Gas venting that bypasses the feather edge of marine hydrate,offshore Mauritania

Methane can be released from the vast marine hydrate reservoirs that surround continents into oceans and perhaps the atmosphere. But how these pathways work within the global carbon cycle now and during a warmer world is only partially understood. Here we use 3-D seismic data to identify what we interpret to be a gas venting system that bypasses the hydrate stability zone (HSZ) offshore of Mauritania. This venting is manifested by the presence of the acoustic wipe-out (AWO) across a densely faulted succession above a salt diapir and a set of morphological features including a substantial, ∼260 m wide and ∼32 m deep, pockmark at the seabed. The base of the HSZ is marked by a bottom simulating reflector (BSR) which deflects upwards above the diapir, rather than mimicking the seabed. We use a numerical modelling to show that this deflection is caused by the underlying salt diapir. It creates a trapping geometry for gas sealed by hydrate-clogged sediment. After entering the HSZ, some methane accumulated as hydrate in the levees of a buried canyon. Venting in this locality probably reduces the flux of gas to the landward limit of feather edge of hydrate, reducing the volume of gas that would be susceptible for release during a warmer world.     

Pockmark-like depressions near the Goliat hydrocarbon field,Barents Sea: Morphology and genesis

Pockmarks are observed worldwide along the continental margins and are inferred to be indicators of fluid expulsion. In the present study, we have analysed multibeam bathymetry and 2D/3D seismic data from the south-western Barents Sea, in relation to gas hydrate stability field and sediment type, to examine pockmark genesis. Seismic attributes of the sediments at and beneath the seafloor have been analysed to study the factors related to pockmark formation. The seabed depths in the study area are just outside the methane hydrate stability field, but the presence of higher order hydrocarbon gases such as ethane and/or propane in the expelled fluids may cause localised gas hydrate formation. The selective occurrence of pockmarks in regions of specific seabed sediment types indicates that their formation is more closely related to the type of seabed sediment than the source path of fluid venting such as faults. The presence of high acoustic backscatter amplitudes at the centre of the pockmarks indicates harder/coarser sediments, likely linked to removal of soft material. The pockmarks show high seismic reflection amplitudes along their fringes indicating deposition of carbonates precipitated from upwelling fluids. High seismic amplitude gas anomalies underlying the region away from the pockmarks indicate active fluid flow from hydrocarbon source rocks beneath, which is blocked by overlying less permeable formations. In areas of consolidated sediments, the upward flow is limited to open fault locations, while soft sediment areas allow diffused flow of fluids and hence formation of pockmarks over a wider region, through removal of fine-grained material.     

Gas hydrate associated with mud diapirs in southern Okinawa Trough

Many mud diapirs have been recognized in southern Okinawa Trough by a multi-channel seismic surveying on R/V KEXUE I in 2001. Gas hydrates have been identified, by the seismic reflection characteristics, the velocity analysis and the impedance inversion. Geothermal heat flow around the central of the mud diapir has been determined theoretically by the Bottom Simulating Reflectors (BSRs). Comparing the BSR derived and the measured heat flow values, we infer that the BSR immediately at the top of the mud diapirs indicate the base of the saturated gas hydrate formation zone (BSGHFZ), but not, as we ordinarily know, the base of the gas hydrate stability zone (BGHSZ), which could be explained by the abnormal regional background heat flow and free gas flux associated with mud diapirs. As a result, it helps us to better understand the generation mechanism of the gas hydrates associated with mud diapirs and to predict the gas hydrate potential in the southern Okinawa Trough.     

Mapping gas hydrate and fluid flow indicators and modeling gas hydrate stability zone (GHSZ) in the Ulleung Basin,East (Japan) Sea: Potential linkage between the occurrence of mass failures and gas hydrate dissociation

