Magnetic properties of basalts and geodynamics of the rift zone in the southern Red Sea

Magnetic properties of young rift basalts in the southern Red Sea are studied in detail. It is found that basalt samples dredged in the rift zone are characterized by a large spread in magnetic parameters. The magnetic properties of the basalts are shown to indicate a complex evolution of the Red Sea rift zone. Titanomagnetite grains of the basalts are mostly affected by single-phase oxidation processes and have preserved paleomagnetic information. However, basalts discovered near the rift axis yield evidence of multiphase oxidation of titanomagnetite grains, which is untypical of young oceanic basalts. These basalts have high Curie points and large values of the natural remanent magnetization and Koenigsberger parameter. The corresponding samples were taken in nontransform zones where rocks have experienced the action of significant tectonic forces and, moreover, anomalous geomagnetic field patterns correlate with the position of these zones. Using the magnetic properties of the basalts, the northern segment of the rift axis is relocated.     

A Nd isotopic study of the Kerguelen Islands: Inferences on enriched oceanic mantle sources

The origin of the highly differentiated igneous rocks of the Kerguelen Islands and the nature of their source regions have been investigated by a Nd isotopic study. The Nd isotopic compositions of syenites and granites are identical to those of gabbros and basalts and indicate a common source. The isotopic data preclude the involvement ofold continental crustal material in the genesis of these granitic and alkalic rocks. The data from the Kerguelen samples greatly extend the Nd-Sr isotopic correlation observed for uncontaminated basalts from the oceanic mantle. The large Nd isotopic variations in the Kerguelen samples could be explained by mixing of deep mantle material brought up by a plume and the upper oceanic mantle or by heterogeneities in the lower mantle. An important finding of this study is that there are enriched mantle sources under the oceanic regions. These enriched sources may be ancient in age and are compatible with the 2-b.y. age inferred from the Pb isotope data of these samples. Earth models in future must incorporate this feature of the oceanic mantle in a consideration of mantle-crust evolutionary relationships.     

The subcontinental versus suboceanic debate,I Lead-neodymium-strontium isotopes in primary alkali basalts from a shield area the Ahaggar volcanic suite

Pb, Nd and Sr isotopic compositions have been determined in lherzolite-xenolith-bearing alkali-basalts from the center of the African shield. The present data are very similar to those reported for ocean-island basalts and do not support the hypothesis of different mantle sources for alkali-basalts from continental and oceanic areas. From these observations and on the basis of data obtained for xenolith in kimberlite and for tholeiitic continental basalts one may infer the following terrestrial mantle structure: whereas oceanic tholeiites would originate in upper oceanic mantle, oceanic and continental alkali basalts would come from the lower mantle and tholeiitic continental basalts from the continental lithosphere.     

Transition from platemargin to intraplate environment: Geochemistry of basalts in Paleogene Liaohe basin,northeastern China

Mesozoic and Cenozoic volcanic rocks are widely distributed in the circum-Pacific area of eastern China. These rocks have long been genetically linked to westward subduction of the paleo-Pacific oceanic plate to the eastern Asia continent[1,2]. Research in re-cent years[3―6] has attained conclusions that a simple paleo-Pacific subduction model does not work well in interpreting all the volcanic rocks in eastern China, although some of them could be attributed to circum-Pacific interaction …     

The TiO2–K2O–P2O5 diagram: A method of discriminating between oceanic and non-oceanic basalts

The TiO₂–K₂O–P₂O₅ ternary diagram is proposed as a method of discriminating between oceanic and non-oceanic (continental) basalts. This diagram is effective for non-alkaline “primitive” basalts: fractionated rocks cannot be adequately discriminated. Suitable analyses are those which have total alkalies ≤ 20% in an (Fe₂O₃ + FeO)–MgO–(Na₂O + K₂O) diagram. The proposed dividing line separates 93% of 222 ocean-floor and ocean-ridge basalts into the oceanic field and > 80% of continental basalt analyses into the non-oceanic field. Two exceptions are the Tertiary basalts of Greenland and the Deccan Traps which have oceanic affinities. “Continental” suites displaying an oceanic affinity in the TiO₂–K₂O–P₂O₅ diagram may be a result of abortive attempts to generate new sea floor. Preliminary results for dike swarms and Archean basalts suggest preponderant oceanic affinities. Alteration and metamorphism of oceanic basalts generally occasion enrichment of K₂O relative to TiO₂ and P₂O₅.     

