皖南-浙西下古生界碳沥青成因及南方海相"有效烃源岩"问题探讨

赋存于皖南—浙西的固体碳沥青分为古油藏裂解碳沥青和古油藏破坏次生充填碳沥青两种类型,阐明了两类碳沥青的不同成因机制。重新认定了浙西“康山沥青脉”为碳沥青而不是泥岩。论证了皖南、浙西碳沥青的烃源为下寒武统、中—上奥陶统至下志留统、中—上寒武统等。认为加里东运动—广西事件期间是下扬子盆地相区以下寒武统黑页岩为烃源的油藏形成和部分破坏的主要时期。针对南方的油气勘探,提出了只有在晚期成藏中作出贡献的源岩才是“有效烃源岩”的新概念。     

皖南-浙西下古生界碳沥青成因及南方海相“有效烃源岩“问题探讨

赋存于皖南-浙西的固体碳沥青分为古油藏裂解碳沥青和古油藏破坏次生充填碳沥青两种类型,阐明了两类碳沥青的不同成因机制.重新认定了浙西“康山沥青脉“为碳沥青而不是泥岩.论证了皖南、浙西碳沥青的烃源为下寒武统、中-上奥陶统至下志留统、中-上寒武统等.认为加里东运动-广西事件期间是下扬子盆地相区以下寒武统黑页岩为烃源的油藏形成和部分破坏的主要时期.针对南方的油气勘探,提出了只有在晚期成藏中作出贡献的源岩才是“有效烃源岩“的新概念.     

四川盆地磨溪地区龙王庙组储层沥青的地球化学特征及其意义

根据储层中沥青的产状、元素组成、固体碳同位素、饱和烃色谱、生物标志化合物以及芳烃色谱-质谱等,对磨溪地区龙王庙组储层固体沥青的地球化学特征、成因及来源进行了剖析。研究结果表明,其总体上具有低H/C原子比值、高反射率的特征,是古油藏原油经裂解形成的残留物。储层沥青的正构烷烃分布较为完整,碳数在C₁₆-C₃₁范围,没有受到明显的生物降解作用。其可能的烃源岩发育于还原环境,有机质来源于低等水生生物,为海相泥页岩。固体沥青碳同位素值介于-33.1‰~-35.4‰之间,与下寒武统烃源岩干酪根碳同位素具有很好的可比性,同时,其生物标志化合物组成也与下寒武统烃源岩相似,表明其烃源来自于下寒武统筇竹寺组。     

湘西黔东地区铅锌矿床与古油藏关系初探

本文以湖南花垣铅锌矿床和贵州牛角塘铅锌矿床为例,探讨了湘西黔东地区铅锌矿与古油藏的关系。二者在空间分布上关系密切,存在"共生"和"上油下矿"两种关系,下寒武统清虚洞组既是铅锌矿重要的赋矿层位也是古油藏储集层之一;铅锌矿源层可能为新元古代基底岩系或下寒武统石牌组碎屑岩,古油藏烃源岩主要为下寒武统牛蹄塘组。古油藏中的油田卤水萃取了石牌组碎屑岩中的铅锌等成矿物质,形成成矿流体并运移,在古油藏形成后,由于加里东末期的构造运动的影响,古油藏和成矿流体的平衡被打破导致铅锌矿质沉淀,在这个过程中古油藏中的油田卤水可能为铅锌矿的沉淀提供了部分硫源。铅锌矿成矿时代与加里东期形成或破坏的古油藏时间上较为一致。     

寒武系烃源古油藏油裂解气特征及成藏条件

在寒武系为母源的气藏中,普遍存在的固体沥青、25-降藿烷、氮气等三种物质,实际是古油藏残余油裂解的产物。25-降藿烷一般与氧化—降解油有关,氮气来自油藏水洗时溶入的大气,二者共同反映古油藏经历的抬升破坏作用。寒武系烃源一般经历过两次成藏:加里东—海西期形成“油藏”,燕山—喜马拉雅期裂解为“气藏”。寒武系油裂解气成藏的地质条件是:古构造聚油、后期改造适度、叠合盆地增熟、断层作为油气运移通道等。围绕加里东—海西期古油藏寻找原生、次生油裂解气是今后寻找寒武系来源油气的重要途径。     

