Characterization and identification of na-cl sources in ground water

Elevated concentrations of sodium (Na+) and chloride (Cl-) in surface and ground water are common in the United States and other countries, and can serve as indicators of, or may constitute, a water quality problem. We have characterized the most prevalent natural and anthropogenic sources of Na+ and Cl- in ground water, primarily in Illinois, and explored techniques that could be used to identify their source. We considered seven potential sources that included agricultural chemicals, septic effluent, animal waste, municipal landfill leachate, sea water, basin brines, and road deicers. The halides Cl-, bromide (Br), and iodide (I) were useful indicators of the sources of Na+-Cl- contamination. Iodide enrichment (relative to Cl-) was greatest in precipitation, followed by uncontaminated soil water and ground water, and landfill leachate. The mass ratios of the halides among themselves, with total nitrogen (N), and with Na+ provided diagnostic methods for graphically distinguishing among sources of Na+ and Cl- in contaminated water. Cl/Br ratios relative to Cl- revealed a clear, although overlapping, separation of sample groups. Samples of landfill leachate and ground water known to be contaminated by leachate were enriched in I and Br; this provided an excellent fingerprint for identifying leachate contamination. In addition, total N, when plotted against Cl/Br ratios, successfully separated water contaminated by road salt from water contaminated by other sources.     

Emerging Contaminants at a Closed and an Operating Landfill in Oklahoma

Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty‐eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.     

The Geochemistry of Boron in a Landfill Monitoring Program

Ground water monitoring data collected during the past eight years at a permitted municipal solid waste (MSW) disposal facility located in the midwestern United States indicated fluctuations in typical leachate indicator parameter concentrations. Apparent trends in the data inferred leachate outbreak, generating suspicion as to the integrity of the landfill liner. Eight ground water monitoring wells were installed in three distinct geologic units at the landfill facility, including glacial drift, silurian dolomite, and a post-glacial peat fen, which is downgradient from the landfill. Piezometer nests were used to define ground water gradients at the site. Using boron as an indicator, the occurrence of analytes of concern in the downgradient monitoring wells were shown to be indicative of the natural geochemistry of site ground water. This work emphasizes the importance of understanding site hydrogeology during the interpretation of ground water quality data.     

Options for the Treatment and Management of Municipal Landfill Leachate: Common and Specific Issues

This paper aims to explore information from the literature for emphasizing the state‐of‐the art and progress in landfill leachate generation, fate and migration, and treatment. Leachate composition is discussed in terms of types of waste disposed and the processes occurring within landfill. The focus is also on potential pathways of environmental contamination by leachate, which may increase environmental and human health risk. The analysis addresses the opportunity and support for decision making concerning alternatives for leachate management and treatment. Advantages and limitations of treatment methods and processes are discussed considering leachate transfer, physico‐chemical methods, biodegradation, and combined methods.     

Characterization of a dismissed landfill via electrical resistivity tomography and mise-à-la-masse method

Electrical resistivity methods are widely used for environmental applications, and they are particularly useful for the characterization and monitoring of sites where the presence of contamination requires a thorough understanding of the location and movement of water, that can act as a carrier of solutes. One such application is landfill studies, where the strong electrical contrasts between waste, leachate and surrounding formations make electrical methods a nearly ideal tool for investigation. In spite of the advantages, however, electrical investigation of landfills poses also challenges, both logistical and interpretational. This paper presents the results of a study conducted on a dismissed landfill, close to the city of Corigliano d'Otranto, in the Apulia region (Southern Italy). The landfill is located in an abandoned quarry, that was subsequently re-utilized about thirty years ago as a site for urban waste disposal. The waste was thought to be more than 20 m thick, and the landfill bottom was expected to be confined with an HDPE (high-density poli-ethylene) liner. During the digging operations performed to build a nearby new landfill, leachate was found, triggering an in-depth investigation including also non-invasive methods. The principal goal was to verify whether the leachate is indeed confined, and to what extent, by the HDPE liner. We performed both surface electrical resistivity tomography (ERT) and mise-à-la-masse (MALM) surveys, facing the severe challenges posed by the rugged terrain of the abandoned quarry complex. A conductive body, probably associated with leachate, was found as deep as 40 m below the current landfill surface i.e. at a depth much larger than the expected 20 m thickness of waste. Given the logistical difficulties that limit the geometry of acquisition, we utilized synthetic forward modeling in order to confirm/dismiss interpretational hypotheses emerging from the ERT and MALM results. This integration between measurements and modeling helped narrow the alternative interpretations and strengthened the confidence in results, confirming the effectiveness of non-invasive methods in landfill investigation and the importance of modeling in the interpretation of geophysical results.     

