Composition and heterogeneity of anorthositic impact melt at Mistastin Lake crater, Labrador

Anorthositic impact melt rocks, their target rocks (principally anorthosite, mangerite, granodiorite) and zircon clasts from the ∼36-Ma-old, 28-km-wide Mistastin Lake crater of northern Labrador (55°53′N; 63°18′W) have been examined in order to evaluate the scale and origin of compositional heterogeneities in impact melts produced in craters of moderate size. In particular we assess whether and, if so, how the initial composition of the impact melt was modified as it entrained mineral clasts derived from the underlying rocks over which it flowed when it moved away from the shock-induced, central melting zone. A secondary goal was to determine if zircon clasts in the impact melts are present in the proportions of their target rock sources and/or the substrate lithologies over which they flowed. Chemical compositions of bulk samples of 33 melt rocks and 14 target rocks were measured by XRF and SN-ICPMS. Matrix compositions of nine samples of impact melt rocks were determined by EPMA and LA-ICPMS. Zircon grains from four samples of target rock and zircon clasts from three samples of impact melt rock were measured for multi-element composition, U-Pb age and Hf-isotopic composition by LA-(MC)-ICPMS.The data reveal compositional heterogeneities in the impact melts on the scales of both bulk samples and matrices. Bulk samples can be divided into compositions with high and low concentrations of high-field-strength elements (HFSE; Ti, Zr, Nb) and Fe, Ba, Ce and Y. High HFSE-type melt rocks formed when impact melt entrained large quantities of clasts from mangerite, which is rich in HFSE. Matrix compositions of bulk samples do not show the HFSE distinction but are affected by the introduction of low-temperature melts from the clasts to form dispersed, micron-scale silica-rich heterogeneities.The best estimate of sources of the initial impact melt is ∼73% anorthosite, ∼7% mangerite and ∼20% granodiorite, based on least-squares modeling of major-element compositions of the matrices of thinner flows. Zircon derived from anorthosite can be distinguished from zircon from mangerite and granodiorite by higher Nb/Ta and Eu/Eu* ratios and more negative initial ε Hf values. Zircon clasts >40 mm in size in the impact melt rocks are dominantly or exclusively derived from mangerite and granodiorite rather than from anorthosite. Because anorthosite was the principal source of impact melt at Mistastin, zircon may be a poor provenance indicator for anorthosite contributions to impact melts, particularly where grains smaller than 40 microns are not analyzed.     

Shock effects in plagioclase feldspar from the Mistastin Lake impact structure,Canada

Shock metamorphism, caused by hypervelocity impact, is a poorly understood process in feldspar due to the complexity of the crystal structure, the relative ease of weathering, and chemical variations, making optical studies of shocked feldspars challenging. Understanding shock metamorphism in feldspars, and plagioclase in particular, is vital for understanding the history of Earth's moon, Mars, and many other planetary bodies. We present here a comprehensive study of shock effects in andesine and labradorite from the Mistastin Lake impact structure, Labrador, Canada. Samples from a range of different settings were studied, from in situ central uplift materials to clasts from various breccias and impact melt rocks. Evidence of shock metamorphism includes undulose extinction, offset twins, kinked twins, alternate twin deformation, and partial to complete transformation to diaplectic plagioclase glass. In some cases, isotropization of alternating twin lamellae was observed. Planar deformation features (PDFs) are notably absent in the plagioclase, even when present in neighboring quartz grains. It is notable that various microlites, twin planes, and compositionally different lamellae could easily be mistaken for PDFs and so care must be taken. A pseudomorphous zeolite phase (levyne‐Ca) was identified as a replacement mineral of diaplectic feldspar glass in some samples, which could, in some instances, also be potentially mistaken for PDFs. We suggest that the lack of PDFs in plagioclase could be due to a combination of structural controls relating to the crystal structure of different feldspars and/or the presence of existing planes of weakness in the form of twin and cleavage planes.     

