Quality, palynology, and palaeoenvironmental interpretation of the Ilgin lignite, Turkey

The Ilgin lignite field can be subdivided into the Haramiköy and Kurugöl areas which are separated by an area of basement and a fault. The lignite-bearing sequence consists mainly of fluvial and lacustrine Neogene deposits. The Ilgin lignite, averaging 8 m (up to 25 m) thick, is blackish brown and dark brown in colour. The lignite contains abundant brown wood, plant remains and white gastropod shells. Samples have an average of 38.9% moisture on an as-received basis and a mean of 3.9% total sulphur on an air-dried basis. Geochemical analysis, using an ICP-MS, was undertaken. Thirteen lignite core samples from three boreholes drilled in the Kurugöl area were ashed at 750°C. The average trace element contents of the lignite show a higher concentration of U (average 43 ppm) when compared to the range for most coals in the world, while the others (Ti, P, Sc, Be, Mn, Co, Cu, Zn, Ga, As, Rb, Sr, Zr, Nb, Mo, Cs, Ba, Y, Ta, W, Tl, Pb, Bi, Th, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, Lu) agree with the global ranges. The Ilgin lignite is identified as of Middle Miocene (Middle Serravallian) age and occurs within lacustrine sediments deposited under subtropical climatic conditions.     

Occurrence,distribution, and composition of sulfide minerals,Boulder batholith,montana

Sulfide minerals in the Boulder batholith occur 1. as disseminated grains, visible in hand specimens; 2. in aplitic-pegmatitic pods and masses; 3. along joint and shear surfaces; 4. in hydrothermal veins; and 5. as minute masses within pyrite and silicate minerals and along intergranular sites. Hydrothermally altered rocks have an average sulfide content of 0.8 weight per cent, compared to an average of 0.01 per cent for unaltered rocks. Unaltered rock of the batholith may contain as much as 0.7 weight per cent sulfide. Sulfide inclusions in pyrite, the most abundant sulfide of the batholith, are common and represent a captured iss-phase which later changed to chalcopyrite plus pyrrhotite or mackinawite. Inclusions are most abundant, and more complex, in pyrites of hydrothermally altered and ore rocks. Electron-probe analyses show that pyrites of the Boulder batholith have very similar compositions to those found for pyrites from other ore deposits around the world.     

Transformations of the stuffed cristobalites, K2MSiO4, M=Mg, Zn, Co, Cd, with temperature and composition

The effects of composition and of temperature on the orthorhombic, Pca2 ₁ to cubic, F4ˉ3m transition of the stuffed cristobalite structure are reported. A distorton index which measures the departure of the orthorhombic unit cell from a metrically cubic cell shows that at room temperature, distortion increases in the progression K₂CdSiO₄ <K₂MgSiO₄ <K₂ZnSiO₄≈K₂CoSiO₄. High temperature X-ray powder measurements document an apparently discontinuous transition to a structure of F4ˉ3m symmetry. Differential scanning calorimetry shows a sharp, reversible, first order transition to the high temperature phase at about 500–600 °C for these compounds. Measured transformation enthalpies in the range of 7 to 16 J/g correlate roughly with the distortion index. The transformation involves tetrahedral rotation to an orientationally disordered cubic structure which retains an ordered M²⁺/Si distribution. Received: 8 November 1996 / Revised, accepted: 14 October 1997     

Nd,Sr, Pb,Ar, and 0 isotopic systematics of Sturgeon Lake kimberlite,Saskatchewan, Canada: constraints on emplacement age,alteration, and source composition

