Changes in carbon and nutrient fluxes from headwaters to ocean in a mountainous temperate to subtropical basin

Water erosion provides major links in global cycles of carbon (C), nitrogen (N) and phosphorus (P). Although significant research on erosion mechanisms has been done, there is still little knowledge on C, N and P fluxes across landscapes to the ocean and their controlling factors in subtropical climates. A four‐year study quantifying and comparing particulate and dissolved C, N and P from multiple scales (microplot, plot, microcatchment, subcatchment, catchment, sub‐basin and basin) was performed in Thukela basin (≈30 000 km²), South Africa. The basin climate was largely subtropical‐humid [mean annual precipitation (MAP) > 980 mm yr^‐1], but temperate (MAP >2000 mm yr^‐1) on the highlands. Open grassland, cropland and bushland were the major land uses. On average, 65, 24 and 4 g m^‐2 yr^‐1 C, N and P were displaced from original topsoil positions, but only 0.33, 0.005 and 0.002 mg m^‐2 yr^‐1 were, respectively, exported to the ocean. The fluxes decreased by 95, 97 and 84%, respectively, from plot to microcatchment outlet; and decreased further in downstream direction by >99% from microcatchment to basin outlet. The hillslope (microplot to microcatchment) fluxes correlated strongly with rainfall parameters. Particulate contributions dominated hillslope fluxes at 73, 81 and 76% of total annual C, N and P, respectively. Although particulate C dominated in the microcatchment‐catchment reach (55%), N (54%) and P (69%) were dominated by dissolved forms. The lower basin zone was dominated by dissolved flux contributions at 93, 81 and 78% for C, N and P for the sub‐basin outlet. These results suggested spatially varying drivers of C, N and P losses from the landscape to the ocean, via the river network. Deposition was envisaged the dominant hillslope level loss process, which gradually gave way to mineralization and biotic uptake in the river network as flux contributions shifted from being predominantly particulate to dissolved forms. Copyright © 2017 John Wiley & Sons, Ltd.     

The increase of rainfall erosivity and initial soil erosion processes due to rainfall acidification

The drastic growth of population in highly industrialized urban areas, as well as fossil fuel use, is increasing levels of airborne pollutants and enhancing acid rain. In rapidly developing countries such as Iran, the occurrence of acid rain has also increased. Acid rain is a driving factor of erosion due to the destructive effects on biota and aggregate stability; however, little is known about its impact on specific rates of erosion at the pedon scale. Thus, the present study aimed to investigate the effect of acid rain at pH levels of 5.25, 4.25, and 3.75 for rainfall intensities of 40, 60, and 80 mm h^?1 on initial soil erosion processes under dry and saturated soil conditions using rainfall simulations. The results were compared using a two‐way ANOVA and Duncan tests and showed that initial soil erosion rates with acidic rain and non‐acidic rain under dry soil conditions were significantly different. The highest levels of soil particle loss due to splash effects in all rainfall intensities were observed with the most acidic rain (pH = 3.75), reaching maximum values of 16 g m^?2 min^?1. The lowest levels of particle losses were observed in the control plot where non‐acidic rain was used, with values ranging from 3.8 to 8.1 g m^?2 min^?1. Similarly, under saturated soil conditions, the lowest level of soil particle loss was observed in the control plot, and the highest peaks of soil loss were observed for the most acidic rains (pH = 3.75 and pH = 4.25), reaching maximum average values of 40 g m^?2 min^?1. However, for saturated soils with acidic water but with non‐acidic rain, the highest soil particle loss was observed for the control plot for all the rainfall intensities. In conclusion, acidic rain has a negative impact on soils, which can be more intense with a concomitant increase in rainfall intensity. Rapid solutions, therefore, need to be found to reduce the emission of pollutants into the air, otherwise, rainfall erosivity may drastically increase.     

Lockdown as an Empirical Strategy to Curb Air Pollution: Evidence from a Quasi-Natural Experiment

In this study, three approaches namely parallel, sequential, and multiple linear regression are applied to analyze the local air quality improvements during the COVID-19 lockdowns. In the present work, the authors have analyzed the monitoring data of the following primary air pollutants: particulate matter (PM₁₀ and PM_2.5), nitrogen dioxide (NO₂), sulfur dioxide (SO₂), and carbon monoxide (CO). During the lockdown period, the first phase has most noticeable impact on airquality evidenced by the parallel approach, and it has reflected a significant reduction in concentration levels of PM₁₀ (27%), PM_2.5 (19%), NO₂ (74%), SO₂ (36%), and CO (47%), respectively. In the sequential approach, a reduction in pollution levels is also observed for different pollutants, however, these results are biased due to rainfall in that period. In the multiple linear regression approach, the concentrations of primary air pollutants are selected, and set as target variables to predict their expected values during the city's lockdown period.The obtained results suggest that if a 21-days lockdown is implemented, then a reduction of 42 µg m⁻³ in PM₁₀, 23 µg m⁻³ in PM_2.5, 14 µg m⁻³ in NO₂, 2 µg m⁻³ in SO₂, and 0.7 mg m⁻³ in CO can be achieved.     

