Homogenization of carbonate-bearing microinclusions in diamond at <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> parameters of the upper mantle

The staged high-pressure annealing of natural cubic diamonds with numerous melt microinclusions from the Internatsional’naya kimberlite pipe was studied experimentally. The results mainly show that the carbonate phases, the daughter phases in partially crystallized microinclusions in diamonds, may undergo phase transformations under the mantle P–T conditions. Most likely, partial melting and further dissolution of dolomite in the carbonate–silicate melt (homogenization of inclusions) occur in inclusions. The experimental data on the staged high-pressure annealing of diamonds with melt microinclusions allow us to estimate the temperature of their homogenization as 1400–1500°C. Thus, cubic diamonds from the Internatsional’naya pipe could have been formed under quite high temperatures corresponding to the lithosphere/asthenosphere boundary. However, it should be noted that the effect of selective capture of inclusions with partial loss of volatiles in relation to the composition of the crystallization medium is not excluded during the growth. This may increase the temperature of their homogenization significantly between 1400 and 1500°C.     

Deciphering the geologic memory of a Permian conglomerate of the Southern Alps by pebble <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> estimates

The volcano–clastic sequence of Trompia Valley, which caps the Tre Valli Bresciane Variscan basement (TVB), comprises the Dosso dei Galli Conglomerate (DGC), the oldest deposit containing up to metre-sized metamorphic pebbles. This Lower Permian formation of the Trompia Basin was fed by the erosion products of the Variscan chain. We used microstructural and mineral chemical data on metamorphic pebbles of the DGC to infer a quantitative tectono-thermal evolution of the eroded pre-Permian basement and to compare them with those of TVB and the surrounding Southalpine basement units (tectono-metamorphic units = TMUs). Metapelitic and metaintrusive pebbles record a polyphase metamorphism with two metamorphic re-equilibrations: the first under epidote amphibolite facies (M1, ) and the second under greenschist facies (M2) conditions. Rock types and metamorphic data largely match those of TVB basement unit. The structural and metamorphic records in the pebbles are pre-Permian, and the conglomerate matrix is non-metamorphic. The DGC deposition age (283 ± 1–280.5 ± 2 Ma) constrains the minimal exhumation age of its basement source. The lack of staurolite bearing assemblages in metamorphic pebbles suggests that the DGC basement source was already exhumed to shallow structural levels (greenschist facies conditions) before the thermal equilibration consequent upon continental crust thickening induced by the Variscan collision.     

First Data on the Age and <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> Formation Conditions of Zones of Low-Angle Dip Schistosity of the Belomorian Mobile Belt

The low-angle dip schistosity zones of the Belomorian mobile belt of northern Karelia are zones of plastic flow of thrust origin. They were formed from 1.85 to 1.90 Ga: 1879 ± 21 Ma according to ⁴⁰Ar/³⁹Ar for amphibole from amphibolites and 1857 ± 13 Ma according to the Sm–Nd isochron in amphibolites. The P–T parameters of rock metamorphism in low-angle dip schistosity zones correspond to the boundary of amphibolite and granulite facies of metamorphism: T = 640–765°C, rarely rising to 826°C; P = 8.0–11.7 kbar. The hypothesis of the two-stage Paleoproterozoic metamorphism of rocks of the Belomorian mobile belt was introduced.     

The transformation features of impurity defects in natural diamonds of various habits under high <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> conditions

The results of the investigations of the transformation of impurity defects in natural diamonds of various habits at the stage of high-temperature annealing at P = 6 GPa and T = 2200°C are presented. The studies conducted allowed us to ascertain that the transformations of Aand B-defects in diamonds of octahedral and cubic habits follow general regularities. This fact shows that most of the diamonds of cubic habit with low degree of aggregation of nitrogen centers were not really annealed over a long-term interval. Unlike octahedral diamonds, those of cubic habit are characterized by a pronounced increase in the peak of H-containing defects (3107 cm^–1) after annealing.     

<Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">V</Emphasis>–<Emphasis Type="Italic">T</Emphasis> equation of state of CaAl<Subscript>4</Subscript>Si<Subscript>2</Subscript>O<Subscript>11</Subscript> CAS phase

The thermoelastic parameters of the CAS phase (CaAl₄Si₂O₁₁) were examined by in situ high-pressure (up to 23.7 GPa) and high-temperature (up to 2,100 K) synchrotron X-ray diffraction, using a Kawai-type multi-anvil press. P–V data at room temperature fitted to a third-order Birch–Murnaghan equation of state (BM EOS) yielded: V _0,300 = 324.2 ± 0.2 Å³ and K _0,300 = 164 ± 6 GPa for K′ _0,300 = 6.2 ± 0.8. With K′ _0,300 fixed to 4.0, we obtained: V _0,300 = 324.0 ± 0.1 Å³ and K _0,300 = 180 ± 1 GPa. Fitting our P–V–T data with a modified high-temperature BM EOS, we obtained: V _0,300 = 324.2 ± 0.1 Å³, K _0,300 = 171 ± 5 GPa, K′ _0,300 = 5.1 ± 0.6 (?K _0,T /?T) _P  = ?0.023 ± 0.006 GPa K^?1, and α_0,T  = 3.09 ± 0.25 × 10^?5 K^?1. Using the equation of state parameters of the CAS phase determined in the present study, we calculated a density profile of a hypothetical continental crust that would contain ~10 vol% of CaAl₄Si₂O₁₁. Because of the higher density compared with the coexisting minerals, the CAS phase is expected to be a plunging agent for continental crust subducted in the transition zone. On the other hand, because of the lower density compared with lower mantle minerals, the CAS phase is expected to remain buoyant in the lowermost part of the transition zone.     

Gently sloping shear zones in the Belomorian Mobile Belt: Geology,structure, and <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> parameters

The Belomorian Mobile Belt (BMB) in northern Karelia mostly consists of gently sloping shear zones, whose gneisses and migmatized amphibolites and blastomylonites are typically thinly banded, with their banding consistently dipping north- and northeastward. These gently sloping shear zones were not affected by folding after they were produced and are not cut by Paleoproterozoic metabasite dikes. Intrusive metabasites in the gently sloping shear zones make up relatively small (usually <5 m) equant or elongate bodies and occur as fragments of larger bodies. These fragments are often concentrated in stripes. Metabasites in the gently sloping shear zone are sometimes also found as lenses and tabular bodies of relatively small thickness, which are conformable with the foliation of the host rocks. The gently sloping shear zones cut across older domains of more complicated structure, which suggests that these zones are gently sloping ductile shear zones. Along these zones, the nappes were thrust south- and southwestward, and this process was the last in the origin of major structural features of BMB when the Paleoproterozoic Lapland–Kola orogen was formed. Practically identical age values were obtained for the gently sloping shear zone in the two widely separated Engonozero and Chupa segments of BMB: 1879 ± 21 Ma (⁴⁰Ar/³⁹Ar amphibole age of amphibolite whose protolith was mafic rock) and 1857 ± 13 Ma (Sm–Nd mineral isochron age of garnet amphibolites after gabbronorite). The P–T metamorphic parameters in these gently sloping shear zones are remarkably different from the metamorphic parameters outside these zones: the pressure is 3–4 kbar lower and the temperature is 60–100°C lower. Thrusting-related decompression triggered the transition from the older high-pressure episode of Paleoproterozoic metamorphism to a younger syn-thrusting higher temperature metamorphic episode. The peak metamorphic parameters corresponding to the boundary between the amphibolite and granulite facies were reached only in the central portions of the shear zones: T= 680–760°C, P = 8.0–11.9 kbar. In areas of the most intense migmatization, temperature estimates in the central portions of the shear are as high as 810–830°C. The marginal portions of the shear zones were formed at lower temperatures of 610–630°C. The temperature heterogeneous and rock heating in the gently sloping shear zones may have resulted from flows of high-temperature metamorphic fluid that were focused to the central portions of the zones.     

Analysis of MOST light curves of the active stars <Emphasis Type="Italic">ɛ</Emphasis> Eri AND <Emphasis Type="Italic">κ</Emphasis> Cet

We have analyzed light curves from the MOST satellite for the two active dwarfs ? Eri and κ Cet. Our maps of the stellar surface-temperature inhomogeneities were obtained with no a priori assumptions about the shape, configuration, and number of spots. We find variations of the surface-temperature inhomogeneities with time, also on time scales about equal to their rotation periods. We consider a model of a spotted star with two types of surface inhomogeneities—spots and related plage fields—and demonstrate that the best agreement between the theoretical and observed light curves is achieved for small ratios of the plage-field area to the area of cool spots. This conclusion indicates that long-term brightness variations of stars younger than the Sun are mainly due to variable spots on their surfaces, while the contribution from plage fields becomes more significant for older stars.     

