Subduction-zone peridotites and their records of crust-mantle interaction

Subduction is the core process of plate tectonics. The mantle wedge in subduction-zone systems represents a key tectonic unit, playing a significant role in material cycling and energy exchange between Earth's layers. This study summarizes research progresses in terms of subduction-related peridotite massifs, including supra-subduction zone(SSZ) ophiolites and mantle-wedge-type(MWT) orogenic peridotites. We also provide the relevant key scientific questions that need be solved in the future. The mantle sections of SSZ ophiolites and MWT orogenic peridotites represent the mantle fragments from oceanic and continental lithosphere in subduction zones, respectively. They are essential targets to study the crust-mantle interaction in subduction zones. The nature of this interaction is the complex chemical exchanges between the subducting slab and the mantle wedge under the major control of physical processes. The SSZ ophiolites can record melt/fluid-rock interaction, metamorphism,deformation, concentration of metallogenic elements and material exchange between crust and mantle, during the stages from the generation of oceanic lithosphere at spreading centers to the initiation, development, maturation and ending of oceanic subduction at continental margins. The MWT orogenic peridotites reveal the history of strong metamorphism and deformation during subduction, the multiple melt/fluid metasomatism(including silicatic melts, carbonatitic melts and silicate-bearing C-HO fluids/supercritical fluids), and the complex cycling of crust-mantle materials, during the subduction/collision and exhumation of continental plates. In order to further reveal the crust-mantle interaction using subduction-zone peridotites, it is necessary to utilize high-spatial-resolution and high-precision techniques to constrain the complex chemical metasomatism, metamorphism,deformation at micro scales, and to reveal their connections with spatial-temporal evolution in macro-scale tectonics.     

Origin of the deep fluids in the paleosubduction zones in western Tianshan: Evidence from Pb- and Sr-isotope compositions of high-pressure veins and host rocks

Fluids in the deep subduction zones play an impor-tant role in the process of crust-mantle interaction. This has been proved by a large number of studies on the geochemistry of island arc volcanic rocks[1―9]. Study on high-pressure metamorphic rocks within orogen shows that the dehydration and devolatilization of subducted oceanic crust and sediments can release amounts of water during progressive metamorph- ism[10―13]. The origin of the fluids in the subduction zones provides important info…     

The seismogenic zone of subduction thrust faults

Abstract Subduction thrust faults generate earthquakes over a limited depth range. They are aseismic in their seaward updip portions and landward downdip of a critical point. The seaward shallow aseismic zone, commonly beneath accreted sediments, may be a consequence of unconsolidated sediments, especially stable-sliding smectite clays. Such clays are dehydrated and the fault may become seismogenic where the temperature reaches 100--150°C, that is, at a 5--15 km depth. Two factors may determine the downdip seismogenic limit. For subduction of young hot oceanic lithosphere beneath large accretionary sedimentary prisms and beneath continental crust, the transition to aseismic stable sliding is temperature controlled. The maximum temperature for seismic behavior in crustal rocks is ～ 350°C, regardless of the presence of water. In addition, great earthquake ruptures initiated at less than this temperature may propagate with decreasing slip to where the temperature is ～ 450°C. For subduction beneath thin island arc crust and beneath continental crust in some areas, the forearc mantle is reached by the thrust shallower than the 350°C temperature. The forearc upper mantle probably is aseismic because of stable-sliding serpentinite hydrated by water from the underthrusting oceanic crust and sediments. For many subduction zones the downdip seismogenic width defined by these limits is much less than previously assumed. Within the narrowly defined seismic zone, most of the convergence may occur in earthquakes. Numerical thermal models have been employed to estimate temperatures on the subduction thrust planes of four continental subduction zones. For Cascadia and Southwest Japan where very young and hot plates are subducting, the downdip seismogenic limit on the subduction thrust is thermally controlled and is shallow. For Alaska and most of Chile, the forearc mantle is reached before the critical temperature, and mantle serpentinite provides the limit. In all four regions, the seismogenic zones so defined agree with estimates of the extent of great earthquake rupture, and with the downdip extent of the interseismic locked zone.     

