2C or not 2C?

Political attention has increasingly focused on limiting warming to 2 °C. However, there is no consensus on both questions “Is the 2 °C target achievable?” and “What should be done with this target that becomes increasingly difficult to achieve?”. This paper aims at disentangling the points of deep uncertainty underlying this absence on consensus. It first gives simple visualizations of the challenge posed by the 2 °C target and shows how key assumptions (on the points of deep uncertainty) influence the answer to the target achievability question. It then proposes an “uncertainties and decisions tree”, linking different beliefs on climate change, the achievability of different policies, and current international policy dynamics to various options to move forward on climate change.     

GRIB2介绍及解码初探

由于气象数据种类不断增多,对数量和质量的要求越来越高,而字符编码的局限性使得字符编码不能很好地满足这样的需求。WMO建议逐渐由字符编码向表格驱动码过渡。该文介绍了表格驱动码中的一种,即二进制格点加工数据(GRIB码)。首先介绍GRIB码的第1个版本(GRIB1)的编码格式,使用的模板技术及GRIB1目前在使用过程中的一些缺陷。然后着重分析了GRIB码的第2个版本(GRIB2)新的编码格式和特点,以及GRIB2在表示丰富的数据方面的优越性,最后对GRIB2解码过程中需要注意的一些问题进行了阐述。     

PAGES 2k

了解过去的环境变化是预估未来环境变化的钥匙。但是,只有了解了环境变化的区域特征,才能正确认识环境变化的形成机制。Wanner等在2002年就提出了"长期再分析与动力学"(LITRED)问题,指出在欧洲已经有可能进行"古(气候)再分析"。2005年Wanner进一步提出研究"过去区域气候变率"的问题。在气候变率及其可预报性(CLIVAR)科学指导委员会(SSC)的支持下,于2009年7月召开了过去全球变化2000年气候团队(PAGES 2k)第1次网络会议,确定了要研究的8个     

Siberian CO2 efflux in winter as a CO2 source and cause of seasonality in atmospheric CO2

Over three years, we found a consistent CO₂ efflux from forest tundra of the Russian North throughout the year, including a large (89 g C m^–2 yr^–1) efflux during winter. Our results provide one explanation for the observations that the highest atmospheric CO₂ concentration and greatest seasonal amplitude occur at high latitudes rather than over the mid-latitudes, where fossil fuel sources are large, and where high summer productivity offset by winter respiration should give large seasonal oscillations in atmospheric CO₂. Winter respiration probably contributed substantially to the boreal winter CO₂ efflux. Respiration is an exothermic process that produces enough heat to warm soils and promote further decomposition. We suggest that, as a result of this positive feedback, small changes in surface heat flux, associated with human activities in the North or with regional or global warming, could release large quantities of organic carbon that are presently stored in permafrost.     

Measurements of H2S and SO2 over the Atlantic Ocean

Concentrations of sulfur gases H₂S and SO₂ have been measured in the marine atmosphere over the Atlantic Ocean at various sites. Mean values of 40 ng H₂S m^-3 STP and 209 ng SO₂ m^-3 STP are the results of the measurements. A diurnal variation of H₂S concentration was detected on the west coast of Ireland with nighttime concentrations of up to 200 ng H₂S m^-3 STP and values below detection limit (15 ng H₂S m^-3 STP) during daytime.     

Growth of monodisperse,submicron aerosol particles exposed to SO2, H2O2, and NH3

The growth of monodisperse particles (0.07 to 0.5 µm) exposed to SO₂ (0–860 ppb), H₂O₂ (0–150 ppb) and sometimes NH₃ (0–550 ppb) in purified air at 22 °C at relative humidities ranging from 25 to 75% were measured using the Tandem Differential Mobility Analyzer technique. The experiments were performed in a flow reactor with aqueous (NH₄)₂SO₄ and Na₂SO₄ droplets. For (NH₄)₂SO₄ droplets the fractional diameter growth was independent of size above 0.3 µm but decreased with decreasing size below that. When NH₃ was added the fractional growth increased with decreasing size. Measurements were compared with predictions of a model that accounts for solubility of the reactive gases, the liquid phase oxidation of SO₂ by H₂O₂, and ionic equilibria. Agreement between measured and predicted droplet growth is reasonable when the ionic strength effects are included. Theory and experiments suggest that NH₃ evaporation is responsible for the decrease in relative growth rates for small aqueous ammonium sulfate particles. The observed droplet growth rates are too slow to explain observed growth rates of secondary atmospheric sulfate particles.     

