The effects of alongshore variation in bottom topography on a boundary current—(topographically induced upwelling)

A theory which describes the constant f-plane flow of a steady inviscid baroclinic boundary current over a continental margin with a bathymetry that varies slowly in the alongshore but rapidly in the offshore directions is developed in the parameter regime (L_D/L)² ≤ Ro 1, where L_D is the internal deformation radius, L the horizontal length scale, and Ro the Rossby number. To lowest order in the Rossby number the flow is along isobaths with speed q_o = V_u(h,z)|Vh|/α, where V_u(h,z) is the upstream speed, α the upstream bottom slope at depth h, and Vh the bottom slope downstream at depth h. The lowest order flow produces a variation in the vertical component of relative vorticity along the isobath as the magnitude and direction of Vh vary in the downstream direction. The variation of vorticity requires a vertical as well as a cross-isobath flow at first order in the Rossby number. The first order vertical velocity is computed from the vorticity equation in terms of upstream conditions and downstream variations of the bathymetry. The density, pressure, and cross-isobath flow at first order in the Rossby number are then calculated. It is shown that in the cyclonic region of current (d/dh(V_u/α) > 0), if the isobaths diverge in the downstream direction ((∂/∂s)|Vh| < 0), then upwelling and onshore flow occur. The theory is applied to the northeastern Florida shelf to explain bottom temperature observations.     

Density-dependent dispersion in heterogeneous porous media Part II: Comparison with nonlinear models

The results of a series of high-resolution numerical experiments are used to test and compare three nonlinear models for high-concentration-gradient dispersion. Gravity stable miscible displacement is considered. The first model, introduced by Hassanizadeh, is a modification of Fick’s law which involves a second-order term in the dispersive flux equation and an additional dispersion parameter β. The numerical experiments confirm the dependency of β on the flow rate. In addition, a dependency on travelled distance is observed. The model can successfully be applied to nearly homogeneous media (σ² = 0.1), but additional fitting is required for more heterogeneous media.The second and third models are based on homogenization of the local scale equations describing density-dependent transport. Egorov considers media that are heterogeneous on the Darcy scale, whereas Demidov starts at the pore-scale level. Both approaches result in a macroscopic balance equation in which the dispersion coefficient is a function of the dimensionless density gradient. In addition, an expression for the concentration variance is derived. For small σ², Egorov’s model predictions are in satisfactory agreement with the numerical experiments without the introduction of any new parameters. Demidov’s model involves an additional fitting parameter, but can be applied to more heterogeneous media as well.     

Water–Rock interactions in the basement beneath Long Valley Caldera: an oxygen isotope study of the Long Valley Exploratory Well drill cores

