Variations in surface manifestations at vulcano (Aeolian Islands,Italy) as a possible evidence of deep processes

Five years of geochemical surveillance at Vulcano have shown interesting changes in the physico-chemical characters of the fumaroles at the crater and of the phreatic waters in the surrounding area. In particular, 1) The maximum temperature of the fumaroles, which had been of about 200°C for at least 30 years, rose suddenly to above 300°C: after a period of rather constant values, a decreasing trend has recently been observed; 2) An increase of CO₂, S compounds and HF with respect to HCl, B, Br occurred in the gas composition contemporaneous to the rise in temperature. This increase is now gradually declining; 3) Higher concentrations of sulphate ion and silica in phreatic waters accompanied the thermal changes observed at the fumaroles. According to a model previously proposed (Martini et al., 1980), the increase in the above mentioned factors would reflect an increasing magmatic contribution to the volcanic system, which might be due to an increased permeability to fluids at depth. Because a sensible seismic shock occurred in the area a few months after the first chemical and thermal variations had been observed, such variations may be regarded as forerunners of the seismic event, and may be used to forecast some months in advance changes occurring at depth. The work was carried out within the research programme of C.N.R. Centro di Studio per la Mineralogia e la Geochimica dei Sedimenti, Florence, Italy.     

Achieving a paradigm shift in environmental and living resources management in the Gulf of Guinea: the large marine ecosystem approach

The Gulf of Guinea is situated in the narrow protrusion of eastern Equatorial Atlantic between latitudes 2 degrees S and 5 degrees N and longitudes 8 degrees W to 12 degrees E, spanning a coastline length of approximately 130 nautical miles. The dominant feature of this shallow ocean off the coast of countries in Western Africa is the Guinea Current. The distinctive bathymetry, hydrography, productivity and trophodynamics of this shallow ocean qualify it as a large marine ecosystem (LME) and is indeed recognized as the number 28 of the 64 delineated LMEs globally. This area is one of the world's productive marine areas that is rich in fishery resources, oil and gas reserves, precious minerals and an important global reservoir of marine biological diversity. Unfortunately, pollution from residential and industrial sources has affected the waters of the Gulf of Guinea resulting in habitat degradation, loss of biological diversity and productivity, and degenerating human health. In reversing this trend of marine environmental degradation, the countries of the region adopted an integrated and holistic approach using the LME concept to sustainably manage the environmental and living resources of the region. The concept is predicated on the fact that marine environmental pollution and living resources respect no political or geographical boundaries and so require a holistic and regional approach for its management. The Gulf of Guinea countries through the Global Environment facility funded regional/communal project on water pollution control and biodiversity conservation achieved a paradigm shift in living resources and environmental management in the region using the LME concept.     

Copper in natural waters in Transbaikalia

Cu concentrations in surface (river and lake) and subsurface waters are determined. The geographic pattern of Cu distribution in natural water is identified. This pattern is controlled by the difference between its concentrations in drained rocks and soils and the geochemical redox conditions of its migration. Territories with low, medium, and elevated Cu concentrations in natural waters are identified. The concentrations of Cu in natural waters of the region are found to be generally lower than the Clarke values.     

A quasi three-dimensional model for flow and transport in unsaturated and saturated zones: 1. Implementation of the quasi two-dimensional case

A quasi three-dimensional (QUASI 3-D) model is presented for simulating the subsurface water flow and solute transport in the unsaturated and in the saturated zones of soil. The model is based on the assumptions of vertical flow in the unsaturated zone and essentially horizontal groundwater flow. The 1-D Richards equation for the unsaturated zone is coupled at the phreatic surface with the 2-D flow equation for the saturated zone. The latter was obtained by averaging 3-D flow equation in the saturated zone over the aquifer thickness. Unlike the Boussinesq equation for a leaky-phreatic aquifer, the developed model does not contain a storage term with specific yield and a source term for natural replenishment. Instead it includes a water flux term at the phreatic surface through which the Richards equation is linked with the groundwater flow equation. The vertical water flux in the saturated zone is evaluated on the basis of the fluid mass balance equation while the horizontal fluxes, in that equation, are prescribed by Darcy law. A 3-D transport equation is used to simulate the solute migration. A numerical algorithm to solve the problem for the general quasi 3-D case was developed. The developed methodology was exemplified for the quasi 2-D cross-sectional case (QUASI2D). Simulations for three synthetic problems demonstrate good agreement between the results obtained by QUASI2D and two fully 2-D flow and transport codes (SUTRA and 2DSOIL). Yet, simulations with the QUASI2D code were several times faster than those by the SUTRA and the 2DSOIL codes.     

