Eclogites of the Snowbird tectonic zone: petrological and U-Pb geochronological evidence for Paleoproterozoic high-pressure metamorphism in the western Canadian Shield

Eclogite occurs within the southern domain of the East Athabasca mylonite triangle in northern Saskatchewan. Situated at the boundary between the Archean Rae and Hearne Provinces of the western Canadian Shield, the East Athabasca mylonite triangle is a fundamental exposure of the ~3,000-km-long Snowbird tectonic zone. The eclogite occurs in association with a variety of lower crustal high-pressure granulites that record a complex metamorphic history from 2.6 to 1.9 Ga. Temperatures of the eclogite facies metamorphism are constrained by garnet-clinopyroxene exchange thermometry at 920–1,000 °C. Minimum pressure conditions are recorded by the jadeite+quartz=albite geobarometer at 1.8–2.0 GPa. A near-isothermal decompression path to granulite facies conditions is inferred from retrograde reaction textures involving the formation of granulite facies assemblages such as orthopyroxene-plagioclase and pargasite-plagioclase. U-Pb IDTIMS zircon geochronology of the eclogite yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb date of 1,904.0±0.3 Ma, which we interpret as the time of peak eclogite facies metamorphism. SHRIMP in situ analyses of metamorphic zircons included within omphacitic clinopyroxene support this interpretation with a weighted mean ²⁰⁷Pb/²⁰⁶Pb date of 1,905±19 Ma. Inclusion suites of high-pressure phases and the petrographic setting of zircon are a direct link between zircon growth and eclogite facies metamorphism. Zircon from one eclogite sample has older cores that are 2.54 Ga, which is a minimum age for the emplacement or earliest metamorphism of the gabbroic protolith. U-Pb rutile data indicate slow cooling at ~1°C/Ma below ~500 °C from 1.88 to 1.85 Ga. The formation and exhumation of the eclogites at ca.1.9 Ga has important implications for the tectonic significance of the Snowbird tectonic zone during the Paleoproterozoic. The eclogites described here are consistent with transport of continental crust to mantle depths during the Paleoproterozoic, followed by rapid buoyancy-driven exhumation to normal lower crustal depths.Editorial responsibility: T.L. Grove     

南阿尔金高压-超高温麻粒岩变质作用:大陆地壳超深俯冲与折返过程的记录

南阿尔金造山带是目前报道的具有最深俯冲记录的大陆超高压变质带,其内出露有高压-超高温麻粒岩,它们对深入理解大陆地壳岩石超深俯冲与折返过程具有重要意义.介绍了对南阿尔金巴什瓦克地区长英质麻粒岩和基性麻粒岩的岩相学、矿物化学、相平衡模拟及锆石U-Pb年代学研究成果.其中基性麻粒岩主要记录了深俯冲大陆地壳折返过程的变质演化:包括高压榴辉岩相、高压-超高温麻粒岩相、低压-超高温麻粒岩相及随后的近等压降温演化阶段;长英质麻粒岩除了记录与基性麻粒岩相似的折返过程外,还记录了从角闪岩相到超高压榴辉岩相的进变质演化过程.结合已有研究资料,确定超高压榴辉岩阶段峰期条件> 7~9 GPa和>1 000℃,可达到斯石英稳定域.锆石年代学显示两种岩石类型的原岩和变质年龄均分别在900 Ma和500 Ma左右.变质作用与年代学研究表明,南阿尔金大陆地壳岩石在早古生代发生超深俯冲至200~300 km后,折返至加厚地壳底部发生高压-超高温变质作用,随后被快速抬升至地壳浅部发生低压-超高温变质作用并经历迅速冷却.      

Oxygen and carbon isotopic constraints on the development of eclogites, Holsnøy, Norway

Eclogite formation on the island of Holsnøy required the addition of water to anhydrous granulite-facies protoliths. In order to assess this process, oxygen and carbon isotope ratios of whole rock powders and mineral separates from eclogites and granulites have been measured. Whole rock oxygen isotope ratios range from 7.3 to 6.0%. SMOW in granulites (average = 6.38%.) and 7.2 to 6.1%. in eclogites (average = 6.55%.). Field relations permit identification of the granulite protolith of eclogites. Oxygen isotope measurements show shifts of up to 0.5%. between some eclogites compared to their corresponding granulite protoliths, indicating open system and locally heterogeneous fluid behavior. Mineral pair fractionations in the eclogites show disequilibrium, are incompatible with slow cooling and diffusive exchange between phases, and suggest that open system fluid movement continued after eclogite-facies metamorphism. Carbonate is also present in some of the eclogites as a primary mineral (dolomite) and as part of a retrograde assemblage (calcite). Textural evidence suggests that carbonate formation occurred during and after eclogite formation, however all measured carbonate is out of isotopic equilibrium with eclogite facies minerals, due to the influx of retrograde fluids. Massive calcite marble pods, containing amphibolite facies cale-silicate minerals, have average δ¹⁸O of 9.5 ± 0.6%., while calcite in retrograded eclogites has δ¹⁸O 17.7 ± 2.7%., The δ¹³C (≈ −4 ± 0.8%.) is indistinguishable between these two groups.