The Ulleung Basin, East (Japan) Sea, is well-known for the occurrence of submarine slope failures along its entire margins and associated mass-transport deposits (MTDs). Previous studies postulated that gas hydrates which broadly exist in the basin could be related with the failure process. In this study, we identified various features of slope failures on the margins, such as landslide scars, slide/slump bodies, glide planes and MTDs, from a regional multi-channel seismic dataset. Seismic indicators of gas hydrates and associated gas/fluid flow, such as the bottom-simulating reflector (BSR), seismic chimneys, pockmarks, and reflection anomalies, were re-compiled. The gas hydrate occurrence zone (GHOZ) within the slope sediments was defined from the BSR distribution. The BSR is more pronounced along the southwestern slope. Its minimal depth is about 100 m below seafloor (mbsf) at about 300 m below sea-level (mbsl). Gas/fluid flow and seepage structures were present on the seismic data as columnar acoustic-blanking zones varying in width and height from tens to hundreds of meters. They were classified into: (a) buried seismic chimneys (BSC), (b) chimneys with a mound (SCM), and (c) chimneys with a depression/pockmark (SCD) on the seafloor. Reflection anomalies, i.e., enhanced reflections below the BSR and hyperbolic reflections which could indicate the presence of gas, together with pockmarks which are not associated with seismic chimneys, and SCDs are predominant in the western-southwestern margin, while the BSR, BSCs and SCMs are widely distributed in the southern and southwestern margins. Calculation of the present-day gas-hydrate stability zone (GHSZ) shows that the base of the GHSZ (BGHSZ) pinches out at water depths ranging between 180 and 260 mbsl. The occurrence of the uppermost landslide scars which is below about 190 mbsl is close to the range of the GHSZ pinch-out. The depths of the BSR are typically greater than the depths of the BGHSZ on the basin margins which may imply that the GHOZ is not stable. Close correlation between the spatial distribution of landslides, seismic features of free gas, gas/fluid flow and expulsion and the GHSZ may suggest that excess pore-pressure caused by gas hydrate dissociation could have had a role in slope failures.     

大洋蛇纹岩化无机成因甲烷水合物稳定带底界模拟

随着深海调查研究的不断深入,发现大洋基性和超基性岩与水相互作用可发生蛇纹岩化作用产生无机成因甲烷等烃类气体,可能在大洋区海底形成水合物。为评估大洋蛇纹岩化无机成因甲烷水合物生成热力学条件及水合物稳定带分布特征,本文利用实测的原位温度、水深等条件,结合甲烷水合物-水-游离气三相平衡温压条件,计算了马里亚纳弧前蛇纹岩泥火山、北大西洋Fram海峡超慢速扩张脊和Lost City慢速扩张脊3个不同地质构造环境的蛇纹岩化发育的大洋区海底环境甲烷水合物稳定带底界,并对其水合物发育潜力进行了评估。研究表明马里亚纳弧前蛇纹岩泥火山和北大西洋Fram海峡超慢速扩张脊满足天然气水合物发育的热力学条件,可能发育有甲烷水合物,相应的水合物稳定带底界深度分别约为858～2 515和153～232 mbsf。大西洋Lost City喷口附近发育甲烷水合物可能性较小。     

Gas hydrate saturation from acoustic impedance and resistivity logs in the Shenhu area, South China Sea

During the China’s first gas hydrate drilling expedition -1 (GMGS-1), gas hydrate was discovered in layers ranging from 10 to 25 m above the base of gas hydrate stability zone in the Shenhu area, South China Sea. Water chemistry, electrical resistivity logs, and acoustic impedance were used to estimate gas hydrate saturations. Gas hydrate saturations estimated from the chloride concentrations range from 0 to 43% of the pore space. The higher gas hydrate saturations were present in the depth from 152 to 177 m at site SH7 and from 190 to 225 m at site SH2, respectively. Gas hydrate saturations estimated from the resistivity using Archie equation have similar trends to those from chloride concentrations. To examine the variability of gas hydrate saturations away from the wells, acoustic impedances calculated from the 3 D seismic data using constrained sparse inversion method were used. Well logs acquired at site SH7 were incorporated into the inversion by establishing a relation between the water-filled porosity, calculated using gas hydrate saturations estimated from the resistivity logs, and the acoustic impedance, calculated from density and velocity logs. Gas hydrate saturations estimated from acoustic impedance of seismic data are ∼10-23% of the pore space and are comparable to those estimated from the well logs. The uncertainties in estimated gas hydrate saturations from seismic acoustic impedances were mainly from uncertainties associated with inverted acoustic impedance, the empirical relation between the water-filled porosities and acoustic impedances, and assumed background resistivity.     

