云开地区变质沉积岩碎屑锆石U-Pb年龄、Lu-Hf同位素特征及其地质意义

华夏陆块西南部云开地块变质杂岩主要由天堂山岩群和云开群以及古生代花岗质岩石组成。天堂山岩群主要由片麻岩、变粒岩、石英岩等岩石组成,变质程度较深;云开群主要由片岩、板岩、千枚岩、变质砂岩等岩石组成。应用LA-ICP-MS U-Pb微区定年和Lu-Hf同位素分析以及全岩地球化学分析方法,本文对天堂山岩群和云开群变质沉积岩进行了研究。在阴极发光图像中,变质沉积岩的锆石显示岩浆震荡环带,但普遍遭受重结晶改造及存在变质增生边。由于变质增生边普遍较窄,U-Pb定年和Hf同位素分析几乎都在具岩浆环带和重结晶结构的成分域上完成的。具岩浆环带和重结晶结构的成分域的Th/U比值普遍大于0.1。年龄变化从3000~500Ma,但主要集中在600~1200Ma之间,主峰值为960Ma左右。碎屑锆石的ε_(Hf)(t)值在-25.6~15.4之间,两阶段Hf模式年龄在972~4496Ma之间。全岩地球化学分析显示LREE富集,HREE亏损,具有较明显的负Eu异常(δEu=0.55~0.71),天堂山岩群与云开群REE配分模式一致,反映源区物质相似,主要来源于花岗质地壳物质。结合前人研究成果,可得出如下结论:天堂山岩群与云开群形成时代没有明显差别,虽然它们在变质变形方面存在较明显区别;天堂山岩群和云开群沉积时代为古生代早期-新元古代;格林威尔期岩浆岩为主要物源区,新元古代时期华夏陆块处于格林威尔造山带内与之相邻;华夏陆块存在太古宙古老陆壳。     

U-Pb SHRIMP dating of zircons from metamorphic complexes in eastern Kamchatka

The metamorphic complexes of eastern Kamchatka exposed on the Khavyven Highland and Karaginsky Island, as well as on the Kamchatka and Ozernoi peninsulas, compose large (up to 1.5 km) elongated blocks spatially associated with ophiolitic peridotite and gabbroic rock bodies (the Khavyven Highland and Karaginsky Island) or make up isolated fragments and blocks among serpentinite melange (the Ozernoi and Kamchatka peninsulas). The degree of metamorphism of the primary rocks varies from the greenschist/amphibolite boundary facies (Karaginsky Island and the Khavyven Highland) to the high-pressure amphibolite facies (the Ozernoi and Kamchatka peninsulas).     

Chemistry and genesis of garnets in metamorphic rocks

250 analyses of garnets in metamorphic pelitic, arkosic, and pyroclastic rocks from the Stavanger area have been made by means of a microprobe (ARL-EMX). The relations between chemistry and metamorphic grade are discussed. The dependence of the Mn content upon temperature, pressure, chemistry of the parent rocks and oxygen fugacity is a very sophisticated one.It is shown that the Mn content of the garnets depends on the oxygen fugacity of the system and that the oxygen fugacity is strongly linked to the behaviour of graphite during increasing metamorphism.Examples described by Miyashiro (1953) and Engel and Engel (1960) are in agreement with the model presented here.Some observations show an influence of primary sedimentary enrichments of manganese upon the first occurrence of garnets in the course of metamorphism.     

包含变质岩分类三要素的主要变质岩分类表

变质岩分类的三要素是:变质岩的物质成分(化学成分、矿物成分)、变质岩的组构(结构、构造)和变质岩的成因(变质作用类型和形成变质岩的物理化学条件).由于变质岩的化学成分、矿物成分、组构特征和形成变质岩的地质环境十分复杂,致使至今尚无以变质岩分类三要素为基础的、内容比较完善的分类方案.本文中主要变质岩的分类是以其分类三要素为基础编制的,首次将不同成因的变质岩类并列于同一表中、将鉴定变质岩的主要标志性矿物成分和组构特征列入同一分类表中.该分类对鉴定变质岩石具有可操作性和实用性,分类表中涵盖了自然界主要的变质岩石.     