Both whole rock and carbonate stable isotope data are interpreted as indicating a continued history of fluid infiltration during and after peak eclogite facies metamorphism. The most probable source of fluids are from dewatered sediments tectonically juxtaposed during the Caledonian orogeny.     

Retention of Precambrian Rb/Sr phlogopite ages through Caledonian eclogite facies metamorphism, Bergen Arc Complex, W-Norway

The Lindås Nappe, Caledonides W-Norway was affected by two major tectonometamorphic events. A Precambrian granulite facies event at T=800–900°C, P<10 kbar was followed by localized Caledonian eclogite facies (T=650–700°C and P>15 kbar) and localized amphibolite facies reworking. During the granulite–eclogite facies transition, anorthositic rocks were converted from garnet granulites to kyanite eclogites, while phlogopite-bearing spinel lherzolite reacted to garnet lherzolite. The eclogite and amphibolite facies reequilibration took place along shear zones and fluid pathways. In the unhydrated and undeformed parts, the minerals preserved their granulite facies composition with constant Fe/Mg ratios from core to rim, suggesting diffusional reequilibration. Rb/Sr age dating was carried out on relict granulite facies minerals from three lenses of ultramafites (Alvfjellet, Hundskjeften and Kvamsfjellet). Phlogopite from phlogopite lherzolite at Alvfjellet give 857±9 Ma, while clinopyroxene, amphibole, phlogopite and whole rock from a lherzolite at Hundskjeften yield an age of 842±12 Ma (MSWD=1.9). Clinopyroxene, feldspar, orthopyroxene phlogopite and whole rock from websterite, Kvamsfjellet, yield an age of 835±7 Ma (MSWD<1), while clinopyroxene, phlogopite and whole rock from a lherzolite from the same lens gives a result of 882±9 Ma. These results are interpreted as minimum ages for the granulite facies event and only slightly younger than, or overlap with previous U–Pb zircon ages (929±1 Ma) and Sm–Nd garnet–pyroxene ages (890–923 Ma) interpreted to date the end of the granulite facies event. By contrast, ages obtained for the eclogite and amphibolite facies range from 460 (U–Pb, sphene), 440 (Ar–Ar), 419 (U–Pb, zircon) to 410 Ma (Rb/Sr mineral ages).

These results demonstrate that the reopening temperature for the Rb/Sr system in phlogopite–biotite under dry and static high-pressure conditions is, in the given mineral assemblages, at least 650°C, considerably higher than the 300–400°C assumed as the closure temperature of this system. We ascribe this elevated reopening temperature to fluid absent conditions that prevented element transport and rehomogenization.     

造山带中成对出现的高压麻粒岩与榴辉岩及其地球动力学意义

在一些典型碰撞造山带中,高压麻粒岩与榴辉岩在空间和时间上密切相关,它们之间的关系对揭示碰撞造山带的造山过程和造山机制具有重要意义.本文以中国西部的南阿尔金、柴北缘及中部的北秦岭造山带为例,详细陈述了这3个地区榴辉岩和相关的高压麻粒岩的野外关系、变质演化和形成时代,目的是要建立大陆碰撞造山带中榴辉岩和相关高压麻粒岩形成的地球动力学背景模式.南阿尔金榴辉岩呈近东西向分布在江尕勒萨依,玉石矿沟一带,与含夕线石副片麻岩、花岗质片麻岩和少量大理岩构成榴辉岩一片麻岩单元,榴辉岩中含有柯石英假象,其峰期变质条件为P=2.8～3.0GPa,T=730～850℃,并在抬升过程中经历了角闪岩-麻粒岩相的叠加;大量年代学研究显示其峰期变质时代为485～500Ma.南阿尔金高压麻粒岩分布在巴什瓦克地区,包括高压基性麻粒岩和高压长英质麻粒岩,它们与超基性岩构成了一个大约5km宽的构造岩石单元,与周围角闪岩相的片麻岩为韧性剪切带接触.长英质麻粒岩和基性麻粒岩的峰期组合均具有蓝晶石和三元长石(已变成条纹长石),形成的温压条件为T=930～1020℃,P=1.8～2.5GPa,并在退变质过程中经历了中压麻粒岩相变质作用叠加.锆石SHRIMP测定显示巴什瓦克高压麻粒岩的峰期变质时代为493～497Ma.都兰地区的榴辉岩分布柴北缘HP-UHP变质带的东端,在榴辉岩和围岩副片麻岩中均发现有柯石英保存,形成的峰期温压条件为T=670～730℃和P=2.7～3.25GPa,退变质阶段经过了角闪岩相的叠加;榴辉岩相变质时代为420～450Mao都兰地区的高压麻粒岩分布在阿尔茨托山西部,高压麻粒岩包括基性麻粒岩长英质麻粒岩,基性麻粒岩的峰期矿物组合为Grt+Cpx+Pl±Ky±Zo+Rt±Qtz,长英质麻粒岩的峰期矿物组合为：Grt+Kf+Ky+Pl+Qtz.峰期变质条件为T=800～925℃,P=1.4～1.85GPa,退变质阶段经历了角闪岩-绿片岩的改造,高压麻粒岩的变质时代为420～450Ma.北秦岭榴辉岩分布在官坡-双槐树一带,榴辉岩的峰期变质组合为Grt+Omp±Phe+Qtz+Rt,所计算的峰期温压条件为T=680～770℃和P=2.25～2.65GPa,年代学数据显示榴辉岩的变质时代为500Ma左右.北秦岭高压麻粒岩分布在含榴辉岩单元的南侧松树沟一带,包括高压基性麻粒岩和高压长英质麻粒岩,与超基性岩在空间上密切伴生,高压麻粒岩的峰期温压条件为T=850～925℃,P=1.45～1.80GPa,锆石U-Pb年代学研究显示其峰期变质时代为485～507Ma.以上三个实例显示,出现在同一造山带、在空间上伴生的高压麻粒岩和榴辉岩有各自不同的变质演化历史,但榴辉岩中的榴辉岩相变质时代和相邻的高压麻粒岩中的高压麻粒岩相变质作用时代相同或相近,这种成对出现的榴辉岩和高压麻粒岩代表了它们同时形成在造山带中不同的构造环境中,即榴辉岩的形成于大陆俯冲带中,而高压麻粒岩可能形成在俯冲带之上增厚的大陆地壳根部.     

