Incrustations and fumarolic condensates at kilauea volcano, Hawaii: field, drill-hole and laboratory observations

Hawaiian volcanoes characteristically have but few of the many types of minerals found in incrustations of other volcanic areas. In Hawaii sulfates resulting from air oxidation of volatiles predominate, and fluorides produced during rock alteration by fumarolic gases are prominent. Halides are generally found where reducing conditions exist in fumaroles and lava lake drill holes. The most common mineral types are sulfur, opaline silica, gypsum, ralstonite, and thenardite. Minerals from the same deposit are found to vary markedly in the content of the less abundant components. Condensates from vapor issuing from fumaroles show little quantitative relationship in component content to incrustations deposited at the same fumaroles. It is believed that an energetically favorable isomorphic substitution of some elements in the crystal lattice of a depositing mineral may lead to the build-up of a high concentration of an element from a lean vapor. Equilibrium calculations applied to condensate studies give a good quantitative approximation to the concentrations of the elements found in natural systems, but when applied to incrustations they serve only to indicate general compositional relations. Laboratory studies have shown the important role of chlorides in metal transfer in the gas phase in high-temperature aqueous systems, but only in the absence of oxygen. These studies also demonstrated the important role of HF in rock alteration and in the transfer of silica.     

Formation mechanism of condensates,waxy and heavy oils in the southern margin of Junggar Basin,NW China

It is a challenge to determine the source and genetic relationship of condensate, waxy and heavy oils in one given complicated petroliferous area, where developed multiple sets of source rocks with different maturity and various chemical features.The central part of southern margin of Junggar Basin, NW China is such an example where there are condensates, light oils, normal density oils, heavy crude oils and natural gases. The formation mechanism of condensates has been seriously debated for long time;however, no study has integrated it with genetic types of waxy and heavy oils. Taking the central part of southern margin of Junggar Basin as a case, this study employs geological and geochemical methods to determine the formation mechanism of condensates,waxy and heavy oils in a complicated petroliferous area, and reveals the causes and geochemical processes of the co-occurrence of different types of crude oils in this region. Based on detailed geochemical analyses of more than 40 normal crude oils, light oils,condensates and heavy oils, it is found that the condensates are dominated by low carbon number n-alkanes and enriched in light naphthenics and aromatic hydrocarbons. Heptane values of these condensates range from 19% to 21%, isoheptane values from1.9 to 2.1, and toluene/n-heptane ratios from 1.5 to 2.0. The distribution of n-alkanes in the condensates presents a mirror image with high density waxy crude oils and heavy oils. Combined with the oil and gas-source correlations of the crude oils, condensates and natural gas, it is found that the condensates are product of evaporative fractionation and/or phase-controlled fractionation of reservoir crude oils which were derived from mature Cretaceous lacustrine source rocks in the relatively early stage. The waxy oils are the intermediate products of evaporative fractionation and/or phase-controlled fractionation of reservoir crude oils, while the heavy oils are in-situ residuals. Therefore, evaporative fractionation and/or phase-controlled fractionation would account for the formation of the condensate, light oil, waxy oil and heavy oil in the central part of southern margin of Junggar Basin, resulting in a great change of the content in terms of light alkanes, naphthenics and aromatics in condensates, followed by great uncertainties of toluene/n-heptane ratios due to migration and re-accumulation. The results suggest that the origin of the condensate cannot be simply concluded by its ratios of toluene/n-heptane and n-heptane/methylcyclohexane on the Thompson's cross-plot, it should be comprehensively determined by the aspects of geological background, thermal history of source rocks and petroleum generation,physical and chemical features of various crude oils and natural gas, vertical and lateral distribution of various crude oils in the study area.     