A reassessment of current volcanic emissions from the Central American arc with specific examples from Nicaragua

The Central American volcanic arc supplies a significant proportion of the persistent annual global sulphur dioxide emissions from volcanoes. In November/December 2003, we completed a survey of the arc section from Mombacho to San Cristóbal in Nicaragua recording individual mean fluxes of 800, 530 and 220 Mg day^− 1 in the plumes from San Cristóbal, Telica and Masaya, respectively. An assessment of fluxes published since 1997 along the entire Central America arc yields a mean total arc flux of SO₂ of 4360 Mg day^− 1 or 8–16% of the annual estimated global volcanic SO₂ flux to the troposphere. New field data shows that Masaya volcano continues to show stable HCl/SO₂ and HF/SO₂ ratios, suggesting a sustained flux of these components of ∼ 220 and 30 Mg day^− 1, respectively (1997 to 2004). Masaya's plume composition also appears to have been stable, between 2001 and 2003, with respect to all the particulate species measured, with significant fluxes of SO₄²⁻ (4 Mg day^− 1), Na⁺ (0.9–1.3 Mg day^− 1) and K⁺ (0.7 Mg day^− 1). Extrapolating the Masaya plume species ratios to the entire Central American arc gives mean HCl and HF fluxes of 1300 and 170 Mg day^− 1 and a particulate sulphate flux of 40 Mg day^− 1 for 1997 to 2004, although without further understanding of the degassing processes and sources at depth of these different volatiles, these arc-scale estimates should be treated with caution. Combining our arc scale mean SO₂ flux with published measurements of volcanic gas compositions with respect to CO₂ and H₂O allows us to estimate mean CO₂ fluxes of 4400–9600 Mg day^− 1 and H₂O fluxes of 70,000–78,000 Mg day^− 1 for the arc. Preliminary comparisons of these estimates of outgassing rates with published volatile input fluxes into the Central American subduction zone, suggest that Cl is more efficiently recycled through the subduction zone than CO₂. The results for H₂O are inconclusive.     

The effects of tillage induced surface roughness,slope and discharge rate on soil detachment by concentrated flow: An experimental study

Soil erosion in sloping cropland is a key water and soil conservation issue in the Loess Plateau region, China. How surface roughness influences soil detachment remains unclear due to the inconsistent results obtained from existing studies. The objectives of the present study were to evaluate the effects of tillage practices on soil detachment rate in sloping cropland and establish an accurate empirical model for the prediction of soil detachment rates. A series of movable bed experiments were conducted on sloping surfaces under three different tillage practices (manual dibbling, manual hoeing, and contour drilling), with a smooth surface (non-tillage) as a control. The research indicated that soil detachment rate significantly increased with roughness (p < 0.05) since the average soil detachment rate was the highest under the contour drilling treatment (6.762 g m⁻² s⁻¹), followed by manual hoeing (4.180 g m⁻² s⁻¹), and manual dibbling (3.334 g m⁻² s⁻¹); the lowest detachment rate was observed under the non-tillage treatment (3.214 g m⁻² s⁻¹). Slope gradient and unit discharge rate were positively correlated with soil detachment rate and proved to be more influential than soil surface roughness. Four composite hydraulic parameters were introduced to estimate soil detachment rate on tilled surfaces. Regression analyses revealed that stream power was the most effective predictor of soil detachment rate compared with unit length shear force, shear stress, and unit stream power. By integrating surface roughness as a variable, the detachment rate could be accurately described as a nonlinear function of stream power and surface roughness. The results of the present study indicate that tillage practice could influence soil loss on sloping cropland, considering the higher soil detachment rates under all tillage practices tested compared with non-tillage. The results are attributed mainly to concentrated flow caused by the high water storage levels on tilled surfaces, which could damage surface microtopography and, subsequently, the development of headcuts.     