Phanerozoic high-pressure eclogite and intermediate-pressure granulite facies metamorphism in the Gyeonggi Massif, South Korea: Implications for the eastward extension of the Dabie–Sulu continental collision zone

Petrological analysis, zircon trace element analysis and SHRIMP zircon U–Pb dating of retrogressed eclogite and garnet granulite from Bibong, Hongseong area, SW Gyeonggi Massif, South Korea provide compelling evidence for Triassic (231.4 ± 3.3 Ma) high-pressure (HP) eclogite facies (M1) metamorphisms at a peak pressure–temperature (P–T) of ca. 16.5–20.0 kb and 775–850 °C. This was followed by isothermal decompression (ITD), with a sharp decrease in pressure from 20 to 10 kb and a slight temperature rise from eclogite facies (M1) to granulite facies (M2), followed by uplift and cooling. Granitic orthogneiss surrounding the Baekdong garnet granulite and the ophiolite-related ultramafic lenticular body near Bibong records evidence for a later Silurian (418 ± 8 Ma) intermediate high-pressure (IHP) granulite facies metamorphism and a prograde P–T path with peak P–T conditions of ca. 13.5 kb and 800 °C. K–Ar ages of biotite from garnet granulites, amphibolites, and granitic orthogneisses in and around the Bibong metabasite lenticular body are 208–219 Ma, recording cooling to about 310 °C after the Early Triassic metamorphic peak. Neoproterozoic zircon cores in the retrogressed eclogite and granitic orthogneiss provide evidence that the protoliths of these rocks were  800 and  900 Ma old, respectively, similar to the ages of tectonic episodes in the Central Orogenic Belt of China. This, and the evidence for Triassic HP/UHP metamorphism in both China and Korea, is consistent with a regional tectonic link within Northeast Asia from the time of Rodinia amalgamation to Triassic continent–continent collision between the North and South China Blocks, and with an eastward extension of the Dabie–Sulu suture zone into the Hongseong area of South Korea.     

北秦岭造山带的早古生代多期变质作用

北秦岭造山带的秦岭岩群以高级变质岩石为特征,主要包括少量榴辉岩、高压麻粒岩和区域上广泛分布的麻粒岩-角闪岩相变质岩石。年代学研究显示秦岭岩群中不同岩石记录了多期变质作用。已有的定年资料给出北秦岭官坡地区的榴辉岩的年龄为500Ma左右,代表榴辉岩相的变质时代。结合岩相学资料,对两个高压麻粒岩样品的SHRIMP和LA-ICPMS U-Pb测定分别获得504±7Ma 和506±3Ma的年龄,应代表高压麻粒岩相变质时代。这表明高压麻粒岩和相邻的榴辉岩有相近的变质时代,但形成在造山带中不同的构热造环境中。西峡地区的角闪二辉麻粒岩的U-Pb定年给出两组早古生代年龄,一组为440±2Ma,可能代表了中低压麻粒岩相的变质时代,另一组为426±1Ma,应代表区域角闪岩相的变质时代。桐柏山北部的石榴二辉麻粒岩的U-Pb定年数据给出436±1Ma的年龄,为中压麻粒岩相的变质时代。这些资料表明北秦岭造山带经历了早奥陶世的俯冲和地壳增厚作用,并在晚志留世遭受了广泛的巴罗式区域变质作用。     

The crust-mantle boundary beneath cratons and craton margins: a transect across the south-west margin of the Kaapvaal craton

“Lower-crustal suite” xenoliths occur in “on-craton” and “off-craton” kimberlites located across the south-western margin of the Kaapvaal craton, southern Africa.