大别地体超高压变质岩石锆石Lu-Hf同位素研究

对大别山南部超高压变质带双河和黄镇地区的榴辉岩、片麻岩和硬玉石英岩中变质锆石进行了原位LA-MC-ICPMS的Lu-Hf同位素分析.双河和黄镇的榴辉岩及双河的硬玉石英岩有低176Lu/177Hf和低176Hf/177Hf组成,两地的片麻岩有高176Hf/177Hf比和高且分散的176Lu/177Hf组成.锆石Hf同位素分布主要受变质原岩的形成时代控制,增生锆石基本上继承了原岩锆石的Hf同位素特征,既有增生锆石相对有低176Lu/177Hf和高176Hf/177Hf、继承重结晶锆石相对有高176Lu/177Hf和低176Hf/177Hf的特征,也有二者相互重叠没有区别的,它主要受原岩性质和变质过程中锆石遭受的溶蚀程度控制.增生锆石的低Lu/Hf是锆石在变质过程中Lu含量下降和Hf含量增高造成的,增生锆石的高176Hf/177Hf继承自岩石中其它高Lu/Hf比矿物的长期演化.继承锆石的初始Hf同位素组成εHf值和亏损地幔模式年龄TDM示踪表明,各超高压变质原岩的时代和成因是复杂的：双河榴辉岩原岩物质源自25亿年的亏损地幔和至少27亿年以上的古老晚太古地壳混合.双河片麻岩原岩年龄相同,但有不同的壳幔混合物源.黄镇榴辉岩原岩主要源于亏损幔源岩浆形成的初生地壳的重循环,很少的地壳混染.黄镇片麻岩和榴辉岩的物源区年龄相同.两地片麻岩原岩物源主要来自弱亏损地幔,存在古老地壳物质和地幔物质的混合.大别地区超高压变质岩锆石的Lu-Hf同位素特征主要反映了7～8亿年和18～19亿年时扬子克拉通北缘地区的岩浆活动特点和大地构造环境.     

变质岩中锆石在薄片下的原位阴极发光研究

大多数阴极发光研究都是在从岩石样品分选出的锆石上进行的。然而,要弄清形成演化历史复杂的锆石成因很困难。为了克服这一不足,更好地了解锆石是如何受周围环境的影响,对变质岩广泛分布的大青山地区3个变质岩石样品进行了薄片下的锆石阴极发光研究。主要结论为:包裹在造岩矿物中的锆石,变质增生边不发育,但可发生不同程度的重结晶;流体对锆石重结晶和变质增生边形成具有重要的意义,流体可来自岩石体系之外,也可来自其内部;以往的研究中,一些重结晶锆石可能被错误地当作了变质增生锆石。     

河北省宽城县孤山子超基性岩体锆石U-Pb年龄及Hf同位素特征

华北克拉通北缘在早石炭世晚期—中二叠世出露大量中酸性侵入岩体,但基性-超基性岩体出露较少,因而缺乏对该时期地幔性质的认识。笔者对位于内蒙古地轴以南百余千米的孤山子超基性岩体开展锆石U-Pb定年、微量元素、Lu-Hf同位素组成测试分析。结果显示,孤山子超基性岩体LA-ICP-MS锆石U-Pb加权平均年龄为296.9±2.6 Ma,为早二叠世的岩浆活动产物。锆石(样号:GSZ-B3)微量元素含量低,具有强Ce正异常和弱Eu负异常特征以及较低的εHf(t)=-1.9~-7.5(n=17),表明其源区主要为富集的岩石圈地幔。锆石tDM、tCDM远大于其U-Pb年龄,表明岩石圈地幔形成过程中有再造古老地壳加入。对比内蒙古地轴上的同时代波罗诺岩体含角闪辉长岩(297±1 Ma)的锆石εHf(t)(-17.0~-14.1),孤山子超基性岩体的锆石εHf(t)明显偏大,表明孤山子超基性岩体的源区富集程度相对较小。此外,孤山子超基性岩体还有2个锆石测点εHf(t)分别为3.2、4.0,指示母岩浆中有少量亏损幔源物质加入,这暗示了华北克拉通北缘局部地区,在晚古生代已有岩石圈拉张减薄的趋势。     

