Long-term simulations of thermal and hydraulic characteristics in a mountain massif: The Mont Blanc case study, French and Italian Alps

 The use of hydrothermal simulation models to improve the prediction of water inflows in underground works during drilling is tested in the Mont Blanc tunnel, French and Italian Alps. The negative thermal anomaly that was observed during the drilling of this tunnel in 1960 is reproduced by long-term, transient hydrothermal simulations. Sensitivity analysis shows the great inertia of thermal phenomena at the massif scale. At the time of tunnel drilling, the massif had not reached thermal equilibrium. Therefore, a set of simulation scenarios, beginning at the end of the last glacial period, was designed to explain the anomaly encountered in the tunnel in 1960. The continuous cooling of alpine massifs due to infiltration of waters from the surface has occurred for 12,000 years and is expected to continue for about 100,000 years. Comparisons of water-discharge rates simulated in the tunnel with those observed indicate that this hydrothermal method is a useful tool for predicting water inflows in underground works. Received, May 1998 · Revised, March 1999 · Accepted, April 1999     

Groundwater processes and sedimentary uranium deposits

 Hydrologic processes are fundamental in the emplacement of all three major categories of sedimentary uranium deposits: syngenetic, syndiagenetic, and epigenetic. In each case, the basic sedimentary uranium-enrichment cycle involves: (1) leaching or erosion of uranium from a low-grade provenance; (2) transport of uranium by surface or groundwater flow; and (3) concentration of uranium by mechanical, geochemical, or physiochemical processes. Although surface flow was responsible for lower Precambrian uranium deposits, groundwater was the primary agent in upper Precambrian and Phanerozoic sedimentary uranium emplacement. Meteoric or more deeply derived groundwater flow transported uranium in solution through transmissive facies, generally sands and gravels, until it was precipitated under reducing conditions. Syndiagenetic uranium deposits are typically concentrated in reducing lacustrine and swamp environments, whereas epigenetic deposits accumulated along mineralization fronts or tabular boundaries. The role of groundwater is particularly well illustrated in the bedload fluvial systems of the South Texas uranium province. Upward migration of deep, reducing brines conditioned the host rock before oxidizing meteoric flow concentrated uranium and other secondary minerals. Interactions between uranium-transporting groundwater and the transmissive aquifer facies are also reflected in the uranium mineralization fronts in the lower Tertiary basins of Wyoming. Similar relationships are observed in the tabular uranium deposits of the Colorado Plateau. Received, May 1998 · Revised, July 1998 · Accepted, September 1998     

Hydrogeology of the Mercosul aquifer system in the Paraná and Chaco-Paraná Basins, South America, and comparison with the Navajo-Nugget aquifer system, USA

 The giant Mercosul aquifer system consists of Triassic-Jurassic eolian-fluvio-lacustrine sandstones confined by Cretaceous basalt flows, and it covers about 1,195,500 km² (461,583 miles²) in South America. The aquifer system encompasses all of the Paraná Basin and part of the Chaco-Paraná Basin and is one of the world's largest. The eolian Botucatu Sandstone and its equivalents form an important part of this system. Maps of structure, thickness of overlying rocks, and water temperature, and a potentiometric map, all based on 322 wells, define hydrogeologic characteristics and provide the basis for establishing guidelines for the long-term equilibrium use of this important multinational aquifer system. The Mercosul aquifer system is divided into two domains – the larger and better understood Paraná Basin and the smaller and less well understood Chaco-Paraná Basin. Most of the northern part of the Paraná Basin has axially-directed groundwater flow, whereas the southern part of the aquifer discharges mostly to the southwest into the Corrientes Province of Argentina, with negligible discharge into the Atlantic Ocean. The Mercosul aquifer system is conservatively estimated to have been flushed at least 180 times since deposition. Various factors are responsible for this flushing, including appreciable rainfall since the end of the Cretaceous Period, probable uplift of the basins' borders in Late Cretaceous time, simple basin geometry, long-term riverine and groundwater flow to the southwest (ancestral and present Paraná River Systems), and stable cratonic setting. Key hydraulic properties of the Mercosul aquifer system are compared to those of the eolian Jurassic Navajo-Nugget System of the western United States. The results demonstrate the importance of tectonics and climate on the evolution of sub-continental aquifer systems. Received, September 1997 / Revised, December 1998 / Accepted, January 1999     

