Charging of the Penglai 9-1 oil field,Bohai Bay basin,China: Functions of the delta on accumulating petroleum

The Penglai 9-1 (PL9-1) oil field, which contains China's third largest offshore oil accumulation (in-place reserves greater than 2.28 × 10⁸ ton or 1.49 × 10⁹ bbl), was found in shallow reservoirs (700–1700 m, 2297–5577 ft) within the most active fault zone in east China. The PL9-1 field contains two oil-bearing series, the granite intrusions in Mesozoic (Mz) and both the sandstone reservoirs in Neogene Guantao (Ng) and Neogene Minghuazhen (Nm) Formation. The origins of the PL9-1 field, both in terms of source rock intervals and generative kitchens, were determined by analyzing biomarker distributions for 61 source rock samples and 33 oil samples. The Mesozoic granite intrusions, which hold more than 80% of the oil reserves in the field, were charged in the west by oil generated from the third member (Es₃) of the Shahejie Formation in the Bodong depression. The Neogene reservoirs of the PL9-1 field were charged in the west by oil generated from the third member (Es₃) of the Shahejie Formation in the Bodong depression and in the south by oil generated from the first member (Es₁) of the Shahejie Formation in the Miaoxibei depression. Interactive contact between the large fan delta and the mature source rocks residing in the Es₃ Formation of the Bodong depression resulted in a high expulsion efficiency from the source rocks and rapid oil accumulation in the PL9-1 field, which probably explains how can this large oil field accumulate and preserve within the largest and most active fault zone in east China.     

Mechanisms of petroleum accumulation in the Bozhong sub-basin, Bohai Bay Basin, China. Part 1: Origin and occurrence of crude oils

The origin of the fourteen major oil fields in the Bozhong sub-basin, Bohai Bay basin was studied based on the results of Rock-Eval pyrolysis on more than 700 samples and biomarker analysis on 61 source rock samples and 87 oil samples. The three possible source rock intervals have different biomarker assemblages and were deposited in different environments. The third member of the Oligocene Dongying Formation (E₃d₃, 32.8–30.3 Ma in age) is characterized mainly by high C₁₉/C₂₃ tricyclic terpane (>0.75), high C₂₄ tetracyclic terpane/C₂₆ tricyclic terpane (>2.5), low gammacerane/αβ C₃₀ hopane (<0.15) and low 4-methyl steranes/ΣC₂₉ steranes (<0.15) ratios, and was deposited in sub-oxic to anoxic environments with significant terrigenous organic matter input. The first (E₂s₁, 35.8–32.8 Ma) and third (E₂s₃, 43.0–38.0 Ma) members of the Eocene Shahejie Formation have low C₁₉/C₂₃ tricyclic terpane and low C₂₄ tetracyclic terpane/C₂₆ tricyclic terpane ratios and were deposited in anoxic environments with minor terrestrial organic matter input, but have different abundances of 4-methyl steranes and gammacerane. The hydrocarbon-generating potential and biomarker associations of these three source rock intervals were controlled by tectonic evolution of the sub-basin and climate changes. Three oil families derived from E₂s₃, E₂s₁ and E₃d, respectively, and three types of mixed oils have been identified. All large oil fields in the Bozhong sub-basin display considerable heterogeneities in biomarker compositions and originated from more than one source rock interval, which suggests that mixing of oils derived from multiple source rock intervals or multiple generative kitchens, and/or focusing of oils originated from a large area of a generative kitchen, is essential for the formation of large oil fields in the Bozhong sub-basin. E₂s₃- and E₂s₁-derived oils experienced relatively long-distance lateral migration and accumulated in traps away from the generative kitchen. E₃d₃-derived oils had migrated short distances and accumulated in traps closer to the generative kitchen. Such a petroleum distribution pattern has important implications for future exploration. There is considerable exploration potential for Dongying-derived oils in the Bozhong sub-basin, and traps close to or within the generative kitchens have better chance to contain oils generated from the Dongying Formation.     

