过铝花岗岩的研究动向和进展——兼论西藏过铝花岗岩

本文主要讨论了过铝花岗岩的含义、类型、构造环境以及两种主要过铝花岗岩类的成因。并以西藏过铝花岗岩为例,阐述和分析其分布特征、主要岩石类型和岩石学、地球化学特征,初步认为西藏过铝花岗岩的成因是新特提斯洋关闭后印度板块与欧亚板块碰撞造山作用的结果,主要属同撞碰花岗岩。     

Stable isotope compositions of tourmalines from granites and related hydrothermal rocks of the Karagwe-Ankolean belt,northwest Tanzania

Tourmaline is a ubiquitous mineral in the Mid-Proterozoic, peraluminous, syn- to post-tectonic granites and aplites and the related hydrothermal rocks of the Karagwe-Ankolean belt in northwest Tanzania. Electron microprobe analysis indicates that tourmalines from all of the intrusive and hydrothermal lithologies: (1) belong to the schorl-dravite solid-solution series; and (2) plot within the field occupied by tourmaline from Li-poor granitoids on the Fe-Al-Mg classification diagram. Oxygen isotope compositions range from +12.2 to +11.6‰ (SMOW) for magmatic tourmalines and from +10.8 to +9.8‰ for those of hydrothermal origin. Hydrogen isotope compositions vary from −79 to − 65‰ (SMOW) for magmatic tourmalines and from −99 to −84‰ for hydrothermal tourmalines. Water contents measured by manometry are constant at 3.0–3.2 wt.%. Within the broad grouping there arc systematic variations in both chemical [particularly Fe_tot/(Fe_tot + Mg ratio)] and isotopic composition that relate to evolving magmatic and hydrothermal conditions. Igneous differentiation [increasing Fe_tot/(Fe_tot + Mg) in magmatic tourmaline] has produced trends with higher δ¹⁸O in quartz, lower δ¹⁸O in tourmaline, and larger Δ_QTZ.−TOUR.-values, that reflect a combination of a reduction of crystallization temperature and an increase of Fe_tot/ (Fe_tot + Mg) in the residual melt. Subsequent cooling and interaction of an exsolved, B-rich magmatic fluid with the pelitic country rocks, resulted in the deposition of hydrothermal tourmaline with increasing Fe_tot/(Fe_tot + Mg) ratios, and progressively lower δ¹⁸O and δD -values.     

Petrogenesis of the early Eocene I-type granites in west Yingjiang (SW Yunnan) and its implication for the eastern extension of the Gangdese batholiths

This study reports new zircon U–Pb and Hf isotopes and whole-rock elemental and Sr–Nd isotopic data for the gneissic granite and leucogranite from the Nabang metamorphic zone, Yingjiang area (West Yunnan, SW China). The metamorphosed granitoids crystallized during the early Eocene (~ 55–50 Ma) with zircons showing ε_Hf(t) values from + 11 to − 5.3 and crustal model ages of 1.5 to 0.42 Ga, comparable to those of coeval I-type granitoids from the Gangdese batholith, southern Lhasa. The rocks are characterized by metaluminous and weakly peraluminous hornblende-bearing gneissic granites with A/CNK = 0.95–1.09, Na₂O > K₂O, coupled with low initial Sr isotopic values of 0.7049–0.7070 and high ε_Nd(t) values from + 1.1 to − 7.1. The rocks were derived from crustal materials involving ancient upper crust/sedimentary and juvenile mantle-derived rocks. Together with available data from nearby regions, it is proposed that the early Eocene granitoids in the Nabang and Tengliang area can be correlated to the Gangdese granitoids and represent the southeastward continuation of the magmatic arc resulting from the Neotethyan subduction in southern Tibet. The petrogenesis of early Eocene granitoids in western Yunnan was probably related to the rollback of the subducting Neotethyan slab that caused the remelting of the crustal materials newly modified by the underplated basaltic magma.     

