The role of gypsum and/or dolomite dissolution in tufa precipitation: lessons from the hydrochemistry of a carbonate–sulphate karst system

The precipitation of freshwater carbonates (tufa) along karstic rivers is enhanced by degassing of carbon dioxide (CO₂) downstream of karstic springs. However, in most karstic springs CO₂ degassing is not enough to force the precipitation of tufa sediments. Little is known about the role of dissolution of gypsum or dolomite in the hydrochemistry of these systems and how this affects the formation of tufa deposits. Here we present a monitoring study conducted over a year in Trabaque River (Spain). The river has typical karst hydrological dynamics with water sinking upstream and re‐emerging downstream of the canyon. Mixing of calcium–magnesium bicarbonate and calcium sulphate waters downstream of the sink enhances the dissolution of carbonates and potentially plays a positive role in the formation of tufa sediments. However, due to the common‐ion effect, dissolution of dolomite and/or gypsum causes precipitation of underground calcite cements as part of the incongruent dissolution of dolomite/dedolomitization process, which limits the precipitation of tufa sediments. Current precipitation of tufa is scant compared to previous Holocene tufa deposits, which likely precipitated from solutions with higher saturation indexes of calcite (SIcc values) than nowadays. Limited incongruent dissolution of dolomite/dedolomitization favours higher SIcc values. This circumstance occurs when waters with relatively high supersaturation of dolomite and low SO₄^2? composition sink in the upper sector of the canyon. In such a scenario, the process of mixing waters enhances the exclusive dissolution of limestones, preventing the precipitation of calcite within the aquifer and favouring the increase of SIcc values downstream of the springs. Such conditions were recorded during periods of high water level of the aquifers and during floods. This research shows that the common‐ion effect caused by the dissolution of gypsum and/or dolomite rocks can limit [or favour] the precipitation of tufa sediments depending on the occurrence [or not] of incongruent dissolution of dolomite/dedolomitization. Copyright © 2016 John Wiley & Sons, Ltd.     

Aeolian deposits on a Scottish mountain summit: characteristics,provenance, history and significance

The summit plateau of The Storr (719 m) in northern Skye is mantled by a sheet of aeolian sediment up to 2·9 m thick, covering an area of 33 000 m² with a volume of 41 000 m³. The deposits are of massive, poorly sorted sand with significant components of silt and fine gravel, and contain clasts up to 109 mm in length. The thickness and coarseness of the deposits decline westwards and northwards away from the highest cliffs, implying that the sediment comprises particles dislodged from rockwalls and blown upwards in an accelerating vertical or near-vertical airflow, settling through a lower-velocity flow onto the plateau surface where they are trapped by vegetation. Radiocarbon dating of soils buried under and within the deposits suggests that accumulation began after 7·2–6·9 calendar ka BP but before 5·6–5·3 calendar ka BP , and was probably initiated by exposure of the present rockwall by a massive landslide at c. 6·5 ± 0·5 calendar ka BP . Pollen analyses of buried organic horizons suggest that a vegetation mat dominated by grasses and sedges was present throughout the period of sediment deposition. Sediment accumulation over much of the plateau averaged 10–20 mm per century throughout the late Holocene, but reached c. 60 mm per century in the area of the thickest deposits. The volume of the deposits implies the removal of 420–480 mm of rock (averaged over the face) during the late Holocene, and suggests that small-scale granular disaggregation and release of small clasts constitute a major component of rockwall retreat under present conditions. The origin of the Storr deposits suggests that plateau-top aeolian sediments on other Scottish mountains accumulated in a similar way, but have been eroded and redeposited on lee slopes following breakage of vegetation cover. © 1998 John Wiley & Sons, Ltd.     

Overbank deposition along the concave side of the Red River meanders,Manitoba, and its geomorphic significance

Slow earth sliding is pervasive along the concave side of Red River meanders that impinge on Lake Agassiz glaciolacustrine deposits. These failures form elongated, low‐angled (c. 6 to 10°) landslide zones along the valleysides. Silty overbank deposits that accumulated during the 1999 spring freshet extend continuously along the landslide zones over hundreds of metres and aggraded the lower slopes over a distance 50 to 80 m from the channel margin. The aggradation is not obviously related to meander curvature or location within a meander. Along seven slope profiles surveyed in 1999 near Letellier, Manitoba, the deposits locally are up to 21 cm thick and generally thin with increasing distance from, and height above, the river. Local deposit thickness relates to distance from the channel, duration of inundation of the landslide surface, mesotopography, and variations in vegetation cover. Immediately adjacent to the river, accumulated overbank deposits are up to 4 m thick. The 1999 overbank deposits also were present along the moderately sloped (c. 23 to 27°) concave banks eroding into the floodplain, but the deposits are thinner (locally up to c. 7 cm thick) and cover a narrower area (10 to 30 m wide) than the deposits within the landslide zones. Concave overbank deposition is part of a sediment reworking process that consists of overbank aggradation on the landslide zones, subsequent gradual downslope displacement from earth sliding, and eventually reworking by the river at the toe of the landslide. The presence of the deposits dampens the outward migration of the meanders and contributes to a low rate of contemporary lateral channel migration. Concave overbank sedimentation occurs along most Red River meanders between at least Emerson and St. Adolphe, Manitoba. © Her Majesty the Queen in right of Canada.     