Evaluation of gases,condensates, and SO2 emissions from Augustine volcano,Alaska: the degassing of a Cl-rich volcanic system

After the March–April 1986 explosive eruption a comprehensive gas study at Augustine was undertaken in the summers of 1986 and 1987. Airborne COSPEC measurements indicate that passive SO₂ emission rates declined exponentially during this period from 380±45 metric tons/day (T/D) on 7/24/86 to 27±6 T/D on 8/24/87. These data are consistent with the hypothesis that the Augustine magma reservoir has become more degassed as volcanic activity decreased after the spring 1986 eruption. Gas samples collected in 1987 from an 870°C fumarole on the andesitic lava dome show various degrees of disequilibrium due to oxidation of reduced gas species and condensation (and loss) of H₂O in the intake tube of the sampling apparatus. Thermochemical restoration of the data permits removal of these effects to infer an equilibrium composition of the gases. Although not conclusive, this restoration is consistent with the idea that the gases were in equilibrium at 870°C with an oxygen fugacity near the Ni–NiO buffer. These restored gas compositions show that, relative to other convergent plate volcanoes, the Augustine gases are very HCl rich (5.3–6.0 mol% HCl), S rich (7.1 mol% total S), and H₂O poor (83.9–84.8 mol% H₂O). Values of D and ¹⁸O suggest that the H₂O in the dome gases is a mixture of primary magmatic water (PMW) and local seawater. Part of the Cl in the Augustine volcanic gases probably comes from this shallow seawater source. Additional Cl may come from subducted oceanic crust because data by Johnston (1978) show that Cl-rich glass inclusions in olivine crystals contain hornblende, which is evidence for a deep source (>25km) for part of the Cl. Gas samples collected in 1986 from 390°–642°C fumaroles on a ramp surrounding the inner summit crater have been oxidized so severely that restoration to an equilibrium composition is not possible. H and O isotope data suggest that these gases are variable mixtures of seawater, FMW, and meteoric steam. These samples are much more H₂O-rich (92%–97% H₂O) than the dome gases, possibly due to a larger meteoric steam component. The 1986 samples also have higher Cl/S, S/C, and F/Cl ratios, which imply that the magmatic component in these gases is from the more degassed 1976 magma. Thus, the 1987 samples from the lava dome are better indicators than the 1986 samples of degassing within the Augustine magma reservoir, even though they were collected a year later and contain a significant seawater component. Future gas studies at Augustine should emphasize fumaroles on active lava domes. Condensates collected from the same lava-dome fumarole have enrichments ot 10⁷–10² in Cl, Br, F, B, Cd, As, S, Bi, Pb, Sb, Mo, Zn, Cu, K, Li, Na, Si, and Ni. Lower-temperature (200°–650°C) fumaroles around the volcano are generally less enriched in highly volatile elements. However, these lower-termperature fumaroles have higher concentration of rock-forming elements, probably derived from the wall rock.     

The case for an unfractionated244Pu/238U ratio in high-temperature condensates

The coarse-grained, Ca-rich inclusions in the Allende meteorite are the highest-temperature condensates from the cooling solar nebula and, as such, the oldest solid objects in the solar system. All refractory elements with condensation points above the accretion temperature of the inclusions whose concentrations in them have been measured are seen to be present in the inclusions in unfractionated proportion to one another relative to C1 chondrites when data are averaged for a large number of inclusions. Observational data for U and theoretical data for both U and Pu suggest that these elements exhibited refractory behavior in the solar nebula. An experiment is proposed in which fissiogenic Xe and U contents are measured in a suite of these inclusions to obtain the²⁴⁴Pu/²³⁸U ratio of the solar system at the time of initial condensation with an uncertainty of ±15%.     

Some space gravity formulas and the dimensions and the mass of the Earth

Summary Adopting thePizzetti-Somigliana method and using elliptic integrals we have obtained closed formulas for the space gravity field in which one of the equipotential surfaces is a triaxial ellipsoid. The same formulas are also obtained in first approximation of the equatorial flattening avoiding the use of the elliptic integrals. Using data from satellites and Earth gravity data the gravitational and geometric bulge of the Earth's equator are computed. On the basis of these results and on the basis of recent gravity data taken around the equator between the longitudes 50° to 100° E, 155° to 180° E, and 145° to 180° W, we question the advantage of using a triaxial gravity formula and a triaxial ellipsoid in geodesy. Closed formulas for the space field in which a biaxial ellipsoid is an equipotential surface are also derived in polar coordinates and its parameters are specialized to give the international gravity formula values on the international ellipsoid. The possibility to compute the Earth's dimensions from the present Earth gravity data is the discussed and the value ofMG=(3.98603×10²⁰ cm³ sec^–2) (M mass of the Earth,G gravitational constant) is computed. The agreement of this value with others computed from the mean distance Earth-Moon is discussed. The Legendre polinomials series expansion of the gravitational potential is also added. In this series the coefficients of the polinomials are closed formulas in terms of the flattening andMG.Publication Number 327, and Istituto di Geodesia e Geofisica of Università di Trieste.     