Heat-flow regimes and the hydrate stability zone of a transient,thermogenic, fault-controlled hydrate system (Woolsey Mound northern Gulf of Mexico)

This study aims to constrain the base of the hydrates stability field in structurally complexsites using the case of Woolsey Mound, a fault-controlled, transient, thermogenic hydrates system, in Mississippi Canyon Block 118, northern Gulf of Mexico. We have computed the base of the hydrates stability field integrating results from a recent heat-flow survey, designed to investigate geothermal anomalies along fault zones which exhibit different fluid flux regimes. An advanced “compositional” simulator was used to model hydrate formation and dissociation at Woolsey Mound and addresses the following hypotheses:

• 1.Migrating thermogenic fluids alter thermal conditions of the Hydrate Stability Zone (HSZ), so heat-flow reflects fault activity;
• 2.Gas hydrate formation and dissociation vary temporally at active faults, temporarily sealing conduits for migration of thermogenic fluids;
• 3.High salinity and inclusion of thermogenic gases with higher molecular weight than methane produce opposite effects on the depth to the bottom of the hydrate stability zone.

Applications of results include identifying and quantifying hydrate deposits in shallow sediments using an interdisciplinary approach that includes multiple resolution seismic data evaluation, geological and geochemical groundtruthing and heat-flow analyses as a proxy for activity along faults.     

High-resolution seismic characterization of the gas and gas hydrate system at Green Canyon 955, Gulf of Mexico,USA

The Pliocene and Pleistocene sediments at lease block Green Canyon 955 (GC955) in the Gulf of Mexico include sand-rich strata with high saturations of gas hydrate; these gas hydrate accumulations and the associated geology have been characterized over the past decade using conventional industry three-dimensional (3D) seismic data and dedicated logging-while-drilling (LWD) borehole data. To improve structural and stratigraphic characterization and to address questions of gas flow and reservoir properties, in 2013 the U.S. Geological Survey acquired high-resolution two-dimensional (2D) seismic data at GC955. Combined analysis of all available data improves our understanding of the geological evolution of the study area, which includes basin-scale migration of the Mississippi River sediment influx as well as local-scale shifting of sedimentary channels at GC955 in response to salt-driven uplift, structural deformation associated with the salt uplift, and upward gas migration from deeper sediments that charges the main gas hydrate reservoir and shallower strata. The 2D data confirm that the sand-rich reservoir is composed principally of sediments deposited in a proximal levee setting and that episodes of channel scour, interspersed with levee deposition, have resulted in an assemblage of many individual proximal levee deposit “pods” each with horizontal extent up to several hundred meters. Joint analysis of the 2D and 3D data reveals new detail of a complex fault network that controls the fluid-flow system; large east-west trending normal faults allow fluid flow through the reservoir-sealing fine-grained unit, and smaller north-south oriented faults provide focused fluid-flow pathways (chimneys) through the shallower sediments. This system has enabled the flow of gas from the main reservoir to the seafloor throughout the recent history at GC955, and its intricacies help explain the distributed occurrences of gas hydrate in the intervening strata.     

Gas hydrate and free gas indications within the Cenozoic succession of the Bjørnøya Basin, western Barents Sea

Multichannel seismic data, containing high-amplitude reflections from Cenozoic sediments of the Bjørnøya Basin, southwestern Barents Sea, have been studied, inferring the existence of gas hydrate and free gas. The Cenozoic succession comprises Late Palaeocene and Early Eocene claystones and siltstones and locally also some sandstones overlain by Late Pleistocene glaciogenic sediments. The inferred gas hydrate and free gas accumulations are mainly located in the vicinity of larger faults which can be followed up to base Tertiary level, and which seem to have controlled the geographical distribution of the accumulations. Free gas accumulations are inferred to occur most frequently within the Late Palaeocene strata that occur below the gas hydrate stability zone, and indicate that relatively small gas leakages from deeper accumulations have dominated. Larger gas leakages have probably led to gas migration up into the gas hydrate stability zone and, together with the increasing thickness of the hydrate stability zone towards the north, control the distribution of the suspected gas hydrates. The inferred gas leakages are closely related to the Cenozoic evolution of the Barents Sea, and are probably caused by gas expansion due to the removal of up to 1 km of sediments from the Barents Sea shelf and/or reservoir tilting during the Late Cenozoic glaciations which affected this area.     

