Element geochemistry of weathering profile of dolomitite and its implications for the average chemical composition of the upper-continental crust--Case studies from the Xinpu profile,northern Guizhou Province,China

Geochemical behavior of chemical elements is studied in a dolomitite weathering profile in upland of karst terrain in northern Guizhou.Two stages can be recognized during the process of in situ weathering of dolomitite:the stage of sedentary accumulation of leaching residue of dolomitite and the stage of chemical weathering evolution of sedentary soil.Ni,Cr,Mo,W and Ti are the least mobile elements with reference to Al.The geochemical behavior of REE is similar to that observed in weathering of other types of rocks.Fractionation of REE is noticed during weathering,and the two layers of REE enrichments are thought to result from downward movement of the weathering front in response to changes in the environment.It is considered that the chemistry of the upper part of the profile,which was more intensively weathered,is representative of the mobile components of the upper curst at the time the dolomitite was formed,while the less weathered lower profile is chemically representative of the immobile constitution.Like glacial till and loess,the "insoluble" materials in carbonate rocks originating from chemical sedimentation may also provide valuable information about the average chemical composition of the upper continental crust.     

Structure and composition of the continental crust in East China

Crustal structures of nine broad tectonic units in China, except the Tarim craton, are derived from 18 seismic refraction profiles including 12 geoscience transects. Abundances of 63 major, trace and rare earth elements in the upper crust in East China are estimated. The estimates are based on sampling of 11 451 individual rock samples over an area of 950 000 km², from which 905 large composite samples are prepared and analyzed by 13 methods. The middle, lower and total crust compositions of East China are also estimated from studies of exposed crustal cross sections and granulite xenoliths and by correlation of seismic data with lithologies. All the tectonic units except the Tarim craton and the Qinling orogen show a four-layered crustal structure, consisting of the upper, middle, upper lower, and lowermost crusts. P-wave velocities of the bulk lower crust and total crust are 6.8–7.0 and 6_:4–6.5 km/s, respectively. They are slower by 0.2–0.4 km/s than the global averages. The bulk lower crust is suggested to be intermediate with 58% SiO₂ in East China. The results contrast with generally accepted global models of mafic lower crusi. The proposed total crust composition in East China is also more evolved than previous estimates and characterized by SiO₂=64%, a significant negative Eu anomaly (Eu/Eu* = 0.80), deficits in Sr and transition metals, a near-arc magma La/Nd ratio (3.0), and a calculatedμ(²³⁸U/²⁰⁴Pb) value of 5. In addition, it has the following ratios of element pairs exhibiting similar compatibility, which are identical or close to the primitive mantle values: Zr/Hf=37, Nb/Ta=17.5, Ba/Th=87, K/Pb=0.12x10⁴, Rb/Cs=25, Ba/Rb=8.94, Sn/Sm=0.31, Se/Cd=1.64, La/ As=10.3, Ce/Sb=271, Pb/Bi=57, Rb/TI=177, Er/Ag=52, Cu/Au=3.2×10⁴, Sm/Mo=7.5, Nd/W=40, CI/Li=10.8, F/Nd=21.9, and La/B=1.8. Project supported by the National Natural Science Foundation of China (Grant Nos. 49625305, 49573183, 49673184, 49794043), the State Comission of Education, the Ministry of Geology and Mineral Resources of China (Grant No. 850514), the Open Laboratory of Constitution, Interaction and Dynamics of the Crust-Mantle System, and the Alexander-von-Humboldt Foundation of Germany.     