Assessment of the impact of different vegetation patterns on soil erosion processes on semiarid loess slopes

Soil erosion hinders the recovery and development of ecosystems in semiarid regions. Rainstorms, coupled with the absence of vegetation and improper land management, are important causes of soil erosion in such areas. Greater effort should be made to quantify the initial erosion processes and try to find better solutions for soil and water conservation. In this research, 54 rainfall simulations were performed to assess the impacts of vegetation patterns on soil erosion in a semiarid area of the Loess Plateau, China. Three rainfall intensities (15 mm h^‐1, 30 mm h^‐1 and 60 mm h^‐1) and six vegetation patterns (arbors‐shrubs‐grass ‐A‐S‐G‐, arbors‐grass‐shrubs ‐A‐G‐S‐, shrubs‐arbors‐grass ‐S‐A‐G‐, shrubs‐grass‐arbors ‐S‐G‐A‐, grass‐shrubs‐arbors ‐G‐S‐A‐ and grass‐arbors‐shrubs ‐G‐A‐S‐) were examined at different slope positions (summits, backslopes and footslopes) in the plots (33.3%, 33.3%, 33.3%), respectively. Results showed that the response of soil erosion to rainfall intensity differed under different vegetation patterns. On average, increasing rainfall intensity by 2 to 4 times induced increases of 3.1 to 12.5 times in total runoff and 6.9 to 46.4 times in total sediment yield, respectively. Moreover, if total biomass was held constant across the slope, the patterns of A‐G‐S and A‐S‐G (planting arbor at the summit position) had the highest runoff (18.34 L m^‐2 h^‐1) and soil losses (197.98 g m^‐2 h^‐1), while S‐A‐G had the lowest runoff (5.51 L m^‐2 h^‐1) and soil loss (21.77 g m^‐2 h^‐1). As indicated by redundancy analysis (RDA) and Pearson correlation results, a greater volume of vegetation located on the back‐ and footslopes acted as effective buffers to prevent runoff generation and sediment yield. Our findings indicated that adjusting vegetation position along slopes can be a crucial tool to control water erosion and benefit ecosystem restoration on the Loess Plateau and other similar regions of the world. Copyright © 2018 John Wiley & Sons, Ltd.     

Plot‐scale measurement of soil erosion at the experimental area of Sparacia (southern Italy)

Obtaining good quality soil loss data from plots requires knowledge of the factors that affect natural and measurement data variability and of the erosion processes that occur on plots of different sizes. Data variability was investigated in southern Italy by collecting runoff and soil loss from four universal soil‐loss equation (USLE) plots of 176 m², 20 ‘large’ microplots (0·16 m²) and 40 ‘small’ microplots (0·04 m²). For the four most erosive events (event erosivity index, R_e ≥ 139 MJ mm ha^?1 h^?1), mean soil loss from the USLE plots was significantly correlated with R_e. Variability of soil loss measurements from microplots was five to ten times greater than that of runoff measurements. Doubling the linear size of the microplots reduced mean runoff and soil loss measurements by a factor of 2·6–2·8 and increased data variability. Using sieved soil instead of natural soil increased runoff and soil loss by a factor of 1·3–1·5. Interrill erosion was a minor part (0·1–7·1%) of rill plus interrill erosion. The developed analysis showed that the USLE scheme was usable to predict mean soil loss at plot scale in Mediterranean areas. A microplot of 0·04 m² could be used in practice to obtain field measurements of interrill soil erodibility in areas having steep slopes. Copyright © 2003 John Wiley & Sons, Ltd.     

