金平棉花地钛磁铁矿大坡矿段成矿条件

基性-超基性岩浆杂岩是区内钛磁铁矿床的母岩体,矿体产于岩体中及边部,凤港组角闪斜长片麻岩和黑云斜长片麻岩是有利围岩,矿床成因属岩浆晚期结晶分异-变质矿床。预测本区有中-大型铁矿规模的找矿前景。     

河南信阳高梁店铁铜矿床娄子湾矿段地质特征与找矿方向

河南信阳高梁店铁铜矿床位于桐柏山东北侧,为一火山-沉积变质改造型含铜磁铁矿矿床。矿体主要呈透镜状产出于矽卡岩化二郎坪岩群大栗树岩组斜长角闪(片)岩中,具明显的层控特征。矿石矿物主要为磁铁矿和黄铜矿,矽卡岩化和硅化为近矿围岩的主要蚀变类型。结合地质、钻探和物探资料,笔者认为,大栗树岩组矽卡岩化的斜长角闪(片)岩为找矿有利层位,娄子湾已知矿体南东侧、何家湾矿化露头地段有较好的找矿前景,可在该地区开展进一步找矿工作。     

柬埔寨王国贡布省速富县本库比磁铁矿床地质地球物理特征及找矿标志

柬埔寨王国贡布省速富县拉巴乡本库比磁铁矿床是产于大面积第四系覆盖区下由磁铁角闪辉石岩、辉绿岩、斜长岩、斜长花岗岩组成的杂岩体内的矿床,本文通过对矿床地质地球物理特征的论述,揭示矿体产出的地质特征及赋存规律,总结提出了区域上的找矿标志：（1）地势较高地段分布的崩塌积成因的褐铁矿碎块是直接的找矿标志;（2）磁法勘探所圈定的磁异常是重要的找矿标志.（3）与矿区同期次出露的磁铁角闪辉石岩、斜长岩、辉绿岩体及斜长花岗岩组成的杂岩体或单独某一岩类是重要的找矿标志.     

西昆仑赞坎铁矿地质特征与富矿成因探讨

<正>赞坎铁矿位于西昆仑造山带塔什库尔干地块西段,是近年新发现的一个大型沉积变质型磁铁矿床(陈俊魁等,2011;冯昌荣,2012)。铁矿体顶底板围岩分别为古元古代布伦阔勒群斜长角闪片岩和黑云母石英片岩;矿区南部出露早古生代花岗岩及霏细斑岩岩体;矿石类型以条带状及浸染状磁铁矿石为主,兼具少     

宁芜南段和睦山铁矿床矿物学特征及其成因意义

位于宁芜矿集区南部钟姑矿田内的和睦山铁矿床是长江中下游成矿带内的一个典型的中型玢岩铁矿床,其主矿体呈似层状或透镜状产于闪长(玢)岩体与中-上三叠统地层接触带及其附近的灰岩中。近矿围岩蚀变矿化强烈,并具有显著的分带特征。岩(矿)相学研究表明,该矿床的形成经历了成矿前期(钠长石阶段)、主成矿期(阳起石-磷灰石-Ⅰ型磁铁矿阶段、浅闪石-金云母-Ⅱ型磁铁矿阶段和赤铁矿阶段)和成矿后期(石英-黄铁矿阶段和碳酸盐阶段)。矿物学研究表明,热液浅闪石较早阶段阳起石更富Al和Na、而贫Si;晚阶段Ⅱ型磁铁矿较早阶段Ⅰ型磁铁矿更富Ti和Al、而贫Mg。由岩体到矿体方向,金云母中Mg O含量逐渐富集,而Fe O和Ti O2含量逐渐降低,说明浅闪石-金云母-Ⅱ型磁铁矿阶段的成矿温度高于阳起石-磷灰石-Ⅰ型磁铁矿阶段,且阳起石-磷灰石-Ⅰ型磁铁矿阶段成矿热液在演化过程中,温度是逐渐降低的。综合研究表明,和睦山铁矿床为中-高温气液交代充填成因,Ⅰ型磁铁矿的形成以热液交代作用为主,Ⅱ型磁铁矿的生成则以热液充填作用为主,钠化对铁的活化和迁移起了重要作用。     

云南福贡县大和铁矿地质特征及找矿标志

云南福贡县大和铁多金属矿区,磁铁矿体呈层状、透镜状赋存于古元古界崇山岩群b岩段(Pt_1~b)中,矿体明显受地层层位控制。含矿岩性为一套变质的角闪质岩,分别有角闪黑云变粒岩、角闪黑云片岩、黑云石英片岩等。该铁矿工业类型属需选铁矿的磁性铁矿,成因类型为火山-沉积变质型磁铁矿床。     