Elements in Cottonwood Trees as an Indicator of Ground Water Contaminated by Landfill Leachate

Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site.
Leaf samples of broad-leafed cottonwood, Populus deltoides , were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or "well plant," functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby.
Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.     

Pre‐treatment of Waste Foundry Sand Via Solidification/Stabilization

This study was performed to propose a suitable treatment for waste foundry sand (WFS) before persistent disposal. It was observed that solidification/stabilization (S/S), which is the common pre‐treatment method because of its comparatively easy and inexpensive applicability, can treat WFS including dissolved organic carbon (DOC) above hazardous landfilling limits. Regular sand was partially replaced with WFS with a ratio of 0–90 wt% in order to prepare three different kinds of mortar samples, where Portland limestone cement (PLC) alone, calcium lime (CL) alone, and PLC together with CL were contained as binders. Leaching behaviors of all S/S products were analyzed according to the TS EN 12457‐4 leaching test. The treatment efficiency was assessed to reduce the DOC content to the levels under the European landfill acceptance criteria. Furthermore, heavy metals (Ni, Zn, Cr), fluoride (F^?), total dissolved solids leachability, and total organic carbon content were analyzed in order to investigate the pre‐treatment ability and to determine whether S/S products can be disposed of in a landfill site with municipal wastes or in a separate landfill site. The results showed that S/S of WFS is an efficient pre‐treatment technique before its disposal in a landfill and provides economical advantages compared to hazardous waste landfilling.     

Decision Analysis for Leachate Control at a Fractured Rock Landfill

The municipal landfill at the Complexe Environnemental de Saint-Michel (CESM) in Montreal, which is the third largest in North America, is located in a former quarry in fractured limestone. Impressive measures are taken to monitor and control biogas and leachate generated at the site. Leachate containment is presently performed with a pumping well completed within the waste. The efficiency of the well in controlling off-site leachate migration is questioned because field observations strongly suggest that the nearby former Francon quarry is diverting local ground water flow. To address this issue, four additional hydraulic control options are considered: (1) increased pumping at the existing waste well; (2) new pumping wells in the rock on the eastern limit of the site; (3) new injection wells in the rock on the eastern limit; and (4) combination of new injection wells at the same location and new water supply wells upgradient of the landfill. We evaluated the four hydraulic control options at the CESM using two coupled models: (1) a decision model based on an objective function weighting the risk, costs, and benefits of each option translated into dollar units; and (2) a numerical ground water flow model to represent the effect of operational conditions and ascertain success. Decision analysis offers a quantitative unbiased tool to evaluate the potential and relative cost of each option, but qualitative considerations and judgment still must be used for a complete evaluation. Our analysis confirms that scenario 4, which was the intuitively favored option, represents the best containment strategy.     

Nitrogen Removal from Landfill Leachate Using an Infiltration Bed Coupled with a Denitrification Barrier

Treatment of nitrogen in landfill leachate has received considerable attention recently because of the relatively low levels at which some nitrogen species (i.e., NH3) can be toxic to aquatic life forms. This study reports on the results of a three-year, pilot-scale field trial demonstrating the use of infiltration bed and nitrate barrier technology to achieve nitrogen removal in landfill leachate. The infiltration bed comprises an unsaturated sand layer overlying a saturated layer of waste cellulose solids (sawdust), which acts as a carbon source for heterotrophic denitrification. When loaded at a rate of 1 to 3 cm/day, the infiltration bed was successful at lowering leachate inorganic nitrogen (NH₄⁺+ NO₃^-) levels averaging 24.8 mg/L N by 89%, including 96% in the third year of operation. The surface water discharge criteria for un-ionized ammonia (NH3) were met on all occasions in the treated leachate during the second and third years of operation. Nitrogen attenuation is presumed to occur by a two-step process in which leachate NH₄⁺ is first oxidized to NO₃^- in the unsaturated sand layer and then is converted to nitrogen gas (N₂) by denitrification occurring in the underlying sawdust layer. Mass balance calculations suggest that the sawdust layer has sufficient carbon to allow denitrification to proceed for long periods (1.0 to 30 years) without replenishment. Because this technology is simple to construct and is relatively maintenance free, it should be attractive for use at smaller landfills where the installation of conventional treatment plants may not be feasible.     