Controls on a scale explicit analysis of sheet erosion

Although the impact of sheet erosion on the evolution of soils, soil properties and associated ecosystem services across landscapes is undisputed, there are still large uncertainties in the estimation of sheet erosion, as the results obtained are highly scale dependent. Consequently, there is a need to develop a scale‐explicit understanding of sediment erosion yields, from microplot to hillslope through to plot, to surmount actual erosion modelling flaws and to improve guidance for erosion mitigation. The main objective of this study was to compare sediment yields from small and large plots installed under different environmental conditions and to interpret these results in terms of the main mechanisms and controlling factors of sheet erosion. Fifteen 1 × 1 m² and ten 2 × 5 m² plots were installed on a hillslope in the foothills of the Drakensberg, South Africa. Data of runoff, sediment concentration (SC), soil loss (SL) and rainfall characteristics obtained during the 2009–2010 rainy season at the two spatial scales and from different soils, vegetation cover, geology and topographic conditions were used to identify the main controlling factors of sheet erosion. Scale ratios for SC and SL were subsequently calculated to assess the level of contribution of rain‐impacted flow (RIF) to overall sheet erosion. The average runoff rate (n = 17 events) ranged between 4.9 ± 0.4 L m^‐2 on 1 m² and 5.4 ± 0.6 L m² on 10 m², which did not correspond to significant differences at P < 0.05 level. Sediment losses were significantly higher on the 10 m² plots, compared with the 1 m² plots (2.2 ± 0.4 vs 1.5 ± 0.2 g L^‐1 for SC; 9.8 ± 1.8 vs 3.2 ± 0.3 g m^‐2 for SL), which illustrated a greater efficiency of sheet erosion on longer slopes. Results from a principal component analysis, whose two first axes explained 60% of the data variance, suggested that sheet erosion is mainly controlled by rainfall characteristics (rainfall intensity and amount) and soil surface features (crusting and vegetation coverage). The contribution of RIF to sheet erosion was the lowest at high soil clay content (r = 0.26) and the highest at high crusting and bulk density (r = 0.22), cumulative rainfall amount in the season and associated rise in soil water table (r = 0.29). Such an explicit consideration of the role of scale on sediment yields and process domination by either in situ (soil and soil surface conditions) or ex situ (rainfall characteristics and antecedent rainfall) factors, is expected to contribute to process‐based modelling and erosion mitigation. Copyright © 2012 John Wiley & Sons, Ltd.     

Spatial prediction of temporal soil moisture dynamics using HYDRUS‐1D

This article investigates the soil moisture dynamics within two catchments (Stanley and Krui) in the Goulburn River in NSW during a 3‐year period (2005–2007) using the HYDRUS‐1D soil water model. Sensitivity analyses indicated that soil type, and leaf area index were the key parameters affecting model performance. The model was satisfactorily calibrated on the Stanley microcatchment sites with a single point rainfall record from this microcatchment for both surface 30 cm and full‐profile soil moisture measurements. Good correlations were obtained between observed and simulated soil water storage when calibrations for one site were applied to the other sites. We extended the predictions of soil moisture to a larger spatial scale using the calibrated soil and vegetation parameters to the sites in the Krui catchment where soil moisture measurement sites were up to 30 km distant from Stanley. Similarly good results show that it is possible to use a calibrated soil moisture model with measurements at a single site to extrapolate the soil moisture to other sites for a catchment with an area of up to 1000 km² given similar soils and vegetation and local rainfall data. Site predictions were effectively improved by our simple data assimilation method using only a few sample data collected from the site. This article demonstrates the potential usefulness of continuous time, point‐scale soil moisture data (typical of that measured by permanently installed TDR probes) and simulations for predicting the soil wetness status over a catchment of significant size (up to 1000 km²). Copyright © 2012 John Wiley & Sons, Ltd.     

Mercury cycling during acid rain recovery at the forested Lesní potok catchment,Czech Republic

From 2011 to 2019, mercury (Hg) stores and fluxes were studied in the small forested catchment Lesní potok (LES) in the central Czech Republic using the watershed mass balance approach together with internal measurements. Mean input fluxes of Hg via open bulk deposition, beech throughfall and spruce throughfall during the periodwere 2.9, 3.9 and 7.6 μg m⁻² year⁻¹, respectively. These values were considerably lower than corresponding deposition Hg fluxes reported in the early years of the 21st century from catchments in Germany. Current bulk precipitation inputs at unimpacted Czech mountainous sites were lower than those in Germany. The largest Hg inputs to the catchment were via litterfall, averaging 22.6 and 17.8 μg m⁻² year⁻¹ for beech and spruce stands. The average Hg input, based on the sum of mean litterfall and throughfall deposition, was 23.0 μg m⁻² year⁻¹, compared to the estimated Hg output in runoff of 0.5 μg m⁻² year⁻¹, which is low compared to other reported values. Thus, only ~2% of Hg input is exported in stream runoff. Stream water Hg was only weakly related to dissolved organic carbon (DOC) but both concentrations were positively correlated with water temperature. The estimated total soil Hg pool averaged 47.5 mg m⁻², only 4% of which was in the O-horizon. Thus Hg in the O-horizon pool represents 72 years of deposition at the current input flux and 3800 years of export at the current runoff flux. Age-dating by ¹⁴C suggested that organic soil contains Hg from recent deposition, while mineral soil at 40–80 cm depth contained 4400-year old carbon, suggesting the soil had accumulated atmospheric Hg inputs through millennia to reach the highest soil Hg pool of the soil profile. These findings suggest that industrial era intensification of the Hg cycle is superimposed on a slower-paced Hg cycle during most of the Holocene.     