Hydrocarbon generation and expulsion characteristics of Eocene source rocks in the Huilu area,northern Pearl River Mouth basin,South China Sea: Implications for tight oil potential

In recent years, new oil reservoirs have been discovered in the Eocene tight sandstone of the Huilu area, northern part of the Pearl River Mouth basin, South China Sea, indicating good prospects for tight oil exploration in the area. Exploration has shown that the Huilu area contains two main sets of source rocks: the Eocene Wenchang (E₂w) and Enping (E₂e) formations. To satisfy the requirements for further exploration in the Huilu area, particularly for tight oil in Eocene sand reservoirs, it is necessary to re-examine and analyze the hydrocarbon generation and expulsion characteristics. Based on mass balance, this study investigated the hydrocarbon generation and expulsion characteristics as well as the tight oil resource potential using geological and geochemical data and a modified conceptual model for generation and expulsion. The results show that the threshold and peak expulsion of the E₂w source rocks are at 0.6% vitrinite reflectance and 0.9% vitrinite reflectance, respectively. There were five hydrocarbon expulsion centers, located in the western, eastern, and northern Huizhou Sag and the southern and northern Lufeng Sag. The hydrocarbon yields attributed to E₂w source rocks are 2.4 × 10¹¹ tons and 1.6 × 10¹¹ tons, respectively, with an expulsion efficiency of 65%. The E₂e source rock threshold and peak expulsion are at 0.65% vitrinite reflectance and 0.93% vitrinite reflectance, respectively, with hydrocarbon expulsion centers located in the centers of the Huizhou and Lufeng sags. The yields attributed to E₂e source rocks are 1.1 × 10¹¹ tons and 0.2 × 10¹¹ tons, respectively, with an expulsion efficiency of 20%. Using an accumulation coefficient of 7%–13%, the Eocene tight reservoirs could contain approximately 1.3 × 10¹⁰ tons to 2.3 × 10¹⁰ tons, with an average of 1.8 × 10¹⁰ tons, of in-place tight oil resources (highest recoverable coefficient can reach 17–18%), indicating that there is significant tight oil potential in the Eocene strata of the Huilu area.     

Organic geochemistry and reservoir characterization of the organic matter-rich calcilutite in the Shulu Sag,Bohai Bay Basin,North China

Although extensive studies have been conducted on unconventional mudstone (shales) reservoirs in recent years, little work has been performed on unconventional tight organic matter-rich, fine-grained carbonate reservoirs. The Shulu Sag is located in the southwestern corner of the Jizhong Depression in the Bohai Bay Basin and filled with 400–1000 m of Eocene lacustrine organic matter-rich carbonates. The study of the organic matter-rich calcilutite in the Shulu Sag will provide a good opportunity to improve our knowledge of unconventional tight oil in North China. The dominant minerals of calcilutite rocks in the Shulu Sag are carbonates (including calcite and dolomite), with an average of 61.5 wt.%. The carbonate particles are predominantly in the clay to silt size range. Three lithofacies were identified: laminated calcilutite, massive calcilutite, and calcisiltite–calcilutite. The calcilutite rocks (including all the three lithofacies) in the third unit of the Shahejie Formation in the Eocene (Es₃) have total organic carbon (TOC) values ranging from 0.12 to 7.97 wt.%, with an average of 1.66 wt.%. Most of the analyzed samples have good, very good or excellent hydrocarbon potential. The organic matter in the Shulu samples is predominantly of Type I to Type II kerogen, with minor amounts of Type III kerogen. The temperature of maximum yield of pyrolysate (T_max) values range from 424 to 452 °C (with an average of 444 °C) indicating most of samples are thermally mature with respect to oil generation. The calcilutite samples have the free hydrocarbons (S₁) values from 0.03 to 2.32 mg HC/g rock, with an average of 0.5 mg HC/g rock, the hydrocarbons cracked from kerogen (S₂) yield values in the range of 0.08–57.08 mg HC/g rock, with an average of 9.06 mg HC/g rock, and hydrogen index (HI) values in the range of 55–749 mg HC/g TOC, with an average of 464 mg HC/g TOC. The organic-rich calcilutite of the Shulu Sag has very good source rock generative potential and have obtained thermal maturity levels equivalent to the oil window. The pores in the Shulu calcilutite are of various types and sizes and were divided into three types: (1) pores within organic matter, (2) interparticle pores between detrital or authigenic particles, and (3) intraparticle pores within detrital grains or crystals. Fractures in the Shulu calcilutite are parallel to bedding, high angle, and vertical, having a significant effect on hydrocarbon migration and production. The organic matter and dolomite contents are the main factors that control calcilutite reservoir quality in the Shulu Sag.     