Exploring the dating of “dirty” speleothems and cave sinters using radiocarbon dating of preserved organic matter

Speleothems and other carbonate deposits such as tufa containing high proportions of detrital material can be difficult to chemically date due to detrital thorium levels causing a high level of error in conventional U-Th disequilibrium dating. Here we investigate the use of an alternative technique centring on radiocarbon dating of organic matter preserved within the detrital fraction. Non-acid soluble humic, particulate and detritally absorbed organic matter was recovered from eight samples from a flowstone sinter formed within a roman aqueduct at Trento in Italy with a maximum age of 100 CE (1850 cal yr BP), and two repeat samples from a dripstone formed within the 20th Century on a wire fence at Lilly-Pilly Cave, Buchan Caves Reserve in Victoria, Australia. In the aqueduct samples the median calibrated ¹⁴C ages ranged from 2232 to 2889 cal yr BP, with 95.4% probability age range in the youngest and oldest samples of 2153–2337 and 2342–3449 cal yr BP respectively. The median age of the more modern dripstone was 336 cal yr BP, with a 95.4% probability age range of 148–486 cal yr BP. These results provide very approximate ball-park estimates of the age of the sample, but are consistently too old when compared to the known maximum ages of formation. It is hypothesised that this offset is due to a combination of the nature of the organic carbon transported from the source organic matter pools, and reworking of both modern and old organic carbon by in situ microbial communities.     

Transverse canyon incision and sedimentary basin excavation driven by drainage integration,Aravaipa Creek,AZ, USA

Drainage reorganization events have the potential to drive incision and erosion at high rates normally attributed to tectonic or climatic forcing. It can be difficult, however, to isolate the signal of transient events driven by drainage integration from longer term tectonic or climatic forcing. We exploit an ideal field setting in Aravaipa Creek Basin of southeastern Arizona, USA, to isolate just such a signal. Aravaipa Creek Basin underwent a period of transient incision that formed Aravaipa Canyon, evacuating a significant volume of sedimentary basin fill and Tertiary bedrock from the previously internally drained basin. We use digital terrain analyses to reconstruct the pre-incision landscapes of both Aravaipa Creek Basin and the adjacent Lower San Pedro Basin, which we use to quantify the magnitude of incision and erosion since the drainage basins integrated. Terrestrial cosmogenic nuclide burial dates from ¹⁰Be and ²⁶Al concentrations in latest stage basin fill in Aravaipa Creek enable us to calculate long-term incision and erosion rates from 3 Myr to the present. A ¹⁰Be concentration–depth profile from the Lower San Pedro Basin confirms that the San Pedro River incised into its high stand deposits prior to 350 000–400 000 years ago. Combining our landscape reconstructions with these age constraints, we determine that the transient rates of incision that created Aravaipa Canyon were 150 m/Myr or more, but that the background rate of erosion since integration is an order of magnitude lower, between 10 and 20 m/Myr. These results support our growing understanding that tectonic and climatic forcings need not apply for all episodes of rapid, transient incision and erosion during landscape evolution. © 2018 John Wiley & Sons, Ltd.     

Testing less-conventional methods to date a late-pleistocene to Holocene eruption: Radiocarbon dating of paleosols and 36Cl exposure ages at Pelado volcano,Sierra Chichinautzin,Central Mexico

Despite their significance for estimating hazards and forecasting future activity, dating young volcanic deposits and landforms (<50,000 yrs old) remains a challenge due to the limitations inherent to the different isotopic chronometers used. The Trans-Mexican Volcanic Belt is one of the most active and populated continental arcs worldwide, yet its temporal pattern of activity is poorly constrained. Such deficiency is particularly problematic for the Sierra Chichinautzin Volcanic Field (SCVF) that is located at the doorstep of Mexico City and Cuernavaca and is hence a major source of risk for these cities. Existing ages for this area derive mostly from either radiocarbon on charcoal, which is rare and may be contaminated, or ⁴⁰Ar/³⁹Ar on rock matrix, which is poorly precise for this time period and rock type. Here, we focus on the Pelado monogenetic volcano, which is located in the central part of the SCVF and erupted both explosively and effusively, producing a large lava shield and a widespread tephra blanket. This unique eruptive event was previously dated at ∼12 calibrated (cal) kyrs BP, using radiocarbon dating on charcoal from deposits related to the eruption. To test alternative dating approaches and confirm the age of this significant eruption, we applied two less conventional techniques, radiocarbon dating of bulk paleosol samples collected below the complete tephra sequence at nine sites around the shield, and in-situ ³⁶Cl exposure dating of two samples of an aphyric lava from the base of the shield. Radiocarbon paleosol ages span a continuous time interval from 13.2 to 20.2 cal kyrs BP (2σ), except for one anomalously young sample. This wide age spread, along with the low organic contents of the paleosols, may be due to erosive conditions, related to the sloping topography of the sampling sites and the cool and relatively dry climate of the Younger Dryas (11.7–12.9 ka), during which the Pelado eruption probably occurred. The two ³⁶Cl-dated lava samples have consistent ages at 1σ analytical errors of 15.5 ± 1.4 ka and 13.2 ± 1.2 ka, respectively, yielding an average age of 14.3 ± 1.6 ka for this lava flow. The high full uncertainty in ³⁶Cl ages (24%) is due to high rock Cl content. We conclude that paleosol radiocarbon dating is useful if numerous samples are analyzed and climatic and relief conditions at the time of the eruption and at the sites of tephra deposition are considered. The ³⁶Cl dating technique is an alternative method to date volcanic eruptions, as it gave consistent results, but in the specific case of Pelado volcano, the high Cl content in the analyzed rocks increases the age uncertainties.     