Gas hydrates in the western deep-water Ulleung Basin, East Sea of Korea

Geophysical surveys and geological studies of gas hydrates in the western deep-water Ulleung Basin of the East Sea off the east coast of Korea have been carried out by the Korea Institute of Geoscience and Mineral Resources (KIGAM) since 2000. The work included a grid of 4782 km of 2D multi-channel seismic reflection lines and 11 piston cores 5–8 m long. In the piston cores, cracks generally parallel to bedding suggest significant in-situ gas. The cores showed high amounts of total organic carbon (TOC), and from the southern study area showed high residual hydrocarbon gas concentrations. The lack of higher hydrocarbons and the carbon isotope ratios indicate that the methane is primarily biogenic. The seismic data show areas of bottom-simulating reflectors (BSRs) that are associated with gas hydrates and underlying free gas. An important observation is the numerous seismic blanking zones up to 2 km across that probably reflect widespread fluid and gas venting and that are inferred to contain substantial gas hydrate. Some of the important results are: (1) BSRs are widespread, although most have low amplitudes; (2) increased P-wave velocities above some BSRs suggest distributed low to moderate concentration gas hydrate whereas a velocity decrease below the BSR suggests free gas; (3) the blanking zones are often associated with upbowing of sedimentary bedding reflectors in time sections that has been interpreted at least in part due to velocity pull-up produced by high-velocity gas hydrate. High gas hydrate concentrations are also inferred in several examples where high interval velocities are resolved within the blanking zones. Recently, gas hydrate recoveries by the piston coring and deep-drilling in 2007 support the interpretation of substantial gas hydrate in many of these structures.     

南海北部大陆边缘天然气水合物稳定带厚度的地热学研究

The exploration of unconventional and/or new energy resources has become the focus of energy research worldwide,given the shortage of fossil fuels.As a potential energy resource,gas hydrate exists only in the environment of high pressure and low temperature,mainly distributing in the sediments of the seafloor in the continental margins and the permafrost zones in land.The accurate determination of the thickness of gas hydrate stability zone is essential yet challenging in the assessment of the exploitation potential.The majority of previous studies obtain this thickness by detecting the bottom simulating reflectors(BSRs) layer on the seismic profiles.The phase equilibrium between gas hydrate stable state with its temperature and pressure provides an opportunity to derive the thickness with the geothermal method.Based on the latest geothermal dataset,we calculated the thickness of the gas hydrate stability zone(GHSZ) in the north continental margin of the South China Sea.Our results indicate that the thicknesses of gas hydrate stability zone vary greatly in different areas of the northern margin of the South China Sea.The thickness mainly concentrates on 200–300 m and distributes in the southwestern and eastern areas with belt-like shape.We further confirmed a certain relationship between the GHSZ thickness and factors such as heat flow and water depth.The thickness of gas hydrate stability zone is found to be large where the heat flow is relatively low.The GHSZ thickness increases with the increase of the water depth,but it tends to stay steady when the water depth deeper than 3 000 m.The findings would improve the assessment of gas hydrate resource potential in the South China Sea.     

Evidence of gas hydrate from downhole logging data in the Ulleung Basin, East Sea

The Gas Hydrate Research and Development Organization (GHDO) of Korea successfully accomplished both coring (hydraulic piston and pressure coring) and logging (logging-while-drilling, LWD, and wireline logging) to investigate the presence of gas hydrate during the first deep drilling expedition in the Ulleung Basin, East Sea of Korea (referred to as UBGH1) in 2007. The LWD data from two sites (UBGH1-9, UBGH1-10) showed elevated electrical resistivity (>80 Ω-m) and P-wave velocity (>2000 m/s) values indicating the presence of gas hydrate. During the coring period, the richest gas hydrate accumulation was discovered at these intervals. Based on log data, the occurrence of gas hydrate is primarily controlled by the presence of fractures. The gas hydrate saturation calculated using Archie’s relation shows greater than 60% (as high as ∼90%) of the pore space, although Archie’s equation typically overestimates gas hydrate saturation in near-vertical fractures. The saturation of gas hydrate is also estimated using the modified Biot-Gassmann theory (BGTL) by Lee and Collett (2006). The saturation values estimated rom BGTL are much lower than those calculated from Archie’s equation. Based on log data, the hydrate-bearing sediment section is approximately 70 m (UBGH1-9) to 130 m (UBGH1-10) in thickness at these two sites. This was further directly confirmed by the recovery of gas hydrate samples and pore water freshening collected from deep drilling core during the expedition. LWD data also strongly support the interpretation of the seismic gas hydrate indicators (e.g., vent or chimney structures and bottom-simulating reflectors), which imply the probability of widespread gas hydrate presence in the Ulleung Basin.     