Geochemical studies on the intensity of chemical weathering in Luochuan loess-paleosol sequence, China

Major and trace element analyses of the Luochuan loess-paleosol sequence in China were performed in order to understand the cheniical weathering processes occurring on the I.oess Plateau during the last 600 ka. Results reveal that most elements in the loess remain immobile durlng chemical weathering. The typical stable elements are Al, K, Ti, Rb and REE, while the main mobile elements are Ca, Sr, P, Mg and Na. 120ess and paleosol experience the incipient stage of chemical weathering characterized by acid leaching and carbonate dissolution. Alteration of silicates in the sequence seems to be limited. Features of less chemical weathering of the loess and paleosol could he indicators for the dry-cold clinlate dominated on the Loess Plateau during the Quaternary. Project supported hy thc Nzitional Natural Science Foundation of China     

Chemical composition of upper crust in eastern China

In an area of 3.3×10⁶ km² within eastern China, 28 253 rock samples were collected systematically and combined into 2718 composite samples which were analyzed by 15 reliable methods using national preliminary certified reference materials (CRMs) for data quality monitoring. The average chemical compositions of the exposed crust, the sedimentary cover and the exposed basement as well as the upper crust for 76 chemical elements in eastern China are given. A key basic geology projcct supported by Ministry of Geology and Mineral Resources of China.     

Nature and growth rate of the Northern Izu–Bonin (Ogasawara) arc crust and their implications for continental crust formation

The bulk composition of the continental crust throughout geological history is thought by most previous workers to be andesitic. This assumption of an andesitic bulk composition led to an early hypothesis by 72 ) that the continental crust was created by arc magmatism. This hypothesis for the origin of continental crust was challenged by several authors because: (i) the mean rate of arc crust addition obtained by 50 ) is too small to account for some certain phases of rapid crustal growth; and (ii) the bulk composition of ocean island arcs, the main contributor to the Archean and early Proterozoic crust, is basaltic rather than andesitic ( 4 ; 49 ). New data from the Northern Izu–Bonin arc are presented here which support the 72 ) hypothesis for the origin of the continental crust by andesitic arc magma. A geological interpretation of P wave crustal structure obtained from the Northern Izu–Bonin arc by 66 ) indicates that the arc crust has four distinctive lithologic layers: from top to bottom: (i) a 0.5–2-km-thick layer of basic to intermediate volcaniclastic, lava and hemipelagite (layer A); (ii) a 2–5-km-thick basic to intermediate volcaniclastics, lavas and intrusive layer (layer B); (iii) a 2–7-km-thick layer of felsic (tonalitic) rocks (layer C); and (iv) a 4–7-km-thick layer of mafic igneous rocks (layer D). The chemical composition of the upper and middle part of the northern Izu–Bonin arc is estimated to be similar to the average continental crust by 73 ). The rate of igneous addition of the Northern Izu–Bonin arc since its initial 45-Ma magmatism was calculated as 80 km³/km per million years. This rate of addition is considered to be a reasonable estimate for all arcs in the western Pacific. Using this rate, the global rate of crustal growth is estimated to be 2.96 km³/year which exceeds the average rate of crustal growth since the formation of the Earth (1.76 km³/year). Based on this estimate of continental growth and the previously documented sediment subduction and tectonic erosion rate (1.8 km³/year, 24 ), several examples of growth curves of the continental crust are presented here. These growth curves suggest that at least 50% of the present volume of the continental crust can be explained by arc magmatism. This conclusion indicates that arc magmatism is the most important contributor to the formation of continental crust, especially at the upper crustal level.     

Chemical weathering history of the southern Tajikistan loess and paloclimate implications

Major chemical elements and Rb, Sr, Ba abundances were measured for loess samples from Chashmanigar loess-soil sequence in southern Tajikistan. And the degree of element loss and intensity of weathering of the samples were calculated. From these calculations we found that the paleosol horizons of the Chashmanigar section were chemically weathered to some extent and the weathering intensity of the soils is stronger than that of loess horizons, indicating that paleosols in southern Tajikistan were deposited in relatively warm and humid interglacial ages. In addition, the southern Tajikistan loess deposited before 0.9Ma BP was more intensely weathered than that deposited after 0.9Ma BP, which may imply the intensification of aridity in this area since 0.9Ma BP.     