Metamorphism, partial preservation, and exhumation of ultrahigh-pressure belts

The Dabie-Sulu belt of east-central China, the Kokchetav Complex of northern Kazakhstan, the Maksyutov Complex of the South Urals, the Dora Maira Massif of the Western Alps, and the Western Gneiss Region of southwestern Norway lie astride intracontinental suture zones. All represent collisional mountain belts. Adjoining Eurasian regions exhibit little or no evidence of a coeval calc-alkaline arc. Each metamorphic complex contains mineralogic and textural relics of the presence or former existence of coesite ± diamond. Other ultrahigh-P, moderate-T metamorphic phases, including K-rich clinopyroxene, Mg-rich garnet, ellenbergerite, lawsonite, Al-rutile, glaucophane, high-Si phengite, and associations such as coesite + dolomite, magnesite + diopside, and talc + kyanite, diopside, jadeite, or phengite also testify to pressures approaching or exceeding 2.8 GPa. Each of the five well-studied Eurasian ultrahigh-pressure complexes consists chiefly of old, cool continental crust. Deep-seated recrystallization took place during the Phanerozoic. Subduction zones constitute the only known plate-tectonic environment where such high-P, low-T conditions exist. A model involving underflow of a salient of continental crust imbedded in oceanic crust-capped lithosphere explains the ultrahigh- pressure metamorphism. Partly exhumed ultrahigh-pressure terranes consist of relatively thin sheets 7 ± 5 km thick. During early stages of plate descent, hydration of relatively anhydrous units occurs, and volatiles are expelled from hydrous rocks. If present, aqueous fluids markedly catalyze reactions. Experimental studies on MORB bulk compositions demonstrate that, for common subduction-zone P–T trajectories, amphibole (the major hydrous phase in metabasaltic rocks) dehydrates at less than ~ 2.0 GPa; accordingly, mafic blueschists and amphibolites expel H₂O at great depth and, except for some coarse-grained, dry metagabbros, tend to recrystallize to eclogite. Serpentinized mantle beneath the oceanic crust devolatilizes at comparable pressures. In contrast, phengite and biotite remain stable to pressures exceeding 3.5 GPa in associated quartzofeldspathic rocks. So, under ultrahigh-pressure conditions, the micaceous lithologies that dominate the continental crust fail to evolve significant H₂O, and may transform incompletely to eclogitic assemblages. Although hydrous rocks expel volatiles during compaction and shallow burial, very deep underflow of partly hydrated oceanic crust + mantle generates most of the volatile flux along and above a subduction zone prior to continental collision. As large masses of sialic crust enter the convergent plate junction, fluid evolution at deep levels severely diminishes, and both convergence and dehydration terminate. After cessation of ultrahigh-pressure recrystallization, tectonic slices of sialic massifs return to shallow depths along the subduction channel, propelled by buoyancy; collisional sheets that retain ultrahigh-pressure effects lose heat efficiently across both upper (extensional, normal fault) and lower (subduction, reverse fault) tectonic contacts. These sheets ascend to midcrustal levels rapidly at average exhumation rates of 2–12 mm/year. Surviving ultrahigh-pressure relics occur as micro-inclusions encased in dense, strong, impermeable, unreactive mineralogic hosts, and are shielded during return towards conditions characteristic of midcrustal levels. Rehydration attending decompression is incomplete; its limited extent reflects the coarse grain size and relative impermeability of the rocks undergoing retrogression, as well as declining temperature and lack of aqueous fluids.     