Micro-hole and multigrain quartz luminescence dating of Paleodeltas at Lake Fryxell,McMurdo Dry Valleys (Antarctica), and relevance for lake history

Relict (perched) lacustrine deltas around the perennially ice-covered lakes in the Taylor Valley, Antarctica, imply that these lakes were up to 40 times larger in area than at present since the last glacial maximum (LGM). These deltas have been used to constrain ice-margin positions in Taylor Valley, and the boundaries of the proposed LGM ice-damned Glacial Lake Washburn. The timing of these high lake levels has depended on ¹⁴C chronologies of algal layers within relict lacustrine deltas. To provide additional geochronometric data for the post-LGM lake-level history, we applied photon-stimulated-luminescence (PSL) sediment dating to polymineral fine silt and sand-size quartz from 7 perched-delta and 3 active-delta sites of different elevations along 3 major meltwater streams entering Lake Fryxell. Our PSL dating of 4 quartz-sand samples from core tops in the seasonal ice-free moat of Lake Fryxell (elevation ∼18 m a.s.l.) and two core-top moat samples from the seasonal moat of Lake Vanda in nearby Wright Valley establish that adequate PSL clock zeroing (by daylight) occurs in regional, modern shoreline deposits. Minimum-age micro-hole PSL results from the moats are consistently near 100 a. Minimum-age micro-hole age estimates for the deltas range from ∼50 to 100 a near the present lake level up to 13.4 ± 1.3 ka at 240 m. These are systematically younger than the comparable, reservoir-uncorrected, ¹⁴C ages that range from 7 ka (cal yr BP) to 13 ka (cal yr BP) near lake level up to 20 ka (cal yr BP) at 220–240 m elevation. Our results indicate the occurrence of a dramatic discrepancy between PSL minimum-age and ¹⁴C age estimates that is presently unresolved.     

2.8-Ma ash-flow caldera at Chegem River in the northern Caucasus Mountains (Russia), contemporaneous granites, and associated ore deposits

Diverse latest Pliocene volcanic and plutonic rocks in the north-central Caucasus Mountains of southern Russia are newly interpreted as components of a large caldera system that erupted a compositionally zoned rhyolite-dacite ash-flow sheet at 2.83 ± 0.02 Ma (sanidine and biotite ⁴⁰Ar/³⁹Ar). Despite its location within a cratonic collision zone, the Chegem system is structurally and petrologically similar to typical calderas of continental-margin volcanic arcs. Erosional remnants of the outflow Chegem Tuff sheet extend at least 50 km north from the source caldera in the upper Chegem River. These outflow remnants were previously interpreted by others as erupted from several local vents, but petrologic similarities indicate a common origin and correlation with thick intracaldera Chegem Tuff. The 11 × 15 km caldera and associated intrusions are superbly exposed over a vertical range of 2,300 m in deep canyons above treeline (elev. to 3,800 m). Densely welded intracaldera Chegem Tuff, previously described by others as a rhyolite lava plateau, forms a single cooling unit, is > 2 km thick, and contains large slide blocks from the caldera walls. Caldera subsidence was accommodated along several concentric ring fractures. No prevolcanic floor is exposed within the central core of the caldera. The caldera-filling tuff is overlain by andesitic lavas and cut by a 2.84 ± 0.03-Ma porphyritic granodiorite intrusion that has a cooling age analytically indistinguishable from that of the tuffs. The Eldjurta Granite, a pluton exposed low in the next large canyon (Baksan River) 10 km to the northwest of the caldera, yields variable K-feldspar and biotite ages (2.8 to 1.0 Ma) through a 5-km vertical range in surface and drill-hole samples. These variable dates appear to record a prolonged complex cooling history within upper parts of another caldera-related pluton. Major W-Mo ore deposits at the Tirniauz mine are hosted in skarns and hornfels along the roof of the Eldjurta Granite, and associated aplitic phases have textural features of Climax-type molybdenite porphyries in the western USA. Similar ⁴⁰Ar/³⁹Ar ages, mineral chemistry, and bulk-rock compositions indicate that the Chegem Tuff, intracaldera intrusion, and Eldjurta Granite are all parts of a large magmatic system that broadly resembles the middle Tertiary Questa caldera system and associated Mo deposits in northern New Mexico, USA. Because of their young age and superb three-dimensional exposures, rocks of the Chegem-Tirniauz region offer exceptional opportunities for detailed study of caldera structures, compositional gradients in volcanic rocks relative to cogenetic granites, and the thermal and fluid-flow history of a large young upper-crustal magmatic system.     