Petrogenesis of the Nanling Mountains granites from South China: Constraints from systematic apatite geochemistry and whole-rock geochemical and Sr–Nd isotope compositions

The widespread Mesozoic granitoids in South China (∼135,300 km²) were emplaced in three main periods: Triassic (16% of the total surface area of Mesozoic granitoids), Jurassic (47%), and Cretaceous (37%). Though much study has been conducted on the most abundant Jurassic Nanling Mountains (NLM) granites, their rock affinities relative to the Triassic Darongshan (DRS) and Cretaceous Fuzhou–Zhangzhou Complex (FZC) granites which are typical S- and I-type, respectively, and the issue of their petrogenetic evolution is still the subject of much debate. In this study, we discuss the petrogenesis of NLM granites using apatite geochemistry combined with whole-rock geochemical and Sr–Nd isotope compositions. Sixteen apatite samples from six granite batholiths, one gabbro, and three syenite bodies in the NLM area were analyzed for their major and trace element abundances and compared with those collected from DRS (n = 7) and FZC (n = 6) granites. The apatite geochemistry reveals that Na, Si, S, Mn, Sr, U, Th concentrations and REE distribution patterns for apatites from DRS and FZC granites basically are similar to the S and I granite types of the Lachlan Fold Belt (Australia), whereas those from NLM granites have intermediate properties and cannot be correlated directly with these granite types. According to some indications set by the apatite geochemistry (e.g., lower U and higher Eu abundances), NLM apatites appear to have formed under oxidizing conditions. In addition, we further found that their REE distribution patterns are closely related to aluminum saturation index (ASI) and Nd isotope composition, rather than SiO₂ content or degree of differentiation, of the host rock. The majority of apatites from NLM granites (ASI = 0.97–1.08 and εNd(T) = −8.8 to −11.6) display slightly right-inclined apatite REE patterns distinguishable from the typical S- and I-type. However, those from few granites with ASI > 1.1 and εNd(T) < −11.6 have REE distribution patterns (near-flat) similar to DRS apatites whereas those from granites with ASI < 1.0 and εNd(T) > −6.6 and gabbro and syenite are similar to FZC apatites (strongly right-inclined). In light of Sr and Nd isotope compositions, magmas of NLM intrusives, except gabbro and syenite, and few granites with εNd(T) > −8, generally do not involve a mantle component. Instead, they fit with a melt derived largely from in situ melting or anatexis of the pre-Mesozoic (mainly Caledonian) granitic crust with subordinate pre-Yanshanian (mainly Indosinian) granitic crust. We suggest that an application, using combined whole-rock ASI and εNd(T) values, is as useful as the apatite geochemistry for recognizing possible sources for the NLM granites.     

Mildly peraluminous high-silica granites in a continental rift: the Drammen and Finnemarka batholiths,Oslo Rift,Norway

The peraluminous Drammen batholith (650 km²) is the largest granite complex within the mainly alkaline province of the Permo-Carboniferous Oslo Rift, and peraluminous to metaluminous granites are also present in the southern part of the otherwise alkaline Finnemarka complex (125 km²). The emplacement of the Drammen granite, and probably most of the other biotite granite complexes, predate the alkaline syenites and granites. The eight separate petrographic types of the Drammen batholith range in SiO₂ from 70 to 79 wt.% and have experienced variable amounts of fractionation of feldspars, biotite, zircon, apatite, titanite and Fe–Ti-oxides. The initial Sr, Nd and Pb isotopic ratios and a decoupling between the variations in the SiO₂ content and the aluminum saturation index [ASI=Al₂O₃/(CaO+Na₂O +K₂O)] show that the various intrusive phases are not strictly comagmatic. The _Nd values of the southern part of Finnemarka (+3.5 to +4) and the northern part of the Drammen granite (+1 to +1.5) are high and indicate insignificant (for Finnemarka) to minor Precambrian crustal or enriched mantle contributions. The very low _Sr values of all of these samples (–1 to –12, outside the main Oslo Rift magmatic array), point to a time integrated Rb-depleted crustal contaminant or an EM1 mantle component. The earliest extruded alkali basalts along the southwestern margin of the Oslo Rift are the only other samples within this low _Sr area, but their isotopic signature may also be linked to a mantle enrichment event (involving an EM1 component), e.g. associated with the Fen carbonatite magmatism 540 Ma ago. For a given ²⁰⁶Pb/²⁰⁴Pb, the ²⁰⁸Pb/²⁰⁴Pb ratios of the Drammen and Finnemarka batholiths are distinctly lower than those of the Skien alkaline volcanics and all other magmatic Oslo Rift rocks. This may indicate that the lithosphere of the central part of the rift had a time integrated Th-depletion. The samples from the southern part of the Drammen batholith, characterized by the presence of abundant miarolitic cavities, have _Nd near 0 (–0.7 to +0.4) but strongly elevated _Sr of +35 to +67. The combined Pb isotopic ratios of all the samples analyzed indicate that the Precambrian crustal anatectic contribution is in the form of time integrated Th-and U-depleted lower crust, and the high +_Sr of the sourthern part of the Drammen granite results from shallow level wallrock assimilation or magma-fluid interactions. The remarkably low contribution of old crustal components to the Finnemarka and the northernmost Drammen batholiths may result from extensive late Precambrian intracustal differentiation in southwestern Scandinavia, leading to widespread upper crustal granites ( 900 Ma) and a correspondingly dense and refractory lower crust, in particular in a zone intersecting the central part of the rift. Liquidus phase relations and mass-balance constrainst permit derivation of the granites from mildly alkaline to tholeiitic melts by extensive crystal fractionation of clinopyroxene-and amphibole-rich assemblages. It is equally possible to form the granitic magmas by partial melting of Permian gabbros of similar composition. Either scenario is consistent with the isotopic constrainst and with the presence of dense cumulates and/or residues in the lower crust. The lack of igneous rocks of intermediate composition associated with the Drammen and Finnemarka batholiths point to an efficient upper crustal density filtering. Considerable amounts of heat would be accumulated in this region if differentiated, intermediate melts could not escape to shallower levels. Successive magma injections would therefore easily result in partial melting of already solidified mafic to intermediate melts and cumulates, and it is suggested that the peraluminous granites formed mainly by water-undersaturated anatexis of mafic material.     

