http://www.sciencedirect.com/science/article/pii/S1674987112000849

New methods are presented for processing and interpretation of shallow marine differential magnetic data,including constructing maps of offshore total magnetic anomalies with an extremely high resolution of up to 1-2 nT,mapping weak anomalies of 5-10 nT caused by mineralization effects at the contacts of hydrocarbons with host rocks,estimating depths to upper and lower boundaries of anomalous magnetic sources,and estimating thickness of magnetic layers and boundaries of tectonic blocks. Horizontal dimensions of tectonic blocks in the so-called "seismic gap" region in the central Kuril Arc vary from 10 to 100 km,with typical dimensions of 25-30 km.The area of the "seismic gap" is a zone of intense tectonic activity and recent volcanism.Deep sources causing magnetic anomalies in the area are similar to the "magnetic belt" near Hokkaido. In the southern and central parts of Barents Sea,tectonic blocks with widths of 30-100 km,and upper and lower boundaries of magnetic layers ranging from depths of 10 to 5 km and 18 to 30 km are calculated.Models of the magnetic layer underlying the Mezen Basin in an inland part of the White Sea-Barents Sea paleorift indicate depths to the lower boundary of the layer of 12-30 km.Weak local magnetic anomalies of 2-5 nT in the northern and central Caspian Sea were identified using the new methods,and drilling confirms that the anomalies are related to concentrations of hydrocarbon.Two layers causing magnetic anomalies are identified in the northern Caspian Sea from magnetic anomaly spectra.The upper layer lies immediately beneath the sea bottom and the lower layer occurs at depths between 30-40 m and 150-200 m.     

http://www.sciencedirect.com/science/article/pii/S1674987113000315

The Panzhihua gabbroic intrusion,part of the plumbing system of the Emeishan large igneous province, intruded late-Proterozoic dolomites and marls about～263 Ma ago.The dolomites in the contact aureole were converted to brucite marbles and a diverse suite of forsterite,diopside and garnet skarns.The variation in mineralogy is explained in part by differences in the composition of the protolith,particularly the proportion of silica minerals and clay,and in part by transfer of elements from intruding magmas.The trace element compositions of most marbles and skarns are very similar to those of unmetamorphosed dolomites and marls,but some contain high Si,Ti,and Fe contents that are interpreted to have come from a magmatic source.Three brucite marbles sampled～10 m from the contact of the intrusion and named "enriched brucite marble" have trace element compositions very different from their dolomitic protolith:their rare earth elements are strongly enriched whereas levels of Nb-Ta,Zr-Hf and Ti are very low.These characteristics resemble those of carbonate liquid in equilibrium with silicate liquid or more probably with silicate minerals in the case of Panzhihua,a similarity we take to indicate that the sample underwent partial melting.Samples taken up to 300 m from the contact contain brucite indicating that high temperatures persisted well into the country rocks.However,other samples collected only tens of metres from the contact are only slightly recrystallized indicating that conditions in the aureole were highly variable.We suggest that temperatures within the aureole were controlled by conduction of heat from the main intrusion and by supply of additional heat from abundant small dykes within the aureole.Circulation of fluids derived from deeper levels in the aureole flushed the carbon dioxide from the dolomite,lowering temperature needed to partially melt carbonate to the temperatures attained near the intrusion.Irregular but extensive heating destabilized the carbonates of the aureole and decarbonation reactions associated with carbonate breakdown and melting emitted a large volume of CO₂,with potential impact on global climate.     

http://www.sciencedirect.com/science/article/pii/S1674987114000334

The Musgrave Province developed at the nexus of the North,West and South Australian cratons and its Mesoproterozoic evolution incorporates a 100 Ma period of ultra-high temperature(UHT) metamorphism from ca.1220 to ca.1120 Ma.This was accompanied by high-temperature A-type granitic magmatism over an 80 Ma period,sourced in part from mantle-derived components and emplaced as a series of pulsed events that also coincide with peaks in UHT metamorphism.The tectonic setting for this thermal event(the Musgrave Orogeny) is thought to have been intracontinental and the lithospheric architecture of the region is suggested to have had a major influence on the thermal evolution.We use a series of two dimensional,fully coupled thermo-mechanical-petrological numerical models to investigate the plausibility of initiating and prolonging UHT conditions under model setup conditions appropriate to the inferred tectonic setting and lithospheric architecture of the Musgrave Province.The results support the inferred tectonic framework for the Musgrave Orogeny,predicting periods of UHT metamorphism of up to 70 Ma,accompanied by thin crust and extensive magmatism derived from both crustal and mantle sources.The results also appear to be critically dependent upon the specific location of the Musgrave Province,constrained between thicker cratonic masses.     

