A radiative transfer model-based method for the estimation of grassland aboveground biomass

This paper presents a novel method to derive grassland aboveground biomass (AGB) based on the PROSAILH (PROSPECT + SAILH) radiative transfer model (RTM). Two variables, leaf area index (LAI, m²m⁻², defined as a one-side leaf area per unit of horizontal ground area) and dry matter content (DMC, gcm⁻², defined as the dry matter per leaf area), were retrieved using PROSAILH and reflectance data from Landsat 8 OLI product. The result of LAI × DMC was regarded as the estimated grassland AGB according to their definitions. The well-known ill-posed inversion problem when inverting PROSAILH was alleviated using ecological criteria to constrain the simulation scenario and therefore the number of simulated spectra. A case study of the presented method was applied to a plateau grassland in China to estimate its AGB. The results were compared to those obtained using an exponential regression, a partial least squares regression (PLSR) and an artificial neural networks (ANN). The RTM-based method offered higher accuracy (R² = 0.64 and RMSE = 42.67 gm⁻²) than the exponential regression (R² = 0.48 and RMSE = 41.65 gm⁻²) and the ANN (R² = 0.43 and RMSE = 46.26 gm⁻²). However, the proposed method offered similar performance than PLSR as presented better determination coefficient than PLSR (R² = 0.55) but higher RMSE (RMSE = 37.79 gm⁻²). Although it is still necessary to test these methodologies in other areas, the RTM-based method offers greater robustness and reproducibility to estimate grassland AGB at large scale without the need to collect field measurements and therefore is considered the most promising methodology.     

Retrieval of wheat leaf area index from AWiFS multispectral data using canopy radiative transfer simulation

Accurate representation of leaf area index (LAI) from high resolution satellite observations is obligatory for various modelling exercises and predicting the precise farm productivity. Present study compared the two retrieval approach based on canopy radiative transfer (CRT) method and empirical method using four vegetation indices (VI) (e.g. NDVI, NDWI, RVI and GNDVI) to estimate the wheat LAI. Reflectance observations available at very high (56 m) spatial resolution from Advanced Wide-Field Sensor (AWiFS) sensor onboard Indian Remote Sensing (IRS) P6, Resourcesat-1 satellite was used in this study. This study was performed over two different wheat growing regions, situated in different agro-climatic settings/environments: Trans-Gangetic Plain Region (TGPR) and Central Plateau and Hill Region (CPHR). Forward simulation of canopy reflectances in four AWiFS bands viz. green (0.52–0.59 μm), red (0.62–0.68 μm), NIR (0.77–0.86 μm) and SWIR (1.55–1.70 μm) were carried out to generate the look up table (LUT) using CRT model PROSAIL from all combinations of canopy intrinsic variables. An inversion technique based on minimization of cost function was used to retrieve LAI from LUT and observed AWiFS surface reflectances. Two consecutive wheat growing seasons (November 2005–March 2006 and November 2006–March 2007) datasets were used in this study. The empirical models were developed from first season data and second growing season data used for validation. Among all the models, LAI-NDVI empirical model showed the least RMSE (root mean square error) of 0.54 and 0.51 in both agro-climatic regions respectively. The comparison of PROSAIL retrieved LAI with in situ measurements of 2006–2007 over the two agro-climatic regions produced substantially less RMSE of 0.34 and 0.41 having more R² of 0.91 and 0.95 for TGPR and CPHR respectively in comparison to empirical models. Moreover, CRT retrieved LAI had less value of errors in all the LAI classes contrary to empirical estimates. The PROSAIL based retrieval has potential for operational implementation to determine the regional crop LAI and can be extendible to other regions after rigorous validation exercise.     

Retrieval of leaf area index in alpine wetlands using a two-layer canopy reflectance model