浙江省北部及邻区中强地震前地倾斜异常特征及其预测意义

解释并讨论了湖州和宁波台１９９３年以来的地倾斜资料,总结了震前有异常显示的６次地震。发现：①异常在现场记录资料中均有显示,异常形态的识别对预报地震有重要的意义;②能观测到异常全过程的倾斜仪与震中的距离基本符合式ｌｇＤｊ＝０．３０３（ＭＳ＋１．６）给出的监测能力半径,大于这个半径的台有时也能观测到异常,但多为短临异常。如果震前记录到异常的全过程,则利用单台资料可能对地震三要素进行预测。     

Crustal and upper mantle structure and the deep seismogenic environment in the source regions of the Lushan earthquake and the Wenchuan earthquake

Following the M w 7.9 Wenchuan earthquake, the M w 6.6 Lushan earthquake is another devastating earthquake that struck the Longmenshan Fault Zone (LFZ) and caused severe damages. In this study, we collected continuous broadband ambient noise seismic data and earthquake event data from Chinese provincial digital seismic network, and then utilized ambient noise tomography method and receiver function method to obtain high resolution shear wave velocity structure, crustal thickness, and Poisson ratio in the earthquake source region and its surroundings. Based on the tomography images and the receiver function results, we further analyzed the deep seismogenic environment of the LFZ and its neighborhood. We reveal three main findings: (1) There is big contrast of the shear wave velocities across the LFZ. (2) Both the Lushan earthquake and the Wenchuan earthquake occurred in the regions where crustal shear wave velocity and crustal thickness change dramatically. The rupture faults and the aftershock zones are also concentrated in the areas where the lateral gradients of crustal seismic wave speed and crustal thickness change significantly, and the focal depths of the earthquakes are concentrated in the transitional depths where shear wave velocities change dramatically from laterally uniform to laterally non-uniform. (3) The Wenchuan earthquake and its aftershocks occurred in low Poisson ratio region, while the Lushan earthquake sequences are located in high Poisson ratio zone. We proposed that the effect of the dramatic lateral variation of shear wave velocity, and the gravity potential energy differences caused by the big contrast in the topography and the crustal thickness across the LFZ may constitute the seismogenic environment for the strong earthquakes in the LFZ, and the Poisson ratio difference between the rocks in the south and north segments of the Longmenshan Fault zone may explain the 5 years delay of the occurrence of the Lushan earthquake than the Wenchuan earthquake.     

喜马拉雅地区与天山地区地壳强地震的孕震因素探讨

利用哈佛大学GCMT数据中心和前人积累的历史地震资料(1962~2016年M W>4.0地震)以及Crust2.0地壳结构统计分析了喜马拉雅地区、天山地区的地壳区域构造与地震活动间的相关性。此外,利用GFZ地学研究中心提供的静态卫星重力模型GGM03S/EGM2008和地形模型Topo计算了2个地区的各类重力异常场,同时还模拟了不同地壳弹性参数下的重力异常场,结果表明喜马拉雅地区重力异常场在水平、垂直方向的梯度特征远大于天山地区的异常特征,且喜马拉雅地区的有效弹性板厚度Te(6~15km)小于天山地区的有效弹性板厚度Te(20~30km)。最后,利用喜马拉雅地区与天山地区的GPS震间三维形变场约束了断层运动模型,结果显示两者主前缘断裂的断层闭锁深度及应力积累状态存在较大的差异。因此认为,造成青藏高原及邻区的边界地壳区域地震活动性差异的动力学因素,与地壳有效弹性板厚度、孕震断层参数及区域应力积累状态等密切相关。     

Correlation of the Radial and Meridional Components of IMF and the Solar Wind Velocity: Dependence on the Time and the Fluctuation Frequency

Geomagnetism and Aeronomy - The behavior of the correlation between the radial BR and normal BN components of the interplanetary magnetic field (IMF) in the dependence on the time, the flow type of...     