Oxygen isotope composition of kaolinite rocks as an indicator of different stages of their lithogenesis

Doklady Earth Sciences -     

苏鲁-大别超高压岩石中锆石SHRIMP U-Pb定年研究——综述和最新进展

如何建立苏鲁-大别超高压岩石深俯冲-超高压-快速折返过程连续而完整的P-T-t轨迹及精细的年代谱系,是目前地学界研究的热点。而变质锆石是否记录深俯冲石英榴辉岩相进变质阶段的年代学信息和超高压峰期变质时代的准确归属,是目前苏鲁-大别超高压变质带需要深入研究的核心问题。本文在对前人同位素年代学方面所取得的成果进行系统总结的基础上。采用锆石中矿物包体激光拉曼和电子探针测试、锆石阴极发光图像成因分析以及SHRIMP U-Pb定年等综合研究手段,确定苏鲁-大别地体榴辉岩及其强退变质围岩在深俯冲-构造折返过程中主要经历了四个阶段的变质演化:深俯冲石英榴辉岩相进变质(Ⅰ)、超高压峰期变质(Ⅱ)、构造折返初期石英榴辉岩相退变质(Ⅲ)和构造折返晚期角闪岩相退变质(Ⅳ)。研究发现,扬子板块(中)新元古代巨量的陆壳物质在早三叠纪(246～244Ma)俯冲到华北板块之下约65km的深处。发生了石英榴辉岩相进变质,相应的变质温压条件为T=542～693℃,P=1.7～2.02GPa。这些高压石英榴辉岩相岩石在中-新三叠纪继续向下俯冲,在235～225Ma期间,俯冲的深度至少达到了170km的地幔深处,并发生了峰期柯石英榴辉岩相超高压变质,相应的变质温压条件为T=722～866℃,P>5.5GPa。苏鲁-大别超高压地体自石英榴辉岩相进变质阶段到超高压峰期变质阶段的俯冲速率为7.0km/Myr。这些超高压岩石在219～216Ma期间,发生了第一次构造抬升至75km的深处,并经历了石英榴辉岩相退变质作用的改造,退变质温压条件为T=730～780℃,P=1.7～2.6GPa。这些退变质岩石在212～205Ma期间,又经历了第二次抬升至25km中-下地壳深处,并叠加了角闪岩相退变质作用,该阶段变质温压条件为T=610～710℃,P=0.7～1.2GPa。苏鲁-大别超高压地体两次构造抬升的速率大致相同,为5.6km/Myr。该项成果不仅确定了苏鲁-大别榴辉岩及其强退变质岩石深俯冲过程石英榴辉岩相进变质-超高压峰期变质、构造折返过程石英榴辉岩相-角闪岩相退变质连续而完整的变质演化P-T-t轨迹及精细的年代谱系,而且对于重新建立苏鲁-大别巨量陆壳物质快速超深俯冲-快速折返的动力学模式有着重要的科学意义。     

Rare-earth elements in high-alumina basaltic rocks from Sardinia

High-alumina basalts and basic andesites, which represent the most “primitive” magma types of the Cenozoic andesitic series of Sardinia, show a spatial chemical zonation with respect to REE. The basaltic rocks from the northern and south-central part of the island have REE patterns typical of calc-alkaline rocks with an enrichment of light REE and fractionation of heavy REE. In contrast, those from the southernmost part have a pattern similar to typical continental tholeiites with only a small light-REE enrichment and unfractionated heavy REE.The present data suggest that basaltic rocks may be formed by anatexis of upper-mantle material with mineral assemblages containing either garnet (calc-alkaline rocks) or spinel (rocks of tholeiitic affinities). The presence of garnet or spinel could merely reflect mineral phase transformation and indicates a different depth of fusion for the various types of basaltic rocks with those of tholeiitic affinities originating at a shallower depth than the calcalkaline rocks. The REE data are consistent with the generation of the basaltic rocks by partial melting of mantle peridotite overlying a subducted plate.     