Rock types include mafic granulite (plagioclase-bearing assemblages), eclogite (plagioclase-absent assemblages with omphacitic clinopyroxene) and garnet pyroxenite (“orthopyroxene-bearing eclogite”). The mafic granulites are subdivided into three groups: garnet granulites (cpx + grt + plag + qtz); two pyroxene garnet granulites (cpx + opx + grt + plag); kyanite granulites (cpx + grt + ky + plag + qtz). Reaction microstructures preserved in many of the granulite xenoliths involve the breakdown of plagioclase by a combination of reactions: (1) cpx + plag → grt + qtz; (2) plag → grt + ky + qtz; (3) plag → cpx (jd-rich) + qtz. Compositional zoning in minerals associated with these reactions records the continuous transition from granulite facies mineral assemblages and pressure (P) — temperature (T) conditions to those of eclogite facies.

Two distinct P-T arrays are produced: (1) “off-craton” granulites away from the craton margin define a trend from 680 °C, 7.5 kbar to 850 °C, 12 kbar; (2) granulite xenoliths from kimberlites near the craton margin and “on-craton” granulites produce a trend with similar geothermal gradient but displaced to lower T by ˜ 100 °C. Both P-T fields define higher geothermal gradients than the model steady state conductive continental geotherm (40 mWm²) and are not consistent with the paleogeotherm constructed from mantle-derived garnet peridotite xenoliths.

A model involving intrusion of basic magmas around the crust/mantle boundary followed by isobaric cooling is proposed to explain the thermal history of the lower crust beneath the craton margin. The model is consistent with the thermal evolution of the exposed Namaqua-Natal mobile belt low-pressure granulites and the addition of material from the mantle during the Namaqua thermal event (c. 1150 Ma). The xenolith P-T arrays are not interpreted as representing paleogeotherms at the time of entrainment in the host kimberlite. They most likely record P-T conditions “frozen-in” during various stages of the tectonic juxtaposition of the Namaqua Mobile Belt with the Kaapvaal craton.     

中国大陆科学钻探主孔榴辉岩Sm-Nd年龄及其地质意义

南苏鲁中国大陆科学钻探主孔CCSD-MH及地表的榴辉岩Sm—Nd同位素年龄测试结果显示，每件样品中全岩（Wr)与石榴石(Grt)和绿辉石(Omp)点均在一条直线上。除样品B210R186以外，其余5件榴辉岩均给出十分相近的Sm—Nd等时线年龄，位于202．6-219Ma之间，这与榴辉岩围岩——片麻岩锆石边缘记录的近等温减压退变质年龄(200-220Ma)十分接近，表明测试的榴辉岩中石榴石的Sm—Nd同位素体系有可能在近等温减压退变质时重置，并在向角闪岩相退变质过渡时封闭。因此，笔者测定的202．6-219Ma的Sm-Nd全岩-矿物等时线年龄，应代表了南苏鲁榴辉岩在构造折返过程中近等温减压阶段的退变质年龄，而不能代表苏鲁地体的超高压变质年龄。     

Conditions and timing of high-pressure Variscan metamorphism in the South Carpathians, Romania

High-pressure (HP) metamorphic rocks, including garnet peridotite, eclogite, HP granulite, and HP amphibolite, are important constituents of several tectonostratigraphic units in the pre-Alpine nappe stack of the Getic–Supragetic (GS) basement in the South Carpathians. A Variscan age for HP metamorphism is firmly established by Sm–Nd mineral–whole-rock isochrons for garnet amphibolite, 358±10 Ma, two samples of eclogite, 341±8 and 344±7 Ma, and garnet peridotite, 316±4 Ma.

A prograde history for many HP metamorphic rocks is documented by the presence of lower pressure mineral inclusions and compositional zoning in garnet. Application of commonly accepted thermobarometers to eclogite (grt+cpx±ky±phn±pg±zo) yields a range in “peak” pressures and temperatures of 10.8–22.3 kbar and 545–745 °C, depending on tectonostratigraphic unit and locality. Zoisite equilibria indicate that activity of H₂O in some samples was substantially reduced, ca. 0.1–0.4. HP granulite (grt+cpx+hb+pl) and HP amphibolite (grt+hbl+pl) may have formed by retrogression of eclogites during high-temperature decompression. Two types of garnet peridotite have been recognized, one forming from spinel peridotite at ca. 1150–1300 °C, 25.8–29.0 kbar, and another from plagioclase peridotite at 560 °C, 16.1 kbar.