Managing atmospheric CO2

A coupled carbon cycle-climate model is used to compute global atmospheric CO₂ and temperature variation that would result from several future CO₂ emission scenarios. The model includes temperature and CO₂ feedbacks on the terrestrial biosphere, and temperature feedback on the oceanic uptake of CO₂. The scenarios used include cases in which fossil fuel CO₂ emissions are held constant at the 1986 value or increase by 1% yr^–1 until either 2000 or 2020, followed by a gradual transition to a rate of decrease of 1 or 2% yr^–1. The climatic effect of increases in non-CO₂ trace gases is included, and scenarios are considered in which these gases increase until 2075 or are stabilized once CO₂ emission reductions begin. Low and high deforestation scenarios are also considered. In all cases, results are computed for equilibrium climatic sensitivities to CO₂ doubling of 2.0 and 4.0 °C.Peak atmospheric CO₂ concentrations of 400–500 ppmv and global mean warming after 1980 of 0.6–3.2 °C occur, with maximum rates of global mean warming of 0.2–0.3 °C decade^–1. The peak CO₂ concentrations in these scenarios are significantly below that commonly regarded as unavoidable; further sensitivity analyses suggest that limiting atmospheric CO₂ to as little as 400 ppmv is a credible option.Two factors in the model are important in limiting atmospheric CO₂: (1) the airborne fraction falls rapidly once emissions begin to decrease, so that total emissions (fossil fuel + land use-induced) need initially fall to only about half their present value in order to stabilize atmospheric CO₂, and (2) changes in rates of deforestation have an immediate and proportional effect on gross emissions from the biosphere, whereas the CO₂ sink due to regrowth of forests responds more slowly, so that decreases in the rate of deforestation have a disproportionately large effect on net emission.If fossil fuel emissions were to decrease at 1–2% yr^–1 beginning early in the next century, emissions could decrease to the rate of CO₂ uptake by the predominantly oceanic sink within 50–100 yrs. Simulation results suggest that if subsequent emission reductions were tied to the rate of CO₂ uptake by natural CO₂ sinks, these reductions could proceed more slowly than initially while preventing further CO₂ increases, since the natural CO₂ sink strength decreases on time scales of one to several centuries. The model used here does not account for the possible effect on atmospheric CO₂ concentration of possible changes in oceanic circulation. Based on past rates of atmospheric CO₂ variation determined from polar ice cores, it appears that the largest plausible perturbation in ocean-air CO₂ flux due to changes of oceanic circulation is substantially smaller than the permitted fossil fuel CO₂ emissions under the above strategy, so tieing fossil fuel emissions to the total sink strength could provide adequate flexibility for responding to unexpected changes in oceanic CO₂ uptake caused by climatic warming-induced changes of oceanic circulation.     

COMPARISON OF GLOBAL CLIMATE CHANGE SIMULATIONS FOR 2 × CO2-INDUCED WARMING

In this article we compile 108 national and international studies on global climate change, each projecting a quantitative impact on global surface-air temperature due to a doubling of the atmospheric CO₂ concentration. These predictions, documented between 1980 and 1995, are based primarily on climate-modeling research, including radiative-convective, energy-balance, and general circulation models. Collectively over the past 15 years, the average (mean) temperature change projection due to doubled CO₂ is +2.62°C, with a range of 0.16–8.7°C. General circulation models tend to estimate slightly higher values (2.98°C), compared with radiative-convective models (1.98°C) and energy-balance models (2.54°C). During the years 1980 through 1995, an increasing trend in predictions is noticed, although the mean temperature change prediction each year has remained fairly consistent near 2–3°C. These findings suggest that the estimated sensitivity of the climate system continues to remain comparable to the range calculated in earlier studies. However, tremendous advancements in the capacity of climate models continue to reveal important uncertainties in the dynamic nature of global atmospheric interactions. The predictions continue to validate the need for a global policy relating to human influence on global climate change.     