Hydrogeologic modeling of the genesis of carbonate-hosted lead-zinc ores

 Carbonate-hosted lead–zinc ore deposits in the Mississippi Valley region of North America and in the central midlands region of Ireland provide good examples where ancient groundwater migration controlled ore formation deep within sedimentary basins. Hydrogeologic and geochemical theories for ore genesis are explored in this paper with mathematical models that allow for complex permeability fields in two or three dimensions, hydrothermal flows in fault systems, and coupled effects of geochemical reactions. The hydrogeologic framework of carbonate-hosted ores is analyzed with the aim of developing a quantitative understanding of the necessary and sufficient processes required to form large ore deposits. Numerical simulations of basin-scale hydrodynamics and of deposit-scale reactive flow are presented to demonstrate the processes controlling low-temperature Pb–Zn ore genesis in two world-class ore districts, in southeast Missouri, USA, and central Ireland. The numerical models presented here provide a theoretical basis for the following observations: (1) topography-driven brine migration was the most effective mechanism for forming the large ore districts of the Mississippi Valley, such as the Viburnum Trend of southeast Missouri, during the uplift of the Appalachian–Ouachita mountain belt in late Paleozoic time; (2) three-dimensional flow fields were created by a dolomite facies of the Viburnum Trend, which acted as a giant lens for focusing metal and heat in southeast Missouri to produce the largest known concentration of lead in the Earth's crust; (3) ore-mineralization patterns were controlled locally by basement relief, permeability structure, and sandstone pinchouts, because of their effects on cooling and fluid-flow rates along the Viburnum Trend; (4) both density-driven and topography-driven fluid flow were important for ore genesis in the Irish midlands, where brines moved northward away from the Variscan orogen, leaked into the Hercynian basement, and discharged along normal faults up into the sedimentary cover; and (5) mixed convection within northeast–southwest fault planes elevated heat flow and flow rates that fed ore deposition by fluid mixing, in some cases near the Carboniferous seafloor in Ireland. Received, February 1998 · Revised, July 1998 · Accepted, September 1998     

Hydrogeologic and hydrochemical framework of the shallow groundwater system in the southern Voltaian Sedimentary Basin, Ghana

 The southern Voltaian Sedimentary Basin underlies an area of about 5000 km² in east-central Ghana. Groundwater in the basin occurs in fractures in highly consolidated siliciclastic aquifers overlain by a thin unsaturated zone. Aquifer parameters were evaluated from available aquifer-test data on 28 shallow wells in the basin. Hydraulic-conductivity values range from 0.04–3.6 m/d and are about two orders of magnitude greater than the hydraulic conductivity calculated using Darcy's Law and the average groundwater velocity estimated from carbon-14 dating. Linear-regression analysis of the transmissivity and specific-capacity data allowed the establishment of an empirical relationship between log transmissivity and log specific capacity for the underlying aquifers. Groundwater chemistry in the basin is controlled by the weathering of albitic plagioclase feldspar. The weathering rates of various minerals were estimated using ¹⁴C-derived average velocity in the basin. The weathering rate of albite was calculated to be 2.16 μmol L^–1 yr^–1 with the resulting formation of 3.3 μmol L^–1 yr^–1 of kaolinite and 0.047 μmol L^–1 yr^–1 of calcite. The low porosity and permeability of the aquifers in the basin are attributed to the precipitation of secondary minerals on fracture surfaces and interlayer pore spaces. Received, September 1997 Revised, July 1998, August 1998 Accepted, August 1998     

Modeling alternative paths of chemical evolution of Na-HCO3-type groundwater near Oak Ridge, Tennessee, USA

 This paper demonstrates that both cation exchange, a commonly invoked mechanism, and silicate hydrolysis, which is less commonly considered, can produce Na-HCO₃-type water in sedimentary rocks. Evolution of Na-HCO₃ groundwater beneath the Oak Ridge Reservation, Tennessee, USA, was studied by comparing observed end-member groundwater composition from multiport samplers to compositions generated by reaction-path geochemical models. Observed groundwater compositions could be reproduced by either the silicate-hydrolysis model or the cation-exchange model. Secondary minerals precipitated in the silicate-hydrolysis model are similar to those present along fractures in the shale and carbonate host rocks, and observed molar Sr²⁺/Ca²⁺ ratios more closely resemble evolution from shale weathering. Both mechanisms should be considered to understand the evolution of Na-HCO₃ groundwater. Received, April 1998 · Revised, January 1999 · Accepted, March 1999     

