The El Achour (Algiers,Algeria) landslide delimitation using the H/V ambient vibration method

We present in this work investigations using seismic ambient vibration to delimitate the El Achour landslide (Algiers), upon which independent geotechnical studies were carried out. Acquisition campaign of ambient vibration on the El Achour site on June 2009 and June 2015, over a surface of about 2 ha, consisted of 64 records of ambient noise with a 10 to 20 m grid size. This approach consists of simple, light, and fast H/V acquisitions, in order to determine the extension of the unstable zone, the depth of the sliding surface, and to test the effectiveness of this method. Two peaks were interpreted as one being for the sliding surface and the other for the lithological interface. As results, in the stable area, they are satisfactory. Indeed, the points in this area are not intermediate peaks which could be related to potential sliding surfaces, which led us to think that we could delineate, using this method, the unstable area from the stable area. The HVSR method allows to determine the thickness of the geological formations and to highlight the lateral and vertical facies changes in broad area.     

Assessment of predominant frequencies using ambient vibration in the Kachchh region of western India: implications for earthquake hazards

The Kachchh region is the second most seismically active region in India after the Himalaya. One of the disastrous Indian earthquakes of the millennium was the Bhuj earthquake of January 26, 2001, which caused about 14,000 casualties and huge property damage. The main reason for such devastation is due to lack of earthquake awareness and poor construction practices. Hence, an increase in the knowledge and awareness, based on improved seismic hazard assessment, is required to mitigate damage due to an earthquake. Natural predominant ground frequencies have been investigated in the Kachchh region of western India using ambient vibrations. The horizontal-to-vertical spectral ratio technique has been applied to estimate the predominant frequency at 126 sites. The ambient vibration measurements were conducted for about 1 h at each site in the continuous mode recording at 100 samples/s. We have validated the estimated predominant frequency with earthquake data recorded at six broadband stations in the region. It has been observed that geological time period has a significant effect on predominant frequency of the ground. The estimated predominant frequencies vary from 0.24 to 2.25 Hz for the Quaternary, 0.41–2.34 Hz for the Tertiary, 0.32–4.91 Hz for the Cretaceous, and 0.39–8.0 Hz for the Jurassic/Mesozoic. In the Deccan trap, it varies from 1.30 to 3.80 Hz. We found distinct variation of predominant frequencies of sites associated with hard rock and soft soil. The predominant frequencies were related to the thickness of the sediments, which are deduced by other geophysical and geological methods in the region. Our results suggest that frequencies of the region reveals the site characteristics that can be considered for studying the seismic risks to evolve a plan for disaster risk mitigation for the region.     

Ambient seismic vibration analysis and ground characterization in the vicinity of Algiers seismic zone

The Dar El Beida area, situated in the Mitidja basin, in the north central Tellian Atlas is characterized by its Plio-Quaternary sediments. The site effect analysis in this zone surrounding Algiers city is very important. The soil is constituted from recent soft sediments capable of amplifying seismic motion. Indeed, the analysis thanks to the ratio H/V ambient vibration method confirms these assumptions. An electric resistivity tomography strengthened the results obtained from ambient vibration for site characterization. This demonstrates once again the more or less homogeneous character of formations in this area. However, strongly amplifying its sediments largely explains the seismic acceleration of 0.52 g recorded following the 2003 Boumerdes earthquake.     

Local site effects estimated from ambient vibration measurements at the Nubian habitations area in Kurkur,Aswan, Egypt

The Egyptian government proposed a general plan, aiming to construct new settlements for Nubians in south Aswan in different places around Nasser’s Lake, one of these settlements in Kurkur area. This area are affecting by near distance earthquakes from Kalabsha faults system. These earthquakes generated great site effects on the sedimentary layers that in turn significantly influenced earthquake ground motions in the area. The main objective of the current study is to estimate the effect of local geology on seismic motion in terms of fundamental resonance frequency (f₀) and the corresponding H/V amplitude values (A₀) using the Nakamura technique. Ambient vibration measurements were carried out at 40 sites that are representative for the different geological units beneath the area. The recorded signals were processed using the horizontal-to-vertical (H/V) spectral ratio Nakamura’s technique. Analysis of spatial distribution of the fundamental frequencies (f₀) and the corresponding H/V amplitudes (A₀) showed that the f₀ value varies from 0.98 to 2.74 Hz, while A₀ varies from 2.2 to 6.6 within the study area. Output of this study is very important for solving the problems, which associated with the construction of various civil engineering purposes, for land-use planning and for earthquakes resistant structure design.     