Raman study of shock features in plagioclase feldspar from the Mistastin Lake impact structure,Canada

Plagioclase feldspar is one of the most abundant minerals on the surface of the Earth, the Moon, and Mars, and is also commonly found in meteorites. Studying shock effects in feldspar thus provides us with fundamental information about impact cratering processes on planetary bodies. In this study, plagioclase from monomict and polymict breccias, impact melt rocks, and shock‐metamorphosed target rocks, from throughout the Mistastin Lake impact structure, Canada, was examined using 514 nm laser Raman spectroscopy. As one of the very few impact structures with anorthosite in the target rocks, the Mistastin Lake impact structure provides a unique opportunity to study shocked plagioclase displaying progressive shock metamorphic features. A series of microscopic features was observed within plagioclase, including twins, needle‐like inclusions, planar features, and alteration. The lack of planar deformation features is notable. Raman spectra of these features suggest that this technique is capable of differentiating and classifying shock features in low to moderately shocked rocks. Caution should be exercised, however, as Raman spectra collected from unshocked plagioclase references with known compositions indicate that peak width and peak ratio of the Raman peaks in lower wave number region (<350 cm^?1) and the main signature peaks around 500 cm^?1 vary with chemical composition and crystal orientation. Data collected from diaplectic glass suggest that Raman features are efficient in distinguishing crystalline plagioclase and diaplectic glass. We also observed significant variations in the Raman intensities collected from diaplectic glass, which we ascribe to the localized disorder or inhomogeneity of shock pressure and temperature throughout the target.     

Eminescu impact structure: Insight into the transition from complex crater to peak-ring basin on Mercury

Peak-ring basins represent an impact-crater morphology that is transitional between complex craters with central peaks and large multi-ring basins. Therefore, they can provide insight into the scale dependence of the impact process. Here the transition with increasing crater diameter from complex craters to peak-ring basins on Mercury is assessed through a detailed analysis of Eminescu, a geologically recent and well-preserved peak-ring basin. Eminescu has a diameter (∼125 km) close to the minimum for such crater forms and is thus representative of the transition. Impact crater size-frequency distributions and faint rays indicate that Eminescu is Kuiperian in age, geologically younger than most other basins on Mercury. Geologic mapping of basin interior units indicates a distinction between smooth plains and peak-ring units. Our mapping and crater retention ages favor plains formation by impact melt rather than post-impact volcanism, but a volcanic origin for the plains cannot be excluded if the time interval between basin formation and volcanic emplacement was less than the uncertainty in relative ages. The high-albedo peak ring of Eminescu is composed of bright crater-floor deposits (BCFDs, a distinct crustal unit seen elsewhere on Mercury) exposed by the impact. We use our observations to assess predictions of peak-ring formation models. We interpret the characteristics of Eminescu as consistent with basin formation models in which a melt cavity forms during the impact formation of craters at the transition to peak ring morphologies. We suggest that the smooth plains were emplaced via impact melt expulsion from the central melt cavity during uplift of a peak ring composed of BCFD-type material. In this scenario the ringed cluster of peaks resulted from the early development of the melt cavity, which modified the central uplift zone.     

The evolution of the Onaping Formation at the Sudbury impact structure

Abstract– The 1.4–1.6 km thick Onaping Formation consists of a complex series of breccias and “melt bodies” lying above the Sudbury Igneous Complex (SIC) at the Sudbury impact structure. Based on the presence of shocked lithic clasts and various “glassy” phases, the Onaping has been described as a “suevitic” breccia, with an origin, at least in part, as fallback material. Recent mapping and a redefined stratigraphy have emphasized similarities and differences in its various vitric phases, both as clast types and discrete intrusive bodies. The nature of the Onaping and that of other “suevitic” breccias overlying impact melt sheets is reviewed. The relative thickness, internal stratigraphic and lithological character, and the relative chronology of depositional units indicate multiple processes were involved over some time in the formation of the Onaping. The Sudbury structure formed in a foreland basin and water played an essential role in the evolution of the Onaping, as indicated by a major hydrothermal system generated during its formation. Taken together, observations and interpretations of the Onaping suggest a working hypothesis for the origin of the Onaping that includes not only impact but also the interaction of sea water with the impact melt, resulting in repeated explosive interactions involving proto‐SIC materials and mixing with pre‐existing lithologies. This is complicated by additional brecciation events due to the intrusion of proto‐SIC materials into the evolving and thickening Onaping. Fragmentation mechanisms changed as the system evolved and involved vesiculation in the formation of the upper two‐thirds of the Onaping.     