The Long Valley Exploratory Well, at the center of the Resurgent Dome of Long Valley caldera, penetrated pre-caldera basement rocks at a depth of 2101.72–2313.0 m, beneath the caldera-forming Bishop Tuff and post-caldera Early Rhyolite. The basement rocks contain prominent quartzites, with ubiquitous milky white quartz veins (with minor calcite and pyrite) and fractures of varied orientation and geometry. The other members of the basement sequence are very fine-grained quartz-rich graphitic pelites with calcite veins, spotted hornfels, and shallow intrusive rocks. Previous studies established the presence of a post-caldera, paleohydrothermal system (500–100 ka) to a depth of 2000 m that affected the Bishop Tuff and a recent (40 ka to present) hydrothermal system at shallow depth (<1 km). The deeper extent of these hydrothermal activities is established in this paper by a detailed oxygen isotope analysis of the drill core samples. 238 analyses of δ¹⁸O in 50 quartz veins within the 163.57 m depth interval of basement rocks reveal extreme heterogeneity in δ¹⁸O values (8–19.5‰). Majorities of the 84 bulk analyses of quartzites show variation of δ¹⁸O within a narrow range of 14–16‰. However, certain samples of these quartzites near the contacts with veins and fractures exhibit sharp drops in δ¹⁸O. The interbedded pelitic rocks and spotted hornfels have whole-rock δ¹⁸O ranging from 2.2 to 11.8‰. Clear, euhedral vuggy quartz that partially fills earlier open fractures in both the quartzites and quartz veins, has distinctive δ¹⁸O, ranging between −3.2 and +8.4‰. Low values of δ¹⁸O are also found in the hydrothermal minerals and whole rocks adjacent to the thin veins, clearly indicating infiltration of meteoric water. Three distinct observed patterns of fractionation in δ¹⁸O between veins and host quartzites are analyzed with the principles of mass balance, equilibrium oxygen isotope fractionation in closed system, and kinetically controlled oxygen isotope exchange in an open system. This analysis suggests that the early quartz veins formed due to a magmatic-hydrothermal activity with no influx of external water once the system comprising the sedimentary envelope and a magmatic-hydrothermal fluid phase became closed. Two-stage isotopic exchange processes caused fractionation in the δ values that originally formed arrays with slope 1 in a δ_{vein quartz}–δ_{host quartzite} space. Another array in the same space, with near zero slope was also formed due to variation in temperature, initial isotopic compositions of the quartzite sequence and the fluid phase. Variation in temperature was mostly in the range of 300–400°C giving Δ (=δ_{vein quartz}–δ_{host quartzite})≈−2.8 to +2.8. The δ¹⁸O of the fluid could range from −5 to +10; however a narrower range of +5 to +10 can explain the data. This episode of hydrothermal activity could take place either as a single pulse or in multiple pulses but each as a closed system. A later, fracture-controlled, meteoric water (δ¹⁸O−0.46 to −12.13) flow and interaction (at 250°C) is interpreted from the analysis of δ¹⁸O values of the coexisting quartz and calcite pairs and existence of markedly ¹⁸O-depleted pelitic horizons interbedded with ¹⁸O-enriched quartzite layers. Thus, the interpreted earlier magmatic-hydrothermal activity was overprinted by a later meteoric-hydrothermal activity that resulted in steep arrays of δ¹⁸O values in the δ_{vein quartz}–δ_{host quartzite} space. Calculations show that the likely life span of the post-caldera, hydrothermal activity in the depth range of 2.1–2.3 km beneath Long Valley was 0.08–0.12 Ma. Diffusive ±advective transport of oxygen isotopes from fracture-channelized meteoric water to nearly impermeable wall rocks caused a lowering of δ¹⁸O values in the quartz over short distances and in calcites over greater distances. Thus, the hydrothermal activity appears pervasive even though the meteoric water flow was primarily controlled by fractures.     

An oxygen isotope study of hydrothermal alteration in the Lake City caldera, San Juan Mountains, Colorado

A 23-m.y.-old, fossil meteoric-hydrothermal system in the Lake City caldera (11 × 14 km) has been mapped out by measuring δ ¹⁸O values of 300 rock and mineral samples. δ ¹⁸O varies systematically throughout the caldera, reaching values as low as −2. Great topographic relief, regional tilting, and variable degrees of erosion within the caldera all combine to give us a very complete section through the hydrothermal system, from the surface down to a depth of more than 2000 m. The initial δ ¹⁸O value of the caldera-fill Sunshine Peak Tuff was very uniform (+7.2 ± 0.1), making it easy to determine the exact amount of ¹⁸O depletion experienced by each sample during hydrothermal alteration. Also, we have excellent stratigraphic control on depths beneath the mid-Tertiary surface, quantitative information on mineralogical alteration products, and accurate data on the shape of the central resurgent intrusion, which was the principal ‘heat engine’ that drove the hydrothermal circulation. Major conclusions are: (1) Although pristine mid-Tertiary meteoric waters in this area had δ ¹⁸O −14, these fluids were ¹⁸O-shifted upward to about δ¹⁸O = −8 to −5 prior to entering the shallow convective system associated with the resurgent intrusive rocks. Although there was undoubtedly radial inflow toward the caldera from all directions, the highly fractured Eureka Graben, southwest of the caldera, was probably the principal source of recharge groundwater for the Lake City system. (2) Fluid flow within the caldera was dominated by three major categories of permeable zones: the porous megabreccia units (which dip outward from the resurgent dome), vertical fractures and faults related to resurgence, and the caldera ring fault itself. All of these zones exhibit marked ¹⁸O depletions, and they are also typically intensely mineralogically altered. (3) The resurgent intrusive stock and its contact metamorphic aureole of hornfels both experienced water/rock ratios lower than the permeable zones; however, they have similarly low δ ¹⁸O values because they were altered at higher temperatures. (4) Throughout the caldera, the δ ¹⁸O of Sunshine Peak Tuff decreases with increasing depth (about 6 per mil/km), indicative of a shallow thermal gradient, typical of a convective hydrothermal system. The near-surface portion of this gradient was controlled by the temperature drop associated with boiling in the uprising fluid. (5) Deeply circulating meteoric water rose along permeable ring fractures 3 to 5 km beneath the mid-Tertiary surface. These fluids were drawn into the shallow convective system through the lower, porous, megabreccia units. Near the resurgent intrusions, fluid flow was again directed upward where resurgence-related, near-vertical fractures intersect the megabreccia units.     