Bioattenuation in groundwater impacted by landfill leachate traced with δ13C

The impact on groundwater imparted by the infiltration of high dissolved organic carbon (DOC) leachate from capped, unlined landfills can be attenuated by biogeochemical reactions beyond the waste source, although such reactive loss in the aquifer is difficult to distinguish from conservative advective dispersion. Compound-specific measurement of δ(13)C in carbon species, including CH(4), dissolved inorganic carbon (DIC), and the major DOC compounds (acetate, humic acid, and fulvic acid) provides a constraint in this assessment that can assist in exercises of modeling and prediction of leachate transport. The Trail Road municipal landfill near Ottawa, Ontario, Canada, hosts an unlined sector which produces a highly enriched leachate (DOC >4500 mg/L) that provides a good site to examine reactive attenuation within the receptor aquifer. Acetate, a sentinel component of leachate DOC (~1000 mg C/L), is absent in impacted groundwater. Mass balance calculations together with reaction modeling suggest continued acetate fermentation with calcite control on DIC and δ(13)C(DIC) evolution. In groundwater within 50 m of the landfill, methane concentrations are elevated (~10 mg/L), consistent with acetate fermentation, whereas δ(13)C(CH4) measurements in deeper groundwater range down to -51‰ compared with -60‰ in the landfill demonstrating oxidative loss. DOC in the deep aquifer is remarkably depleted to values less than -40‰ suggesting methanotrophic bacteria selectively consume isotopically light CH(4) to fix carbon. Continued reaction of leachate DOC in groundwater is demonstrated by evolution away from conservative mixing lines on diagrams of δ(13)C vs. concentrations of DIC and DOC.     

A Risk-Based Approach for Managing Hazardous Waste

In 1992, the U.S. Environmental Protection Agency (EPA) proposed risk-based management of hazardous waste. A major component of the proposed rule is the determination of non-site- specific screening concentration levels from waste leachate. Ground water at a downgradient exposure point must not exceed those screening levels, or more stringent requirements would apply.
The screening concentration level is determined with verified models and equations that simulate the transport and attenuation of chemicals as they travel from the source area to the exposure point. A consortium of screening levels is determined in this paper by considering varying physical, chemical, and biological conditions. In addition, a method is developed for multi component leaching from contaminated soils in a landfill to determine the time-dependent behavior of a finite source. Finally, this paper discusses infiltration rate through the clay liner.     

基于水文-地球物理模型的地下水污染磁电阻率异常动态监测仿真

We present a forward-modeling investigation of time-dependent ground magnetometric resistivity （MMR） anomalies associated with transient leachate transport in groundwater systems. Numerical geo-electrical models are constructed based on the hydrological simulation results of leachate plumes from a highly conceptualized landfill system and the resultant MMR responses are computed using a modified finite difference software MMR2DFD. Three transmitter configurations （i.e., single source, MMR-TE, and MMR-TM modes） and two hydrological models （i.e., uniform and faulted porous media） are considered. Our forward modeling results for the uniform porous medium indicates that the magnetic field components perpendicular to the dominant current flow contain the most information of the underground targets and the MMR-TE mode is an appropriate configuration for detecting contaminant plumes. The modeling experiments for the faulted porous medium also confirm that the MMR method is capable of mapping and monitoring the extent of contaminant plumes in aroundwater systems.     

Artificial Sweeteners Identify Spatial Patterns of Historic Landfill Contaminated Groundwater Discharge in an Urban Stream