Biostratigraphy versus isotope geochronology: Testing the Urals island arc model

Formation of the Urals volcanic-hosted massive sulphide(VHMS) deposits is considered to be related with the intra-oceanic stage of island arc(s) development in the Upper Ordoviciane Middle Devonian based on the biostratigraphic record of ore-hosting sedimentary rocks. However, the direct Re-Os dating of four known VHMS systems in the Urals gives significantly younger Re-Os isochron ages ranging from355 ± 15 Ma up to 366 ± 2 Ma. To address this discrepancy, we performed SHRIMP U-Pb dating on zircons extracted from rhyodacites(Eifelian biostratigraphic age of 393 -388 Ma) from the footwall of the Alexandrinka VHMS deposit which has a Re-Os isochron age of sulphides of 355 ± 15 Ma.New ²⁰⁶ Pb/²³⁸ U mean age of 374 ± 3 Ma(MSWD ? 1.4 and probability ? 0.11) is considered to be the crystallisation age of the host volcanic rock. This age is ca. 15 Ma younger than the Eifelian(393 -388 Ma)biostratigraphic age and overlaps the Frasniane Famennian boundary(372 ± 2 Ma), characterised by the final stages of Magnitogorsk Arc e East European continent collision. Such an inconsistency with geochronological age may be due to a reburial of conodonts during resedimentation as a result of erosion of older rocks in younger sedimentary sequences.     

华北克拉通南缘A型花岗岩的年代学和Nd-Hf同位素组成:对古元古代晚期伸展事件的制约

河南上店和登封古元古代晚期A型花岗岩的锆石LA-ICP-MS U-Pb年代学、岩石地球化学和Nd-Hf同位素研究为讨论华北克拉通南缘中部古元古代晚期构造演化提供了依据。结果表明,上店花岗斑岩和登封正长花岗岩中锆石发育振荡生长环带,结合高的Th/U比值(0.36~1.64),表明其为岩浆成因,岩浆锆石的207Pb/206Pb加权平均年龄分别为1801Ma、1801Ma和1795Ma,即它们形成于古元古代晚期;上店花岗斑岩具有高SiO_2(70.30%~71.83%)、富碱(K2O+Na2O=8.76%~11.01%)、贫Ca O(0.18%~0.36%)、P2O5(0.12%~0.15%)和MgO(0.02%~0.20%)的特征,富集LILEs(Cs、Rb、Ba和K)、贫HFSEs(Nb、Ta、Zr和Hf)和强烈亏损Sr、P、Ti元素,具有负的Eu异常(δEu=0.44~0.59),结合高的FeOT/(FeOT+MgO)比值(0.94~1.00)和10000×Ga/Al比值(2.70~3.74),暗示其为A型花岗岩,具造山后A2型花岗岩特征;上店花岗斑岩的全岩εNd(t)值变化于-8.94~-6.87之间,tDM2=3243~3049Ma,锆石εHf(t)值介于-14.1~-6.5之间,tDM2=3030~2655Ma;登封正长花岗岩的锆石εHf(t)值介于-11.3~-8.4之间,tDM2=2887~2744Ma。上述结果暗示,上店和登封A型花岗岩均来源于幔源岩浆底侵作用下的中-新太古代基底物质的部分熔融,形成于华北克拉通东部和西部陆块碰撞造山后的伸展环境。     

Petrogenesis of the Nanling Mountains granites from South China: Constraints from systematic apatite geochemistry and whole-rock geochemical and Sr–Nd isotope compositions