Rb-Sr isotopic dating of phlogopite megacryst samples separated from Sturgeon Lake kimberlite, Saskatchewan, yields a crystallization age of 98±1 Ma (2 , MSWD=1.2; ⁸⁷Sr/⁸⁶Sr(t)=0.7059). The ⁴⁰Ar/³⁹Ar analyses of a phlogopite megacryst sample indicate the presence of large amounts of excess ⁴⁰Ar and yield an excessively old age of 410 Ma. Assessment of the Ar data using isotope correlation plots indicates clustering of the data points about a mixing line between the radiogenic ⁴⁰Ar component at 98 Ma and a trapped component with uniform ³⁶Ar/⁴⁰Ar and Cl/⁴⁰Ar. Values of {ie212-1} as high as +20%. (VSMOW) for calcite from the groundmass and a whole-rock sample indicate pervasive lowtemperature alteration. The {ie212-2} of matrix carbonate is-11.3%. (PDB), slightly lighter than typical values from the literature. The {ie212-3} values of about +5%. (VSMOW) for brown phlogopite megacrysts may be primary, green phlogopites are interpreted to be an alteration product of the brown variety and are 2%. heavier. Initial Nd-Sr-Pb isotopic ratios for a whole-rock sample {ie212-4}; ⁸⁷Sr/⁸⁶Sr=0.7063, ²⁰⁶Pb/²⁰⁴Pb=18.67, ²⁰⁷Pb/²⁰⁴Pb=15.54, ²⁰⁸Pb/²⁰⁴Pb=38.97) suggest an affinity with group I kimberlites. Initial {ie212-5} values of +1.7 and +0.5 (⁸⁷Sr/ ⁸⁶Sr(t)=0.7053 and 0.7050) for eclogitic and lherzolitic garnet megacryst samples, and values of 0.0 for two phlogopite megacryst samples reflect an origin from an isotopically evolving melt due to assimilation of heterogeneous mantle. Lilac high-Cr lherzolitic garnet megacrysts give an unusually high {ie212-6} of +28.6 (⁸⁷Sr/⁸⁶Sr=0.7046) indicating a xenocrystic origin probably from the lithospheric mantle. The very radiogenic ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb ratios of the kimberlite are consistent with melting of EM II (enriched) mantle components.     

关于加强我国实物地质资料统筹保管工作的思考

实物地质资料是地质勘探工作形成的宝贵资源,确保重要实物地质资料安全妥善保管是实现其潜在价值有效保存和高效利用的重要保障,而如何改进日益增长的重要岩芯保管需求和有限的库房建设之间的矛盾,是当前我国实物地质资料保管工作面临的重要问题。本文系统总结了近年来我国实物地质资料保管工作在制度建设、库房建设等方面取得的重要成果,分析了当前面临的主要问题,研究并提出了我国实物地质资料统筹保管工作的总体布局、机制建立等方面的建议,为提升我国实物地质资料统筹保管能力提供参考     

Sm-Nd isotope study of early Archean rocks,Qianan, Hebei Province,China

A Sm-Nd study of mafic amphibolite which occurs as lensoid masses in migmatitic quartz dioriticto-granitic gneiss was undertaken in order to determine if it has an early Archean age. Six amphibolite samples define an isochron yielding an age of 3.50 ± 0.08 b.y. with an initial ϵ_Nd value of +3.3 ± 0.3.. Three samples of quartz dioritic gneiss lie close to this isochron, and have Sm-Nd model ages of ca. 3.5 b.y. referenced to a “epleted mantle” source. A sample of K-feldspar-rich granitic gneiss gives a younger model age of about 2.9 b.y. The non-zero initial ϵ_Nd value of the mafic amphibolites can be compared with chondritic meteorite samples measured in this laboratory, and is, therefore, precisely determined. If the initial ϵ_Nd value can be regarded as representative of the original igneous rocks, then it indicates that the mantle magma source was severely depleted with respect to magmaphile elements. This suggests that the geochemistry of the early Archean mantle may have been similar to that of the modern upper mantle and may require that a large pre-Archean continental crust have been present on the earth.     

Thermoluminescence dating of sediments from Oulainen and Vimpeli, Ostrobothnia, Finland

Mean ages of 94 ka and 121 ka were obtained at Oulainen for two sand layers situated above and below an organic deposit previously correlated with the Brörup interstadial. At Vimpeli, TL dates obtained for sand layers embedded in an organic deposit suggest an age for this deposit of 107 ka. The uncertainty in this result is considerable, however. Problems encountered in dating these sediments and the reliability of the results are discussed.     

