Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

Effects of Temperature and Humidity upon the Entrainment of Sedimentary Particles by Wind

Aeolian transport of sedimentary particles is a well-recognized phenomenon in cold regions, but the effect of low temperature (T) and specific humidity (q) upon particle entrainment has not previously been investigated. This study reports on wind-tunnel experiments (-12 °C T 32 °C, and 1 g kg^-1 q 10 g kg^-1) that suggest the aerodynamic drag required to entrain sand sized particles can be 30% lower in cold or high latitude settings, as compared to hot deserts. For any given regional wind velocity, this effect will increase the wind strength index and thereby the proportion of time a surface is active at low temperature.The influence of air temperature and humidity upon the threshold for particle motion is determined by three physical processes: (1) The effect of air viscosity and density on the fluid drag force acting to dislodge sedimentary particles; (2) the effect of viscosity on the turbulent wake shed from these particles, and the frequency and magnitude of burst-sweep events; and (3) the development of inter-particle cohesion via adsorbed water. This study considers the relative importance of each of these processes. The threshold friction velocity model of Shao and Lu is revised to incorporate the inter-particle force associated with hygroscopic water. It is found to perform well when tested against the experimental data obtained for this study.     

The behaviour of aerosol optical depth during clear summer days in Athens,Greece

Summary The integral aerosol optical depths (k ) at the hour of 08:20 Local Standard Time (LST), are compared with those calculated previously at 11:20 and 14:20 LST, for clear days during summer in Athens over the period 1962–1988. The mean values at 08:20 LST were consistently lower than the values at 11:20 and 14:20 LST. The influence of the vertical wind profile on the values ofk was also investigated. A comparison was made of the wind profiles at 02:00 and 14:00 LST, for days in which the 11:20 and 14:20 LST values ofk were 0.200 andk 0.350, respectively. The corresponding bulk wind shear s was also found for the period 1980–1988. The most significant results occurred with the first category of days. The resultant wind velocities from the surface to the 900 hPa level, in each hour were higher by 2–4 m·s^–1 with respect to the corresponding values for the second category. At 02:00 LST the bulk wind shear showed a considerable difference (1.8) between the two categories of days in the surface to 700 hPa layer at 02:00 LST. Finally, the associated weather conditions that appear to initiate a period of low values ofk (k 0.200) at 11:20 and 14:20 LST were examined for the period 1980–1988. Fifteen such cases were identified and it was found that they all occurred after the passage of weak cold fronts.With 6 Figures     

Some meteorological aspects of air pollution in Athens,Greece

Summary The purpose of this paper is to examine some meteorological aspects of air pollution in the Athens area, Greece. Over recent years much attention has been directed to the importance of spells of weather in providing conditions that give rise to inversion of temperature at or near ground level, and hence to risks of severe incidents of air pollution. So, emphasis is given to the importance of anticyclonic conditions, associated with pronounced stability during ground level radiation inversions, when the same sampling sites show high concentration of both SO₂ and smoke. Fifteen years of surface and radiosonde data obtained from Hellinikon Airport Athens are used for a climatological base. The meteorology of high concentration episodes has also been examined and the synoptic characteristics for the onset and end of such episodes have been identified. Finally, trends of pollution episodes and calculation of an air stagnation index for Athens have been obtained, which give a predicting indication about the occurrence of high pollution concentration.With 11 Figures     

Influence of foehn winds on air temperature and humdity in the Polish Carpathians

Summary The present study concerns an attempt to determine the influence of foehn winds on air temperature and humidity in the Polish Carpathians. This was carried out using the mean monthly temperature and relative humidity obtained from a number of synoptic stations. Periods with classical foehn conditions and the whole period (1966–1985) of record were analysed.With 3 Figures     

Monoterpene concentrations in and above a forest of scots pine

Diurnal and vertical ambient air measurements of the monoterpenes have been made in and above a Scots pine (Pinus sylvestris) forest of central Sweden, within the boreal northern coniferous biome. Sampling was done with Tenax TA, and analysis by GC and ion trap detection. Daytime mixing ratios were on the order of tenths of a ppbv from the forest floor to the top of the forest, and a factor of 2 or 3 lower above the forest. Mixing ratios at night were at the ppbv level, highest near the forest floor and the crown, and decreased with height above the forest. The highest total concentration observed was 8 ppbv inside the forest at 3 am (GMT). The average terpene composition was 3-carene 32%, -pinene 29%, limonene 18%, -pinene 10%, -phellandrene 7%, camphene 5%, and sabinene at less than 2%. The 3-carene/-pinene ratio varied with wind direction and speed, relative humidity, and wet/dry vegetation, but not with ozone or NO₂ concentration, solar radiation, or temperature. Variations in the observed terpene composition at the sampling site are mainly caused by the influence of other vegetation in the vicinity of the site. It would seem that wet Scots pine emits more 3-carene relative to -pinene than does dry pine.     