Microseismic and acoustic emission effect on gas outburst hazard triggered by shock wave: a case study

It has a significant and practical meaning for warning precisely gas outburst to reveal microseismic (MS) and acoustic emission (AE) effect of gas outburst precursor. It was thoroughly investigated and discussed on MS and AE effect on an abnormal gas outburst triggered by a strong rockburst using MS- and AE-monitoring systems through spectral analysis technique. We obtained main conclusions are as: (1) MS amplitude prominently decreased prior to outburst, the spectrum significantly moved from extremely low-frequency to high-frequency band, and evolved from “single-peak type” (the center frequency was about 1.5–3.5 Hz) to “multi-peak type” (the peak frequencies were about 25, 50, 75 and 125 Hz, respectively). (2) During the initiative stage of outburst, MS spectrum manifested the broadband distribution, and the predominant frequency was about 20–35 Hz. The high-frequency portion was generated by micro-cracks, and the low-frequency part attributed to macro-fracture for gas outburst channel. (3) The rockburst stimulated micro-fissures formation for gas emission channels, and maintained the event count of MS and AE signals in a relatively higher level, which is a major discrepancy to the common belief that both the total energy and event count should simultaneously and suddenly reduce to the lowest value in a non-outburst coal seam.     

羌塘盆地油气二维地震勘探进展综述

本文详细讨论了羌塘盆地二十多年来二维地震勘探所取得的进展。羌塘盆地除发育背景干扰外,还发育多种面波散射、线性干扰、折射波和多次折射波;检波器大组合能压制背景和面波散射干扰,但不能压制速度较高的线性干扰、折射波和多次折射波。最佳激发因素为常规可控震源振动台次3台1次,驱动幅度70%,扫描频率6～84Hz,扫描长度18s;低频可控震源振动台次2台1次,驱动幅度60%,扫描频率1. 5～84Hz,扫描长度16s;大吨位可控震源振动台次2台1次,驱动幅度70%,扫描频率6～84Hz,扫描长度16s。炸药震源为单井高速层下7m激发,最浅井深18m,药量18kg;组合方式激发为2口井×15m×12kg或3口井×12m×8kg。尽管可控震源单炮的能量、信噪比、频谱及子波一致性与炸药震源相比较并不占优,但可控震源激发在高密度高覆盖采集条件下仍能获得等同于或明显优于井炮激发质量的地震剖面资料。从"环保、安全、经济、高效"上考虑,羌塘盆地宜采用可控震源和井炮联合的宽线高密度高覆盖采集方案,3L3S或2L3S,960次以上覆盖为可控震源最佳观测系统;2L3S,360次左右覆盖为井炮震源最佳观测系统。北羌塘坳陷构造稳定,容易获取高品质地震资料,南羌塘坳陷构造过于复杂,资料信噪比低,可能不太适合开展地震勘探工作。文章最后还讨论了冻土层静校正和激发接收方面存在的问题及解决方案。     

Thermal structure and metamorphic evolution of the Piemont-Ligurian metasediments in the northern Western Alps

In the Western Alps, the Piemont-Ligurian oceanic domain records blueschist to eclogite metamorphic conditions during the Alpine orogeny. This domain is classically divided into two “zones” (Combin and Zermatt-Saas), with contrasting metamorphic evolution, and separated tectonically by the Combin fault. This study presents new metamorphic and temperature (RSCM thermometry) data obtained in Piemont-Ligurian metasediments and proposes a reevaluation of the P–T evolution of this domain. In the upper unit (or “Combin zone”) temperatures are in the range of 420–530 °C, with an increase of temperature from upper to lower structural levels. Petrological evidences show that these temperatures are related to the retrograde path and to deformation at greenschist metamorphic conditions. This highlights heating during exhumation of HP metamorphic rocks. In the lower unit (or “Zermatt-Saas zone”), temperatures are very homogeneous in the range of 500–540 °C. This shows almost continuous downward temperature increase in the Piemont-Ligurian domain. The observed thermal structure is interpreted as the result of the upper and lower unit juxtaposition along shear zones at a temperature of ~500 °C during the Middle Eocene. This juxtaposition probably occurred at shallow crustal levels (~15–20 km) within a subduction channel. We finally propose that the Piemont-Ligurian Domain should not be viewed as two distinct “zones”, but rather as a stack of several tectonic slices.     

