青海北祁连冷龙岭地区水系沉积物元素地球化学特征及异常圈定

青海冷龙岭地区位于北祁连成矿段的东段,是形成与海相火山岩有关的块状硫化物矿床及岩浆热液型矿床的有利地区,具有良好的找矿潜力。在1∶5万水系沉积物测量成果的基础上,对青海冷龙岭地区Au、Cu、Pb、Zn等17种元素的地球化学特征进行了初步分析,发现本区Ag、Pb、Zn、W、Sn、Bi、Mo、Ba、Cd等元素丰度明显高于青海省及祁连地区水系沉积物的平均丰度值;元素分布特征显示下奥陶统阴沟群除Hg、La、Ce相对贫化外,各元素都呈现不同程度的浓集,加里东期侵入岩中Ag、Cu、Pb、Zn、W、Au、Sn、Bi等元素富集程度较高,海西期正长岩内Ba、La、Ce等元素富集程度较为显著;R型聚类分析和因子分析显示区内的主要成矿元素组合为Cu Pb Ag Mo Ba La Ce,Au具有独立成矿的潜力。结合元素地球化学参数及富集离散特征,认为本区Au、Ag、Cu、Pb、Zn、Mo、La、Ce等元素具有一定的找矿潜力。本次工作共圈定8个综合异常。根据研究区成矿地质背景、异常特征及查证成果,与该区域内浪力克铜矿床和青分岭金矿床的地质地球化学特征对比研究后,优选出干沙河和三道路圈—倒阳河2个成矿远景区。     

Regional geochemical prospecting in Calabria, Southern Italy

A governmental regional drainage survey assessed the mineral potential of Calabria in 1974. The Calabria area of southern Italy is a mineralized region in which Penninic and Austro-Alpine nappes, comprising ophiolites, metasedimentary rocks (phyllites, paragneiss, granulites, amphibolites) and granitic and granodiorite plutons, are overthrusting carbonate Apenninic nappes. Pre-Alpine stratabound and vein-type base-metal sulfide mineralization predominate, tectonically redistributed during the Alpine orogeny.A total of 5518 samples of the original 6999 active stream sediments from an area of 10,000 km² were analyzed by X-ray fluorescence and atomic absorption for Cu, Pb, Zn, Hg, Fe, Mn, As, W, Mo, Sn, and Be on the minus 180 μm fraction. Follow-up investigation of a 39-km² area around Bivongi-Ferdinandea using 760 soil samples analyzed for Fe, Mn, Zn, Cu, Pb, K, Mo, and Au, investigated molybdenite and chalcopyrite occurrences associated with granodiorite.A five-factor R-mode factor analysis reflected geological and mineralization features in the reconnaissance data. Factor 1 (Fe-Mn-Cu-Zn) is related to the Fe and Mn distribution in the stream sediments. Factor 2 (Be-Sn) reflects presence of pegmatites within metamorphic and magmatic rocks. Factor 5 (Mo) is essentially a single-element factor. Factor 4 (As-Pb-Zn-Hg-Cu) reflects mineralization. Factor 3 (W-Ba) does not cluster in association with any specific lithological unit. Significant metal associations, recognized from R-mode factor analysis, were used as independent variables and regressed against the original metal concentration of each sample. Residuals of multiple regression analysis, differentiated features representing mineralization from those related either to lithologic or geochemical parameters. New prospecting targets were identified and areas of known mineral occurrences were evident in the distinction of residuals.R-mode factor analysis of data from the follow-up investigation identified three factors. Factor 2 (Mo-K) reflects Mo mineralization and associated hydrothermally altered areas but does not suggest additional target areas.     