Gas hydrate identified in sand-rich inferred sedimentary section using downhole logging and seismic data in Shenhu area,South China Sea

Downhole wireline log (DWL) data was acquired from eight drill sites during China's first gas hydrate drilling expedition (GMGS-1) in 2007. Initial analyses of the acquired well log data suggested that there were no significant gas hydrate occurrences at Site SH4. However, the re-examination of the DWL data from Site SH4 indicated that there are two intervals of high resistivity, which could be indicative of gas hydrate. One interval of high resistivity at depth of 171–175 m below seafloor (mbsf) is associated with a high compressional- wave (P-wave) velocities and low gamma ray log values, which suggests the presence of gas hydrate in a potentially sand-rich (low clay content) sedimentary section. The second high resistivity interval at depth of 175–180 mbsf is associated with low P-wave velocities and low gamma values, which suggests the presence of free gas in a potentially sand-rich (low clay content) sedimentary section. Because the occurrence of free gas is much shallower than the expected from the regional depth of the bottom simulating reflector (BSR), the free gas could be from the dissociation of gas hydrate during drilling or there may be a local anomaly in the depth to the base of the gas hydrate stability zone. In order to determine whether the low P-wave velocity with high resistivity is caused by in-situ free gas or dissociated free gas from the gas hydrate, the surface seismic data were also used in this analysis. The log analysis incorporating the surface seismic data through the construction of synthetic seismograms using various models indicated the presence of free gas directly in contact with an overlying gas hydrate-bearing section. The occurrence of the anomalous base of gas hydrate stability at Site SH4 could be caused by a local heat flow conditions. This paper documents the first observation of gas hydrate in what is believed to be a sand-rich sediment in Shenhu area of the South China Sea.     

Potential map of gas hydrate formation in Caspian Sea based on physicochemical stability evaluation of methane hydrate

Preliminary studies of Caspian Sea have shown the possibility of gas hydrate accumulations, because of suitable physicochemical conditions, existence of clayey deposits, and high concentrations of organic matter. Studies have indicated that gas hydrates are mainly composed of methane. Therefore, based on physicochemical equations for methane hydrate stability in different pressure, temperature, and salinity, this study was designed to calculate the potential of gas hydrate formation in the Caspian Sea basin. For this, data of more than 600 locations were analyzed and in each location, upper and lower limits of methane hydrate formation zone were calculated. Then, the zoning maps of upper and lower limits were prepared which can be useful for exploring the gas hydrate as an energy source or predicting gas hydrate hazards. According to the calculations and maps, methane hydrate formation in Caspian Sea, theoretically, can take place from near the seabed to 4000 and 2500 m beneath the sea surface when low and high geothermal gradient are supposed, respectively. By comparing the results with gas hydrate zones revealed in geophysical profiles, it has been shown that, in Caspian Sea, gas hydrates probably accumulate near the lower limit when a high geothermal gradient is assumed.     

Estimation of seismic velocities and gas hydrate concentrations: A case study from the Shenhu area,northern South China Sea

In the Shenhu area of the northern South China Sea (SCS), canyon systems and focused fluid flow systems increase the complexity of the gas hydrate distribution in the region. It also induces difficulties in predicting the hydrate reservoir characteristics and quantitatively evaluating reservoir parameters. In this study, several inversion methods have been executed to estimate the velocities of strata and gas hydrate concentrations along a profile in the Shenhu area. The seismic data were inverted to obtain the reflection coefficient of each stratum via a spectral inversion method. Stratigraphic horizons were then delineated by tracking the inverted reflectivities. Based on the results of spectral inversion, a low-frequency velocity field of the strata was constructed for acoustic impedance inversion. Using a new iterative algorithm for acoustic impedance inversion, reflection coefficients were converted into velocities, and the velocity variations of the strata along a 2D seismic line were then obtained. Subsequently, gas hydrate saturations at well SH2 were estimated via the shale-corrected resistivity method, the chloride ion concentration method and three different rock physics models. The results were then compared to determine the optimal rock physics model, and the modified Wood equation (MWE) was found to be appropriate for this area. Finally, the inverted velocities and MWE were used to predict the distribution and concentrations of gas hydrates along the seismic line. The estimated spatial distribution of gas hydrates is consistent with that from sonic logging and resistivity data at well SH2, and with the drilling results. Therefore, this method is applicable in areas with no well data, or with few wells, and provides an effective tool for predicting and evaluating gas hydrates using seismic data.     