Attenuation in Southeastern Carpathians area: Result of upper mantle inhomogeneity

The systematic analysis of seismograms recorded on the Romanian territory using Vrancea intermediate-depth earthquakes shows a strong asymmetric pattern relative to the epicentral area: on one side, in the Transylvanian Basin and the Eastern Carpathians (approximately along the inner volcanic chain), the amplitudes are reduced by a factor of 20 on average and the high frequencies are attenuated, in contrast with the other side, in the foreland platform. This pattern is explained by a significant attenuation increase caused by a strong lateral variation of the structure in the upper mantle, immediately towards NW of the Vrancea seismic active volume. This region corresponds to the most recent volcanic activity in the Persani Mountains and with the low-velocity body adjacent toward NW to the high-velocity body subducted beneath Vrancea area as indicated by seismic tomography and heat flow results. The CALIXTO'99 tomography experiment, deployed for 6 months in 1999, provides the largest number of observations for Vrancea earthquakes ever recorded on the Romanian territory. We select data from 8 earthquakes generated in this time interval in the Vrancea nest, which were recorded with signal / noise ratio greater than 5 by at least 25 stations. All of them are small- to moderate-magnitude events (3.6 ≤ M_w ≤ 4.2). The attenuation is much more important in the high-frequency range (> 1 Hz), than at low frequencies. Since the large Vrancea earthquakes can radiate significant energy in the low-frequency range (< 1 Hz), our results show that the seismic hazard level is much more uniform all over the Romanian territory in the low-frequency range than in the high-frequency range.     

Correction to: Application of analytical hierarchy process (AHP) for flood risk assessment: a case study in Malda district of West Bengal,India

Flow pulsations in two-phase and single-phase near-critical fluids are considered as a possible source of ultra-low-frequency seismo-electromagnetic variations. The conditions for generation and suppression of density wave instability in the crust are analyzed and the surface electromagnetic effect due to streaming potential generation is estimated. The upper limit of amplitude of magnetic field variations due to density wave instability is about 0.1 nT for single-phase supercritical and 1 nT for two-phase flow oscillations in the frequency range \(10^{-4}{-}10^{-2}~\) Hz for the temperature gradients and spatial scales possible during strike slip events. The signal is characterized by a decaying amplitude with typical relaxation time of about several quasi-periods. The possibility of generation of very low-frequency flow pulsations in two-phase fluids via individual bubble evolution and interaction with external acoustic waves is discussed.     

Hydrogeochemical and isotopic characterization of the groundwater in the Chari-Baguirmi depression, Republic of Chad

The Chari Baguirmi groundwater in the Republic of Chad is undergoing a steady deterioration both qualitative and quantitative due to climatic (severe droughts) and anthropogenic (overexploitation) constraints. However, this major water resource has not been to date the object of any comprehensive scientific investigation. To fill this gap and consider a sustainable exploitation, a hydrodynamic and hydrochemical study was undertaken. This aquifer is located south of Lake Chad and displays a significant natural piezometric depression. Piezometric campaign on an area of 70,000 km², bounded by Lake Chad, the Chari River, the mountains of Guera and the dunes of Harr, was conducted to understand the hydrodynamics of the groundwater. Water samples were collected on 124 points scattered over the study area. Hydrochemical and isotopic analyses (¹⁸O and ²H) were achieved on all samples. The interpretation of hydrochemical data was done using the Piper diagram, the multivariate analysis (hierarchical ascending classification), the index of base exchanges and ratios of Na/Cl, Na/SO₄, Cl/SO₄, Br/Cl, Sr/Ca. The hydrochemical results coupled with groundwater isotopes data allowed to understand the processes that govern the mineralization and the origin of groundwater salinity. These investigations allowed on the one hand to differentiate between two poles of water mixing and second, to demonstrate that the mineralization process and origin of salinity in the center of depression are both related to the lithology of the geological formations crossed by groundwater flow and climatic events causing evaporation of water from the aquifer.     