沉积盆地形成的地球动力学机制及其分类

沉积盆地的形成主要与地球内部的热和物质的对流密切相关,它是沉积盆地形成和演化的原始动力。软流圈上涌高度,莫霍面或地幔羽的位置是地幔对流的具体的表现.根据地球内部流变学界限,岩石圈的性质和厚度,板内应力和沉积负荷可以将原始盆地划分为克拉通盆地。拉张盆地,挤压盆地和走滑盆地。     

The effects of Holocene barrier-island evolution on water-table elevations, Hatteras Island, North Carolina, USA

 On Hatteras Island, North Carolina, USA, complex stratigraphy results from surficial sediments being superimposed on an inherited Pleistocene platform. Numerical simulations used to simulate water-table profiles on the island illustrate the influence that the complex stratigraphy has on water-table elevations. Field data consist of water-table profiles collected from a cross-island transect of wells. These profiles show unusually high water-table elevations in the south-central portion of Hatteras Island. Geophysical data are used to constrain the subsurface stratigraphy. Simple analytical solutions to the groundwater flow equation using laterally varying recharge rates cannot match mean water-table profiles. More complex numerical simulations, which do match the profiles, indicate that the elevated water levels result from a low-permeability unit that extends several kilometers along the longitudinal axis of the island. Island geomorphology and ground-penetrating radar (GPR) data suggest that this unit is a former interdunal wetland that has been buried by a series of parabolic dunes. Received, September 1999 / Revised, March 2000 / Accepted, March 2000     

The role of the Spanish Committee of the International Association of Hydrogeologists in the management and protection of Spain's groundwater resources

 Spain is a relatively large European country (ca. 500,000 km²) with extensive semiarid areas in which there exists a large number of good aquifers. In some areas, these aquifers are intensively developed and are the most important sources of fresh water. Nevertheless, groundwater development and protection has rarely been duly considered by the Spanish Water Administration, despite the pressure to remedy this situation by various groups of experts, some of them members of the Water Administration. The Spanish Committee of the International Association of Hydrogeologists (IAH) has been very active during the last decade in promoting activities to spread groundwater science, technology, and management in Spain and outside, mostly in Latin America, and in trying to orient water policy toward issues of groundwater. These activities include mainly the organization of technical and scientific meetings on current topics such as groundwater in the new Water Act, overexploitation, groundwater in water-resources planning, groundwater pollution, natural-recharge estimation and others. The impact of these activities on the recent water policy of Spain seems significant, and the experience gained may be applicable to other countries. Received, February 1997 · Revised, July 1997 · Accepted, July 1997     

Analysis of thermal parameters of Triassic,Permian and Carboniferous sedimentary rocks in central Poland

The paper shows thermal tests results (thermal conductivity, specific heat) carried out during the research project to recognize the potential of hot dry rocks for heat and electricity production in Poland. Analysis of such parameters of the rock medium has fundamental significance in search of structures for location of enhanced geothermal systems (EGS). Analyses of thermal conductivity as well as specific heat determine the possibility of effective extraction of heat from hot rock formations and its efficient transfer to the land surface. Reservoir rock should be characterized by the lowest possible porosity and permeability, and the highest possible thermal conductivity. In order to recognize reservoir parameters of rocks that form potential reservoirs for EGS, 300 samples of sedimentary rocks were taken from 11 wells located in central Poland. For samples, sizes of which enabled measurement of thermal parameters, tests of thermal conductivity and specific heat were carried out. Independently, measurements of porosity were made. The porosity magnitude determines values of measured thermal parameters. Measurements of thermal conductivity of rocks were made for 24 samples collected from Triassic, Permian and Carboniferous deposits in six wells. Measurements of specific heat on rock samples were made for 20 rock samples. Among sedimentary rocks, principally sandstones and limestones with reservoir parameters favourable for this type of systems are considered to be petrogeothermal reservoirs and are often characterized by favourable thermal parameters for EGS. Copyright © 2014 John Wiley & Sons, Ltd.     

