächst nicht von selbst verständlichen Bildungsvorgang zuordnen will. H. Schneiderhöhn (1954)     

Characterization of low-molecular-weight organic acids isolated from the Toarcian argillite pore water (Tournemire site,France)

Bacterial activity in the near-field environment of radioactive waste disposal facilities in deep argillaceous rocks is currently under investigation. Bacterial development could be enhanced by the availability of low-molecular-weight organic acids (LMWOA) dissolved in the pore water of clayey rocks. This study firstly aimed at isolating and characterizing the LMWOA of the Toarcian argillite from the Tournemire Underground Research Laboratory (France, Aveyron). It also aimed at assessing the disturbing effects that could be induced by a disposal facility on the type and release of LMWOA (exposure to oxygen, alkaline pH, temperature increase). Under the experimental conditions investigated at 60 °C, the mean dissolved organic carbon (DOC) is about 15 mg L⁻¹ with a LMWOA proportion of 35 %. The main LMWOA are composed of formate, fumarate, propionate, acetate, and lactate. DOC is mainly influenced by both temperature and pH increases, whereas the LMWOA type nature and release are more specifically affected by the exposure to oxygen.     

Downstream changes of total and partitioned metal concentrations in the flood deposits of the river Geul (The Netherlands)

The floodplain soils in the Guel basin have unacceptably high levels of pollution,v brought about by metal mining and related industrial activities in the past. Spoil heaps still exist along the Geul river and these are susceptible to erosion and leaching processes. An additional source of metals is formed by erosion of older, locally highly contaminated streambank deposits. These older sediments are polluted as a result of solid waste disposal containing metalliferous ore and tailings in the sand fraction. At present, these sediments function as a major source of heavy metals during high flow stages when streambanks are undermined and suspended sediments are deposited on the floodplains. The flood deposits have a relatively coarse texture, i.e. 70% dry weight in the fraction > 63 um.In order to obtain an indication about the potential mobility of the heavy metals in these deposits, 16 samples (8 samples < 63 um and 8 samples > 63 um) out of a set of 122 were subjected to a sequential extraction scheme as proposed by Calmano & Förstner (1983). It was found that up to 80% of the metals may be present in the first three leaching stages (exchangeable cations, carbonate fraction and easily reducible fraction) and that hardly any difference exists between the chemical partitioning of metals in the size fractions < 63 um and > 63 um. Moreover, as the total metal concentrations exponentially decrease along the 40 km distance away from the source area, the percentage of metals in these 3 potentially mobile fractions steadily increases. It is concluded that despite the rapid decay of total metal concentrations, Large amounts of potentially mobile metals are probably stored in the floodplain sediments even at a large distance from the source area.