Hydrothermal alteration at the Lonar Lake impact structure,India: Implications for impact cratering on Mars

Abstract— The 50,000 year old, 1.8 km diameter Lonar crater is one of only two known terrestrial craters to be emplaced in basaltic target rock (the 65 million year old Deccan Traps). The composition of the Lonar basalts is similar to martian basaltic meteorites, which establishes Lonar as an excellent analogue for similarly sized craters on the surface of Mars. Samples from cores drilled into the Lonar crater floor show that there are basaltic impact breccias that have been altered by post‐impact hydrothermal processes to produce an assemblage of secondary alteration minerals. Microprobe data and X‐ray diffraction analyses show that the alteration mineral assemblage consists primarily of saponite, with minor celadonite, and carbonate. Thermodynamic modeling and terrestrial volcanic analogues were used to demonstrate that these clay minerals formed at temperatures between 130°C and 200°C. By comparing the Lonar alteration assemblage with alteration at other terrestrial craters, we conclude that the Lonar crater represents a lower size limit for impact‐induced hydrothermal activity. Based on these results, we suggest that similarly sized craters on Mars have the potential to form hydrothermal systems, as long as liquid water was present on or near the martian surface. Furthermore, the Fe‐rich alteration minerals produced by post‐impact hydrothermal processes could contribute to the minor iron enrichment associated with the formation of the martian soil.     

Incipient melt formation and devitrification at the Wanapitei impact structure,Ontario, Canada

Abstract— The Wanapitei impact structure is ～8 km in diameter and lies within Wanapitei Lake, ～34 km northeast of the city of Sudbury. Rocks related to the 37 Ma impact event are found only in Pleistocene glacial deposits south of the lake. Most of the target rocks are metasedimentary rocks of the Proterozoic Huronian Supergroup. An almost completely vitrified, inclusion-bearing sample investigated here represents either an impact melt or a strongly shock metamorphosed, pebbly wacke. In the second, preferred interpretation, a number of partially melted and devitrified clasts are enclosed in an equally highly shock metamorphosed arkosic wacke matrix (i.e., the sample is a shocked pebbly wacke), which records the onset of shock melting. This interpretation is based on the glass composition, mineral relicts in the glass, relict rock textures, and the similar degree of shock metamorphism and incipient melting of all sample components. Boulder matrix and clasts are largely vitrified and preserve various degrees of fluidization, vesiculation, and devitrification. Peak shock pressure of ～50–60 GPa and stress experienced by the sample were somewhat below those required for complete melting and development of a homogeneous melt. The rapid cooling and devitrification history of the analyzed sample is comparable to that reported recently from glasses in the suevite of the Ries impact structure in Germany and may indicate that the analyzed sample experienced an annealing temperature after deposition of somewhere between 650 °C and 800 °C.     