Arsenic mobility in alteration products of sulfide-rich, arsenopyrite-bearing mine wastes, Snow Lake, Manitoba, Canada

The Arsenopyrite Residue Stockpile (ARS) in Snow Lake, Manitoba contains approximately 250,000 tons of cyanide treated, refractory arsenopyrite ore concentrate. The residue was deposited between 1950 and 1959 in an open waste rock impoundment, and remained exposed until 2000, when the pile was capped with layers of waste rock and clay. During the time when the ARS was exposed to the atmosphere, arsenopyrite, pyrrhotite, pyrite and chalcopyrite were oxidized producing scorodite, jarosite and two generations of amorphous Fe sulfo-arsenates (AISA). These secondary phases attenuated some of the As released to pore water during oxidation in the upper layers of the ARS. The imposition of the cap prevented further oxidation. The secondary As minerals are not stable in the reduced environment that currently dominates the pile. Therefore, As currently is being released into the groundwater. Water in an adjacent monitoring well has concentrations of >20 mg/L total As with relative predominance of As(III).     

A New Sauropod, Gongxianosaurus, from the Lower Jurassic of Sichuan, China

The paper describes an early and primitive sauropod dinosaur, Gongxianosaurus shibeiensis (gen. et sp. nov.), from the Dongyuemiao Member of the Lower Jurassic Ziliujing Formation in Shibei Township, Gongxian County, Sichuan Province, China, which is one of the 5 dinosaur fossils discovered in Gongxian in 1997. Except the skull which is incomplete, the fossils are well preserved. It has some features of both sauropods and prosauropods. It is an intermediate type in the evolution of dinosaurs from prosauropods to sauropods and provides materials for the study of the origin and evolution of the sauropod dinosaur fauna. The discovery of this new sauropod furnishes a way for the stratigraphic correlation between the Early Jurassic Ziliujing Formation in the Sichuan basin and the Lower Jurassic Lufeng Formation in the Central Yunnan basin.     

Vein formation and distribution,Ohio and Mt. Baldy districts,Marysvale, Piute County,Utah, USA

The Ohio and Mt. Baldy mining districts near Marysvale, Utah, are situated within a calc-alkalic rock assemblage of the Bullion Canyon Volcanics. The assemblage is divisible into three portions: 1) a lower laharic sequence of epiclastic breccias and autobreccias, 2) a middle portion containing mostly lava flows, including a dacite flow with cupola magma characteristics, and tuff and lapilli breccias, and 3) an upper portion containing a local volcanic vent complex and the ash-flow Delano Peak Tuff Member. Fissuring and veining accompanied magmatic doming. Vein types include: 1) early-stage quartz veins, 2) preproductive main-stage quartz veins, 3) productive main-stage quartz veins, and 4) alunite veins. Each vein of the latter two types is surrounded by advanced argillic, sericitic, argillic, and propylitic alteration halos. Environmental changes during vein fluid deposition account for a district wide zonation of vein types: 1) the boiling level accounts for bonanza precious metal deposits at shallower depths than base metal deposits, and 2) a change from an alkaline or neutral state to an acidic, oxygenated environment, near the paleo-water table, accounts for the presence of alunite veins at shallower depths than ore-bearing veins. Vein mineralogy and texture, wallrock alteration, and geologic structure suggest that an unexposed, ore-generating pluton underlies the area and that the districts represent fringe area mineralization and surface expression of a postulated, ore-bearing pluton.     