Sedimentary characteristics and seismic geomorphology of gravity-flow channels in a rift basin: Oligocene Shahejie Formation,Qinan Slope,Huanghua Depression of Bohai Bay Basin,China

Deep-water gravity-flow sandstones are important hydrocarbon exploration and production targets in the Bohai Bay Basin, a Paleogene intra-continental rift basin in eastern China. In this paper, the seismic-sedimentology techniques are used to characterize, in plan view, the temporal and spatial evolution of a gravity-flow-channel complex of the Paleogene Shahejie Formation (Es) on the Qinan faulted-monoslope (Qinan Slope), Bohai Bay Basin. The results show that two or three gravity-flow channels, 9–12 km long and 0.5–2 km wide, were successively developed in later Es (Es1z–Es1s). The channels initially experienced westward migration and then shifted eastward. The corresponding wireline logs of the channel-fill sequences mainly present blocky-shaped or bell-like configurations, whereas their seismic profile features are characterized by strong amplitude reflections, such as U-shaped, plate-like, spindle-shaped and lenticular configurations.The syndepositional activity of three normal faults, i.e., the Nandagang Fault to the northwest, the Zhangbei Fault to the northeast and the Zhaobei Fault to the east led to gradient changes of the Qinan Slope, which have controlled the plan morphology (width, curvature, and bifurcation) of the gravity-flow channels. In the medium-late period of Es1z, triggered by intensive faulting on the three faults, the gradient of the Qinan Slope was steepened abruptly, resulting in an increase of flow velocity and erosion amplitude to underlying deposits. As a result, channels exhibiting narrow and straight configurations in plan view were formed. During the stage of early Es1z and Es1s, tectonic activity intensity was relatively low and the gradient of the Qinan Slope was gentle, so channels with great width and curvature were bifurcated and merged downstream.Comparison of the faulting amplitude of the three syndepositional faults suggests that the Nandagang and Zhaobei faults were inversely strengthened in the Es1z and Es1s. The Nandagang Fault to the west was found to be more active than the Zhaobei Fault to the east in the Es1z stage. This condition was reversed in Es1s. For that reason, the channels migrated to the west in the Es1z stage and then went back to the east during Es1s.Core analysis shows that the channel fills are mainly composed of sandy-debrites, slumps and turbidites. Among them, sandy debrites dominate deposition in terms of reservoir volume and hydrocarbon potential. These units primarily consist of sandstones and gravel-bearing sandstones, with bed thicknesses ranging from 10 to 40 m, an average porosity of 11% and a permeability of 25 mD. Being mostly encased in organic-rich dark mudstones, these sandy debrites are significant hydrocarbon exploration targets.The results of this study are not only useful to the hydrocarbon exploration and development planning for the Qinan Slope, but also helpful when considering other faulted-depressions in the Bohai Bay Basin and other intra-continent rifted basins around the world, particularly in terms of gravity-flow hydrocarbon exploration and research.     

Oil migration through preferential petroleum migration pathway (PPMP) and polycyclic faults: A case study from the Shijiutuo Uplift,Bohai Bay basin,China

The Shijiutuo uplift is an oil enriched uplift in the offshore Bohai Bay Basin. Petroleum migration is a key factor for oil enrichment in Neogene reservoirs far away from the hydrocarbon kitchen. In this article, an integration of geological, geophysical and geochemical analyses are employed to investigate the petroleum migration and accumulation on the Shijiutuo uplift. Hydrocarbons in the QHD32-6 and QHD33 oilfields are mainly originated from the third (E₂s₃) and first (E₂s₁) member of the Shahejie Formation. The shallow traps have significant contributions of late-stage E₂s₁-derived oil. Lateral petroleum migration is a major mechanism forming large oilfields on the Shijiutuo uplift. The large oilfields have multiple hydrocarbon kitchens, multiple source rocks, and numerous preferential petroleum migration pathways (PPMPs). Once petroleum arrives at the structural highs on the Shijiutuo uplift through the Guantao Formation (N₁g) carrier-beds, neotectonic faults cutting through Guantao (N₁g) and Minghuazhen (N₁m^L) formations could serve as effective conduits for vertical petroleum migration. Neotectonic faults have experienced polycyclic fault activities. Fluid inclusions indicate episodic hydrocarbon charging. Crude oils display duplex properties of biodegradation and non-biodegradation, which is strong evidence for multiple and episodic oil charging on the Shijiutuo uplift. Finally, episodic petroleum charging along polycyclic neotectonic faults causes the late-stage E₂s₁-derived oils to occur in the shallow reservoirs.     

