东昆仑南地体苦海岩群副片麻岩锆石年代学研究

东昆仑南地体最古老的变质基底为苦海岩群,出露于苦海-温泉一带。采用LA-ICP-MS方法对苦海岩群副片麻岩中的锆石进行测试,得出苦海岩群副片麻岩的最大沉积时代为新元古代早期且在志留纪(423 Ma)遭受变质。通过与东昆仑北地体变质基底金水口岩群的锆石年龄谱对比,苦海岩群和金水口岩群的锆石年龄谱中都存在1 550~1 650 Ma、1 900~2 100 Ma、2 350~2 550 Ma的年龄段峰值,两岩群可能存在相似的物源区;年龄谱中最年轻的岩浆锆石峰值年龄分别为750~800 Ma和900~1 250 Ma,两岩群的最大沉积时代相近,分别为新元古代早期(Pt_3)、中元古代晚期-新元古代早期(Pt_(2-3));年龄谱中都存在400~450 Ma的变质年龄峰值,两岩群在志留纪均发生角闪岩相变质,说明它们在前志留纪有着相似的演化历史。即使昆南地体和昆北地体之间在早古生代期间存在洋盆,该洋盆也不会太大。     

南苏鲁超高压变质地体中罗迪尼亚超大陆裂解事件的记录

通过苏鲁超高压变质地体南部不同类型超高压变质岩石的原岩重塑．揭示超高压变质岩的原岩形成于由大陆玄武质岩石、辉长岩、表壳岩和花岗岩组成的被动陆缘拉伸构造环境。中国大陆科学钻探主孔中不同类型超高压变质岩石的锆石SHRIMP U-Pb定年表明。花岗质片麻岩原岩年龄为780～680Ma；榴辉岩、石榴角闪岩的原岩年龄为765～730Ma，副片麻岩中包含了730Ma、680Ma、621Ma和较年轻的继承性碎屑锆石和结晶锆石年龄。结合前人的研究成果表明，苏鲁超高压变质地体南部正片麻岩类和榴辉岩的原岩所代表的花岗岩浆和基性岩浆活动为罗迪尼亚超大陆形成后的新元古代裂解事件的产物．而副片麻岩的原岩为新元古代．古生代时期形成的扬子被动陆缘的沉积-火山表壳盖层，它们与结晶基底一起在240～220Ma期间经历了超高压变质作用。     

柴北缘都兰地区片麻岩的起源及形成时代:锆石U-Pb年代学、REE和Hf同位素的证据

在柴北缘HP-UHP变质带东端的都兰地区,大量正、副片麻岩中包裹有少量榴辉岩和超基性岩。这些片麻岩普遍显示出角闪岩相变质作用特征,但是野外关系和少量副片麻岩中的柯石英包体显示这些片麻岩与榴辉岩一起经历了超高压变质作用。本文通过两个片麻岩样品的锆石U-Pb年代学测定,结合稀土元素和Hf同位素分析,来确定这些片麻岩的原岩起源和变质作用时代。锆石的阴极发光图像分析、稀土元素特征、U-Pb定年结果显示锆石具有明显的核、幔、边结构;岩浆成因的锆石核部获得的不一致线上交点年龄为2322～2365Ma,反映了源区经历过一期古元古代早期的岩浆热事件;岩浆和变质成因的幔部给出的不一致上交点年龄为1830～1837Ma,反映了片麻岩在古元古代晚期经历的变质和深熔作用。锆石幔部获得的不一致线下交点年龄451～465Ma与边部3个近于谐和点的加权平均年龄466Ma在误差范围内基本一致,结合锆石增生的边部较为平坦的重稀土配分型式、低的Th/U值,代表片麻岩发生榴辉岩相变质作用的时代。古元古代早期和晚期年龄的锆石大部分具有负的εHf(t)值,锆石的二阶段Hf模式年龄主要分布于2725～2835Ma之间,说明片麻岩的继承性碎屑锆石源区存在太古代的地壳生长事件,并在古元古代经历过两期再循环和改造事件。都兰地区的部分片麻岩具有与其北侧欧龙布鲁克微陆块中变质基底相似的早期演化历史,但前者在早古生代与所夹的榴辉岩的原岩一起发生了深俯冲作用。     