Sapphirine-Bearing Ultrahigh-Temperature Granulites of the Anabar Shield: Chemical Composition,U–Pb Zircon Ages,and <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> Conditions of Metamorphism

The results of thermobarometry yielded the P–T parameters of formation and evolution of sapphirine- bearing granulites in the Anabar shield with peak values of UHT metamorphism in the range of T = 920–1000°C at P = 9–11 kbar. Isotope–geochronological data indicate a polymetamorphic evolution of these rocks. Detrital zircon cores in the center of crystals yielded ages of 3.36, 2.75, 2.6, and 2.5 Ga. Later, superimposed metamorphic transformations of the detrital zircon formed rims dated to 2.4, 2.3, 2.2, and 1.83 Ga. A potential provenance source of the detrital zircons could be hypersthene plagiogneisses and metabasics of the Daldyn Group with a premetamorphic age no less than 3.32 Ga and products of their metamorphism of about 2.7 Ga old.     

Experimental studies of the <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis>–H<Subscript>2</Subscript>O near-liquidus phase relations of basaltic andesite from North Sister Volcano,High Oregon Cascades: constraints on lower-crustal mineral assemblages

We have mapped the mineralogy onto the H₂O-undersaturated liquidus surface of basaltic andesite from North Sister Volcano to constrain the crystalline assemblage with which, and P–T–H₂O conditions at which, the melt last equilibrated before erupting. Combining our high pressure experimental results with examples of tectonically exposed lower arc crust, geophysical constraints, trace element geochemistry, and melt inclusion volatile contents, we conclude that an anhydrous, augite-rich gabbro at ∼12 kbar and ∼1,175°C is the most probable lithology with which North Sister basaltic andesite with ∼3.5 wt% H₂O last equilibrated before erupting. We speculate that reaction between this gabbro and primitive mantle-derived precursor melts buffered the compositions of magmas erupted from this volcano resulting in their remarkably limited compositional range.     

Bearing capacity of strip footings on <Emphasis Type="Italic">c</Emphasis>–<Emphasis Type="Italic">φ</Emphasis> soils with square voids

The presence of underground voids has an adverse influence on the performance of shallow foundations. In this study, the bearing capacity and failure mechanism of footings placed on cohesive-frictional soils with voids are evaluated using discontinuity layout optimization. By introducing a reduction coefficient, a set of design charts that can be directly applied to the classical bearing capacity formulation is presented. The results indicate that the undrained bearing capacity with voids is sensitive to soil weight and cohesion, as both the bearing capacity and stability issues exist in the problem. The failure mechanism is directly related to a variety of soil properties, the locations of single voids, and the horizontal distance between two voids. The presence of voids has a more dominant effect on c–φ soils compared to that on undrained soil. An interpretation of the critical and adverse locations for single-void and dual-void cases with various soil strengths is presented.     

Bearing capacity factor, <Emphasis Type="Italic">N</Emphasis><Subscript><Emphasis Type="Italic">γ</Emphasis></Subscript>, for unsaturated soils by ZEL method

Bearing capacity of foundations is often determined for saturated state of the soil, regarding its simple and conservative results. This assumption, however, results in very uneconomic and overconservative design for a wide range of climates in the world. In this paper, plasticity equations were employed and extended for unsaturated soils to establish a theoretical approach to investigate the bearing capacity of unsaturated soils. It is achieved by combining the concept of effective stress and plasticity equations in terms of effective stress in unsaturated soils. The advantage of Bishop’s (4) effective stress concept was employed to simplify the equations. The equations were then transformed onto the zero extension lines directions to generalize this method for both associative and non-associative problems by which both stress and velocity field can be determined for unsaturated soils. A computer code was also developed to solve the relatively complex plasticity equations for a wide range of soil friction angles and matric suctions to compute the corresponding bearing capacity factor, N _γ , for strip foundations with smooth and rough base. This factor seems to be one of the major contributors in the bearing capacity of shallow foundations. The results have been presented in design charts and theoretical equations.     

Immobilized <Emphasis Type="Italic">β</Emphasis>-lactamase on Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> magnetic nanoparticles for degradation of <Emphasis Type="Italic">β</Emphasis>-lactam antibiotics in wastewater

The emergence of antibiotics residues in pharmaceutical industrial wastewater has been a significant environment problem. However, current methods of treating antibiotic-polluted wastewater are inefficient, of high cost and time-consuming. In this study, highly effective enzymatic Fe₃O₄ magnetic nanoparticles were developed, which is extremely simple and can degrade antibiotics in a fast manner at a low cost. β-Lactamase, a representative enzyme for β-lactam antibiotic degradation, was covalently immobilized on the surface of magnetic nanoparticles modified with amino groups by a simple cross-linking process. The immobilized β-lactamase displayed a wider pH and temperature range for penicillin G degradation than the free enzyme. Meanwhile, the thermostability and storage stability of the immobilized β-lactamase were improved. Fifty milligrams magnetic nanoparticles immobilized with β-lactamase can thoroughly degrade 100 mL penicillin G (5–50 mg L^?1) within 5 min. Even if the β-lactamase immobilized on the nanoparticles was reused 35 times in the 5 mg L^?1 penicillin G solution, it still kept more than 95% degradation efficiency. These suggest that magnetic nanoparticles immobilized with β-lactamase have a sufficient capacity for degrading antibiotics in wastewater and will serve as a practical and economical solution to antibiotic pollution in pharmaceutical industrial wastewater treatment.     