Geomorphology and the controls of geohydrology on waterlogging in Gangetic Plains,North Bihar,India

Waterlogging is a complex phenomenon, the severity of which depends on a number of natural as well as anthropogenic factors. The present study pertains to the evaluation of control exerted by various factors, viz geomorphology, relief, groundwater fluctuation, rainfall, catchment area and canal–road network density, on waterlogging in the north Bihar region of Gangetic Plains. Satellite images IRS P6 LISS III acquired in the years 2005 and 2006 were used to map temporal variability in surface waterlogging which revealed a reduction of 52 % in the waterlogging area during the pre-monsoon. The seasonal groundwater fluctuation was examined using 2005–2006 pre- and post-monsoon water level data. It clearly indicated that a large portion of the area was also under highly critical groundwater level occurring at a depth of less than 1 m belowground surface during the post-monsoon periods. The percentage of waterlogged area per square kilometer in each geomorphological unit clearly depicts that the Kosi megafan (Lower), because of a high density of paleochannels, comprises the highest post-monsoon waterlogged area. The Tropical Rainfall Measuring Mission (TRMM) data were analyzed for the period 1998–2009 to examine the spatial variability of rainfall over the entire catchment during the monsoon period. The high incidence of post-monsoon surface waterlogging delineated through satellite data and high average rainfall (>1,100 mm) in the same area indicates a positive relationship between rainfall and surface waterlogging. Waterlogging is more prominent in the lower relief zones, but anomalous relative rise in waterlogging within 40–50 m of relief zone was attributed to anthropogenic factors primarily related to the development of canal network.     

Geochemistry of deep-sea sediments in two cores retrieved at the mouth of the Coatzacoalcos River delta,western Gulf of Mexico,Mexico

Coastal margins, especially the river-influenced coastal areas, are considered as active interfaces between the continental and oceanic environments, which have huge dispersal of detrital materials and heavy metal input. It is well determined that the fine-grained sediments are important reservoir for the accumulation of heavy metals. In this study, we analyzed the radiocarbon age, texture, organic matter, carbonate content, and geochemical compositions of two sediment cores (GM42 and GM44) retrieved in front of the Coatzacoalcos River mouth basin, southwestern Gulf of Mexico (～864 and 845 m water depth, respectively). Our objective was to infer the sedimentation rate, intensity of weathering, provenance, and influence of anthropogenic activities on heavy metal contamination in sediments. The radiocarbon-age measurements of mixed planktonic foraminifera for core GM44 reveals an age of 21,289 ± 136 cal. years B.P., which fall within the Late Glacial Maximum (LGM; 21000 ± 2000 years B.P). The calculated sedimentation rate for core GM42 (~0.013 cm/year) is lower than in core GM44 (0.022 cm/year), which is probably due to the variations in detrital sediment input and/or seafloor topography. The weathering indices such as chemical index of alteration (CIA), chemical index of weathering (CIW), and plagioclase index of alteration (PIA) suggested that the source area experienced low to moderate intensity of chemical weathering under warm to humid climatic conditions. The SiO₂/Al₂O₃, Al₂O₃/Na₂O, and K₂O/Al₂O₃ ratio values indicated moderate to high compositional maturity. The major and trace element concentrations suggested that the sediments were likely derived from intermediate source rocks. The heavy metal contents indicated that the sediments were not contaminated by the industrial waste disposals supplied by the Coatzacoalcos River. The redox proxy sensitive elements such as V, Cr, Cu, and Zn indicated an oxic depositional environment for the deep-sea sediment cores. The application of discrimination diagrams for the geochemistry data revealed a passive margin setting for the sediment cores. The compositional variations observed at the upper sections (<30 cm) between the two sediment cores revealed that the type of detrital sediments supplied by the Coatzacoalcos River to the deep sea area is not uniform, which is also revealed by the variation in sedimentation rate.     