Osmium-strontium-neodymium-lead isotopic covariations in mid-ocean ridge basalt glasses and the heterogeneity of the upper mantle

Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (¹⁸⁷Os/¹⁸⁶Os and ¹⁸⁷Os/¹⁸⁸Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions.     

Origin of Icelandic basalts: A review of their petrology and geochemistry

The petrology and geochemistry of Icelandic basalts have been studied for more than a century. The results reveal that the Holocene basalts belong to three magma series: two sub-alkaline series (tholeiitic and transitional alkaline) and an alkali one. The alkali and the transitional basalts, which occupy the off-rift volcanic zones, are enriched in incompatible trace elements compared to the tholeiites, and have more radiogenic Sr, Pb and He isotope compositions. Compared to the tholeiites, they are most likely formed by partial melting of a lithologically heterogeneous mantle with higher proportions of melts derived from recycled oceanic crust in the form of garnet pyroxenites compared to the tholeiites. The tholeiitic basalts characterise the mid-Atlantic rift zone that transects the island, and their most enriched compositions and highest primordial (least radiogenic) He isotope signature are observed close to the centre of the presumed mantle plume. High-MgO basalts are found scattered along the rift zone and probably represent partial melting of refractory mantle already depleted of initial water-rich melts. Higher mantle temperature in the centre of the Iceland mantle plume explains the combination of higher magma productivity and diluted signatures of garnet pyroxenites in basalts from Central Iceland. A crustal component, derived from altered basalts, is evident in evolved tholeiites and indeed in most basalts; however, distinguishing between contamination by the present hydrothermally altered crust, and melting of recycled oceanic crust, remains non-trivial. Constraints from radiogenic isotope ratios suggest the presence of three principal mantle components beneath Iceland: a depleted upper mantle source, enriched mantle plume, and recycled oceanic crust.The study of glass inclusions in primitive phenocrysts is still in its infancy but already shows results unattainable by other methods. Such studies reveal the existence of mantle melts with highly variable compositions, such as calcium-rich melts and a low-¹⁸O mantle component, probably recycled oceanic crust. Future high-resolution seismic studies may help to identify and reveal the relative proportions of different lithologies in the mantle.     

The origin of high-amplitude magnetic anomalies at the intersection of the Juan de Fuca ridge and Blanco fracture zone

The intersection of the Juan de Fuca ridge and Blanco fracture zone is characterized by unusually high amplitude magnetic anomalies (over 1500 nT) which appear to be associated with a body roughly 50 km in length and 20 km in width aligned along the fracture zone. Simple three-dimensional magnetic models indicate that this anomaly is probably caused by a highly magnetized block of material situated in the western end of the Blanco fracture zone near its intersection with the Juan de Fuca ridge. Rock magnetization studies of tholeiitic basalts dredged from this area confirm the presence of highly magnetized basalts near the ridge crest/transform fault intersection. These tholeiitic basalts are enriched in iron and titanium relative to “normal” oceanic tholeiites, apparently the result of extensive shallow fractionation involving olivine, plagioclase, and clinopyroxene. Magnetic model studies indicate that an average thickness of no more than 500 m of these iron-rich basalts is necessary to produce the observed anomaly pattern. Comparison of these basalts with samples previously dredged from the Juan de Fuca ridge crest suggests that these Fe-rich, highly magnetized basalts probably “leaked” out of the southernmost portion of the Juan de Fuca ridge.     

Nd-isotope systematics of ∼2.7 Ga adakites, magnesian andesites, and arc basalts, Superior Province: evidence for shallow crustal recycling at Archean subduction zones