Ultradeep diamonds originate from deep subducted sedimentary carbonates

Diamonds are renowned as the record of Earth’s evolution history. Natural diamonds on the Earth can be distinguished in light of genetic types as kimberlitic diamonds (including peridotitic diamonds and eclogitic diamonds), ultrahigh-pressure metamorphic diamonds and ophiolitic diamonds. According to the inclusion mineralogy, most diamonds originated from continental lithospheric mantle at depths of 140–250 km. Several localities, however, yield ultradeep diamonds with inclusion compositions that require a sublithospheric origin (>~250 km). Ultradeep diamonds exhibit distinctions in terms of carbon isotope composition, N-concentration, mineral inclusions and so on. The present study provides a systematic compilation concerning the features of ultradeep diamonds, based on which to expound their genesis affinity with mantle-carbonate melts. The diamond-parental carbonate melts are proposed to be stemmed from the Earth’s crust through subduction of oceanic lithosphere. Ultradeep diamonds are classified into a subgroup attaching to kimberlitic diamonds grounded by formation mechanism, and present connections in respect of carbon origin to eclogitic diamonds, ultrahigh-pressure metamorphic diamonds and ophiolitic diamonds.     

俯冲带的后撤与弧后扩张

西太平洋地壳年龄较老,因而岩石层较冷和比重较大,俯冲带的角度也较大,活动和成熟的弧后盆地则较多;条件与之相反的东太平洋弧后盆地则较少.本文探讨这种相关关系的力学成因,计算了俯冲板块诱生的弧后上涌地幔流动.计算表明,俯冲角度大及存在后撤俯冲时,有利于在弧后地区产生明显的上涌地幔流,这种深部热物质的上涌会导致弧后扩张.反之,年龄较轻的海洋地块较热和较轻,俯冲角度一般也较小,不易诱生上涌地幔物质流动和弧后扩张.大陆地壳密度小于地幔物质,大陆碰撞区就更不具备弧后扩张的条件.     

俯冲带的后撤与弧后扩张

西太平洋地壳年龄较老,因而岩石层较冷和比重较大,俯冲带的角度也较大,活动和成熟的弧后盆地则较多;条件与之相反的东太平洋弧后盆地则较少.本文探讨这种相关关系的力学成因,计算了俯冲板块诱生的弧后上涌地幔流动.计算表明,俯冲角度大及存在后撤俯冲时,有利于在弧后地区产生明显的上涌地幔流,这种深部热物质的上涌会导致弧后扩张.反之,年龄较轻的海洋地块较热和较轻,俯冲角度一般也较小,不易诱生上涌地幔物质流动和弧后扩张.大陆地壳密度小于地幔物质,大陆碰撞区就更不具备弧后扩张的条件.     

The water content and hydrogen isotope composition of continental lithospheric mantle and mantle-derived mafic igneous rocks in eastern China

The water contents of minerals and whole-rock in mantle-derived xenoliths from eastern China exhibit large variations and are generally lower than those from other on- and off-craton lithotectonic units. Nevertheless, the water contents of mineral and whole-rock in Junan peridotite xenoliths, which sourced from the juvenile lithospheric mantle, are generally higher than those elsewhere in eastern China. This suggests that the initial water content of juvenile lithospheric mantle is not low. There is no obvious correlation between the water contents and Mg^# values of minerals in the mantle xenoliths and no occurrence of diffusion profile in pyroxene, suggesting no relationship between the low water content of mantle xenolith and the diffusion loss of water during xenolith ascent with host basaltic magmas. If the subcontinental lithospheric mantle (SCLM) base is heated by the asthenospheric mantle, the diffusion loss of water is expected to occur. On the other hand, extraction of basaltic melts from the SCLM is a more efficient mechanism to reduce the water content of xenoliths. The primary melts of Mesozoic and Cenozoic basalts in eastern China have water contents, as calculated from the water contents of phenocrysts, higher than those of normal mid-ocean ridge basalts (MORB). The Mesozoic basalts exhibit similar water contents to those of island arc basalts, whereas the Cenozoic basalts exhibit comparable water contents to oceanic island basalts and backarc basin basalts with some of them resembling island arc basalts. These observations suggest the water enrichment in the mantle source of continental basalts due to metasomatism by aqueous fluids and hydrous melts derived from dehydration and melting of deeply subducted crust. Mantle-derived megacrysts, minerals in xenoliths and phenocrysts in basalts from eastern China also exhibit largely variable hydrogen isotope compositions, indicating a large isotopic heterogeneity for the Cenozoic SCLM in eastern China. The water content that is higher than that of depleted MORB mantle and the hydrogen isotope composition that is deviated from that of depleted MORB mantle suggest that the Cenozoic continental lithospheric mantle suffered the metasomatism by hydrous melts derived from partial melting of the subducted Pacific slab below eastern China continent. The metasomatism would lead to the increase of water content in the SCLM base and then to the decrease of its viscosity. As a consequence, the SCLM base would be weakened and thus susceptible to tectonic erosion and delamination. As such, the crust-mantle interaction in oceanic subduction channel is the major cause for thinning of the craton lithosphere in North China.     