In this paper, we focused on the retrieval of the LAI in an alpine wetland located in western part of China in late August and early July 2011. A two-layer canopy reflectance model (ACRM) was used to establish the relationships between the LAI and the reflectance of near-infrared (NIR) and red (RED) wavebands. The reflectance data were derived from Landsat TM L1T product and the Terra and Aqua MODIS 16-day and 8-day composite reflectance products (MOD/MYD09) at 250 m resolution. Due to the lack of the information about some major input parameters for ACRM, which are sensitive to model outputs in the reflectance of NIR and RED wavebands, the inverse problem was ill-posed. To overcome this problem, a method of increasing the sensitivity of the LAI while reducing the influence of other model free parameters based on the study of free parameters’ sensitivity to the ACRM outputs and the region’s features was studied. The area of interest was divided into two parts using the approximately statistic normalized difference vegetation index (NDVI) value around 0.5. One part was sparse vegetation (0.1 < NDVI < 0.5), which is more sensitive to soil background effects and less sensitive to the canopy biophysical and biochemical variables. The other part was dense vegetation (0.5 ≤ NDVI < 1.0), which is less sensitive to soil background effects and more sensitive to plant canopies and leaf parameters. Then, the relationships of ρ_nir–LAI and ρ_red–LAI were established using a look-up table algorithm for the two parts. Furthermore, a regularization technique for fast pixel-wise retrieval was introduced to reduce the elements of LUT sets while maintaining a relatively high accuracy. The results were very promising compared to the field measured LAI values that the correlation (R²) of the measured LAI values and retrieved LAI values reached 0.95, and the root-mean-square deviation (RMSD) was 0.33 for late August, 2011, while the R² reached 0.82 and RMSD was 0.25 for early July 2011.     

Above ground biomass estimation in an African tropical forest with lidar and hyperspectral data

The estimation of above ground biomass in forests is critical for carbon cycle modeling and climate change mitigation programs. Small footprint lidar provides accurate biomass estimates, but its application in tropical forests has been limited, particularly in Africa. Hyperspectral data record canopy spectral information that is potentially related to forest biomass. To assess lidar ability to retrieve biomass in an African forest and the usefulness of including hyperspectral information, we modeled biomass using small footprint lidar metrics as well as airborne hyperspectral bands and derived vegetation indexes. Partial Least Square Regression (PLSR) was adopted to cope with multiple inputs and multicollinearity issues; the Variable of Importance in the Projection was calculated to evaluate importance of individual predictors for biomass. Our findings showed that the integration of hyperspectral bands (R² = 0.70) improved the model based on lidar alone (R² = 0.64), this encouraging result call for additional research to clarify the possible role of hyperspectral data in tropical regions. Replacing the hyperspectral bands with vegetation indexes resulted in a smaller improvement (R² = 0.67). Hyperspectral bands had limited predictive power (R² = 0.36) when used alone. This analysis proves the efficiency of using PLSR with small-footprint lidar and high resolution hyperspectral data in tropical forests for biomass estimation. Results also suggest that high quality ground truth data is crucial for lidar-based AGB estimates in tropical African forests, especially if airborne lidar is used as an intermediate step of upscaling field-measured AGB to a larger area.     

Intercomparison and validation of MODIS and GLASS leaf area index (LAI) products over mountain areas: A case study in southwestern China

The validation study of leaf area index (LAI) products over rugged surfaces not only gives additional insights into data quality of LAI products, but deepens understanding of uncertainties regarding land surface process models depended on LAI data over complex terrain. This study evaluated the performance of MODIS and GLASS LAI products using the intercomparison and direct validation methods over southwestern China. The spatio-temporal consistencies, such as the spatial distributions of LAI products and their statistical relationship as a function of topographic indices, time, and vegetation types, respectively, were investigated through intercomparison between MODIS and GLASS products during the period 2011–2013. The accuracies and change ranges of these two products were evaluated against available LAI reference maps over 10 sampling regions which standed for typical vegetation types and topographic gradients in southwestern China.The results show that GLASS LAI exhibits higher percentage of good quality data (i.e. successful retrievals) and smoother temporal profiles than MODIS LAI. The percentage of successful retrievals for MODIS and GLASS is vulnerable to topographic indices, especially to relief amplitude. Besides, the two products do not capture seasonal dynamics of crop, especially in spring over heterogeneously hilly regions. The yearly mean LAI differences between MODIS and GLASS are within ±0.5 for 64.70% of the total retrieval pixels over southwestern China. The spatial distribution of mean differences and temporal profiles of these two products are inclined to be dominated by vegetation types other than topographic indices. The spatial and temporal consistency of these two products is good over most area of grasses/cereal crops; however, it is poor for evergreen broadleaf forest. MODIS presents more reliable change range of LAI than GLASS through comparison with fine resolution reference maps over most of sampling regions. The accuracies of direct validation are obtained for GLASS LAI (r = 0.35, RMSE = 1.72, mean bias = −0.71) and MODIS LAI (r = 0.49, RMSE = 1.75, mean bias = −0.67). GLASS performs similarly to MODIS, but may be marginally inferior to MODIS based on our direct validation results. The validation experience demonstrates the necessity and importance of topographic consideration for LAI estimation over mountain areas. Considerable attention will be paid to the improvements of surface reflectance, retrieval algorithm and land cover types so as to enhance the quality of LAI products in topographically complex terrain.     