CO<Subscript>2</Subscript> and He degassing at El Chichón volcano,Chiapas, Mexico: gas flux,origin and relationship with local and regional tectonics

During 2007–2008, three CO₂ flux surveys were performed on El Chichón volcanic lake, Chiapas, Mexico, with an additional survey in April 2008 covering the entire crater floor (including the lake). The mean CO₂ flux calculated by sequential Gaussian simulation from the lake was 1,190 (March 2007), 730 (December 2007) and 1,134 g m⁻² day⁻¹ (April 2008) with total emission rates of 164 ± 9.5 (March 2007), 59 ± 2.5 (December 2007) and 109 ± 6.6 t day⁻¹ (April 2008). The mean CO₂ flux estimated from the entire crater floor area was 1,102 g m⁻² day⁻¹ for April 2008 with a total emission rate of 144 ± 5.9 t day⁻¹. Significant change in CO₂ flux was not detected during the period of survey, and the mapping of the CO₂ flux highlighted lineaments reflecting the main local and regional tectonic patterns. The ³He/⁴He ratio (as high as 8.1 R _A) for gases in the El Chichón crater is generally higher than those observed at the neighbouring Transmexican Volcanic Belt and the Central American Volcanic Arc. The CO₂/³He ratios for the high ³He/⁴He gases tend to have the MORB-like values (1.41 × 10⁹), and the CO₂/³He ratios for the lower ³He/⁴He gases fall within the range for the arc-type gases. The high ³He/⁴He ratios, the MORB-like CO₂/³He ratios for the high ³He/⁴He gases and high proportion of MORB-CO₂ (M = 25 ±15%) at El Chichón indicate a greater depth for the generation of magma when compared to typical arc volcanoes.     

The impact of upland land management on flooding: results from an improved pasture hillslope

In response to growing concern about impacts of upland agricultural land management on flood risk, an intensely instrumented experimental catchment has been established at Pontbren, a sheep‐farmed headwater catchment of the River Severn, UK. Primary aims are to develop understanding of the processes governing flood generation and the associated impacts of land management practices, and to bridge the gap between process understanding and ability to predict effects on downstream flooding. To achieve this, the experiment is designed to operate at plot (～100 m²), hillslope (～0·1 km²) and small catchment scale (～10 km²). Hillslope‐scale data, from an under‐drained, agriculturally ‘improved’ pasture, show that drain flow is a dominant runoff process. However, depending on antecedent moisture conditions, overland flow may exceed drain flow rates and can be an important contributor to peak flow runoff at the hillslope‐scale. Flow, soil tension data and tracer tests confirm the importance of macropores and presence of perched water tables under ‘normal’ wet conditions. Comparisons of pasture runoff with that from within a 10 year‐old tree shelterbelt show significantly reduced overland flow due to the presence of trees and/or absence of sheep. Comparisons of soil hydraulic properties show significant increases in hydraulic conductivity and saturated moisture content of soil under trees compared to adjacent improved pasture. Copyright © 2008 John Wiley & Sons, Ltd.     

Vertical hydraulic exchange and the contribution of hyporheic community respiration to whole ecosystem respiration in the River Lahn (Germany)

To quantify the contribution of hyporheic community respiration to whole running-water ecosystem respiration in a cultural landscape setting, we studied the vertical hydraulic exchange in riffle–pool sequences of the River Lahn (Germany). We used flow through curves from four tracer experiments to estimate flow velocities in the surface and subsurface water. Generally, vertical exchange velocities were higher in riffle sections and a high temporal variability was observed (range of values 0.11–1.08 m day⁻¹). We then used (1) the exchange velocities and (2) time series of dissolved oxygen concentration in surface and subsurface water to calculate hyporheic respiration. Hyporheic respiration was estimated in a range of 10–50 mg O₂ m⁻³ day⁻¹ for the upper sediment layer (first 20 cm). It was much lower in the deeper sediment layer (20–40 cm), ranging from 0 to 10 mg O₂ m⁻³ day⁻¹ (volumes are volumes of interstitial water; the average porosity was 20%). We determined primary production and respiration of the biofilm growing on the sediment by modelling dissolved oxygen concentration time series for a 2,450 m long stream reach (dissolved oxygen concentrations with diurnal variations from 8 to 16 mg L⁻¹). Modelled respiration rates ranged from 2 to 21 g O₂ m² day⁻¹. All information was integrated in a system analysis with numerical simulations of respiration with and without sediments. Results indicated that hyporheic respiration accounted for 6 to 14% of whole ecosystem respiration. These values are much lower than in other whole system respiration studies on more oligotrophic river systems.     