An association of adakite, magnesian andesite (MA), and Nb-enriched basalt (NEB) volcanic flows, which erupted within ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts, has recently been documented in ∼2.7 Ga Wawa greenstone belts. Large, positive initial ?_Nd values (+1.95 to +2.45) of the adakites signify that their basaltic precursors, with a short crustal residence, were derived from a long-term depleted mantle source. It is likely that the adakites represent the melts of subducted late Archean oceanic crust. Initial ?_Nd values in the MA (+0.14 to +1.68), Nb-enriched basalts and andesites (NEBA) (+1.11 to +2.05), and ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts and andesites (+1.44 to +2.44) overlap with, but extend to lower values than, the adakites. Large, tightly clustered ?_Nd values of the adakites, together with Th/Ce and Ce/Yb systematics of the arc basalts that rule out sediment melting, place the enriched source in the sub-arc mantle. Accordingly, isotopic data for the MA, NEBA, and ‘normal’ arc basalts can be explained by melting of an isotopically heterogeneous sub-arc mantle that had been variably enriched by recycling of continental material into the shallow mantle in late Archean subduction zones up to 200 Ma prior to the 2.7 Ga arc. If the late Archean Wawa adakites, MA, and basalts were generated by similar geodynamic processes as their counterparts in Cenozoic arcs, involving subduction of young and/or hot ocean lithosphere, then it is likely that late Archean oceanic crust, and arc crust, were also created and destroyed by modern plate tectonic-like geodynamic processes. This study suggests that crustal recycling through subduction zone processes played an important role for the generation of heterogeneity in the Archean upper mantle. In addition, the results of this study indicate that the Nd-isotope compositions of Archean arc- and plume-derived volcanic rocks are not very distinct, whereas Phanerozoic plumes and intra-oceanic arcs tend to have different Nd-isotopic compositions.     

Geochemical characteristics of Carboniferous greenstones in the Inner Zone of Southwest Japan

Abstract Greenstones, representing remnants of paleo-oceanic crust, occur in Permian and Jurassic accretionary complexes of the Inner Zone in the Southwestern Japan arc. The formation age of most of the greenstones is early Carboniferous, based on fossil ages for overlying limestones and Sm-Nd isotope ages of the greenstones themselves. The geochemistry of such greenstones is similar to those of present-day oceanic islands. Greenstones of the Permian accretionary complex (Akiyoshi belt) are alkalic and tholeiitic in composition. Some alkali basalts show peculiar features from an EM-1 mantle source, such as the Gough Island and Tristan da Chunha basalts in the South Atlantic. Greenstones of the Jurassic accretionary complex (Tamba belt) are also alkali and tholeiitic basalts with both basalt types in the northern part of the Tamba belt coming from strongly depleted characters similar to a mid-ocean ridge basalt source mantle. The variable geochemistry of the oceanic basalts is explained by hypothesis on existence of a Carboniferous mantle plume below the spreading ridge which divides the Farallon and Izanagi plates. The Akiyoshi belt seamounts and/or oceanic islands of the Farallon plate and Tamba belt seamounts and/or oceanic islands of the Izanagi plate formed simultaneously by the upwelling of the thermal plume. Some part of the Akiyoshi belt basalts originated locally from an EM-1 mantle source, while basalts from the northern parts of the Tamba belt have a normal-type mid-ocean ridge basalt (N-MORB) source component. Existence of an N-MORB signature is consistent with the presence of a spreading center in a Carboniferous 'Pacific Ocean' that caused separation of the Farallon and Izanagi plates. Disparity in accretion ages of the basaltic rocks in the Permian and Jurassic may have been caused by differences in the relative motion of the two plates.     

Native iron in the Earth and space

Thermomagnetic and microprobe studies of native iron in the terrestrial upper-mantle hyperbasites (xenoliths in basalts), Siberian traps, and oceanic basalts are carried out. The results are compared to the previous data on native iron in sediments and meteorites. It is established that in terms of the composition and grain size and shape, the particles of native iron in the terrestrial rocks are close to each other and to the extraterrestrial iron particles from sediments and meteorites. This suggests that the sources of the origin of these particles were similar; i.e., the formation conditions in the Earth were close to the conditions in the meteorites’ parent bodies. This similarity is likely to be due to the homogeneity of the gas and dust cloud at the early stage of the solar system. The predominance of pure native iron in the sediments can probably be accounted for by the fact that interstellar dust is mostly contributed by the upper-mantle material of the planets, whereas the lower-mantle and core material falls on the Earth mainly in the form of meteorites. A model describing the structure of the planets in the solar system from the standpoint of the distribution of native iron and FeNi alloys is proposed.     