Faunistic Substantiation of Stratigraphic Occurrence of the <Emphasis Type="Italic">Pleuromeia</Emphasis> (<Emphasis Type="Italic">Isoëtopsida</Emphasis>) Plant in the Triassic of Gorny Mangyshlak,Republic of Kazakhstan

Joint burial places of mollusks and Pleuromeia plants allow specification of a period of stratigraphic occurrence of this genus in the west of the Republic of Kazakhstan within the Gorny Mangyshlak. Two places of occurrences of pleuromeias were found in marine Triassic rocks: one in the Karadzhatyk Formation of the northern slope of the Karatauchik Range close to the Dolnapa well, where the fossils of Pleuromeia sternbergii (Münster) Corda plants are associated with ammonoid shells, and the other one in the Karaduan Formation of the southern slope of Mt. Karashek, where this plant was found along with bivalves and gastropods. The mollusk fauna from both occurrences indicates that the Mangyshlak pleuromeias occurred from the late Olenekian Substage to Anisian Stage.     

Intrusion of shoshonitic magmas at shallow crustal depth: <Emphasis Type="Italic">T</Emphasis>–<Emphasis Type="Italic">P</Emphasis> path,H<Subscript>2</Subscript>O estimates,and AFC modeling of the Middle Triassic Predazzo Intrusive Complex (Southern Alps,Italy)

The multi-pulse shoshonitic Predazzo intrusive complex represents an ideal igneous laboratory for investigating the chemical and physical conditions of magma emplacement in a crustal context, since numerical models can be constrained by field evidence. It constitutes the most intriguing remnant of the Middle Triassic magmatic systems of the Dolomitic Area (Southern Alps), preserved by the Alpine tectonics. Predazzo Intrusive Complex comprises silica saturated (pyroxenites/gabbros to syenites), silica undersaturated (gabbros to syenites), and silica oversaturated (granites and syenogranites) rock suites. In this paper, we modeled its emplacement and evolution with a multiple thermo-/oxy-barometric, hygrometric, and EC-AFC approach. At odds with what proposed in literature but according to the field evidence, the emplacement of the Predazzo Intrusive Complex occurred at shallow depth (<?6 km). In this context, the different pulses differed slightly in bulk water content, but shared a common thermal regime, with temperatures between 1000 and 1100 °C and ~?600 °C at low-to-moderate oxidizing conditions (? 0.1 to +?0.7 ΔFMQ). The interaction between the intrusion and the shallow crustal rocks was minimal, with Sr and Nd isotopic compositions indicating an average of 5–6% assimilation of crust. A thermo- and oxy-barometric comparison with the nearby Mt. Monzoni also enabled to speculate about the solidification time of the intrusion, which we infer took place over about 700 ka.     

HeII <Emphasis Type="Italic">λ</Emphasis>304 emission above sunspot umbrae

Observations of sunspot umbrae in the HeII λ304 Å and HeI λ10830 Å lines are analyzed and compared. Spectral observations in the HeI λ10830 line obtained on the Large Non-Eclipse Solar Coronograph of the Sayan Solar Observatory are used, together with HeII λ304 data obtained with the SOHO/EIT and CORONAS-f spacecraft. The contrast in the HeII λ304 line was chosen as an indicator of the UV flux. The dependences of the contrast in the HeII λ304 line and the parameters of the HeI λ10830 IR triplet on the sunspot area are obtained. The sunspot areas were determined using white-light images. A division of the dependences of the parameters of the HeI λ10830 and HeII λ304 lines on the sunspot area into two branches can be distinguished for leading and trailing sunspots. Possible origins of this behavior of the line parameters are discussed.     