The transport of water in subduction zones

The transport of water from subducting crust into the mantle is mainly dictated by the stability of hydrous minerals in subduction zones. The thermal structure of subduction zones is a key to dehydration of the subducting crust at different depths. Oceanic subduction zones show a large variation in the geotherm, but seismicity and arc volcanism are only prominent in cold subduction zones where geothermal gradients are low. In contrast, continental subduction zones have low geothermal gradients, resulting in metamorphism in cold subduction zones and the absence of arc volcanism during subduction. In very cold subduction zone where the geothermal gradient is very low(?5?C/km), lawsonite may carry water into great depths of ?300 km. In the hot subduction zone where the geothermal gradient is high(25?C/km), the subducting crust dehydrates significantly at shallow depths and may partially melt at depths of 80 km to form felsic melts, into which water is highly dissolved. In this case, only a minor amount of water can be transported into great depths. A number of intermediate modes are present between these two end-member dehydration modes, making subduction-zone dehydration various. Low-T/low-P hydrous minerals are not stable in warm subduction zones with increasing subduction depths and thus break down at forearc depths of ?60–80 km to release large amounts of water. In contrast, the low-T/low-P hydrous minerals are replaced by low-T/high-P hydrous minerals in cold subduction zones with increasing subduction depths, allowing the water to be transported to subarc depths of 80–160 km. In either case, dehydration reactions not only trigger seismicity in the subducting crust but also cause hydration of the mantle wedge. Nevertheless, there are still minor amounts of water to be transported by ultrahigh-pressure hydrous minerals and nominally anhydrous minerals into the deeper mantle. The mantle wedge overlying the subducting slab does not partially melt upon water influx for volcanic arc magmatism, but it is hydrated at first with the lowest temperature at the slab-mantle interface, several hundreds of degree lower than the wet solidus of hydrated peridotites. The hydrated peridotites may undergo partial melting upon heating at a later time. Therefore, the water flux from the subducting crust into the overlying mantle wedge does not trigger the volcanic arc magmatism immediately.     

The influence of crustal structure on compositions of subduction-related magmas

A survey of Sr isotopic ratios and other compositional features of subduction-related magma suites reveals significant correlations between these averaged parameters and characteristics of the underlying crust (i.e., thickness, composition, and age). These observations lead to the conclusion that crust and(or) mantle rocks in the hanging walls of subduction zones are involved in modification of primary mafic magmas (typically basalt or basaltic andesite). It is proposed that mafic magmas will stagnate within the crust or uppermost mantle where they may differentiate and react with wall rocks. The extent to which such processes manifest themselves will depend upon details of the local crustal structure. In particular, the composition and age of the crust will strongly influence such parameters as Sr, Nd and Pb isotopic compositions. Such data strongly indicate the involvement of crustal rocks in locales underlain by old sialic crust (e.g., central Andes). Depending upon the level of magma stagnation and evolution within the crust, different trends in isotopic composition may result. These isotopic trends may be enhanced by partial melting of the wall rocks to produce relatively silicic anatectic magmas, and locally they may reflect subduction of continental sediments. Interpretation of the isotopic data may be more ambiguous in locales underlain by younger and more mafic continental crust (Cascades, E Eleutians) and those underlain by oceanic crust owing to the similarity in isotopic composition of primary magmas and the latter crustal materials. Yet some degree of crustal involvement in magmatic evolution seems highly probable even in these more primitive terranes. Consequently, most island arc magmas, and especially those more evolved than basalt, are probably not primary in the sense that they do not represent direct melts of the upper mantle. Studies of arc volcanic rocks may yield misleading conclusions concerning processes of magma generation related to subduction unless evolutionary processes are defined and their effects considered. It appears that modern volcanic arcs provide a poor analog for models of early crustal development because the modern mantle-derived magmatic components are more mafic in composition than average continental crust.     