Ophiolites of the Eastern Peninsulas zone (Eastern Kamchatka): Age, composition, and geodynamic diversity

Abstract   The geological, geochemical and mineralogical data of dismembered ophiolites of various ages and genesis occurring in accretionary piles of the Eastern Peninsulas of Kamchatka enables us to discriminate three ophiolite complexes: (i) Aptian–Cenomanian complex: a fragment of ancient oceanic crust, composed of tholeiite basalts, pelagic sediments, and gabbroic rocks, presently occurring in a single tectonic slices (Afrika complex) and in olistoplaques in Pikezh complex of the Kamchatsky Mys Peninsula and probably in the mélange of the Kronotsky Peninsula; (ii) Upper Cretaceous complex, composed of highly depleted peridotite, gabbro and plagiogranite, associated with island arc tholeiite, boninite, and high-alumina tholeiitic basalt of supra-subduction origin; and (iii) Paleocene–Early Eocene complex of intra-island arc or back-arc origin, composed of gabbros, dolerites (sheeted dykes) and basalts produced from oceanic tholeiite melts, and back-arc basin-like dolerites. Formation of the various ophiolite complexes is related to the Kronotskaya intra-oceanic volcanic arc evolution. The first ophiolite complex is a fragment of ancient Aptian–Cenomanian oceanic crust on which the Kronotskaya arc originated. Ophiolites of the supra-subduction zone affinity were formed as a result of repeated partial melting of peridotites in the mantle wedge up to the subduction zone. This is accompanied by production of tholeiite basalts and boninites in the Kamchatsky Mys segment and plagioclase-bearing tholeiites in the Kronotsky segment of the Kronotskaya paleoarc. The ophiolite complex with intra-arc and mid-oceanic ridge basalt geochemical characteristics was formed in an extension regime during the last stage of Kronotskaya volcanic arc evolution.     

The Harrat Al-Birk basalts in southwest Saudi Arabia:characteristic alkali mafic magmatism related to Red Sea rifting

Harrat Al-Birk volcanics are products of the Red Sea rift in southwest Saudi Arabia that started in the Tertiary and reached its climax at ~ 5 Ma.This volcanic field is almost monotonous and is dominated by basalts that include mafic-ultramafic mantle xenoliths(gabbro,websterite,and garnet-clinopyroxenite).The present work presents the first detailed petrographic and geochemical notes about the basalts.They comprise vesicular basalt,porphyritic basalt,and flow-textured basalt,in addition to red and black scoria.Geochemically,the volcanic rock varieties of the Harrat Al-Birk are low- to medium-Ti,sodic-alkaline olivine basalts with an enriched oceanic island signature but extruded in a within-plate environment.There is evidence of formation by partial melting with a sort of crystal fractionation dominated by clinopyroxene and Fe-Ti oxides.The latter have abundant titanomagnetite and lesser ilmenite.There is a remarkable enrichment of light rare earth elements and depletion in Ba,Th and K,Ta,and Ti.The geochemical data in this work suggest Harrat Al-Birk basalts represent products of watersaturated melt that was silica undersaturated.This melt was brought to the surface through partial melting of asthenospheric upper mantle that produced enriched oceanic island basalts.Such partial melting is the result of subducted continental mantle lithosphere with considerable mantle metasomatism of subducted oceanic lithosphere that might contain hydrous phases in its peridotites.The fractional crystallization process was controlled by significant separation of clinopyroxene followed by amphiboles and Fe-Ti oxides,particularly ilmenite.Accordingly,the Harrat Al-Birk alkali basalts underwent crystal fractionation that is completely absent in the exotic mantle xenoliths(e.g.Nemeth et al.in The Pleistocene Jabal Akwa A1 Yamaniah maar/tuff ring-scoria cone complex as an analogy for future phreatomagmatic to magmatic explosive eruption scenarios in the Jizan Region,SW Saudi Arabia 2014).     

Possible contribution of the asthenosphere, below the subducted oceanic lithosphere, to the genesis of arc magmas: Geochemical evidence from the andean southern volcanic zone (33–46°S)

The application of the Sr/Ca-Ba/Ca systematics to volcanic rocks of the Andean Southern Volcanic Zone (33°S–46°S) has revealed a good correlation between the estimated degree of partial melting required to generate primary magmas and the projected extensions of the oceanic Nazca plate fracture zones under the continental South American plate. Magmas erupted at volcanic centers situated above these projections are thought to have been derived from primary magmas generated by relatively high degrees of melting, whereas those erupted at other centers are thought to have evolved from magmas produced by comparatively low degree of fusion. We interpret this relationship to reflect the facilitation of heat and mass transfer from the asthenosphere below the subducted oceanic lithosphere to the subarc mantle by the fracture zones. This contribution enhances the degree of melting of the subarc mantle source as well as the fraction of material derived from the subducted oceanic crust. This model predicts the predominance of basalts depleted in incompatible trace elements in centers located above the Nazca plate fracture zone extensions and of basalts enriched in incompatible trace elements in centers situated between boundaries of fracture extensions.     