Geological,geochemical, stable isotope,and fluid inclusion characteristics of epithermal gold mineralization,Velvet District,Nevada

Gold mineralization in the Velvet District occurs in an eastward dipping sequence of late Tertiary rhyolitic ash-flow tuffs, flows, and tuffaceous sediments in northwestern Nevada. Minor gold and silver concentrations are associated with irregular zones of brecciation, argillic alteration, and quartz veining along north-northeast trending normal faults. Reaction of mineralizing fluids with wallrock produced an argillic alteration assemblage of illite, mixed-layer clays, smectite, and kaolinite. Illite alteration and highest gold concentrations appear to be associated with zones of high water/rock ratios. Kaolinite, smectite, alunite, and opal are postulated to have formed during a steam-dominated episode of alteration.Fluid inclusion studies indicate that the quartz veins were deposited in the temperature range 230 to 280°C from fluids which had salinities equivalent to 0.2–0.8 weight percent NaCl. δ ¹⁸O of quartz veins varies from ?2.5 to $\text{+6.7 ‰}$ and indicates that the ore fluid must have been Tertiary meteroric water. Stable isotope data appear to define a zone of concentrated fluid flow and potential subsurface mineralization in the southeastern part of the district. Fluid inclusion and isotope studies can be used in combination with more standard geochemical, geophysical, and geological information to provide site-specific targets for epithermal metal concentrations.     

Organic Facies Characteristics of Quaternary Sediments,Gulf of Izmit,Marmara Sea,Turkey

The classification of organic facies from samples obtained by submarine drilling between Hersek Burnu and Kaba Burun in the Gulf of Izmit was determined using organic geochemistry methods. The host sediment is composed of pebbles, sand, silt, and clay, some of which are rich in organic matter. Results indicate an early diagenesis stage according to total organic carbon (0.11-1.78%) and vitrinite reflectance (0.12-0.32%) values. Rock-Eval pyrolysis data display hydrogen indices (HI) of 3 to 97 mg HC/g TOC and oxygen indices (OI) of 29 to 245 mg HC/g CO₂. Microscopic studies show that the dominant organic matter is oxic and terrestrial. These data demonstrate that the organic facies were developed in this environment. The CD facies reflects a mixture of source materials including terrestrial plant detritus, and reworked and fine-grained amorphous organic matter. The D facies consists of highly decomposed, reworked organic matter. These types of organic facies generally appear to be weakly sorted in marine and lake sediments.     

Recession of Milam Glacier,Kumaun Himalaya,Observed via Lichenometric Dating of Moraines

Glaciers being very sensitive to climate change have been identified as one of the best indicators of climate change and evidences have proved that most of the Himalayan glaciers have receded with an increased rate during the recent past under the influence of global warming. Lichenometric study was carried out on the moraines of Milam glacier (located in Pithoragarh district of Uttarakhand) with the help of lichen species Dimelaena oreina having an average annual growth rate of 1.31 mm. The study revealed that Milam glacier has receded 1450 m in last 69.37 years with an average recession rate of 20.90 m/year. Since lichenometric studies are cost effective and ecofriendly in comparison to carbon dating, satellite and remote sensing based studies and also reliable, hence, it should be promoted in Himalaya which is an abode of glaciers.     

Architecture of vertically stacked fluvial deposits,Atane Formation,Cretaceous, Nuussuaq,central West Greenland

Excellent exposures of thick, multistorey, fluvial deposits from the deltaic Atane Formation on south‐east Nuussuaq, central West Greenland, show the architecture of up to 100 m thick continuously aggrading fluvial depositional complexes. The succession comprises vertically stacked channel belt sandstones separated by thin floodplain deposits, with little to no incision between storeys. Architectural elements and palaeocurrent patterns of channel deposits indicate deposition in large, relatively stable, low‐sinuosity rivers, probably located within an incised valley. Gradual transitions from channel to floodplain deposits accompanied by a gradual change from floodplain to spillover sand suggest avulsion on the floodplain as a possible mechanism for the vertically alternating channel and floodplain deposits. Despite its relative proximity to contemporaneous sea‐level (ca 35 km upstream from the palaeo‐shoreline) the depositional complex is entirely non‐marine. The aggrading nature of the deposits suggests a continuously rising base level coupled with a high and steady sediment supply. Vertical alternations between floodplain and channel deposits may be forced by subtle interruptions in this balance or autocyclic mechanisms on the floodplain. This study provides an example of aggrading lowstand/non‐marine transgressive systems tract deposits.     