Neodymium isotopic study of Baffin Bay water: sources of REE from very old terranes

Water samples were collected from Baffin Bay and surrounding areas in order to evaluate this region as a potential source of Nd from old continental material to Atlantic water. The isotopic data ranged from ε_Nd(0) = −9.0 to −26 with most of the data around ε_Nd(0) = −20 compared with values of North Atlantic Deep Water (NADW) with ε_Nd(0) = −13.5. The concentration of Nd in Baffin Bay waters was as high as 6 × 10⁻¹² g/g compared with 2.5 × 10⁻¹² g/g for NADW. The combination of low ε_Nd and high Nd concentration indicates that Baffin Bay may be a significant source of Nd from very old crustal material. A simple box model was used to evaluate the contribution to the Nd budget of NADW and it was concluded that a substantial fraction of the Nd from ancient crustal sources that is required to maintain the isotopic composition of NADW could be supplied by Baffin Bay outflow.     

An anomalous subauroral red arc on 4 August, 1972: comparison of ISIS-2 satellite data with numerical calculations

This study compares the Isis II satellite measurements of the electron density and temperature, the integral airglow intensity and volume emission rate at 630 nm in the SAR arc region, observed at dusk on 4 August, 1972, in the Southern Hemisphere, during the main phase of the geomagnetic storm. The model results were obtained using the time dependent one-dimensional mathematical model of the Earth’s ionosphere and plasmasphere (the IZMIRAN model). The major enhancement to the IZMIRAN model developed in this study to explain the two component 630 nm emission observed is the analytical yield spectrum approach to calculate the fluxes of precipitating electrons and the additional production rates of N⁺₂, O⁺₂, O⁺(⁴S), O⁺(²D), O⁻(²P), and O⁺(²P) ions, and O(¹D) in the SAR arc regions in the Northern and Southern Hemispheres. In order to bring the measured and modelled electron temperatures into agreement, the additional heating electron rate of 1.05 eV cm⁻³ s⁻¹ was added in the energy balance equation of electrons at altitudes above 5000 km during the main phase of the geomagnetic storm. This additional heating electron rate determines the thermally excited 630 nm emission observed. The IZMIRAN model calculates a 630 nm integral intensity above 350 km of 4.1 kR and a total 630 nm integral intensity of 8.1 kR, values which are slightly lower compared to the observed 4.7 kR and 10.6 kR. We conclude that the 630 nm emission observed can be explained considering both the soft energy electron excited component and the thermally excited component. It is found that the inclusion of N₂(v > 0) and O₂(v > 0) in the calculations of the O⁺(⁴S) loss rate improves the agreement between the calculated N_e and the data on 4 August, 1972. The N₂(v > 0) and O₂(v > 0) effects are enough to explain the electron density depression in the SAR arc F-region and above F2 peak altitude. Our calculations show that the increase in the O⁺ + N₂ rate factor due to the vibrationally excited nitrogen produces the 5–19% reductions in the calculated quiet daytime peak density and the 16–24% decrease in NmF2 in the SAR arc region. The increase in the O⁺ + N₂ loss rate due to vibrationally excited O₂ produces the 7–26% decrease in the calculated quiet daytime peak density and the 12–26% decrease in NmF2 in the SAR arc region. We evaluated the role of the electron cooling rates by low-lying electronic excitation of O₂(a¹δ_g) and O₂(b¹σ_g⁺), and rotational excitation of O₂, and found that the effect of these cooling rates on T_e can be considered negligible during the quiet and geomagnetic storm period 3–4 August, 1972. The energy exchange between electron and ion gases, the cooling rate in collisions of O(³P) with thermal electrons with excitation of O(¹D), and the electron cooling rates by vibrational excitation of O₂ and N₂ are the largest cooling rates above 200 km in the SAR arc region on 4 August, 1972. The enhanced IZMIRAN model calculates also number densities of N₂(B³π_g⁺), N₂(C³π_u), and N₂(A³σ_u⁺) at several vibrational levels, O(¹S), and the volume emission rate and integral intensity at 557.7 nm in the region between 120 and 1000 km. We found from the model that the integral integral intensity at 557.7 nm is much less than the integral intensity at 630 nm.     