Are spatial patterns of soil moisture at plot scales generalisable across catchments,climates, and other characteristics? A synthesis of synoptic soil moisture across the Mid-Atlantic

The spatial variation of soil moisture over very small areas (<100 m²) can have nonlinear impacts on cycling and flux rates resulting in bias if it is not considered, but measuring this variation is difficult over extensive temporal and spatial scales. Most studies examining spatial variation of soil moisture were conducted at hillslope (0.01 km²) to multi-catchment spatial scales (1000 km²). They found the greatest variation at mid wetness levels and the smallest variation at wet and dry wetness levels forming a concave down relationship. There is growing evidence that concave down relationships formed between spatial variation of soil moisture and average soil moisture are consistent across spatial scales spanning several orders of magnitude, but more research is needed at very small, plot scales (<100 m²). The goal of this study was to characterise spatial variation in shallow soil moisture at the plot scale by relating the mean of measurements collected in a plot to the standard deviation (SD). We combined data from a previous study with thousands of new soil moisture measurements from 212 plots in eight catchments distributed across the US Mid-Atlantic Region to (1) test for a generalisable mean–SD relationship at plot scales, (2) characterise how landcover, land use, season, and hillslope position contribute to differences in mean–SD relationships, and (3) use these generalised mean–SD relationships to quantify their impacts on catchment scale nitrification and denitrification potential. Our study found that 98% of all measurements formed a generalised mean–SD relationship like those observed at hillslope and catchment spatial scales. The remaining 2% of data comprised a mean–SD relationship with greater spatial variation that originated from two riparian plots reported in a previous study. Incorporating the generalised mean–SD relationship into estimates of nitrification and denitrification potential revealed strong bias that was even greater when incorporating mean–SD observations from the two riparian plots with significantly greater spatial variation.     

Nitrogen retention in a floodplain backwater of the upper Mississippi River (USA)

Backwaters connected to large rivers retain nitrate and may play an important role in reducing downstream loading to coastal marine environments. A summer nitrogen (N) inflow-outflow budget was examined for a flow-regulated backwater of the upper Mississippi River in conjunction with laboratory estimates of sediment ammonium and nitrate fluxes, organic N mineralization, nitrification, and denitrification to provide further insight into N retention processes. External N loading was overwhelmingly dominated by nitrate and 54% of the input was retained (137 mg m⁻² day⁻¹). Ammonium and dissolved organic N were exported from the backwater (14 and 9 mg m⁻² day⁻¹, respectively). Nitrate influx to sediment increased as a function of increasing initial nitrate concentration in the overlying water. Rates were greater under anoxic versus oxic conditions. Ammonium effluxes from sediment were 26.7 and 50.6 mg m⁻² day⁻¹ under oxic and anoxic conditions, respectively. Since anoxia inhibited nitrification, the difference between ammonium anoxic–oxic fluxes approximated a nitrification rate of 29.1 mg m⁻² day⁻¹. Organic N mineralization was 64 mg m⁻² day⁻¹. Denitrification, estimated from regression relationships between oxic nitrate influx versus initial nitrate concentration and a summer lakewide mean nitrate concentration of 1.27 mg l⁻¹, was 94 mg m⁻² day⁻¹. Denitrification was equivalent to only 57% of the retained nitrate, suggesting that another portion was assimilated by biota. The high sediment organic N mineralization and ammonium efflux rate coupled with the occurrence of ammonium export from the system suggested a possible link between biotic assimilation of nitrate, mineralization, and export.     

Quantifying the effects of plant litter in the topsoil on the soil detachment process by overland flow in typical grasslands of the Loess Plateau,China