Gas hydrate characterization and grain-scale imaging of recovered cores from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

Using cryogenic scanning electron microscopy (CSEM), powder X-ray diffraction, and gas chromatography methods, we investigated the physical states, grain characteristics, gas composition, and methane isotopic composition of two gas-hydrate-bearing sections of core recovered from the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well situated on the Alaska North Slope. The well was continuously cored from 606.5 m to 760.1 m depth, and sections investigated here were retrieved from 619.9 m and 661.0 m depth. X-ray analysis and imaging of the sediment phase in both sections shows it consists of a predominantly fine-grained and well-sorted quartz sand with lesser amounts of feldspar, muscovite, and minor clays. Cryogenic SEM shows the gas-hydrate phase forming primarily as a pore-filling material between the sediment grains at approximately 70-75% saturation, and more sporadically as thin veins typically several tens of microns in diameter. Pore throat diameters vary, but commonly range 20-120 microns. Gas chromatography analyses of the hydrate-forming gas show that it is comprised of mainly methane (>99.9%), indicating that the gas hydrate is structure I. Here we report on the distribution and articulation of the gas-hydrate phase within the cores, the grain morphology of the hydrate, the composition of the sediment host, and the composition of the hydrate-forming gas.     

Sediment mounds and other sedimentary features related to hydrate occurrences in a columnar seismic blanking zone of the Ulleung Basin, East Sea, Korea

A mound related to a cold vent in a columnar seismic blanking zone (CSBZ) was formed around site UBGH1-10 in the central Ulleung Basin (2077 m water depth), East Sea, Korea. The mound is 300–400 m wide and 2–3 m high according to multi-beam bathymetry, 2–7 kHz sub-bottom profiler data, and multi-channel reflection seismic data. Seafloor topography and characteristics were investigated using a remotely operated vehicle (ROV) around site UBGH1-10, which is located near the northern part of the mound. The origin of the mound was investigated through lithology, mineralogy, hydrate occurrence, and sedimentary features using dive cores, piston cores, and a deep-drilling core. The CSBZ extends to ∼265 ms two-way traveltime (TWT) below the seafloor within a mass-transport deposit (MTD) unit. Gas hydrate was entirely contained 6–141 m below the seafloor (mbsf) within hemipelagic deposits intercalated with a fine-grained turbidite (HTD) unit, characteristically associated with high resistivity values at site UBGH1-10. The hydrate is commonly characterized by veins, nodules, and massive types, and is found within muddy sediments as a fracture-filling type. Methane has been produced by microbial reduction of CO₂, as indicated by C₁/C₂₊, δ¹³CCH4, and δD₄CH analyses. The bowl-shaped hydrate cap revealed at 20–45 ms TWT below the seafloor has very high resistivity and high salinity, suggesting rapid and recent gas hydrate formation. The origin of the sediment mound is interpreted as a topographic high formed by the expansion associated with the formation of the gas hydrate cap above the CSBZ. The lower sedimentation rate of the mound sediments may be due to local enhancement of bottom currents by topographic effects. In addition, no evidence of gas bubbles, chemosynthetic communities, or bacterial mats was observed in the mound, suggesting an inactive cold vent.     

Evidence for gas hydrate occurrences in the Canadian Arctic Beaufort Sea within permafrost-associated shelf and deep-water marine environments