Very high-frequency and seasonal cave atmosphere PCO2 variability: Implications for stalagmite growth and oxygen isotope-based paleoclimate records

Cave air P_CO2 at two Irish sites varied dramatically on daily to seasonal timescales, potentially affecting the timing of calcite deposition and consequently climate proxy records derived from stalagmites collected at the same sites. Temperature-dependent biochemical processes in the soil control CO₂ production, resulting in high summer P_CO2 values and low winter values at both sites. Large Large-amplitude, high-frequency variations superimposed on this seasonal cycle reflect cave air circulation. Here we model stalagmite growth rates, which are controlled partly by CO₂ degassing rates from drip water, by considering both the seasonal and high-frequency cave air P_CO2 variations. Modeled hourly growth rates for stalagmite CC-Bil from Crag Cave in SW Ireland reach maxima in late December (0.063 μm h^− 1) and minima in late June/early July (0.033 μm h^− 1). For well-mixed ‘diffuse flow’ cave drips such as those that feed CC-Bil, high summer cave air P_CO2 depresses summer calcite deposition, while low winter P_CO2 promotes degassing and enhances deposition rates. In stalagmites fed by well-mixed drips lacking seasonal variations in δ¹⁸O, integrated annual stalagmite calcite δ¹⁸O is unaffected; however, seasonality in cave air P_CO2 may influence non-conservative geochemical climate proxies (e.g., δ¹³C, Sr/Ca). Stalagmites fed by ‘seasonal’ drips whose hydrochemical properties vary in response to seasonality may have higher growth rates in summer because soil air P_CO2 may increase relative to cave air P_CO2 due to higher soil temperatures. This in turn may bias stalagmite calcite δ¹⁸O records towards isotopically heavier summer drip water δ¹⁸O values, resulting in elevated calcite δ¹⁸O values compared to the ‘equilibrium’ values predicted by calcite–water isotope fractionation equations. Interpretations of stalagmite-based paleoclimate proxies should therefore consider the consequences of cave air P_CO2 variability and the resulting intra-annual variability in calcite deposition rates.     

Determination of thermodynamic properties of (Fe,Mg)-pyroxenes at 1000 K by the emf method

Emf measurements were made on the cell Pt|Fe,(Fe,Mg)_xSi₂O₆,SiO₂|(ZrO₂)_0.85(CaO)_0.15|Fe,FeO|Pt at 1000 K. Using the present data, the standard free energy of formation of ferrosilite (compound FeSiO₃), from the component oxides FeO and SiO₂, is calculated to be −6.35 ± 0.80 kJ/mol. The activity-composition relation for pyroxene solid solution shows that it has a positive deviation from ideality at 1000 K. The present results are compared with the results of other workers.ΔG_mix andΔG^ex are calculated and plotted againstN_FeSiO3.     

A new analytical solution for water table fluctuations in coastal aquifers with sloping beaches

The Boussinesq equation appears as the zeroth-order term in the shallow water flow expansion of the non-linear equation describing the flow of fluid in an unconfined aquifer. One-dimensional models based on the Boussinesq equation have been used to analyse tide-induced water table fluctuations in coastal aquifers. Previous analytical solutions for a sloping beach are based on the perturbation parameter, _N=αcotβ (in which β is the beach slope, α is the amplitude parameter and is the shallow water parameter) and are limited to tan⁻¹(α)βπ/2. In this paper, a new higher-order solution to the non-linear boundary value problem is derived. The results demonstrate the significant influence of the higher-order components and beach slope on the water table fluctuations. The relative difference between the linear solution and the present solution increases as and α increase, and reaches 7% of the linear solution.     