http://www.sciencedirect.com/science/article/pii/S1674987114000449

We review petrologic observations of reaction textures from high-grade rocks that suggest the passage of fluids with variable alkali activities. Development of these reaction textures is accompanied by regular compositional variations in plagioclase, pyroxenes, biotite, amphibole and garnet. The textures are interpreted in terms of exchange and net-transfer reactions controlled by the K and Na activities in the fluids. On the regional scale, these reactions operate in granitized, charnockitized, syenitized etc. shear zones within high-grade complexes. Thermodynamic calculations in simple chemical systems show that changes in mineral assemblages, including the transition from the hydrous to the anhydrous ones, may occur at constant pressure and temperature due only to variations in the H2O and the alkali activities. A simple procedure for estimating the activity of the two major alkali oxides, K2O and Na2O, is imple- mented in the TWQ software. Examples of calculations are presented for well-documented dehydration zones from South Africa, southern India, and Sri Lanka. The calculations have revealed two end-member regimes of alkalis during specific metamorphic processes： rock buffered, which is characteristic for the precursor rocks containing two feldspars, and fluid-buffered for the precursor rocks without K-feldspar. The observed reaction textures and the results of thermodynamic modeling are compared with the results of available experimental studies on the interaction of the alkali chloride and carbonate-bearing fluids with metamorphic rocks at mid-crustal conditions. The experiments show the complex effect of alkali activities in the fluid phase on the mineral assemblages. Both thermodynamic calculations and experiments closely reproduce paragenetic relations theoretically predicted by D.S. Korzhinskii in the 1940s.     

http://www.sciencedirect.com/science/article/pii/S1674987112000308

The Panguan Syncline contains abundant coal resources,which may be a potential source of coalbed methane.In order to evaluate the coalbed methane production potential in this area,we investigated the pore-fracture system of coalbed methane reservoirs,and analyzed the gas sorption and seepage capacities by using various analytical methods,including scanning electron microscopy（SEM）,optical microscopy,mercury-injection test,low-temperature N₂ isotherm adsorption/desorption analyses,lowfield nuclear magnetic resonance and methane isothermal adsorption measurements.The results show that the samples of the coal reservoirs in the Panguan Syncline have moderate gas sorption capacity.However, the coals in the study area have favorable seepage capacities,and are conductive for the coalbed methane production.The physical properties of the coalbed methane reservoirs in the Panguan Syncline are generally controlled by coal metamorphism:the low rank coal usually has low methane sorption capacity and its pore and microfractures are poorly developed;while the medium rank coal has better methane sorption capacity,and its seepage pores and microfractures are well developed,which are sufficient for the coalbed methane’s gathering and exploration.Therefore,the medium rank coals in the Panguan Syncline are the most prospective targets for the coalbed methane exploration and production.     

http://www.sciencedirect.com/science/article/pii/S1674987111000466

The Ordos Basin of North China is not only an important uranium mineralization province, but also a major producer of oil,gas and coal in China.The genetic relationship between uranium mineralization and hydrocarbons has been recognized by a number of previous studies,but it has not been well understood in terms of the hydrodynamics of basin fluid flow.We have demonstrated in a previous study that the preferential localization of Cretaceous uranium mineralization in the upper part of the Ordos Jurassic section may have been related to the interface between an upward flowing,reducing fluid and a downward flowing,oxidizing fluid.This interface may have been controlled by the interplay between fluid overpressure related to disequilibrium sediment compaction and which drove the upward flow,and topographic relief,which drove the downward flow.In this study,we carried out numerical modeling for the contribution of oil and gas generation to the development of fluid overpressure,in addition to sediment compaction and heating.Our results indicate that when hydrocarbon generation is taken into account,fluid overpressure during the Cretaceous was more than doubled in comparison with the simulation when hydrocarbon generation was not considered.Furthermore,fluid overpressure dissipation at the end of sedimentation slowed down relative to the no-hydrocarbon generation case.These results suggest that hydrocarbon generation may have played an important role in uranium mineralization,not only in providing reducing agents required for the mineralization,but also in contributing to the driving force to maintain the upward flow.     

