The palaeomagnetism and magnetic fabric of cave sediments from Grønligrotta and Jordbrugrotta, Norway

Summary. Twenty-four oriented specimens of laminated clay were obtained from vertical sections in two caves in northern Norway. Studies of the magnetic remanence and susceptibility anisotropy show that the magnetization is depositional in origin and due to magnetite. The palaeomagnetic record in one section is correlated with results from a Swiss lake sediment core to suggest an age of 9600–6800 yr bp for the cave clay. It is shown that the susceptibility lineation produced on gently sloping surfaces was predominantly controlled by gravity and cannot therefore be used directly to estimate the palaeoflow or palaeofield directions.     

Unmixing magnetic remanence curves without a priori knowledge

Many of the natural materials studied in rock and environmental magnetism contain a mixed assemblage of mineral grains with a variety of different origins. Mathematical decomposition of the bulk magnetic mineral assemblage into populations with different properties can therefore be a source of useful environmental information. Previous investigations have shown that such unmixing into component parts can provide insights concerning source materials, transport processes, diagenetic alteration, authigenic mineral growth and a number of other processes. A new approach will be presented that performs a linear unmixing of remanence data into coercivity based end-members using only a minimal number of assumptions. A non-negative matrix factorization (NMF) algorithm for unmixing remanence data into constituent end-members is described with case studies to demonstrate the utility of the approach. The shape of the end-members and their abundances obtained by NMF is based solely on the variation in the measured data set and there is no requirement for mathematical functions or type curves to represent individual components. Therefore, in contrast to previous approaches that aimed to unmix curves into components corresponding to individual minerals and domain states, NMF produces a genetically more meaningful decomposition showing how a data set can be represented as a linear sum of invariant parts. It has been found that the NMF algorithm performs well for both absolute and normalized remanence curves, with the capacity to process thousands of measured data points rapidly.     

Imaging distribution patterns of magnetic minerals by a novel high-Tc-SQUID-based field distribution measuring system: application to Permian sediments

A newly developed field distribution measuring system based on a high- T _c SQUID has been employed in the study of magnetic mineral distribution in several Permian sedimentary rocks. The instrument consists of a small, 1.4×1.4 mm sized YBaCu-oxide SQUID magnetic field sensor that is operated in a thin-walled dewar, so that the sample's surface, at room temperature, can be scanned at a distance of only ∼1.5 mm. The samples were subjected to a saturation remanence perpendicular to the surface and the scanning measurements in zero field reveal that the magnetization might be carried by only a small part of a sample, in one case associated with secondary oxide phases. High-resolution magnetic scans can aid in the interpretation of the magnetic remanence acquisition process.     

Laboratory studies of depositional DRM

Summary. Acquisition of magnetic remanence in slurries of fme grained organic muds settling in long tubes is investigated using a cryogenic magnetometer. The average settling behaviour of remanence carrying grains relative to the whole sediment gives information about the relative magnetic grain size spectrum, whereas the response of settled deposits to vibration gives an indication of the degree of alignment of particles and their average shape.
Two classes of behaviour are apparent in both the time and field dependence of detrital remanent magnetization (DRM) acquisition. Dilute slurries settling in the Earth's field (analogous to detrital sedimentation) acquire a remanence which reaches a maximum after about 2 day, whereas for concentrated slurries (analogous to slumped or bioturbated sediments) this takes only a matter of minutes. The field dependence of DRM in dilute slurries is in plausible quantitative agreement with Stacey's extension of the classical Langevin expression for the susceptibility of a paramagnetic gas, whereas concentrated slurries show a quasi-linear dependence of DRM on the applied field. Inclination errors are generally absent, but do appear in fields less than about 0.5 Oe, and when the magnetic fraction settles out preferentially. A weak negative dependence of DRM on temperature is found, but the results are too crude to provide a further test of Stacey's theory.
Remanence acquisition in slurries settled in zero field indicates that short term post-depositional magnetization processes are relatively unimportant in slurries that have ceased to compact rapidly. A large increase in remanence from naturally occurring sediments to slowly redeposited long cores, to rapidly settled slurries is best explained as a feature of compaction.     

