首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
Hallimond tube flotation experiments have been carried out on the two calcium minerals scheelite and calcite using dodecylammonium chloride as collector. The main variables studied were the calcium ion concentration and the pH.In the case of scheelite, addition of calcium chloride markedly lowered the flotation recovery. Recovery was also lowered when the pH was reduced below about 10. Since it is known that the zeta potential of scheelite is almost independent of pH this confirms that co-adsorption of un-ionized amine is necessary for good flotation. Other un-ionized long-chain molecules can replace the amine; thus it was shown that excellent flotation can be obtained event at about pH 7 by adding dodecanol together with dodecylammonium chloride. With the completely ionic trimethyldodecylammonium chloride recoveries were poor and were independent of pH.In the case of calcite, calcium chloride had no immediate effect on flotation recovery, but at low collector concentrations marked depression occurred after many hours standing in the presence of calcium ions. The effect of pH on flotation of calcite was anomalous and there appear to be two pH regions in which recoveries are high.The results are discussed and attention is drawn to the need for more thorough studies of the calcium carbonate/water interface.  相似文献   

2.
分形奇异(特征)值分解方法与地球物理和地球化学异常重建   总被引:15,自引:4,他引:11  
李庆谋  成秋明 《地球科学》2004,29(1):109-118
地球物理和地球化学异常是找矿的重要依据.地球物理和地球化学异常取决于地层、构造在成矿时间上的多样性与空间上排列、叠置的复杂性.地层、构造因素是构造、岩浆、沉积与成矿地球化学等多种动力学过程的综合反映.这些岩石和构造的因素以及动力过程相互渗透和影响决定了最终地质、地球物理与地球化学场.本文提出的在GIS环境下实现的分形奇异值分解(MSVD) 异常重建方法, 不仅可以提取地球物理和地球化学等异常, 而且能够进一步刻画其中的线性和环状构造、细微的局部纹理结构特征.该方法首先对地球物理和地球化学等网格数据进行二维矩阵的奇异值分解, 之后用左特征向量矩阵与右特征向量矩阵的直积构造一个正交完备基.地球物理和地球化学二维数据可以投影到该正交基上, 其投影系数是矩阵的奇异值.在该正交完备空间的某些子空间上对地球物理和地球化学等数据进行滤波.为了选择子空间, 本文定义了上述正交完备基中的能谱密度、能谱半径(或尺度) 与能量测度.在此基础上与空间域及频率域类比, 探讨了能量测度与能谱密度呈现分形(fractal和bifractal) 规律.利用分形关系的间断点, 设计分形奇异值重建算子, 实现对地球物理和地球化学异常的分解.以加拿大NovaScotia南部布格重力异常与As地球化学异常为例, 采用MSVD方法分解Au、Wu -Sn -U等已知矿有关的地球化学异常.发现重建异常能很好地用于解释已知矿点的分布规律.重建的地球化学异常显现了地球化学中的线状和环状异常; 重建的布格重力异常有效勾勒出原图中不易发现的纹理结构, 这些纹理结构可以合理地解释已知矿点在侵入岩体内及其周围的分布规律.应用实例表明, 该方法不仅可以从起因复杂的异常中区分出背景、异常场, 还可以识别代表了成矿源岩、流体、运移通道、赋存空间等异常因素引起的纹理、结构与构造特征.同时实现了GIS环境下交互可视化的MSVD处理与解释系统, 增强了地质异常定量分析的实用性与可操作性.   相似文献   

3.
A model has been developed to describe the breakage behavior of particle breakage in a smooth double roll crusher. In addition to this, an empirical relationship has been obtained between Hardgrove Grindability Index (HGI) of material and breakage parameters. The model uses matrix method of breakage process analysis. Experiments were carried out in a laboratory scale smooth double roll crusher using different materials. The model has been verified experimentally and gives product size distribution after breakage which matches with the experimental distribution well within the satisfactory range.  相似文献   

4.
5.
The spontaneous imbibition phenomenon is an important process in hydrocarbon recovery. Laboratory study of imbibition is affected by many parameters including, rock characteristics, boundary conditions, length of the sample, variable interfacial tension, and sample heterogeneity. Investigating spontaneous imbibition enhances our understanding of the imbibition mechanism and, hence, helps improve waterflooding used in the oil industry. A simple apparatus has been developed to resemble naturally fractured reservoirs. Using the developed apparatus, the effects of lithology, permeability, and wettability on spontaneous imbibition have been experimentally investigated. Some encountered unexpected technical problems during the experiments are overcome and reported in this paper. Details of the developed apparatus are shown and spontaneous imbibition results are presented. First, the effect of permeability on the oil recovery rate is presented. In addition, obtained curves of oil recovery by water spontaneous imbibition using different lithology are presented. Finally, results of oil recovery from Berea sandstone core sample before and after wettability alteration are shown.  相似文献   