http://www.sciencedirect.com/science/article/pii/S1674987110000319

The 3-D geometry of the seismicity in Hindu Kush–Pamir–western China region has been defined by seismic records for 1975–1999 from the National Earthquake Information Center, the U.S. Geological Survey, and over 16,000 relocated earthquakes since 1975 recorded by the Xinjiang seismic network of China. The results show that most Ms ≥ 5.0 hypocenters in the area are confined to a major intracontinental seismic shear zone (MSSZ). The MSSZ, which dips southwards in Pamir has a north-dipping counterpart in the Hindu Kush to the west; the two tectonic realms are separated by the sinistral Chaman transform fault of the India–Asia collisional zone. We demonstrate that the MSSZ constitutes the upper boundary of a south-dipping, actively subducting Pamir continental plate. Three seismic concentrations are recognized just above the Pamir MSSZ at depths between 45–65 km, 95–120 km, and 180–220 km, suggesting different structural relationships where each occurs. Results from focal mechanism solutions in all three seismological concentrations show orientations of the principal maximum stress to be nearly horizontal in an NNW–SSE direction. The south-dipping Pamir subduction slab is wedge-shaped with a wide upper top and a narrow deeper bottom; the slab has a gentle angle of dip in the upper part and steeper dips in the lower part below an elbow depth of ca. 80–120 km. Most of the deformation related to the earthquakes occurs within the hanging wall of the subducting Pamir slab. Published geologic data and repeated GPS measurements in the Pamir document a broad supra-subduction, upper crustal zone of evolving antithetic (i.e. north-dipping) back-thrusts that contribute to north-south crustal shortening and are responsible for exhumation of some ultrahigh-pressure rocks formed during earlier Tethyan plate convergence. An alternating occurrence in activity of Pamir and Chaman seismic zones indicates that there is interaction between strike-slip movement of the Chaman transform fault system and deep-subduction of the Pamir earthquake zone. Pamir subduction-related seismicity becomes shallower in depth with increasing distance east of the transform fault. Therefore, sinistral movement of the Chaman transform fault appears to be influencing continental deep-subduction in the Pamir region and may provide an explanation for the unusual south-dipping geometry of the intracontinental Pamir plate.     

http://www.sciencedirect.com/science/article/pii/S1674987112001260

Archaea have unique glycerol dialkyl glycerol tetraether (GDGT) lipids that can be used to develop paleotemperature proxies such as TEX₈₆. This research is to validate proposed GDGT-proxies for paleotemperature determination in the South China Sea (SCS). Samples were collected from core-top sediments (0–5 cm) in the northern SCS. Total lipids were extracted to obtain core GDGTs, which were identified and quantified using liquid chromatography-mass spectrometry (LC-MS). The abundance of isoprenoidal GDGTs (iGDGTs) ranged from 271.5 ng/g dry sediment to 1266.3 ng/g dry sediment, whereas the branched GDGTs (bGDGTs), supposedly derived from terrestrial sources, ranged from 22.2 ng/g dry sediment to 56.7 ng/g dry sediment. The TEX₈₆-derived sea surface temperatures ranged from 20.9 °C in the coast (water depth < 160 m) to 27.9 °C offshore (water depth > 1000 m). TEX₈₆-derived temperatures near shore (<160 m water depth) averaged 23.1 ± 2.5 °C (n = 4), which were close to the satellite-derived winter mean sea surface temperature (average 22.6 ± 1.0 °C, n = 4); whereas the TEX₈₆-derived temperatures offshore averaged 27.4 ± 0.3 °C (n = 7) and were consistent with the satellite mean annual sea surface temperature (average 26.8 ± 0.4 °C, n = 7). These results suggest that TEX₈₆ may record the sea surface mean annual temperature in the open ocean, while it likely records winter sea surface temperature in the shallower water.     