Remotely detecting canopy nitrogen concentration and uptake of paddy rice in the Northeast China Plain

The influence of morphophysiological variation at different growth stages on the performance of vegetation indices for estimating plant N status has been confirmed. However, the underlying mechanisms explaining how this variation impacts hyperspectral measures and canopy N status are poorly understood. In this study, four field experiments involving different N rates were conducted to optimize the selection of sensitive bands and evaluate their performance for modeling canopy N status of rice at various growth stages in 2007 and 2008. The results indicate that growth stages negatively affect hyperspectral indices in different ways in modeling leaf N concentration (LNC), plant N concentration (PNC) and plant N uptake (PNU). Published hyperspectral indices showed serious limitations in estimating LNC, PNC and PNU. The newly proposed best 2-band indices significantly improved the accuracy for modeling PNU (R² = 0.75–0.85) by using the lambda by lambda band-optimized algorithm. However, the newly proposed 2-band indices still have limitations in modeling LNC and PNC because the use of only 2-band indices is not fully adequate to provide the maximum N-related information. The optimum multiple narrow band reflectance (OMNBR) models significantly increase the accuracy for estimating the LNC (R² = 0.67–0.71) and PNC (R² = 0.57–0.78) with six bands. Results suggest the combinations of center of red-edge (735 nm) with longer red-edge bands (730–760 nm) are very efficient for estimating PNC after heading, whereas the combinations of blue with green bands are more efficient for modeling PNC across all stages. The center of red-edge (730–735 nm) paired with early NIR bands (775–808 nm) are predominant in estimating PNU before heading, whereas the longer red-edge (750 nm) paired with the center of “NIR shoulder” (840–850 nm) are dominant in estimating PNU after heading and across all stages. The OMNBR models have the advantage of modeling canopy N status for the entire growth period. However, the best 2-band indices are much easier to use. Alternatively, it is also possible to use the best 2-band indices to monitor PNU before heading and PNC after heading. This study systematically explains the influences of N dilution effect on hyperspectral band combinations in relating to the different N variables and further recommends the best band combinations which may provide an insight for developing new hyperspectral vegetation indices.     

A visible band index for remote sensing leaf chlorophyll content at the canopy scale

Leaf chlorophyll content is an important variable for agricultural remote sensing because of its close relationship to leaf nitrogen content. The triangular greenness index (TGI) was developed based on the area of a triangle surrounding the spectral features of chlorophyll with points at (670 nm, R₆₇₀), (550 nm, R₅₅₀), and (480 nm, R₄₈₀), where R_λ is the spectral reflectance at wavelengths of 670, 550 and 480, respectively. The equation is TGI = −0.5[(670 − 480)(R₆₇₀ − R₅₅₀) − (670 − 550)(R₆₇₀ − R₄₈₀)]. In 1999, investigators funded by NASA's Earth Observations Commercialization and Applications Program collaborated on a nitrogen fertilization experiment with irrigated maize in Nebraska. Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data and Landsat 5 Thematic Mapper (TM) data were acquired along with leaf chlorophyll meter and other data on three dates in July during late vegetative growth and early reproductive growth. TGI was consistently correlated with plot-averaged chlorophyll-meter values at the spectral resolutions of AVIRIS, Landsat TM, and digital cameras. Simulations using the Scattering by Arbitrarily Inclined Leaves (SAIL) canopy model indicate an interaction among TGI, leaf area index (LAI) and soil type at low crop LAI, whereas at high LAI and canopy closure, TGI was only affected by leaf chlorophyll content. Therefore, TGI may be the best spectral index to detect crop nitrogen requirements with low-cost digital cameras mounted on low-altitude airborne platforms.     