黄土高原最老红粘土的发现及其地质意义

黄土高原红粘土的形成演化与青藏高原隆起、亚洲季风形成演化等有着十分密切的关系。黄土高原中部厚达303m的朝那黄土-红粘土剖面的古地磁年代学表明红粘土形成于8．1Ma，是目前黄土高原上发现的最老的红粘土沉积。这个事实表明大约在8．1Ma：本区构造活动频繁，断裂十分发育，使得鄂尔多斯夷平面解体，六盘山地区呈断块上升，而六盘山以东地区下沉接受红粘土沉积。这可能指示了毗邻的青藏高原有一次显著的构造隆升。     

Rock-magnetic proxies of climate change in the loess-palaeosol sequences of the western Loess Plateau of China

Results of the first detailed study of the climate proxy record in the loess-palaeosol sequence at Xining-one of the few palaeoclimate sites in the currently arid western Loess Plateau of China-illustrate the importance of making many types of rock-magnetic measurements other than susceptibility. A multiparameter approach yielded confirmation that here, as elsewhere in the Loess Plateau, the susceptibility enhancement in palaeosols was caused primarily by ultrafine magnetite and maghaemite. Nevertheless, magnetic enhancement was caused not exclusively by changes in relative grain size, but also by variations in concentration and mineralogy of the magnetic fraction.
The effects of concentration variations were removed through normalization of susceptibility and anhysteretic remanence with saturation magnetization and saturation remanence, respectively. the resulting signal was ascribed more confidently to variation in magnetic grain size, which in turn was interpreted as a better proxy of pedogenesis than simple susceptibility. Variations in magnetic mineralogy were also determined to constrain interpretations further. the data were then used to discuss climate history at Xining. Finally, results from Xining were compared with other western sites and contrasted with eastern sites.
In summary: (1) data is presented from a new Loess Plateau site which also appears to yield a global climate signal; (2) a demonstration is made of a more rock-magnetically robust way to separate concentration, composition and grain-size controls on susceptibility and other magnetic parameters; and (3) models are provided for inter-regional comparisons of palaeoclimate proxy records.     

Rotational remanent magnetization (RRM) and its high temporal and thermal stability

The time and temperature stability of various types of magnetic remanence has been measured in pottery samples containing magnetite and in a clay sample containing manganese ferrite. The time decay of rotational remanent magnetization (RRM), anhysteretic remanent magnetization (ARM) and a low-field isothermal remanent magnetization (IRM) has been measured. While the decay of the last two remanences is easily measurable at about 2 and 19 per cent per decade of time, respectively, the decay of RRM is too small to be measured, being less than about 0.1 per cent per decade of time. Thermal demagnetization of thermoremanent magnetization (TRM), ARM and RRM indicates that RRM is also the most thermally stable. The implications of these experiments are that rocks which exhibit gyromagnetic effects such as RRM contain highly stable particles and therefore are likely to be most suitable for palaeomagnetism.     

Measurements of the Natural Remanent Magnetism and Anisotropy of Susceptibility of some Swedish Glacial Silts

Summary. This paper describes the results of measurements of the magnetic remanence and anisotropy of susceptibility of some Swedish varved silts. An attempt has been made to observe in nature the effects, which have been demonstrated in the laboratory, of water currents on these properties and to obtain new data on the effects of slopes on the direction of remanence.
It was not possible to obtain quantitative confirmation of the effects of water currents though it is shown that the field results fit qualitatively with those from the laboratory and that the effects of currents may in favourable circumstances be neglected or corrected for. By combining the new data on the effects of slopes with those previously published it has been found possible to demonstrate the importance of grain size in determining the magnitude of the bedding error correction and an expression has been found which gives this correction to an accuracy comparable with the error of measurement of remanence direction.
It is concluded that, since all known systematic deviations of the remanence direction may now be corrected for, it should be possible, in suitable circumstances, to obtain reliable estimates of field directions over the last 10,000 years from measurements on the Swedish varves.     

Short-term viscous effects on measurements of remanance

Summary. The magnetic remanence of some rock specimens, when measured in mu-metal shielded magnetometers, appear to include a rapidly acquired (<3-5 s), but slow decaying (> 100 s) component that has a characteristic direction for each magnetometer, which seems to be related to the sequence of specimen positions during measurement. This spurious remanence can be mistaken for a stable, linear, geologically meaningful magnetic vector. The effect can be partially reduced by passing a small current through a coil wound around the mu-metal opening, and largely, but not completely, eliminated by placing the magnetometer in field-free space.     