http://www.sciencedirect.com/science/article/pii/S1674987114000644

正1.Introduction This special issue of Geoscience Frontiers is a tribute volume honoring the life and career of Jacques Touret.A set of research papers has been assembled,which broadly reflect his research interests over his 50 plus year career.These papers focus on the role that fluids play during the formation and evolution of the Earth's crust.Below I provide a brief summary of the life of Jacques Touret,along with a select bibliography of his more important papers.This is then followed by a brief introduction to the papers assembled for this special issue.     

http://www.sciencedirect.com/science/article/pii/S1674987111001307

South China Sea(SCS) is the largest Western Pacific marginal sea.However,microbial studies have never been performed in the cold seep sediments in the SCS.In 2004."SONNE" 177 cruise found two cold seep areas with different water depth in the northern SCS.Haiyang 4 area,where the water depth is around 3000 m.has already been confirmed for active seeping on the seafloor.such as microbial mats,authigenic carbonate crusts and bivalves.We investigated microbial abundance and diversity in a 5.55-111 sediment core collected from this cold seep area.An integrated approach was employed including geochemistry and 16S rRNA gene phylogenetic analyses.Here,we show that microbial abundance and diversity along with geochemistry profiles of the sediment core revealed a coupled reaction between sulphate reduction and methane oxidation.Acridine orange direct count results showed that microbial abundance ranges from 10~5 to 10~6 cells/g sediment(wet weight).The depth-related variation of the abundance showed the same trend as the methane concentration profile.Phylogenetic analysis indicated the presence of sulphate-reducing bacteria and anaerobic methane-oxidizing archaea.The diversity was much higher at the surface,but decreased sharply with depth in response to changes in the geochemical conditions of the sediments,such as methane,sulphate concentration and total organic carbon.Marine Benthic Group B.Chloroflexi and JSl were predominant phylotypes of the archaeal and bacterial libraries,respectively.     

http://www.sciencedirect.com/science/article/pii/S1674987114000668

Microbial diversity in the hydrate-containing (sites SH3B and SH7B) and-free (sites SH1B, SH5B, SH5C) sediments collected from the Shenhu area of the South China Sea (SCS) was investigated using 16S rR...     

http://www.sciencedirect.com/science/article/pii/S1674987111001356

A total of 103 surface sediment samples collected from the water depth range of 15—3300 m along Vijaydurg-Karwar stretch of central west coast of India were analyzed for foraminiferal content. Relict benthic foraminiferal assemblage was noted within 50—135 m water depth.The relict benthic foraminiferal assemblage that includes Amphistegina,Operculum and Alveolinetta in sediment samples within the water depth of 85—135 m indicates presence of coral reef at this depth during Early Holocene. The presence of barnacle fouling on Relict foraminifera at 60—90 m confirms the paleo-shoreline. The shallow depth zone is characterized by presence of agglutinated relict foraminifera.The agglutinated forms indicate freshwater influx,which eventually increased the sea level and subsequently deteriorated the paleo-coral reef.     

http://www.sciencedirect.com/science/article/pii/S1674987111001009

The North Yellow Sea Basin is a Mesozoic and Cenozoic basin.Based on basin-margin facies,sedimentary thinning,size and shape of the basin and vitrinite reflectance.North Yellow Sea Basin is not a residual basin.Analysis of the development of the basin’s three structural layers,self-contained petroleum systems,boundary fault activity,migration of the Mesozoie—Cenozoic sedimentation centers, different basin structures formed during different periods,and superposition of a two-stage extended basin and one-stage depression basin,the North Yellow Sea Basin is recognized as a superimposed basin.     

http://www.sciencedirect.com/science/article/pii/S1674987114001133

A chronological study of seamount rocks in the South China Sea basin provides a great opportunity to understand the expansion and evolution history of the sea basin. In this paper, we analyzed the 40Ar...     