Bronze Age at Lake Bourget (NW Alps, France): Vegetation, human impact and climatic change

Pollen analyses of three sediment cores performed on the archaeological lake dwellings of Chindrieux and Tresserve (Savoie, France), on the eastern shore of Lake Bourget, enable the reconstruction of vegetation history and human impact during the Bronze Age. Results show a good correlation between lake-level fluctuations and the evolution of anthropogenic indicators. The end of the Neolithic period and the early Bronze Age are characterised by a discreet occupation of the Lake Bourget surroundings, in spite of a warmer climatic condition. The middle Bronze Age, contemporaneous with wetter and cooler conditions, is related to a decrease in pollen of cultivated plants and weed. Farming activities reappear in the late Bronze Age and human impact increases suddenly at the very end of the late Bronze Age. Three anthropogenic phases are clearly visible: a short decrease in anthropogenic indicators and a high lake-level phase occur in the middle of this period of intense farming development. A new decrease in human impact appears at the beginning of the Iron Age.     

Natural Environmental Changes versus Human Impact in a Florida Estuary (Rookery Bay, USA)

Assessing the impact of climate change and anthropogenic activity on Florida coastal areas requires a thorough understanding of natural climate variability. The available instrumental record, however, is too short and too limited to capture the full range of natural variability. In order to provide additional data on the natural state of the climate system and to evaluate the influence of human impact, we reconstructed climatic and environmental changes of the past 300 years. Pre- (before 1900 ad) and post-human impact conditions were compared in Rookery Bay, a subtropical, southern Florida estuary and its bordering wetland system. Biomarkers from terrestrial and aquatic environments were used to reconstruct temperature, runoff, and aquatic productivity. Pre-anthropogenic conditions before 1750 ad indicate a relatively large contribution of mangrove-derived organic matter, locally decreasing at the end of this period. After 1750 ad follows a relatively stable period in which biomarker concentrations indicate relatively low levels of runoff and aquatic production. Enhanced anthropogenic activities, such as land clearance and hydrological alterations, end this period of stability by altering the hydrological conditions. This leads to a more dynamic system which is more sensitive to disturbances of vegetation and drainage, as evidenced by peak terrestrial biomarker fluxes during the twentieth century. These episodes of enhanced runoff resulted in eutrophication and algal blooms in Rookery Bay. Natural climate phenomena, such as a positive AMO phase and hurricane activity, might have added to ongoing processes during the twentieth century.     

Climatic signals in lacustrine deposits of the Upper Yacoraite Formation,Western Argentina: Evidence from clay minerals,analcime, dolomite and fibrous calcite

Authigenic clays are an important control on reservoir quality in lacustrine carbonates but remain challenging to predict. Lacustrine depositional systems respond to climatic variations in rainfall, surface runoff and groundwater input, and evaporation, and result in rapid and frequent changes in lake volume; this is expressed through changing water depth and shoreline position. In the upper portion of the Early Palaeocene Yacoraite Formation of the Salta Basin in Argentina, extensive lacustrine deposits were deposited during the sag phase of rifting. Prior high-resolution stratigraphic studies have suggested that climatic factors control microbial carbonate sequences within a ‘balanced fill’ lake, with variation in the lake level having a major influence on facies association changes. This study characterizes the evolution of facies and mineralogy within the Yacoraite Formation, focusing on the distribution of clay minerals, making a link between the high, medium and low-frequency sequence stratigraphic cycles. The low-frequency transgressive hemicycle of the upper portion of the Yacoraite Formation is comprised of abundant siliciclastic facies, suggesting a wetter period. Microbialites occurring in this interval are coarse-grained and agglutinated. Detrital clay minerals such as illite and chlorite and associated siliciclastic sediments were input to the lake during high-frequency transgressive periods. During high-frequency regressive hemicycles, sedimentation was dominated by carbonate facies with Ca-rich dolomite and the authigenic clays are comprised of chlorite/smectite mixed-layers. By contrast, the low frequency regressive hemicycle records fine-grained agglutinated microbialite with horizons of fibrous calcite, more stoichiometric dolomite, barite and authigenic magnesian smectite. This indicates elevated ion concentrations in the lake under intense evaporation during an arid period. Understanding the conditions that are favourable for formation and preservation of authigenic clays within the lacustrine environment can improve understanding of reservoir quality in comparable economically important deposits.     