The formation of present-day resources of surface and subsurface waters in European Russia

Variations in the characteristics of the annual, dry-season, and minimal monthly runoff in rivers of European Russia for the recent 35 years (1975?C2005) have been estimated and analyzed in comparison with a period of approximately the same duration (1935?C1969). The genesis of runoff for different river basins and the major causes of current changes in runoff characteristics have been studied. Regional regularities in the hydrological and geohydrological processes have been identified, and zoning of the territory has been performed with identification of specific features in the formation of river runoff in the European North and the basins of the Volga, Don, Ural, etc. The natural resources of surface and subsurface waters over 1970?C2005 have been re-estimated with the construction of appropriate maps. Water availability and load on water resources have been analyzed.     

On the relationship between historical land‐use change and water availability: the case of the lower Tarim River region in northwestern China

Natural ecosystems in the region of the lower Tarim River in northwestern China strongly deteriorated since the 1950s due to an expanding desertification. As a result, the downstream Tarim River reaches became permanently dry land. This historical evolution in land‐use change is typically the result of the anthropogenic impact on natural ecosystems. On the basis of a spatially distributed hydrological catchment model bidirectionally linked with a fully hydrodynamic MIKE11 river model, land‐use changes characterized by historical changes in leaf area index (LAI) of vegetation, as well as the evolution of irrigated surface areas, can be causally related to changes in water resources (groundwater storage and surface water resources). An increased surface area of irrigated (agricultural) land, together with a majority of inefficient irrigation methods, did lead to a strong increase of water resources consumption of the farmlands located in the upper Tarim River area. Evidently, this evolution influenced available water resources downstream in the Tarim basin. As a result, farmland has been gradually relocated to the upstream regions. This has led to reduced flows from the upper Tarim stream, which subsequently accelerated the dropping of the groundwater level downstream in the basin. This study moreover demonstrates that land surface biomass changes (cumulative LAI) along the lower Tarim River are strongly related to the changes in groundwater storage. Copyright © 2012 John Wiley & Sons, Ltd.     

Isotopic analysis to quantify the role of the Indian monsoon on water resources of selected river basins in the Himalayas

Western disturbances (WDs) and Indian summer monsoon (ISM) led precipitation play a central role in the Himalayan water budget. Estimating their contributions to water resource is although a challenging but essential for hydrologic understanding and effective water resource management. In this study, we used stable water isotope data of precipitation and surface waters to estimate the contribution of ISM and WDs to the water resources in three mountainous river basins - Indus, Bhagirathi and Teesta river basins of western, central and Eastern Himalayas. The study reveals distinct seasonality in isotope characteristics of precipitation and surface waters in each river basin is due to changes in moisture source, hydrometeorology and relief. Despite steady spatial variance in the slope and intercept of regression lines from the Teesta to Indus and the Bhagirathi river basins, the slope and intercept are close to the global meteoric water line and reported local meteoric water line of other regions in the Himalayas and the Tibetan Plateau. The two-component end-member mixing method using d-excess as tracer were used to estimate the contribution from ISM and WD led precipitation to surface water in aforementioned river basins. The results suggest that the influence of the ISM on the water resources is high (>72% to annual river flow) in Teesta river basin (eastern Himalayas), while as the WDs led precipitation is dominantly contributing (>70% average annual river flow) to the surface waters in the Indus river basin (western Himalayas). The contribution of ISM and WD led precipitation in Bhagirathi river basin is 60% and 40%, respectively. The findings demonstrate that the unusual changes in the ISM and WD moisture dynamics have the potential to affect the economy and food security of the region, which is dependent on the availability of water resources. The obtained results are of assistance to policy makers/mangers to make use of the information for better understanding hydrologic response amid unusual behaviour of the dual monsoon system over the region.     