The boring billion? – Lid tectonics, continental growth and environmental change associated with the Columbia supercontinent

The evolution of Earth＇s biosphere,atmosphere and hydrosphere is tied to the formation of continental crust and its subsequent movements on tectonic plates.The supercontinent cycle posits that the continental crust is periodically amalgamated into a single landmass,subsequently breaking up and dispersing into various continental fragments.Columbia is possibly the first true supercontinent,it amalgamated during the 2.0-1.7 Ga period,and collisional orogenesis resulting from its formation peaked at 1.95-1.85 Ga.Geological and palaeomagnetic evidence indicate that Columbia remained as a quasi-integral continental lid until at least 1.3 Ga.Numerous break-up attempts are evidenced by dyke swarms with a large temporal and spatial range; however,palaeomagnetic and geologic evidence suggest these attempts remained unsuccessful.Rather than dispersing into continental fragments,the Columbia supercontinent underwent only minor modifications to form the next supercontinent （Rodinia） at 1.1 -0.9 Ga; these included the transformation of external accretionary belts into the internal Grenville and equivalent collisional belts.Although Columbia provides evidence for a form of ‘lid tectonics’,modern style plate tectonics occurred on its periphery in the form of accretionary orogens.The detrital zircon and preserved geological record are compatible with an increase in the volume of continental crust during Columbia＇s lifespan; this is a consequence of the continuous accretionary processes along its margins.The quiescence in plate tectonic movements during Columbia＇s lifespan is correlative with a long period of stability in Earth＇s atmospheric and oceanic chemistry.Increased variability starting at 1.3 Ga in the environmental record coincides with the transformation of Columbia to Rodinia; thus,the link between plate tectonics and environmental change is strengthened with this interpretation of supercontinent history.     

http://www.sciencedirect.com/science/article/pii/S1674987112000643

Incipient charnockites represent granulite formation on a mesoscopic scale and have received considerable attention in understanding fluid processes in the deep crust.Here we report new petrological data from an incipient charnockite locality at Rajapalaiyam in the Madurai Block,southern India,and discuss the petrogenesis based on mineral phase equilibrium modeling and pseudosection analysis. Rajapalaiyam is a key locality in southern India from where diagnostic mineral assemblages for ultrahigh-temperature（UHT） metamorphism have been reported.Proximal to the UHT rocks are patches and lenses of charnockite（Kfs + Qtz + Pl + Bt + Opx + Grt + Ilm） occurring within Opx-free Grt-Bt gneiss（Kfs + Pl + Qtz + Bt + Grt + Ilm + Mt） which we report in this study.The application of mineral equilibrium modeling on the charnockitic assemblage in NCKFMASHTO system yields a p-T range of～820℃and～9 kbar.Modeling of the charnockite assemblage in the MnNCKFMASHTO system indicates a slight shift of the equilibrium condition toward lower p and T（～760℃and～7.5 kbar）. which is consistent with the results obtained from geothermobarometry（710—760℃,6.7—7.5 kbar）. but significantly lower than the peak temperatures（>1000℃） recorded from the UHT rocks in this locality,suggesting that charnockitization is a post-peak event.The modeling of T versus molar H₂O content in the rock（M（H₂O）） demonstrates that the Opx-bearing assemblage in charnockite and Opxfree assemblage in Grt-Bt gneiss are both stable at M（H₂O） = 0.3 mol%-0.6 mol%.and there is no significant difference in water activity between the two domains.Our finding is in contrast to the previous petrogenetic model of incipient charnockite formation which envisages lowering of water activity and stabilization of orthopyroxene through breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid.T-X_Fe³⁺（= Fe₂O₃/（FeO + Fe₂O₃） in mole） pseudosections suggest that the oxidation condition of the rocks played a major role on the stability of orthopyroxene:Opx is stable at X_Fe³⁺ <0.03 in charnockite.while Opx-free assemblage in Grt-Bt gneiss is stabilized at X_Fe³⁺ >0.12.Such low oxygen fugacity conditions of X_Fe³⁺ <0.03 in the charnockite compared to Grt-Bt gneiss might be related to the infiltration of a reduced fluid（e.g.,H₂O + CH₄） during the retrograde stage.     