The role of vibrationally excited nitrogen in the formation of the mid-latitude negative ionospheric storms

Millstone Hill ionospheric storm time measurements of the electron density and temperature during the ionospheric storms (15-16 June 1965; 29–30 September 1969 and 17–18 August 1970) are compared with model results. The model of the Earth’s ionosphere and plasmasphere includes interhemispheric coupling, the H⁺, O⁺(⁴S), O⁺(²D), O⁺(²P), NO⁺, O⁺₂ and N⁺₂ ions, electrons, photoelectrons, the electron and ion temperature, vibrationally excited N₂ and the components of thermospheric wind.In order to model the electron temperature at the time of the 16 June 1965 negative storm, the heating rate of the electron gas by photoelectrons in the energy balance equation was multiplied by the factors 5–30 at he altitude above 700 km for the period 4.50-12.00 LT, 16 June 1965. The [O]/[N₂] MSIS-86 decrease and vibrationally excited N₂ effects are enough to account for the electron density depressions at Millstone Hill during the three storms. The factor of 2 (for 27–30 September 1969 magnetic storm) and the & actor 2.7 (for 16–18 August 1970 magnetic storm) reduction in the daytime peak density due to enhanced vibrationally excited N₂ is brought about by the increase in the O⁺+N₂ rate factor.     

Macroscopic representation of structural geometry for simulating water and solute movement in dual-porosity media

The structure of macroporous or aggregated soils and fractured rocks is generally so complex that it is impractical to measure the geometry at the microscale (i.e., the size and the shape of soil aggregates or rock matrix blocks, and the myriad of fissures or fractures), and use such data in geometry-dependent macroscale flow and transport models. This paper analyzes a first-order type dual-porosity model which contains a geometry-dependent coefficient, β, in the mass transfer term to macroscopically represent the size and shape of soil or rock matrix blocks. As a reference, one- and two-dimensional geometry-based diffusion models were used to simulate mass transport into and out of porous blocks of defined shapes. Estimates for β were obtained analytically for four different matrix block geometries. Values for β were also calculated by directly matching analytical solutions of the diffusion models for a number of selected matrix block geometries to results obtained with the first-order model assuming standard boundary conditions. Direct matching improved previous results for cylindrical macropore geometries, especially when relatively small ratios between the outer soil mantle and the radius of the inner cylinder were used. Results of our analysis show that β is closely related to the ratio of the effective surface area available for mass transfer, and the soil matrix volume normalized by the effective characteristic length of the matrix system. Using values of β obtained by direct matching, an empirical function is derived to estimate macroscopic geometry coefficients from medium properties which in principle are measurable. The method permits independent estimates of β, thus allowing the dual-porosity approach eventually to be applied to media with complex and mixed types of structural geometry.     

Morphology and composition of spinel in Pu’u ’O’o lava (1996–1998), Kilauea volcano, Hawaii

