Uninhabited habitats on Mars

Investigations of Mars as a potential location for life often make the assumption that where there are habitats, they will contain organisms. However, the observation of the ubiquitous distribution of life in habitable environments on the Earth does not imply the presence of life in martian habitats. Although uninhabited habitats are extremely rare on the Earth, a lack of a productive photosynthetic biosphere on Mars to generate organic carbon and oxygen, thus providing a rapidly available redox couple for energy acquisition by life and/or a lack of connectivity between habitats potentially increases the scope and abundance of uninhabited habitats for much of the geological history of the planet. Uninhabited habitats could have existed on Mars from the Noachian to the present-day in impact hydrothermal systems, megaflood systems, lacustrine environments, transient melted permafrost, gullies and local regions of volcanic activity; and there may be evidence for them in martian meteorites. Uninhabited habitats would provide control habitats to investigate the role of biology in planetary-scale geochemical processes on the Earth and they would provide new constraints on the habitability of Mars. Future robotic craft and samples returned from Mars will be able to directly show if uninhabited habitats exist or existed on Mars.     

Zones of photosynthetic potential on Mars and the early Earth

Ultraviolet radiation is more damaging on the surface of Mars than on Earth because of the lack of an ozone shield. We investigated micro-habitats in which UV radiation could be reduced to levels similar to those found on the surface of present-day Earth, but where light in the photosynthetically active region (400-700 nm) would be above the minimum required for photosynthesis. We used a simple radiative transfer model to study four micro-habitats in which such a theoretical Martian Earth-like Photosynthetic Zone (MEPZ) might exist. A favorable radiation environment was found in martian soils containing iron, encrustations of halite, polar snows and crystalline rocks shocked by asteroid or comet impacts, all of which are known habitats for phototrophs on Earth. Although liquid water and nutrients are also required for life, micro-environments with favorable radiation environments for phototrophic life exist in a diversity of materials on Mars. This finding suggests that the lack of an ozone shield is not in itself a limit to the biogeographically widespread colonization of land by photosynthetic organisms, even if there are no other UV-absorbers in the atmosphere apart from carbon dioxide. When applied to the Archean Earth, these data suggest that even with the worst-case assumptions about the UV radiation environment, early land masses could have been colonized by primitive photosynthetic organisms. Such zones could similarly exist on anoxic extra-solar planets lacking ozone shields.     

Microbial life in martian ice: A biotic origin of methane on Mars?

Despite the fact that microbial cells are unlikely to be found in the Martian soil in the near future, this paper is written on the assumption that some of the seasonally varying concentration of Martian methane is due to ongoing methanogenesis. It is first pointed out that life might have arisen on Mars first and been transported to Earth later. A case is made that an icy origin of life is more likely than a hot origin, especially if biomolecules take advantage of the high encounter rates and stability against hydrolysis, and that microorganisms feed on the ions that comprise eutectic solutions in ice. Although certain difficulties are avoided if RNA and DNA grow while adsorbed on clay grains, double strand-breaks of microbial DNA due to alpha radioactivity are a far greater threat to microbial survival on clay or other rock types than in ice. Developing a relation between the rate of microbial metabolism in ice and the experimentally determined rate of production of trapped gases of microbial origin, one can estimate the concentration of methanogens that could account for the methane production rate as a function of temperature of their habitat. The result, of order 1 cell cm⁻³ in the Martian subsurface, seems an attainable goal provided samples are taken from at least 1 or 2 m below the hostile surface of Mars. Instruments on NASA’s 2011 Mars Science Lab will measure stable isotopes for methane, water, and carbon dioxide, which on Earth served to distinguish abiotic, thermogenic, and microbial origins. Future measurements of chirality of biomolecules might also provide evidence for Martian life.     