Local foehn effects in the upper Isar Valley, part 1: Observations

Summary An unusually strong nocturnal downvalley wind can be regularly observed in the upper Isar Valley close to Mittenwald (Bavarian Alps) when a high-pressure system is located over Central Europe or when ambient southerly winds are present. Due to the structure of the local topography, this downvalley wind has foehn-like properties in the sense that the breakthrough of the flow into the valley is characterized by a strong increase in temperature and a decrease in relative humidity. Therefore the author called this flow Minifoehn. In fact, wind speeds are low in comparison to deep foehn, but gusts may reach values up to 20ms^–1, even under the influence of high pressure systems with weak atmospheric pressure gradients. To investigate the Minifoehn, surface stations have been installed for collecting temperature, humidity, wind and pressure data. Measurements have shown that the Minifoehn represents the upper part of one of the drainage currents which flows over a mountain ridge into the valley at Mittenwald. Nocturnally cooled air drains from a plateau south of Mittenwald through different valleys which merge again near Mittenwald. It seems that the forcing of the nocturnal currents is dominated by the temperature difference between this plateau and the free atmosphere above Mittenwald at the same level. Strong temperature differences are found during clear winter nights and in case of subsidence inversions. Moreover, the appearance of the Minifoehn in autumn and winter is so frequent that we even may find a climatic effect: the upper Isar Valley is usually free of fog during these seasons and nocturnal temperatures are often considerably higher than in other Bavarian Alpine valleys at comparable altitude.     

Stable Isotope Ratios: Hurricane Olivia

The oxygen and hydrogen isotopic compositions of rains from HurricaneOlivia (1994) in the eastern Pacific were measured. The rains werecollected on 24 and 25 September during airplane flights conducted at anelevation of 3 km. Hurricane Olivia peaked in intensity to a category-4storm between the two dates. Isotope ratios of rains from HurricaneOlivia were markedly lower ( ¹⁸O = –13.9to –28.8) than that of rain collected from a thunderstormat an elevation of 2.3 km outside the influence of Olivia (¹⁸O = –3.8). A distinct decrease in isotoperatios from the first day to the next ( ¹⁸O =–18.4 to –21.9) in Hurricane Olivia wasattributed to decreased updraft velocities and outflow aloft. Thisshifted the isotopic water mass balance so that fewer hydrometeors werelifted and more ice descended to flight level. A decrease in the averagedeuterium excess from the first day to the next (d = 15.5 to 7.1)was attributed to an increase in the relative humidity of the watervapor `source' area. We hypothesize that the `source' region for therain was in the boundary layer near the storm center and that becausethe hurricane was at peak intensity prior to the second day the relative humidity was higher.     

The validation of various schemes for parameterizing evaporation from bare soil for use in meteorological models: A numerical study using in situ data

Parameterization of evaporation from a non-plant-covered surface is very important in the hierarchy strategy of modelling land surface processes. One of the representations frequently used in its computation is the resistance formulation. The performance of the evaporation schemes using the , , and their combination resistance approaches to parameterize evaporation from bare soil surfaces is discussed. For that purpose, the nine schemes, based on a different dependence of and on volumetric soil moisture content and its saturated value, are used.The tests of performances of the considered schemes are based on time integrations by the land surface module (BARESOIL) using observed data. The 23 data sets at a bare surface experimental site in Rimski anevi, Yugoslavia on chernozem soil, were used for the resistance algorithm evaluation. The quality of the schemes was compared with the observed values of the latent heat flux using several statistical parameters.     