Evolution of the Quaternary melitite-nephelinite Herchenberg volcano (East Eifel)

The Quaternary Herchenberg composite tephra cone (East Eifel, FR Germany) with an original bulk volume of 1.17·10⁷ m³ (DRE of 8.2·10⁶ m³) and dimensions of ca. 900·600·90 m (length·width·height) erupted in three main stages: (a) Initial eruptions along a NW-trending, 500-m-long fissure were dominantly Vulcanian in the northwest and Strombolian in the southeast. Removal of the unstable, underlying 20-m-thick Tertiary clays resulted in major collapse and repeated lateral caving of the crater. The northwestern Lower Cone 1 (LC1) was constructed by alternating Vulcanian and Strombolian eruptions. (b) Cone-building, mainly Strombolian eruptions resulted in two major scoria cones beginning initially in the northwest (Cone 1) and terminating in the southeast (Cones 2 and 3) following a period of simultaneous activity of cones 1 and 2. Lapilli deposits are subdivided by thin phreatomagmatic marker beds rich in Tertiary clays in the early stages and Devonian clasts in the later stages. Three dikes intruded radially into the flanks of cone 1. (c) The eruption and deposition of fine-grained uppermost layers (phreatomagmatic tuffs, accretionary lapilli, and Strombolian fallout lapilli) presumably from the northwestern center (cone 1) terminated the activity of Herchenberg volcano. The Herchenberg volcano is distinguished from most Strombolian scoria cones in the Eifel by (1) small volume of agglutinates in central craters, (2) scarcity of scoria bomb breccias, (3) well-bedded tephra deposits even in the proximal facies, (4) moderate fragmentation of tephra (small proportions of both ash and coarse lapilli/bomb-size fraction), (5) abundance of dense ellipsoidal juvenile lapilli, and (6) characteristic depositional cycles in the early eruptive stages beginning with laterally emplaced, fine-grained, xenolith-rich tephra and ending with fallout scoria lapilli. Herchenberg tephra is distinguished from maar deposits by (1) paucity of xenoliths, (2) higher depositional temperatures, (3) coarser grain size and thicker bedding, (4) absence of glassy quenched clasts except in the initial stages and late phreatomagmatic marker beds, and (5) predominance of Strombolian, cone-building activity. The characteristics of Herchenberg deposits are interpreted as due to a high proportion of magmatic volatiles (dominantly CO₂) relative to low-viscosity magma during most of the eruptive activity.     

Monogenetic vulcanism in sierra Chichinautzin,Mexico

The variation in the activity patterns of the Chichinautzin volcanic rocks is discussed. This sequence of lavas and pyroclastic deposits is located in the central part of the Mexican Volcanic Belt, directly south of Mexico City, and is typical of its Quaternary monogenetic vulcanism. One-hundred and fourty-six volcanoes and their deposits covering 952 km² were mapped. Cone density is 0.15 km² with heights ranging from to 315 m and crater diameters from 50 to 750 m. Ratios of cone height/diameter decreased from 0.20 to 0.12 with age. Basal diameters varied from 0.1 km to 2 km. Lavas are mainly blocky andesites but some dacites and basalts were found. Lengths of flows range from 1.0 to 21.5 km with heights of 0.5 to 300 m and aspect rations of 21.4 to 350. Three types of volcanic structures are found in the area: scoria cones, lavas cones and thick flows lacking a cone. Pyroclastic deposits are basically Strombolian although some deposits were produced by more violent activity and lava cones seem to have formed by activity transitional to Hawaiian-type vulcanism. Therre is a dominant E-W trend shown mainly by the orientation of cone clusters. The Chichinautzin volcanic centers are compared to the monogenetic volcanoes of the Toluca and Paricutin areas which are similar.     