Salt structures in the Laizhouwan depression, offshore Bohai Bay basin, eastern China: New insights from 3D seismic data

Using the new high-quality 3D seismic data, this paper addresses the salt structures in the KL11 area of the Laizhouwan depression in the southern offshore Bohai Bay basin. In the study area, the salt in the Sha-4 Member of the Paleogene Shahejie Formation thickened, and then formed an S–N trending salt wall, which changes shape regularly along its trend from salt diapir to salt pillow. The change in thickness of the suprasalt layers record five growth phases of the salt wall from the Eocene to the Quaternary: (1) early diapirism, (2) active diapirism, (3) passive diapirism, (4) relative structural quiescence, and (5) arching. The evolution of the salt structures was mostly governed by the multi-phase compression induced by the dextral strike-slip of the Tan–Lu fault, which formed a restraining bend in the study area. There was an original passive stock in the south, which was later tectonically squeezed by E–W compression and became a diapir. As the shortening propagated to the north from the original stock, the salt pillow was created in the north. Relative structural quiescence then followed until the next phase of compression, which arched the thick roof of the salt wall.     

Mineralogical and chemical distribution of the Es3L oil shale in the Jiyang Depression,Bohai Bay Basin (E China): Implications for paleoenvironmental reconstruction and organic matter accumulation

The Es₃^L (lower sub-member of the third member of the Eocene Shahejie Formation) shale in the Jiyang Depression is a set of relatively thick and widely deposited lacustrine sediments with elevated organic carbon, and is considered to be one of the most important source rocks in East China. We can determine the mineralogy, organic and inorganic geochemistry of the Es₃^L shale and calculate paleoclimate indexes by using multiple geochemical proxies based on organic chemistry (total organic carbon [TOC] and Rock-Eval pyrolysis), major and trace elements, X-Ray diffraction, and carbon and oxygen isotope data from key wells alongside ECS (Elemental Capture Spectroscopy) well log data. These indicators can be used to analyze the evolution of the paleoenvironment and provide a mechanism of organic matter (OM) accumulation. The Es₃^L oil shale has high TOC abundance (most samples >3.0%) and is dominated by Type I kerogens. Additionally, the organic-rich shale is rich in CaO and enrichment in some trace metals is present, such as Sr, Ba and U. The positive δ¹³C and negative δ¹⁸O values, high Sr/Ba, B/Ga and Ca/Ca + Fe ratios and low C/S ratios indicate that the Es₃^L shales were mainly deposited in a semi-closed freshwater-brackish water lacustrine environment. The consistently low Ti/Al and Si/Al ratios reflect a restricted but rather homogeneous nature for the detrital supply. Many redox indicators, including the Th/U, V/(V + Ni), and δU ratios, pyrite morphology and TOC-TS-Fe diagrams suggest deposition under dysoxic to suboxic conditions. Subsequently, the brackish saline bottom water evolved into an anoxic water body under a relatively arid environment, during which organic-lean marls were deposited in the early stage. Later, an enhanced warm-humid climate provided an abundant mineral nutrient supply and promoted the accumulation of algal material. OM input from algal blooms reached a maximum during the deposition of the organic-rich calcareous shale with seasonal laminations. High P/Ti ratios and a strongly positive relationship between the P and TOC contents indicate that OM accumulation in the oil shale was mainly controlled by the high primary productivity of surface waters with help from a less stratified water column. Factors such as the physical protection of clay minerals and the dilution of detrital influx show less influence on OM enrichment.     

