新疆十红滩层间氧化带型砂岩铀矿同位素地球化学研究

文章在对吐哈盆地十红滩层间氧化带型砂岩铀矿床地下水和粘土矿物的氢、氧同位素，钙质砂岩的碳、氧同位素，黄铁矿和长石的铅、硫同位素组成进行分析测试的基础上，系统总结了矿床的地球化学特征；认为形成层间氧化带和铀矿化的层间水主要来自大气降水，研究区水与有机烃类气体同位素交换、强烈的蒸发作用和水岩反应是控制地下水和矿物中同位素分馏的主要机制，层间氧化带和铀富集成矿是地下水在低温、常压下对围岩长期作用的结果，钙质砂岩的碳和黄铁矿的硫均主要为生物有机成因，盆地深部的煤成油、气也参与了成矿作用。     

Sulfur Isotopes of Framboidal Pyrite in the Permian-Triassic Boundary Clay at Meishan Section

Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section, while their sulfur isotopes were determined. The majority of framboids is less than 5 μm in diameter, with some large-sized framboids. Also, euhedral gypsums were observed in the boundary clay. The authors suppose that most of the pyrite framboids formed just below the redox boundary and stopped growing after entering the lower water column. The result indicates that it was probably lower dysoxia condition in the temporal ocean. Moreover, the authors also presume that some pyrite was oxidated to sulfates accompanying the fluctuation of redox condition, which would probably be the origin of the negative sulfur isotopes of gypsum and CAS reported before. In addition, sulfur isotope of framboidal pyrite suggests that sulfur is originated from bacterial sulfate reduction in anoxic condition. Therefore, this study confirms that the ocean was widely anoxic during the Permian-Triassic transitional period. However, the redox condition in temporal ocean was probably not stable, with short-term fluctuations.     

广东长坑金银矿床的成矿地球化学——硫同位素研究

长坑矿床金、银矿石硫化物的δ＾３４Ｓ分别以高离散的负值和相对较集中的正值为特征。在主要成矿阶段硫同位素基本达到平衡或近平衡分馏条件下，采用大本模式分析表明，硫同位素分布特征可能与成矿流体物理化学条件不同有关，即形成金矿石的热液偏酸性、ｆｏ２较高，而银矿化期的流体近中性、ｆｏ２较低；此外，伴随硫化物沉淀的储库效应对此也有一定的影响。热液的总硫同位素组成可取为４‰－７‰，应主要来自围岩中的沉积硫。成矿     

湖南沃溪钨-锑-金建造矿床同生成因的微量元素和硫同位素证据

对岩矿石和矿物的微量元素、稀土元素和硫同位素地球化学的研究表明,湖南沃溪钨-锑-金建造矿床系海底同生热水沉积作用的产物。矿石与围岩中微量元素和稀土元素含量的变化关系,反映了一种复杂的热液、海水以及陆源碎屑的联合影响。矿石及其中矿物(石英)的稀土元素配分模式可与许多沉积喷流型(sedex型)块状硫化物矿石及其共生的喷流岩相对比,暗示了两者具有相似的形成机理。矿石的硫同位素资料显示,生物成因硫与热液成因硫(下伏沉积柱中硫化物的溶解和/或部分海水硫酸盐的还原)共同参与了成矿作用过程。     

试论天马山硫金矿床的成矿物质来源

根据矿体的赋存空间、岩矿石组合特征、控矿构造条件等的不同,将矿床分为三个含矿地段,各含矿地段具有不同的矿化类型的矿体。通过野外观察和矿石中微量元素、同位素的分析,探讨了矿床的成矿物质来源。研究表明,金等金属元素主要来源于岩浆,硫有地层和岩浆两个来源,但以后者为主。     

东濮凹陷盐湖相烃源岩有机硫同位素分布特征及其地球化学意义

盐湖相烃源岩单体烃硫同位素分布特征和影响因素研究薄弱.采用气相色谱-电感耦合等离子体质谱,结合色谱/质谱、微量元素以及碳氧同位素技术,对东濮凹陷北部盐湖相烃源岩进行了分析.结果 表明,不同单体含硫化合物的δ34S值有较大差异,以δ34S=25.00‰为界,将烃源岩分成了两类,第一类:δ34S＞25.00‰,主要为卫城地...     

Sulfur geochemistry of Jurassic high-sulfur coals from Egypt

Jurassic high-sulfur coals from the Maghara area in Egypt were analyzed for the abundance and isotopic composition of different forms of sulfur. Analyses indicated that the sulfur occurs in the form of organic, pyrite, and sulfate forms. Pyrite sulfur represents the major fraction, while sulfate sulfur is minor and could be formed during sample preparation for the analyses.The δ³⁴S CDT values of the organic sulfur are positive ranging between 1.0‰ and 13.5‰ with an average of 9.1‰. Pyrite δ³⁴S values are also positive ranging between 1.5‰ and 15.4‰ with an average of 6.6‰. The high δ³⁴S values of the organic sulfur in the Maghara coals suggest a freshwater origin of the organic components of these coals. The lack of correlation between pyrite and organic sulfur isotopes implies different incorporation mechanisms of sulfur. The high-sulfur contents along with the positive and high δ³⁴S values suggest a marine origin of pyrite sulfur and support the geological interpretation of marine invasion after the peat formation that was responsible for the incorporation of the pyrite sulfur.The occurrence of pyrite as euhedral crystals as well as the high and positive δ³⁴S values of the pyrite sulfur indicates the formation of pyrite during diagenesis as a result of marine water invasion of the preexisting peat in a brackish coastal plain environment.     