The Quetzalapa Pumice: a voluminous late Pleistocene rhyolite deposit in the eastern Trans-Mexican Volcanic Belt

The study area is located in the east part of the Trans-Mexican Volcanic Belt, in the Las Cumbres Volcanic Complex (LCVC) which lies between two large stratovolcanoes: Pico de Orizaba (5700 m a.s.l.) to the south, and Cofre de Perote (4200 m a.s.l.) to the NNE. The most conspicuous structure of the LCVC is a 4-km-diameter circular crater with a dacitic dome in the center, which constitutes the remains of a destroyed stratovolcano.The Quetzalapa Pumice (QP) was produced by a plinian eruption that was dated by the ¹⁴C method at 20 000 yr. BP. The eruptive sequence consists predominantly of pumice fall deposits and scarce intra-plinian pyroclastic flow deposits, which crop out on the west flank of the LCVC. The absence of post-plinian ignimbrite deposits is striking.The deposits are well sorted, clast-supported with reverse grading at the base, with a medium to high accessory lithics content. The maximum average thickness of the deposit in the proximal areas is about 15 m and has been divided into three members: the Basal Member (BM), 2 m thick with four submembers (BMf₁, BMf₂, BMf₃, and BMafl), the Intermediate Member (IM), 10 m thick with two submembers (IMpf and IMaf), and the Upper Member (UM), 3 m thick with four submembers (UMpl, UMsdf, UMwaf, and UMpls).The predominant component of the fall deposits is a white, highly vesiculated pumice with 71% SiO₂ content. Plagioclase is the most abundant mineral followed by 1–3-mm-long biotite phenocrysts. The accessory lithics are lavas mostly of andesitic composition. Their abundance increases toward the uppermost levels of the sequence.We calculate a minimum volume of 8.4 km³ (2.22 km³ dense rock equivalent), for the entire QP deposit. Isopach and isopleth maps show that the IM deposit has an elongated distribution with a NNE–SSW direction, whereas the UM deposit has a circular distribution.We estimate a maximum eruptive column height for the IM of 20 km. Field studies and isopach and isopleth maps indicate that the eruptive column was affected by a strong wind.Previous studies located the QP source in the Las Cumbres crater. However, based on the isopach and isopleth distribution, and the lack of pumice fall deposits inside the Las Cumbres crater, we consider that the QP emission center is located on the west flank of the LCVC, and was buried by its own pumice fall deposits. It coincides with an explosion crater called La Capilla formed during the closing phase of the QP eruption.A ‘pumice fountain’ model is proposed to explain the observed sequence of deposits. According to this model, the material was emitted through a ‘hose-type’ conduit during a monogenetic eruption of rhyolitic composition. This kind of volcanic activity is not extensively reported in the literature.     

Emplacement age and PGE geochemistry of lamprophyres in the Laowangzhai gold deposit,Yunnan, SW China

Widely-distributed lamprophyres in the Laowangzhai gold deposit were associated closely with gold ores. Phlogopite⁴⁰Ar/³⁹Ar dating suggests that the emplacement age of lamprophyric magma ranges from (30.8±0.4) to (34.3±0.2) Ma, and gold mineralization took place at (26.4±0.2) Ma. PGE geochemical tracing indicates that gold in the gold deposit did not come from the primitive lamprophyric magma. The tempo-spatial paragenesis between lamprophyres and mesothermal gold deposits along the Jinsha-Red River belt may be attributed to the fact that they formed in the same tectonic setting.

     

26Al and 10Be dating of late pleistocene and holocene fill terraces: a record of fluvial deposition and incision,Colorado front range

Cosmogenic ²⁶Al, ¹⁰Be, and ¹⁴C dating of fluvial fill terraces in steep canyons of the Colorado Front Range provides a temporal framework for analysing episodic aggradation and incision. Results from Boulder Canyon show that terrace heights above the modern channel (grade) can be divided into: (1) Bull Lake (≳100 ka; 20–15 m above grade); (2) Pinedale (32–10 ka; 15–4 m above grade); and (3) Holocene age (<4 m above grade). No pre‐Bull Lake deposits are preserved along Boulder Canyon, and only three small remnants >15 m above grade record Bull Lake deposition. Well‐preserved terraces of Pinedale age suggest that the range of terrace height above grade reflects short‐term fluctuations in the river profile during periods of rapidly changing stream load and power. Net river incision apparently occurred during transitions to interglacial periods. Soil development and stratigraphic position, along with limited cosmogenic and ¹⁴C dating, suggest that ∼130 ka terraces in Boulder Canyon correlate with the Louviers Alluvium, and that 32 to 10 ka fills in the canyon correlate with the Broadway Alluvium on the adjacent High Plains. Late Pleistocene incision rates (∼0·15 m ka⁻¹) along Boulder Canyon exceed pre‐late Pleistocene incision rates, and are higher than middle to late Pleistocene incision rates (∼0·04 m ka⁻¹) on the High Plains. This study provides an example of how modern geochronologic techniques allow us to understand better rivers that drain glaciated catchments. Copyright © 2002 John Wiley & Sons, Ltd.     