The widespread Mesozoic granitoids in South China (135,300 km²) were emplaced in three main periods: Triassic (16% of the total surface area of Mesozoic granitoids), Jurassic (47%), and Cretaceous (37%). Though much study has been conducted on the most abundant Jurassic Nanling Mountains (NLM) granites, their rock affinities relative to the Triassic Darongshan (DRS) and Cretaceous Fuzhou–Zhangzhou Complex (FZC) granites which are typical S- and I-type, respectively, and the issue of their petrogenetic evolution is still the subject of much debate. In this study, we discuss the petrogenesis of NLM granites using apatite geochemistry combined with whole-rock geochemical and Sr–Nd isotope compositions. Sixteen apatite samples from six granite batholiths, one gabbro, and three syenite bodies in the NLM area were analyzed for their major and trace element abundances and compared with those collected from DRS (n = 7) and FZC (n = 6) granites. The apatite geochemistry reveals that Na, Si, S, Mn, Sr, U, Th concentrations and REE distribution patterns for apatites from DRS and FZC granites basically are similar to the S and I granite types of the Lachlan Fold Belt (Australia), whereas those from NLM granites have intermediate properties and cannot be correlated directly with these granite types. According to some indications set by the apatite geochemistry (e.g., lower U and higher Eu abundances), NLM apatites appear to have formed under oxidizing conditions. In addition, we further found that their REE distribution patterns are closely related to aluminum saturation index (ASI) and Nd isotope composition, rather than SiO₂ content or degree of differentiation, of the host rock. The majority of apatites from NLM granites (ASI = 0.97–1.08 and εNd(T) = −8.8 to −11.6) display slightly right-inclined apatite REE patterns distinguishable from the typical S- and I-type. However, those from few granites with ASI > 1.1 and εNd(T) < −11.6 have REE distribution patterns (near-flat) similar to DRS apatites whereas those from granites with ASI < 1.0 and εNd(T) > −6.6 and gabbro and syenite are similar to FZC apatites (strongly right-inclined). In light of Sr and Nd isotope compositions, magmas of NLM intrusives, except gabbro and syenite, and few granites with εNd(T) > −8, generally do not involve a mantle component. Instead, they fit with a melt derived largely from in situ melting or anatexis of the pre-Mesozoic (mainly Caledonian) granitic crust with subordinate pre-Yanshanian (mainly Indosinian) granitic crust. We suggest that an application, using combined whole-rock ASI and εNd(T) values, is as useful as the apatite geochemistry for recognizing possible sources for the NLM granites.     

东天山黄山-镜儿泉过铝花岗岩矿物学、地球化学及年代学研究

对东天山黄山-镜儿泉一带黄山南、镜儿泉、图拉尔根沟三个过铝花岗岩作了岩相学、矿物学、地球化学、sr-Nd同位素和锆石U-Pb年代学研究.锆石U-Pb LA-ICP-MS原位定年测得黄山南岩体结晶年龄为259.9±1.4Ma(MSWD=0.86),图拉尔根沟岩体结晶年龄为275.4±8.3Ma(MSWD=29),均侵位于二叠纪碰撞后伸展环境.三个过铝花岗岩均具有低锶同位素初始比值(Isr=0.6969～0.70396)、高εNd(t)值( 5.5～ 7.2)以及年轻的亏损地幔单阶段模式年龄(tDM=0.48～0.56Ga),表明其岩浆源区均为来源于亏损地幔的新生地壳岩石.这种新生地壳岩石可能为偏酸性的火山岩.三个岩体的矿物学和地球化学可分为两类:一类以黄山南白云母花岗岩为代表,为强过铝花岗岩(A/CNK>1.1),强烈亏损Ba、sr和Ti而富集Cs、Rb和K,具有高的Rb/sr(2.03～14.5)和Al2O3/TiO2(110～1592),低的Nb/Ta(3.24～6.76)比值,其稀土元素配分曲线呈"V"字形,显示强烈铕亏损(Eu/Eu*=0.04～0.55),表明这类岩体的直接源岩以泥质岩为主.另一类以图拉尔根沟二云母花岗岩为代表,为弱过铝(1   