Lead isotope study of orogenic lherzolite massifs

Orogenic lherzolites allow for almost “in-situ” observation of mantle isotopic heterogeneities on a restricted geographical scale, in contrast to basalts for which melting processes have averaged original mantle compositions over uncertain scales. Pb isotopes from whole rocks and clinopyroxenes from the massifs of Lherz (Pyrenees), Lanzo (Alps), Beni Bousera (Morocco) and Zabargad (Red Sea) show internal heterogeneities that encompass the entire range of variation observed in oceanic basalts. Some depleted lherzolites have a very unradiogenic composition similar to that of the most depleted ridge tholeiites. Pyroxenites from mafic layers generally have more radiogenic compositions, some of them comparable to the most radiogenic oceanic island results. The isotopic differences between lherzolites and pyroxenites vanish where layers are very closely spaced ( < 2 cm). In this case, the lherzolites may have equilibrated with the more Pb-rich pyroxenites through solid-state diffusion under mantle conditions. These results directly illustrate the smallest scales at which Pb isotopic heterogeneity may survive within the mantle.The genesis of these heterogeneities are discussed within the framework of the “marble cake” mantle model [1], where lherzolites are residues left over after oceanic crust extraction, whereas pyroxenites represent either basaltic or cumulate portions of the oceanic crust, reinjected by subduction and stretched by solid-state mixing during mantle convection. The Pb isotope data suggest that each massif was involved in several cycles of convective overturn, segregation and reinjection of the oceanic crust, during periods well over 1 Ga.If the upper mantle is made of interlayered radiogenic and unradiogenic layers, basalt heterogeneities may result from preferential melt-extraction from different layers depending on the degree of melting, as well as from large-scale, plume-related mantle heterogeneities. Orogenic lherzolites therefore allow direct observation of disseminated small-scale heterogeneities previously inferred from observations of oceanic basalts from seamounts and ridges.     

Quaternary volcanism of the Japanese Islands

Abstract Quaternary volcanism of the Japanese Islands is examined from the perspective of experimental petrology, geographic distribution of volcanoes and spatial geochemical variations. The dehydration of amphibole and chlorite at a 110 km depth and of phlogopite at ∼180 km in the downdragged hydrous mantle layer would result in the occurrence of two volcanic chains parallel to the trench axis. Long-term subduction of the old Pacific plate and recent subduction of the young Philippine Sea plate beneath East Japan and West Japan volcanic belts respectively, would be critical for the significant difference in intensity, style and geochemistry of Quaternary volcanism between the two volcanic belts. The geochemistry of volcanic rocks in Northeast Japan and those in the Ryukyu arc is typical of 'island-arcs' having low LIL/HFS element ratios, while alkalic basalts along the Japan Sea coast side in Southwest Japan have high LIL/HFS ratios similar to intra-continental or oceanic island basalts. Across-arc variations in eruptive volume and distributional density of volcanoes and in geochemistry are documented in Northeast Japan and are well explained by the decreasing degrees of partial melting toward back-arc side, and the difference in geochemistry of fluids supplied by the downdragged hydrous layer.     

Geological setting of basaltic rocks in an accretionary complex,Khangai–Khentei Belt,Mongolia

We describe the mode of occurrence and geochemical characteristics of basalts, in the Khangai–Khentei belt in Mongolia, overlain by Middle Paleozoic radiolarian chert in an extensive accretionary complex. These basalts are greatly enriched in K, Ti, Fe, P, Rb, Ba, Th, and Nb in comparison to the composition of the mid‐ocean ridge basalts, indicative of within‐plate alkaline type. Ti/Y vs Nb/Y and MnO/TiO₂/P₂O₅ ratios of the basalts also suggest within‐plate affinities. Considering the geochemical characteristics as well as the conformable relationship with the overlying radiolarian chert, the alkaline basalts were clearly not continental but formed a pelagic oceanic island. The mode of occurrence and geochemistry of the basalts show that the alkaline basaltic volcanic activity had taken place to form an oceanic island in the Paleozoic pelagic region sufficiently far from continents to allow radiolarian ooze accumulation.     