Transitional impact craters on the Moon: Insight into the effect of target lithology on the impact cratering process

We studied a data set of 28 well‐preserved lunar craters in the transitional (simple‐to‐complex) regime with the aim of investigating the underlying cause(s) for morphological differences of these craters in mare versus highland terrains. These transitional craters range from 15 to 42 km in diameter, demonstrating that the transition from simple to complex craters is not abrupt and occurs over a broad diameter range. We examined and measured the following crater attributes: depth (d), diameter (D), floor diameter (D_f), rim height (h), and wall width (w), as well as the number and onset of terraces and rock slides. The number of terraces increases with increasing crater size and, in general, mare craters possess more terraces than highland craters of the same diameter. There are also clear differences in the d/D ratio of mare versus highland craters, with transitional craters in mare targets being noticeably shallower than similarly sized highland craters. We propose that layering in mare targets is a major driver for these differences. Layering provides pre‐existing planes of weakness that facilitate crater collapse, thus explaining the overall shallower depths of mare craters and the onset of crater collapse (i.e., the transition from simple to complex crater morphology) at smaller diameters as compared to highland craters. This suggests that layering and its interplay with target strength and porosity may play a more significant role than previously considered.     

Mineralogy and petrology of melt rocks from the Popigai impact structure,Siberia

Abstract— The late Eocene Popigai impact structure of Siberia comprises an approximately 0.5–1.5 km thick, ˜100 km diameter sequence of clast-rich and clast-poor andesitic to rhyolitic impact melt rocks and impact breccias, underlain by Archean to Proterozoic crystalline basement and Proterozoic to Phanerozoic sedimentary rocks. The fine-grained to cryptocrystalline texture of the more melt-rich rocks, despite their occurrence in bodies locally in excess of 800 m thick and 28 km long, suggests that the melt crystallized in response to (1) cooling by the clast load, and/or; (2) rapid nucleation on finely brecciated clasts, which have since been assimilated and/or; (3) crystallization enhanced by the relatively low water contents of the melts. Rapid crystallisation of the melt is indicated by the lack of zoning in minerals, the presence of glass, the lack of strain recovery features in clasts and the lack of evidence for fractionation in the major and trace elements, including the rare earth elements. Optical and analytical electron microscopy reveal that the previously reported division of the melt rocks into high- and low-temperature variants based on hand sample appearance, or glass content, is not warranted. Clasts within the melt-rich rocks exhibit a wide range of shock metamorphic features, though they are not distributed in the impact melts in a systematic manner. This indicates that the melt-rich rocks were well mixed during their formation, thus juxtaposing unshocked with shocked material. Injection of mesostasis melt into partially melted checkerboard plagioclase and orthopyroxene clasts also occurred during this mixing stage.     

Revisiting the Gow Lake impact structure,Saskatchewan, Canada

The ~5 km diameter Gow Lake impact structure formed in the Canadian Shield of northern Saskatchewan approximately 197 Myr ago. This structure has not been studied in detail since its discovery during a regional gravity survey in the early 1970s. We report here on field observations from a 2011 expedition that, when combined with subsequent laboratory studies, have revealed a wealth of new information about this poorly studied Canadian impact structure. Initially considered to be a prototypical central peak (i.e., a complex) impact structure, our observations demonstrate that Gow Lake is actually a transitional impact structure, making it one of only two identified on Earth. Despite its age, a well-preserved sequence of crater-fill impactites is preserved on Calder Island in the middle of Gow Lake. From the base upward, this stratigraphy is parautochthonous target rock, lithic impact breccia, clast-rich impact melt rock, red clast-poor impact melt rock, and green clast-poor impact melt rocks. Discontinuous lenses of impact melt-bearing breccia also occur near the top of the red impact melt rocks and in the uppermost green impact melt rocks. The vitric particles in these breccias display irregular and contorted outlines. This, together with their setting within crater-fill melt rocks, is indicative of an origin as flows within the transient cavity and not an airborne mode of origin. Following impact, a hydrothermal system was initiated, which resulted in alteration of the crater-fill impactites. Major alteration phases are nontronite clay, K-feldspar, and quartz.     