Sequence stratigraphy and importance of syndepositional structural slope-break for architecture of Paleogene syn-rift lacustrine strata,Bohai Bay Basin,E. China

Sequence stratigraphy and syndepositional structural slope-break zones define the architecture of the Paleogene syn-rift, lacustrine succession in eastern China's Bohai Bay Basin. Jiyang, Huanghua and Liaohe subbasins are of particular interest and were our primary research objectives. Interpretation of 3D seismic data, well logs and cores reveals: One first-order sequence, 4 second-order sequences, and ten to thirteen third-order sequences were identified on the basis of the tectonic evolution, lithologic assemblage and unconformities in the subbasins of Bohai Bay Basin. Three types of syndepositional paleo-structure styles are recognized in this basin. They are identified as fault controlled, slope-break zone; flexure controlled, slope-break zone; and gentle slope.The three active structural styles affect the sequence stratigraphy. Distinct third-order sequences, within second-order sequences, have variable systems tract architecture due to structuring effects during tectonic episodes. Second-order sequences 1 and 2 were formed during rifting episodes 1 and 2. The development of the third-order sequences within these 2 second-order sequences was controlled by the active NW and NE oriented fault controlled, slope-break zones. Second-order sequence 3 formed during rifting episode 3, the most intense extensional faulting of the basin. Two types of distinctive lacustrine depositional sequence were formed during rifting episode 3: one was developed in an active fault controlled, slope-break zone, the other in an active flexure controlled, slope-break zone. Second-order sequence 4 was formed during the fourth episode of rifting. Syndepositional, fault- and flexure-controlled slope-break zones developed in the subsidence center (shore to offshore areas) of the basin and controlled the architecture of third-order sequences in a way similar to that in second-order sequence 3. Sequences in the gentle slope and syndepositional, flexure controlled slope-break zones were developed in subaerial region.Distribution of lowstand sandbodies was controlled primarily by active structuring on the slope-break zones, and these sandbodies were deposited downdip of the slope-break zones. Sand bodies within lowstand systems tracts have good reservoir quality, and are usually sealed by the shale sediments of the subsequent transgressive systems tract. They are favorable plays for stratigraphic trap exploration.     

The origin and charging directions of Neogene biodegraded oils: A geochemical study of large oil fields in the middle of the Shijiutuo Uplift,Bohai Sea,China

Two large oil fields (QHD32-6 and QHD33-1), located in the middle part of the Shijiutuo Uplift, have generally suffered mild biodegradation. Based on multivariate statistical analysis of the biomarker parameters, this study discussed the origin and charging directions for these two oil fields.In contrast to Ed₃-derived oil, all available oil samples from these two large oil fields displayed low C₁₉/C₂₃, C₂₄/C₂₆ and high G/H and 4-MSI, which are attributed to the mixtures of oils derived from the Shahejie (Es₁ and Es₃) source rocks. Oils in QHD32-6, which contain relatively more Es₃-derived oil, are called Group I oils, and most oils in QHD33-1, which share relatively more Es₁-derived oil, are called Group II oils. Our mixed oil experiments reveal the predominant Es₃- and Es₁-derived oil contribution for Group I and Group II oil groups, respectively; however, the selection of end member oils warrants further research.Based on comparisons of biomarker parameters, the QHD32-6 oil field was mainly charged in the north by oil generated from Shahejie formation source rocks in the Bozhong depression. However, oils from the north of QHD32-6 field display a remarkable difference to the oils in the south of this field, which may indicate that a charging pathway exists from the QHD33-1 field. Considering the variations in biomarker compositions in the west to -east and northwest to -southeast sections across the QHD33-1 and QHD32-6 oil fields, it can be deduced that Es₃-sourced oil migrated westward to the QHD32-6 traps, and then charging by Es₁ oil from the Bozhong Sag resulted in the QHD33-1 oil field being characterized by the mixture of Es₃- and Es₁-sourced oil. Moreover, migration of Es₁-derived oil from the Qinnan Sag was not identified, implying that the QHD33-1 oil field is mainly charged from the northeast of the Bozhong Sag.     