华北克拉通阜平杂岩新太古代-古元古代多期地质事件及其构造性质

本文收集了阜平杂岩新太古代早期-古元古代晚期基底岩石的岩石地球化学、锆石U-Pb年代学、同位素地球化学和变质作用资料,以期对阜平杂岩早寒武纪演化历史进行初步总结.阜平新太古代早期~2.7 Ga片麻岩原岩为英云闪长岩,具有TTG质片麻岩的地球化学特征;其锆石ε_Hf（t）具有较高的正值（+5.44~+7.50）,单阶段模式年龄为2 745~2 824 Ma,表明新太古代早期为阜平杂岩强烈的地壳生长时期.新太古代晚期片麻岩的时代集中于2 543~2 484 Ma,主要岩石类型为英云闪长岩-奥长花岗岩-花岗闪长岩（TTG）,同时区域内还存在二长花岗岩.TTG质片麻岩的ε_Nd（t）值为-1.64~+0.96,单阶段模式年龄为2.76~3.04 Ga;锆石ε_Hf（t）值为-1.9~+7.91,单阶段和两阶段模式年龄分别为2 546~2 888 Ma和2 548~3 119 Ma.这些TTG岩石主要为新太古代早期岩石的部分熔融,并有少量中太古代地壳物质参与.近于同期具有岛弧性质的辉长岩和变质作用暗示阜平杂岩新太古代晚期可能经历了俯冲和弧-陆或陆-陆碰撞.古元古代中期（2.1~2.0 Ga）阜平地区花岗质岩浆活动强烈.该阶段花岗岩具有A型花岗岩特征,与同期的火山-沉积岩系形成于华北克拉通古元古代中期伸展的陆内裂谷环境中.阜平杂岩中基性麻粒岩包体记录的变质作用时代为1.89~1.85 Ga,并具有顺时针演化的P-T轨迹,其代表了古元古代晚期裂谷闭合的陆内造山过程,表明华北最终克拉通化.      

胶东地块东部变质岩锆石U-Pb定年和氧同位素研究

对胶东地块东部高压-超高压变质岩作了系统的锆石U-Ph定年和矿物氧同位素分析,结果对这些变质岩的原岩性质提供了制约。研究得到:(1)区域花岗片麻岩及岩浆锆石普遍不同程度地亏损~(18)O,3个片庥岩样品中岩浆核锆石U-Pb年龄分别为723±36Ma、738±17Ma和744±63Ma,低δ~(18)O值(-0.42～4.14‰)岩浆核锆石说明其原岩为新元古代低δ~(18)O值岩浆岩,石英-石榴石氧同位素温度及少量印支期变质锆石的出现,指示片麻岩与榴辉岩曾经共同经历了印支期超高压变质作用;(2)花岗片麻岩中的榴辉岩原岩年龄有两种,一种是新元古代,其U-Ph年龄为806±79Ma。另一种是古元古代晚期,其 U-Pb年龄为1838±41Ma。这2个榴辉岩的超高压变质年龄分别为229±3Ma和242±21Ma。多数榴辉岩中的变质增生或变质重结晶锆石也具有低δ~(18)O值特征(0.22～3.4‰),指示在榴辉宕相变质作用之前,这些榴辉岩原岩为低δ~(18)O值蚀变岩或低δ~(18)O值基性岩浆岩;(3)大理岩中榴辉岩变质增生锆石δ~(18)O值高达15.9‰,U-Pb年龄为229±4Ma,指示在榴辉岩相变质作用之前,榴辉岩原岩与大理岩一样具有高δ~(18)O值;(4)斜长角闪岩的原岩U-Pb年龄为1719±18Ma,与同时期榴辉岩原岩一起构成扬子板块北缘新元古代岩浆侵位时的裂谷肩部围岩,在三叠纪大陆碰撞时同样受到变质改造。     

柴北缘夹榴辉岩的片麻岩（片岩）地球化学、Sm-Nd和U-Pb同位素研究——深俯冲的前寒武纪变质基底？

在柴北缘的鱼卡-锡铁山-沙柳河一带,出露夹有榴辉岩透镜体的花岗质片麻岩(正片麻岩)和副片麻岩(片岩)。地球化学和Sm-Nd同位素数据显示副片麻岩(片岩)与正片麻岩具有类似的地球化学成分和一致的Nd模式年龄(1.88～2.18Ga),结合副片麻岩(片岩)局部包在正片麻岩中的野外关系,正片麻岩可能为副片麻岩(片岩)原地熔融作用的产物。U-Pb锆石测定表明熔融作用产生的正片麻岩的岩浆形成时代为952Ma。另外,这些夹榴辉岩的片麻岩(片岩)也与柴北缘北侧不夹榴辉岩的深变质基底片麻岩和中南祁连地块的变质基底片麻岩有相似Sm-Nd同位素特征和近一致Nd模式年龄(1.87～2.26Ga)。表明它们具有明显的亲缘关系,可能来源于具有古元古代晚期地壳形成年龄的同一变质基底。然而,与柴北缘北 侧和祁连地块的深变质基底岩石不同的是,这套含榴辉岩的片麻岩(片岩)明显遭受了早古生代变质作用的影响,正片麻岩锆石U-Pb测定获得的下交点年龄为478±44Ma,与柴北缘地区榴辉岩的变质锆石的年龄在误差范围内一致;而已在都兰地区副片麻岩锆石中柯石英包体的发现也证明了含榴辉岩的片麻岩(片岩)与榴辉岩一样同样经历了UHP变质作用。因此,我们认为柴北缘含榴辉岩的片麻岩虽然具有与相邻变质基底相似的早期演化历史,但在早古生代又与所夹的榴辉岩     