Carbonate eolianites,quartz sands,and Quaternary sea-level cycles,Western Australia: A chronostratigraphic approach

Marine and eolian carbonate deposits, grouped under the name “Tamala Limestone”, have been investigated along thousands of kilometers of coastal Western Australia (WA). Relative-age diagenetic features of carbonate sand dunes or “eolianites” indicate that coastal ridges decrease in age seaward, reflecting coastal accretion during successive sea-level stands. Yellow- to red-stained quartz sands are associated with eolianites as pits, lenses, extensive beds, and even 40-m-high dunes.A regional survey using whole-rock and land snail amino acid epimerization geochronology confirms the eolianite succession and provides a means of correlating widespread deposits along a steep climatic gradient and 16° of latitude. AMS ¹⁴C and uranium–thorium (U/Th) ages provide independent radiometric calibration of the amino acid ratios, and eolianite ages can be estimated using a parabolic kinetic model.Over 90% of the sampled eolianite deposits comprise Aminozones A, C, E (125 ka), F?, G, and H, and correlate with interglacials from <10 ka (Holocene) to ca. 500 ka. In contrast, at the type locality of the Tamala Limestone along the Zuytdorp Cliffs, the upper eolianite-paleosol units are characterized by advanced stages of cavernous weathering, pedogenesis, and recrystallization. In the same units, sediment and snail samples generally yield very low or non-detectable levels of amino acids. These factors along with the stratigraphic complexity of the deposits reflect an age much greater than a large majority of sites along the WA coastline. These findings encourage a revision of the existing classification and nomenclature of Quaternary carbonate deposits in WA, as well as a reexamination of the underlying mechanisms related to the formation and emplacement of both carbonate and quartz dunes.     

Origin and stratigraphy of phreatomagmatic deposits at the Pleistocene Sinker Butte Volcano, Western Snake River Plain, Idaho

Sinker Butte is the erosional remnant of a very large basaltic tuff cone of middle Pleistocene age located at the southern edge of the western Snake River Plain. Phreatomagmatic tephras are exposed in complete sections up to 100 m thick in the walls of the Snake River Canyon, creating an unusual opportunity to study the deposits produced by this volcano through its entire sequence of explosive eruptions. The main objectives of the study were to determine the overall evolution of the Sinker Butte volcano while focusing particularly on the tephras produced by its phreatomagmatic eruptions. Toward this end, twenty-three detailed stratigraphic sections ranging from 20 to 100 m thick were examined and measured in canyon walls exposing tephras deposited around 180° of the circumference of the volcano.Three main rock units are recognized in canyon walls at Sinker Butte: a lower sequence composed of numerous thin basaltic lava flows, an intermediate sequence of phreatomagmatic tephras, and a capping sequence of welded basaltic spatter and more lava flows. We subdivide the phreatomagmatic deposits into two main parts, a series of reworked, mostly subaqueously deposited tephras and a more voluminous sequence of overlying subaerial surge and fall deposits. Most of the reworked deposits are gray in color and exhibit features such as channel scour and fill, planar-stratification, high and low angle cross-stratification, trough cross-stratification, and Bouma-turbidite sequences consistent with their being deposited in shallow standing water or in braided streams. The overlying subaerial deposits are commonly brown or orange in color due to palagonitization. They display a wide variety of bedding types and sedimentary structures consistent with deposition by base surges, wet to dry pyroclastic fall events, and water saturated debris flows.Proximal sections through the subaerial tephras exhibit large regressive cross-strata, planar bedding, and bomb sags suggesting deposition by wet base surges and tephra fallout. Medial and distal deposits consist of a thick sequence of well-bedded tephras; however, the cross-stratified base-surge deposits are thinner and interbedded within the fallout deposits. The average wavelength and amplitude of the cross strata continue to decrease with distance from the vent. These bedded surge and fall deposits grade upward into dominantly fall deposits containing 75–95% juvenile vesiculated clasts and localized layers of welded spatter, indicating a greatly reduced water-melt ratio. Overlying these “dryer” deposits are massive tuff breccias that were probably deposited as water saturated debris flows (lahars). The first appearance of rounded river gravels in these massive tuff breccias indicates downward coring of the diatreme and entrainment of country rock from lower in the stratigraphic section. The “wetter” nature of these deposits suggests a renewed source of external water. The massive deposits grade upward into wet fallout tephras and the phreatomagmatic sequence ends with a dry scoria fall deposit overlain by welded spatter and lava flows.Field observations and two new ⁴⁰Ar–³⁹Ar incremental heating dates suggest the succession of lavas and tephra deposits exposed in this part of the Snake River canyon may all have been erupted from a closely related complex of vents at Sinker Butte. We propose that initial eruptions of lava flows built a small shield edifice that dammed or disrupted the flow of the ancestral Snake River. The shift from effusive to explosive eruptions occurred when the surface water or rising ground water gained access to the vent. As the river cut a new channel around the lava dam, water levels dropped and the volcano returned to an effusive style of eruption.     