Mars Express and Venus Express multi-point observations of geoeffective solar flare events in December 2006

In December 2006, a single active region produced a series of proton solar flares, with X-ray class up to the X9.0 level, starting on 5 December 2006 at 10:35 UT. A feature of this X9.0 flare is that associated MeV particles were observed at Venus and Mars by Venus Express (VEX) and Mars Express (MEX), which were ∼80° and ∼125° east of the flare site, respectively, in addition to the Earth, which was ∼79° west of the flare site. On December 5, 2006, the plasma instruments ASPERA-3 and ASPERA-4 on board MEX and VEX detected a large enhancement in their respective background count levels. This is a typical signature of solar energetic particle (SEP) events, i.e., intensive MeV particle fluxes. The timings of these enhancements were consistent with the estimated field-aligned travel time of particles associated with the X9.0 flare that followed the Parker spiral to reach Venus and Mars. Coronal mass ejection (CME) signatures that might be related to the proton flare were twice identified at Venus within <43 and <67 h after the flare. Although these CMEs did not necessarily originate from the X9.0 flare on December 5, 2006, they most likely originated from the same active region because these characteristics are very similar to flare-associated CMEs observed on the Earth. These observations indicate that CME and flare activities on the invisible side of the Sun may affect terrestrial space weather as a result of traveling more than 90° in both azimuthal directions in the heliosphere. We would also like to emphasize that during the SEP activity, MEX data indicate an approximately one-order of magnitude enhancement in the heavy ion outflow flux from the Martian atmosphere. This is the first observation of the increase of escaping ion flux from Martian atmosphere during an intensive SEP event. This suggests that the solar EUV flux levels significantly affect the atmospheric loss from unmagnetized planets.     

The prospects for life on Mars: A pre-Viking assessment

Mariner 9 has provided a refutation or reinterpretation of several historical claims for Martian biology, and has permitted an important further characterization of the environmental constraints on possible Martian organisms. Four classes of conceivable Martian organisms are identified, depending on the environmental temperature, T, and water activity, a_w: Class I, high T, high a_w; Class II, low T, high a_w; Class III, high T, low a_w; and Class IV, low T, low a_w. The Viking lander biology experiments are essentially oriented toward Class I organisms, although arguments are given for the conceivable presence on Mars of organisms in any of the four classes. Organisms which extract their water requirements from hydrated minerals or from ice are considered possible on Mars, and the high ultraviolet flux and low oxygen partial pressure are considered to be negligible impediments to Martian biology. Large organisms, possibly detectable by the Viking lander cameras, are not only possible on Mars; they may be favored. The surface distribution of Martian organisms and future search strategies for life on Mars are discussed.     

Could organic matter have been preserved on Mars for 3.5 billion years?

3.5 billion years (byr) ago, when it is thought that Mars and Earth had similar climates, biological evolution on Earth had made considerable progress, such that life was abundant. It is therefore surmised that prior to this time period the advent of chemical evolution and subsequent origin of life occurred on Earth and may have occurred on Mars. Analysis for organic compounds in the soil buried beneath the Martian surface may yield useful information regarding the occurrence of chemical evolution and possibly biological evolution. Calculations based on the stability of amino acids lead to the conclusion that remnants of these compounds, if they existed on Mars 3.5 byr ago, might have been preserved buried beneath the surface oxidizing layer. For example, if phenylalanine, an amino acid of average stability, existed on Mars 3.5 byr ago, then 1.6% would remain buried today, or 25 pg-2.5 ng of C g-1 Martian soil may exist from remnants of meteoritic and cometary bombardment, assuming that 1% of the organics survived impact.     

Field-aligned currents and parallel electric field potential drops at Mars. Scaling from the Earth’ aurora

The observations of electron inverted ‘V’ structures by the MGS and MEX spacecraft, their resemblance to similar events in the auroral regions of the Earth, and the discovery of strong localized magnetic field sources of the crustal origin on Mars, raised hypotheses on the existence of Martian aurora produced by electron acceleration in parallel electric fields. Following the theory of this type of structures on Earth we perform a scaling analysis to the Martian conditions. Similar to the Earth, upward field-aligned currents necessary for the generation of parallel potential drops and peaked electron distributions can arise, for example, on the boundary between ‘closed’ and ‘open’ crustal field lines due to shears of the flow velocity of the magnetosheath or magnetospheric plasmas. A steady-state configuration assumes a closure of these currents in the Martian ionosphere. Due to much smaller magnetic fields as compared to the Earth case, the ionospheric Pedersen conductivity is much higher on Mars and auroral field tubes with parallel potential drops and relatively small cross scales to be adjusted to the scales of the localized crustal patches may appear only if the magnetosphere and ionosphere are decoupled by a zone with a strong E_∥. Another scenario suggests a periodic short-circuit of the magnetospheric electric fields by a coupling with the conducting ionosphere.     