Palaeomagnetism and magnetic fabric in the Freetown Complex, Sierra Leone

About six separately orientated cores were collected at each of 14 sites distributed throughout the arcuate, west-dipping, 6  km thick, Freetown layered igneous complex. Alternating field and thermal demagnetization both isolate a stable component of remanent magnetism which corresponds to a palaeomagnetic south pole from 13 sites (nine reverse, four normal polarity) at 82.9°S, +32.7°E ( α ₉₅ = 5.6°). This is indistinguishable from that reported in 1971 based on alternating field demagnetization of cores from 10 orientated hand samples.
  The difference between the Freetown pole (age: 193 ± 3  Ma) and other mid-Jurassic poles from West Africa could be due to its greater age. The difference between the whole West African Jurassic pole group and the Karoo pole from southern Africa, however, suggests moderate (∼10°) differential rotation of West Africa relative to the Kaapvaal craton.
  A prevalent magnetic foliation fabric coincides generally with the petrological layering, as might be expected, but a ubiquitous magnetic lineation is predominantly down-dip. This is compatible with a down-dip pyroxene lineation reported to be present in some field outcrops, and interpreted in terms of late-stage deformation during the slow crystallization and cooling of the large igneous body. However, a fold test shows that the igneous layering had already achieved its present attitude before the Complex cooled to ∼570 °C (the maximum blocking temperature of the characteristic remanence).     

Palaeomagnetic constraints on the age of deformation of the Sierras Australes thrust and fold belt, Argentina

A palaeomagnetic study has been carried out on late Palaeozoic rocks exposed in the Sierras Australes thrust and fold belt of Buenos Aires province (Argentina), in the early Permian red sandstones and clay siltstones of the Tunas Formation. The sections sampled are exposed in the eastern parts of the belt, in Sierra de las Tunas (north) and Sierra de Pillahuincó (south). More than 300 specimens were collected from 25 sites, in three localities with different structural attitudes. Demagnetization at high temperatures isolated a characteristic remanence at 20 sites. All the localities have a reverse characteristic remanence, suggesting that the magnetization was acquired during the Kiaman interval. Stepwise tectonic tilt correction suggests that the Tunas Formation in these localities acquired its magnetization during folding in early Permian times. Palaeomagnetic poles were computed for each locality based on partial tilt-corrected remanence directions. Taking into account the fact that these localities are close to one another and that the rocks are all of reverse polarity, a group syntectonic palaeomagnetic pole called Tunas was calculated: longitude: 13.9°E, latitude: 63.0°S; A ₉₅ = 5.4°, K = 39.7, N = 19. This pole is consistent with previously calculated poles from South America assigned to the early Permian. In age it corresponds to the early Permian San Rafaelic tectonic phase of the Sierras Australes. Independent geological evidence indicates that the Tunas Formation underwent syndepositional deformation. We conclude that the Tunas Formation was deposited, deformed and remagnetized, all during the early Permian.     

Mineral magnetic signatures in a long core from Lake Qarun, Middle Egypt

The analysis and interpretation of changes in mineral magnetic signatures from a long (ca. 8.2 m) sedimentary sequence recovered from Lake Qarun, Middle Egypt in 2003 spanning a timescale of approximately the last 2,000 years is reported. A suite of mass specific susceptibility and magnetic remanence measurements were made at irregular intervals downcore on 39 samples. These samples were selected on the basis of trends and abrupt changes in whole-core magnetic susceptibility measured using a Bartington^® MS2E sensor and were analysed for low and high temperature loss on ignition and their particle size distribution. Trends in all mineral magnetic concentration parameters are remarkably similar and were initially used to divide the core into three magnetically distinct zones. The upper and lower sections of the core (0–119 cm and 445–822 cm depth) are characterised by low values for all magnetic concentration parameters. Between 153 and 380 cm depth, concentration parameters are considerably higher, although somewhat variable. The S ratio and percentage loss of remanence after 24 h (IRM_loss) follow a different trend and are inversely related to each other. A low S ratio (<0.7) is associated with a loss of remanence of >4%. On the basis of these parameters, the core can be divided into four zones, and differences in magnetic mineralogy between these four zones were confirmed by measurement of IRM acquisition curves. The major difference between concentration parameters and ratios or percentage loss of IRM lies in the identification of an additional zone below 619 cm depth where the S ratio is high and IRM_loss is low. There is little evidence to suggest that the magnetic signatures are controlled by particle size or by trends in organic matter and/or carbonate content. The signatures appear to be predominantly detrital and show little evidence of post-depositional alteration through dissolution or authigenic addition of bacterial magnetite or greigite. Analysis of Saharan dust deposition rates in Northern Egypt suggests that atmospheric fallout is likely to make only a very minor contribution (<1%) to sedimentation rates in Lake Qarun. The downcore trends therefore appear to reflect major changes in fluvial sediment sources over the ca. 2,000 year time period spanned by this ～8 m core. Preliminary mineral magnetic characterisations of potential local sources suggest that these cannot account for the range of signatures recorded in the Qarun sediments and it is hypothesised that these sediments are derived from Nile river floods.     