The Variscan evolution of the pre-Mesozoic basement in the South Carpathians is similar to that in other segments of the European Variscides, including widespread HP metamorphism, in which P–T–t characteristics are specific to individual tectonostratigraphic units, the presence of diverse types of garnet peridotite, diachronous subduction and accretion, nappe assembly in pre-Westphalian time due to collision of Laurussia, Gondwana, and amalgamated terranes, and finally, rapid exhumation, cooling, and deposition of eroded debris in Westphalian to Permian sedimentary basins.     

High-temperature,high-pressure granulites (retrogressed eclogites) in the central region of the Lewisian,NW Scotland: Crustal-scale subduction in the Neoarchaean

Eclogites and associated high-pressure (HP) rocks in collisional and accretionary orogenic belts preserve a record of subduction and exhumation, and provide a key constraint on the tectonic evolution of the continents. Most eclogites that formed at high pressures but low temperatures at > 10–11 kbar and 450–650 °C can be interpreted as a result of subduction of cold oceanic lithosphere. A new class of high-temperature (HT) eclogites that formed above 900 °C and at 14 to 30 kbar occurs in the deep continental crust, but their geodynamic significance and processes of formation are poorly understood. Here we show that Neoarchaean mafic–ultramafic complexes in the central granulite facies region of the Lewisian in NW Scotland contain HP/HT garnet-bearing granulites (retrogressed eclogites), gabbros, lherzolites, and websterites, and that the HP granulites have garnets that contain inclusions of omphacite. From thermodynamic modeling and compositional isopleths we calculate that peak eclogite-facies metamorphism took place at 24–22 kbar and 1060–1040 °C. The geochemical signature of one (G-21) of the samples shows a strong depletion of Eu indicating magma fractionation at a crustal level. The Sm–Nd isochron ages of HP phases record different cooling ages of ca. 2480 and 2330 Ma. We suggest that the layered mafic–ultramafic complexes, which may have formed in an oceanic environment, were subducted to eclogite depths, and exhumed as HP garnet-bearing orogenic peridotites. The layered complexes were engulfed by widespread orthogneisses of tonalite–trondhjemite–granodiorite (TTG) composition with granulite facies assemblages. We propose two possible tectonic models: (1) the fact that the relicts of eclogitic complexes are so widespread in the Scourian can be taken as evidence that a > 90 km × 40 km-size slab of continental crust containing mafic–ultramafic complexes was subducted to at least 70 km depth in the late Archaean. During exhumation the gneiss protoliths were retrogressed to granulite facies assemblages, but the mafic–ultramafic rocks resisted retrogression. (2) The layered complexes of mafic and ultramafic rocks were subducted to eclogite-facies depths and during exhumation under crustal conditions they were intruded by the orthogneiss protoliths (TTG) that were metamorphosed in the granulite facies. Apart from poorly defined UHP metamorphic rocks in Norway, the retrogressed eclogites in the central granulite/retrogressed eclogite facies Lewisian region, NW Scotland have the highest crustal pressures so far reported for Archaean rocks, and demonstrate that lithospheric subduction was transporting crustal rocks to HP depths in the Neoarchaean.     

Diffusion versus recrystallization processes in Rb-Sr geochronology: Isotopic relics in eclogite facies rocks, Western Gneiss Region, Norway

Rb-Sr and U-Pb isotopic data for granulite facies rocks, forming textural relics with respect to eclogite facies metamorphism in the Western Gneiss Region (WGR) of Norway, highlight the importance of textures and mineral reaction kinetics for the interpretation of geochronological data. Studied rocks from Bårdsholmen, southern WGR, were subjected to granulite facies metamorphism at 955 ± 3 Ma (U-Pb, zircon). Later on, they experienced a subduction-related, kinetically stranded eclogitization (T > 650 °C at ∼20 kbar) at 404 ± 2 Ma (Rb-Sr multimineral internal isochron data), followed by exhumation through amphibolite facies conditions. Full conversion of granulite to eclogite was restricted to zones of fluid infiltration and deformation. Despite the fact that metamorphic temperatures vastly exceeded the commonly assumed ‘closure temperature’ for Rb-Sr in submillimeter-sized biotite for several Ma during eclogite facies overprint, Sr-isotopic signatures of relic biotite have not been fully reset. Large biotite crystals nearly record their Sveconorwegian (Grenvillian) crystallization age. Sr signatures of other granulite facies phases (feldspar, pyroxenes, amphibole) remained unchanged, with the exception of apatite. The results imply that isotopic signatures much closer correspond to the P, T conditions of formation recorded by a dated phase and its paragenesis, than to a temperature history. In texturally well-equilibrated high-grade rocks which experienced no mineral reactions and remained devoid of free fluids during exhumation, like granulites or eclogites, isotopic resetting during cooling is either kinetically locked, or restricted to sluggish intermineral diffusion which demonstrably does not lead to full isotopic homogenization. In texturally unequilibrated rocks, textural relics are likely to represent isotopic relics. It is shown that for both high-grade rocks and for rocks with textural disequilibria, geologically meaningful isotopic ages based on isochron methods can only be derived from sub-assemblages in isotopic equilibrium, which have to be defined by analysis of all rock-forming minerals. Conventional two-point ‘mica ages’ for such rocks are a priori geochronologically uninterpretable, and valid multimineral isochron ages a priori do not record cooling but instead date recrystallization-inducing processes like fluid-rock interaction.     

