Geochemical and mineralogical characteristics of recent clastic sediments from lower Godavari river: Implications of source rock weathering

The major, trace and rare earth elements geochemistry and clay mineral compositions in the river bed sediments from lower reaches of Godavari river suggest that they are derived from weathering of felsic rocks. Trace and rare earth elemental compositions indicate evidence of sedimentary sorting during transportation and deposition. Lower concentrations of transition elements, such as V, Ni and Cr imply enrichment of felsic minerals in these bed sediments. The REE pattern in lower Godavari sediments is influenced by the degree of source rock weathering. The light rare earth elements (LREE) content are indicating greater fractionation compared to the heavy rare earth elements (HREE). A striking relationship is observed between TiO₂ and gZREE content suggesting a strong control by LREE-enriched titaniferous minerals on REE chemistry. Shale-normalized REE pattern demonstrate a positive Eu anomaly, suggesting weathering of feldspar and their secondary products, which are enriched in Eu. Chondrite-normalised REE pattern is characteristic of felsic volcanic, granites and gnessic source rocks. Trace elemental compositions in sediments located near urban areas suggest influence of anthropogenic activity. Chemical Index of Alteration (CIA) is high (avg. 65.76), suggesting a moderate chemical weathering environment. X-ray diffraction analysis of clay fraction shows predominance of clay minerals that are formed because of the chemical weathering of felsic rocks.     

Investigating groundwater flow components in an Alpine relict rock glacier (Austria) using a numerical model

Relict rock glaciers are complex hydrogeological systems that might act as relevant groundwater storages; therefore, the discharge behavior of these alpine landforms needs to be better understood. Hydrogeological and geophysical investigations at a relict rock glacier in the Niedere Tauern Range (Austria) reveal a slow and fast flow component that appear to be related to the heterogeneous structure of the aquifer. A numerical groundwater flow model was used to indicate the influence of important internal structures such as layering, preferential flow paths and aquifer-base topography. Discharge dynamics can be reproduced reasonably by both introducing layers of strongly different hydraulic conductivities or by a network of highly conductive channels within a low-conductivity zone. Moreover, the topography of the aquifer base influences the discharge dynamics, which can be observed particularly in simply structured aquifers. Hydraulic conductivity differences of three orders of magnitude are required to account for the observed discharge behavior: a highly conductive layer and/or channel network controlling the fast and flashy spring responses to recharge events, as opposed to less conductive sediment accumulations sustaining the long-term base flow. The results show that the hydraulic behavior of this relict rock glacier and likely that of others can be adequately represented by two aquifer components. However, the attempt to characterize the two components by inverse modeling results in ambiguity of internal structures when solely discharge data are available.     

Surveying the anthropogenic impact of the Moldau river sediments and nearby soils using magnetic susceptibility

Measuring magnetic susceptibility is a method which is used to estimate the amount of magnetic particles in soils, sediments or dusts. Changes in magnetic susceptibility can be due to various reasons: input from different sources of sediments, e.g. from different soils or rocks, atmospheric fallout of anthropogenic dusts containing magnetic particles produced by fossil fuel combustion, steel production or road traffic. In the case of river sediments, input from the catchment is of primary significance. The main aim of this investigation was to test the potential of magnetic susceptibility screening in identifying the effect and significance of anthropogenic activities in an area with complex geological conditions. We investigated the magnetic susceptibility of riverbed sediments of the largest river of the Czech Republic, the Moldau river. Besides that, the magnetic signal of nearby topsoils as well as of outcropping bedrocks in the vicinity of the river was examined. In the upper 300 km of the river, the magnetic enhancement of the river sediments can be linked to anthropogenic activities. Positive correlations were found in the river sediments between the contents of Cu and Zn and magnetic susceptibility, while Fe, Mn and Ni did not show a correlation with magnetic susceptibility. However, the major geogenic magnetic anomaly in the area around the Slapy dam has made it impossible to unambiguously interpret the magnetic signal in terms of anthropogenic impact in the last 80 km downstream.     

Land disposal of river and lagoon dredged sediments

The Jacarepaguá lagoon system, in the Western part of the city of Rio de Janeiro, Brazil, with an area of 8 km² receives the contributions of a number of rivers crossing largely populated and industrial areas without adequate sanitation and drainage. Since 1996 studies have been carried out to assist future dredging works and disposal of rivers and lagoons sediments. These studies included full characterization of these sediments and evaluation of the contamination of the dredged material with emphasis on the assessment of heavy metals. The present paper report these studies to assess a large dredging programme of about 3.8 million m³ of the river basins and 4 million m³ of lagoons sediments to be disposed inland.     