Effect of land management on ecosystem carbon fluxes at a subalpine grassland site in the Swiss Alps

Summary The influence of agricultural management on the CO₂ budget of a typical subalpine grassland was investigated at the Swiss CARBOMONT site at Rigi-Seebodenalp (1025m a.s.l.) in Central Switzerland. Eddy covariance flux measurements obtained during the first growing season from the mid of spring until the first snow fall (17 Mai to 25 September 2002) are reported. With respect to the 10-year average 1992–2001, we found that this growing season had started 10 days earlier than normal, but was close to average temperature with above-normal precipitation (100–255% depending on month). Using a footprint model we found that a simple approach using wind direction sectors was adequate to classify our CO₂ fluxes as being controlled by either meadow or pasture. Two significantly different light response curves could be determined: one for periods with external interventions (grass cutting, cattle grazing) and the other for periods without external interventions. Other than this, meadow and pasture were similar, with a net carbon gain of –128±17g Cm^–2 on the undisturbed meadow, and a net carbon loss of 79±17g Cm^–2 on the managed meadow, and 270±24g Cm^–2 on the pasture during 131 days of the growing season, respectively. The grass cut in June reduced the gross CO₂ uptake of the meadow by 50±2% until regrowth of the vegetation. Cattle grazing reduced gross uptake over the whole vegetation period (37±2%), but left respiration at a similar level as observed in the meadow.     

A study of a fair weather boundary layer in TOGA-COARE: Parameterization of surface fluxes in large scale and regional models for light wind conditions

The study focuses on a way to parameterize the effect of subgrid scale convective motions on surface fluxes in large scale and regional models for the case of light surface winds. As previously proposed, these subgrid effects are assumed to scale with the convection intensity through the relationship: where is the mean velocity of the wind, U₀ the velocity of the mean wind, w_* the free convection velocity, and an empirical coefficient to be determined. Both observations and numerical simulation are presently used to determine the free convection coefficient .Large eddy simulation of a fair weather convective boundary layer case observed during TOGA-COARE is performed. Comparisons between observations and the simulation of surface properties and vertical profiles in the planetary boundary layer are presented. The simulated vertical turbulent fluxes of heat, moisture and buoyancy range well within estimates from aircraft measurements.The most important result is that the true free convection coefficient , directly estimated from simulation, leads to a value of 0.65, smaller than the ones estimated from temporal and spatial variances. Using observations and simulation, estimates of from temporal and spatial variances are obtained with similar values 0.8. From both theoretical derivations and numerical computations, it is shown that estimates of the true from variances are possible but only after applying a correction factor equal to 0.8. If this correction is not used, is overestimated by about 25%. The time and space sampling problem is also addressed in using numerical simulations.     

An observational study of heat fluxes and their relationships with net radiation

Experimental evidence indicates that the diurnal behaviour of the fluxes of heat into the ground and into the atmosphere versus the net flux of radiation can be modelled by closed curves, the hourly values folowing one another in either a clockwise or counter clockfashion. A general formulation to express the different heat fluxes as a function of net radiation is proposed. This relationship between the different heat fluxes and can be expressed as a sum of three terms: the first indicates a direct proportionality to , the second gives the deviation from linearity and depends on /t, and the third gives the value of the flux when = 0. The formulae are then expressed as a function of time and the ratios between the heat fluxes and are evaluated. A comparison with the approximations generally used shows that the latter may be considered as particular cases of the more general equations proposed here.     

Arctic hazes in summer over Greenland and the North American Arctic: II. Nature and concentrations of accumulation-mode and giant particles

Airborne measurements made during August 1985 over Greenland and its environs show that both accumulation-mode (0.1 m D2.0 m) and giant (D2 m) particles were present in relatively high concentrations in arctic haze layers and that the accumulation-mode particles dominated light scattering. Particles with diameters (D) between 1 and 4 m consisted predominately of mixed materials, small and dense inclusions, and probably organic compounds containing sulfur. Many of the particles from 0.1 to 1 m in diameter were also of mixed composition, with sulfuric acid, ammonium sulfate and organics probably the dominant constituents.     

An observational aircraft-based study of sea-breeze frontogenesis

In the summer of 1988/89 flights were carried out in the Coorong coastal area of South Australia to investigate sea-breeze fronts. The flights yielded data sets of the structure of the fronts in the cross-frontal direction with a spatial resolution of approximately 3 m. The study is focused on the budgets of sensible and latent heat in the vicinity of the front and on frontogenesis/frontolysis processes which are closely related to budget considerations.The frontogenesis relationships and the budgets were established on a 2 km length scale by low-pass filtering of the space series. As the wind components were measured with high accuracy, all processes which determine frontogenesis could be evaluated and are displayed in x,z-cross-sections: these are the confluence, shear and diabatic effects, all of which play a role in q/x-, q/z-, /x- as well as /z-frontogenesis. A detailed analysis is given for two different states of frontal development. The presented results shed much light on the governing physical processes in the frontal region with strong emphasis on the effects of confluence-generated updrafts, on shear instabilities causing bulges and clefts in the frontal surface as well as producing the elevated frontal head, and on processes related to differential heating and moistening.     