Os isotope systematics in ocean island basalts

New ReOs isotopic results for Os-poor basalts from St. Helena, the Comores, Samoa, Pitcairn and Kerguelen dramatically expand the known range of initial ¹⁸⁶Os/¹⁸⁷Os ratios in OIBs to values as high as 1.7. In contrast to the Os isotopic uniformity of Os-rich basalts from the HIMU islands of Tubuai and Mangaia found by Hauri and Hart [1], our values for St. Helena span most of the known range of Os isotopic variability in oceanic basalts (initial ¹⁸⁷Os/¹⁸⁶Os ranges from 1.2 to 1.7). Generation of such radiogenic Os in the mantle requires melting of source materials that contain large proportions of recycled oceanic crust. The very low Os concentrations of most of the basalts analyzed here, however, leave them susceptible to modification via interaction with materials containing radiogenic Os in the near-surface environment. Thus the high ¹⁸⁶Os/¹⁸⁷Os ratios may result from assimilation of radiogenic Os-rich marine sediments, such as Mn oxides, within the volcanic piles traversed by these magmas en route to the surface. Furthermore, the Os isotopic signatures of Os-rich, olivine-laden OIBs may reflect the accumulation of lithospheric olivine, rather than simply their mantle source characteristics. The extent to which these processes alter the view of the mantle obtained via study of ReOs systematics in oceanic basalts is uncertain. These effects must be quantified before ReOs systematics in OIBs can be used with confidence to investigate the nature of mantle heterogeneity and its causes.     

Identification of recycled continental material in the mantle from Sr,Nd and Pb isotope investigations

Pb, Nd and Sr isotope compositions of oceanic basalts have been used to identify recycled components of continent derivation in the mantle. The isotopic compositions of Sr, Nd and Pb, together with U, Pb, Sm, Nd, Rb, and Sr abundances have been determined for back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins, in addition to basalts from South Sandwich Islands, Ascension, St. Helena and Tristan da Cunha. Comparisons made between the isotopic compositions of South Sandwich Islands basalts and Atlantic MORB glasses permit the identification of recycled components of continent derivation in the source of the island arc basalts. Recycled Sr of continent derivation is also recognisable in back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins. However, contemporary reinjection of material with the isotopic structures similar to those identified as a component of island arc and back-arc regions cannot be the sole or dominant influence on the fine structure observed in MORB glasses from the Atlantic Ocean, nor the isotopic compositions of Tristan da Cunha, St. Helena and Ascension basalts. Recycled materials are likely to have been responsible for the generation of these heterogeneities only if they have been stored in the mantle for periods of time exceeding 10⁹ years.     

Trace elements in ocean ridge basalts

A correlary of sea floor spreading is that the production rate of ocean ridge basalts exceeds that of all other volcanic rocks on the earth combined. Basalts of the ocean ridges bring with them a continuous record in space and time of the chemical characteristics of the underlying mantle. The chemical record is once removed, due to chemical fractionation during partial melting. Chemical fractionations can be evaluated by assuming that peridotite melting has proceeded to an olivine-orthopyroxene stage, in which case the ratios of a number of magmaphile elements in the extracted melt closely match the ratios in the mantle. Comparison of ocean ridge basalts and chondritic meteorites reveals systematic patterns of element fractionation, and what is probably a double depletion in some elements. The first depletion is in volatile elements and is due to high accretion temperatures of a large percentage of the earth from the solar nebula. The second depletion is in the largest, most highly charged lithophile elements (“incompatible elements”), probably because the mantle source of the basalts was melted previously, and the melt, enriched in these elements, was removed. Migration of melt relative to solid under ocean ridges and oceanic plates, element fractionation at subduction zones, and fractional melting of amphibolite in the Precambrian are possible mechanisms for depleting the mantle in incompatible elements. Ratios of transition metals in the mantle source of ocean ridge basalts are close to chondritic, and contrast to the extreme depletion of refractory siderophile elements, the reason for which remains uncertain. Variation of ocean ridge basalt chemistry along the length of the ridge has been correlated with ridge elevation. Thus chemically anomalous ridge segments up to 1000 km long appear to broadly coincide with regions of high magma production (plumes, hot spots). Basalt heterogeneity at a single location indicates mantle heterogeneity on a smaller scale. Variation of ocean ridge basalt chemistry with time has not been established, in fact, criteria for recognizing old oceanic crust in ophiolite terrains are currently under debate. The similarity of rare earth element patterns in basalt from ocean ridges, back-arc basins, some young island arcs, and some continental flood basalts illustrates the dangers of tectonic labeling by rare earth element pattern.