柴北缘绿梁山高压基性麻粒岩的变质演化历史：岩石学及锆石SHRIMP年代学证据

高压基性麻粒岩出露在柴北缘HP/UHP变质带的绿梁山地区,它主要呈透镜体状分布在石榴蓝晶(夕线)黑云片麻岩中。岩石学和矿物学数据显示高压基性麻粒岩经历了多阶段变质历史,早期可能经历了榴辉岩相变质作用(p>15kbar),以石榴子石中保留的少量绿辉石为特征;高压麻粒岩组合(Grt-Cpx-Pl-Qtz±Amp±Rt-Ilm)为退变质作用产物,其形成的变质条件为p=9.6~13.5kbar,T=730~870℃。晚期的变质反应以围绕石榴子石和后成合晶生成斜方辉石的为特征,形成的p-T条件为6.2~8.5kbar和720~860℃。高压基性麻粒岩中的锆石SHRIMP测定共获得两组年龄,分别为(448±3)Ma和(421±5)Ma。结合锆石阴极发光和矿物包体研究,前者代表高压麻粒岩阶段的变质年龄,后者代表晚期与斜方辉石形成有关的中低压麻粒岩阶段的变质年龄。这些年龄结果显示麻粒岩相变质作用持续了大约27Ma,这可能与早古生代祁连地块与柴达木地块碰撞作用所引起的地壳加厚和后来的热松驰有关。     

Petrology and geochronology of eclogites from the Variscan Schwarzwald (F.R.G.)

The Moldanubian basement of the Schwarzwald contains basic to ultrabasic rocks of both crustal and mantle origin which display high-pressure mineral assemblages or relics of such. In order to constrain the P-T-t evolution of the crustal high-pressure rocks, petrological and geochronological studies have been carried out on three eclogite samples. Geothermobarometric estimations indicate minimum metamorphic pressures of 1.6 GPa and equilibration temperatures of 670 750°C. Reaction textures document various metamorphic stages during exhumation of the high-pressure rocks. The age of high-pressure metamorphism is constrained by Sm-Nd isochrons of 332±13 Ma, 334±11 Ma, and 337±6 Ma defined by garnet, whole rock and clinopyroxene. For one sample, large garnets show prominent growth zoning in terms of major elements, Sm, Nd, and inclusions, dividing the grains into two growth stages. Sm-Nd isotope analyses on these garnets indicate that the time span between the two growth stages is too small to be resolved, reflecting a rather rapid metamorphic evolution. This result is further constrained by a Rb-Sr isochron age of 325±6 Ma on retrograde biotite and whole rock on the same sample. For one of the studied eclogites, formation of the magmatic precursor rocks is possibly approximated by the Ordovician U-Pb upper intercept age of a discordia from zircons.     

苏鲁造山带东北端石榴辉石麻粒岩的Sm-Nd同位素年代学及其大地构造含义

大量含石榴石的基性麻粒岩透镜体出露于苏鲁变质带的北部及邻近地区,它们可能是再变质的高压变质岩石。在详细的岩相学研究的基础上,确定采自莱西和文登的样品WD01、WD04、ML06 是由高压麻粒岩经中-高压麻粒岩相再变质形成的,而采自威海的样品WH1 是由柯石英榴辉岩经中-高压麻粒岩相再变质形成的。Sm-Nd 同位素年代学研究也证实了二者的重大差别。3 个高压麻粒岩样品的矿物-全岩内部等时线年龄分别是1 846+ /-76Ma,1 743+ /-79Ma 和1 752+ /-30Ma,TDM 模式年龄是3.3Ga,3.0Ga 和2.8Ga.上述数据说明原岩形成在太古宙,而1 800Ma 是麻粒岩相降压变质事件的记录,这与华北克拉通前寒武纪高压麻粒岩的年代学一致。威海样品的Sm-Nd 同位素特征则完全不同。矿物和全岩形不成等时线,表现出它们之间的同位素不平衡。ε_Nd(0)值高达+ 127,TDM 模式年龄是1.3Ga.这与Jahn(1994,1996)对威海同类样品的测定结果相同。可以推测威海样品的原岩是元古宙岩石,在后来复杂的变质过程中,在水岩相互作用和岩浆及重熔作用的影响下,同位素系统发生重大变化。同位素年代学为苏鲁变质带和华北克拉通的界限是昆嵛山岩浆-变质杂岩带提供了依据。     