6.
Long-chain amines, used in potash ore flotation as collectors, are insoluble in NaCl–KCl saturated brine. In commercial applications, these amines are melted at 70–90 °C, dispersed in acidic solution of hydrochloric or acetic acids, and such emulsions are then introduced to the flotation pulp.To model the commercial potash ore flotation process, dodecyl amine, used in this study, was melted at 70 °C, dispersed in hydrochloric acid aqueous solution and was added to a KCl–NaCl saturated brine at room temperature. This results in the precipitation of the amine. The present study summarizes the influence of the conditions on the particle size and morphology of the precipitating amine particles. Methyl isobutyl carbinol (MIBC), common frother in flotation processes, was shown to affect amine dispersion when added into a hot amine emulsion prior to mixing with a saturated brine. This study demonstrates that the precipitating amine particles are selectively abstracted by KCl particles, but not by NaCl particles.  相似文献   

7.
Amine post-combustion carbon capture technology is based on washing the flue gas with a solvent that captures CO2. Thus, a small fraction of this solvent can be released together with the cleaned flue gas. This release may cause environmental concerns, both directly and indirectly through subsequent solvent degradation into other substances in the atmosphere. The paper presents the ammonia emission from CO2 capture pilot plant (1 tonne CO2 per day) using 40 wt% aminoethylethanolamine solvent, along with the efficiency of the water wash unit. In addition, the temperature effect of lean amine entering the absorber on ammonia emission was studied. Furthermore, the concentrations of other compounds such as SO2, SO3, NO2, CS2 and formaldehyde were monitored. The literature review on the NH3 emission from a pilot plant using aminoethylethanolamine solvent has not been published. The results show that the main source of ammonia emission is the absorber and that emission (in the range 27–50 ppm) corresponds to typical NH3 release from CO2 capture pilot plant using an amine solvent. The emission of amines and amine degradation products is a complex phenomenon which is difficult to predict in novel solvents, and for this reason the significance of new solvents testing in a pilot scale has been highlighted.  相似文献   

8.
The study of surface waves (Rayleigh wave) finds their virtuous applications in a numerous geological and geophysical fields including water, oil, gas, and other subsurface geological probing and exploration. The present paper efforts to investigate the influence of initial stress, Earth magnetism, and gravity on propagation of Rayleigh waves. Considered model is consist of a liquid layer lying over a magnetoelastic orthotropic half-space under self-weight and initial stress. Method of separation of variable is used to solve the equation of motion. Solutions of governing equations are obtained in terms of displacement. Frequency relation for Rayleigh wave has been obtained and matched with classical Rayleigh wave equation. In addition to classical case, some existing results have been deduced as particular case of the present study. Obtained results have been shown through numerical illustrations. It is found that the considered parameters (initial stress, Earth magnetism, and gravity) have prominent effect on phase velocity of Rayleigh wave. Graphical representations have been made to exhibit the velocity profile of Rayleigh waves for different cases with the help of MATHEMATICA. The present study may be useful for seismologists and engineers who are concern with applications of wave propagation in magnetoelastic orthotropic medium.  相似文献   

9.
A formulation has been derived for the flow of non-Newtonian (power-law) fluids in deformable, fractured porous media. The formulation is enhanced with a subgrid scale model to accurately represent the flow of the power-law fluids inside the cracks. The resulting equations have been discretised using standard (Lagrangian) finite element shape functions and with non-uniform rational B-splines (NURBS), which have been cast into a standard finite element datastructure using Bézier extraction. The effect of the power-law index on the velocity inside the fracture and on the total fluid flow through the porous medium has been analysed for a typical boundary-value problem. It is shown that large differences between non-Newtonian and linearised Newtonian fluids can occur for the fluid velocity inside the fracture. This can significantly influence the total fluid transport through the domain. A mesh sensitivity study has been carried out as well and shows that markedly smaller element sizes are required in order to obtain accurate results for the local flow inside the fracture, compared with the element sizes necessary for obtaining accurate results inside the porous medium away from the fracture. Moreover, a comparison has been made between the results obtained using standard Lagrange polynomials and those obtained using NURBS. It is shown that while both discretisation methods are able to accurately simulate the deformations and pressures in the porous medium, the higher interelement continuity of NURBS is mandatory for obtaining correct values of the fluid velocities inside the fracture, especially near the tips.  相似文献   