Comparison of UAV and WorldView-2 imagery for mapping leaf area index of mangrove forest

Unmanned Aerial Vehicle (UAV) remote sensing has opened the door to new sources of data to effectively characterize vegetation metrics at very high spatial resolution and at flexible revisit frequencies. Successful estimation of the leaf area index (LAI) in precision agriculture with a UAV image has been reported in several studies. However, in most forests, the challenges associated with the interference from a complex background and a variety of vegetation species have hindered research using UAV images. To the best of our knowledge, very few studies have mapped the forest LAI with a UAV image. In addition, the drawbacks and advantages of estimating the forest LAI with UAV and satellite images at high spatial resolution remain a knowledge gap in existing literature. Therefore, this paper aims to map LAI in a mangrove forest with a complex background and a variety of vegetation species using a UAV image and compare it with a WorldView-2 image (WV2).In this study, three representative NDVIs, average NDVI (AvNDVI), vegetated specific NDVI (VsNDVI), and scaled NDVI (ScNDVI), were acquired with UAV and WV2 to predict the plot level (10 × 10 m) LAI. The results showed that AvNDVI achieved the highest accuracy for WV2 (R² = 0.778, RMSE = 0.424), whereas ScNDVI obtained the optimal accuracy for UAV (R² = 0.817, RMSE = 0.423). In addition, an overall comparison results of the WV2 and UAV derived LAIs indicated that UAV obtained a better accuracy than WV2 in the plots that were covered with homogeneous mangrove species or in the low LAI plots, which was because UAV can effectively eliminate the influence from the background and the vegetation species owing to its high spatial resolution. However, WV2 obtained a slightly higher accuracy than UAV in the plots covered with a variety of mangrove species, which was because the UAV sensor provides a negative spectral response function(SRF) than WV2 in terms of the mangrove LAI estimation.     

Non-linear partial least square regression increases the estimation accuracy of grass nitrogen and phosphorus using in situ hyperspectral and environmental data

Grass nitrogen (N) and phosphorus (P) concentrations are direct indicators of rangeland quality and provide imperative information for sound management of wildlife and livestock. It is challenging to estimate grass N and P concentrations using remote sensing in the savanna ecosystems. These areas are diverse and heterogeneous in soil and plant moisture, soil nutrients, grazing pressures, and human activities. The objective of the study is to test the performance of non-linear partial least squares regression (PLSR) for predicting grass N and P concentrations through integrating in situ hyperspectral remote sensing and environmental variables (climatic, edaphic and topographic). Data were collected along a land use gradient in the greater Kruger National Park region. The data consisted of: (i) in situ-measured hyperspectral spectra, (ii) environmental variables and measured grass N and P concentrations. The hyperspectral variables included published starch, N and protein spectral absorption features, red edge position, narrow-band indices such as simple ratio (SR) and normalized difference vegetation index (NDVI). The results of the non-linear PLSR were compared to those of conventional linear PLSR. Using non-linear PLSR, integrating in situ hyperspectral and environmental variables yielded the highest grass N and P estimation accuracy (R² = 0.81, root mean square error (RMSE) = 0.08, and R² = 0.80, RMSE = 0.03, respectively) as compared to using remote sensing variables only, and conventional PLSR. The study demonstrates the importance of an integrated modeling approach for estimating grass quality which is a crucial effort towards effective management and planning of protected and communal savanna ecosystems.     

Assessment of leaf carotenoids content with a new carotenoid index: Development and validation on experimental and model data

Leaf carotenoids content (LCar) is an important indicator of plant physiological status. Accurate estimation of LCar provides valuable insight into early detection of stress in vegetation. With spectroscopy techniques, a semi-empirical approach based on spectral indices was extensively used for carotenoids content estimation. However, established spectral indices for carotenoids that generally rely on limited measured data, might lack predictive accuracy for carotenoids estimation in various species and at different growth stages. In this study, we propose a new carotenoid index (CARI) for LCar assessment based on a large synthetic dataset simulated from the leaf radiative transfer model PROSPECT-5, and evaluate its capability with both simulated data from PROSPECT-5 and 4SAIL and extensive experimental datasets: the ANGERS dataset and experimental data acquired in field experiments in China in 2004. Results show that CARI was the index most linearly correlated with carotenoids content at the leaf level using a synthetic dataset (R² = 0.943, RMSE = 1.196 μg/cm²), compared with published spectral indices. Cross-validation results with CARI using ANGERS data achieved quite an accurate estimation (R² = 0.545, RMSE = 3.413 μg/cm²), though the RBRI performed as the best index (R² = 0.727, RMSE = 2.640 μg/cm²). CARI also showed good accuracy (R² = 0.639, RMSE = 1.520 μg/cm²) for LCar assessment with leaf level field survey data, though PRI performed better (R² = 0.710, RMSE = 1.369 μg/cm²). Whereas RBRI, PRI and other assessed spectral indices showed a good performance for a given dataset, overall their estimation accuracy was not consistent across all datasets used in this study. Conversely CARI was more robust showing good results in all datasets. Further assessment of LCar with simulated and measured canopy reflectance data indicated that CARI might not be very sensitive to LCar changes at low leaf area index (LAI) value, and in these conditions soil moisture influenced the LCar retrieval accuracy.     