Chemical weathering history of the southern Tajikistan loess and paleoclimate implications

In recent years, the loess deposits in Central Asia have attracted increasing attention of Qua-ternary paleoclimate researchers[1—8]. The centre of the loess deposits in this area is located in southern Tajikistan, where thick and continuous loess sectio…     

中国大陆地壳与上地幔精细结构探测十条第一剖面和其作用与科学意义

地球内部物理学和地球动力学在地球科学研究领域里占有重要地位.为了研究和探索我国大陆不同大地构造单元和板内特异块体与其界带的深部介质属性、结构和深层物理-力学过程,已在我国最先构思、设计、布署并实施了十条人工源深部地震探测剖面.沿这十条第一剖面进行了高精度的地震反射、宽角反射和折射波场观测,进行了数据采集,获得了深部高分辨率的信息.通过数据处理和反演求得了各剖面辖区的沉积建造、结晶基底、地壳与土地幔的差异和层、块精细速度结构,发现、研究和提出了一系列的重要科学问题并取得了一系列新认识.为研究成山、成盆、成岩、成矿、成灾,圈层耦合和深化认识地球本体与动力学响应打下了坚实的基础,明确指出了其深入研究的内涵和发展导向.     

Preliminary seismic anisotropy in the upper crust of the south segment of Xiaojiang faults and its tectonic implications

The Xiaojiang faults,striking north-to-south(NS),and the Honghe faults,striking north-to-west(NW),are first-order block boundaries that intersect to form a concentrated stress zone at an acute angle in the southern part of the Sichuan-Yunnan rhombic block(SYB).It is also a crucial zone for material escaping from the Tibetan Plateau(TP)due to the collision between the Indian Plate and the Eurasian Plate.In December 2017,the Institute of Earthquake Forecasting of the China Earthquake Administration(CEA)deployed a linear temporary seismic broadband array,the Honghe-Xiaojiang temporary Seismic Array(HX Array),across first-order block boundaries in the southern SYB.By using the waveform data of small earthquakes recorded by stations in the HX Array across Xiaojiang faults from 2017 to 2019,and by permanent seismic stations of the China National Earthquake Networks from 2012 to 2019,this paper adopts the systematic analysis method of shear-wave splitting(SWS),SAM method,to obtain preliminary results for seismic anisotropy in the upper crust.The study area can be divided into two subzones according to the spatial distribution of the directions of polarization of the fast shear-wave(PFS)at the stations:the northern zone(zone A,where the HX Array is located)and the southern zone(zone B,to the south of the HX Array).The results show that the directions of the PFS at stations in zone A were highly consistent,dominant in the NE direction,correlated with the in-situ principal compressive stress,and were seemingly unaffected by the Xiaojiang faults.The directions of the PFS as recorded at stations in zone B were more complicated,and were dominant in the NS direction parallel to that of the regional principal compressive stress.This suggests the joint influence of complex tectonics and regional stress in this narrow wedge area.By referring to the azimuthal anisotropy derived from seismic ambient noise in the southeast margin of the TP,the NS direction of the PFS in the middle and lower crust,and its EW direction in the upper mantle,this paper concludes that azimuthal anisotropy in the upper crust differed from that in the lower crust in the south segment of Xiaojiang faults,at least beneath the observation area,and azimuthal anisotropy in the crust was different from that in the upper mantle.The results support the pattern of deformation of ductile flow in the lower crust,and the decoupling between the upper and lower crusts as well as that between the crust and the mantle in the study area.The crustal directions of the PFS appeared to be independent of the Xiaojiang faults,suggesting that the influence of the South China block on the SYB passed through the Xiaojiang faults to the Yimen region.The results of this study indicate that anisotropic studies based on data on the dense temporary seismic array can yield clearer tectonic information,and reveal the complex spatial distribution of stress and deformation in the upper crust of the south segment of Xiaojiang faults.     