Management of an aquifer with artificial recharge using water balance

Abstract

This study considers the management of an aquifer with artificial recharge whose water resources are mainly used for irrigation and where the irrigation return flows and natural discharge are considerable. These two variables are dependent on the use and increase of water resources. The interaction between some inflow and outflow variables is taken into account in the computation of the actual volume of water available, there being a pre-established artificial recharge of the aquifer. Conversely, the artificial recharge for a given water demand may be calculated. The most important inflow and outflow variables are used in an equation system (the water balance for each period of time) for these interactions and the total inflow and outflow. An iterative procedure is developed that solves the equation and with it the computation of the actual availability of water and storage.     

Lateral flow thresholds for aspen forested hillslopes on the Western Boreal Plain,Alberta, Canada

To predict the long‐term sustainability of water resources on the Boreal Plain region of northern Alberta, it is critical to understand when hillslopes generate runoff and connect with surface waters. The sub‐humid climate (P ≤ ET) and deep glacial sediments of this region result in large available soil storage capacity relative to moisture surpluses or deficits, leading to threshold‐dependent rainfall‐runoff relationships. Rainfall simulation experiments were conducted using large magnitude and high intensity applications to examine the thresholds in precipitation and soil moisture that are necessary to generate lateral flow from hillslope runoff plots representative of Luvisolic soils and an aspen canopy. Two adjacent plots (areas of 2·95 and 3·4 m²) of contrasting antecedent moisture conditions were examined; one had tree root uptake excluded for two months to increase soil moisture content, while the second plot allowed tree uptake over the growing season resulting in drier soils. Vertical flow as drainage and soil moisture storage dominated the water balances of both plots. Greater lateral flow occurred from the plot with higher antecedent moisture content. Results indicate that a minimum of 15–20 mm of rainfall is required to generate lateral flow, and only after the soils have been wetted to a depth of 0·75 m (C‐horizon). The depth and intensity of rainfall events that generated runoff > 1 mm have return periods of 25 years or greater and, when combined with the need for wet antecendent conditions, indicate that lateral flow generation on these hillslopes will occur infrequently. Copyright © 2008 John Wiley & Sons, Ltd.     

Water resources and ecological conditions in the Tarim Basin

Temporal sequential analyses of the hydrological observational data in the Tarim Ba-sin over the last forty years revealed an annual increase of 2 × 107m3 in the water quantities at thethree headstreams of the upper courses and an annual decrease of 3 × 107m3 in the water flowfrom Alaer, which is on the upper main stream. A prediction of the trends indicates that there canbe severe situations under which intermittent water interceptions occur. By means of approximateestimations on vegetative water consumption through phreatic evaporation combined with a quotaassessment, the ecological water demands required to maintain the ecological environment in themainstream area over the three different targeted years of 2005, 2010 and 2030 are defined asstanding at 31.86× 108m3, 36.27× 108m3 and 41.04× 108m3 respectively. Ecological fragility in-dexes are established on the basis of the selection of environmental sensitivity factors. Rationalevaluations give proof that the lower reaches of the mainstream have already turned into zoneswhere their ecological environments are gravely damaged. Multi-objective optimization should beconducted and protective schemes be framed within the threshold limits of the bearing capacitiesof water resources and the environment.     

Improved understanding of spring and stream water responses in headwaters of the Indian Lesser Himalaya using stable isotopes,conductivity and temperature as tracers

Stable isotope data are presented for precipitation, spring and stream water in a headwater catchments in the Indian Lesser Himalaya. Isotopic contents of phreatic groundwater followed the local meteoric water line and showed minimal alteration by evaporation, suggesting fast recharge. Mean isotopic values for springs and the stream were close to the weighted annual mean for precipitation, indicating recharge was in synchrony with seasonal rainfall distribution. Precipitation exhibited isotopic declines of ?0.6‰ and ?0.2‰ δ¹⁸O per 100 m rise in elevation in July and August (monsoon), respectively. The time lag of one month between rainfall and spring discharge, combined with the isotopic lapse rate indicated a recharge elevation of 70–165 m above the spring outflow point, implying the water originated within the catchment. Time series of electrical conductivity and temperature of spring, seepage and stream waters confirmed the rapid recharge and limited storage capacity of the shallow aquifers.     