Ore petrology and metamorphic history of Zn-Pb ores,Monteneve, Tyrol,N. Italy

Bands of sphalerite, pyrrhotite, galena, and chalcopyrite are found within and conformable with two distinctive stratigraphic horizons of the metasedimentary Breonie Metalliferous series of northern Italy. Banding is attributable to deposition and metamorphism. Gangue minerals and ore minerals are intergrown and of comparable grain size. Sulfide textures, an older and a younger generation, are metamorphic in origin. Older textures include porphyroblasts, coarse grain, annealing twins, and concentrations of selected minerals along grain boundaries and in fold hinges. Younger generation textures include minute fractures, breccia, mylonite, mineral preferred orientation, deformation twins, linear arrays of small grains, grain size reduction of an order of magnitude, and pressure shadows. The younger deformation textures were slightly modified by syntectonic and posttectonic recrystallization, annealing, and grain growth. Metamorphic textures combined to erase original depositional features except for the layering and conformability inherited from an early sedimentary sulfide setting.Work carried out within the "Progetto Finalizzato Geodinamica", subproject 4, Operative Unit 4. 2. 3., C. N. R. contracts nos. 78. 00821, 79. 00509, 80. 01380. Publication No. 422 of the "Progetto Finalizzato Geodinamica"     

A morphological, sedimentological and geophysical investigation of the Woore Moraine, Shropshire, England

The Bar Hill-Whitchurch-Wrexham Morainic Complex is a large-scale glacial landform thought to represent either the maximum extent or the re-advance of the British-Irish Ice Sheet during the Late Devensian. The origin of the moraine remains uncertain as its key characteristics have not been studied in detail due to a lack of exposures from which its large-scale structure can be determined. The development of new technologies has enabled detailed examination of the topography and internal structure of such large-scale landforms. This paper describes a multi-disciplinary approach involving digital geomorphological mapping using enhanced resolution NextMAP™ digital surface models, geophysical imaging (electrical resistivity tomography) and conventional sedimentological analyses. This combination of techniques is useful for elucidating the origin of a large glacial landform in a region of poor exposure. Digital elevation models such as NextMAP™ offer an efficient and accurate method for landform-mapping, whilst electrical resistivity tomography was able to map the major constituent sediments of the moraine, which had in turn been identified in the single exposure available. Additional geophysical techniques should however be applied to provide further structural data and thereby enable a more detailed interpretation of the moraine's internal structure. Preliminary findings indicate that the moraine is a glaciotectonic landform composed of diamicton and glaciofluvial sediments, an origin consistent with recent suggestions that the Cheshire Plain contained an active ice lobe during the last glacial maximum.     

Anatomical Study of Cretaceous, Permineralized, Bennettitalean Fossils from Heilongjiang Province, NE China

Well-preserved Cretaceous trunk fragments of Cycadeoidea (Cycadeoidaceae) were recently found in Keshan County, Heilongjiang Province, Northeast China. These fossils represent important evidence of the distribution of this group of plants in East Asia. In these trunk fragments, the stem cortices and leaf bases with cones are preserved. The leaf bases are rhombic with cones infrequently distributed among leaf bases. The cortex is broad and consists of fundamental parenchyma cells, numerous secretory ducts and C-shaped leaf traces with adaxial secondary xylem and abaxial secondary phloem. The genus Cycadeoidea, which is widely distributed in the Cretaceous deposits of East Asia, North America and Western Europe, was an important component of Cretaceous floras. Bennettitalean trunk fossils with well-preserved anatomical structures are rarely known from China. These fossils are important for studies of the evolution of genus Cycadeoidea and for stratigraphic correlation.     