福建龙岩大洋-莒舟花岗岩地球化学、年代学、铪同位素特征及其地质意义

为了揭示闽西南龙岩地区大洋、莒舟花岗岩体的成因、侵位时代及其与成矿的关系,在岩石学、地球化学研究基础上,利用LA-MC-ICPMS锆石U-Pb、Lu-Hf同位素测试方法对上述岩体进行年龄测定及铪同位素示踪。岩石学特征表明大洋、莒舟岩体具有多期次侵入特征,岩性主要为花岗岩、似斑状花岗岩以及花岗闪长岩。大洋岩体花岗闪长岩的年龄为(136.2±0.9)Ma,细粒花岗岩的年龄为(125.0±1.7)Ma,似斑状花岗岩的年龄为(132.0±0.2)Ma,莒舟似斑状花岗岩的年龄为(132.4±0.8)Ma。岩石地球化学成分上具有富硅、富铝、低钛、高钾钙碱性特征,富集大离子亲石元素(K、Rb、Cs、Pb等),亏损高场强元素(Nb、Ta、Zr、Ce、Ti等),微量元素表现出后造山伸展背景的特征。稀土含量较低,总稀土含量分别为92.76×10–6~176.26×10–6和116.63×10–6~213.95×10–6,具有显著的负铕异常(δEu=0.01~0.54)和稀土分布模式差异性特征。总体上具有较高的Na2O+K2O值、Ga/Al值及Rb含量,低Zr含量,具有高分异Ⅰ型花岗岩成因特征。两个代表性样品锆石εHf(t)值分别为–16.47~–5.95和–11.05~–3.35,对应的二阶段模式年龄分别为1567~2221 Ma和1400~1889 Ma,来源于古元古—中元古代地壳物质重熔。在以上研究基础上,讨论了两个岩体的成因及其所代表的构造环境,进而探讨了大洋、莒舟花岗岩与成矿的关系。     

东秦岭花山复式岩基中蒿坪与金山庙花岗岩体岩石地球化学、锆石U-Pb年代学和Lu-Hf同位素组成

蒿坪与金山庙花岗岩体位于华北陆块南缘,是熊耳山地区花山复式岩基的重要组成部分。锆石LA-ICP-MS U-Pb定年显示,蒿坪岩体两个样品年龄为128.7±1.0Ma 和129.3±2.4Ma,金山庙岩体一个样品年龄为127.6±1.6Ma,均为早白垩世岩浆作用的产物。蒿坪岩体以发育碱性长石大斑晶为主要特征,主要组成矿物为碱性长石、斜长石、石英、黑云母和少量角闪石等,而金山庙岩体矿物组合则为碱性长石、斜长石、石英和黑云母。化学组成上二岩体均具高硅准铝、富碱高钾及富铁贫镁的特征,轻重稀土元素分馏显著,Eu异常较弱或无明显Eu异常,Eu/Eu^*为0.69~1.26,富集Cs、Rb、Ba、Sr等大离子亲石元素,亏损Nb、Ta、Ti、Y等高场强元素,在成因类型上可归为I型花岗岩,其中金山庙岩体经历了更高程度的分离结晶作用(D.I.=96.6~97.3),应属高分异I型花岗岩。锆石Lu-Hf同位素分析结果显示,蒿坪岩体ε_Hf(t)为-10.2~-13.3,t_DM2为1.8 Ga~2.0 Ga,金山庙岩体ε_Hf(t) 为-13.3~-17.5,t_DM2为2.0~2.2Ga,表明二者的源区很可能是遭受了幔源或新生地壳改造的太华群古老基底物质。根据区域地质和全岩地球化学组成及产出动力地质背景的全面分析,表明蒿坪与金山庙岩体应形成于扬子陆块与华北陆块碰撞造山后的陆内伸展引张环境,是古特提斯构造域向古太平洋构造域转换体制下岩浆作用的产物。在成岩过程中,蒿坪和金山庙岩浆体系释放出大量富挥发组分(如F, Cl)的热液流体(特别是高分异的金山庙岩体),萃取富集了围岩中的成矿物质或是叠加改造了先期(印支期或燕山早期)形成的金矿床,使之运移至构造交汇部位规模性成矿。     

Berdyaush pluton of rapakivi granites,South Urals: New data on the geological structure and geodynamic evolution

The new version of the geological structure of the Berdyaush pluton (a single intrusion of rapakivi granites in the Urals) presented in this paper is significantly distinct from the previous structural schemes. Rapakivi granites compose no more than 10–20% of the area of the pluton and they are widespread only in its northeastern and southwestern flanks. The contacts between gabbro (I phase), hybrid syenodiorites (II phase), and rapakivi granites (III phase) are transitional, metasomatic. The hybrid syenodiorites and rapakivi granites are formed after gabbroic rocks as a result of their intense thermal and metasomatic transformation by the deep fluids. The driving force of this process could be the unilateral compression of the Berdyaush pluton resulting from formation of the eastward continental rift in the beginning of the Middle Riphean.