Impact melt rocks from the Late Paleocene Hiawatha impact structure,northwest Greenland

Impact melt rocks formed during hypervelocity impact events are ideal for studying impact structures. Here, we describe impact melt rock samples collected proximal to the 31 km wide 58 Ma Hiawatha impact structure, northwest Greenland, which is completely covered by the Greenland Ice Sheet. The melt rocks contain diagnostic shock indicators (e.g., planar deformation features [PDF] in quartz and shocked zircon) and form three groups based on melt textures and chemistry: (i) hypocrystalline, (ii) glassy, and (iii) carbonate-based melt rocks. The exposed foreland directly in front of the structure consists of metasedimentary successions and igneous plutons; however, the carbonate-based impactites indicate a mixed target sequence with a significant carbonate-rich component. Well-preserved organic material in some melt rocks indicates that North Greenland at the time of impact was host to abundant organic material, likely a dense high-latitude temperate forest. Geochemical signatures of platinum-group elements in selected samples indicate an extraterrestrial component and support previous identification of a highly fractionated iron impactor in glaciofluvial sand. Our results illustrate the possibility to study impact structures hidden beneath a thick ice sheet based on transported samples and this opens a new avenue for identifying other potential impact craters in Greenland and Antarctica.     

New impact‐melt rock from the Roter Kamm impact structure,Namibia: Further constraints on impact age,melt rock chemistry,and projectile composition

Abstract— A new locality of in situ massive impact‐melt rock was discovered on the south‐southwestern rim of the Roter Kamm impact structure. While the sub‐samples from this new locality are relatively homogeneous at the hand specimen scale, and despite being from a nearby location, they do not have the same composition of the only previously analyzed impact‐melt rock sample from Roter Kamm. Both Roter Kamm impact‐melt rock samples analyzed to date, as well as several suevite samples, exhibit a granitic‐granodioritic precursor composition. Micro‐chemical analyses of glassy matrix and Al‐rich orthopyroxene microphenocrysts demonstrate rapid cooling and chemical disequilibrium at small scales. Platinum‐group element abundances and ratios indicate an ordinary chondritic composition for the Roter Kamm impactor. Laser argon dating of two sub‐samples did not reproduce the previously obtained age of 3.7 ± 0.3 (1s?) for this impact event, based on ⁴⁰Ar/³⁹Ar dating of a single vesicular impact‐melt rock. Instead, we obtained ages between 3.9 and 6.3 Ma, with an inverse isochron age of 4.7 ± 0.3 Ma for one analyzed sub‐sample and 5.1 ± 0.4 Ma for the other. Clearly a post‐5 Ma impact at Roter Kamm remains indicated, but further analytical work is required to better constrain the currently best estimate of 4–5 Ma. Both impactor and age constraints are clearly obstructed by the inherent microscopic heterogeneity and disequilibrium melting and cooling processes demonstrated in the present study.     

Incipient devitrification of impact melt particles at Bosumtwi crater,Ghana: Implications for suevite cooling history and melt dispersion

The petrographic, mineralogical, and geochemical compositions of the incipient devitrification products in impact melt fragments found in outer suevites at the Bosumtwi impact crater were studied to reconstruct the postimpact environmental constraints on the suevite formation and to refine its cooling history. Our study shows that devitrified melt/particles contain numerous microlitic crystals and crystal aggregates of different shapes derived from rapid cooling. The matrix of melt/particles in Bosumtwi suevites contains abundant Mg‐hercynite (pleonaste)‐type spinels with sizes rarely exceeding a few micrometers. High nucleation density of microlites suggests rapid crystallization under strong undercooling in the presence of abundant volatiles. Although the Bosumtwi impact event took place in a continental environment, the possible sources for elevated fluid/volatile content could have been the groundwater in the deeply weathered and fractured‐jointed Birimian basement, dewatering of abundant hydrous phases in weathered crust or hydrothermally altered basement, and the shale/phyllite–greywacke lithologies in the target rocks. Our results show that enough volatiles were present in the target rocks at the time of impact for the effective impact melt dispersion observed in Bosumtwi impactites.     