Numerical models of subduction of the oceanic crust with basaltic plateaus

Light continents and islands characterized by a crustal thickness of more than 30 km float over a convective mantle, while the thin basaltic oceanic crust sinks completely in subduction zones. The normal oceanic crust is 7 km thick. However, anomalously thick basaltic plateaus forming as a result of emplacement of mantle plumes into moving oceanic lithospheric plates are also pulled into the mantle. One of the largest basaltic plateaus is the Ontong Java plateau on the Pacific plate, which arose during the intrusion of a giant superplume into the plate ～100 Myr ago. Notwithstanding its large thickness (averaging ～30 km), the Ontong Java plateau is still experiencing slow subduction. On the basis of numerical modeling, the paper analyzes the oceanic crust subduction process as a function of the mantle convection vigorousness and the density, thickness, viscosity, and shape of the crust. Even a simplified model of thermocompositional convection in the upper mantle is capable of explaining the observed facts indicating that the oceanic crust and sediments are pulled into the mantle and the continental crust is floating on the mantle.     

Recycling of the continental crust

In order to understand the evolution of the crust-mantle system, it is important to recognize the role played by the recycling of continental crust. Crustal recycling can be considered as two fundamentally distinct processes: 1) intracrustal recycling and 2) crust-mantle recycling. Intracrustal recycling is the turnover of crustal material by processes taking place wholly within the crust and includes most sedimentary recycling, isotopic resetting (metamorphism), intracrustal melting and assimilation. Crust-mantle recycling is the transfer of crustal material to the mantle with possible subsequent return to the crust. Intracrustal recycling is important in interpreting secular changes in sediment composition through time. It also explains differences found in crustal area-age patterns measured by different isotopic systems and may also play a role in modeling crustal growth curves based on Nd-model ages. Crustal-mantle recycling, for the most part, is a subduction process and may be considered on three levels. The first is recycling with only short periods of time in the mantle (<10 m.y.). This may be important in explaining the origin of island-arc and related igneous rocks; there is growing agreement that 1–3% recycled sediment is involved in their origin. Components of recycled crustal material, with long-term storage (up to 2.5 b.y.) in the mantle as distinct entities, has been suggested for the origin of ocean island and ultrapotassic volcanics but there is considerably less agreement on this interpretation. A third proposal calls for the return of crustal material to the mantle with efficient remixing in order to swamp the geochemical and isotopic signature of the recycled component by the mantle. This type of recycling is required for steady-state models of crustal evolution where the mass of the continents remains constant over geological time. It is unlikely if crust-mantle recycling has exceeded 0.75 km³/yr over the past 1–2 Ga.Good evidence exists that selective recycling is an important process. Sedimentary rocks preserved in different tectonic settings are apparently recycled at different rates, resulting in a bias in the sediment types preserved in the geologic record. Selective recycling has important implications for the interpretation of Nd model ages of old sedimentary rocks and in the analysis of accreted terranes. Although there is evidence that continental crust was formed prior to 3.8 Ga, the oldest preserved rocks do not exceed this age. It is likely that the intense meteorite bombardment, which affected the earth during the period 4.56–3.8 Ga, coupled with rapid mantle convection, which resulted from greater heat production, caused the destruction and probable recycling into the mantle of any early formed crust.Although crust-mantle recycling is seen as a viable process, it is concluded that crustal growth has exceeded crust-mantle recycling since at least 3.8 Ga. Intracrustal recycling has not been given adequate consideration in models of crustal growth based on isotopic data (particularly Nd model ages). It is concluded that crustal growth curves based on Nd model ages, while vastly superior to those based on K/Ar or Rb/Sr, tend to underestimate the volume of old crust, due to crust-mantle and/or intracrustal recycling.     