Martian cratering 12. Utilizing primary crater clusters to study crater populations and meteoroid properties

Images from Mars Global Surveyor and later images from Mars Reconnaissance Orbiter reveal that roughly half of the meteoroids striking Mars (at meter to few decameter crater diameters) fragment in the Martian atmosphere, producing small clusters of primary impact craters. Statistics of these “primary clusters” yield valuable information about important Martian phenomena and properties of interplanetary bodies, including meteoroid behavior in the Martian atmosphere, bulk strengths of bodies striking Mars, and the fraction of Martian “field secondary” craters, a datum that would improve crater count chronometry. Many Martian impactors fragment at altitudes significantly higher than 18 km above the mean surface of Mars, and we find that most bodies striking Mars and Earth have low bulk strengths, consistent with crumbly or highly fractured objects. Applying statistics of primary clusters at various elevations and independent diameter bins, we describe a technique to estimate the percentage of semirandomly scattered “field secondary” craters. Our provisional estimate of this percentage, in the diameter range ~250 m down to ~22 m, is ~40% to ~80% of the total impacts, with the higher percentages at smaller diameters. Our data argue against earlier suggestions of overwhelming dominance by either primaries or secondaries in this diameter range.     

The provenance,formation, and implications of reduced carbon phases in Martian meteorites

This review is intended to summarize the current observations of reduced carbon in Martian meteorites, differentiating between terrestrial contamination and carbon that is indigenous to Mars. Indeed, the identification of Martian organic matter is among the highest priority targets for robotic spacecraft missions in the next decade, including the Mars Science Laboratory and Mars 2020. Organic carbon compounds are essential building blocks of terrestrial life, so the occurrence and origin (biotic or abiotic) of organic compounds on Mars is of great significance; however, not all forms of reduced carbon are conducive to biological systems. This paper discusses the significance of reduced organic carbon (including methane) in Martian geological and astrobiological systems. Specifically, it summarizes current thinking on the nature, sources, and sinks of Martian organic carbon, a key component to Martian habitability. Based on this compilation, reduced organic carbon on Mars, including detections of methane in the Martian atmosphere, is best described through a combination of abiotic organic synthesis on Mars and infall of extraterrestrial carbonaceous material. Although conclusive signs of Martian life have yet to be revealed, we have developed a strategy for life detection on Mars that can be utilized in future life‐detection studies.     

On the model structure of the gravity field of Mars

A discussion is presented about the constraints used in constructing a model for the internal structure of Mars. The most important fact is that the Martian chemical model proposed by Wänke and Dreibus (WD) has stood the test of time. This means that the chondritic ratio Fe/Si = 1.71 can be used as a constraint in constructing an interior structure model of the planet. Consideration is given to the constructing of the reference surface of Mars. It is concluded that the effectively hydrostatic-equilibrium model of Mars is well suited for this purpose. The areoid heights and gravity anomalies in the model of Mars are calculated. The results are shown in the figures (maps) and comments made. The results are compared with the similar data for the Earth. Mars deviates much more strongly from the hydrostatic equilibrium than the Earth. It is suggested that the average thickness of the Martian elastic lithosphere should exceed that of the Earth’s continental lithosphere.     

A search for amino acids and nucleobases in the Martian meteorite Roberts Massif 04262 using liquid chromatography‐mass spectrometry

The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography‐mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot‐water extracts with high relative abundances of β‐alanine and γ‐amino‐n‐butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight‐chained amine‐terminal n‐ω‐amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of ?24‰ ± 6‰ for β‐alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n‐ω‐amino acids may be due to a high temperature Fischer‐Tropsch‐type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses.     