Structure of weathered clastic crust and its petroleum potential

Weathered clastic crust can be subdivided into weathered clay and leached zone in terms of variable weathering of different minerals and mobility of weathered products.On the basis of clastic outcrops and well cores in the Junggar Basin,the dark red Fe-rich weathered clay is formed in an arid environment,whereas the light blue Al-rich weathered clay under humid conditions.According to the geochemical analysis,a new weathering index for weathered clastic crust is built mainly on Fe and Al contents,accurately indicating the weathered clay,sandy leached zone,and muddy leached zone in the Junggar Basin.The breaking pressure of weathered clay is rather large,the same as that of normal muddy cap,effectively to seal oil or gas.The porosity of underlying leached zone is greatly enhanced by weathering and leaching,but its permeability is a function of clay mineral content,i.e.,the higher the clay content,the worse the permeability.Weathered crust provides effective sealing conditions for both top and bottom layers of a petroleum reservoir,and is important in the clastic hydrocarbon exploration.     

PGE geochemistry of Jiding ophiolite in Tibet and its constraint on mantle processes

The total PGE amount (σPGE) of mantle peridotite in the Jiding ophiolite is slightly higher than that of the primitive mantle, but the PGE contents of basalt are higher than those of the mid-ocean ridge basalt (MORB), with obviously lower Pd/Ir ratios. The accumulates, dyke swarm and basalts show remarkable negative Pt and positive Rh anomalies, resulting in the special N-type PGE patterns. Mantle peridotite and crustal rocks have similar distribution patterns. It is proposed that the PGE distribution patterns in the Jiding ophiolite are closely related with a higher degree of partial melting of the mantle in this region. Magmatic crystallization-differentiation led to PGE fractionation, thus making the contents of PGE in the accumulates decrease in the ascending direction. The higher content of Au in the Jiding ophiolite is the result of metasomatic alteration at later stages. Pt-Pd fractionation indicates that both the PGEs are controlled by their alloy and sulfide phases. Positive Rh anomalies seem to be related with higher oxygen fugacity in the melts.     

Stretching characteristics and its dynamic significance of the northern continental margin of South China Sea

To investigate the thinning of the whole crust, and the contribution of the upper versus lower crust to the stretching since Cenozoic, we calculated the stretching factor of the northern margin of South China Sea with data such as whole crustal thickness, depth of Cenozoic sedimentary basement and the horizontal displacement of faults. An isometric line drawing on whole crustal stretching factor is then obtained. Along the seismic Line 1530 in Baiyun sag, we also calculated the stretching factors of the upper and lower crust. The results suggest that the whole crustal thickness decreases seaward while the whole crustal stretching factor increases from shelf to slope. The Moho upwells highest beneath where the crust is thinned most. The value of the whole crustal stretching factor ranges from 1.5 to 6. Two areas were thinned intensely: the center of Yinggehai Basin, and the Baiyun sag in the Pearl River Mouth Basin. The calculation of the upper and lower crustal stretching factors from DSP1530 in Baiyun sag shows that the original crust of Baiyun sag should be thinned before deformation. Its pre-Cenozoic evolution as well as tectonic position during Cenozoic might be responsible for that.     

Variations in chemical compositions of the eolian dust in Chinese Loess Plateau over the past 2.5 Ma and chemical weathering in the Asian inland

Major and trace elements as well as strontium isotopic composition have been analyzed on the acid-insoluble (AI) phase of the loess-paleosol sequence from Luochuan, Shaanxi Province, China. Results show that the chemical composition of AI phase of loess and paleosols is distinctive to the average composition of upper continental crust (UCC), characterized by depletion of mobile elements Na, Ca and Sr. The distribution pattern of elements in AI phase reveals that initial dust, derived from a vast area of Asian inland, has suffered from Na- and Ca-removed chemical weathering compared to UCC. Some geochemical parameters (such as CIA values, Na/K, Rb/Sr and⁸⁷Sr/⁸⁶Sr ratios) display a regular variation and evolution, reflecting that the chemical weathering in the source region of loess deposits has decreased gradually since 2.5 Ma with the general increase of global ice volume. This coincidence reflects that the aridity of Asian inland since the Quaternary is a possible regional response to the global climate change.     