Plant litter can be incorporated into topsoil by a natural process, affecting the soil erosion process. This is a widespread phenomenon in erosion-prone areas. This study was conducted to investigate the effect of litter incorporation on the process of soil detachment on the Loess Plateau, China. Four common plant litters (Bothriochloa ischaemum L. Keng., Artemisia sacrorum Ledeb., Setaria viridis L. Beauv., and Artemisia capillaris Thunb.) were collected, then incorporated into the silt loam soil at five rates (0.1, 0.4, 0.7, 1.0, and 1.3 kg m⁻²) on the basis of our field investigation. Twenty litter–soil treatments and one bare soil control were prepared. After 50 days of natural stabilization, 30 soil samples of each treatment were collected. We used a flume test to scour the soil samples under six flow shear stress conditions (5.66, 8.31, 12.21, 15.55, 19.15, and 22.11 Pa). The results showed that the different incorporated litter masses and morphological characteristics, such as litter tissue density (ranging from 0.52 to 0.68 g cm⁻³), length density (2.34 to 91.00 km m⁻³), surface area density (LSAD; 27.9 to 674.2 m² m⁻³), and volume ratio (0.003 to 0.050 m³ m⁻³), caused varied soil detachment capacities (0.043 to 4.580 kg·m⁻²·s⁻¹), rill erodibilities (0.051 to 0.237 s m⁻¹), and critical shear stresses (2.02 to 6.83 Pa). The plant litter incorporated within the soil reduced the soil detachment capacities by 38%–59%, lowered the rill erodibilities by 32%–46%, and increased the critical shear stresses by 98%–193% compared with the bare soil control. The soil containing B. ischaemum (L.) Keng. litter was more resistant to erosion. By comparing different parameters, we found that the contact area between the litter and soil was the main factor affecting the soil detachment process. The soil erosion resistance increased with the increasing contact area between the soil and litter. Furthermore, the litter incorporation effect on rill erodibility can be comprehensively reflected by LSAD (R² = .93; Nash–Sutcliffe efficiency = 0.79), which could be used to adjust the rill erodibility parameter in physical process-based soil erosion models.     

The replacement of native plants by exotic species may affect the colonization and reproduction of aquatic hyphomycetes

The tropical riparian zone has a high diversity of plant species that produce a wide variety of chemical compounds, which may be released into streams. However, in recent decades there has been an extensive replacement of tropical native vegetation by Eucalyptus monocultures. Our objective was to compare fungal colonization of Eucalyptus camaldulensis leaves with fungal colonization of native plant species from riparian zones in Brazilian Cerrado (savannah) streams. The fungal colonization and enzymatic activity significantly influenced leaf litter decomposition. Fungal sporulation rates from leaf litter varied significantly with leaf species, with E. camaldulensis showing the highest sporulation rate (1226 conidia mg⁻¹AFDM day⁻¹) and leaf mass loss (23.2 ± 0.9%). This species has the lowest lignin content and highest N concentration among the studied species. Among the studied native species, we observed the highest sporulation rate for Protium spruceanum (271 conidia mg⁻¹AFDM day⁻¹), Maprounea guianensis (268 conidia mg⁻¹AFDM day⁻¹) and Copaifera langsdorffii (196 conidia mg⁻¹AFDM day⁻¹). Overall, native plant species of the Brazilian Cerrado exhibited recalcitrant characteristics and a higher lignin:N ratio. Therefore, variations in the physical and chemical characteristics of the leaf litter could explain the higher decay rate and reproductive activity observed for E. camaldulensis. However, the detritus of this species were colonized almost exclusively by Anguillospora filiformis (99.6 ± 0.4%) and exhibited a reduction in aquatic hyphomycetes species diversity. Our results suggest that the disturbance in the composition of riparian vegetation and consequently, in the diversity of leaf litter input into streams, could change the patterns and rates of leaf litter utilization by microbial decomposers. These changes may have important consequences in the processing of organic matter and, consequently, in the functioning of freshwater ecosystems.     

Soil erosion rates on sloping cultivated land on the Loess Plateau near Ansai,Shaanxi Province,China: An investigation using 137Cs and rill measurements

Sediment yields from the rolling hills area of the Loess Plateau in northern China (10000–25000 t km⁻² yr⁻¹) are amongst the highest in the world. The sediment is believed to derive from both the deep gullies that dissect the rolling plateau and the steep cultivated fields on the slopes of the mounds between the gullies. However, there are few reliable data for erosion rates on the cultivated fields and it is suspected that current estimates (10000–16000 t km⁻² yr⁻¹) based on empirical relationships (derived from erosion plot studies) exceed the true values. This study sought to address the need for more information concerning erosion of the cultivated fields through derivation of erosion rates from measurements of rill volume and caesium-137 (¹³⁷Cs) inventories for typical fields near the village of Ansai, Shaanxi Province. The derived erosion rates are discussed and compared with estimates based on empirical relationships derived from erosion plot data. Where erosion rate estimates based on both rill volume data and ¹³⁷Cs inventories are available, they show good agreement in the pattern of downslope variation. Both show a sharp decline in erosion rates at a slope length of c. 50 m. This is tentatively attributed to a change from transport-limited to detachment-limited conditions, where rill incision reaches the undisturbed loess at the base of the plough layer. No such decline is visible in the predictions based on empirical relationships derived from erosion plot data. Further evidence is presented that supports the suggestion that these empirical relationships overestimate erosion rates at slope lengths in excess of c. 50 m. It is tentatively suggested that the rates of soil erosion from sloping cultivated fields in the rolling hills area are more likely to lie in the range 8000–10000 t km⁻² yr⁻¹ than in the higher range suggested by the empirical relationships. © 1998 John Wiley & Sons, Ltd.     