Effects of oil cracking on fluorescence color,homogenization temperature and trapping pressure reconstruction of oil inclusions from deeply buried reservoirs in the northern Dongying Depression,Bohai Bay Basin,China

The effects of oil cracking on fluorescence color, homogenization temperature (T_ho) and trapping pressure (P_t) of oil inclusions from deeply buried reservoirs (DBRs) (3672–4359 m) in the northern Dongying Depression were determined based on fluorescence spectroscopy and homogenization temperatures of oil inclusions, kinetic modeling of crude oil cracking, and petroleum inclusion thermodynamics modeling.The modeling results demonstrate that fluorescence color, T_ho and predicted P_t have strong relationships with the transformation rate via cracking of oil to gas (T_r), and the formation temperature (T_f) that the inclusions experienced. The fluorescence color is hardly influenced at all during the initial stages of oil cracking (T_r < 13%, T_f < 160 °C), but fluorescence color begins to shift toward shorter wavelengths (blue shift) during progressive oil cracking (T_r < 24%, T_f < 190 °C). With further oil cracking, the fluorescence color may either experience no change or continue its blue shift. Eventually the fluorescence color will disappear as the aromatic compounds are completely cracked. The T_ho increases at first (T_r < 24%, T_f < 190 °C), but then decreases or even becomes negative during major oil cracking. The reconstructed P_t values show a corresponding reverse trend.Oil inclusions from DBRs and other shallow reservoirs in the Dongying Depression show an obvious blue shift in fluorescence color at a depth of approximate 4000 m (T_f = 160 °C) and generally contain solid bitumen below 4000 m, supporting the effect of oil cracking on fluorescence variation, consistent with the modeling result. The T_ho from DBRs in the Minfeng area increases with increasing burial depth (T_f < 190 °C), which is also consistent with the modeling results. However, the T_ho of oil inclusions with blue-white fluorescence from DBRs in the Shengtuo area did not show such a trend. Recent trapping, high trapping pressure and higher-maturity oil may have led to a low-degree of oil cracking, and thus less modification of T_ho in the Shengtuo area.Oil cracking results in consistent volume ratios of pyrobitumen to oil inclusions (F_vpy) in the same fluid inclusion assemblage, and the F_vpy value increases with oil cracking level, which can be used to recognize if oil cracking has occurred in oil inclusions and what level of oil cracking they have experienced.As the oil cracking model used in this study did not account for the role of pressure, it is more applicable for oil inclusions that were trapped under normally pressured conditions. Oil inclusions trapped under overpressured conditions will be less influenced by oil cracking.     

Quantitative evaluation of the reservoir potential and controlling factors of semi-deep lacustrine tempestites in the Eocene Lijin Sag of the Bohai Bay Basin,East China

Ancient lacustrine storm-deposits that act as petroleum reservoirs are seldom reported. The Lijin Sag, which is located in the southeastern corner of the Bohai Bay Basin in East China, is a NE–SW trending Cenozoic half-graben basin. Some of its Eocene deposits (Bindong deposits) were interpreted as lacustrine tempestites. The Bindong tempestites, which developed in the lower part of the upper fourth member of the Shahejie Formation (Es4¹), constitute a new kind of petroleum reservoir and are novel petroleum exploration targets in the Bindong Area. However, the characteristics of the Es4¹ Bindong tempestite reservoirs and their controlling factors are poorly understood. Point-count analyses of thin sections, scanning electron microscope image analyses, X-ray diffractometry data, and the petrophysical parameters of the Bindong tempestite reservoirs were utilized to estimate the reservoir quality. The reservoirs have undergone significant diagenetic alteration, which can be divided into negative and positive aspects. The negative alteration includes compaction, authigenic minerals, and cementation such as carbonates, clay minerals and overgrowths of quartz and feldspar. The uneven distribution of carbonate cement increased the reservoir’s heterogeneity, with carbonate cement commonly precipitating along the sandstone-mudstone contacts. The primary porosity was severely reduced because of compaction and extensive carbonate cementation. Positive alteration includes dissolution, carbonate cementation, undercompaction and fractures. Carbonate cementation exhibited both positive and negative effects on the reservoir quality. Overall, the objective reservoir quality is quite poor. A quantitative evaluation of the reservoirs’ potential was conducted. The cutoff values of several of the reservoir’s parameters were calculated. The lower limits of the porosity and permeability are 8.35–5.85% and 1.2587–0.2753 × 10^–3 μm², respectively, depending on the depth. The upper limits of the carbonate and mud content are approximately 18.5% and 9–10%, respectively. A fundamental understanding of these characteristics will provide necessary information for extracting hydrocarbons from analogous subsurface reservoirs.