http://www.sciencedirect.com/science/article/pii/S1674987111000387

Fluid flow is an integral part of hydrothermal mineralization,and its analysis and characterization constitute an important part of a mineralization model.The hydrodynamic study of mineralization deals with analyzing the driving forces,fluid pressure regimes,fluid flow rate and direction,and their relationships with localization of mineralization.This paper reviews the principles and methods of hydrodynamic studies of mineralization,and discusses their significance and limitations for ore deposit studies and mineral exploration. The driving forces of fluid flow may be related to fluid overpressure,topographic relief,tectonic deformation, and fluid density change due to heating or salinity variation,depending on specific geologic environments and mineralization processes.The study methods may be classified into three types,megascopic(field) observations, microscopic analyses,and numerical modeling.Megascopic features indicative of significantly overpressured (especially lithostatic or supralithostatic) fluid systems include horizontal veins,sand injection dikes,and hydraulic breccias.Microscopic studies,especially microthermometry of fluid inclusions and combined stress analysis and microthermometry of fluid inclusion planes(FIPs) can provide important information about fluid temperature,pressure,and fluid-structural relationships,thus constraining fluid flow models.Numerical modeling can be carried out to solve partial differential equations governing fluid flow, heat transfer,rock deformation and chemical reactions,in order to simulate the distribution of fluid pressure, temperature,fluid flow rate and direction,and mineral precipitation or dissolution in 2D or 3D space and through time.The results of hydrodynamic studies of mineralization can enhance our understanding of the formation processes of hydrothermal deposits,and can be used directly or indirectly in mineral exploration.     

http://www.sciencedirect.com/science/article/pii/S1674987113001345

Many elongated, lenticular plutons of porphyritic granitoids are distributed mainly near the southern and northern margin of the Chhotanagpur Gneissic Complex （CGC） which belongs to the EW to ENE-WSW tending 1500 km long Proterozoic orogenic belt amalgamat ng the North and South Indian cratonic blocks. The late Grenvillian （1071 ±64 Ma） Raghunathpur porphyritic granitoid gneiss （PGG） batholith comprising alkali feldspar granite, granite, granodiorite, tonalite, quartz syenite and quartz monzonite intruded into the granitoid gneisses of southeastern part of CGC in the Purulia district, West Bengal and is aligned with ENE-WSW trending North Purulia sr~ear zone, Mineral chemistry, geochemistry, physical condition of crystallization and petrogenetic model of Raghunathpur PGG have been discussed for the first time. The petrographic and geochemical features （including major and trace- elements, mineral chemistry and S7Sr/S6Sr ratio） suggest these granitoids to be classified as the shosh- onitic type. Raghunathpur batholith was emplaced at around 800 ~C and at 6 kbar pressure tectonic discrimination diagrams reveal a post-collision tectonic setting while structural studies reveal its emplacement in the extensional fissure of North Purulia shear zone. l＇he Raghunathpur granitoid is compared with some similar granitoids of Europe and China to draw its petrogenetic model. Hybridi- zation of mantle-generated enriched mafic magma and crustal magma at lower crust and later fractional crystallization is proposed for the petrogenesis of this PGG. Mafic magma generated in a post-collisional extension possibly because of delamination of subducting slab. Raghunathpur batholith had emplaced in the CGC during the final amalgamation （~ 1.0 Ga） of the North and South Indian cratonic blocks. Granitoid magma, after its generation at depth, was transported to its present level along megadyke channel, ways within shear zones.     

The genesis of the slab window-related Arzular low-sulfidation epithermal gold mineralization （eastern Pontides, NE Turkey）

The Arzular mineralization is one of the best examples of epithermal gold deposits in the eastern Pontides orogenic belt.The mineralization is hosted by the subduction-related basaltic andesites and is mainly controlled by E-W and NE-SW trending fracture zones.The main ore minerals are galena, sphalerite,pyrite.chalcopyrite.tetrahedrite and gold.Homogenization temperatures of fluid inclusions are between 130 and 295℃ for quartz and between 90 and 133℃ for sphalerite.Sulphur isotope values obtained from pyrite,galena and sphalerite vary between 1.2‰ and 3‰.indicating that sulphur belongs to magmatic origin and was derived from the Lutetian non-adakitic granitic intrusions in the region.Oxygen isotope values are between 15.0‰ and 16.7‰ and hydrogen isotope values are between -87‰ and -91‰ The sulphur isotope thermometer yielded temperatures in the range of 244-291℃ for the ore formation.Our results support the hypothesis that the Arzular mineralization is a low-sulfidation epithermal gold deposit associated with non-adakitic subduction- related granitic magmas that were generated by slab window-related processes in a south-dipping subduction zone during the Lutetian.