安徽池州许桥—乌古墩铅锌矿石榴子石和锆石U-Pb定年

石榴子石U-Pb定年在限定金属矿床形成时代上具有一定的优越性,而且近年来得到不少成功地应用。作为长江中下游的重要组成部分,池州地区燕山期岩浆活动强烈,伴随有成矿作用。然而,由于矿体赋存于沉积围岩中,区内的铅锌矿化时代目前还很模糊。本次对许桥—乌谷墩铅锌矿中多条岩脉及石榴子石进行多种矿物原位U-Pb定年。乌谷墩矿区内见有两种岩性的岩脉,其一为闪长玢岩,与铜、钼矿化关系密切,锆石U-Pb定年结果为146～141 Ma;另一为细粒花岗岩,与钼矿化关系密切,锆石U-Pb定年结果为113.4±2 Ma。矽卡岩中石榴子石U-Pb定年结果为148～143 Ma,形成时代与闪长玢岩脉一致。根据现有数据,池州地区存在3个阶段的成岩成矿作用：第一阶段（150～135 Ma）,主要形成中酸性侵入岩和与之相关的铜、金、钼、铅、锌等矿床;第二阶段（134～124 Ma）,形成钾长花岗岩和相关的铅锌钼矿化;第三阶段（115～110 Ma）,岩浆活动接近尾声,主要发育花岗岩脉,并伴随弱的钼矿化。结合区域成矿规律,池州地区的成矿作用不完全与长江中下游地区相同,且池州区内的多期Mo （W）矿化可能与中-新元古代增生地壳多阶段活化有关。     

老挝普老地区多金属矿地球化学异常特征及找矿前景

普老地区Pb、Zn、Sn多金属异常区位于老挝北部长山成矿带,1∶5万水系沉积物地球化学测量发现了以Pb、Sn为主,伴生Zn、Ag、W、Sb、Bi、As、Hg、Cu、Au等元素异常。1∶1万土壤地球化学测量圈定了3个综合异常带,Pb、Zn、Sn等元素具有异常强度高、规模大、浓集中心明显的特点,经异常检查发现铅锌、锡多金属矿化点13处。研究和分析异常区元素的地球化学分布和异常特征,认为该区多金属异常为矿致异常,具有寻找热液型铅锌、锡及多金属矿的潜力。     

Sensitive High-Resolution Ion Microprobe U-Pb Zircon and 40Ar-39Ar Muscovite Ages of the Yinshan Deposit in the Northeast Jiangxi Province, South China

The Yinshan deposit in the Jiangnan tectonic belt in South China consists of Pb‐Zn‐Ag and Cu‐Au ore bodies. This deposit contains approximately 83 Mt of the Cu‐Au ores at 0.52% Cu and 0.8 g/t Au, and 84 Mt of the Pb‐Zn‐Ag ores at 1.25% Pb, 1.02% Zn and 33.3 g/t Ag. It is hosted by low‐grade metamorphosed sedimentary rocks and mafic volcanic rocks of the lower Mesoproterozoic Shuangqiaoshan Group, and continental volcanic rocks of the Jurassic Erhuling Group and dacitic subvolcanic rocks. The ore bodies mainly consist of veinlets of sulfide minerals and sulfide‐disseminated rocks, which are divided into Cu‐Au and Pb‐Zn‐Ag ore bodies. The Cu‐Au ore bodies occur in the area close to a dacite porphyry stock (No. 3 stock), whereas Pb‐Zn‐Ag bodies occur in areas distal from the No. 3 stock. Muscovite is the main alteration mineral associated with the Cu‐Au ore bodies, and muscovite and chlorite are associated with the Pb‐Zn‐Ag ores. A zircon sensitive high‐resolution ion microprobe U‐Pb age from the No. 3 dacite stock suggests it was emplaced in Early Jurassic. Three ⁴⁰Ar‐³⁹Ar incremental‐heating mineral ages from muscovite, which are related to Cu‐Au and Pb‐Zn‐Ag mineralization, yielded 179–175 Ma. These muscovite ages indicate that Cu‐Au mineralization occurred at 178.2±1.4 Ma (2σ), and Pb‐Zn‐Ag mineralization at 175.4±1.2 Ma (2σ) and 175.3±1.1 Ma (2σ), which supports a restricted period for the mineralization. The Early Jurassic ages for the mineralization at Yinshan are similar to that of the porphyry Cu mineralization at Dexing in Jiangnan tectonic belt, and suggest that the polymetallic mineralization occurred in a regional transcompressional tectonic regime.     