Atmospheric response to soil-frost and snow in Alaska in March

Summary A hydro-thermodynamic soil-vegetation model including soil freezing/thawing (soil-frost) and snow-metamorphism has been integrated into the PennState/NCAR Mesoscale Meteorological Model MM5 in a two-way coupled mode. A hierarchy of simulations with and without the soil-frost module, each combined with and without the snow module, shows the influence of snow-cover and soil-frost on weather in Alaska. Herein the landscape is featured as it is typically by mesoscale models.Theoretical considerations suggest that organic soil types should be considered in mesoscale modeling because of their different thermal and hydrological behavior as compared to mineral soils. The Ludwig-Soret and Dufour effects are small, but increase appreciably during freezing/thawing and snow-melt.The snow and soil-frost processes have a demonstrable impact on the surface thermal and hydrological regimes and on the near-surface atmospheric conditions even on the short (synoptic) timescales. The presence of snow-cover results in a highly stable stratification. In cloud-free areas, the enhanced loss of radiant energy and cooling of the air over snow-cover lead to a positive feedback to relatively colder, drier conditions. In cloudy areas, a positive feedback to warmer, moister conditions develops over snow-cover. As the changes in atmospheric humidity and temperature caused by snow-cover propagate into the pressure field, sea level pressure is lower by more than 1hPa in the simulations with snow-cover. Although the effect of soil-frost alone is an order of magnitude smaller, the soil-frost snow system leads to an increase of the pressure difference to 1.2hPa. The changes in the pressure field alter wind speed and direction slightly.Soil-frost results in soil temperature differences of 2–5K in the upper soil layers, while snow results in differences of 3–10K. Soil-frost has a notably greater impact in cloud-free than cloudy areas. When a snow-cover is present, frozen soil enhances the insulating effect of a snow-cover in cloudy areas, but reduces it in cloud-free areas. In cloudy areas, soil-frost without snow-cover leads to cooler, drier atmospheric conditions relative to no frost. In cloudy areas, soil-frost under a snow-cover reduces the water supply to the atmosphere as compared to snow-covered conditions without soil-frost. The combined effects of soil-frost and snow increase precipitation locally by as much as 12.2mm/ 48h. If mesoscale modeling does not consider the soil-frost snow system, predicted water vapor fluxes will be too high in cloud-free areas, and too low in cloudy areas.     

Occurrence of roll circulations in a shallow boundary layer

Meteorological measurements taken at the Näsudden wind turbine site during slightly unstable conditions have been analyzed. The height of the convective boundary layer (CBL) was rather low, varying between 60 and 300 m. Turbulence statistics near the ground followed Monin-Obukhov similarity, whereas the remaining part of the boundary layer can be regarded as a near neutral upper layer. In 55% of the runs, horizontal roll vortices were found. Those were the most unstable runs, with -z _i/L > 5. Spectra and co-spectra are used to identify the structures. Three roll indicators were identified: (i) a low frequency peak in the spectrum of the lateral component at low level; (ii) a corresponding increase in the vertical component at mid-CBL; (iii) a positive covariance {ovvw} together with positive wind shear in the lateral direction (V/z) in the CBL. By applying these indicators, it is possible to show that horizontal roll circulations are likely to be a common phenomenon over the Baltic during late summer and early winter.     