Accessory and opaque minerals in impact melt rocks of the Boltysh structure,Ukraine

Electron microprobe analyses of accessory and opaque minerals from the impact melt rocks of the Boltysh structure, in the central part of the Ukrainian Shield, are presented in this report. Our study establishes a variety of minerals represented by native metals, alloys, oxides, sulfides, phosphates, and silicates, formed during several stages of cooling and solidification of the thick impact melt sheet. Baddeleyite was determined to be the earliest high‐temperature mineral to occur in the impact melt rocks. Iron and titanium oxides crystallized earlier or simultaneously with the microliths of orthopyroxene and feldspars. High concentrations of TiO₂, Al₂O₃, and Cr₂O₃ were identified in some hematite varieties. Cu‐ and Ni‐bearing pyrrhotites occur in impact melt rocks with a glassy matrix. Native metals—copper, platinum, and silver—were likely formed due to the hydrothermal alteration of the upper unit of the impact melt sheet. Zircon is the only accessory mineral found in impact melt rocks that is preserved from the basement granites of the Boltysh structure.     

Geochemical evidence of an extraterrestrial component in impact melt breccia from the Paleoproterozoic Dhala impact structure,India

The Paleoproterozoic Dhala structure with an estimated diameter of ~11 km is a confirmed complex impact structure located in the central Indian state of Madhya Pradesh in predominantly granitic basement (2.65 Ga), in the northwestern part of the Archean Bundelkhand craton. The target lithology is granitic in composition but includes a variety of meta‐supracrustal rock types. The impactites and target rocks are overlain by ~1.7 Ga sediments of the Dhala Group and the Vindhyan Supergroup. The area was cored in more than 70 locations and the subsurface lithology shows pseudotachylitic breccia, impact melt breccia, suevite, lithic breccias, and postimpact sediments. Despite extensive erosion, the Dhala structure is well preserved and displays nearly all the diagnostic microscopic shock metamorphic features. This study is aimed at identifying the presence of an impactor component in impact melt rock by analyzing the siderophile element concentrations and rhenium‐osmium isotopic compositions of four samples of impactites (three melt breccias and one lithic breccia) and two samples of target rock (a biotite granite and a mafic intrusive rock). The impact melt breccias are of granitic composition. In some samples, the siderophile elements and HREE enrichment observed are comparable to the target rock abundances. The Cr versus Ir concentrations indicate the probable admixture of approximately 0.3 wt.% of an extraterrestrial component to the impact melt breccia. The Re and Os abundances and the ¹⁸⁷Os/¹⁸⁸Os ratio of 0.133 of one melt breccia specimen confirm the presence of an extraterrestrial component, although the impactor type characterization still remains inconclusive.     

Multiphase emplacement of impact melt sheet into the footwall: Offset dykes of the Sudbury Igneous Complex,Canada

The offset dykes of the Sudbury Igneous Complex comprise two distinct main magmatic facies, a high-temperature inclusion-free quartz diorite (QD), and a subsequently intruded lower temperature, mineralized, and inclusion-rich quartz diorite (MIQD). The MIQD facies was emplaced after QD dykes had solidified. Key controlling factors of the two injection phases were (1) the development of a coherent roof, which confined the melt sheet; and (2) the periodic increase of melt and fluid pressure within the melt sheet. For the injection of QD melt, the melt pressure exceeded the normal stress acting on fracture surfaces. For the later refracturing of QD dykes and the injection of MIQD melt, the melt pressure increased further, exceeding the tensile strength of, and the normal stress acting on, QD dykes. We associate the melt pressure increase required for both injection episodes with degassing and devolatilization of cooling melt close to the roof. Within the hydraulically connected melt column, the related pressure increase was transmitted to the base of the melt sheet where QD and MIQD melt was extracted into dykes. Residual core to rim thermal gradients in the QD dykes produced tensile strength gradients, accounting for the typically central location of MIQD dykes within QD dykes.     