Combining UAV-based plant height from crop surface models,visible, and near infrared vegetation indices for biomass monitoring in barley

In this study we combined selected vegetation indices (VIs) and plant height information to estimate biomass in a summer barley experiment. The VIs were calculated from ground-based hyperspectral data and unmanned aerial vehicle (UAV)-based red green blue (RGB) imaging. In addition, the plant height information was obtained from UAV-based multi-temporal crop surface models (CSMs). The test site is a summer barley experiment comprising 18 cultivars and two nitrogen treatments located in Western Germany. We calculated five VIs from hyperspectral data. The normalised ratio index (NRI)-based index GnyLi (Gnyp et al., 2014) showed the highest correlation (R² = 0.83) with dry biomass. In addition, we calculated three visible band VIs: the green red vegetation index (GRVI), the modified GRVI (MGRVI) and the red green blue VI (RGBVI), where the MGRVI and the RGBVI are newly developed VI. We found that the visible band VIs have potential for biomass prediction prior to heading stage. A robust estimate for biomass was obtained from the plant height models (R² = 0.80–0.82). In a cross validation test, we compared plant height, selected VIs and their combination with plant height information. Combining VIs and plant height information by using multiple linear regression or multiple non-linear regression models performed better than the VIs alone. The visible band GRVI and the newly developed RGBVI are promising but need further investigation. However, the relationship between plant height and biomass produced the most robust results. In summary, the results indicate that plant height is competitive with VIs for biomass estimation in summer barley. Moreover, visible band VIs might be a useful addition to biomass estimation. The main limitation is that the visible band VIs work for early growing stages only.     

Retrieval of leaf water content spanning the visible to thermal infrared spectra

The objective of this study was to investigate the entire spectra (from visible to the thermal infrared; 0.390–14.0 μm) to retrieve leaf water content in a consistent manner. Narrow-band spectral indices (calculated from all possible two band combinations) and a partial least square regression (PLSR) were used to assess the strength of each spectral region. The coefficient of determination (R²) and root mean square error (RMSE) were used to report the prediction accuracy of spectral indices and PLSR models. In the visible-near infrared and shortwave infrared (VNIR–SWIR), the most accurate spectral index yielded R² of 0.89 and RMSE of 7.60%, whereas in the mid infrared (MIR) the highest R² was 0.93 and RMSE of 5.97%. Leaf water content was poorly predicted using two-band indices developed from the thermal infrared (R² = 0.33). The most accurate PLSR model resulted from MIR reflectance spectra (R² = 0.96, RMSE = 4.74% and RMSE cross validation RMSE_CV = 6.17%) followed by VNIR–SWIR reflectance spectra (R² = 0.91, RMSE = 6.90% and RMSE_CV = 7.32%). Using thermal infrared (TIR) spectra, the PLSR model yielded a moderate retrieval accuracy (R² = 0.67, RMSE = 13.27% and RMSE_CV = 16.39%). This study demonstrated that the mid infrared (MIR) and shortwave infrared (SWIR) domains were the most sensitive spectral region for the retrieval of leaf water content.     