Leachate-contaminated groundwater from historical municipal landfills, typically lacking engineered liners and leachate collection systems, poses a threat to nearby urban streams, particularly to benthic ecosystems. Effective monitoring and assessment of such sites requires understanding of the spatial patterns (i.e., two-dimensional footprint) of contaminated groundwater discharge and associated controlling factors. However, discharges from groundwater contaminated by modern wastewater can complicate site assessments. The objectives of this study were to (1) demonstrate the use of artificial sweeteners (AS): saccharin (SAC), cyclamate (CYC), acesulfame (ACE), and sucralose (SUC), to distinguish groundwater discharge areas influenced by historic landfill leachate (elevated SAC and sometimes CYC; low ACE and SUC concentrations) from those influenced by wastewater (high ACE and SUC concentrations), and (2) investigate contaminant discharge patterns for two gaining urban stream reaches adjacent historic landfills at base flows. Contaminant discharge patterns revealed by the AS were strongly controlled by hyporheic flow (low AS concentrations), particularly for the straight reach, and stream sinuosity, particularly for the meandering reach. These patterns were different and the contaminant footprint coverage (<25% of streambed area) much less than most past studies (typically >50% coverage), likely due to the homogeneous streambed-aquifer conditions and shallow, narrow landfill plume in this setting.     

A Graphical Approach for Determining Dilution-Attenuation Factors: Basic Theory and Approach for Submerged Sources

The dilution attenuation factor (DAF) is a quantity used to relate the concentration of leachate leaving a source zone (e.g., landfill, impoundment, or contaminated soils) to its impact on down-gradient ground water quality. The DAF is of importance because it plays a key role in U.S. Environmental Protection Agency (EPA)'s methodologies for developing soil cleanup goals and for managing hazardous wastes. In this work, a simplistic graphically-based approach for determining site-specific and generic DAFs was developed. In this case the DAF is based on time-and vertically-averaged concentrations along the plume centerline, and the mathematical framework employs well-known analytical and semianalytical solutions for dissolved contaminant transport. Finite sources with a range of decay characteristics are allowed for. One unique feature of this work is that the graphical approach allows for varying levels of sitespecificity, and thus can be used when one has a little, or a lot, of site-specific information. The graphs visually indicate the sensitivity to various parameters, which is valuable information not easily gleaned from most numerical software simulators. This approach is, however, not applicable to very complex hydrogeologic settings (e.g., fractured geology), or to ground water flows that cannot be reasonably approximated as one-dimensional.     

The Effect of Fatty Acid Diffusion in Leachate on the Propagation of Concentration Waves in the Process of Municipal Solid Waste Decomposition

A distributed model of municipal solid waste decomposition is proposed. The main model parameters are concentrations of municipal solid waste, volatile fatty acids, and the biomass of methane-producing microorganisms. Numerical analysis of the model is made. Diffusion of fatty acids in leachate, which facilitates the formation of anaerobic conditions, is shown to cause the formation of concentration chemical waves propagating in the space. The area of initiation methane production is found to expand.     

ISMISIP: an inexact stochastic mixed integer linear semi-infinite programming approach for solid waste management and planning under uncertainty

An inexact stochastic mixed integer linear semi-infinite programming (ISMISIP) model is developed for municipal solid waste (MSW) management under uncertainty. By incorporating stochastic programming (SP), integer programming and interval semi-infinite programming (ISIP) within a general waste management problem, the model can simultaneously handle programming problems with coefficients expressed as probability distribution functions, intervals and functional intervals. Compared with those inexact programming models without introducing functional interval coefficients, the ISMISIP model has the following advantages that: (1) since parameters are represented as functional intervals, the parameter’s dynamic feature (i.e., the constraint should be satisfied under all possible levels within its range) can be reflected, and (2) it is applicable to practical problems as the solution method does not generate more complicated intermediate models (He and Huang, Technical Report, 2004; He et al. J Air Waste Manage Assoc, 2007). Moreover, the ISMISIP model is proposed upon the previous inexact mixed integer linear semi-infinite programming (IMISIP) model by assuming capacities of the landfill, WTE and composting facilities to be stochastic. Thus it has the improved capabilities in (1) identifying schemes regarding to the waste allocation and facility expansions with a minimized system cost and (2) addressing tradeoffs among environmental, economic and system reliability level.     

Natural attenuation of volatile organic compounds (VOCs) in the leachate plume of a municipal landfill: using alkylbenzenes as process probes

More than 70 individual VOCs were identified in the leachate plume of a closed municipal landfill. Concentrations were low when compared with data published for other landfills, and total VOCs accounted for less than 0.1% of the total dissolved organic carbon. The VOC concentrations in the core of the anoxic leachate plume are variable, but in all cases they were found to be near or below detection limits within 200 m of the landfill. In contrast to the VOCs, the distributions of chloride ion, a conservative tracer, and nonvolatile dissolved organic carbon, indicate little dilution over the same distance. Thus, natural attenuation processes are effectively limiting migration of the VOC plume. The distribution of C2-3-benzenes, paired on the basis of their octanol-water partition coefficients and Henry's law constants, were systematically evaluated to assess the relative importance of volatilization, sorption, and biodegradation as attenuation mechanisms. Based on our data, biodegradation appears to be the process primarily responsible for the observed attenuation of VOCs at this site. We believe that the alkylbenzenes are powerful process probes that can and should be exploited in studies of natural attenuation in contaminated ground water systems.     