Surface wave tomography of the crust and upper mantle of Chinese mainland and its neighboring region

Introduction The three-dimensional S wave velocity of Chinese mainland and its neighboring region in-verted by surface wave dispersion data plays an important role in studying the lateral variation of lithosphere and geodynamic process, and understanding the forming and evolution of Chinese mainland and the relationship between shallow and deep structures. The three-dimensional veloc-ity structures of China and its major tectonic blocks were respectively studied by SONG, et al (1993), ZHOU…     

Seismic tomography of the crust and upper mantle in the Bohai Bay Basin and its adjacent regions

In the Bohai Bay Basin and its adjacent regions(112°―124°E,34°―42°N),there exists abundant gas-petroleum while modern inter-plate seismic activity is robust.Although the tectonic structure of this region is very complicated,plenty of geological,geophysical and geochemical data and results are obtained through previous researches.On the basis of absorbing previous results,especially various kinds of geological and geophysical results,we collect and process the arrival time of P-wave phases of local events and tele-seismic events recorded by the station within this region from 1978 to 2004,build the responding initial model,and image the velocity structure of the crust and upper mantle of this region via tomography.The perturbation images of various depths and velocity profiles imply that the velocity structure of the crust and upper mantle in the Bohai Bay Basin and its adjacent regions is mainly influenced by the surface tectonic units,and is characterized by "Stripped along east-west,and zoned along south-north";some large-scaled faults penetrate Moho and lithosphere,and provide the channels for the basic lava or hot mass upwelling from the mantle.     

青藏高原中部地壳和上地幔各向异性分析

对布设于青藏高原中部INDEPTH-III宽频带数字地震台阵的41个台站记录的远震体波资料所提取出的P波接收函数和SKS波形资料做偏振分析,并采用以误差为权的叠加分析方法求得每一个台站的Pms和SKS快波偏振方向和快慢波的时间延迟,获得了从拉萨块体中部,经喀喇昆仑—嘉黎断裂系和班公湖—怒江缝合带,到羌塘块体中部的地壳和岩石圈地幔的地震波各向异性图像.从各向异性分析结果可以看到:Pms快慢波的时间延迟为0.3~0.5 s,在拉萨块体,快波方向主要为NE-SW向,在羌塘块体,快波方向为近E-W向.SKS快慢波的时间延迟为1~2 s,主要分布在拉萨块体的北端和羌塘块体,并且向靠近班公湖—怒江缝合带和昆仑—嘉黎断裂带的方向时差增大,快波方向基本与Pms快波方向一致.在喀喇昆仑—嘉黎断裂带以南的拉萨块体中部没有测量到明显的SKS分裂,这可能与该区存在双层快轴方向近垂直的各向异性层有关.结合研究区已有的研究成果可以推测:拉萨块体地壳各向异性层的快轴方向与印度—欧亚板块汇聚方向一致,可能与地壳较强刚性有关,其在板块汇聚过程中不易发生流展变形;而羌塘块体地壳和岩石圈中各向异性层的快轴方向与青藏高原物质逃逸方向一致,表明这一块体流变性均较强,在板块汇聚挤压力的作用下发生了侧向流变变形.     