Groundwater as a geologic agent: An overview of the causes, processes, and manifestations

 The objective of the present paper is to show that groundwater is a general geologic agent. This perception could not, and did not, evolve until the system nature of basinal groundwater flow and its properties, geometries, and controlling factors became recognized and understood through the 1960s and 1970s. The two fundamental causes for groundwater's active role in nature are its ability to interact with the ambient environment and the systematized spatial distribution of its flow. Interaction and flow occur simultaneously at all scales of space and time, although at correspondingly varying rates and intensities. Thus, effects of groundwater flow are created from the land surface to the greatest depths of the porous parts of the Earth's crust, and from a day's length through geologic times. Three main types of interaction between groundwater and environment are identified in this paper, with several special processes for each one, namely: (1) Chemical interaction, with processes of dissolution, hydration, hydrolysis, oxidation-reduction, attack by acids, chemical precipitation, base exchange, sulfate reduction, concentration, and ultrafiltration or osmosis; (2) Physical interaction, with processes of lubrication and pore-pressure modification; and (3) Kinetic interaction, with the transport processes of water, aqueous and nonaqueous matter, and heat. Owing to the transporting ability and spatial patterns of basinal flow, the effects of interaction are cumulative and distributed according to the geometries of the flow systems. The number and diversity of natural phenomena that are generated by groundwater flow are almost unlimited, due to the fact that the relatively few basic types are modified by some or all of the three components of the hydrogeologic environment: topography, geology, and climate. The six basic groups into which manifestations of groundwater flow have been divided are: (1) Hydrology and hydraulics; (2) Chemistry and mineralogy; (3) Vegetation; (4) Soil and rock mechanics; (5) Geomorphology; and (6) Transport and accumulation. Based on such a diversity of effects and manifestations, it is concluded that groundwater is a general geologic agent. Received, December 1998 · Revised, January 1999 · Accepted, January 1999     

Geology and hydrogeology of the Dammam Formation in Kuwait

 The Dammam Formation of Middle Eocene age is one of the major aquifers containing useable brackish water in Kuwait. Apart from the paleokarst zone at the top, the Dammam Formation in Kuwait consists of 150–200 m of dolomitized limestone that is subdivided into three members, on the basis of lithology and biofacies. The upper member consists of friable chalky dolomicrite and dolomite. The middle member is mainly laminated biomicrite and biodolomicrite. The lower member is nummulitic limestone with interlayered shale toward the base. Geophysical markers conform to these subdivisions. Core analyses indicate that the upper member is the most porous and permeable of the three units, as confirmed by the distribution of lost-circulation zones. The quality of water in the aquifer deteriorates toward the north and east. A potentiometric-head difference exists between the Dammam Formation and the unconformably overlying Kuwait Group; this difference is maintained by the presence of an intervening aquitard. Received, February 1997 Revised, June 1997, September 1997 Accepted, January 1998     

Controls on the chemical composition of groundwater from alluvial aquifers in the Wanaka and Wakatipu basins, Central Otago, New Zealand

 Groundwater in alluvial aquifers of the Wakatipu and Wanaka basins, Central Otago, New Zealand, has a composition expressed in equivalent units of Ca²⁺≫Mg²⁺≅Na⁺>K⁺ for cations, and HCO₃ ^–≫SO₄ ^2->NO₃ ^–≅Cl^– for anions. Ca²⁺ and HCO₃ ^– occur on a 1 : 1 equivalent basis and account for >80% of the ions in solution. However, some groundwater has increased proportions of Na⁺ and SO₄ ^2-, reflecting a different source for this water. The rock material of the alluvial aquifers of both basins is derived from the erosion and weathering of metamorphic Otago Schist (grey and green schists). Calcite is an accessory mineral in both the grey and green schists at <5% of the rock. Geological mapping of both basins indicates that dissolution of calcite from the schist is the only likely mechanism for producing groundwater with such a constant composition dominated by Ca²⁺ and HCO₃ ^– on a 1 : 1 equivalent basis. Groundwater with higher proportions of Na⁺ and SO₄ ^2- occurs near areas where the schist crops out at the surface, and this groundwater represents deeper and possibly older water derived from basement fluids. Anomalously high K⁺ in the Wakatipu basin and high NO₃ ^– concentrations in the Wanaka basin cannot be accounted for by interaction with basement lithologies, and these concentrations probably represent the influence of anthropogenic sources on groundwater composition. Received, June 1996 Revised, March 1997, July 1997 Accepted, July 1997     