10.
硼硅玻璃是目前压水堆应用最多的可燃毒物材料,产品中硼同位素组成的准确测定对燃耗预估及产品质量判定具有重要意义。文章基于直接熔融热电离质谱法,首先探讨了硅元素对硼酸中硼同位素测量结果的影响,结果表明:Si/B质量比小于9时,硅对NIST 951a硼酸标准物质测量结果无显著干扰,采用直接熔融热电离质谱法测定核电用硼硅玻璃中硼同位素比值具有可行性;随后,详细分析了Na/B摩尔比、甘露醇和石墨加入量3个参数对测试结果的影响,得到的最佳参数为Na/B摩尔比9、加入甘露醇及3μL石墨发射剂;最后,采用优化测试参数,对实际硼硅玻璃样品进行了测试,并以NIST 951a硼酸标准物质为外标对测量结果进行分馏校正,结果发现分馏校正后样品的不确定度来源主要是标准物质。研究成果可满足硼硅玻璃的燃耗预估及产品质量的快速判定需要。  相似文献   

11.
The separation of residual gravity anomaly from regional gravity has considerably been studied for many years in gravity explorations. In addition, it is considered as a critical step in gravity data inversion. Some techniques have been developed for regional–residual anomaly separation both in space and frequency domains. One of these techniques for computing the regional anomaly is nonlinear filtering. In this paper, some techniques such as low-pass filtering, Butterworth, upward continuation, and nonlinear filtering are used to on synthetic gravity data in present of random noise and noise free for the purpose of residual–regional anomaly separation. The obtained results of techniques are compared with each other. The results have shown that separation methods are so efficient where synthetic models are located in shallow depth. Moreover, it is found that in comparison with other separation techniques, nonlinear filtering is more efficient in residual–regional anomaly separation and upward continuation technique is more efficient than Butterworth filter and low-pass filter. In addition, all of the obtained results have shown that Butterworth and low-pass filters are the same.  相似文献   

12.
Cesium values for 21 geostandards obtained by flame emission spectrometry are presented. Analytical sensitivity was separately determined for each sample by the method of standard addition to cancel effects of chemical interferences. Three types of chemical interferences have been found and their magnitude has been measured. Correction factors have been derived to improve the accuracy of analytical values reported in the literature that were obtained by calibration against a single standard.  相似文献   

13.
影响硅灰石产物性质的工艺研究   总被引:9,自引:0,他引:9  
为研究硅灰石酸处理产物的比表面积及产率的影响因素,作者设计了一个三因素,两水平的正交实验,并做了最佳条件实验,即验证实验,结果证实了正交实验结论的正确性,即快速加酸,有机助剂和无机助剂,有利于提高硅灰石酸处理产物的比表面积和产率。  相似文献   

14.
Numerous approaches exist for the prediction of the settlement improvement offered by the vibro-replacement technique in weak or marginal soil deposits. The majority of the settlement prediction methods are based on the unit cell assumption, with a small number based on plane strain or homogenisation techniques. In this paper, a comprehensive review and assessment of the more popular settlement prediction methods is carried out with a view to establishing which method(s) is/are in best agreement with finite element predictions from a series of PLAXIS 2D axisymmetric analyses on an end-bearing column. The Hardening Soil Model in PLAXIS 2D has been used to model the behaviour of both the granular column material and the treated soft clay soil. This study has shown that purely elastic settlement prediction methods overestimate the settlement improvement for large modular ratios, while the methods based on elastic–plastic theory are in better agreement with finite element predictions at higher modular ratios. In addition, a parameter sensitivity study has been carried out to establish the influence of a range of different design parameters on predictions obtained using a selection of elastic–plastic methods.  相似文献   

15.
The rate of consumption of sulphide in the sulphidizing reactions of malachite and chrysocolla has been measured. The oxidation of sulphide ions at the surface of sulphidized chrysocolla was shown to take place. The influence of thiosulphate anions on the xanthate flotation of sulphidized malachite and chrysocolla was investigated and it was shown to depress the flotation of chrysocolla strongly.The result suggest, that the presence of thiosulphate as a product of simultaneous oxidation can be one of the reasons for the more difficult flotation of sulphidized chrysocolla.  相似文献   

16.
Dynamic replacement (DR) is a relatively new ground-modification technique that has been used successfully to stabilize organic soil deposits by replacing the organic soil with sand columns. A full-scale DR field study was conducted in order to assess its effectiveness on Florida organic soils. A computer-based quality control system was developed using data-acquisition-management techniques to evaluate the degree of improvement of the organic soil layer at a given stage of treatment. One of the DR drop locations was instrumented in order to select technical criteria such as the print spacing and the number of blows per print for effective DR implementation, and to facilitate monitoring of the improvement of soil properties. The new quality control system evaluates the effects of treatment by computing the dynamic settlement modulus (DSM) from the impact acceleration data collected during the treatment period. This paper presents the results obtained from the pilot study and their subsequent use in establishing evaluation criteria for the test programme. It is also shown how the DSM-based treatment criteria are in agreement with those obtained from conventional methods. Hence, it is concluded that with the use of the quality control system presented, the implementation of any DR programme can be effectively monitored.  相似文献   