广东中生代岩浆作用矿床成矿系列

广东中生代与壳幔岩浆活动有关的成矿作用十分强烈,多期成矿作用明显.在前人工作的基础上,根据矿床的成矿时代、成矿地质构造环境、主要成矿作用及形成的矿床组合,将中生代与岩浆作用有关的矿床厘定为6个矿床成矿系列：1）云开与印支期岩浆活动有关的铌、钽、磷、铁矿床成矿系列;2）粤北与燕山期花岗岩有关的有色金属、稀有金属、贵金属、非金属、铀矿床成矿系列;3）深大断裂带与燕山期基性-中酸性侵入岩有关的铜、铅、锌、金、铁、钼、钨、水晶、砷、硫铁、钒、钛矿床成矿系列;4）深变质带与区域变质、动力变质及燕山期花岗岩类有关的金、银矿床成矿系列;5）沿海与燕山期火山-侵入活动有关的铁、铜、金、银、铅、锌、钨、锡、钼、铌、钽、硫铁、水晶、萤石、叶蜡石、重晶石矿床成矿系列;6）阳春-罗定与燕山晚期壳源花岗岩类侵入活动有关的锡、钨、钼、铜、铁、铅、锌、银矿床成矿系列.论述了各成矿系列的基本特征,并对成矿系列形成的构造背景和成矿作用的时空分布及演化规律进行了探讨.     

A comparative study of stream water and stream sediment as geochemical exploration media in the Rio Tanama porphyry copper district,Puerto Rico

To test the relative effectiveness of stream water and sediment as geochemical exploration media in the Rio Tanama porphyry copper district of Puerto Rico, we collected and subsequently analyzed samples of water and sediment from 29 sites in the rivers and tributaries of the district. Copper, Mo, Pb, Zn, SO₄^2?, and pH were determined in the waters; Cu, Mo, Pb, and Zn were determined in the sediments. In addition, copper in five partial extractions from the sediments was determined. Geochemical contrast (anomaly-to-background quotient) was the principal criterion by which the effectiveness of the two media and the five extractions were judged.Among the distribution patterns of metals in stream water, that of copper most clearly delineates the known porphyry copper deposits and yields the longest discernable dispersion train. The distribution patterns of Mo, Pb, and Zn in water show little relationship to the known mineralization. The distribution of SO₄^2? in water delineates the copper deposits and also the more extensive pyrite alteration in the district; its recognizable downstream dispersion train is substantially longer than those of the metals, either in water or sediment. Low pH values in small tributaries delineate areas of known sulfide mineralization.The distribution patterns of copper in sediments clearly delineate the known deposits, and the dispersion trains are longer than those of copper in water.The partial determinations of copper related to secondary iron and manganese oxides yield the strongest geochemical contrasts and longest recognizable dispersion trains. Significantly high concentrations of molybdenum in sediments were found at only three sites, all within one-half km downstream of the known copper deposits. The distribution patterns of lead and zinc in sediments are clearly related to the known primary lead-zinc haloes around the copper deposits. The recognizable downstream dispersion trains of lead and zinc are shorter than those of copper.     

黑龙江省某地区地球化学异常、地质特征及成矿预测

在黑龙江某地区1:5万水系沉积物测量的基础上,对测区内可能富集成矿的Bi、Cu、Hg、W、As、Au、Mo、Zn、Sb、Ag、Pb等元素地球化学特征进行了系统阐述,其中极有可能成矿的元素是Bi、Hg、Cu、Zn、W、Mo。     

谢通门色药异常区铜找矿前景浅析

本文在区域地质、水系沉积物测量、土壤测量和高精度磁测等方面对色药异常区的铜找矿前景进行初步分析。利用1∶5万水系沉积物测量编制异常图,发现区内Mo、Cu、Bi、Pb、Zn、Sb、Sn、W、Ag、Hg等元素均有不同规模的异常,且Mo、Cu异常规模较大。通过高精度磁测结果显示区内有3个磁异常,已知铜矿化点均位于磁异常附近。通过土壤测量数据研究元素间的组合关系,推断区内可能的矿床类型与酸性侵入岩有关的斑岩型铜多金属矿。并对区内已发现的1号铜矿化点进行重点研究,表明区内寻找与中酸性侵入岩有关的铜多金属矿具有良好的找矿前景。     

Rb-Sr and Sm-Nd Isochron Ages of the Dongmozhazhua and Mohailaheng Pb-Zn Ore Deposits in the Yushu area,southern Qinghai and Their Geological Implications