Deep carbon cycle in subduction zones

The carbon cycle between the deep Earth and the atmosphere(i.e., the deep carbon cycle) can significantly affect the global climate on both long and short time scales. Although carbon in the deep Earth can be released to the atmosphere in many ways, plate subduction is the only pathway for the return of carbon from the surface to the deep Earth. Owing to diversity in the forms of carbon and the special physicochemical property of carbonates, the behavior of carbon and carbonates in subduction zones significantly affects the products of subduction processes, the oxygen fugacity in subduction zones, and the activation and migration of elements during the crust-mantle interaction. Therefore, the carbon cycle in subduction zones plays an important role in maintaining a habitable climate by regulating the atmospheric CO_2 concentration, which significantly affects the global climate, and in causing fundamental changes in the physical and chemical properties of the mantle that result in a heterogeneous mantle. In this study, we review and discuss previous studies and scientific problems regarding the carbon cycle in subduction zones from four aspects: observation and tracing of the carbon cycle, migration and variation of carbon during subduction,carbon flux, and the effect of the carbon cycle.     

Continental subduction and exhumation of high-pressure rocks: insights from thermo-mechanical laboratory modelling

Thermo-mechanical physical modelling of continental subduction is performed to investigate the exhumation of deeply subducted continental crust. The model consists of two lithospheric plates made of new temperature sensitive analogue materials. The lithosphere is underlain by liquid asthenosphere. The continental lithosphere contains three layers: the weak sedimentary layer, the crust made of a stronger material, and of a still stronger lithospheric mantle. The whole model is subjected to a constant vertical thermal gradient, causing the strength reduction with depth in each lithospheric layer. Subduction is driven by both push force and pull force. During subduction, the subducting lithosphere is heating and the strength of its layers reduces. The weakening continental crust reaches maximal depth of about 120 km and cannot subduct deeper because its frontal part starts to flow up. The subducted crust undergoes complex deformation, including indicated upward ductile flow of the most deeply subducted portions and localised failure of the subducted upper crust at about 50-km depth. This failure results in the formation of the first crustal slice which rises up between the plates under the buoyancy force. This process is accompanied by the delamination of the crustal and mantle layers of the subducting lithosphere. The delamination front propagates upwards into the interplate zone resulting in the formation of two other crustal slices that also rise up between the plates. Average equivalent exhumation rate of the crustal material during delamination is about 1 cm/year. The crust-asthenosphere boundary near the interplate zone is uplifted. The subducted mantle layer then breaks off, removing the pull force and thereby stopping the delamination and increasing horizontal compression of the lithosphere. The latter produces shortening of the formed orogen and the growth of relief. The modelling reveals an interesting burial/exhumation evolution of the sedimentary cover. During initial stages of continental subduction the sediments of the continental margin are dragged to the overriding plate base and are partially accreted at the deep part of the interplate zone (at 60-70 km-depth). These sediments remain there until the beginning of delamination during which the pressure between the subducted crust and the overriding plate increases. This results in squeezing the underplated sediments out. Part of them is extruded upwards along the interplate zone to about 30-km depth at an equivalent rate of 5-10 cm/year.     