The morphology and composition of spinel in rapidly quenched Pu’u ’O’o vent and lava tube samples are described. These samples contain glass, olivine phenocrysts (3–5 vol.%) and microphenocrysts of spinel (0.05 vol.%). The spinel surrounded by glass occurs as idiomorphic octahedra 5–50 μm in diameter and as chains of octahedra that are oriented with respect to each other. Spinel enclosed by olivine phenocrysts is sometimes rounded and does not generally form chains. The temperature before quenching was calculated from the MgO content of the glass and ranges from 1150°C to 1180°C. The oxygen fugacity before quenching was calculated by two independent methods and the log f_O2 ranged from −9.2 to −9.9 (delta QFM=−1). The spinel in the Pu’u ’O’o samples has a narrow range in composition with Cr/(Cr+Al)=0.61 to 0.73 and Fe²⁺/(Fe²⁺+Mg)=0.46 to 0.56. The lower the calculated temperature for the samples, the higher the average Fe²⁺/(Fe²⁺+Mg), Fe³⁺ and Ti in the spinel. Most zoned spinel crystals decrease in Cr/(Cr+Al) from core to rim and, in the chains, the Cr/(Cr+Al) is greater in the core of larger crystals than in the core of smaller crystals. The occurrence of chains and hopper crystals and the presence of Cr/(Cr+Al) zoning from core to rim of the spinel suggest diffusion-controlled growth of the crystals. Some of the spinel crystals may have grown rapidly under the turbulent conditions of the summit reservoir and in the flowing lava, and the crystals may have remained in suspension for a considerable period. The rapid growth may have caused very local (μm) gradients of Cr in the melt ahead of the spinel crystal faces. The crystals seem to have retained the Cr/(Cr+Al) ratio that developed during the original growth of the crystal, but the Fe²⁺/(Fe²⁺+Mg) ratio may have equilibrated fairly rapidly with the changing melt composition due to olivine crystallization. Six of the samples were collected on the same day at various locations along a 10-km lava tube and the calculated pre-collection temperatures of the samples show a 5°C drop with distance from the vent. The average Fe²⁺/(Fe²⁺+Mg) of the spinel in these samples shows a weak positive correlation with decreasing MgO in the glass of these samples. The range in Cr₂O₃ (0.041–0.045 wt.%) of the glass for these six samples is too small to distinguish a consistent change along the lava tube. The spinel in the Pu’u ’O’o samples shows a zoning trend in a Cr–Al–Fe³⁺ diagram almost directly away from the Cr apex. This compares with a zoning trend in rapidly quenched MORB samples away from Cr coupled with decreasing Fe³⁺. The trend away from Cr displayed by spinel in rapidly quenched samples is in marked contrast to the trend of increasing Fe³⁺ shown by spinel in slowly cooled lava.     

Hydrothermal vent waters at 13°N on the East Pacific Rise: isotopic composition and gas concentration

Gas concentrations and isotopic compositions of water have been measured in hydrothermal waters from 13°N on the East Pacific Rise. In the most Mg-depleted samples ( 5 × 10⁻³ moles/kg) the gas concentrations are: 3–4.5 × 10⁻⁵ cm³ STP/kg helium, 0.62–1.24 cm³ STP/kg CH₄, 10.80–16.71 × 10⁻³ moles/kg CO₂. The samples contain large quantities (95–126 cm³/kg) of H₂ and some carbon monoxide (0.26–0.36 cm³/kg) which result from reaction with the titanium sampling bottles. δ¹³C in methane and CO₂ (−16.6 to −19.5 and −4.1 to −5.5 respectively) indicate temperatures between 475 and 550°C, whereas δ¹³C_CO is compatible with formation by reduction of CO₂ on Ti at 350°C close to the sampling temperature.³He/⁴He are very homogeneous at (7.5 ± 0.1)R_A(³He/⁴He = 1.0 × 10⁻⁵) and very similar to already published data as well as CH₄/³He ratios between 1.4 and 2.1 × 10⁶.¹⁸O and D in water show enrichments from 0.39 to 0.69‰ and from 0.62 to 1.49‰ respectively. These values correspond to W/R ratios of 0.4–7. The distinct¹⁸O enrichments indicate that the isotopic composition of the oceans is not completely buffered by the hydrothermal circulations. The³He-enthalpy relationship is discussed in terms of both hydrothermal heat flux and³He mantle flux.     

Nitrogen isotope geochemistry of basaltic glasses: implications for mantle degassing and structure?