Field observations and surface characteristics of pristine block-and-ash flow deposits from the 2006 eruption of Merapi Volcano,Java, Indonesia

A series of pristine block-and-ash flow deposits from the May–June 2006 eruption of Merapi represent an exceptional record of small-volume pyroclastic flows generated by gravitational lava-dome collapses over a period of about two months. The deposits form nine overlapping lobes reaching ~ 7 km from the summit in the Gendol River valley on the volcano's southern flank, which were produced by successive flows generated during and after the major dome-collapse event on June 14. Both, single pulse (post-June 14 events) and multiple-pulse pyroclastic flows generated by sustained dome collapses on June 14 are recognised and three types of deposits, spread over an area of 4.7 km², are distinguished, totalling 13.3 × 10⁶ m³: (1) valley-confined basal avalanche deposits (11.7 × 10⁶ m³) in the Gendol River valley, (2) overbank pyroclastic-flow and associated surge deposits (1.4 × 10⁶ m³), where parts of the basal avalanche spread laterally onto interfluves and were subsequently channeled into the surrounding river valleys and (3) dilute ash-cloud surge deposits (0.2 × 10⁶ m³) along valley margins. Variations in the distribution, surface morphology and lithology of the deposits are related to the source materials involved in individual pyroclastic-flow-forming events and varying modes of transport and deposition of the different flows. Inferred flow velocities of the largest block-and-ash flows generated on June 14 vary from 43.8–13.5 m/s for the basal avalanche and from 62.6–24.2 m/s for the ash-cloud surge. The minimum temperatures range from 400 °C for the basal avalanche to 165 °C for the overlying ash cloud. Due to the potential of being re-channeled into adjacent river valleys and flowing laterally away from the main river channel, the overbank pyroclastic flows are considered the most hazardous part of the block-and-ash flow system. The conditions that lead to their development during flow transport and deposition must be taken into account when assessing future pyroclastic flow hazards at Merapi and similar volcanoes elsewhere.     

Influence of storm-related sediment storage on the sediment delivery from tributary catchments in the upper Waipaoa River,New Zealand

Although much is known about overall sediment delivery ratios for catchments as components of sediment production and sediment yield, little is known about the component of temporary sediment storage. Sediment delivery ratios focused on the influence of storm-related sediment storage are measured at Matakonekone and Oil Springs tributaries of the Waipaoa River basin, east coast of New Zealand. The terrace deposits of both tributaries show abundant evidence of storm-related sedimentation, especially sediment delivered from Cyclone Bola, a 50 year return rainfall event which occurred in 1988. The sediment delivery ratio is calculated by dividing the volume of sediment transported from a tributary to the main stream by the volume of sediment generated at erosion sites in the tributary catchment. Because the sediment delivery volume is unknown, it can be calculated as the difference between sediment generation volume and sediment storage volume in the channel reach of the tributary. The volume of sediment generated from erosion sites in each tributary catchment was calculated from measurements made on aerial photographs dating from 1960 (1:44 000) and 1988 (1:27 000). The volume of sediment stored in the tributary can be calculated from measurements of cross-sections located along the tributary channel, which are accompanied by terrace deposits dated by counting annual growth rings of trees on terrace surfaces. Sediment delivery ratios are 0·93 for both Matakonekone catchment and Oil Springs catchment. Results indicate that Oil Springs catchment has contributed more than twice the volume of sediment to the Waipaoa River than the Matakonekone catchment (2·75 × 10⁶ m³ vs 1·22 × 10⁶ m³). Although large volumes of sediment are initially deposited during floods, subsequent smaller flows scour away much of these deposits. The sediment scouring rate from storage is 1·25 × 10⁴ m³ a⁻¹ for Matakonekone stream and 0·83 × 10⁴ m³ a⁻¹ for Oil Springs stream. Matakonekone and Oil Springs channels respond to extreme storms by instantaneously aggrading, then gradually excavating the temporarily stored sediment. Results from Matakonekone and Oil Springs streams suggest a mechanism by which event recurrence interval can strongly influence the magnitude of a geomorphic change. Matakonekone stream with its higher stream power is expected to excavate sediment deposits more rapidly and allow more rapid re-establishment of storage capacity. Copyright © 1999 John Wiley & Sons, Ltd.     

Large mafic eruptions at Alban Hills Volcanic District (Central Italy): Chronostratigraphy,petrography and eruptive behavior

Despite its ultra-potassic, basic geochemistry (40 ≤ SiO₂ ≤ 50 wt.%), the Alban Hills Volcanic District was characterized by a highly explosive phase of activity, the Tuscolano–Artemisio phase, which emplaced very large volumes (several tens of km³ each cycle) of pyroclastic-flow deposits, mafic in composition (SiO₂ ≤ 45 wt.%) in the time span 600–350 ka. In contrast to the abundance of pyroclastic-flow deposits, very scarce basal Plinian deposits and, more in general, fallout deposits are associated to these products. While some of the pyroclastic-flow deposits have been described in previous literature, no specific work on the Tuscolano–Artemisio phase of activity has been published so far. In particular, very little is known on the products of the early stages, as well as of the final, post-caldera activity of each eruptive cycle. Here we present a comprehensive stratigraphic and geochronologic study of the Tuscolano–Artemisio phase of activity, along with new textural and petrographic data. We describe the detailed stratigraphy and petrography of five reference sections, where the most complete suites of products of the eruptive cycles, comprising the initial through the final stages, are exposed. We assess the geochronology of these sections by means of 18 new ⁴⁰Ar/³⁹Ar age determinations, integrating them with 16 previously performed, aimed to describe the eruptive behavior of the Alban Hills Volcanic District during this phase of activity, and to assess the recurrence time and the duration of the dormancies.The overall explosive activity appears to be strictly clustered in five eruptive cycles, fairly regularly spaced in time and separated by very long dormancies, in the order of several ten of kyr, during which no volumetrically appreciable eruption occurred, as the lack of deposits dated to this time-interval testify. We propose a volcano-tectonic model that explains this peculiar eruptive behavior, unparalleled in the other coeval volcanic districts of the Tyrrhenian margin of Italy, as related to the local transpressive tectonic regime.     