17.
The application of high-pressure roll mills (HPRM) for industrial comminution has been growing, particularly because of its energy efficiency. Many aspects of HPRM comminution have not been fully characterized because the performance of the machine is affected by numerous parameters that still need to be investigated and optimized. The present paper is concerned with the effect of feed moisture on HPRM performance. The comminution of minus 8-mesh dolomite feed at several different moisture levels was conducted with a laboratory HPRM to delineate the effect of feed moisture on product characteristics, specific energy consumption, and such mill operating parameters as applied load, roll gap and roll speed. The results showed definite effects of moisture on these parameters and the product size distribution, most likely because of lubrication of the particles in the compacting bed as they pass through the roll gap.  相似文献   

18.
The formation of highly surface-active ionomolecular complexes has been suggested recently to be a phenomenon that governs the pH-dependence of hematite flotation using oleate. The differential thermogravimetric work reported in the literature on alkylamine-alkylamine hydrochloride mixtures shows complete complexing of them when present in equimolar amounts. The pH dependence of quartz flotation using amine, speculated in the past to be due to various mechanisms, is discussed in the light of these results. The additional correlation obtained for flotation with surfactant complex formation suggests the role of such complexes in froth flotation to be of wide application.  相似文献   

19.
This paper presents the effects of addition of lime and lime along with gypsum on the compressibility behavior of two class F fly ashes. Since the fly ashes develop strength and exhibit lower compression, consolidation testing with conventional duration of load increment may not be appropriate. Hence, an attempt has been made to assess the minimum duration of load increment necessary to study the compressibility characteristics of such materials. Thus compressibility behavior of fly ashes with additives has been studied using conventional consolidation test with different durations of load increments varying from 30 min to 48 h. The results obtained indicated that 30 min of duration of load increment can be used to assess the compressibility behavior of such materials. The effect of lime which reduces the compression is seen to be maximum from the results obtained with the duration of load increment of 30 min but gradually reduces with higher durations of load increment. It has also been observed that the rate of decrease in the compressibility is maximum up to 2.5% lime and gradual thereafter. The compressibility of lime treated fly ashes further reduces when gypsum is incorporated, the optimum gypsum percentage being 2.5. This reduction in the compressibility of fly ashes enhanced by incorporating lime and gypsum makes them versatile in the construction of embankments and for structural fills, particularly reducing the time required in between laying of each lift.  相似文献   

20.
Despite the abundant evidence for the enrichment of phosphorus during the petrogenesis of natural ferro-basalts, the effect of phosphorus on the physical properties of these melts is poorly understood. The effects of phosphorus on the viscosity, density and redox ratio of a ferro-basaltic melt have been determined experimentally. The viscosity measurements were obtained using the concentric cylinder method on a ferro-basaltic melt above its liquidus, at 1 atm, in equilibrium with air and with CO2. The density measurements were performed using the double Pt-bob Archimedean method at superliquidus conditions under 1 atm of air. The redox ratio was obtained by wet chemical analysis of samples collected during physical property measurements. Phosphorus pentoxide reduces ferric iron in ferro-basaltic melt. The reduction due to P2O5 is much larger than that for most other oxide components in basaltic melts. A coefficient for the reduction of ferric iron has been generated for inclusion in calculation schemes. The effect of P2O5 on the viscosity is shown to be complex. The initial reduction of ferric iron with the addition of P2O5 results in a relatively small change in viscosity, while further addition of P2O5 results in a strong increase. The addition of phosphorus to a ferro-basaltic melt also reduces the density. A partial molar volume of 64.5±0.7 cm3/mol for P2O5 in this melt has been obtained at 1300° C, yielding a volume of 12.9 cm3/mol per oxygen, consistent with a tetrahedral coordination for this high field strength cation. The effects of P2O5 on redox state, density and viscosity provide constraints on the structural role of phosphorus in these melts. The results suggest a complex interaction of phosphorus with the aluminosilicate network, and tetrahedral ferric iron. In light of the significant effects of phosphorus on the physical and chemical properties of ferro-basaltic liquids, and the extreme enrichments possible in these liquids in nature, the role of phosphorus in these melts should, in future, be considered more carefully.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号