The presence of a wedge of offshore permafrost on the shelf of the Canadian Beaufort Sea has been previously recognized and the consequence of a prolonged occurrence of such permafrost is the possibility of an underlying gas hydrate regime. We present the first evidence for wide-spread occurrences of gas hydrates across the shelf in water depths of 60–100 m using 3D and 2D multichannel seismic (MCS) data. A reflection with a polarity opposite to the seafloor was identified ∼1000 m below the seafloor that mimics some of the bottom-simulating reflections (BSRs) in marine gas hydrate regimes. However, the reflection is not truly bottom-simulating, as its depth is controlled by offshore permafrost. The depth of the reflection decreases with increasing water depth, as predicted from thermal modeling of the late Wisconsin transgression. The reflection crosscuts strata and defines a zone of enhanced reflectivity beneath it, which originates from free gas accumulated at the phase boundary over time as permafrost and associated gas hydrate stability zones thin in response to the transgression. The wide-spread gas hydrate occurrence beneath permafrost has implications on the region including drilling hazards associated with the presence of free gas, possible overpressure, lateral migration of fluids and expulsion at the seafloor. In contrast to the permafrost-associated gas hydrates, a deep-water marine BSR was also identified on MCS profiles. The MCS data show a polarity-reversed seismic reflection associated with a low-velocity zone beneath it. The seismic data coverage in the southern Beaufort Sea shows that the deep-water marine BSR is not uniformly present across the entire region. The regional discrepancy of the BSR occurrence between the US Alaska portion and the Mackenzie Delta region may be a result of high sedimentation rates expected for the central Mackenzie delta and high abundance of mass-transport deposits that prohibit gas to accumulate within and beneath the gas hydrate stability zone.     

Source and accumulation of gas hydrate in the northern margin of the South China Sea

The northern South China Sea (NSCS) experienced continuous evolution from an active continental margin in the late Mesozoic to a stable passive continental margin in the Cenozoic. It is generally believed that the basins in the NSCS evolved as a result of Paleocene–Oligocene crustal extension and associated rifting processes. This type of sedimentary environment provides a highly favourable prerequisite for formation of large-scale oil- and gas–fields as well as gas hydrate accumulation. Based on numerous collected data, combined with the tectonic and sedimentary evolution, a preliminary summary is that primitive coal-derived gas and reworked deep gas provided an ample gas source for thermogenic gas hydrate, but the gas source in the superficial layers is derived from humic genesis. In recent years, the exploration and development of the NSCS oil, gas and gas hydrate region has provided a basis for further study. A number of 2D and 3D seismic profiles, the synthetic comparison among bottom simulating reflector (BSR) coverage characteristics, the oil-gas area, the gas maturity and the favourable hydrate-related active structural zones have provided opportunities to study more closely the accumulation and distribution of gas hydrate. The BSR has a high amplitude, with high amplitude reflections below it, which is associated with gas chimneys and pockmarks. The high amplitude reflections immediately beneath the BSR are interpreted to indicate the presence of free gas and gas hydrate. The geological and geochemical data reveal that the Cenozoic northern margin of the NSCS has developed coal-derived gas which forms an abundant supply of thermogenic gas hydrate. Deep-seated faults and active tectonic structures facilitate the gas migration and release. The thermogenic gas hydrate and biogenic gas are located at different depths, have a different gas source genesis and should be separately exploited. Based on the proven gas hydrate distribution zone, we have encircled and predicted the potential hydrate zones. Finally, we propose a simple model for the gas hydrate accumulation system in the NSCS Basin.     

Distribution and expression of gas seeps in a gas hydrate province of the northeastern Sakhalin continental slope, Sea of Okhotsk

Multidisciplinary surveys were conducted to investigate gas seepage and gas hydrate accumulation on the northeastern Sakhalin continental slope (NESS), Sea of Okhotsk, during joint Korean–Russian–Japanese expeditions conducted from 2003 to 2007 (CHAOS and SSGH projects). One hundred sixty-one gas seeps were detected in a 2000 km² area of the NESS (between 53°45′N and 54°45′N). Active gas seeps in a gas hydrate province on the NESS were evident from features in the water column, on the seafloor, and in the subsurface: well-defined hydroacoustic anomalies (gas flares), side-scan sonar structures with high backscatter intensity (seepage structures), bathymetric structures (pockmarks and mounds), gas- and gas-hydrate-related seismic features (bottom-simulating reflectors, gas chimneys, high-amplitude reflectors, and acoustic blanking), high methane concentrations in seawater, and gas hydrates in sediment near the seafloor. These expressions were generally spatially related; a gas flare would be associated with a seepage structure (mound), below which a gas chimney was present. The spatial distribution of gas seeps on the NESS is controlled by four types of geological structures: faults, the shelf break, seafloor canyons, and submarine slides. Gas chimneys that produced enhanced reflection on high-resolution seismic profiles are interpreted as active pathways for upward gas migration to the seafloor. The chimneys and gas flares are good indicators of active seepage.