Cycling of trace metals (Mn, Fe, Mo, U, V, Cr) in deep pore waters of intertidal flat sediments

Trace metals (Mn, Fe, Mo, U, Cr, V) were studied in pore waters of an intertidal flat located in the German Wadden Sea. The study system is an example of a permeable tidal flat system where pore water exchange is affected by tidal driven pressure gradients besides diffusion. Permanently installed in situ samplers were used to extract pore waters down to 5 m depth throughout one year. The samplers were either located close to the tidal flat margin or in central parts of the tidal flat. Despite dynamic sedimentological and hydrological conditions, the general trends with depth in deep tidal flat pore waters are remarkably similar to those observed in deep sea environments. Rates of trace metal cycling must be comparably large in order to maintain the observed pore water profiles. Trace metals further show similar general trends with depth close to the margin and in central parts of the tidal flat. Seasonal sampling revealed that V and Cr vary concurrent with seasonal changes in dissolved organic carbon (DOC) concentration. This effect is most notable close to the tidal flat margin where sulphate, DOC, and nutrients vary with season down to some metres depth. Seasonal variations of Mn, Fe, Mo, and U are by contrast limited to the upper decimetres of the sediment. Their seasonal patterns depend on organic matter supply, redox stratification, and particulate matter deposited on sediment surfaces. Pore water sampling within one tidal cycle provides evidence for pore water advection in margin sediments. During low tide pore water flow towards the creekbank is generated by a hydraulic gradient suggesting that deep pore waters may be seeping out of creekbank sediments. Owing to the enrichment of specific elements like Mn in pore water compared to sea water, seeping pore waters may have an impact on the chemistry of the open water column. Mass balance calculations reveal that the impact of deep pore waters on the Mn budget in the open water column is below 4%. Mn deep pore water discharge of the whole Wadden Sea is estimated to be about 9% of the total dissolved riverine Mn input into the Southern North Sea.     

Holocene evolution of a coastal lagoon, Lake of Tunis, Tunisia

Historical records demonstrate that the Lake of Tunis, Tunisia, was an open bay that became separated from the Mediterranean by an accreting barrier spit, forming a lagoon. Closure of the lagoon was caused by increased sedimentation as a consequence of Roman deforestation of the Medjerda River drainage basin to the north and subsequent accelerated longshore transport. The separation of the lagoon from the Mediterranean was completed in the early 1500s. At present, the 48 km² lagoon averages less than 1 m in depth and reaches eutrophic conditions in the late summer. Consistent with the historical records, the lagoon sedimentary column shows three distinct successive environments of deposition: (1) an arid continental environment; (2) an open marine bay; and (3) the present brackish to hypersaline lagoon. These depositional environments are represented by the lower grey layer, which is less than 0-5 m thick, the middle olive-grey layer, which varies from 1 to 5 m in thickness, and the upper black layer, which is 1 m thick. All of the strata are predominantly silt plus clay, but usually contain at least 10% sand. The lower grey layer consists of pitted quartz sand, with very few abraded, broken molluscan fragments and benthic foraminifera with thick tests. An arid, subaerial depositional environment of latest Pleistocene time best explains these sediment and fossil assemblages. In the middle olive-grey layer, coral, coralline algae, open marine graeses and the dominance of foraminifera over ostracods (expressed as a low percentage of ostracods/ostracods plus foraminifera) attest to a depositional environment of an open marine bay. A sharp increase in the percentage of ostracods/ostracods plus foraminifera and organic carbon from the middle olive-grey layer to the upper black layer signifies a major change in depositional environment. The predominance of ostracods over foraminifera, abundance of gastropods characteristic of eutrophic conditions, high organic carbon content and absence of macro-fossils characteristic of open marine conditions clearly indicate that the upper black layer was deposited in a brackish to hypersaline, eutrophic lagoon which has persisted to the present. Seismic records indicate a karstic bedrock surface underlying the lagoon. The surface is marked by considerable relief, and shows a linear depression which may represent an early sixteenth century ship canal. Heavy metal analyses of total samples in five cores demonstrate that Mn and Fe vary randomly, and are apparently derived from natural sources only. Cd, Cr, Pb, Cu and Zn are typically highest in the uppermost unit, which reflects levels of human contamination since closure of the lagoon.