基于背景噪声方法的花岗岩型稀土矿地壳浅部结构特征及构造意义: 以江西赣州安西矿区为例

稀土资源是国家的战略性资源,在国民经济和国家安全等方面作用重大.目前,针对该资源的开发利用需要进一步加强勘探方法和成矿模式的研究.本研究在江西省赣州市安西镇稀土矿区10 km×6 km的区域内布设了一个约100台短周期地震仪器构成的面状台阵,以及两个48 m长各由25个短周期地震仪构成的线性台阵.通过背景噪声三维成像方法反演获得矿区地表至2.2 km深度的地壳浅部三维横波速度结构.以典型花岗岩风化壳为例,使用面波的相移成像法,反演了从地表全风化层至约40 m深度的一维横波速度结构.以该一维速度结构为参考,使用噪声谱比法（HVSR）探测了矿区内的松散沉积厚度,并结合钻孔数据验证了该方法对花岗岩型风化壳基底面的有效探测.综合上述结果,本研究通过三维横波速度结构圈定了安西岩体中稀土的成矿母岩（花岗岩）在上地壳的分布范围和形态,显示了安西岩体所处的丘陵盆地的构造背景为花岗岩型稀土矿成矿过程提供有利条件;结合HVSR结果、一维横波速度模型和钻孔数据,探测了富集稀土矿的风化壳从全风化层顶部至母岩的深度和结构,松散沉积厚度显示了矿集区和山区的沉积环境差异.本研究可以为花岗岩型稀土资源的勘探提供一系列基于背景噪声地震学的方法和策略,建立了火山岩型风化壳的起源、发育和演化的构造模型,为该类稀土矿的深-浅部结构演化过程和构造活动影响研究提供参考.

     

北京大海坨4.9级地震前白家疃井地热地形变前兆异常

北京大海坨ＭＬ＝４．９地震前，白家疃地热，地形变两种观测项目，同时观测记录到明显的异常变化，具有短期和短促，突发的临震异常特点，采取针对性的分析方法，结果较好，为单台项（前兆方法）综合预报提供了震兆观测实例。     

高分辨折射地震资料处理方法及其应用

高分辨折射探测剖面近几年在我国的一些重要地学基础研究项目，特别是在中国地震局“十五” 期间开展的城市活断层探测及复杂上部地壳精细结构研究中得到了越来越广泛的应用.本文对在用传统有限差分方法处理高分辨折射地震资料时的缺陷及其改进算法的研究进展进行了较全面的讨论，对一些缺陷我们已给出了解决的方案，并已成功地应用于实际人工地震高分辨折射测量资料的分析处理，取得了较好的效果，还给出了将改进方法应用于深反射剖面初至波处理解释的一个应用实例，对于另一些缺陷我们在对国内外该领域研究现状调研的基础上，给出了目前我们正在进行中的解决方案.     

Petrography and geochemistry of upper Triassic sandstones from the Tumengela Formation in the Woruo Mountain area,North Qiangtang Basin,Tibet: Implications for provenance,source area weathering,and tectonic setting

The petrography and major and trace element concentrations of the sandstones from the Tumengela Formation in the Woruo Mountain area, North Qiangtang Basin, are studied to determine their provenance, intensity of weathering and tectonic setting. The detrital compositions of the Tumengela sandstone samples are dominated by quartz (58.0–70.1 %, average 64.7 %) and lithic fragments (21.8–35.9 %, average 27.3 %), but low in feldspar content (4.9–12.9 %, average 8.0 %). The sandstones can be classified as litharenite and feldspathic litharenite according to their detrital compositions, which is consistent with the geochemical data. The detrital modal compositions reflect that these sandstones are probably derived from a recycled orogenic source. The index of chemical variability (ICV) and SiO₂/Al₂O₃ ratio values suggest that the compositional maturity and recycling were moderate. The weathering indices such as the chemical index of alteration (CIA), plagioclase index of alteration (PIA), chemical index of weathering (CIW), and Al₂O₃–(CaO* + Na₂O)–K₂O (A–CN–K) diagram indicate that the intensities of weathering in the source area were moderate. The Al₂O₃/TiO₂, Th/Co, La/Sc, La/Co, Th/Sc, Cr/Th ratio values and the discriminant function of the Tumengela sandstones indicate that the sediments were mainly derived from felsic source rocks, while also mixed with intermediate source rocks. The comparison of rare earth element patterns and its Eu anomalies to the probable source rocks infer that the sandstones were derived from the combination of granite, rhyolite, dacite, and gneisses. The proximal central uplift belt was probably the primary provenance area as evidenced by the petrographical and geochemical features of the Tumengela sandstones. The multidimensional tectonic discrimination diagram based on major elements show a collision setting (80 %) combined with a rift setting (20 %) for the Tumengela sandstones, which is consistent with the general geology of the study areas.