Located on the northeast margin of the Qiangtang terrane between the Jinshajiang suture zone and Bangonghu-Nujiang suture zone, the Dongmozhazhua and Mohailaheng Pb-Zn deposits in the Yushu area of Qinghai Province are representative Pb-Zn deposits of the Pb-Zn-Cu polymetallic mineralization belt in the northern part of the Nujiang-Lancangjiang-Jinshajiang area, which are in the front belt of the Yushu thrust nappe system. The formed environments of these two deposits are different from those of sediment-hosted base metal deposits elsewhere in the world. The authors hold that they were formed during the Indian-Asian continental collision and developed within the foldthrust belt combined with thrust and strike-slip-related Cenozoic basins in the interior of the collisional zone. Studying on the metallogenic epochs of these two deposits is helpful to the understanding of ore-forming regularity of the regional Pb-Zn-Cu mineralization belt and also to the search for new deposits in this region. The age of the Dongmozhazhua deposit has been determined by the Rb-Sr isochron method for sphalerite residues, whereas the age of the Mohailaheng deposit has been determined by the Rb-Sr isochron method for sphalerite residues and the Sm-Nd isochron method for fluorite. The age of the Dongmozhazhua deposit is 35.0±0.0 Ma((87Sr/86Sr)0=0.708807) for sphalerite residues. The age of the Mohailaheng deposit is 32.2±0.4 Ma((87Sr/86Sr)0=0.708514) for sphalerite residues and 31.8±0.3 Ma((143Nd/144Nd)0=0.512362) for fluorite with an average of 32.0 Ma. Together with the regional geological setting during mineralization, a possible tectonic model for metallogeny of the Dongmozhazhua and Mohailaheng Pb-Zn deposits has been established. These two ages are close to the ages of the Pb-Zn deposits in the Lanping and Tuotuohe basins, indicating that it is possible that the narrow 1000-kilometer-long belt controlled by a thrust nappe system on the eastern and northern margins of the Tibetan plateau could be a giant Pb-Zn mineralized belt.     

秦岭成矿带成矿特征和找矿方向

秦岭成矿带是我国有色、贵金属工业的重要矿产资源基地,也是最具成矿潜力和找矿远景的地区之一。近年的综合研究工作表明,秦岭造山带是一个多旋回复合大陆碰撞造山带,自太古代以来经历了多种构造体制的转化和多期构造热事件发生,伴随有多个构造成矿旋回,所形成的含矿建造、成矿作用及矿床组合具有多样性。根据成矿时代、构造、建造、成矿作用及矿床组合特征分析,认为秦岭造山带铜、钼、铅、锌、银、金、汞、锑等内生金属矿床主要受7个主要的成矿系统控制,形成了18个主要成矿系列,并对各成矿系列及其典型矿床的地质特征和近几年找矿新发现进行了系统的论述,建立了铜、金、铅、锌、银等矿床系列的区域成矿模式。对区域优势矿种的成矿谱系研究表明,本区成矿在时间演化上表现出明显多旋回性、继承性、新生性和叠加性特征,华力西期与印支末-燕山期是成矿大爆发期,最有利于大型超大矿床形成;在空间分布上,具有明显的侧向和垂向分带性。在此基础上,对秦岭成矿带的成矿潜力及成矿远景区进行了评价和划分,指出秦岭地区热水喷流沉积型与密西西比型铅锌银矿床、微细浸染型与石英脉构造蚀变岩型金矿床、斑岩型钼钨铜矿床及低温热液型汞锑矿床等具有很大的找矿前景。并划分出5个区域成矿远景带和17个重要成矿预测区。     

河北省张家口崇礼区北部地球化学特征及其找矿指示

地球化学测量成果被广泛而成熟地运用在矿产勘查工作中,为明确张家口崇礼区北部成矿、找矿的地球化学指示信息,对该区水系沉积物测量及异常查证成果进行了综合分析。通过计算元素富集系数和变异系数、开展R型聚类分析、统计化探异常区岩石的地质年代、对比该区化探异常及已知矿床与典型矿床的成矿要素,从而推断了该区找矿主攻元素为Ag、Pb、Zn、Mo、Cd,且Ag、Pb、Zn和Mo、W 2组元素分别具有共伴生关系,指出该区化探异常主要受燕山期岩浆热液控制。综合分析认为,本区找矿模型为蔡家营式次火山-热液型多金属矿床,具有寻找次火山-热液型Ag、Pb、Zn、Mo多金属矿床的潜力。     