Are hydrodynamic shape effects important when modelling the formation of depositional remanent magnetization?

Recent conceptual models have attributed the weak depositional remanent magnetizations observed in natural sediments to flocculation processes in the water column. Magnetic particles included into flocs have not only to rotate themselves into alignment with the geomagnetic field but also the larger particles to which they are attached, making remanence acquisition an inefficient process. Alignment is hindered further when the magnetization vectors of the particles in any given floc partially cancel, reducing the overall magnetic torque. Existing numerical simulations of flocculation effects on depositional remanence formation have been limited to spherical bodies with translational and rotational motion acting independently of each other. In the case of non-spherical flocs, the translational and rotational motion are coupled and such bodies will describe a complex trajectory through the water column. Calculations will be presented that show the torque exerted on a non-spherical floc by the surrounding water can be orders of magnitude greater than the magnetic torque. Non-spherical flocs will, therefore, align less efficiently with the geomagnetic field and hydrodynamic effects may play an important role in controlling the magnitude of sedimentary remanence.     

Effect of compaction on the acquisition of a detrital remanent magnetization in fine-grained sediments

Summary. Measurements of the detrital remanent magnetization (DRM) of redeposited deep-sea sediment of the silty clay grade are described. Variations in the magnitude of an observed remanence inclination error are related to conditions of sediment accumulation, contrasted here as grain-by-grain settling from a dilute dispersion or by settling from a concentrated slurry. For these artificial redepositions post-depositional compaction is shown to be a major factor in shallowing the observed inclination from the ambient field inclination. The term compactive DRM is tentatively assigned to describe such behaviour.     

The magnetic and pore fabrics of extruded and pressed ceramic models

Ceramics were used as a model to investigate the pore fabric originated during ductile deformation. The magnetic anisotropy was used to measure the pore fabric after pore saturation by a ferromagnetic fluid. The ductile deformation of the ceramics was investigated by measuring the magnetic anisotropy of dry specimens. The character and symmetry of the pore fabric are compatible with those of the deformations forming the fabric of the ceramics: in the linearly extruded ceramics, the pore fabric is dominantly prolate, while in the pressed ceramics it is dominantly oblate.     

A catalogue of Spanish archaeomagnetic data

A total of 58 new archaeomagnetic directions has been determined from archaeological structures in Spain. Together with five previous results they allow the compilation of the first archaeomagnetic catalogue for Spain, which includes 63 directions with ages ranging between the 2nd century BC and the 20th century AD. Characteristic remanence directions have been obtained from stepwise thermal and alternating field demagnetization. The hierarchical structure has been respected in the calculation of the mean site directions. Rock magnetic experiments reveal that the main magnetic carrier is magnetite or titanomagnetite with different titanium contents. The age estimate of the studied structures is generally well justified by archaeological constraints. For six structures the proposed date is also supported by physical methods. The data are in close agreement with the French secular variation (SV) curve. This catalogue represents the first step in the construction of a SV curve for the Iberian Peninsula, which will be of much use in archaeomagnetic dating and in modelling of the Earth's magnetic field in Western Europe.     