高频振动下散粒体-结构界面临界状态强度特征试验研究

高铁桥梁、路基工程中的桩基础持续承受列车运行引发的振动荷载,当前350 km/h车速下的车致振动已高达近40 Hz。随着车速的进一步提升,可能给桩基础承载性能带来不利影响。桩-土界面是桩和地基土之间力和变形传递的重要媒介,很大程度上决定着桩基础的长期服役性能。但目前对于高频振动荷载下桩-土界面相互作用行为的认识和研究均不足。基于自主研制的可实现土-结构界面高频振动耦合静力剪切的试验装置,研究了散粒体-结构界面在振动下的临界状态强度特征,探讨了振动加速度、法向应力、结构面粗糙度、颗粒形状和振动频率的影响。结果表明：振动会导致界面强度衰减,部分振动条件下的界面强度甚至低于静力条件下的0.5倍;振动下的界面强度随振动加速度、频率的增大而下降,随法向应力的增大而提高。最后,基于摩尔-库仑强度理论,建立了振动下的散粒体-结构界面强度准则。     

Factors controlling mechanisms of groundwater salinization and hydrogeochemical processes in the Quaternary aquifer of the Eastern Nile Delta, Egypt

In this study, combining interpretations of conservative dissolved ions and environmental isotopes in water were used to investigate the main factors and mechanisms controlling groundwater salinization and hydrogeochemical processes in the Eastern Nile Delta, Egypt. Hydrogeochemical and isotopic study has been carried out for 61 water samples from the study area. Total dissolved solid (TDS) contents of groundwater are highly variable rising along flowpath from the south (410 mg/L) to the north (14,784 mg/L), implying significant deterioration and salinization of groundwater. Based on TDS and ionic ratios, groundwater samples were classified into three groups. In low-saline groups, water chemistry is greatly influenced by cation exchange, mineral dissolution/precipitation, anthropogenic pollutants and mixing with surface water. Whilst, in high-saline groups, water chemistry is affected by salt-water intrusion, reverse cation exchange and evaporation. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta and saturation index approaches. The δ¹⁸O–δ²H relationship plots on a typical evaporation line, suggesting potential evaporation of the recharging water prior to infiltration. Isotope evidence concludes that the groundwater have been considerably formed by mixing between depleted meteoric water recharged under different climatic conditions and recently infiltrating enriched surface water and excess of irrigation water. The δ¹⁸O data in conjunction with chloride concentrations provide firm evidence for impact of dissolution of marine-origin evaporite deposits, during past geologic periods, on groundwater salinity in the northern region. Moreover, the relation between ¹⁴C activities and Cl^? concentration confirms this hypothesis.     

Carbon isotopes and geochemical processes in CO2-rich cold mineral water,N-Portugal

This paper summarizes a new outlook on the conceptual model of Melgaço–Messegães CO₂-rich cold (≈18 °C) mineral water systems, issuing in N of Portugal, based on their isotopic (²H, ³H, ¹³C, ¹⁴C and ¹⁸O) and geochemical features. Stable isotopes indicate the meteoric origin of these CO₂-rich mineral waters. Based on the isotopic fractionation with the altitude, a recharge altitude between 513 up to 740 m a.s.l. was estimated, corroborating the tritium results. The lowest ³H content (0 TU) is found in the groundwater samples with the highest mineralization. The mineral waters circulation are mainly related to a granitic and granodioritic environment inducing two different groundwater types (Ca/Na–HCO₃ and Na/Ca–HCO₃), indicating different underground flow paths. Calcium dissolution is controlled by hydrolysis of rock-matrix silicate minerals (e.g. Ca-plagioclases) and not associated to anthropogenic sources. The shallow dilute groundwaters exhibit signatures of anthropogenic origins (e.g. NO₃) and higher Na/Ca ratios. The stable isotopes together with the geochemistry provided no indication of mixing between the regional shallow cold dilute groundwater and mineral water systems. The heavy isotopic signatures identified in the δ¹³C data (δ¹³C = 4.7 ‰, performed on the total dissolved inorganic carbon (TDIC) of CO₂-rich mineral waters) could be derived from a deep-seated (upper mantle) source or associated to methanogenesis (CH₄ source). The negligible ¹⁴C content (≈2 pmC) determined in the TDIC of the mineral waters, corroborates the hypothesis of a mantle-derived carbon source to the mineral groundwater systems or dissolution of carbonate layers at depth.     