The nitrogen isotope geochemistry of 15 basaltic glasses has been investigated using stepped heating and high sensitivity static vacuum mass spectrometry. At low temperature (< 600°C) the glasses release small amounts of nitrogen with δ¹⁵N_AIR, averaging −0.3‰, suggesting surficial adsorption of atmospheric nitrogen. At high temperature, usually with a maximum at 1000°C, indigenous nitrogen with a concentration ranging from 0.2 to 2.1 ppm is released. The δ¹⁵N values of this high temperature release show a wide range from −4.5‰ to +15.5‰. There is no correlation between N ppm and δ¹⁵N, and the samples apparently form 3 groups with distinctive δ¹⁵N. Six MORB glasses from the Mid-Atlantic Ridge, East Pacific Rise and Juan de Fuca Ridge define a group with δ¹⁵N = +7.5 ± 1.3‰. In contrast two Indian Ocean MORB glasses (Carlsberg Ridge and Gulf of Aden) gave negative δ¹⁵N averaging −3.2‰. Glasses from Loihi Seamount have high δ¹⁵N averaging +14.0 ± 1.0‰. Comparison of the δ¹⁵N data with the mantle models derived from helium and argon isotope studies suggests that the wide range in δ¹⁵N may reflect in part heterogeneities in the mantle related to its degassing history. It is possible, however, that magmatic degassing processes have also affected nitrogen isotopic compositions, and the data cannot yet be unambiguously interpreted in terms of source variations.     

O, S, Sr, and Pb isotope variations in volcanic rocks from the Northern Mariana Islands: implications for crustal recycling in intra-oceanic arcs

Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ¹⁸O = +5.7 to +6.6 (‰ SMOW) andδ³⁴S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ¹⁸O = +6.3 ± 0.2 are slightly enriched in¹⁸O with respect to unfractionated basalts of<53%SiO₂ with meanδ¹⁸O = +6.0 ± 0.1. This¹⁸O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ¹⁸O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ¹⁸OSiO₂ trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO₂; therefore, the meanδ³⁴S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of¹⁸O and³⁴S in Mariana Arc parental magmas relative to ocean floor basalts withδ¹⁸O ca. + 5.7‰ andδ³⁴S = ca.0.3‰ is attributed to the recycling of¹⁸O- and³⁴S-rich crustal components (sediment withδ¹⁸O = ca. + 25‰ and seawater sulfate withδ³⁴S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.     

Identification of magnetosheath mirror modes in Equator-S magnetic field data

Between December 1997 and March 1998 Equator-S made a number of excursions into the dawn-side magnetosheath, over a range of local times between 6:00 and 10:40 LT. Clear mirror-like structures, characterised by compressive fluctuations in |B| on occasion lasting for up to 5 h, were observed during a significant fraction of these orbits. During most of these passes the satellite appeared to remain close to the magnetopause (within 1–2 Re), during sustained compressions of the magnetosphere, and so the characteristics of the mirror structures are used as a diagnostic of magnetosheath structure close to the magnetopause during these orbits. It is found that in the majority of cases mirror-like activity persists, undamped, to within a few minutes of the magnetopause, with no observable ramp in |B|, irrespective of the magnetic shear across the boundary. This suggests that any plasma depletion layer is typically of narrow extent or absent at the location of the satellite, at least during the subset of orbits containing strong magnetosheath mirror-mode signatures. Power spectra for the mirror signatures show predominately field aligned power, a well defined shoulder at around 3–10 × 10⁻² Hz and decreasing power at higher frequencies. On occasions the fluctuations are more sinusoidal, leading to peaked spectra instead of a shoulder. In all cases mirror structures are found to lie approximately parallel to the observed magnetopause boundary. There is some indication that the amplitude of the compressional fluctuations tends to be greater closer to the magnetopause. This has not been previously reported in the Earth’s magnetosphere, but has been suggested in the case of other planets.     

Unified modeling of flow liquefaction and cyclic mobility

Flow liquefaction and cyclic mobility are two different phenomena that are encountered during strong earthquakes. Flow liquefaction is associated with the contractive behavior of loose granular materials and cyclic mobility is associated with the dilative response of both loose and dense granular materials at low confining stresses. These two types of response pertain to the same material and therefore should be modeled in a consistent manner. Whether a soil in a given state exhibits contractive or dilative behavior is dependent on its dilatancy, d=d_v^p/d_q^p. A form of the dilatancy d=d(η,ψ,C) is proposed, where η=q/p is the stress ratio, and ψ and C denote the internal state variables and the intrinsic properties, respectively. It has been shown that such a state-dependent dilatancy is effective in describing both the contractive and dilative behavior. This allows the soil behavior associated with flow liquefaction and cyclic mobility during earthquakes to be modeled in a unified way.     