Lithosphere types in North China: Evidence from geology and geophysics

Deep-seated materials from lithosphere are the ba- sic parameters and the foundation for geodynamic and continental dynamic studies. Division of lithosphere types and their deep-seated materials and structure can provide important evidence in interpreting the com- plex phenomena derived from the processes of forma- tion and evolution of continents, in evaluating the mineral resource potential, in predicting geological disasters and in the research of the continental dy- namic process. Huge lit…     

Tectonic controls on magma genesis and evolution in the northwestern United States

Field, chronologic, chemical, and isotopic data for late Cenozoic basaltic rocks from the northwestern United States illustrate the relationship between crustal structure and tectonic forces in controlling the genesis and evolution of continental volcanism. In the northwestern U.S., the first major episode of basaltic volcanism was triggered by crustal rifting in a “back-arc” environment, east of the westward-migrating volcanic arc created by the subduction of the Juan-de-Fuca plate beneath the North American plate. Rifting and volcanism were concentrated by pre-existing zones of crustal weakness associated with boundaries between the old Archean core of the continent and newly accreted terranes. Basalts erupted during this time (Columbia River, Steens Mountain) show evidence of significant fractionation histories including contamination by crust of varying age depending on the crustal structure at the eruption site. Presumably this reflects ponding and stagnation of primary magmas in the crust or at the crust-mantle interface due to their encounter with thick crust, not yet extended and still containing its low-density, easily fusible component. Continued rifting of this crust, and modification of its composition through extraction of rhyolitic partial melts and deposition of the fractionation products from primary basaltic melts, coupled with a shift in stress orientation roughly 10.5 Ma ago, allowed relatively unfractionated and uncontaminated magmas to begin reaching the surface. In the western part of the region (Oregon Plateau), these magmas tapped a mantle source similar to that which produced most of the ocean island basalts of the northern hemisphere. To the east (Snake River Plain), however, the mantle sampled by basaltic volcanism has isotopic characteristics suggesting it has preserved a record of incompatible element enrichment processes associated with the formation of the overlying Archean crustal section some 2.6 Ga ago.     

Relative depletion of niobium in some arc magmas and the continental crust: partitioning of K, Nb, La and Ce during melt/rock reaction in the upper mantle

Depletion of Nb relative to K and La is characteristic of lavas in subduction-related magmatic arcs, as distinct from mid-ocean ridge basalts. Nb depletion is also characteristic of the continental crust. This and other geochemical similarities between the continental crust and high-Mg# andesite magmas found in arcs suggests that the continental crust may have formed by accretion of andesites. Previous studies have shown that the major element characteristics of high-Mg# andesites may be produced by melt/rock reaction in the upper mantle. In this paper, new data on partitioning of K, Nb, La and Ce between garnet, orthopyroxene and clinopyroxene in mantle xenoliths, and on partitioning of Nb and La between orthopyroxene and liquid, show that garnet and orthopyroxene have Nb crystal/liquid distribution coefficients which are much larger than those of K and La. Similar fractionations of Nb from K and La are expected in spinel and olivine. For this reason, reactions between migrating melt and large masses of mantle peridotite can produce substantial depletion of Nb in derivative liquids. Modeling shows that reaction between ascending, mantle-derived melts and mantle peridotite is a viable mechanism for producing the trace element characteristics of high-Mg# andesite magmas and the continental crust.

Alternatively, small-degree melts of metabasalt and/or metasediment in the subducting slab may leave rutile in their residue, and will thus have large Nb depletions relative to K and La [1]. Slab melts are too rich in light rare earth elements and other incompatible elements, and too poor in compatible elements, to be parental to arc magmas. However, ascending slab melts may be modified by reaction with the mantle. Our new data permit modeling of the trace element effects of reaction between small-degree melts of the slab and mantle peridotite. Modeling shows that this type of reaction is also a viable mechanism for producing the trace element characteristics of high-Mg# andesites and the continental crust. These findings, in combination with previous results, suggest that melt/rock reaction in the upper mantle has been an important process in forming the continental crust and mantle lithosphere.     