四川盆地北缘马元铅锌矿床与古油藏关系研究

马元铅锌矿床是四川盆地北缘重要的铅锌矿床之一,赋矿地层为震旦系灯影组,野外可见大量的沥青与铅锌矿共生/伴生,镜下见早期沥青与闪锌矿、方铅矿共生,沥青的生物标志物与郭家坝组烃源岩极为相似。物质来源方面,铅锌成矿主要的物质来源和两期油气成藏的物质来源均为下寒武统郭家坝组;时间关系方面,铅锌成矿的共生矿物Rb-Sr同位素等时线年龄为(486.7±3.1)Ma,仅可能与第一期古油藏形成、破坏有关。闪锌矿和重晶石包裹体中含有CH4和少量H2S、沥青,表明铅锌成矿流体中富含有古油藏裂解产物。生烃、排烃、初次运移萃取出"双源层"中的铅锌元素,第一期古油藏裂解和短暂TSR作用产生的还原性硫为铅锌络合物沉淀提供了物质基础,第一期古油藏最终完全破坏残留下早期沥青。     

川东南丁山构造震旦系—下古生界油气成藏条件及成藏过程

川东南的构造演化可分成5个阶段:①晚震旦世抬升剥蚀阶段;②早古生代沉降阶段;③晚志留世—泥盆、石炭纪抬升剥蚀阶段;④二叠纪—晚白垩世沉降阶段;⑤晚白垩世—现今快速隆升阶段。震旦系灯影组—下古生界储层沥青与下寒武统和下志留统黑色泥岩之间地球化学特征的对比表明二者有着重要的联系,灯影组烃源来自下寒武统牛蹄塘组。丁山构造一直处于高部位,有利于油气聚集,丁山构造在晚白垩世前圈闭、封盖、储层及保存条件均较好,形成了古油藏。随着埋深的增大,古油藏裂解成古气藏。晚白垩世至今受喜马拉雅运动的影响,通天断层发育,保存条件变差,导致天然气的逸散。丁山构造的油气成藏过程可分为古油藏→古油藏裂解形成古气藏→古气藏破坏三大过程。     

黔中隆起及其周缘地区海相下组合与油气勘探前景

黔中隆起及其周缘地区,主要包括黔西北地区及其东部相邻的麻江古油藏地区,均属扬子台地的一部分,具有相似的构造及盆地演化历史。海相下组合主要是指震旦系、寒武系、奥陶系和志留系。黔中隆起褶皱平缓,断裂活动弱,利于印支期及以前所形成的原生油气藏的保存。黔中隆起的下寒武统烃源岩特别是牛蹄塘组烃源岩比麻江地区古油藏烃源岩发育程度高,震旦系和寒武系白云岩为良好储层,下寒武统泥岩及中上寒武统的膏盐岩可作为直接盖层及区域盖层;再加上该区相对稳定的构造保存条件,只要现今地表淡水下渗的深度不足以沟通深层原生油气藏并使之遭受完全破坏,该区就可能成为中国南方海相下组合石油和天然气勘探的重要地区之一。     

川东南下寒武统牛蹄塘组烃源岩特征及有效性分析

通过地球化学分析、储层沥青薄片镜下鉴定,对川东南下寒武统牛蹄塘组烃源岩宏观特征以及微观地球化学特征进行深入研究,并以震旦系灯影组古油藏为例分析了烃源岩的有效性。结果表明,牛蹄塘组烃源岩厚度稳定,底部暗色泥页岩分别厚约25m-43m,平均有机碳含量介于0．5％-1．0％,现今已达过成熟阶段,为中等烃源岩。牛蹄塘组泥页岩是灯影组古油藏的主要烃源岩,古油藏原油裂解气是灯影组气藏成藏的物质基础。     

江南-雪峰山推覆体前缘沥青古油藏及油源对比

在江南-雪峰山推覆体前缘,下古生界中分布着一系列沥青古油藏。经野外实地观察调查,发现其主要赋存特征有：裂隙型炭沥青、溶洞-孔隙型沥青、裂隙-背斜型沥青、背斜-岩性复合型炭沥青。经过对所采集样品进行地球化学特征综合分析,认为本地区的有机质成熟度较高,并经受多期改造演化。油源对比结果显示,其主要来源于下寒武统的烃源,其次为下志留统的烃源。这一地区的沥青古油藏是一种多源多期成因,并经历了后期强烈改造。     