Formation of dome and basin structures: Results from scaled experiments using non-linear rock analogues

Dome and basin folds are structures with circular or slightly elongate outcrop patterns, which can form during single- and polyphase deformation in various tectonic settings. We used power-law viscous rock analogues to simulate single-phase dome-and-basin folding of rocks undergoing dislocation creep. The viscosity ratio between a single competent layer and incompetent matrix was 5, and the stress exponent of both materials was 7. The samples underwent layer-parallel shortening under bulk pure constriction.Increasing initial layer thickness resulted in a decrease in the number of domes and basins and an increase in amplitude, A, arc-length, L, wavelength, λ, and layer thickness, H_f. Samples deformed incrementally show progressive development of domes and basins until a strain of e_Y=Z = −30% is attained. During the dome-and-basin formation the layer thickened permanently, while A, L, and λ increased. A dominant wavelength was not attained. The normalized amplitude (A/λ) increased almost linearly reaching a maximum of 0.12 at e_Y=Z = −30%. During the last increment of shortening (e_Y=Z = −30 to −40%) the domes and basins did not further grow, but were overprinted by a second generation of non-cylindrical folds. Most of the geometrical parameters of the previously formed domes and basins behaved stable or decreased during this phase. The normalized arc-length (L/H_f) of domes and basins is significantly higher than that of 2D cylindrical folds. For this reason, the normalized arc length can probably be used to identify domes and basins in the field, even if these structures are not fully exposed in 3D.     

Detection of petroleum contamination in river sediments from Quebec City region using GC–IRMS

Isotopic analysis by compound specific gas chromatography–isotope ratio mass spectrometry (GC–IRMS) is used to detect and characterize petroleum pollution in surficial sediments along the St Lawrence River, near Quebec City. Unusually mature n-alkane distributions have been found in some recent intertidal sediments in the region. GC–IRMS results suggest that the n-alkanes are not derived from indigenous organic sources because they carry δ¹³C values between −30.0 and −27.0‰, as well as very small isotopic differences between odd and even numbered n-alkanes, which are both typically associated with petroleum products. Comparison of these sediments with bunker fuel, an oil used in the shipping industry, has shown a close isotopic correlation in some sites, which is further supported by biomarkers. Overall, the contamination has been dispersed along the river but is generally localized around the industrial region where hydrocarbon transfer from shore storage to ships takes place. This study illustrates how GC–IRMS can be used effectively in the detection and characterization of petroleum pollutants in sediments.     

Heavy metals contamination in water and sediments of an urban river in a developing country

Water and sediment samples were collected from 20 location of the Buriganga river of Bangladesh during Summer and Winter 2009 to determine the spatial distribution, seasonal and temporal variation of different heavy metal contents. Sequential extraction procedure was employed in sediment samples for the geochemical partitioning of the metals. Total trace metal content in water and sediment samples were analyzed and compared with different standard and reference values. Concentration of total chromium, lead, cadmium, zinc, copper, nickel, cobalt and arsenic in water samples were greatly exceeded the toxicity reference values in both season. Concentration of chromium, lead, copper and nickel in sediment samples were mostly higher than that of severe effect level values, at which the sediment is considered heavily polluted. On average 72 % chromium, 92 % lead, 88 % zinc, 73 % copper, 63 % nickel and 68 % of total cobalt were associated with the first three labile sequential extraction phases, which portion is readily bioavailable and might be associated with frequent negative biological effects. Enrichment factor values demonstrated that the lead, cadmium, zinc, chromium and copper in most of the sediment samples were enriched sever to very severely. The pollution load index value for the total area was as high as 21.1 in Summer and 24.6 in Winter season; while values above one indicates progressive deterioration of the sites and estuarine quality. The extent of heavy metals pollution in the Buriganga river system implies that the condition is much frightening and may severely affect the aquatic ecology of the river.     

Estimation of the rock mass deformation modulus using a rock classification system

It is often difficult to directly obtain specific design parameters of interest. In these situations, estimation based on empirical correlations is an alternative. The deformation modulus of a rock mass, which is important to know for engineering projects, is measured by in situ tests, such as plate bearing, flat jack, pressure chamber, borehole jacking and dilatometer tests. Nevertheless, these in situ tests are expensive, time consuming and sometimes even impossible. Many attempts have been made to estimate the E modulus using easy-to-obtain parameters of a rock mass. This paper reviews previous studies and the equations that have been developed. In addition, this study presents a new relation developed using a database of 82 dilatometer test results gathered from two dam sites and a tunnel site. Statistical analyses were performed to correlate accessible rock parameters with measured E modulus values from in situ tests. Knowing that discontinuity characteristics and the strength of rock materials are the most important contributors to rock deformability, the focus was on identifying parameters that are affected by the mentioned properties. Among the tested parameters, RMR (Rock Mass Rating) showed the best correlation with the E modulus. Statistical analyses resulted in a new empirical equation that has an acceptable estimation ability.     