Some Advantages of the Duckweed Test to Assess the Toxicity of Environmental Samples

In Germany, wastewater legislation requires all municipal and industrial leachate to be subjected to toxicity tests. However, no phytotoxicity tests using higher plants are currently included among the standard tests. Freshwater microalgae have been used in most phytotoxicity tests and have often been considered as surrogates for higher plants. However, microalgae often do not show the same sensitivity as higher plants and have major disadvantages for the testing of unmodified environmental samples. In the following study, we evaluated the suitability of the giant duckweed Spirodela polyrhiza for assessing the toxicity of a municipal landfill leachate and two leachates of copper mining residue. Duckweed static toxicity tests were performed, and frond number was the endpoint used to calculate EC₅₀ values. Symptoms of stress (chlorosis, necrosis, root destruction, and colony breakup) were also recorded. The landfill leachate was toxic with EC_50;96h values ranging from 1.3 to 2.7% leachate (v/v). Toxicity of the copper slag leachate was largely determined by the elution method used. Leachate obtained using conventional German leaching methods (S4-eluate) was not toxic to duckweed, whereas EC₅₀ values for the pH_stat4-eluate ranged from 3.2 to 4.2% leachate (v/v). The results demonstrate the suitability of S. polyrhiza for the testing of unmodified wastewater samples and provide further evidence for the addition of a duckweed toxicity test to the standard tests conducted in Germany.     

Field and large scale laboratory studies on dynamic properties of emplaced municipal solid waste from two dump sites at Delhi,India

Dynamic properties of municipal solid waste (MSW) from two dump sites located at Delhi, India are evaluated from field and large scale laboratory tests. Shear wave velocity (V_s) profiles of MSW, measured at these two sites using surface wave techniques, are in range of V_s data reported for MSW landfills worldwide. Representative bulk MSW samples were collected from large test pits excavated at the two dump sites to determine the near surface unit weight. Large scale undrained cyclic triaxial (CTX) tests were conducted on reconstituted MSW specimens to investigate the effect of various parameters such as composition, confining pressure, number of loading cycles, loading frequency and saturation on the dynamic properties. Undrained CTX tests, conducted on the specimens with and without fibrous materials demonstrated the effect of fibrous waste constituents on the stiffness and damping behavior of MSW. Specimens consisting of fibrous waste constituents such as plastics and textiles exhibited significantly less modulus reduction compared to specimens with negligible amount of fibrous content. The modulus reduction (G/G_max) and material damping ratio curves derived from the present study are in the range reported for MSW in the literature. The G/G_max curves from present study are in good agreement with curves recommended for MSW at Tri-Cities landfill in USA and Tianziling landfill in China. Dynamic properties evaluated from the present study add to the growing database of the worldwide dataset and can be useful for evaluating the seismic stability and associated permanent deformations of the existing dumps in and around Delhi.     

Syringe‐Tip Filters May Contain the Artificial Sweetener Saccharin

The presence of artificial sweeteners in environmental samples is increasingly used to detect wastewater (and recently landfill leachate) in rivers, lakes and groundwater. Through routine laboratory quality assurance/quality control procedures, it was discovered that some syringe‐tip filters leach saccharin when used to process water samples. We subsequently tested several brands of filters to determine if they leached any of the four common artificial sweeteners analyzed in environmental samples, acesulfame, saccharin, cyclamate, and sucralose. Of the six types of filters tested, only one brand was a source of artificial sweeteners and the only artificial sweetener found was saccharin. The source of the saccharin in the filters is unknown but it is likely the result of some step in the manufacturing process. The saccharin was typically removed from these filters using a distilled water rinse of 13 mL or less. As a precaution, filters should be pre‐tested for the presence of saccharin and/or filters should be flushed with distilled water or sample prior to the collection of water samples for artificial sweetener analyses.