Assessment of heavy metal contamination levels of street dust in the city of Lublin,E Poland

Heavy metals are constantly emitted into the environment and pose a major threat to human health, particularly in urban areas. The threat is linked to the presence of Cd, Cr, Cu, Ni, Pb, and Zn in street dust, which consists of mineral and organic particles originating from the soil, industrial emitters, motor vehicles, and fuel consumption. The study objective was to determine the level of street dust contamination with trace metals in Lublin and to indicate their potential sources of origin. The analyses were carried out with an energy-dispersive X-ray fluorescence spectrometer. The sampling sites (49) were located within the city streets characterised by varying intensity of motor traffic. The following mean content values and their variation (SD) were determined: Cd: 5.1?±?1.7 mg kg^?1, Cr: 86.4?±?23.3 mg kg^?1, Cu: 81.6?±?69.2 mg kg^?1, Ni: 16.5?±?3.9 mg kg^?1, Pb: 44.1?±?16.4 mg kg^?1, and Zn: 241.1?±?94.6 mg kg^?1. The level of pollution was assessed with several widely used geochemical indices (geoaccumulation index, enrichment factor, pollution index, index of ecological risk, and potential ecological risk index). For most of the indices, the mean (median) values are arranged in the following manner: Zn?>?Cu(or Cd)?>?Pb?>?Ni?>?Cr. In general, street dust in Lublin does not show pollution with Cr, Ni, and Pb. I_geo and EF indices show moderate levels for Cu, Cd, and Zn; their presence in street dust is linked with anthropogenic factors (motor traffic). A significant threat is posed by Cd, and more than half of the samples show considerable pollution with cadmium (median for the index of ecological risk: 151). The spatial pattern of indices and the results of statistical analyses (CA, PCA) indicate three groups of elements: (1) Cr and Ni: natural origin; (2) Pb: mixed origin; and (3) Cd, Cu, and Zn: anthropogenic origin (mainly motor vehicle traffic). Higher content values for metals of anthropogenic origin in street dust indicate that it is a source of pollution of soil and air in the city.     

Hydroxyl stretching in phyllosilicates at high pressures and temperatures: an infrared spectroscopic study

The hydroxyl stretching frequencies of four phyllosilicates have been measured at high pressures and temperatures using an externally heated diamond-anvil cell and synchrotron infrared spectroscopy. Spectra were measured up to 26, 31, 21 and 8 GPa at room temperature for samples of talc, pyrophyllite, muscovite and 10-Å phase, respectively. Spectra were also measured in the range 273–500 K at ambient pressure for all samples and at 8–9 GPa for talc and pyrophyllite. The frequency of the Mg₃OH band in talc increases with pressure due to the absence of hydrogen bonding. The different orientation of the hydroxyl group in pyrophyllite and muscovite leads to hydrogen bonding and a decrease in the frequency of the Al₂OH band with pressure. 10-Å phase is approximately equivalent to talc with the addition of interlayer H₂O. In a spectrum of a sample synthesised for 143 h, two hydroxyl stretching bands are clearly resolved on compression. One is the same as the Mg₃OH band in talc, indicating the presence of intra-layer hydroxyl in a talc-like environment with no hydrogen bonding. The other, which separates from the talc-like band at 1 GPa, is associated with intra-layer hydroxyl that is hydrogen bonded to interlayer H₂O. There are equivalent bands in high-pressure spectra of a sample of deuterated 10-Å phase, synthesised for 400 h. This sample shows a greater extent of hydrogen bonding at ambient pressure than the 143 h sample. For all of the phases studied, increasing temperature leads to a decrease in frequency for every hydroxyl stretching vibration, both at low and high pressures. The shifts in frequency with temperature are an order of magnitude greater than the shifts with pressure when normalised to previously measured structural parameters.