Ejection of Martian meteorites

Abstract— We investigated the transfer of meteorites from Mars to Earth with a combined mineralogical and numerical approach. We used quantitative shock pressure barometry and thermodynamic calculations of post‐shock temperatures to constrain the pressure/temperature conditions for the ejection of Martian meteorites. The results show that shock pressures allowing the ejection of Martian meteorites range from 5 to 55 GPa, with corresponding post‐shock temperature elevations of 10 to about 1000 °C. With respect to shock pressures and post‐shock temperatures, an ejection of potentially viable organisms in Martian surface rocks seems possible. A calculation of the cooling time in space for the most highly shocked Martian meteorite Allan Hills (ALH) 77005 was performed and yielded a best‐fit for a post‐shock temperature of 1000 °C and a meteoroid size of 0.4 to 0.6 m. The final burial depths of the sub‐volcanic to volcanic Martian rocks as indicated by textures and mineral compositions of meteorites are in good agreement with the postulated size of the potential source region for Martian meteorites during the impact of a small projectile (200 m), as defined by numerical modeling (Artemieva and Ivanov 2004). A comparison of shock pressures and ejection and terrestrial ages indicates that, on average, highly shocked fragments reach Earth‐crossing orbits faster than weakly shocked fragments. If climatic changes on Mars have a significant influence on the atmospheric pressure, they could account for the increase of recorded ejection events of Martian meteorites in the last 5 Ma.     

Elements of comparison between Martian and terrestrial mesoscale meteorological phenomena: Katabatic winds and boundary layer convection

Terrestrial and Martian atmospheres are both characterised by a large variety of mesoscale meteorological events, occurring at horizontal scales of hundreds of kilometres and below. Available measurements from space exploration and recently developed high-resolution numerical tools have given insights into Martian mesoscale phenomena, as well as similarities and differences with their terrestrial counterparts. The remarkable intensity of Martian mesoscale events compared to terrestrial phenomena mainly results from low density and strong radiative control. This is exemplified in the present paper by discussing two mesoscale phenomena encountered in the lowest atmospheric levels of both planets with notable differences: nighttime katabatic winds (drainage flow down sloping terrains) and daytime boundary layer convection (vertical growth of mixed layer over heated surfaces). While observations of katabatic events are difficult on Earth, except over vast ice sheets, intense clear-cut downslope circulations are expected to be widespread on Mars. Convective motions in the daytime Martian boundary layer are primarily driven by radiative contributions, usually negligible on Earth where sensible heat flux dominates, and exhibit turbulent variances one order of magnitude larger. Martian maximum heat fluxes are not attained close to the surface as on Earth but a few hundreds of metres above, which implies generalised definitions for mixing layer scales such as vertical velocity w_?. Measurements on Mars of winds in uneven topographical areas and of heat fluxes over flat terrains could be useful to assess general principles of mesoscale meteorology applicable to both terrestrial and Martian environments.     

Atmospheric entry heating of micrometeorites at Earth and Mars: Implications for the survival of organics

The atmospheric entry heating of micrometeorites (MMs) can significantly alter their pre‐existing mineralogy, texture, and organic material. The degree of heating depends predominantly on the gravity and atmospheric density of the planet on which they fall. For particles falling on Earth, the alteration can be significant, leading to the destruction of much of the pre‐entry organics; however, the weaker gravity and thinner atmosphere of Mars enhance the survival of MMs and increase the fraction of particles that preserve organic material. This paper investigates the entry heating of MMs on the Earth and Mars in order to examine the MM population on each planet and give insights into the survival of extraterrestrial organic material. The results show that particles reaching the surface of Mars experience a lower peak temperature compared to Earth and, therefore, experience less evaporative mass loss. Of the particles which reach the surface, 68.2% remain unmelted on Mars compared to only 22.8% on Earth. Due to evaporative mass loss, unmelted particles that reach the surface of Earth are restricted to sizes <70 μm whereas particles >475 μm survive unmelted on Mars. Approximately 10% of particles experience temperatures below ~800 K, that is, the sublimation temperature of refractory organics found in MMs. On Earth, this fraction is significantly lower with less than 1% expected to remain below this temperature. Lower peak temperatures coupled with the larger sizes of particles surviving without significant heating on Mars suggest a much higher fraction of organic material surviving to the Martian surface.     

Why exobiology on Mars?