Retrieving aboveground biomass of wetland Phragmites australis (common reed) using a combination of airborne discrete-return LiDAR and hyperspectral data

Wetland biomass is essential for monitoring the stability and productivity of wetland ecosystems. Conventional field methods to measure or estimate wetland biomass are accurate and reliable, but expensive, time consuming and labor intensive. This research explored the potential for estimating wetland reed biomass using a combination of airborne discrete-return Light Detection and Ranging (LiDAR) and hyperspectral data. To derive the optimal predictor variables of reed biomass, a range of LiDAR and hyperspectral metrics at different spatial scales were regressed against the field-observed biomasses. The results showed that the LiDAR-derived H_p99 (99th percentile of the LiDAR height) and hyperspectral-calculated modified soil-adjusted vegetation index (MSAVI) were the best metrics for estimating reed biomass using the single regression model. Although the LiDAR data yielded a higher estimation accuracy compared to the hyperspectral data, the combination of LiDAR and hyperspectral data produced a more accurate prediction model for reed biomass (R² = 0.648, RMSE = 167.546 g/m², RMSE_r = 20.71%) than LiDAR data alone. Thus, combining LiDAR data with hyperspectral data has a great potential for improving the accuracy of aboveground biomass estimation.     

Estimating winter wheat biomass by assimilating leaf area index derived from fusion of Landsat-8 and MODIS data

A sufficient number of satellite acquisitions in a growing season are essential for deriving agronomic indicators, such as green leaf area index (GLAI), to be assimilated into crop models for crop productivity estimation. However, for most high resolution orbital optical satellites, it is often difficult to obtain images frequently due to their long revisit cycles and unfavorable weather conditions. Data fusion algorithms, such as the Spatial and Temporal Adaptive Reflectance Fusion Model (STARFM) and the Enhanced STARFM (ESTARFM), have been developed to generate synthetic data with high spatial and temporal resolution to address this issue. In this study, we evaluated the approach of assimilating GLAI into the Simple Algorithm for Yield Estimation model (SAFY) for winter wheat biomass estimation. GLAI was estimated using the two-band Enhanced Vegetation Index (EVI2) derived from data acquired by the Operational Land Imager (OLI) onboard the Landsat-8 and a fusion dataset generated by blending the Moderate-Resolution Imaging Spectroradiometer (MODIS) data and the OLI data using the STARFM and ESTARFM models. The fusion dataset had the temporal resolution of the MODIS data and the spatial resolution of the OLI data. Key parameters of the SAFY model were optimised through assimilation of the estimated GLAI into the crop model using the Shuffled Complex Evolution-University of Arizona (SCE-UA) algorithm. A good agreement was achieved between the estimated and field measured biomass by assimilating the GLAI derived from the OLI data (GLAI_L) alone (R² = 0.77 and RMSE = 231 g m⁻²). Assimilation of GLAI derived from the fusion dataset (GLAI_F) resulted in a R² of 0.71 and RMSE of 193 g m⁻² while assimilating the combination of GLAI_L and GLAI_F led to further improvements (R² = 0.76 and RMSE = 176 g m⁻²). Our results demonstrated the potential of using the fusion algorithms to improve crop growth monitoring and crop productivity estimation when the number of high resolution remote sensing data acquisitions is limited.     

Remote quantification of phycocyanin in potable water sources through an adaptive model

Cyanobacterial blooms in water supply sources in both central Indiana USA (CIN) and South Australia (SA) are a cause of great concerns for toxin production and water quality deterioration. Remote sensing provides an effective approach for quick assessment of cyanobacteria through quantification of phycocyanin (PC) concentration. In total, 363 samples spanning a large variation of optically active constituents (OACs) in CIN and SA waters were collected during 24 field surveys. Concurrently, remote sensing reflectance spectra (R_rs) were measured. A partial least squares–artificial neural network (PLS–ANN) model, artificial neural network (ANN) and three-band model (TBM) were developed or tuned by relating the R_rs with PC concentration. Our results indicate that the PLS–ANN model outperformed the ANN and TBM with both the original spectra and simulated ESA/Sentinel-3/Ocean and Land Color Instrument (OLCI) and EO-1/Hyperion spectra. The PLS–ANN model resulted in a high coefficient of determination (R²) for CIN dataset (R² = 0.92, R: 0.3–220.7 μg/L) and SA (R² = 0.98, R: 0.2–13.2 μg/L). In comparison, the TBM model yielded an R² = 0.77 and 0.94 for the CIN and SA datasets, respectively; while the ANN obtained an intermediate modeling accuracy (CIN: R² = 0.86; SA: R² = 0.95). Applying the simulated OLCI and Hyperion aggregated datasets, the PLS–ANN model still achieved good performance (OLCI: R² = 0.84; Hyperion: R² = 0.90); the TBM also presented acceptable performance for PC estimations (OLCI: R² = 0.65, Hyperion: R² = 0.70). Based on the results, the PLS–ANN is an effective modeling approach for the quantification of PC in productive water supplies based on its effectiveness in solving the non-linearity of PC with other OACs. Furthermore, our investigation indicates that the ratio of inorganic suspended matter (ISM) to PC concentration has close relationship to modeling relative errors (CIN: R² = 0.81; SA: R² = 0.92), indicating that ISM concentration exert significant impact on PC estimation accuracy.     