Climatological features of glacier and valley winds at the Hintereisferner (Ötztal Alps,Austria)

Summary Homogeneous wind measurements during summer 1971 and the 2 years 1977/78 were analysed at 3 sites of Hintereisferner (HEF) which is a valley-type glacier of 9 km length and northeasterly exposition in the Austrian Ötztal Alps. Some manifestations of glacier winds were found to verify a mesoscale circulation driven by gravity and differential heating of the air above ice surfaces and their ice free moraine surroundings. Modifications are mainly due to local topography and gradient winds.Throughout the year the wind regime at the glacier, esp. at the tongue, is clearly dominated by downsloping winds, reflecting the great potential of snow and ice areas in generating cold air downflow. Undisturbed glacier winds were found to occur most likely on sunny days with weak upper air winds. An influence of katabatic winds down from surrounding moraine slopes is indicated during night time hours. During sunlit hours the occurrence and strength of glacier winds is clearly correlated to the seasonal and daily solar cycle. The development of a regular diurnal variation of wind speeds with a single maximum about 5 m/s during afternoon hours is typical for the glacial wind regime and is most pronounced during the melting season. The observed wind speeds correspond with the diurnal development of vertical and horizontal temperature gradients of the air above the glacier.Clear day northerly winds penetrate most frequently in spring and autumn as far as to the tongue of HEF and are likely to represent thermally driven upvalley winds. They characterize fine weather in alpine valleys, when even signs of a local slope circulation above excessively heated moraine surfaces are indicated too.With 14 Figures     

On the similarity in atmospheric fluctuations of carbon dioxide,water vapor and temperature over vegetated fields

This paper describes the similarity between atmospheric fluctuations of carbon dioxide, water vapor and temperature using data which cover a wide range of instability (0.02 < < 10). The is the Monin-Obukhov stability parameter including the humidity effect.The spectral analysis shows that the coherency between fluctuations of carbon dioxide and water vapor or temperature is very close to unity, and the phase difference is basically out of phase for whole frequency ranges analyzed. The stability dependence of the normalized standard deviation of carbon dioxide is very similar to those of water vapor and temperature. The normalized standard deviation is about 2.5 under near neutral conditions, and it decreases with increasing instability following the -1/3; power law as (-)^-1/3. The skewness factors of carbon dioxide, water vapor and temperature show a systematic departure with increasing instabilities for 0.02 < s- < 1, and level off at high instabilities for 1 < -\s < 10. The stability dependence of the flatness factors is not so clear as that noted in the standrard deviation and skewness factors. Dissipation rates of carbon dioxide, water vapor and temperature variance are well related to the spectral peak wavelength. This seems to be real since the local production and local dissipation rates are the main terms, almost balancing one another in the variance budget equations for scalar entities.     

An improved calibration for tethered balloon wind measurements

A previously published technique for using tethered spherical balloons as anemometers for measuring light low-level winds has been further developed. Earlier data on the relationship between the aerodynamic drag coefficient and the Reynolds number of spherical rubber balloons were combined with a large number of new data and re-analysed; and the errors in the relationship were estimated. The results allowed a more accurate calculation of wind speed from the deflection of a tethered balloon from the vertical. When combined with a new technique for calculating the effects of the tether, this enabled light to moderate low-level winds at fixed heights up to 600 m or more to be measured with simple, cheap, and readily mobile equipment; and a slight modification of the technique allowed measurement of winds in and above fog. Wind speeds measured by the ballon technique showed reasonably good agreement with measurements by an anemometer carried beneath the balloon.Glossary of Symbols a, b, c Coefficients in the relationship between lnC _d and lnR - A Quantity under square root in solution for lnV whena0 - C _d Wind drag coefficient for balloon - C _dc Value ofC _d given by calibration curve of Table I - D Dynamic wind pressure force on balloon - F Buoyant free lift of balloon with load - Re Reynold's number of balloon (sphere) - R = Re/10⁵ - r Radius of sphere - T Tension in tether - V Wind speed - ₈₃() =(lnC _dc -lnC _d ) when 83° , or 0 for other - Error in lnC _d - Elevation of tether where attached to balloon - Elevation of balloon from ground tether point - Molecular viscosity of air - Ratio of circumference to diameter of circle - Density of air     

Relationships of photosynthetically active radiation and shortwave irradiance

Summary Hourly measurements of solar irradiance in the wave band excluding photosynthetically active radiation (PAR) and solar irradiance (SI) were made over a 12-month period at the National Observatory of Athens, for obtaining the ratios of PAR to SI. These irradiance ratios exhibit dependence on sky conditions, with slightly larger values being observed under cloudy skies and seasonal variations, attributable to changes in local air mass climatology. The highest values have been obtained during the growing season (April–September). The mean annual value of 0.473 observed for the irradiance ratio in the PAR band compares favorably with values reported in the literature for different locations over a wide geographical area.With 2 Figures