Pore water testing and analysis: the good,the bad,and the ugly

The increasingly common practice of collecting and assessing sediment pore water as a primary measure of sediment quality is reviewed. Good features of this practice include: pore water is a key exposure route for some organisms associated with sediments; pore water testing eliminates particle size effects; pore water analyses and tests can provide useful information regarding contamination and pollution. Bad features include: pore water is not the only exposure route; pore water tests lack chemical or biological realism: their "sensitivity" relative to other tests may be meaningless due to manipulation and laboratory artifacts; many sediment and surface dwelling organisms are not directly influenced by pore water. Bad features can become ugly if: other exposure pathways are not considered (for toxicity or bioaccumulation); manipulation techniques are not appropriate; pore water tests are inappropriately linked to population-level effects. Pore water testing and analyses can be effective tools provided their limitations are well understood by researchers and managers.     

地震活动性与日月引潮力相关性统计分析

基于ISC地震记录,利用天体动力学中二体问题的轨道方程和摄动理论,确定发震时刻太阳在地面的投影点位置,并进一步计算出太阳相对震中的地心天顶距,将地震按天顶距的大小进行统计,得到地震的太阳天顶距地震频度分布。同样的方法,可得地震的月球天顶距地震频度分布。统计发现:地震的太阳天顶距地震频度和月球天顶距地震频度分布表现出一致的规律性,且较大地震和小地震的活动规律不同,较大地震丛集发生在太阳(月球)天顶距0°和180°附近,与地面引潮力的绝对值分布有较好的一致性;而小地震多丛集在太阳(月球)天顶距60°和120°附近。在此基础上,我们对地震的日月天顶距同时进行统计,建立了日月天顶距地震概率密度分布,结果表明,日月投影点及其对蹠点周围,较大地震发生的概率较高。     

New paleomagnetic data on the Anabar Uplift and the Uchur-Maya region and their implications for the paleogeography and geological correlation of the Riphean of the Siberian Platform

The results of paleomagnetic studies of the reference sections of the Riphean and Late Proterozoic intrusive bodies of two remote areas of the Siberian Platform are presented. Within the limits of the Uchur-Maya region the sedimentary rocks of the Gonam, Omakhta, Ennin and Konder formations were studied; and the Riphean sedimentary rocks of the Burdur and Kotuykan formations on the northern and western slopes of the Anabar Uplift and, also, the Late Proterozoic intrusive complexes, located in the basins of the Fomich, Magan, Dzhogdzho and Kotuykan Rivers were studied. The paleomagnetic poles obtained in the course of this work and the present-day geochronological data give grounds to assume that: (1) the accumulation of the Riphean of the Anabar Uplift occurred after the formation of the Uchurskaya series of the Uchur-Maya region and was completed in approximately 1.5 Ga; (2) the Konder layers, compared according to the correlation pattern accepted at the present time [Semikhatov and Serebryakov, 1983] with the bottoms of the Totta formation, can be related to the appreciably more ancient stratigraphic level; (3) the intrusion of the studied intrusive bodies of the northern and western slopes of the Anabar Uplift occurred nonsimultaneously, although within close time intervals of approximately 1.5 Ga. The estimates of the kinematic parameters of the drift of the Siberian Platform within an interval of 1.7–1.0 Ga is carried out.     

试论岩石破裂和破坏的差异对地震模拟及前兆研究的影响

本文分析讨论了实验地震学研究中很少论及的岩石破裂和破坏的很大差异,指出仅以岩石破坏实验模拟地震特别是前兆研究存在诸多不足.建议以岩石破裂来模拟地震特别是前兆研究,由此可给出较为完整的地震活动图像.岩石破坏前兆已研究的相当多,但大破裂前则未必出现如破坏那样的前兆.大破裂前兆特征比破坏前兆更能反映地震前兆的复杂性,其识别更难,更符合实际.同时议及以岩样的整体黏滑模拟地震研究特别是前兆研究的不足.建议加强对局部现象——大破裂（或黏滑）的前兆特征、预测方法的深入仔细研究.     