黔中隆起及其周缘地区“下组合”油气地质特征

黔中隆起及其周缘地区包括滇黔北部坳陷、黔中隆起、滇东隆起、黔西南坳陷、黔南坳陷和武陵坳陷等六个一级构造单元。“下组合”包括震旦系、寒武系、奥陶系和志留系,具有丰富的油气资源和较好的油气成藏条件。两套区域性海相烃源岩,包括下寒武统牛蹄塘组碳质页岩和上奥陶统五峰组—下志留统龙马溪组石灰岩和碳质页岩,Ro值普遍在2%以上,主体处于高成熟晚期—过成熟早期。上震旦统陡山沱组发育地区性黑色页岩和碳质灰岩等烃源岩。主力储层包括上震旦统灯影组、中—上寒武统、下奥陶统桐梓组—红花园组及下志留统石牛栏组。区域盖层发育于下寒武统下部和下志留统下部,皆以泥质岩为主。各区块海相“下组合”纵向生储盖组合发育情况有所差异,黔中隆起区和黔南坳陷有两套组合,滇黔北部坳陷则有四套组合。以下寒武统牛蹄塘组为烃源岩、上震旦统灯影组白云岩为储层、下寒武统泥岩为盖层的生储盖组合,是黔中隆起及其周缘地区“下组合”勘探的主要目的层系。     

从塔里木盆地看中国海相生油问题

塔里木盆地厚达 5～ 7km的海相寒武、奥陶系 ,可划分出下、中寒武统和中、上奥陶统两套工业性烃源岩。油源对比证实 :盆地目前保存下来的海相成因工业性油藏 ,主要来源于中上奥陶统泥灰岩。正是因为塔里木盆地比四川、鄂尔多斯盆地多了一套中等成熟的中上奥陶统油源岩 ,所以能够找到海相油田。笔者认为 :海相工业性烃源岩不必很厚 ,但w (TOC)应≥0 .5% ,碳酸盐岩要含泥质 ;海相源岩往往并不发育在凹陷中心 ,而发育在 4种有利沉积相带上 ;碳酸盐岩具有“双重母质”的特点 ,浮游藻类偏油 ,底栖藻类偏气。海相源岩的形成模式有“保存模式”和“生产力模式”两种 ,分别对应于塔里木寒武系和中上奥陶统烃源岩。塔里木古生代克拉通早期活动、晚期稳定、持续降温的演化史 ,有利于海相油气的多期成藏和晚期保存。     

中国南方海相生烃成藏研究的若干新进展(一) 南方四套区域性海相烃源岩的分布

通过对上、中、下扬子区121个地表及钻井剖面烃源岩的密集扫描取样和地化分析,系统研究了下寒武统、上奥陶统—下志留统、上二叠统、下二叠统四套区域性海相烃源岩的厚度及有机质丰度的纵横向分布,明确了海相烃源岩在纵向上以下寒武统和上二叠统为最好,横向上以上扬子区为最好,其次为下扬子区;确定了五个烃源岩发育区。明确了海相烃源岩以泥岩为主,碳酸盐岩烃源岩只出现在下二叠统栖霞组—茅口组,实测最大厚度为150m,从而表明中国南方不存在上千米厚的碳酸盐岩烃源岩。对四套海相烃源岩的厚度问题、层位问题、原始生烃潜量和碳酸盐岩烃源岩的鉴别问题等提出了认识。     

X. The Eucla Basin in South Australia

At some time prior to the Ptychagnostus gibbus Zone of the Middle Cambrian the area of deposition of Upper Precambrian (or Lower Cambrian) well‐sorted sands, silts and dolomite was affected by tectonic movements producing uplift of the Tyennan Geanticline and change in the shape of the depositional basin (Spry, Chapter I). Continued tectonic activity and more rapid sinking of the sea floor resulted in a change in sedimentary association from well‐sorted sediments of the orthoquartzite‐limestone suite to poorly sorted sediments of the greywacke suite. Initially siltstone was the main deposit in the Dundas, Huskisson River, Ulverstone, Deloraine and Beaconsfield areas and this has been likened to the initial euxinic phase of geosynclinical development elsewhere (Campana, 1961b).