Seismic,petrologic, and geodetic analyses of the 1999 dome-forming eruption of Guagua Pichincha volcano,Ecuador

Guagua Pichincha, located 14 km west of Quito, Ecuador, is a stratovolcano bisected by a horseshoe-shaped caldera. In 1999, after some months of phreatic activity, Guagua Pichincha entered into an eruptive period characterized by the extrusion of several dacitic domes, vulcanian eruptions, and pyroclastic flows. We estimated the three-dimensional (3-D) P-wave velocity structure beneath Guagua Pichincha using a tomographic inversion method based on finite-difference calculations of first-arrival times. Hypocenters of volcano-tectonic (VT) earthquakes and long-period (LP) events were relocated using the 3-D P-wave velocity model. A low-velocity anomaly exists beneath the caldera and may represent an active volcanic conduit. Petrologic analysis of eruptive products indicates a magma storage region beneath the caldera, having a vertical extent of 7–8 km with the upper boundary at about sea level. This zone coincides with the source region of deeper VT earthquakes, indicating that a primary magma body exists in this region. LP swarms occurred in a cyclic pattern synchronous with ground deformation during magma extrusions. The correlation between seismicity and ground deformation suggests that both respond to pressure changes caused by the cyclic eruptive behavior of lava domes.     

青藏高原盐湖资源的开发利用

本文首先介绍了青藏高原盐湖的基本概况,分布特征;重点叙述了该区盐湖自然资源的类型、盐类沉积矿物组合,卤水的水化学成分,盐湖资源的规模和开发利用现状;提出了今后开发利用盐湖资源的方向和途径。     

青藏高原盐湖资源的开发利用

本文首先介绍了青藏高原盐湖的基本概况,分布特征;重点叙述了该区盐湖自然资源的类型、盐类沉积矿物组合,卤水的水化学成分,盐湖资源的规模和开发利用现状;提出了今后开发利用盐湖资源的方向和途径。     

The 1975–1977 crisis of la Soufriere de Guadeloupe (F.W.I): A still-born magmatic eruption

On July 8, 1976, eruptive activity broke out at la Soufrière de Guadeloupe (F.W.I) after about one year of increasing seismic activity. Seismic activity continued to increase until August 1976, reaching more than 1500 events (a 200-fold increase over the preceding quiet period of a few years) and an energy output of about 10¹⁷ ergs in a day. A total of 26 major phreatic eruptions similar to the July 8 outburst took place during an eight-months period. The steam blasts that characterized the eruptions gave rise to particle- and sometimes block-charged plumes that deposited an estimated 10⁶ m³ of solids. The H₂O-rich gases emitted during the blasts presumably contained other gases (H₂S, SO₂, CO₂...) that were partly adsorbed on solid particles. All material was erupted at temperatures of the order of 100° to 200°C.The observation of vertical migration of earthquake foci in less than a few hours and over about 6 km depth, and of abnormal variations of the geomagnetic field, indicate a deep energy source for the phreatic eruptions. A small proportion of the gases adsorbed on solid particles had a magmatic origin. However, most of the steam and the tephra seemed to originate from superficial levels of a hydrothermal system. Similar phreatic eruptions have occurred several times in recorded history. In the case of la Soufrière, the origin of the phreatic eruptions is best described by an abnormal energy input (versus steady-state) from a crustal magma chamber. The occurrence of truly magmatic eruptions is presumably inhibited by an extensive hydrothermal system. The abrupt release of more power from the magma chamber could have resulted in an explosive pyroclastic eruption.Substantial improvement of the Guadeloupe volcano observatory has followed the 1975–1977 crisis. Permanent telemetered geophysical networks and regular geochemical observations have provided a five year data base of the volcano behavior in its noneruptive state which can be compared to crisis situations.     