青海省枪口南银多金属矿床地质特征、控矿因素及矿床成因

枪口南银多金属矿床地处东昆仑多金属成矿带东段,枪口—哈龙休玛海西-燕山期铁、银、铅、锌、铜、金、钼成矿亚带部分,成矿地质条件优越。枪口南银多金属矿区目前已圈定9条矿化带,21个矿体,主要矿种有金、银、铜、铅、锌、钼等,矿石类型主要为构造热液(脉)型铜铅锌银矿石、构造蚀变岩型金矿石。枪口南矿区构造-岩浆活动强烈,印支期—燕山期构造岩浆活动为矿区成矿提供了热源、成矿物质,区内NE向断裂控制区内金、铜、铅锌等矿体的产出,NW向断裂组控制着区内金、银矿(化)体。NW向断裂组,是区内重要控矿构造;区内中部发现的Ⅳ号含矿斑岩体,具有斑岩型矿床蚀变特征,显示其具有斑岩成矿条件。枪口南银多金属矿床成因有构造热液(脉)型、构造蚀变岩型和斑岩型。     

Stream sediment geochemical exploration for gold in Central Eastern Desert,Egypt: Application of the concentration-number fractal model,factor analysis,and geochemical mineralization probability index

Geochemical exploration by stream sediment sampling using bulk leach extractable gold (BLEG) technique and applying concentration-number (C-N) fractal model, factor analysis (FA), and geochemical mineralization probability index (GMPI) resulted in the recognition of new Au occurrences around the Sukari gold mine in the central Eastern Desert of Egypt. The geochemical data of 128 stream sediment samples collected from the study area was used for delineating the geochemical anomalies and characterizing the dispersion trains of ore and associated elements (Au, Ag, As, Sb, Cu, Pb, Zn, Mo). Statistical analysis of the geochemical data applying the C-N fractal modeling enabled us to identify significant anomaly and background populations of the investigated elements and to construct reliable geochemical anomaly maps. Factor analysis using centered log-ratios (CLR), to address the problem of closed compositional data, revealed significant element associations for mineralization (Au, As, Mo, Zn, Ba), country rock compositions (Rb, Li, Be, Sn, Bi for granite, and Co, Cr, Ni for mafic rocks), and element mobility (e.g. Sb, Zr, and Ag). Weak and moderate Au anomalies that cannot be detected by factor score maps can be delineated clearly by using the C-N fractal method and GMPI distribution map. Our study revealed that Ag, As, and Sb are the main pathfinder elements for gold mineralization in arid to semiarid regions exemplified by the Sukari gold district. Silver can be used as a “direct” pathfinder, whereas As and Sb are “indirect” pathfinders for Au in such regions. The spatial distribution of Au and Ag anomalies indicate that gold mineralization in the Sukari district is structurally controlled. However, the spatial distribution of Cu, Pb, Zn, and Mo is controlled by mineralogical and lithological factors and is not related to any significant base metal deposits.     

青海南部三江北段铜多金属成矿系统演化研究

青海南部三江北段构造成矿带经历了复杂而完整的多期次复合造山及叠加改造地质构造过程,导致复杂丰富的成矿演化,发育一系列大型、超大型的铜、金、铅锌等金属矿床。研究认为,目前青海三江北段主要的成矿系统为:与三叠纪火山喷发作用有关的铁、铜、铅、锌、银等成矿系列,与新生代浅成侵入岩有关的钼、铜、铅、锌多金属成矿系列,与新生代有关的热液叠加改造型铅、锌多金属成矿系列。这些成矿系统代表了区域矿矿产资源进一步勘查的方向。     

南岭地区区域化探数据中钨矿信息提取的方法探讨

在成矿作用地球化学与勘查地球化学分析的基础上,选取W、Sn、Mo、B i、Cu、Pb、Zn、Au、Ag、As、Sb、Hg共十二种元素作为南岭地区钨矿勘查的重要指示元素。对这十二种指标元素采用等权平均归一化,相关系数加权累加归一化和异常能归一化三种方法进行处理,都可较好地反映该区钨元素的矿化信息,且均比钨元素单指标异常信息效果显著。相关系数加权累加归一化指标主要反映钨元素信息,而等权平均归一化指标和异常能归一化指标主要反映成矿元素的共同矿化信息,这二者在南岭地区对钨矿成矿信息都具有较好的指示作用。     