Metamorphic reactions in dry and aluminous granulites: a Perple_X <Emphasis Type="Italic">P–T</Emphasis> pseudosection analysis of the influence of effective reaction volume

In high-Mg, Al metapelites, monophase sapphirine corona occur around spinel–corundum aggregates in monomineralic cordierite layers, and bi-phase orthopyroxene–sillimanite aggregates replace locally warped sapphirine in polygonized cordierite aggregates. P–T phase topologies computed (Perple_X software) using compositions of cordierite-rich layers that host the reaction textures did not match the assemblages for the discontinuous reactions spinel + corundum + cordierite → sapphirine and sapphirine + cordierite → orthopyroxene + sillimanite. Instead, the reaction assemblages were reproduced using P–T pseudosection analysis for micro-domain reaction volumes estimated from compositions of product phases in the volume proportion they occur. The results are consistent with known phase relations deduced using Schreinmakers P–T grids. Apparently, the compositions of cordierite-rich layers that hosted the reaction textures were inadequate chemical proxies for determining P–T–X relations of phase-boundary controlled reactions influenced by compositions of the nearest-neighbor minerals in the proportion they react (effective composition), and not in the proportion they existed in the layer/bulk rock. In other words, P–T–X phase topologies and reconstructed P–T paths in dry and aluminous rocks may be best understood by thermodynamic modeling of reactions using effective reaction volume compositions rather than the bulk composition of the rock or the mineralogical layer that host the reaction textures.     

Hydrodynamical modeling of mass transfer in the close binary system <Emphasis Type="Italic">β</Emphasis> Lyr

We present results of two-dimensional hydrodynamical simulations of mass transfer in the close binary system β Lyr for various radii of the accreting star and coefficients describing the interaction of the gaseous flow and the main component (primary). We take the stellar wind of the donor star into account and consider various assumptions about the radiative cooling of the gaseous flow. Our calculations show that the initial radius of the flow corresponding to our adopted mass-transfer rate through the inner Lagrange point (L₁) of (1–4) × 10^?5M_⊙/yr is large: 0.22–0.29 (in units of the orbital separation). In all the models, the secondary loses mass through both the inner and outer (L₁ and L₂) Lagrange points, which makes the mass transfer in the system nonconservative. Calculations for various values of the primary radius show a strong dependence on the coefficient fv that models the flow-primary interaction. When the radius of the primary is 0.5, there is a strong interaction between the gas flow from L1 and the flow reflected from the primary surface. For other values of the primary radius (0.1 and 0.2), the flow does not interact directly with the primary. The flow passes close to the primary and forms an accretion disk whose size is comparable to that of the Roche lobe and a dense circum-binary envelope surrounding both the disk and the binary components. The density in the disk varies from 10¹² to 10¹⁴ cm^?3, and is 10¹⁰–10¹² cm^?3 in the circum-binary envelope. The temperature in the accretion disk ranges from 30000 to 120000 K, while that in the circum-binary envelope is 4000–18000 K. When radiative cooling is taken into account explicitly, the calculations reveal the presence of a spiral shock in the accretion disk. The stellar wind blowing from the secondary strongly interacts with the accretion disk, circum-binary envelope, and flow from L₂. When radiative cooling is taken into account explicitly, this wind disrupts the accretion disk.     

<Emphasis Type="Italic">BVRI</Emphasis>Hα CCD photometry of the spiral galaxy NGC 3184

We have carried out BVRIHα CCD surface photometry of the spiral galaxy with active star formation NGC 3184 using the 1-m telescope of the Special Astrophysical Observatory. B and Hα data from the ING Archive (La Palma Observatory) were also used. We consider the structure and radial brightness distribution of the galaxy. Stellar populations in different regions of the galaxy are analyzed using two-color diagrams. We have identified and studied star-forming regions in NGC 3184 and estimated their ages based on evolutionary modeling.     

Experimental study of eclogitization and melting of basic rocks at <Emphasis Type="Italic">Р</Emphasis> = 4 GPa and <Emphasis Type="Italic">Т</Emphasis> = 1200–1400°С

Experimental study of gabbro–norite eclogitization and melting at P = 4 GPa has made it possible to reveal the effective influence of fluid and temperature on the phase relationships. The melt composition varies from andesite–dacite in “dry conditions” to phonolite and carbonate in the presence of a fluid. The Grt-containing melting curve is replaced by the Cpx-containing liquidus as the temperature changes or a fluid is added. Hence, the possible presence of “garnetitite” and “clinopyroxenite” in the upper mantle was proved experimentally. The ultimate pressure of the spinel facies at the depth of the eclogite upper mantle is controlled by the stability of Cht ≤ 4 GPa. The revealed similarity of the spectra of REE-adakite, tonalite–trondhjemite–granodiorite (TTG), and melts formed under the partial melting of eclogitized gabbro–norite does not contradict the existing ideas of the eclogite source of the TTG rocks. Wide variations in the interphase microelement distribution factors D (Grt, Cpx)/L are indicative of effective fractionation of the microelements in the course of eclogite melting and differentiation.