塔什库尔干地区赞坎铁矿矿物学特征与成因

赞坎铁矿石西昆仑成矿带近年来新发现的一处超大型铁矿床,矿区内广泛出露古元古代布伦阔勒变质岩层,矿体主要赋存于布伦阔勒岩群角闪斜长片岩和黑云石英片岩内部,部分产于霏细岩与黑云石英片岩接触带内。矿床由Ⅰ~Ⅶ号矿体组成,其中Ⅰ号和Ⅲ号矿体为主要矿体。根据矿石组构、矿物共生关系等特征,成矿过程可划分为早期沉积期、中期变质期及晚期岩浆热液期3个成矿期,其中,岩浆热液期可进一步划分为矽卡岩阶段、热液改造阶段和硫化物阶段。早期沉积期磁铁矿呈微细粒他形晶结构,被变质期石英颗粒包裹,以较低含量的TFeO、MgO、MnO和较高含量的TiO2、Al2O3为特征;中期变质期磁铁矿分布于条带状矿石内,他形晶粒状结构,与早期相比,TFeO、MgO、MnO等含量相对升高而TiO2、Al2O3等含量相对降低;晚期岩浆热液期矽卡岩阶段磁铁矿分布于块状矿石内,自形晶粒状结构,以相对富TFeO、MgO、MnO而贫TiO2、Al2O3为特征;晚期热液改造阶段磁铁矿分布于浸染状矿石中,半自形-自形粒状结构、交代残余结构为主,TFeO、Al2O3、TiO2、MnO等含量变化较大。认为赞坎铁矿是沉积变质型铁矿床,遭受后期岩浆热液作用交代改造。     

新疆阿尔金构造带长青铁矿地质特征

阿尔金构造带是我国西北地区的一个重要成矿带,成矿条件优越,在开展矿产调查中发现了长青铁矿。该铁矿位于阿尔金构造带的中西部,赋存于长沙沟超镁铁质岩中,其分布范围受超镁铁质岩的控制。为扩大找矿成果,继续寻找同类型铁矿,通过对矿区岩石组成、构造变形、矿化蚀变带分布特征、磁铁矿化蚀变带规模、分布及矿体的形态、产状、空间分布规律等矿体特征以及矿石质量特征、围岩特征的研究,总结出了该矿床属于岩浆晚期分异类型并受阿尔金断裂多期改造的特点,归纳了主要找矿标志,为在该区进一步寻找该类型铁矿提供了新的思路。     

陕西左溪磁铁矿床地质特征找矿标志及找矿前景分析

左溪铁矿床位于汉南杂岩带东部,矿体赋存于烧房单元的粗粒角闪辉长岩、似层状苏长岩中,矿体产状总体与区内岩浆分异韵律层方向一致,为典型的岩浆分异型铁矿床。左溪地区找矿潜力大,具有形成中型磁铁矿床的潜力。     

新疆东天山天宇、白石泉杂岩体岩石学、矿物学特征对比研究

天宇和白石泉铜镍矿区含矿镁铁-超镁铁质杂岩体是东疆铜镍成矿带的重要组成部分。天宇矿区杂岩体以角闪辉长岩、角闪单辉橄榄岩、橄榄辉石岩、二辉辉石岩为主;白石泉矿区杂岩体则以辉石闪长岩、角闪辉长岩、橄榄辉石岩、辉石辉长岩、辉石橄榄岩、橄长岩为主;天宇矿区含矿超基性岩中SiO2,Al2O3,CaO,K2O,Na2O的质量分数比白石泉岩体低,Fe2O3,MgO相对较高;两个杂岩体的主要造岩矿物均以橄榄石、辉石、斜长石为主;铜镍矿石的矿物组成都较简单,金属矿物种类基本一致;两个杂岩体基性-超基性岩的成分接近原始岩浆,均来自于地幔,均属含铜镍中等的镁铁质岩石。     