Windblown dust influenced by conventional and undercutter tillage within the Columbia Plateau,USA

Exceedance of the US Environmental Protection Agency national ambient air quality standard for PM10 (particulate matter ≤10 µm in aerodynamic diameter) within the Columbia Plateau region of the Pacific Northwest US is largely caused by wind erosion of agricultural lands managed in a winter wheat–summer fallow rotation. Land management practices, therefore, are sought that will reduce erosion and PM10 emissions during the summer fallow phase of the rotation. Horizontal soil flux and PM10 concentrations above adjacent field plots (>2 ha), with plots subject to conventional or undercutter tillage during summer fallow, were measured using creep and saltation/suspension collectors and PM10 samplers installed at various heights above the soil surface. After wheat harvest in 2004 and 2005, the plots were either disked (conventional) or undercut with wide sweeps (undercutter) the following spring and then periodically rodweeded prior to sowing wheat in late summer. Soil erosion from the fallow plots was measured during six sampling periods over two years; erosion or PM10 loss was not observed during two periods due to the presence of a crust on the soil surface. For the remaining sampling periods, total surface soil loss from conventional and undercutter tillage ranged from 3 to 40 g m^–2 and 1 to 27 g m^–2 while PM10 loss from conventional and undercutter tillage ranged from 0·2 to 5·0 g m^–2 and 0·1 to 3·3 g m^–2, respectively. Undercutter tillage resulted in a 15% to 65% reduction in soil loss and 30% to 70% reduction in PM10 loss as compared with conventional tillage at our field sites. Therefore, based on our results at two sites over two years, undercutter tillage appears to be an effective management practice to reduce dust emissions from agricultural land subject to a winter wheat–summer fallow rotation within the Columbia Plateau. Copyright © 2009 John Wiley & Sons, Ltd.     

Spatial variation of salt-marsh organic and inorganic deposition and organic carbon accumulation: Inferences from the Venice lagoon,Italy

Salt marshes are ubiquitous features of the tidal landscape governed by mutual feedbacks among processes of physical and biological nature. Improving our understanding of these feedbacks and of their effects on tidal geomorphological and ecological dynamics is a critical step to address issues related to salt-marsh conservation and response to changes in the environmental forcing. In particular, the spatial variation of organic and inorganic soil production processes at the marsh scale, a key piece of information to understand marsh responses to a changing climate, remains virtually unexplored. In order to characterize the relative importance of organic vs. inorganic deposition as a function of space, we collected 33 shallow soil sediment samples along three transects in the San Felice and Rigà salt marshes located in the Venice lagoon, Italy. The amount of organic matter in each sample was evaluated using Loss On Ignition (LOI), a hydrogen peroxide (H₂O₂) treatment, and a sodium hypochlorite (NaClO) treatment following the H₂O₂ treatment. The grain size distribution of the inorganic fraction was determined using laser diffraction techniques. Our study marshes exhibit a weakly concave-up profile, with maximum elevations and coarser inorganic grains along their edges. The amount of organic and inorganic matter content in the samples varies with the distance from the marsh edge and is very sensitive to the specific analysis method adopted. The use of a H₂O₂+NaClO treatment yields an organic matter density value which is more than double the value obtained from LOI. Overall, inorganic contributions to soil formation are greatest near the marsh edges, whereas organic soil production is the main contributor to soil accretion in the inner marsh. We interpret this pattern by considering that while plant biomass productivity is generally lower in the inner part of the marsh, organic soil decomposition rates are highest in the better aerated edge soils. Hence the higher inorganic soil content near the edge is due to the preferential deposition of inorganic sediment from the adjacent creek, and to the rapid decomposition of the relatively large biomass production. The higher organic matter content in the inner part of the marsh results from the small amounts of suspended sediment that makes it to the inner marsh, and to the low decomposition rate which more than compensates for the lower biomass productivity in the low-lying inner zones. Finally, the average soil organic carbon density from the LOI measurements is estimated to be 0.044 g C cm⁻³. The corresponding average carbon accumulation rate for the San Felice and Rigà salt marshes, 132 g C m⁻² yr⁻¹, highlights the considerable carbon stock and sequestration rate associated with coastal salt marshes.