Geochemistry of Fe and Mn in surficial sediments of a tropical river and estuary,India—a granulometric approach

Geochemical characteristics of Fe and Mn in sand, silt, and clay fractions as well as in bulk sediments of the tropical perennial Muvattupuzha river and the Central Vembanad estuary of the southwest coast of India have been studied and discussed. The results of a physical fractionation study of Fe and Mn indicated a substantial increase in the content of these metals in silt and clay fractions above that in sand. The riverine silt and clay fractions account for two to three times the enrichment of Fe and Mn than the corresponding sand fraction; the estuarine counterparts indicate four to eight times the enrichment. The observed enrichment of Fe and Mn towards the more finer size grades is mainly due to the increased surface area of the finer clastics, which in turn increase the absorptive ability. However, the mineralogical diversities of the three size fractions also influence the enrichment of Fe and Mn. The spatial distribution of Fe and Mn indicates a marked decrease in the content of the latter than the former towards the high saline zones of the river and the estuary. This variation could be due to the higher solubility of Mn towards the high saline zones of the aquatic environment where reducing condition prevails most of the year.     

大兴安岭岩石圈地幔特征——哈拉哈河-绰尔河橄榄岩捕虏体的证据

大兴安岭哈拉哈河-绰尔河第四纪火山岩中含有尖晶石相和石榴石相橄榄岩捕虏体.本文报道的尖晶石相橄榄岩包括方辉橄榄岩和二辉橄榄岩两类,前者分布数量略高于后者.方辉橄榄岩多数具有较高的平衡温度(1072～1193℃),矿物化学成分变化大,含有高Mg橄榄石和高Cr#尖晶石,这些特征一致表明是古老岩石圈地幔残余的样品.而二辉橄榄岩显示相对均一的矿物化学成分和很宽的平衡温度变化范围(636～1178℃),代表了明显受到改造的岩石圈地幔,可能反映岩石圈地幔的不同深度和局部经历了软流圈与岩石圈相互作用.通过与华北克拉通的对比,发现地处兴蒙造山带的大兴安岭岩石圈地幔中仍保留有相当量的古老岩石圈地幔残余,区别于遭受强烈改造和破坏的华北克拉通东部地区的岩石圈地幔.     

Crustal velocity and Vp/Vs structures beneath central Anatolia from local seismic tomography

We applied a seismic tomography technique to arrival time data generated by local crustal earthquakes in central Anatolia in order to study the three-dimensional velocity and Vp/Vs structures and their relation with the complex tectonic processes and seismic activity occurring in the study region. The relatively equal and large number of both P- and S-wave arrival times comprising a total of 51,650 arrivals and the relatively uniform distribution of the recording stations imply that the obtained velocity anomalies are reliable features down to a depth of 40 km. This is also evident from the results of the checkerboard resolution test, hit count, and the ray-path coverage. The inversion results indicate the existence of strong lateral heterogeneities in the crust and uppermost mantle beneath central Anatolia. Prominent low-velocity anomalies are clearly imaged at all layers especially beneath existing volcanoes and the active fault segments. Higher-than-average Vp/Vs ratios are widely distributed, indicating the possible existence of over-pressurized fluids that may be responsible for the triggering of the large crustal earthquakes along the north and east Anatolian fault zones. We noticed that the seismic activity occurs mainly at the low-velocity areas and to a lesser extent in some high-velocity zones, perhaps because of the complex tectonics and geological structures. These observations imply that all the zones with velocity anomalies—either low or high—are potential sites for strain energy accumulation and subsequent release. The obtained velocity and Vp/Vs models are consistent with previous geophysical measurements conducted beneath central Anatolia and give much deeper understanding of the current seismotectonic processes occurring in the region.     

Two-dimensional stresses in a saturated poro-elastic foundation beneath a rigid structure—part. I. An impervious dam in a river

The problem of an impervious dam on a poro-elastic foundation is solved analytically. Using the known solution for the fluid pressure in the pores, the elastostatic stress field in the solid skeleton is analysed by reduction to two simpler problems whose solutions can be obtained by complex variable techniques. For welded contact, the rotation of the dam base is then found along with the stresses and strains in the ground. Modification for finite friction along the base is outlined in the appendix.     