CCSD超高压变质金红石U-Pb定年及其约束意义

本文尝试性地对来自中国大陆科学钻探(CCSD)主孔及地表的超高压(UHP)变质榴辉岩中的金红石进行了U-Pb定年研究,初步获得了211±22Ma的等时线年龄,这是苏北地区榴辉岩型金红石矿床的第一个直接的年龄结果,结合前人在大别山地区获得的首个准确的金红石U-Pb年龄218Ma及金红石U-Pb体系大约500℃的封闭温度分析,该年龄代表的是UHP变质峰值期后板块折返过程的冷却年龄,峰值期形成的金红石在此时发生了变质重结晶作用.此年龄对整个苏鲁UHP变质地体的俯冲-折返历史及本地区榴辉岩型金红石矿床的形成过程都有重要的约束意义.     

南苏鲁超高压带和高压带边界的准确限定——来自变质岩锆石中矿物包体的证据

南苏鲁地区由 4个岩片组成 ,自西北至东南依次为正片麻岩岩片 (Ⅰ )、表壳岩岩片 (Ⅱ )、含蓝晶石石英岩大理岩岩片 (Ⅲ )和副片麻岩变火山岩片岩岩片 (Ⅳ )。上述构造岩片均经历了强烈的角闪岩相绿片岩相退变质作用的改造。采用激光拉曼、阴极发光和电子探针分析技术 ,对南苏鲁方圆约 380 0km2 范围内 93件锆石样品中的矿物包体进行了系统鉴定。结果表明 ,在第Ⅰ和Ⅱ岩片样品的锆石中均发现以柯石英为代表的超高压 (UHP)矿物包体 ,而在第Ⅲ和Ⅳ岩片锆石中则保存以文石和多硅白云母为代表的高压 (HP)矿物包体。由此推断 ,第Ⅰ和Ⅱ岩片应归属超高压变质带 ,而第Ⅲ和Ⅳ岩片应归属高压变质带。结合变质作用温压条件的研究结果 ,确定超高压岩石峰期变质温压条件为t=72 3～ 85 2℃ ,p≥ 2 .8× 10 3 MPa ;而高压变质岩石峰期变质温压条件为t =5 0 0～ 6 0 0℃ ,p =1.2× 10 3 ～ 2 .5× 10 3 MPa。最新区域填图结果表明 ,南苏鲁东海地区超高压和高压带之间的接触界线为一典型的韧性剪切带。     

Raman spectrum of carbonaceous material: a possible metamorphic grade indicator for low-grade metamorphic rocks

Raman spectral analyses of carbonaceous material (CM) extracted from pelitic samples along two sections traversing the metamorphic belt of Taiwan were carried out in the present study. The results show similar spectral variations of CM with metamorphic grade as those documented in the literature. However, continuous sampling from zeolite facies through prehnite–pumpellyite facies to greenschist facies metamorphic rocks in the present study does reveal some interesting features on the Raman spectra of CM that were not noted before. Both the Raman D (disordered-)/O (ordered-) peak area (i.e. integrated intensity) ratio and the D/O peak width (i.e. full width at half maximum, FWHM) ratio of the CM decrease with progressive metamorphism, but the most prominent change in the D/O peak area ratio occurs in samples of lower greenschist facies metamorphic grade, while the most significant decrease in the D/O peak width ratio occurs in samples near the boundary of prehnite–pumpellyite facies and greenschist facies. This phenomenon is interpreted as a result of the decoupling of the changing rates of in-plane crystallite size and degree of defects of CM with progressive metamorphism. It is postulated that the Raman spectrum of CM can serve as a metamorphic grade indicator to distinguish samples of prehnite–pumpellyite facies metamorphic grade from those of greenschist facies metamorphic grade.     