新疆西天山查岗诺尔铁矿床矿物学特征及其地质意义

查岗诺尔大型磁铁矿床位于西天山阿吾拉勒东段,矿体赋存于下石炭统大哈拉军山组安山质火山碎屑岩或凝灰岩中,主要呈层状、似层状、透镜状,受NW、NWW、NE断裂及环形断裂构造控制。矿区发育石榴石、透辉石、方柱石、阳起石、钾长石、绿帘石、绿泥石、方解石等蚀变矿物,矿石矿物主要为磁铁矿和赤铁矿,伴生的金属矿物以黄铁矿和黄铜矿为主。电子探针分析结果表明,石榴石和辉石分别为钙铁榴石-钙铝榴石系列和透辉石-钙铁辉石系列,其化学组成可表示为Adr37.97~97.89Grs0.19~57.21(Alm+Sps)0.84~4.38和Di28.68~87.46Hd10.46~70.13Jo0.24~5.53,与典型的矽卡岩型铁矿中石榴石和辉石的端员组分相似。在磁铁矿和赤铁矿的Ca+Al+Mn-Ti+V图解中,多数样品落入矽卡岩型铁矿的区域;在磁铁矿的TiO2-Al2O3-MgO图解中,多数样品落入或趋近于沉积变质-接触交代磁铁矿区域。结合矿床地质特征和矿物学研究,认为该矿床的形成与矽卡岩化紧密相关,矽卡岩化对铁成矿有重要的贡献。     

辽宁弓长岭铁矿二矿区条带状铁建造地球化学特征及成因探讨

本文以弓长岭铁矿二矿区磁铁石英岩、磁铁富矿和蚀变围岩样品为研究对象,进行了主量元素、微量元素、稀土元素和Fe同位素的测试。结果表明:磁铁石英岩主要由TFe2O3和SiO2组成,Al2O3和TiO2质量分数较低,微量元素质量分数和稀土元素质量分数均较低;经澳大利亚后太古界平均页岩(PAAS)标准化的稀土配分模式呈现出轻稀土亏损和重稀土富集,La、Eu和Y的正异常明显,Ce的异常不明显,Y/Ho值较高;富集Fe的重同位素,且与海底喷发热液经过氧化沉淀后的Fe同位素特征一致。磁铁富矿与磁铁石英岩的地球化学特征有很好的一致性和继承性,但磁铁富矿的REE和Eu质量分数较高,且较磁铁石英岩富集Fe的轻同位素,范围更大,与蚀变岩的Fe同位素组成相近。弓长岭铁矿的磁铁石英岩是陆源物质加入很少的古海洋化学沉积岩,为喷出的海底热液与海水的混合条件下氧化沉淀形成的。磁铁富矿推测为富Fe的轻同位素热液对磁铁石英岩进行改造,经过去硅富铁作用形成的。     

Fe2+在零价铁还原去除NO3-中的作用效应

零价铁（Fe0） 被广泛用于地下水中硝酸盐原位与异位修复,但二价铁（Fe2+） 的存在对具有氧化膜的Fe0还原硝酸盐的作用效应仍有待研究。以100 目的未经酸化的颗粒状零价铁作为还原剂,采用室内批试验方法,研究了Fe2+在零价铁还原去除NO3-系统中的作用效应。实验结果表明,Fe2+可显著提高Fe0对于NO3-的去除速率与去除效率,且Fe2+浓度越高,去除速率与效率越高;由于未经酸化的Fe0具有氧化膜,反应初期的NO3-还原速率较慢。Fe2+将零价铁表面的Fe2O3氧化膜转化为Fe3O4,加速电子由Fe0向NO3-的转移,促进NO3-还原。此外,在反应系统中加入Fe3O4,可进一步提高Fe0对于硝酸盐的去除能力,若Fe2+不存在,仅添加Fe3O4,NO3-的去除效率没有提高。     

Composition and Assemblage Characteristics of Magnetic Minerals in Layer S_(5-1) of Xifeng and Duanjiapo Sections

Magneticmineralsintheloess paleosolseriesaccountforabout 1 % -2 %ofthetotal (LiuTungshengandZhangZhonghu ,1 962 ) .Duetotheiraerolianorigin ,themagneticmineralsarecomplicatedincomposition ,largeingrainsizerange ,andsignificantlydifferentincrystallinity .Asaresult,researchonthesemagneticmineralswouldbesetwithalotofdifficulties.Previousre searchersemployedopticalmicroscopic ,X raydiffractionandM ssbauerspectrometrictechniquestostudythemagneticmineralsintheloess paleosolseries,andchieflyontheb…     

小秦岭金硐岔金矿床九号石英脉中自然铁的发现及研究

自然铁产于含金石英脉中,其外壳为磁铁矿。多数自然铁外壳被闪锌矿包裹,个别闪锌矿又被包裹在自然铁外壳中.按表面形态自然铁可分为两种类型:园滑状;不规则的港湾状.锯齿状。据穆斯堡尔谱峰面积法,外壳磁铁矿Fe~(+++)/Fe~(++)比值为1.4～1.7.电镜成分面扫描表明,随外壳厚度增加,氧浓度增高而硫浓度降低。不规则状自然铁外壳磁铁矿可能由黄铁矿氧化而来。     