西天山元古界的热液沉积岩及其与成矿的关系

在西天山中元古界蓟县系首次发现硅质岩、钾长岩和透辉岩等热液沉积岩,其中钾长岩和透辉岩在国内外极为少见。通过对这些热液沉积岩的地球化学特征的综合研究,确定这些热液沉积岩为海底喷气—沉积成因。最后,表文还分析了该热液沉积岩形成的构造背景和沉积环境以及与铜矿化的成因联系。根据金属硫化物的硫同位素组成和微量元素组成特征进一步说明热液沉积岩和金属硫化物的主要物质来自深部地层中循环的同生热液。     

试论天马山硫金矿床的成矿物质来源①

根据矿体的赋存空间、岩矿石组合特征、控矿构造条件等的不同,将矿床分为三个含矿地段,各含矿地段具有不同的矿化类型的矿体。通过野外观察和矿石中微量元素、同位素的分析,探讨了矿床的成矿物质来源。研究表明,金等金属元素主要来源于岩浆,硫有地层和岩浆两个来源,但以后者为主。     

辽东半岛金矿床稳定同位素特征

辽东半岛金矿床与中生代中酸性侵入体有比较密切的空间和时间关系。不同矿床类型，其硫同位素组成有较大差别，但其初始硫同位素均表现为岩浆硫特征（δ＾３４Ｓ∑Ｓ≈１‰），与碳、铅、氢、氧等同位素的研究结果相吻合。说明本区金矿化与岩浆活动具有比较密切的成因联系。     

广西东部地区金矿的控矿作用和稳定同位素地球化学研究

该区金矿产于寒武系水口群浅变质岩系砂页岩内,矿化类型主要有蚀变岩型和石英脉型两大类。矿体主要受近东西向和北东向两组脆-韧性剪切带控制。硫同位素组成特征表明,硫源应以深源同熔岩浆热液为主,部分来自地层;氢、氧同位隶组成特征反映成矿溶液以岩浆水为主,混有少量变质水和大气降水;铅同位索组成特征表明铅源以深源为主,混有少量壳源物质,矿床具多源成矿特点。硫、铅、氢氧等稳定同位素研究结合矿床地质特征表明,该区金矿具多源、多成因及多期次成矿特征,矿床成因主要有岩浆热液、变质热液和复合叠加成矿,而以后者为主。     

冀西石湖金矿床地质地球化学特征研究

通过冀西石湖金矿床的矿区地质特征、矿石的微量元素地球化学特征、稀土元素的地球化学特征、稳定同位素地球化学特征等研究,认为石湖金矿的赋矿层位为阜平群团泊口组,硫、铅来源于地幔,金矿床成矿物质主要来源于矿源层.     

潮控与河控下三角洲平原成煤的岩石学和地球化学特征

从显微煤岩组成特征、不同显微组分中有机硫的含量、伴生元素组成、硫同位素的分布特征等方面对内蒙古乌达矿区潮控下三角洲平原形成的高硫煤 9煤层和河控下三角洲平原形成的低硫煤 13煤层进行了研究。结果表明 ,潮控下三角洲平原形成的煤层较之河控下三角洲平原形成的煤层具有较高的镜质组含量 ;伴生元素中 Na、K、V、Mg等含量偏高 ,而稀土元素含量较低 ,稀土元素的含量与煤中的粘土矿物含量成正比 ;黄铁矿和有机硫同位素都比较轻 ,表明高硫煤中硫的来源主要是海水中细菌还原的硫酸盐。     

冀西石湖金矿床地质地球化学特征

文章根据冀西石湖金矿床的矿区地质特征、矿石的微量元素地球化学特征、稀土元素的地球化学特征、稳定同位素地球化学特征等的研究,认为金矿赋矿层位为阜平群团泊口组。硫、铅同位素分析显示硫、铅来源于地幔,研究表明石湖金矿床成矿物质主要来源于矿源层。     

沉积过程对自生黄铁矿硫同位素的约束

自生黄铁矿是海洋沉积物中还原态硫的主要赋存形式,其形成过程与有机质矿化相关,影响全球的C-S-Fe生物地球化学循环。自生黄铁矿硫同位素分馏主要受微生物硫酸盐还原的控制,但近期的研究成果表明局部沉积环境的改变也可以影响黄铁矿硫同位素的组成,特别是在浅海环境。在浅海非稳态沉积环境内,物理再改造和生物扰动作用,导致硫酸盐还原带内生成的硫化物被再氧化,进而影响黄铁矿的硫同位素值。浅海沉积过程容易受到古气候和海平面变化的影响,引起沉积速率的剧烈波动,导致有机质和活性铁输入的不稳定,进而影响成岩系统的开放性和硫酸盐还原速率,最终影响黄铁矿的硫同位素值。另外,沉积速率的改变还影响硫酸盐—甲烷转换带的迁移,造成有机质和甲烷厌氧氧化硫酸盐还原的相互转化,产生不同的硫同位素信号。东海内陆架泥质区为研究沉积过程对自生黄铁矿的形成及其硫同位素组成的约束机制提供了很好的研究材料。该区域有很好的沉积学研究基础,自生黄铁矿丰富、并且个别层位有生物气（甲烷为主）存在,是研究边缘海C-S-Fe循环的理想场所。     