Processing of organic molecules by liquid water was probably an essential requirement towards the emergence of terrestrial primitive life. According to Oparin's hypothesis, organic building blocks required for early life were produced from simple organic molecules formed in a primitive reducing atmosphere. Geochemists favour now a less reducing atmosphere dominated by carbon dioxide. In such an atmosphere, very few building blocks are formed. Import of extraterrestrial organic molecules may represent an alternative supply. Experimental support for such an alternative scenario is examined in comets, meteorites and micrometeorites. The early histories of Mars and Earth clearly show similarities. Liquid water was once stable on the surface of Mars attesting the presence of an atmosphere capable of decelerating C-rich micro-meteorites. Therefore, primitive life may have developed on Mars, as well. Liquid water disappeared from the surface of Mars very early, about 3.8 Ga ago. The Viking missions did not find, at the surface of the Martian soil, any organic molecules or clear-cut evidence for microbial activities such as photosynthesis, respiration or nutrition. The results can be explained referring to an active photochemistry of Martian soil driven by the high influx of solar UV. These experiments do not exclude the existence of organic molecules and fossils of micro-organisms which developed on early Mars until liquid water disappeared. Mars may store below its surface some well preserved clues of a still hypothetical primitive life.     

Orbital observations of meteors in the Martian atmosphere using the SPOSH camera

We investigate the expected performance of a wide-angle camera in Martian orbit, which, unlike previous cameras that have flown to Mars, is capable of recording meteor activity in that planet's atmosphere. We show that, based on our current understanding of meteor physics and the interplanetary meteoroid population, several meteors will be detected by this instrument during a single nightside pass on a low Martian orbit. The instrument will also record the signatures of meteor showers expected to occur every Martian year (1.88 Earth years). The results of this investigation will test models of the flux of “large” (mm-cm) meteoroids at the orbit of Mars and their interaction with the Martian atmosphere.     

Deep versus shallow origin of gravity anomalies, topography and volcanism on Earth, Venus and Mars

The relation between gravity anomalies, topography and volcanism can yield important insights about the internal dynamics of planets. From the power spectra of gravity and topography on Earth, Venus and Mars we infer that gravity anomalies have likely predominantly sources below the lithosphere up to about spherical harmonic degree l=30 for Earth, 40 for Venus and 5 for Mars. To interpret the low-degree part of the gravity spectrum in terms of possible sublithospheric density anomalies we derive radial mantle viscosity profiles consistent with mineral physics. For these viscosity profiles we then compute gravity and topography kernels, which indicate how much gravity anomaly and how much topography is caused by a density anomaly at a given depth. With these kernels, we firstly compute an expected gravity-topography ratio. Good agreement with the observed ratio indicates that for Venus, in contrast to Earth and Mars, long-wavelength topography is largely dynamically supported from the sublithospheric mantle. Secondly, we combine an empirical power spectrum of density anomalies inferred from seismic tomography in Earth’s mantle with gravity kernels to model the gravity power spectrum. We find a good match between modeled and observed gravity power spectrum for all three planets, except for 2?l?4 on Venus. Density anomalies in the Venusian mantle for these low degrees thus appear to be very small. We combine gravity kernels and the gravity field to derive radially averaged density anomaly models for the Martian and Venusian mantles. Gravity kernels for l?5 are very small on Venus below ≈800 km depth. Thus our inferences on Venusian mantle density are basically restricted to the upper 800 km. On Mars, gravity anomalies for 2?l?5 may originate from density anomalies anywhere within its mantle. For Mars as for Earth, inferred density anomalies are dominated by l=2 structure, but we cannot infer whether there are features in the lowermost mantle of Mars that correspond to Earth’s Large Low Shear Velocity Provinces (LLSVPs). We find that volcanism on Mars tends to occur primarily in regions above inferred low mantle density, but our model cannot distinguish whether or not there is a Martian analog for the finding that Earth’s Large Igneous Provinces mainly originate above the margins of LLSVPs.     