Redox-controlled iron isotope fractionation during magmatic differentiation: an example from the Red Hill intrusion, S. Tasmania

This study presents accurate and precise iron isotopic data for 16 co-magmatic rocks and 6 pyroxene–magnetite pairs from the classic, tholeiitic Red Hill sill in southern Tasmania. The intrusion exhibits a vertical continuum of compositions created by in situ fractional crystallisation of a single injection of magma in a closed igneous system and, as such, constitutes a natural laboratory amenable to determining the causes of Fe isotope fractionation in magmatic rocks. Early fractionation of pyroxenes and plagioclase, under conditions closed to oxygen exchange, gives rise to an iron enrichment trend and an increase in $ f_{{{\text{O}}_{2} }} $ of the melt relative to the Fayalite–Magnetite–Quartz (FMQ) buffer. Enrichment in Fe³⁺/ΣFe_melt is mirrored by δ⁵⁷Fe, where ^VIFe²⁺-bearing pyroxenes partition ⁵⁷Fe-depleted iron, defining an equilibrium pyroxene-melt fractionation factor of $ \Updelta^{57} {\text{Fe}}_{{{\text{px}} - {\text{melt}}}} \le - 0.25\,\permille \times 10^{6} /T^{2} $ . Upon magnetite saturation, the $ f_{{{\text{O}}_{2} }} $ and δ⁵⁷Fe of the melt fall, commensurate with the sequestration of the oxidised, ⁵⁷Fe-enriched iron into magnetite, quantified as $ \Updelta^{57} {\text{Fe}}_{{{\text{mtn}} - {\text{melt}}}} = + 0.20\,\permille \times 10^{6} /T^{2} $ . Pyroxene–magnetite pairs reveal an equilibrium fractionation factor of $ \Updelta^{57} {\text{Fe}}_{{{\text{mtn}} - {\text{px}}}} \approx + 0.30\,\permille $ at 900–1,000?°C. Iron isotopes in differentiated magmas suggest that they may act as an indicator of their oxidation state and tectonic setting.     

Mineral Compositions and Equilibria in the Metamorphosed Iron Formation of the Gagnon Region, Quebec, Canada

Forty-seven specimens of the Wabush Iron Formation were collectedfrom ten outcrop areas. Twenty-five specimens contain the assemblage(1), quartz+clinopyroxene+calcite with or without orthopyroxene,grunerite, magnetite, ankerite, and siderite. Five specimenscontain assemblage (2), quartz+clinopyroxene+actinolite+calcite+magnetite+hematite,and two contain assemblage (3), quartz+orthopyroxene+actinolite+magnetite+hematite.In three specimens of assemblage (1), graphite occurs in theabsence of magnetite; pyrrhotite and pyrite occur separatelyor together in specimens with assemblage (1). Thirty-nine clinopyroxenes, 38 orthopyroxenes, 18 grunerites,7 actinolites, 16 calcites, 1 ankerite, and 1 siderite wereanalyzed for iron, manganese, and calcium by X-ray emissionspectrography. Magnesium contents were estimated by assumingstoichiometric proportions. Minerals occurring with hematite show low Fe/(Fe+Mg) ratios,and those in the other assemblages show higher values with awide range of variation. In orthopyroxene, Fe/(Fe+ Mg) rangesfrom 0·17 (with hematite) to 0·77. Regularity in the distributions of Fe, Mn, and Ca between pairsof coexisting minerals shows that equilibrium was attained inmost of the rocks studied. This regularity is also accomplishedin the distribution of Mn between calcite and coexisting silicatesas well as between the silicates themselves. Small differencesin the distributions of Ca and Fe depend on both outcrop areaand mineral assemblage. Phase rule considerations suggest that the specimens with dolomite-ankeriteor magnesitesiderite do not represent equilibrium assemblages.Variations in orthopyroxene compositions in assemblages withpyrite or pyrrhotite, or both, and magnetite indicate non-equilibrationof sulfides with silicates. The presence of the oxygen buffer,magnetite+hematite, attests to the immobility of oxygen duringmetamorphism. Within each outcrop area, over which the temperature and pressureare assumed to have been uniform, variations in the compositionsof the silicates in the sub-assemblages quartz+ orthopyroxene+gruneriteand quartz+orthopyroxene+clinopyroxene+calcite indicate gradientsof µ_H2O µ_CO2 and respectively. As characterizedby the composition of orthopyroxene, both gradients are relativelylow along strike, and high across strike. The direction of gradientsacross strike is almost without reversals, which is consistentwith intergranular diffusion of H₂O and CO₂. Phase rule restrictionsfor a majority of assemblages are not in accord with the simultaneousimposition of µ_H2O and µ_CO2 gradients on the rocks,nor the formation of an H₂O-CO₂ fluid phase during metamorphism.     