Water-rock-tailings interactions and sources of sulfur and metals in the subtropical mining region of Taxco,Guerrero (southern Mexico): A multi-isotopic approach

Multi-isotope (H, O, S, Sr, Pb) systems coupled with conventional (major and trace element) hydrogeochemical analysis were applied to determine the origin of water, to model water-rock-tailings interactions and for source apportionment of sulfur and associated toxic metals in the mining region of Taxco, Guerrero in southern Mexico. Oxygen and H isotopes indicate that meteoric water in the zone is rainwater undergoing varying degrees of isotopic fractionation by atmospheric evaporation whereas Sr isotopes trace the interaction of pristine water from volcanics of the regional recharge zone and subsequently flowing through sandstone and shale to spring points. Leachates form from two distinctive sources (spring water and surface water) having differential interactions with bedrocks prior to entering the tailings. Compared to pristine water, leachates are enriched in sulfate, metals (e.g. Fe, Mn, Pb and Zn) and metalloids (e.g. As). The sulfur isotopic composition of ore-sulfides, leachates, secondary precipitates, regional surface water and hypogenic sulfates is described in terms of a two-component mixing model with shale of Mexcala and limestone of Morelos formations representing the light and heavy end-members, respectively, whereas Sr isotopic composition is bracketed combining three lithogenic (Mexcala/Morelos, Tilzapotla and Taxco Schist) sources. Finally, leachates have a mixture of lead from ore-sulfides and Taxco Schist Formation (Family I) or from ore-sulfides alone (Family II). The application of multiple environmental isotopic techniques is an outstanding tool for elucidating complex interactions of water with bedrocks and tailings and for determining the source of sulfur and toxic metal from mining and other metal polluted environments.     

太行山南段北洺河铁矿S、Pb同位素组成及其对成矿物质来源的示踪

北洺河铁矿是太行山南段邯邢地区主要铁矿床之一,属于二长闪长岩侵入中奥陶统石灰岩形成的典型矽卡岩型铁矿床。针对北洺河矿区矽卡岩和磁铁矿矿石进行了S、Pb同位素分析研究,并结合前人对岩体S、Pb同位素分析结果进行了成矿物质来源探讨。结果表明,北洺河铁矿成矿物质来源复杂,其中硫同位素δ34 S变化范围为12.2‰～16.5‰,明显偏离陨石硫范围,说明成矿物质来源与成矿围岩有关。特别是深部成矿流体在自下而上运移过程中,受围岩石灰岩地层中膏盐层的混染,体现出混合硫来源特点。铅同位素组成中,206Pb/204Pb=17.840～18.793,平均值为18.419;207Pb/204Pb=15.46～15.62,平均值为15.56;208Pb/204 Pb=37.927～39.301,平均值为38.730,表明铅的来源以下地壳铅源为主,兼混有少量幔源铅。     

新疆托里萨Ⅰ金矿床的地质特征及成因研究

新疆托里萨I金矿床产于托里蛇纹岩套的超镁铁岩相内,与超镁铁岩的蚀变交代作用有关.矿床地球化学研究表明该矿床的形成与海底热泉活动有关,是一种新的金矿床类型.     

On the genesis of dabaoshan polymetallic deposit in Guangdong Province,China

The Dabaoshan deposit is a polymetallic deposit containing Mo, W, Cu, Pb and Zn. There is much controversy about the genesis of the deposit. In the early 1960s, it was considered as a meso-hypothermal deposit resulting from interstratified replacement. Recently, some other genetic models have been put forward, e.g. the strata-bound deposit model. Studies of the contents of characteristic elements in pyrite and sphalerite, the compositions of sulfur and lead isotopes, zoning of primary halos, homogenization temperatures of fluid inclusions in minerals from the deposit and element abundances in the strata led to a conclusion that the deposit is of post-magmatic hydrothermal origin.     

南秦岭柞水-山阳矿集区王家坪金矿床地质特征及矿床成因探讨

王家坪矿床位于南秦岭柞水-山阳矿集区东部,金矿体主要产于上泥盆统星红铺组沉积地层中;金属矿物以黄铁矿为主,与金成矿关系密切的矿物为黄铁矿和雌黄.笔者利用LA-ICPMS和LA-MC-ICPMS对成矿期不同阶段硫化物进行微量元素及硫同位素研究,结果表明,该矿床成矿中阶段黄铁矿Co/Ni值为0.003～1.1,均小于1,暗...