Features of interaction between lake water and springs,and evaluation of hydrochemical composition of water in Ifni Lake (High Atlas Mountains,Morocco, north of Africa)

The National Park of Toubkal is located in the High Moroccan Atlas Mountains, one of the regions sheltering the highest summits of North Africa (Mount Toubkal with an elevation of 4167 m). The park is characterized by very important water resources, including Ifni Lake, which is the highest natural lake in Morocco (with an elevation of 2320 m). This lake is located on the southern side of Mt. Toubkal. This area has never been the object of an environmental or hydrological study. The objective of the current study was the characterization of Ifni Lake and the spring waters located in this area, as the basis of a framework to protect natural resources in northern Africa. The hydrochemical composition of water determines its origin and relationship with its catchment. Hydrochemical studies were carried out to assess the ions water composition, and processes governing the hydrochemistry of Ifni Lake water and the springs in the study area. A total of 20 water samples were collected in 2013 and analyzed for various parameters such as pH, electrical conductivity, and major ions. The physico-chemical analysis of the Ifni Lake water showed that this is the least mineralized water studied in this region, having a bicarbonate, calcium, and magnesium as dominate ions. Also there is a relationship between the hydrochemical composition of Ifni Lake and spring waters.     

Current changes in water resources in Lena River basin

The effect of climate on the present-day formation conditions of the regimes of annual and base runoff in Eastern Siberia rivers and changes in those regimes are studied. The significant climate warming in Eastern Siberia in recent decades is shown to be accompanied by not only an increase in air temperature and some increase in precipitation, but also by a considerable changes in the annual and seasonal values of river and groundwater runoff. Hydrometeorological data are used to analyze variations in the mean annual and mean base runoff over the entire observation period divided into subperiods of 1940–1969 and 1970–2005. Plots, diagrams, and tables are constructed for the most representative gauges. The zoning of the territory by the runoff formation conditions was carried out and new estimates were derived for total water resources and natural groundwater resources for 1970–2005 with the construction of maps in ArcMap program.     

Geochemical survey on the phreatic waters of Vulcano (Aeolian Islands,Italy)

In the frame of a geochemical surveillance survey of Vulcano, the phreatic waters, mainly from wells located at the Northern basis of the active volcanic centre, were studied over a time span of sixteen months. On the basis of fundamental chemical composition, contamination by a shallow aquifer of brackish water and hydrothermal alteration of rocks seem the main processes to which the observed chemical picture can be attributed. An R-mode factor analysis procedure allowed to distinguish a principal factor associated to sodium, magnesium, chloride, possibly representing the contribution of the brackish aquifer, and three minor but distinct factors. These are respectively associated to calcium and sulfate, hydrogencarbonate, boric acid, and are considered as reflecting the influence of gaseous compounds from volcanic emanations. The variation in time of this influence appears in correlation with the variation of the observed temperature at the hottest fumaroies of the crater.     

Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: The southern Venice Lagoon coastland

The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ¹⁸O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.     

Likely effects of climate change on groundwater availability in a Mediterranean region of Southeastern Spain

Groundwater resources are typically the main fresh water source in arid and semi‐arid regions. Natural recharge of aquifers is mainly based on precipitation; however, only heavy precipitation events (HPEs) are expected to produce appreciable aquifer recharge in these environments. In this work, we used daily precipitation and monthly water level time series from different locations over a Mediterranean region of Southeastern Spain to identify the critical threshold value to define HPEs that lead to appreciable aquifer recharge in this region. Wavelet and trend analyses were used to study the changes in the temporal distribution of the chosen HPEs (≥20 mm day^?1) over the observed period 1953–2012 and its projected evolution by using 18 downscaled climate projections over the projected period 2040–2099. The used precipitation time series were grouped in 10 clusters according to similarities between them assessed by using Pearson correlations. Results showed that the critical HPE threshold for the study area is 20 mm day^?1. Wavelet analysis showed that observed significant seasonal and annual peaks in global wavelet spectrum in the first sub‐period (1953–1982) are no longer significant in the second sub‐period (1983–2012) in the major part of the ten clusters. This change is because of the reduction of the mean HPEs number, which showed a negative trend over the observed period in nine clusters and was significant in five of them. However, the mean size of HPEs showed a positive trend in six clusters. A similar tendency of change is expected over the projected period. The expected reduction of the mean HPEs number is two times higher under the high climate scenario (RCP8.5) than under the moderate scenario (RCP4.5). The mean size of these events is expected to increase under the two scenarios. The groundwater availability will be affected by the reduction of HPE number which will increase the length of no aquifer recharge periods (NARP) accentuating the groundwater drought in the region. Copyright © 2016 John Wiley & Sons, Ltd.