Understanding the optical responses of leaf nitrogen in Mediterranean Holm oak (Quercus ilex) using field spectroscopy

The direct estimation of nitrogen (N) in fresh vegetation is challenging due to its weak influence on leaf reflectance and the overlaps with absorption features of other compounds. Different empirical models relate in this work leaf nitrogen concentration ([N]_Leaf) on Holm oak to leaf reflectance as well as derived spectral indices such as normalized difference indices (NDIs), the three bands indices (TBIs) and indices previously used to predict leaf N and chlorophyll. The models were calibrated and assessed their accuracy, robustness and the strength of relationship when other biochemicals were considered. Red edge was the spectral region most strongly correlated with [N]_Leaf, whereas most of the published spectral indexes did not provide accurate estimations. NDIs and TBIs based models could achieve robust and acceptable accuracies (TBI_{1310,1720,730}: R² = 0.76, [0.64,0.86]; RMSE (%) = 9.36, [7.04,12.83]). These models sometimes included indices with bands close to absorption features of N bonds or nitrogenous compounds, but also of other biochemicals. Models were independently and inter-annually validated using the bootstrap method, which allowed discarding those models non-robust across different years. Partial correlation analysis revealed that spectral estimators did not strongly respond to [N]_Leaf but to other leaf variables such as chlorophyll and water, even if bands close to absorption features of N bonds or compounds were present in the models.     

Vegetation chlorophyll estimates in the Amazon from multi-angle MODIS observations and canopy reflectance model

As a preparatory study for future hyperspectral missions that can measure canopy chemistry, we introduce a novel approach to investigate whether multi-angle Moderate Resolution Imaging Spectroradiometer (MODIS) data can be used to generate a preliminary database with long-term estimates of chlorophyll. MODIS monthly chlorophyll estimates between 2000 and 2015, derived from a fully coupled canopy reflectance model (ProSAIL), were inspected for consistency with eddy covariance fluxes, tower-based hyperspectral images and chlorophyll measurements. MODIS chlorophyll estimates from the inverse model showed strong seasonal variations across two flux-tower sites in central and eastern Amazon. Marked increases in chlorophyll concentrations were observed during the early dry season. Remotely sensed chlorophyll concentrations were correlated to field measurements (r² = 0.73 and r² = 0.98) but the data deviated from the 1:1 line with root mean square errors (RMSE) ranging from 0.355 μg cm⁻² (Tapajós tower) to 0.470 μg cm⁻² (Manaus tower). The chlorophyll estimates were consistent with flux tower measurements of photosynthetically active radiation (PAR) and net ecosystem productivity (NEP). We also applied ProSAIL to mono-angle hyperspectral observations from a camera installed on a tower to scale modeled chlorophyll pigments to MODIS observations (r² = 0.73). Chlorophyll pigment concentrations (Chl_A+B) were correlated to changes in the amount of young and mature leaf area per month (0.59 ≤  r² ≤  0.64). Increases in MODIS observed Chl_A+B were preceded by increased PAR during the dry season (0.61 ≤ r² ≤  0.62) and followed by changes in net carbon uptake. We conclude that, at these two sites, changes in LAI, coupled with changes in leaf chlorophyll, are comparable with seasonality of plant productivity. Our results allowed the preliminary development of a 15-year time series of chlorophyll estimates over the Amazon to support canopy chemistry studies using future hyperspectral sensors.     