苏鲁造山带东北端石榴辉石麻粒岩的Sm-Nd同位素年代学及其大地构造含义

 大量含石榴石的基性麻粒岩透镜体出露于苏鲁变质带的北部及邻近地区,它们可能是再变质的高压变质岩石。在详细的岩相学研究的基础上,确定采自莱西和文登的样品WD01、WD04、ML06 是由高压麻粒岩经中-高压麻粒岩相再变质形成的,而采自威海的样品WH1 是由柯石英榴辉岩经中-高压麻粒岩相再变质形成的。Sm-Nd 同位素年代学研究也证实了二者的重大差别。3 个高压麻粒岩样品的矿物-全岩内部等时线年龄分别是1 846+ /-76Ma,1 743+ /-79Ma 和1 752+ /-30Ma,TDM 模式年龄是3.3Ga,3.0Ga 和2.8Ga.上述数据说明原岩形成在太古宙,而1 800Ma 是麻粒岩相降压变质事件的记录,这与华北克拉通前寒武纪高压麻粒岩的年代学一致。威海样品的Sm-Nd 同位素特征则完全不同。矿物和全岩形不成等时线,表现出它们之间的同位素不平衡。ε_Nd(0)值高达+ 127,TDM 模式年龄是1.3Ga.这与Jahn(1994,1996)对威海同类样品的测定结果相同。可以推测威海样品的原岩是元古宙岩石,在后来复杂的变质过程中,在水岩相互作用和岩浆及重熔作用的影响下,同位素系统发生重大变化。同位素年代学为苏鲁变质带和华北克拉通的界限是昆嵛山岩浆-变质杂岩带提供了依据。     

Granulite facies xenoliths from Prindle volcano, Alaska: Implications for the northern Cordilleran crustal lithosphere

Xenoliths collected from Prindle volcano, Alaska (Lat. 63.72°N; Long. 141.82°W) provide a unique opportunity to examine the lower crust of the northern Canadian Cordillera. The cone's pyroclastic deposits contain crustal and mantle-derived xenoliths. The crustal xenoliths include granulite facies metamorphic rocks and charnockites, comprising orthopyroxene (opx)–plagioclase (pl)–quartz (qtz) ± mesoperthite (msp) and clinopyroxene (cpx). Opx–cpx geothermometry yields equilibrium temperatures (T) from 770 to 1015 °C at 10 kbar. Pl–cpx–qtz geobarometry yields pressures (P) of  6.6–8.0 kbar. Integrated mesoperthite compositions suggest minimum temperatures of 1020–1140 °C at 10 kbar using solvus geothermometry. The absence of garnet in these rocks indicates a range of maximum pressure of 5–11.3 kbar, and calculated solidi constrain upper temperature limits. We conclude that the granulite facies assemblages represent relatively dry metamorphism at pressures indicative of crustal thicknesses similar to present day ( 36 km). Zircon separates from a single crustal xenolith yield mainly Early Tertiary (48–63 Ma) U–Pb ages which are considerably younger than the cooling ages of the high-pressure amphibolites exposed at the surface. The distribution of zircon ages is interpreted as indicating zircon growth coincident with at least two different thermal events as expressed at surface: (i) the eruption of the Late Cretaceous Carmacks Group volcanic rocks in western Yukon and adjacent parts of Alaska, and (ii) emplacement of strongly bimodal high level intrusions across much of western Yukon and eastern Alaska possibly in an extensional tectonic regime. The distributions of zircon growth ages and the preservation of higher-than-present-day (> 25 ± 3 °C km^− 1) geothermal gradients in the granulite facies rocks demonstrate the use of crustal xenoliths for recovering records of past, lithospheric-scale thermal–tectonic events.     

An 40Ar–39Ar investigation of high-pressure metamorphism and the retrogressive history of mafic eclogites from the Lanterman Range (Antarctica): evidence against a simple temperature control on argon transport in amphibole