Natural arsenic in Triassic rocks: A source of drinking-water contamination in Bavaria, Germany

 The aquifer system of the Upper Triassic Keuper Sandstone, an important source of drinking water in northern Bavaria, is affected by elevated arsenic concentrations. Within the study area of 8000 km², no evidence exists for any artificial source of arsenic. Data from about 500 deep water wells show that in approximately 160 wells arsenic concentrations are 10–150 μg/L. The regional distribution of arsenic in the groundwater shows that elevated arsenic concentrations are probably related to specific lithofacies of the aquifers that contain more sediments of terrestrial origin. Geochemical measurements on samples from four selected well cores show that arsenic has accumulated in the rocks. This indigenous arsenic is the source of arsenic in the groundwater of certain facies of the middle unit of the Keuper Sandstone. Received, June 1998 / Revised, January 1999, May 1999 / Accepted, June 1999     

Karst hydrogeology and origin of thermal waters in the Codru Moma Mountains, Romania

 Two karst areas within Permian and Triassic carbonate rocks of the Codru Moma Mountains in the northwestern part of Romania yield thermal waters. Major karst springs occur where groundwater flow is intercepted by hydraulic barriers, which also results in the movement of water from deeper levels. At Moneasa, thermal groundwater rises along faults and fractures associated with a thrust, and at Vascau Town, water rises along faults marginal to the Beius Basin. Geochemistry suggests that the thermal component of the Moneasa groundwaters is derived from dolomites and that at least a proportion of the Vascau thermal waters originates from deeply buried Permian sandstones. Received, August 1999 / Revised, March 2000 / Accepted, March 2000     

Reconstruction of natural groundwater flow paths in the multiple aquifer system of the northern Negev (Israel), based on lithological and structural evidence

 The Judea Group, a limestone and dolomite karstic aquifer of late Albian–Turonian age, is one of the most important sources of water in Israel. In the western part of the country, the Judea Group aquifer is also known as the Yarkon–Taninim basin. In the northern Negev, the Judea Group is a recipient for fresh water flowing southward from the Hebron Mountains and of brackish paleowater flowing northward from Sinai. Very little is known of the hydraulic properties of this aquifer. In order to outline assumed natural flow paths that existed in this karstic environment prior to groundwater exploitation, use was made of lithological, structural, and paleomorphological features. A detailed hydrogeological conceptual model of the Judea Group aquifer in northern Negev was established by the geological interpretation of high-resolution seismic reflection and by analysis of lithological evidence from boreholes. Isopach, isolith-contour, and isolith-ratio maps were compiled for the main lithological components. Increase in transmissivity values is inversely proportional with the cumulative thickness of argillaceous components. The lithological and hydraulic evidence provides the basis for subdividing the subsurface into distinctive permeability zones for the upper and lower sections of the aquifer; for outlining possible preferential groundwater flow paths for both subaquifers; and for improving understanding of groundwater-salinty variations that result from lithological variability, direction of groundwater flow paths, groundwater flow rates, and the duration of rock/water interactions. In an earlier conceptual model of the basin, the Judea Group aquifer was regarded as a continuous and undisturbed entity. The present study reveals an intricate groundwater flow pattern that is controlled by lithological and structural factors that create zones of preferential flow. This interpretation bears on the overall evaluation of groundwater resources and their management and exploitation. Received, December 1996 · Revised, October 1997, June 1998 · Accepted, July 1998     

Effects of horizontal strain in estimating specific storage and compaction in confined and leaky aquifer systems