Storage diagenesis versus sulphide authigenesis: possible implications in environmental magnetism

Experiments involving the gradual drying out of controlled mixtures of soil and organic lake sediment during storage at room temperature show that this leads to a loss of magnetic susceptibility and isothermal remanence greatly in excess of the initial values for the sediment components of the mixtures. We conclude that during storage in the moist state, soil-derived, fine-grained, ferrimagnetic iron oxides (magnetite and/or maghemite) are transformed to paramagnetic and/or imperfect antiferrimagnetic minerals. The imperfect anti-ferromagnetic component of the initial mixtures, which probably includes goethite, appears to survive and may even increase during storage. The experimental results compare well with the previously documented effects of storing wet sediment from the site, Peckforton Mere, Cheshire, U.K., over a comparable time interval. We conclude that transformation of fine grained ferrimagnets during storage diagenesis may be responsible for many of the examples of loss of magnetic susceptibility and remanence attributed by other authors solely to the oxidation of an iron sulphide such as greigite. Only where greigite is positively identified is it valid to infer a contribution from it to the magnetic properties of lake sediments: loss of susceptibility or remanence during storage is not alone a sufficient basis for such an inference. Early drying of samples will normally avoid the effects of storage diagenesis; and recent sediment samples so treated will, where greigite formation, bacterial magnetite and magnetite dissolution are insignificant, provide a valid basis for source identification on the basis of magnetic properties.     

Synfolding magnetization: detection, testing and geological applications

A correct method for determining the direction of a synfolding remanence is described, and a new test, which in a number of cases can discriminate between a true synfolding remanence and a remanence that is the sum of pre- and post-folding components, is suggested. It is shown that it is possible to reveal the folding evolution of a local object under an assumption that the acquisition of the synfolding remanence was synchronous over this object.     

Gyromagnetic remanence acquired by greigite (Fe3S4) during static three-axis alternating field demagnetization

A magnetic study was carried out on lacustrine sediments from the Zoigê basin, Tibetan Plateau, in order to obtain a better understanding of palaeoclimatic changes there. Gyromagnetic remanence (GRM) acquisition is unexpectedly observed during static three-axis alternating field (AF) demagnetization in about 20 per cent of a large number of samples. X-ray diffraction (XRD) analysis on a magnetic extract clearly shows that greigite is the dominant magnetic mineral carrier. Scanning electron microscopy (SEM) reveals that the greigite particles are in the grain size range of 200–300  nm, possibly in the single-domain state. Greigite clumps of about 3  μm size are sealed by silicates. Fitting of XRD peaks yields a crystalline coherence length of about 15  nm, indicating that the particles seen in the SEM are polycrystalline.
  GRM intensities of most samples are of the same order as the NRM, while others show much stronger GRM although their magnetic properties are similar. Variation of the demagnetization sequence confirms that GRM is mainly produced perpendicular to the AF direction. The anisotropy direction can be derived from GRM, but more systematic studies are needed for detailed conclusions. An attempt to correct for GRM failed due to high GRM intensities and because smaller GRM acquisition was also found along the demagnetization axis. Behaviours of acquisition and AF demagnetization of GRM are comparable with those of NRM, ARM, IRM, indicating fine grain sizes of remanence carriers.     

The Slate Islands meteorite impact site: a study of Shock Remanent Magnetization

Summary. A detailed palaeomagnetic study of the Slate Islands meteorite impact site, northern Lake Superior, has successfully isolated a secondary Component of remanence which on the basis of field relationships, models of impact crater formation and laboratory investigation appears to be a Shock Remanent Magnetization (SRM).
Evidence for this hitherto rare type of naturally formed remanence is that:
(a) the component is confined to rocks having experienced intense shock (50 to more than 100 kb) on the basis of shatter-cone development and the presence of planar features in quartz and felspar
(b) the component appears to have been acquired virtually instantaneously in terms of normal geological processes as a combined palaeomagnetic—shatter cone analysis suggests that it was formed within a time interval (perhaps several minutes in duration) between the moment of impact and the formation of the central uplift
(c) the extent of magnetic resetting decreases with increasing distance from the centre of the impact site, and
(d) the degree of resetting increases with the abundance of low coercivity magnetic grains as given by H_cr , a relationship found by other investigators for experimentally-produced SRM.
Intrusive breccias found on the islands yield a secondary component of TRM or TRCM origin which was frozen in after central uplift formation. Increased convergence of shatter cone axes to a central focus after rotation of host rock blocks according to palaeomagnetic data, suggests that the SRM had the same direction as that found in the breccias and hence was aligned with the ambient field at the time of impact.