Mafic eclogites sampled from a restricted area in the Lanterman Range (Antarctica) retrogressed variably under amphibolite facies metamorphism. Assemblages range from well-preserved eclogite, with minor growth of Na-Ca amphibole, to strongly retrogressed ones with extensive development of Ca amphibole. ⁴⁰Ar-³⁹Ar furnace step-heating experiments on the different amphiboles yield results varying from plateau ages of ~498 Ma to a near-plateau age of ~490 Ma, and the greater the amphibolite retrogression, the younger the age. ⁴⁰Ar-³⁹Ar infrared laser-probe analyses on rock chips from a well-preserved eclogite and a slightly retrogressed one reveal the presence of an excess argon component. Whereas excess argon is invariably present in garnet and clinopyroxene developed under high-pressure metamorphism, it is heterogeneously distributed in amphibole on a millimetre scale. Results indicate that excess argon was incorporated during high-pressure metamorphism; this component was then lost during retrogression, while a change in composition of ambient argon to atmospheric argon occurred. New ⁴⁰Ar-³⁹Ar data and previously published Sm-Nd garnet and U-Pb rutile ages obtained from the same well-preserved eclogite sample suggest that the oldest Na-Ca amphibole age is reliable and not an artefact due to the incorporation of excess argon. The variably retrogressed eclogites are thought to derive from different parts of the enclosing metasedimentary rocks that were variably invaded by fluids during amphibolite facies metamorphism. Thus the circulation of fluids promoting (re)crystallisation, and not temperature, was the main process controlling the rate of argon transport in the studied eclogites. The different ⁴⁰Ar-³⁹Ar ages are interpreted to record diachronous amphibole growth at different crustal levels during exhumation. Data indicate that there was about a 10-Ma interval between the eclogite facies stage (at ̿.5 GPa) and the Ca amphibole-hydration forming reaction (at 0.3-0.5 GPa); this translates into an average exhumation rate of 3-4 km/Ma.     

Early Cooling History of Eciogites from the Dabie-Sulu Orogen： Constraints from Diffusion Kinetics of Garnet

Abstract For the first time, we apply different geospeedometric models to garnet zoning patterns that were obtained in this study from detailed EMP analyses for garnets from eclogites and granulite in the Dabie‐Sulu orogen. Various zonings of cation diffusion were preserved in the garnets, enabling the acquirement of average cooling rates for the high‐to ultrahigh‐pressure rocks without using geochronological approaches. The coesite‐bearing hot eclogites yield fast cooling rates of about 20 to 30°C/Ma subsequent to peak metamorphic temperatures, whereas the cold eclogite gives a relatively slow cooling rate of 8°C/Ma at its initial exhumation. A very slow cooling rate of <0.3°C/Ma is obtained for the granulite at Huangtuling, suggesting that the granulite may not be involved in the continental deep subduction.     

Fluid inclusions in granulites, granulitized eclogites and garnet clinopyroxenites from the Dabie–Sulu terranes, eastern China

Minor granulites (believed to be pre-Triassic), surrounded by abundant amphibolite-facies orthogneiss, occur in the same region as the well-documented Triassic high- and ultrahigh-pressure (HP and UHP) eclogites in the Dabie–Sulu terranes, eastern China. Moreover, some eclogites and garnet clinopyroxenites have been metamorphosed at granulite- to amphibolite-facies conditions during exhumation. Granulitized HP eclogites/garnet clinopyroxenites at Huangweihe and Baizhangyan record estimated eclogite-facies metamorphic conditions of 775–805 °C and ≥15 kbar, followed by granulite- to amphibolite-facies overprint of ca. 750–800 °C and 6–11 kbar. The presence of (Na, Ca, Ba, Sr)-feldspars in garnet and omphacite corresponds to amphibolite-facies conditions. Metamorphic mineral assemblages and P–T estimates for felsic granulite at Huangtuling and mafic granulite at Huilanshan indicate peak conditions of 850 °C and 12 kbar for the granulite-facies metamorphism and 700 °C and 6 kbar for amphibolite-facies retrograde metamorphism. Cordierite–orthopyroxene and ferropargasite–plagioclase coronas and symplectites around garnet record a strong, rapid decompression, possibly contemporaneous with the uplift of neighbouring HP/UHP eclogites.

Carbonic fluid (CO₂-rich) inclusions are predominant in both HP granulites and granulitized HP/UHP eclogites/garnet clinopyroxenites. They have low densities, having been reset during decompression. Minor amounts of CH₄ and/or N₂ as well as carbonate are present. In the granulitized HP/UHP eclogites/garnet clinopyroxenites, early fluids are high-salinity brines with minor N₂, whereas low-salinity fluids formed during retrogression. Syn-granulite-facies carbonic fluid inclusions occur either in quartz rods in clinopyroxene (granulitized HP garnet clinopyxeronite) or in quartz blebs in garnet and quartz matrices (UHP eclogite). For HP granulites, a limited number of primary CO₂ and mixed H₂O–CO₂(liquid) inclusions have also been observed in undeformed quartz inclusions within garnet, orthopyroxene, and plagioclase which contain abundant, low-density CO₂±carbonate inclusions. It is suggested that the primary fluid in the HP granulites was high-density CO₂, mixed with a significant quantity of water. The water was consumed by retrograde metamorphic mineral reactions and may also have been responsible for metasomatic reactions (“giant myrmekites”) occurring at quartz–feldspar boundaries. Compared with the UHP eclogites in this region, the granulites were exhumed in the presence of massive, externally derived carbonic fluids and subsequently limited low-salinity aqueous fluids, probably derived from the surrounding gneisses.