Iron isotope fractionation during skarn-type alteration: Implications for metal source in the Han-Xing iron skarn deposit

The Han-Xing iron mineralization in the central North China Craton is a typical Fe skarn deposit associated with altered diorites. Here we report the Fe isotopic compositions of whole rocks and mineral separates from this deposit with a view to evaluate the Fe isotope fractionation during the formation of Fe skarn deposit, and to constrain the metal source. The Fe isotopes show a large variation both in whole rocks and mineral separates. Altered diorites show a wide range in δ⁵⁶Fe values (− 0.07‰ to + 0.21‰ relative to the Fe isotope standard IRMM-014) which positively correlate with their TFe₂O₃/TiO₂ ratios (Fe₂O₃ and FeO calculated as TFe₂O₃). The positive correlation indicates that heavy Fe isotopes were preferentially leached from diorites during the skarn-type alteration. Among the metallic minerals, pyrite and pyrrhotite are isotopically heavier (+ 0.12‰ to + 0.48‰) than the magnetite (+ 0.07‰ to + 0.21‰). Fe isotope fractionation between mineral pairs demonstrates that magnetite did not attain Fe isotopic equilibrium with pyrite and pyrrhotite, whereas pyrite and pyrrhotite might have attained isotopic equilibrium. Petrological observations and major element data also suggest that iron was leached from the diorites during the skarn-type alteration. If the leached iron provides the main Fe budget of the Han-Xing Fe skarn deposit, magnetite in ores would be isotopically heavier than the unaltered diorite. However, our results are in contrast with the magnetite being isotopically lighter than the unaltered diorite. This suggests that the major Fe source of the Han-Xing Fe skarn deposit is not from the leaching of diorites, and might be from magmatic fluid which is isotopically lighter than the silicate melt. Our data demonstrate that Fe isotopes can be used as important tracers in deciphering the metal source of Fe skarn deposits.     

Dependence of microbial magnetite formation on humic substance and ferrihydrite concentrations

Iron mineral (trans)formation during microbial Fe(III) reduction is of environmental relevance as it can influence the fate of pollutants such as toxic metal ions or hydrocarbons. Magnetite is an important biomineralization product of microbial iron reduction and influences soil magnetic properties that are used for paleoclimate reconstruction and were suggested to assist in the localization of organic and inorganic pollutants. However, it is not well understood how different concentrations of Fe(III) minerals and humic substances (HS) affect magnetite formation during microbial Fe(III) reduction. We therefore used wet-chemical extractions, magnetic susceptibility measurements and X-ray diffraction analyses to determine systematically how (i) different initial ferrihydrite (FH) concentrations and (ii) different concentrations of HS (i.e. the presence of either only adsorbed HS or adsorbed and dissolved HS) affect magnetite formation during FH reduction by Shewanella oneidensis MR-1. In our experiments magnetite formation did not occur at FH concentrations lower than 5 mM, even though rapid iron reduction took place. At higher FH concentrations a minimum fraction of Fe(II) of 25-30% of the total iron present was necessary to initiate magnetite formation. The Fe(II) fraction at which magnetite formation started decreased with increasing FH concentration, which might be due to aggregation of the FH particles reducing the FH surface area at higher FH concentrations. HS concentrations of 215-393 mg HS/g FH slowed down (at partial FH surface coverage with sorbed HS) or even completely inhibited (at complete FH surface coverage with sorbed HS) magnetite formation due to blocking of surface sites by adsorbed HS. These results indicate the requirement of Fe(II) adsorption to, and subsequent interaction with, the FH surface for the transformation of FH into magnetite. Additionally, we found that the microbially formed magnetite was further reduced by strain MR-1 leading to the formation of either dissolved Fe(II), i.e. Fe²⁺, in HEPES buffered medium or Fe(II) carbonate (siderite) in bicarbonate buffered medium. Besides the different identity of the Fe(II) compound formed at the end of Fe(III) reduction, there was no difference in the maximum rate and extent of microbial iron reduction and magnetite formation during FH reduction in the two buffer systems used. Our findings indicate that microbial magnetite formation during iron reduction depends on the geochemical conditions and can be of minor importance at low FH concentrations or be inhibited by adsorption of HS to the FH surface. Such scenarios could occur in soils with low iron mineral or high organic matter content.