The Flexible Global Ocean-Atmosphere-Land system model, Spectral Version 2: FGOALS-s2

The Flexible Global Ocean-Atmosphere-Land System model, Spectral Version 2 (FGOALS-s2) was used to simulate realistic climates and to study anthropogenic influences on climate change. Specifically, the FGOALS-s2 was integrated with Coupled Model Intercomparison Project Phase 5 (CMIP5) to conduct coordinated experiments that will provide valuable scientific information to climate research communities. The performances of FGOALS-s2 were assessed in simulating major climate phenomena, and documented both the strengths and weaknesses of the model. The results indicate that FGOALS-s2 successfully overcomes climate drift, and realistically models global and regional climate characteristics, including SST, precipitation, and atmospheric circulation. In particular, the model accurately captures annual and semi-annual SST cycles in the equatorial Pacific Ocean, and the main characteristic features of the Asian summer monsoon, which include a low-level southwestern jet and five monsoon rainfall centers. The simulated climate variability was further examined in terms of teleconnections, leading modes of global SST (namely, ENSO), Pacific Decadal Oscillations (PDO), and changes in 19th–20th century climate. The analysis demonstrates that FGOALS-s2 realistically simulates extra-tropical teleconnection patterns of large-scale climate, and irregular ENSO periods. The model gives fairly reasonable reconstructions of spatial patterns of PDO and global monsoon changes in the 20th century. However, because the indirect effects of aerosols are not included in the model, the simulated global temperature change during the period 1850–2005 is greater than the observed warming, by 0.6°C. Some other shortcomings of the model are also noted.     

The flexible global ocean-atmosphere-land system model, Grid-point Version 2: FGOALS-g2

This study mainly introduces the development of the Flexible Global Ocean-Atmosphere-Land System Model: Grid-point Version 2 (FGOALS-g2) and the preliminary evaluations of its performances based on results from the pre-industrial control run and four members of historical runs according to the fifth phase of the Coupled Model Intercomparison Project (CMIP5) experiment design. The results suggest that many obvious improvements have been achieved by the FGOALS-g2 compared with the previous version,FGOALS-g1, including its climatological mean states, climate variability, and 20th century surface temperature evolution. For example,FGOALS-g2 better simulates the frequency of tropical land precipitation, East Asian Monsoon precipitation and its seasonal cycle, MJO and ENSO, which are closely related to the updated cumulus parameterization scheme, as well as the alleviation of uncertainties in some key parameters in shallow and deep convection schemes, cloud fraction, cloud macro/microphysical processes and the boundary layer scheme in its atmospheric model. The annual cycle of sea surface temperature along the equator in the Pacific is significantly improved in the new version. The sea ice salinity simulation is one of the unique characteristics of FGOALS-g2, although it is somehow inconsistent with empirical observations in the Antarctic.     

大气二氧化碳对CO2激光辐射各谱线的吸收

本文给出了大气二氧化碳对CO_2激光辐射各谱线吸收的计算公式,并利用标准大气资料计算了各谱线的吸收值。发现在P支谱线中,P(16)线吸收最大;在R支谱线中,R(16)线为最大。当转动量子数J大于或小于16时,吸收值随J值的增大或减小几乎成指数减小。为了验证计算公式的可靠性,在实验室中进行了模拟大气测量,其测量结果和理论计算结果具有较好的一致性。     

Ly(α) absorption cross-section of H2O and O2

The absorption cross-sections of water vapor and oxygen were measured, using a low-pressure radio frequency discharge through traces of hydrogen in argon as a light source for Ly() radiation. The cross-sections are H₂O = 1.59 × 10^–17 cm² and O₂ = 1.13 × 10^–20 + 1.72 × 10^–23 for water and oxygen, respectively, where P is the oxygen pressure in units of Torr. Ly() lamps, such as used for this work, are important light sources for photochemical laboratory work and find applications for trace-gas detection in the atmosphere. For the latter application, accurate cross-sections of water vapor and oxygen are needed.     