Relationship of the Magnetic-Field Strength and the Brightness of the Sunspot Umbra and the Center of a Facular Knot

Geomagnetism and Aeronomy - Two main features define a sunspot as an object: a strong magnetic field and a low umbra temperature. The same can be said about a facular knot, in the center of which...     

太行山与燕山交汇部位的地壳厚度与泊松比分布特征

本文搜集了2001—2013年间在太行山与燕山构造带交汇部位先后布设的4个宽频带流动地震台阵和首都圈固定地震台网共192个台站记录到的全球5.5级以上远震事件波形资料,综合采用接收函数H-κ和CCP叠加分析获得了134个基岩台站下方的地壳厚度和泊松比结果.综合分析与前人研究相吻合但更加精细的地壳约束分布信息,发现研究区域的地壳厚度和泊松比在整体上呈现出从西北到东南方向渐变的特征,在南北重力梯度带两侧及其附近呈现出明显的小尺度地壳结构和物质组分的差异,且可明显区分出太行山地区和燕山构造带及盆山交界处的地壳厚度与泊松比的相对差异,这可能反映了这些地区在华北克拉通的构造演化过程中所经历的不同地壳改造过程.     

Models for the origin and composition of the earth,and the hypothesis of potassium in the Earth's core

Progress in understanding the condensation of planetary constituents from a solar nebula necessitates a re-examination of models for the origin and composition of the Earth. All models which appear to be viable require the Earth to have an Fe–FeS core and the full, or nearly full, solar (i.e. chondritic) K/Si ratio. The crust and upper mantle do not contain the requisite potassium for the entire Earth to have the solar K/Si ratio. Therefore, these models require that much of the Earth's potassium, about 80–90%, must be in the deep interior—in the lower mantle or in the core.The hypothesis that a substantial fraction of the Earth's potassium is in the Fe–FeS core is based on the chalcophilic behavior of potassium. Data including the stability of K₂S, the occurrence of potassium in sulfide phases in meteorites and in metallurgical systems, and most importantly, experiments on potassium partitioning between solid silicates and Fe–FeS melts support this hypothesis. The present data appear to require at least several percent of the Earth's total potassium to be in the core. Incorporation of much larger amounts of potassium into the core, possibly most of the 80–90% of the Earth's potassium which is postulated to be in the deep interior, is not contradicted by the present data. Additional experimental data, at high pressures, are required before quantitative estimates of the core's potassium content can be made.It is likely that⁴⁰K is a significant heat source in the core. Decay of⁴⁰K is a plausible energy source to drive core convection to maintain the geomagnetic field, and to drive mantle convection and seafloor spreading.     

Ophiolites and the oceanic crust: New evidence from the Tyrrhenian sea and the Western Alps

The succession recovered in ODP hole 107–651 in the young oceanic Vavilov basin (Tyrrhenian Sea) comprises, beneath a thick Pleistocene to Upper Pliocene sedimentary cover (chiefly volcanoclastics), four basement units: (1) MORB-type basaltic pillows and breccias; (2) a complex succession made of dolerites, albitites, basaltic breccias, metadolerite pebbles (including an intercalated sandy layer with periodotite clasts); (3) MORB-type basaltic pillows and breccias; (4) highly serpentinized peridotite. Between units 3 and 4, granitoid pebbles occur.This sequence is surprisingly similar to successions known in the Western Alps' Tethyan ophiolites. There, the sediments (Callovian-Oxfordian radiolarian cherts) lie stratigraphically upon breccias mostly derived from underlying serpentinite, and sometimes gabbroic basement. At some places, thin basaltic (tholeiitic) pillows and breccias occur between the radiolarian cherts and the breccias.From the comparison between a present day setting (the central Tyrrhenian Sea) and a formerly emplaced basement succession (the Western Alps), we stress the following (a) both the here-discussed ophiolites and oceanic basement are different from classical ophiolite sequences; (b) both occurrences imply unroofing of mantle rocks that therefore were directly outcropping on the seafloor; (c) such a comparison may indicate a very slow spreading rate for the Alpine Tethyan ocean.