Silt seems to have been the predominant normal deposit during the Middle and early Upper Cambrian, but siliceous oozes and some limestone were also formed. Carbonaceous, pyritic and calcareous silts were deposited. Inter‐bedded with the silts are poorly‐sorted greywackes and greywacke conglomerates with a disrupted framework and graded bedding. Banks and Jennings interpret these as mostly turbidity current deposits. The proportion of greywacke and conglomerate varies through the successions in a cyclic manner (Carey and Banks, 1954; Banks, 1956) such that a conglomerate‐rich section is followed by a greywacke‐rich section and this by a predominantly lutaceous section. These cycles may be interpreted as due to tectonic instability and variation in height of the source area. Faulting of Upper Middle Cambrian and Lower Dresbachian age has been demonstrated near Ulverstone. Campana and King state: “The proportion of coarse material increases upwards in the Dundas and Huskisson successions at least.”

Turbidity currents brought fragments of grey, red, black and banded cherts, banded slate, quartzite, basalt and golden mica (this last presumably from breakdown of Precambrian mica schist) to the Dundas area. In view of the known distribution of chert in western Tasmania a westerly or north‐westerly source is likely. Turbidity currents deposited fragments of chert, claystone, quartzite, slate, greywacke, quartz mica schist, chloritised basic lava and spilite in the Deloraine area indicating a source area with Precambrian rocks and earlier Cambrian sediments and lavas. Near Rocky Boat Harbour the source area contained dolomite, ultrabasic rocks, granite, and Precambrian quartzites and schists.

A difference between the fauna in the silts and in the greywackes is evident in the Hodge Slate at Dundas and the Kateena Formation near Ulverstone at least. The “dendroids” in the Hodge Slate are in the siltstone and the fragmentary trilobites and cystoids in the greywacke. This suggests that the fossils in the greywackes are thanatocoenotic as might be expected and introduces the possibility of remanié fossils and of shallow water fauna intercalated with deeper water fauna. The bathymetric conditions suggested by Hills and Thomas (1954) for the Cambrian of Victoria may thus not be applicable to Tasmania.

Deposition was also interrupted from time to time by lava flows, some of them, at least, submarine. The Mt. Read Volcanics may be Lower Cambrian but acid and basic lavas and pyroclastic rocks are interbedded with or overlie Middle and Upper Cambrian sediments at Zeehan, Dundas, Ulverstone, Smithton and Beaconsfield. Acid volcanic rocks are commoner near the Tyennan Geanticline and basic rocks further away. Possibly during the Dresbachian ultrabasic rocks were intruded as sheets and dykes into Precambrian and earlier Cambrian rocks and by Franconian time were exposed to erosion at Adamsfield.

Deposition may have commenced later at Smithton (Upper Middle Cambrian), Beaconsfield (Lower Dresbachian) and Adamsfield (Lower Franconian) than at Dundas (Lower Middle Cambrian).

Campana and King express the thoughts of Bradley (1957, pp. 114–115) and the author when they state: “The Dundas Group reflects a eugeosynclinical cyclic sedimentation under unstable tectonic conditions. The group is no doubt a synorogenic suite comparable with the Flysch as it was deposited in the narrow subsiding Dundas Trough which developed along the Mt. Read Volcanic Arc, and which is similar to the present deeps of archipelago areas. Such a comparison is enhanced by the succeeding Ordovician conglomerates and sandstones, comparable in some respects with the molassic deposits which displaced the Flysch sedimentation in the Pre‐Alpine troughs (Fig. 12).”

The Cambrian rocks were folded or tilted at least along the western and northern margin of the Tyennan Geanticline and near New River Lagoon, the Tyennan Geanticline was rejuvenated, the Asbestos Range Geanticline raised and the highland areas near Ulverstone and Zeehan uplifted late in the Cambrian or very early in the Ordovician.     