Temperature dependence of the oxygen isotopic fractionation between diatom silica and water

We present a new paleotemperature scale, based on the oxygen isotopic ratio of the non-exchangeable fraction of the oxygen from diatom silica. The equation t = 17.2 − 2.4 (δ¹⁸O_silica − δ¹⁸O_water − 40) − 0.2 (δ¹⁸O_silica − δ¹⁸O_water − 40)² was derived using recent sediment samples from different oceanic areas, the temperature and isotopic composition of the local surface water. Comparison of our results with other relationships established for quartz-water or amorphous silica-water at higher temperature suggests no difference in isotopic fractionation between quartz-water and biogenic silica-water couples.     

Nickel isotope heterogeneity in the early Solar System

We report small but significant variations in the ⁵⁸Ni/⁶¹Ni-normalised ⁶⁰Ni/⁶¹Ni and ⁶²Ni/⁶¹Ni ratios (expressed as ε⁶⁰Ni and ε⁶²Ni) of bulk iron and chondritic meteorites. Carbonaceous chondrites have variable, positive ε⁶²Ni (0.05 to 0.25), whereas ordinary chondrites have negative ε⁶²Ni (− 0.04 to − 0.09). The Ni isotope compositions of iron meteorites overlap with those of chondrites, and define an array with negative slope in the ε⁶⁰Ni versus ε⁶²Ni diagram. The Ni isotope compositions of the volatile-depleted Group IVB irons are similar to those of the refractory CO, CV carbonaceous chondrites, whereas the other common magmatic iron groups have Ni isotope compositions similar to ordinary chondrites. Only enstatite chondrites have identical Ni isotope compositions to Earth and so appear to represent the most appropriate terrestrial building material. Differences in ε⁶²Ni reflect distinct nucleosynthetic components in precursor solids that have been variably mixed, but some of the ε⁶⁰Ni variability could reflect a radiogenic component from the decay of ⁶⁰Fe. Comparison of the ε⁶⁰Ni of iron and chondritic meteorites with the same ε⁶²Ni allows us to place upper limits on the ⁶⁰Fe/⁵⁶Fe of planetesimals during core segregation. We estimate that carbonaceous chondrites had initial ⁶⁰Fe/⁵⁶Fe < 1 × 10^− 7. Our data place less good constraints on initial ⁶⁰Fe/⁵⁶Fe ratios of ordinary chondrites but our results are not incompatible with values as high as 3 × 10^− 7 as determined by in-situ measurements. We suggest that the Ni isotope variations and apparently heterogeneous initial ⁶⁰Fe/⁵⁶Fe results from physical sorting within the protosolar nebula of different phases (silicate, metal and sulphide) that carry different isotopic signatures.     

Scaling model experiments on propagation of electromagnetic waves using salt solution to simulate the Earth's crust: Loma Prieta and Kobe earthquakes

Propagation of electromagnetic (EM) waves from an earthquake focus in the conductive Earth has been investigated using 1/1,000,000 scaling models taking earth-ionosphere and ocean-Moho plane parallel-plate waveguides into account. Microwaves at a frequency, ω_m, a million times higher than that of seismic EM signal (SEMS), ω, were generated at the model focus. They are propagated in a salt solution modeling the earth's crust and reflected by ocean, fault planes, ionosphere and Moho plane all made by aluminum. Distribution of EM power was mapped by scanning a detector antenna over the model Earth's surface. The skin depth, δ, calculated by the exact skin depth equation, 1/δ=ω(μ/2)^1/2 [(1+(1/ωρ)²)^1/2 −1]^1/2 where dielectric constant, and permeability, μ are the same but resistivity, ρ, 10⁻⁶ times smaller than that of Earth, gave 10⁻⁶ times small skin depth validating the model scaling index. Images for evanescent and wave-ripple standing waves disturbed by normal, strike-slip and dip-slip conductive fault planes have been obtained using an aluminum plate. The co-circular contour map above the epicenter due to evanescence was pushed to the north east direction from the epicenter by the presence of ocean for the Loma Prieta earthquake, while to north direction for the Kobe earthquake. The intensity of EM ULF emissions for the Loma Prieta earthquake is discussed quantitatively.