River behaviour and Holocene alluviation: The River Severn at Welshpool,mid-Wales,U.K.

A combination of archaeological evidence, ¹⁴C dates, terrace mapping, heavy metal analysis, grain size analysis and historical maps is used in a detailed analysis of the alluvial history of the River Severn floodplain around Welshpool in mid-Wales, U.K. ‘Welshpool Gravels’ underlie a higher terrace surface up to 6–7 m above the present channel. They form a sequence of gravels at least 30 m in thickness. The upper surface is characterized by a series of braided palaeochannel patterns. These sediments were probably deposited at the end of the last glaciation as outwash, and are contemporaneous with other high, gravelly terrace deposits found in the Severn and other mid-Wales basins. Overlying the Welshpool Gravels on the contemporary floodplain are a variable thickness of finer sediments, the ‘Leighton Silts’. Morphological mapping and dating of two cut-offs to 2850 ± 60 a BP and 1190 ± 70 a BP indicates that a channel pattern similar to the present planform had formed by the mid to late Holocene. From this period, floodplain development has been dominated by a single-thread meandering channel with fine vertical sedimentation and limited lateral gravel accretion. Abandonment of extended lengths of channel formed by an avulsion mechanism is apparent. A combination of historical map data, ¹⁴C dates and the analysis for heavy metals in fine sediments, which were washed into the river system during mining, indicates that there has been at least 4 m of sedimentation since the early 17th century, but only in a central belt of varying width. Metal-rich waste, identified in the fine sediments of this zone of ‘Trehelig Silts’, indicates those areas which were most heavily sedimented during the peak of metalliferous mining in the 18th and 19th centuries. Although the near-channel margins appear to be superficially similar to the older floodplain, the spatial and vertical pattern of historic sedimentation is complex, and is not reflected in marked elevation differences. The division of sedimentation periods into these three broad time-spans (Late Quaternary Terraces, Late Holocene alluviation and avulsion, and the historical metal-mining period) shows that an apparently simple planar floodplain is in reality underlain by complex sedimentation units. Floodplain construction has involved the development of inset units, in cut-offs and adjacent to migrating channels, as well as the expected contrasts between in-channel and overbank environments. This has implications both for alluvial sedimentation modelling and for the identification of high-pollution zones on the floodplain. These cannot be predicted on the basis of simple ‘in-channel’ and ‘overbank’ environments given the historically complex evolution.     

Reconstructing fluvial incision rates based on palaeo-water tables in chalk karst networks along the Seine valley (Normandy,France)

Quantifying rates of river incision and continental uplift over Quaternary timescales offer the potential for modelling landscape change due to tectonic and climatic forcing. In many areas, river terraces form datable archives that help constrain the timing and rate of valley incision. However, old river terraces, with high-level deposits, are prone to weathering and often lack datable material. Where valleys are incised through karst areas, caves and sediments can be used to reconstruct the landscape evolution because they can record the elevation of palaeo-water tables and contain preserved datable material. In Normandy (N. France), the Seine River is entrenched into an extensive karstic chalk plateau. Previous estimates of valley incision were hampered by the lack of preserved datable fluvial terraces. A stack of abandoned phreatic cave passages preserved in the sides of the Seine valley can be used to reconstruct the landscape evolution of the region. Combining geomorphological observations, palaeomagnetic and U/Th dating of speleothem and sediments in eight caves along the Lower Seine valley, we have constructed a new age model for cave development and valley incision. Six identified cave levels up to ∼100 m a.s.l. were formed during the last ~1 Ma, coeval with the incision of the Seine River. Passage morphologies indicate that the caves formed in a shallow phreatic/epiphreatic setting, modified by sediment influxes. The valley's maximum age is constrained by the occurrence of late Pliocene marine sand. Palaeomagnetic dating of cave infills indicates that the highest-level caves were being infilled prior to 1.1 Ma. The evidence from the studied caves, complemented by fluvial terrace sequences, indicates that rapid river incision occurred during marine isotope stage (MIS) 28 to 20 (0.8–1 Ma), with maximal rates of ~0.30 m ka⁻¹, dropping to ~0.08 m ka⁻¹ between MIS 20–11 (0.8–0.4 Ma) and 0.05 m ka⁻¹ from MIS 5 to the present time. © 2020 John Wiley & Sons, Ltd.