Exhumation rate of rocks from Neoproterozoic collisional metamorphic complexes of the Yenisei Ridge

Doklady Earth Sciences -     

Geochemistry of stable oxygen and hydrogen isotopes in minerals and corundum-bearing rocks in northern Karelia as an indicator of their unusual genesis

The paper presents newly obtained data on the oxygen and hydrogen isotopic composition of minerals in corundum occurrences and their host rocks in northern Karelia. Minerals in the Khitoostrov and Varaka corundum-bearing zones have extremely low δ¹⁸O (lower than ?26‰) and δ D (lower than ?215‰), which suggest that the mineral-forming process involved glacial waters and that the minerals preserve the isotopic ratios of their protolith. Aluminous corundum plagioclasites were produced by high-pressure Svecofennian (1.9-1.8 Ga) metamorphism of Paleoproterozoic rocks that had been metasomatized with the involvement of meteoric waters during the Guronian glaciation epoch.     

Oxygen isotope study of metamorphic rocks from the Ouégoa district,New Caledonia

48 minerals from 18 in situ metamorphic rocks (mostly metasediments) from the Ouégoa district have been studied. Particular emphasis was placed on obtaining isotopic data for quartz, calcite and muscovite but some pyroxenes and amphiboles were also examined. Data for Ouégoa rocks show they have tended to be isotopically homogenized by metamorphism and that the effect of increasing metamorphism is to progressively deplete the rocks of heavy C and O isotopes. These results indicate that during metamorphism the rocks isotopically exchanged through the medium of a widespread oxygen-carrying fluid phase. Tentatively assigned temperatures obtained from isotopic data for quartz-calcite and quartz-muscovite pairs, using the calibration curves of Epstein and Taylor (1967), indicate lawsonite in the Ouégoa schists to be stable over a temperature range of 250 to 400° C and epidote from ca. 380° to at least 550° C. Temperatures for metamorphic zones in Ouégoa blueschists closely parallel those obtained for Type III and IV glaucophane-bearing rocks from Ward Creek, California (Taylor and Coleman, 1968). The measured tectonic thickness of lawsonite-bearing schists has been used to calculate a lithostatic pressure increment of 2 Kb and geothermal gradient of 20° C per km for the lawsonite zone. Comparison of lithostatic pressure increment with total pressure increment estimated from the stability relations of lawsonite over the temperature range 250–400° C (3.5 Kb Nitsch, 1972) suggest P _total ≠ P _lithostatic and that that the pressure of the fluid phase may have exceeded lithostatic pressure.     

Rb-Sr isotope systematics in metamorphic rocks,Kongsberg sector,south Norway

Rb-Sr isotope data are presented for gneisses, migmatite neosome material and granitic and gabbroic intrusive rocks from the southern part of the Kongsberg sector, south Norway. The maximum age of the crust in this area appears to be ～1.6 AE. Two metamorphic episodes at ～1.5–1.6 AE and at ～1.1–1.2 AE are recognized. Initial ⁸⁷Sr/⁸⁶Sr ratios for the granitic rocks give evidence for reworking of sialic crust and indicate that approximately 1.6 AE old crust repeatedly acted as a source for granitic magmas for a timespan of ～0.5 AE.     

藏北若拉岗日结合带中的浅变质地层及其锆石SHRIMP U-Pb年龄测定

通过对拉竹龙-西金乌兰湖-金沙江结合带西段若拉岗日一带的地层重新解体厘定,填绘出一套以白云母石英片岩、石英岩、变质石英砂岩为主的绿片岩相浅变质地层.该浅变质地层可与羌塘地块之上的浅变质岩系玛依岗日组对比.对浅变质地层的碎屑锆石进行U-Pb SHRIMP年龄测定,认为所获得的最小年龄值524Ma代表了该套地层沉积时代的下限,再结合该地区出露未变质的泥盆纪地层这一事实,将这套浅变质岩系的形成时代置于早古生代.