Modeling soil parameters using hyperspectral image reflectance in subtropical coastal wetlands

Developing spectral models of soil properties is an important frontier in remote sensing and soil science. Several studies have focused on modeling soil properties such as total pools of soil organic matter and carbon in bare soils. We extended this effort to model soil parameters in areas densely covered with coastal vegetation. Moreover, we investigated soil properties indicative of soil functions such as nutrient and organic matter turnover and storage. These properties include the partitioning of mineral and organic soil between particulate (>53 μm) and fine size classes, and the partitioning of soil carbon and nitrogen pools between stable and labile fractions. Soil samples were obtained from Avicennia germinans mangrove forest and Juncus roemerianus salt marsh plots on the west coast of central Florida. Spectra corresponding to field plot locations from Hyperion hyperspectral image were extracted and analyzed. The spectral information was regressed against the soil variables to determine the best single bands and optimal band combinations for the simple ratio (SR) and normalized difference index (NDI) indices. The regression analysis yielded levels of correlation for soil variables with R² values ranging from 0.21 to 0.47 for best individual bands, 0.28 to 0.81 for two-band indices, and 0.53 to 0.96 for partial least-squares (PLS) regressions for the Hyperion image data. Spectral models using Hyperion data adequately (RPD > 1.4) predicted particulate organic matter (POM), silt + clay, labile carbon (C), and labile nitrogen (N) (where RPD = ratio of standard deviation to root mean square error of cross-validation [RMSECV]). The SR (0.53 μm, 2.11 μm) model of labile N with R² = 0.81, RMSECV= 0.28, and RPD = 1.94 produced the best results in this study. Our results provide optimism that remote-sensing spectral models can successfully predict soil properties indicative of ecosystem nutrient and organic matter turnover and storage, and do so in areas with dense canopy cover.     

Spectral resampling based on user-defined inter-band correlation filter: C3 and C4 grass species classification

In this paper, a user-defined inter-band correlation filter function was used to resample hyperspectral data and thereby mitigate the problem of multicollinearity in classification analysis. The proposed resampling technique convolves the spectral dependence information between a chosen band-centre and its shorter and longer wavelength neighbours. Weighting threshold of inter-band correlation (WTC, Pearson's r) was calculated, whereby r = 1 at the band-centre. Various WTC (r = 0.99, r = 0.95 and r = 0.90) were assessed, and bands with coefficients beyond a chosen threshold were assigned r = 0. The resultant data were used in the random forest analysis to classify in situ C₃ and C₄ grass canopy reflectance. The respective WTC datasets yielded improved classification accuracies (kappa = 0.82, 0.79 and 0.76) with less correlated wavebands when compared to resampled Hyperion bands (kappa = 0.76). Overall, the results obtained from this study suggested that resampling of hyperspectral data should account for the spectral dependence information to improve overall classification accuracy as well as reducing the problem of multicollinearity.     

Assessment of RapidEye vegetation indices for estimation of leaf area index and biomass in corn and soybean crops

Leaf area index (LAI) and biomass are important indicators of crop development and the availability of this information during the growing season can support farmer decision making processes. This study demonstrates the applicability of RapidEye multi-spectral data for estimation of LAI and biomass of two crop types (corn and soybean) with different canopy structure, leaf structure and photosynthetic pathways. The advantages of Rapid Eye in terms of increased temporal resolution (∼daily), high spatial resolution (∼5 m) and enhanced spectral information (includes red-edge band) are explored as an individual sensor and as part of a multi-sensor constellation. Seven vegetation indices based on combinations of reflectance in green, red, red-edge and near infrared bands were derived from RapidEye imagery between 2011 and 2013. LAI and biomass data were collected during the same period for calibration and validation of the relationships between vegetation indices and LAI and dry above-ground biomass. Most indices showed sensitivity to LAI from emergence to 8 m²/m². The normalized difference vegetation index (NDVI), the red-edge NDVI and the green NDVI were insensitive to crop type and had coefficients of variations (CV) ranging between 19 and 27%; and coefficients of determination ranging between 86 and 88%. The NDVI performed best for the estimation of dry leaf biomass (CV = 27% and r² = 090) and was also insensitive to crop type. The red-edge indices did not show any significant improvement in LAI and biomass estimation over traditional multispectral indices. Cumulative vegetation indices showed strong performance for estimation of total dry above-ground biomass, especially for corn (CV ≤ 20%). This study demonstrated that continuous crop LAI monitoring over time and space at the field level can be achieved using a combination of RapidEye, Landsat and SPOT data and sensor-dependant best-fit functions. This approach eliminates/reduces the need for reflectance resampling, VIs inter-calibration and spatial resampling.