Consequences of Incomplete Surface Energy Balance Closure for CO2 Fluxes from Open-Path CO2/H2O Infrared Gas Analysers

We present an approach for assessing the impact of systematic biases in measured energy fluxes on CO₂ flux estimates obtained from open-path eddy-covariance systems. In our analysis, we present equations to analyse the propagation of errors through the Webb, Pearman, and Leuning (WPL) algorithm [Quart. J. Roy. Meteorol. Soc. 106, 85–100, 1980] that is widely used to account for density fluctuations on CO₂ flux measurements. Our results suggest that incomplete energy balance closure does not necessarily lead to an underestimation of CO₂ fluxes despite the existence of surface energy imbalance; either an overestimation or underestimation of CO₂ fluxes is possible depending on local atmospheric conditions and measurement errors in the sensible heat, latent heat, and CO₂ fluxes. We use open-path eddy-covariance fluxes measured over a black spruce forest in interior Alaska to explore several energy imbalance scenarios and their consequences for CO₂ fluxes.     

Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.     

Measurements of stratospheric HO2 and NO2 by matrix isolation and ESR spectroscopy

Vertical profiles of stratospheric HO₂ and NO₂ concentrations were determined using matrix isolation and ESR. Up to 10 different samples per flight were collected in situ by a balloon borne cryosampler. Free radicals and trace constituents which are condensable at 68 K are trapped in a polycristalline H₂O or D₂O matrix. After collection, the samples are stored at a temperature below 83 K until they are analysed in the laboratory by X-band ESR spectroscopy at 4 K. The HO₂ and NO₂ were identified and calibrated by comparison with standard samples collected in the laboratory under typical stratospheric sampling conditions. From several flights over Southern France (44°N) we obtained two profiles of the stratospheric NO₂ mixing ratio. One, from 21 October 1982, agrees well with previous measurements. The other, from 8 October 1981, is lower by one order of magnitude. The few HO₂ data obtained around 35 km altitude agree with previous measurements. An isolated measurement at 17 km altitude is one order of magnitude higher than the model predicted HO₂ concentration.     

Climatic change in Britain: Is SO2 more significant than CO2?

Summary Many climate scientists have suggested that anthropogenic emissions of greenhouse gases may create severe climate problems for Britain; however, the potential cooling effects of sulphur dioxide are widely acknowledged. In this investigation, we analyze British mean annual temperature, mean annual precipitation, and mean diurnal air temperature range over the period 1929–1988. Our analyses of these records reveal (a) a shift in the early 1950s away from warming and toward cooling, (b) a relative decline in maximum air temperatures when compared to minimum air temperatures, (c) a strong decline in the diurnal air temperature range and (d) a significant linkage between diurnal temperature range and precipitation. Given these signals in the observed climate record, it would appear that SO₂ rather than CO₂ has been the major anthropogenic climate influence in Britain over the past four decades.With 6 Figures     

Evaluation of grid-point atmospheric model of IAP LASG version 2 (GAMIL2)

The Grid-point Atmospheric Model of IAP LASG version 2 (GAMIL2) has been developed through upgrading the deep convection parameterization, cumulus cloud fraction and two-moment cloud microphysical scheme, as well as changing some of the large uncertain parameters. In this paper, its performance is evaluated, and the results suggest that there are some significant improvements in GAMIL2 compared to the previous version GAMIL1, for example, the components of the energy budget at the top of atmosphere (TOA) and surface; the geographic distribution of shortwave cloud radiative forcing (SWCF); the ratio of stratiform versus total rainfall; the response of atmospheric circulation to the tropical ocean; and the eastward propagation and spatiotemporal structures of the Madden Julian Oscillation (MJO). Furthermore, the indirect aerosols effect (IAE) is -0.94 W m-2, within the range of 0 to -2 W m-2 given by the IPCC 4th Assessment Report (2007). The influence of uncertain parameters on the MJO and radiation fluxes is also discussed.