北天山温泉群的地质特征、时代和构造意义

北天山温泉群长期以来被认为是古元古代的变质岩。最新的野外调查和锆石SHRIMP U-Pb 测年结果表明,温泉群可 以划分为三个岩石构造单元：（1）前早新元古代变质火山岩和变质沉积岩,主要包括斜长角闪岩、云母片岩、石英片岩、 黑云母片麻岩、大理岩等;（2）早新元古代混合岩和正片麻岩;（3）早古生代未变质变形的辉长岩和闪长岩。上述三种岩 石组合类型均被后期二云母花岗岩（脉）所侵入。温泉县以南的混合岩和花岗片麻岩中锆石的SHRIMP U-Pb 年龄分别为 926±12 Ma 和907±11 Ma,与天山地区出露的新元古代花岗岩类的时代基本一致。结合前人对花岗片麻岩Nd 同位素组成 的研究,花岗片麻岩应为古老地壳物质部分熔融的产物,而同期的混合岩化作用则是新元古代地壳加厚和部分熔融的直接 地质证据。辉长岩和闪长岩侵入到温泉群花岗片麻岩和斜长角闪岩中,其中闪长岩的锆石SHRIMP U-Pb 年龄为452±7 Ma, 并含有1.1 Ga 和1.4 Ga 的继承锆石。根据前人的研究成果,本区早古生代辉长岩和闪长岩具有岛弧岩浆岩的地球化学特征, 可能与准噶尔-巴尔喀什洋的俯冲作用有关,这一俯冲增生作用最终导致伊犁北部与哈萨克斯坦陆块在志留纪拼贴造山, 并使温泉群前寒武纪变质岩与侵入岩发生变质变形作用。     

东昆仑西段阿确墩地区白沙河岩组锆石U-Pb年龄 ——对前寒武纪基底演化的约束

对东昆仑西段阿确墩地区金水口岩群白沙河岩组片麻岩进行了LA-ICP-MS锆石U-Pb年代学研究.结果显示,片麻岩中锆石的年龄范围为2400～410 Ma,峰值范围为1650～1400 Ma,其中存在少量新元古代(1.0～0.9 Ga)和早古生代(410 Ma)的变质锆石,从而限定了原岩的最早沉积时代,为中元古代末期,指...     

俯冲的大陆岛弧--柴北缘片麻岩的地球化学和同位素证据

柴北缘早古生代高压—超高压变质带的片麻岩分为花岗质片麻岩和副片麻岩 ,花岗质片麻岩的原岩形成于新元古代 (90 0～ 10 0 0 Ma) ,岩石类型为英云闪长岩 -奥长花岗岩 -石英二长岩 -花岗岩 ,非活动性元素的特征类似于岛弧环境形成的花岗岩。副片麻岩的原岩可能为富铝的沉积岩 ,其稀土元素特征类似于 PAAS(后太古宙澳大利亚的平均页岩 )的稀土元素分布 ,非活动性元素的特征与大陆岛弧沉积岩的特征类似。根据花岗质片麻岩与副片麻岩的共生关系结合其地球化学特征推测它们的原岩形成于岛弧环境。鱼卡河花岗质片麻岩的εNd(t) =3.2 (t=1.0 Ga) ,TDM=1.3Ga,表明岩浆源区有大量起源于亏损地幔的初始地壳物质。而落凤坡、锡铁山、沙柳河的花岗质片麻岩与副片麻岩的 Sm - Nd同位素组成类似 ,εNd(t) =- 3.4～ - 7.3(t=1.0 Ga) ,TDM=1.8～ 2 .2 Ga,表明岩浆源区为先存的大陆地壳 ,两类片麻岩地球化学特征的相似性说明岩浆源区的成分类似于变质沉积岩的组成。这项研究说明柴北缘早古生代的深俯冲卷入了大量的大陆岛弧岩石。     

柴达木盆地北缘锡铁山副片麻岩所记录的多期构造热事件

在柴达木盆地北缘中段的锡铁山地区,夹有榴辉岩或退变榴辉岩透镜体的2个副片麻岩样品的锆石被用于SHRIMP U pb测定。2个片麻岩样品具有类似的特征,主要由石榴子石、夕线石、长石、黑云母和石英组成,这些矿物组合形成的变质条件, 0.6～0.9GPa和710～820℃,显示两处片麻岩经历了中压麻粒岩相条件的变质作用。锆石的SHRIMP U-Pb测定显示,2个样品获得近一致的早古生代变质年龄(分别为437Ma±6Ma和441Ma±15Ma),代表早古生代的高温变质作用时代。样品XTS-1还得890Ma±14Ma的年龄,所测定的锆石具有明显的变质作用成因特征,代表了新元古代早期的变质事件,反映了这些副片麻在早古生代造山旋回之前可能还经历了晋宁期的变质作用。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.