Geochemistry of Harappan potteries from Kalibangan and sediments in the Ghaggar River: Clues for a dying river

The ephemeral Ghaggar-Hakra River of northwestern India has always been considered to be the remnant of an ancient perennial glacier-fed river(Vedic Saraswati). The exact reason and timing of major hydrological change of this river remains speculative. The river's purported association with the zenith of the Harappan civilisation remains a conjecture because the timings of its fluvial past are still being debated. In this study we have made an attempt to resolve this issue using geochemical provenance of sediments from some dated horizons in the Ghaggar flood plain and that of the material used in the potteries from the Mature Harappan period(4600-3900 yr BP) at Kalibangan. Sampled sedimentary horizons were dated by radiocarbon and optically stimulated luminescence(OSL) methods. Results of our study from the Ghaggar alluvium indicate that the river did have glacial sources during the early Holocene. However, the data from the potteries suggest that during the Mature Harappan period, the sediments in the Ghaggar as used by the potters did not have a higher Himalayan provenance and hence, were not derived from glaciated Himalayas.These findings imply that during the time of the Mature Harappans the Ghaggar had already become a foothill-fed river.     

Use and performance of in-stream structures for river restoration: a case study from North Carolina

In-stream structures including cross-vanes, J-hooks, rock vanes, and W-weirs are widely used in river restoration to limit bank erosion, prevent changes in channel gradient, and improve aquatic habitat. During this investigation, a rapid assessment protocol was combined with post-project monitoring data to assess factors influencing the performance of more than 558 in-stream structures and rootwads in North Carolina. Cross-sectional survey data examined for 221 cross sections from 26 sites showed that channel adjustments were highly variable from site to site, but approximately 60 % of the sites underwent at least a 20 % net change in channel capacity. Evaluation of in-stream structures ranging from 1 to 8 years in age showed that about half of the structures were impaired at 10 of the 26 sites. Major structural damage was often associated with floods of low to moderate frequency and magnitude. Failure mechanisms varied between sites and structure types, but included: (1) erosion of the channel bed and banks (outflanking); (2) movement of rock materials during floods; and (3) burial of the structures in the channel bed. Sites with reconstructed channels that exhibited large changes in channel capacity possessed the highest rates of structural impairment, suggesting that channel adjustments between structures led to their degradation of function. The data question whether currently used in-stream structures are capable of stabilizing reconfigured channels for even short periods when applied to dynamic rivers.     

Characterization of uranium-contaminated sediments from beneath a nuclear waste storage tank from Hanford, Washington: Implications for contaminant transport and fate

The concentration and distribution of uranium (U) in sediment samples from three boreholes recovered near radioactive waste storage tanks at Hanford, Washington, USA, were determined in detail using bulk and micro-analytical techniques. The source of contamination was a plume that contained an estimated 7000 kg of dissolved U that seeped into the subsurface as a result of an accident that occurred during filling of tank BX-102. The desorption character and kinetics of U were also determined by experiment in order to assess the mobility of U in the vadose zone. Most samples contained too little moisture to obtain quantitative information on pore water compositions. Concentrations of U (and contaminant phosphate—P) in pore waters were therefore estimated by performing 1:1 sediment-to-water extractions and the data indicated concentrations of these elements were above that of uncontaminated “background” sediments. Further extraction of U by 8 N nitric acid indicated that a significant fraction of the total U is relatively immobile and may be sequestered in mobilization-resistant phases. Fine- and coarse-grained samples in sharp contact with one another were sub-sampled for further scrutiny and identification of U reservoirs. Segregation of the samples into their constituent size fractions coupled with microwave-assisted digestion of bulk samples showed that most of the U contamination was sequestered within the fine-grained fraction. Isotope exchange (²³³U) tests revealed that ∼51% to 63% of the U is labile, indicating that the remaining fund of U is locked up in mobilization-resistant phases. Analysis by Micro-X-ray Fluorescence and Micro-X-ray Absorption Near-Edge Spectroscopy (μ-XRF and μ-XANES) showed that U is primarily associated with Ca and is predominately U(VI). The spectra obtained on U-enriched “hot spots” using Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLIFS) provide strong evidence for uranophane-type [Ca(UO₂)₂(SiO₃OH)₂(H₂O)₅] and uranyl phosphate [Ca(UO₂)₂(PO₄)₂(H₂O)_10-12] phases. These data show that disseminated micro-precipitates can form in narrow pore spaces within the finer-grained matrix and that these objects are likely not restricted to lithic fragment environments. Uranium mobility may therefore be curtailed by precipitation of uranyl silicate and phosphate phases, with additional possible influence exerted by capillary barriers. Consequently, equilibrium-based desorption models that predict the concentrations and mobility of U in the subsurface matrix at Hanford are unnecessarily conservative.     

Development and validation of computer models for structures in jointed rock

An extensive program was conducted to develop and validate computer models for the deformation of structures in jointed rock. Both discrete element and finite element models were investigated. The program comprised a sequence of seven calculational and experimental studies. In the final step, model predictions were compared with experimental data from a well-instrumented jointed-rock precision test. The results show that the sophisticated models developed were able to predict some elements of structural deformation in jointed rock, but that it is difficult to make high-confidence predictions of all aspects of structural deformation with these models. Copyright © 1999 John Wiley & Sons, Ltd.