Volcaniclastic habitats for early life on Earth and Mars: A case study from ∼3.5 Ga-old rocks from the Pilbara, Australia

Within the context of present and future in situ missions to Mars to investigate its habitability and to search for traces of life, we studied the habitability and traces of past life in ∼3.5 Ga-old volcanic sands deposited in littoral environments an analogue to Noachian environments on Mars. The environmental conditions on Noachian Mars (4.1-3.7 Ga) and the Early Archaean (4.0-3.3 Ga) Earth were, in many respects, similar: presence of liquid water, dense CO₂ atmosphere, availability of carbon and bio-essential elements, and availability of energy. For this reason, information contained in Early Archaean terrestrial rocks concerning habitable conditions (on a microbial scale) and traces of past life are of relevance in defining strategies to be used to identify past habitats and past life on Mars.One such example is the 3.446 Ga-old Kitty’s Gap Chert in the Pilbara Craton, NW. Australia. This formation consists of volcanic sediments deposited in a coastal mudflat environment and is thus a relevant analogue for sediments deposited in shallow water environments on Noachian Mars. Two main types of habitat are represented, a volcanic (lithic) habitat and planar stabilized sediment surfaces in sunlit shallow waters. The sediments hosted small (<1 μm in size) microorganisms that formed colonies on volcanic particle surfaces and in pore waters within the volcanic sediments, as well as biofilms on stabilised sediment surfaces. The microorganisms included coccoids, filaments and rare rod-shaped organisms associated with microbial polymer (EPS). The preserved microbial community was apparently dominated by chemotrophic organisms but some locally transported filaments and filamentous mat fragments indicate that possibly photosynthetic mats formed nearby. Both microorganisms and sediments were silicified during very early diagenesis.There are no macroscopic traces of fossilised life in these volcanic sediments and sophisticated instrumentation and specialized sample preparation techniques are required to establish the biogenicity and syngenicity of the traces of past life. The fact that the traces of life are cryptic, and the necessity of using sophisticated instrumentation, reinforces the challenges and difficulties of in situ robotic missions to identify past life on Mars. We therefore recommend the return of samples from Mars to Earth for a definitive search for traces of life.     

Development and testing of subsurface sampling devices for the Beagle 2 lander

For planetary landing missions, the capability to acquire samples of soil and rock is of high importance whenever complex analyses (e.g. isotopic studies) on these materials are to be carried out, or when samples are to be returned to Earth. Not only surface samples are of relevance, but in recent concepts at least for Mars landing missions also subsurface samples are required. Subsurface material on Mars is believed to have been protected from the inferred oxidants at the immediate surface while also being protected from the UV influx. Therefore, there is considerable hope that in subsurface soil samples on Mars, at least organic matter delivered by meteorites may be detected, and possibly also relics of earlier simple microbial life on the planet. Likewise, samples from the inside of Martian surface rocks promise to have been protected from weathering and for the same reason they are important for organic chemistry studies. In this paper, an overview is given of the development and science of two different subsurface sampling devices for the Beagle 2 lander of ESA's Mars Express mission, being a “Mole” subsurface soil sampler and a small rock coring and sampling mechanism. Besides their sampling function, both the Mole and the Corer/Grinder will provide data on physical properties of Martian soils and rock, respectively, through the way they interact with the sampled materials. Details of the Mole and Corer/Grinder design are presented, along with results of recent tests with prototypes in the laboratory on physically analogous sample materials.     

TOF‐SIMS analysis of polycyclic aromatic hydrocarbons in Allan Hills 84001

Abstract— The presence of polycyclic aromatic hydrocarbons (PAHs) in the Martian meteorite Allan Hills 84001 (ALH 84001) was considered to be a major sign of ancient biogenic activity on planet Mars (McKay et al. 1996). An asserted spatial association of PAHs with carbonates, carriers of so‐called nanofossils, was crucial for their suggested connection to early life forms. Although both observations can be explained individually without employing living organisms, a lateral correlation of PAHs and carbonates would suggest a genetic link between PAHs and the microstructures, favoring a biogenic explanation. On the other hand, without such a correlation, a biogenic or even a Martian origin of the PAHs cannot be inferred. Here we show that there is no correlation of PAHs and carbonates in ALH 84001. Furthermore, a general trend of high PAH concentrations at locations where terrestrial lead is present obviously suggests a terrestrial origin for PAHs in ALH 84001.