Dynamic interaction between impact melt and fragmented basement at Manicouagan: The suevite connection

The interface between impact melt rocks and underlying footwall lithologies within the Manicouagan impact structure is defined by a zone of dynamic mixing (<20 m thick). This zone transitions as a continuum from clast‐free to clast‐bearing impact melt rocks, through melt‐bearing breccias to melt‐free breccias. Field observations; microscopy; and major, trace, and rare earth element analysis indicate that the breccias are derived by blending two endmembers during the impact process: impact melt and brecciated footwall. The product is a basal breccia sequence, which locally includes the rock type referred to as suevite. In this occurrence, the suevite is a submelt sheet variety, in contrast to similar lithologies that are developed atop impact melt sheets, or beyond crater rims. Dynamic mixing between impact melt and basal clastic material at Manicouagan is attributed to the initial high‐speed centrifugal outflow of superheated, low viscosity impact melt over underlying fractured and fragmented footwall, and its centripetal return during the earlier stages of the crater modification process. The interaction of two fluids (melt with a mobilized granular medium) possessing contrasting densities, and moving at different velocities, can facilitate shear instabilities and turbulent mixing that may be characteristic of Kelvin–Helmholtz behavior.     

Complex crater formation: Insights from combining observations of shock pressure distribution with numerical models at the West Clearwater Lake impact structure

Large impact structures have complex morphologies, with zones of structural uplift that can be expressed topographically as central peaks and/or peak rings internal to the crater rim. The formation of these structures requires transient strength reduction in the target material and one of the proposed mechanisms to explain this behavior is acoustic fluidization. Here, samples of shock‐metamorphosed quartz‐bearing lithologies at the West Clearwater Lake impact structure, Canada, are used to estimate the maximum recorded shock pressures in three dimensions across the crater. These measurements demonstrate that the currently observed distribution of shock metamorphism is strongly controlled by the formation of the structural uplift. The distribution of peak shock pressures, together with apparent crater morphology and geological observations, is compared with numerical impact simulations to constrain parameters used in the block‐model implementation of acoustic fluidization. The numerical simulations produce craters that are consistent with morphological and geological observations. The results show that the regeneration of acoustic energy must be an important feature of acoustic fluidization in crater collapse, and should be included in future implementations. Based on the comparison between observational data and impact simulations, we conclude that the West Clearwater Lake structure had an original rim (final crater) diameter of 35–40 km and has since experienced up to ~2 km of differential erosion.     

Cathodoluminescence as a tool to discriminate impact melt,shocked and unshocked volcanics: A case study of samples from the El'gygytgyn impact structure

El'gygytgyn (Chukotka, Arctic Russia) is a well‐preserved impact structure, mostly excavated in siliceous volcanic rocks. For this reason, the El'gygytgyn structure has been investigated in recent years and drilled in 2009 in the framework of an ICDP (International Continental Scientific Drilling Program) project. The target rocks mostly consist of rhyodacitic ignimbrites and tuffs, which make it difficult to distinguish impact melt clasts from fragments of unshocked target rock within the impact breccia. Several chemical and petrologic attempts, other than dating individual clasts, have been considered to distinguish impact melt from unshocked volcanic rock of the targets, but none has proven reliable. Here, we propose to use cathodoluminescence (imaging and spectrometry), whose intensity is inversely correlated with the degree of shock metamorphism experienced by the investigated lithology, to aid in such a distinction. Specifically, impact melt rocks display low cathodoluminescence intensity, whereas unshocked volcanic rocks from the area typically show high luminescence. This high luminescence decreases with the degree of shock experienced by the individual clasts in the impact breccia, down to almost undetectable when the groundmass is completely molten. This might apply only to El'gygytgyn, because the luminescence in volcanic rocks might be due to devitrification and recrystallization processes of the relatively old (Cretaceous) target rock with respect to the young impactites (3.58 Ma). The alteration that affects most samples from the drill core does not have a significant effect on the cathodoluminescence response. In conclusion, cathodoluminescence imaging and spectra, supported by Raman spectroscopy, potentially provide a useful tool for in situ characterization of siliceous impactites formed in volcanic target.