Nitrogen in fluids effecting retrogression of granulite facies gneisses: a debatable mantle connection

The abundance patterns of nitrogen, and chlorine in retrogressed granulite facies gneisses from southern East Greenland exhibit strong enrichment in the vicinity of small-scale shear zones. Sulfur in the shear zones occurs at the same concentration levels as in the adjacent country rock, but is depleted in the transition zone between shear zone and country rock. Within the shear zone sulfur occurs as sulfate, whereas in the country rock granulites it occurs as sulfide. Recrystallization of rock in the shear zone to scapolite-bearing, hornblende-absent assemblages, along with changes in the major element chemistry, demonstrates that these zones define migration pathways of chemically reactive fluids. Consideration of the computed fluid compositions, and of the mass ratios of chlorine/sulfur and nitrogen/sulfur demonstrate that the fluid equilibrated with continental crust prior to its passage through gneisses in the study area. Previous suggestions have been made that the mantle may act as a source region for nitrogen-rich fluids. However, equilibration of these S-, N- and Cl-rich fluids with crustal material precludes the use of element abundances to identify a mantle signature; the bulk of these fluid constituents must be considered crustal derived.     

Metallogenesis of superlarge gold deposits in Jiaodong region and deep processes of subcontinental lithosphere beneath North China Craton in Mesozoic

The study of ore-forming chronology indicates that the superlarge gold deposits in the Jiaodong region were formed in 120±10 Ma. Sr-Nd-Pb isotopic compositions from typical gold deposits suggest that ore-forming materials were derived from the multisources, mantle component was partly involved in mineralization, the deep dynamic processes are the major geological background of large-scale metallogenesis in the Jiaodong region in Mesozoic. The deep processes mainly include the effect of post deep-subduction of continental crust of the central orogen belt and the distant effect of subduction of the paleo-Pacific plate underneath the Eurasian continent. However, lithosphere thinning, crust-mantle interaction, crustal extension and formation of large-type ore-controlling structures would be the comprehensive consequences of the above-mentioned geodynamic processes in the region.     

Nd-isotope systematics of ∼2.7 Ga adakites, magnesian andesites, and arc basalts, Superior Province: evidence for shallow crustal recycling at Archean subduction zones

An association of adakite, magnesian andesite (MA), and Nb-enriched basalt (NEB) volcanic flows, which erupted within ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts, has recently been documented in ∼2.7 Ga Wawa greenstone belts. Large, positive initial ?_Nd values (+1.95 to +2.45) of the adakites signify that their basaltic precursors, with a short crustal residence, were derived from a long-term depleted mantle source. It is likely that the adakites represent the melts of subducted late Archean oceanic crust. Initial ?_Nd values in the MA (+0.14 to +1.68), Nb-enriched basalts and andesites (NEBA) (+1.11 to +2.05), and ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts and andesites (+1.44 to +2.44) overlap with, but extend to lower values than, the adakites. Large, tightly clustered ?_Nd values of the adakites, together with Th/Ce and Ce/Yb systematics of the arc basalts that rule out sediment melting, place the enriched source in the sub-arc mantle. Accordingly, isotopic data for the MA, NEBA, and ‘normal’ arc basalts can be explained by melting of an isotopically heterogeneous sub-arc mantle that had been variably enriched by recycling of continental material into the shallow mantle in late Archean subduction zones up to 200 Ma prior to the 2.7 Ga arc. If the late Archean Wawa adakites, MA, and basalts were generated by similar geodynamic processes as their counterparts in Cenozoic arcs, involving subduction of young and/or hot ocean lithosphere, then it is likely that late Archean oceanic crust, and arc crust, were also created and destroyed by modern plate tectonic-like geodynamic processes. This study suggests that crustal recycling through subduction zone processes played an important role for the generation of heterogeneity in the Archean upper mantle. In addition, the results of this study indicate that the Nd-isotope compositions of Archean arc- and plume-derived volcanic rocks are not very distinct, whereas Phanerozoic plumes and intra-oceanic arcs tend to have different Nd-isotopic compositions.