 Mathematical and numerical distinctions are made between developments of governing equations involving groundwater flow and granular displacement where (1) only vertical strain and no change in total normal load are assumed, and (2) such limitations are eliminated. The former is referred to here as the Jacob-Terzaghi method; the latter is referred to as the Biot method. Numerical comparisons of drawdown, compaction, and strain are made for hypothetical confined and leaky aquifer systems for one- and three-dimensional strain problems. Simulation results indicate that incorporation of horizontal strain results in reduced drawdowns. Vertical compaction for a specified stress distribution is greatly reduced when horizontal strain is invoked. The distribution of strain components indicates that approximately two-thirds of the total volume strain originates from horizontal compaction in pumped aquifers. Incorporation of horizontal strain also affects the distribution of flux through the overlying confining layer as a function of distance from the pumping well and may ultimately affect the interpretation of aquifer-test data. Received, January 1999 / Revised, May 1999, August 1999 / Accepted, August 1999     

沉积盆地中金属成矿与油气成藏的耦合关系

沉积盆地中与油气密切相关的金属矿床主要包括密西西比河谷型(MVT)铅锌矿床、砂页岩型铜-铀矿床、黑色页岩中的金属硫化物矿床、沉积岩容矿的金-锑-砷-汞-铊矿床等。金属矿床与(古)油气藏在空间上的密切共生/伴生关系,暗示了二者成因上的有机联系。在许多MVT铅锌矿床和砂页岩型铜矿床中,与成矿关系密切的原油及其衍生物形成于矿化前,它们为随后的金属成矿直接提供还原硫或充当硫酸盐还原反应的还原剂。在另一些情况下,某些低温热液金属矿床,特别是Au、As、Hg、Sb、Tl矿床与油气表现出同源、同运、同聚的耦合关系,金属成矿与油气成藏同时或近同时进行。与油气具不同耦合关系的金属矿床常表现出不同的特点。与成藏和/或成矿有关的盆地流体大致可分为以碳氢化合物为主的有机流体、以含金属盐水溶液为主的无机流体以及同时富含烃类和金属组分的有机成矿流体3类,盆地中的成矿、成藏作用及其耦合关系受控于这三类流体的演化过程。沉积盆地中金属矿床与油气藏空间上密切的共生/伴生关系以及成矿、成藏过程和机理的相似性,使金属与油气矿产资源的协同勘探和综合预测成为可能。     

Some current methods to represent the heterogeneity of natural media in hydrogeology

We have known for a long time that the material properties of the subsurface are highly variable in space. We have learned that this variability is due to the extreme complexity and variation with time of processes responsible for the formation of the earth's crust, from plate tectonics to erosion, sediment transport, and deposition, as well as to mechanical, climatic, and diagenetic effects. As geologists, we learned how to "read" this complex history in the rocks and how to try to extrapolate in space what we have understood. As physicists, we then learned that to study flow processes in such media we must apply the laws of continuum mechanics. As mathematicians using analytical methods, we learned that we must simplify by dividing this complex continuum into a small number of units, such as aquifers and aquitards, and describe their properties by (constant) equivalent values. In recent years, as numerical modelers, we learned that we now have the freedom to "discretize" this complex reality and describe it as an ensemble of small homogeneous boxes of continuous media, each of which can have different properties. How do we use this freedom? Is there a need for it? If the answer is "yes," how can we assign different rock-property values to thousands or even millions of such little boxes in our models, to best represent reality, and include confidence levels for each selected rock property? As a tribute to Professor Eugene S. Simpson, with whom the first author of this paper often discussed these questions, we present an overview of three techniques that focus on one property, the rock permeability. We explain the motivation for describing spatial variability and illustrate how to do so by the geostatistical method, the Boolean method, and the genetic method. We discuss their advantages and disadvantages and indicate their present state of development. This is an active field of research and space is limited, so the review is certain to be incomplete, but we hope that it will encourage the development of new ideas and approaches.     

The ecological features and significance of hydrology within arid inland river basins of China

 Hydrology and ecology are two important factors affecting the rational utilization of limited water resources within the arid inland basins of China. They depend on, are influenced by, and interact with each other. But, the functions and significance of the hydrological ecology vary from upper through intermediate to lower reaches. Abundant rainfall and large runoff in the upper regions favor the vegetation growth, and the bushy vegetation helps conserve water resources. The large-scale reclamation in the intermediate regions leads to many sustainable oases, but with severely changed hydrological conditions and destroyed ecological systems. Human activities result in the degradation of the vegetation and declination of the ecological system at the intermediate and lower regions. It is necessary to establish study approaches to ecological hydrology in arid inland river basins. Received: 30 October 1997 · Accepted: 26 May 1998