青海省东昆仑昆中断裂带哈图段地质特征及成矿预测

昆中断裂带是东昆仑成矿带发育多条巨型断裂构造之一,控制并切割自元古宙以来的不同地质体,对区域成矿具有明显的控制作用,其次级断裂或主断裂构造的交叉部位往往是成矿通道和容矿部位。研究区位于昆中断裂两侧,属活动区造山带,成矿期次多,类型复杂,具有良好成矿地质条件,已发现矿床、矿（化）点多处,与Nb,Y,La,Cu,Zn,Mo,Au,Ag,As,Pb元素为主的地球化学异常对应较好。     

安徽省池州地区区域成矿模式

安徽省池州地区矿床类型主要有矽卡岩型、斑岩型、热液型、风化淋滤型、沉积叠改型等。矽卡岩型是本区主要的矿床类型,根据其成矿特点可进一步分为：层控式、复合式、接触式。,矿床（体）主要赋存在S—O间剥离面奥陶系汤头组、泥盆系顶部层位、泥盆～石炭系界面、石炭系黄龙一船山组、二叠一三叠系碳酸盐地层。燕山早期中酸性岩浆岩、层间滑脱构造、有利成矿的碳酸盐地层、不同方向不同性质的构造结合部位是本区重要的成矿条件。本文在总结前人成果资料的基础上,建立了本区区域成矿模式,将矿床成矿系列主要划分为三个：①与燕山早期钙碱性幔壳同熔型第一次侵入体有关的以W、Mo为主的成矿系列;②与燕山早期钙碱性慢壳同熔型闪长岩类岩体有关的Cu、Fe、S、Pb、Zn、W、Mo、（Au、Ag）成矿系列;③与燕山晚期陆壳改造型富硅富碱花岗岩有关的Ag、Cu、Fe、Pb、Zn多金属成矿系列。     

皖南粒七湾钨钼矿成矿地质特征及找矿远景

通过水系沉积物地化扫面在安徽省祁门县粒七湾圈出了W、Mo、Cu、Bi、Ag等多元素组合异常,检查发现该异常区出露有花岗斑岩体,经探槽揭露取样分析发现有钨钼矿化.在2009年通过进一步工作,取得了找矿突破. 粒七湾钨钼矿为典型斑岩型钨钼矿化,矿化见于岩体内部,呈细脉浸染状产出,矿化的强弱主要受岩体内部裂隙发育程度制约,矿体呈似层状、透镜状,产状较平缓;主要矿体间断地赋存于标高-146.5~80.0m间,共圈出矿体26个,初步估算钨、钼资源量(333+334)均可达中型规模. 矿区的土壤中有以 W、Mo、Cu、Bi、Pb、Zn 元素为组合的地化异常响应,各异常元素分带现象明显,W、Mo、Cu、Bi为异常内带元素,Pb、Zn矿则为异常外带元素,W、Mo的异常侬集中心指示了矿化富集区. 矿区东北部分布有一个磁异常,反映存在隐伏小岩体,根据区域磁异常分析,该岩体可能与粒七湾岩体同源,具有良好找矿远景     

浙江临安西天目地区找矿潜力分析

浙江临安西天目地区地处早古生代扬子被动陆缘和晚中生代西太平洋活动陆缘构造叠加区域.该区发育碳酸盐岩建造,有大量的脉岩出露,环形、放射状断裂构造发育,具有面型蚀变及铜、铅、锌、金等多个矿（化）点;重磁等物探信息显示,该区深部发育EW向深断裂和隐伏岩体;化探扫面揭示,区内钨、钼、铋、铜、铅、锌、金、银、砷等元素背景高;自然重砂调查反映,白钨矿、铅族、钼族等重砂矿物组合具有异常显示.综合成矿地质条件及物、化、重砂异常等信息,认为该区具有寻找斑岩型、夕卡岩型、低温热液型钨、钼、铜、铅锌、金银等多位一体矿床的潜力.