江汉盆地海相探区中寒武统盐下层勘探潜力浅析

江汉海相探区内中寒武统覃家庙组膏盐岩盐下层系中发育有两套良好的生储盖组合.对盐下层系生、储、盖特点和分布规律的分析表明,上震旦统陡山沱组及下寒武统水井沱组发育页岩烃源岩,上震旦统灯影组碳酸盐岩和下寒武统石龙洞组碳酸盐岩有良好的储集条件,而覃家庙组的膏盐岩和下寒武统石牌组-天河组泥质岩又为盐下的油气聚集提供了区域性盖层条...     

扬子地区古生代主要烃源岩有机质富集的环境动力学机制与差异

在扬子地块古生界发育了3套区域性的优质烃源岩,即:下寒武统、上奥陶统一下志留统、二叠系(中、上二叠统).下寒武统烃源岩主要由硅质岩(留茶坡组)和上部的硅质泥岩、碳质泥岩(或石煤)(牛蹄塘组)组成.早寒武世在台一盆转换带(或台地边缘)广泛发育的海底热液活动,喷流出大量的富硅流体,使大量硅岩得以在台缘外侧-盆地区沉淀;同时...     

贵州黄平凹陷下古生界油气勘探潜力

黄平凹陷上震旦统—三叠系为碳酸盐岩与碎屑岩交互沉积,厚度达5000～6000m,曾具有较好的油气成藏过程。主要有三套烃源岩,即震旦系陡山沱组黑色碳质泥页岩,为"好"烃源岩;下寒武统九门冲组炭质泥页岩和灰岩,以及下寒武统变马冲组—耙榔组泥页岩、炭质泥岩,均为"较好"烃源岩。含油气层主要为下寒武统九门冲组石灰岩、变马冲组—耙榔组砂岩、志留系翁项群二段砂岩和三段泥岩中的砂岩夹层。盖层分布广,厚度大,封盖性好。生储盖组合重复出现,油源、构造的配置关系很好,具有较好的油气保存条件。近期的浅层地震资料表明,虎庄背斜和鱼洞向斜分别可是寻找深层天然气和浅层油气的远景构造。     

生物标志化合物在地层划分与对比中的应用——以塔里木盆地下古生界为例

生物标志化合物是指沉积岩或原油和煤中碳—碳骨架稳定的特征化合物 ,它通常是用于油源对比和古沉积环境的恢复。本次研究在地层划分与对比中尝试利用正常甾烷分布的差异 ,研究表明 ,塔里木盆地寒武系—下奥陶统和中上奥陶统的甾烷分布特征完全不同 :前者的 C2 8甾烷含量高于后者 ,正常甾烷的分布是 C2 9>C2 8>C2 7,呈反“L”型分布 ;后者的 C2 7甾烷含量高于前者 ,甾烷的分布是 C2 9>C2 7>C2 8,呈“V”字型分布。寒武系—下奥陶统和中上奥陶统甾烷分布由反“L”型变为“V”型 ,说明生物在演化过程中 ,有机质的来源及化学结构组成发生了明显变化 ,据此可用于塔里木盆地下古生界的地层划分与对比。     

Early Paleozoic orogeny in southern South America

In northwest Argentina, weakly metamorphic clastic and calcareous sedimentary rocks of latest Precambrian to Lower Cambrian age (Puncoviscana Formation and related units) contain an abundant ichnofauna of both chronostratigraphic and paleoenvironmental value. In the western and central Sierras Pampeanas, metasedimentary and metavolcanic rocks are considered to form part of the same geotectonic unit. This “Pampean orogenic cycle” includes geosynclinal sedimentation of latest Precambrian to Lower Cambrian age, as well as magmatism, metamorphism and deformation of Middle to Upper Cambrian age, documented by an angular unconformity below the Upper Cambrian to Devonian rocks of the “Famatinian orogenic cycle”. In some of the metamorphic rocks of the Pampean Cycle a pre-Ordovician folding is also distinguished from a later tectonic overprinting. Hence, the concept of a Pampean cycle differs from other concepts of late Precambrian orogenic cycles of South America which are only defined by radiometric ages. The Pampean orogenesis may be compared with the Ross orogenesis of the Transantarctic Mts., the Tyennan orogenesis of Australia and some of the deformation phases of the Damara orogen in Namibia.     

塔中隆起海相碳酸盐岩大型凝析气田成藏特征与勘探

多次资评与勘探实践表明塔中隆起成藏条件优越,海相碳酸盐岩油气资源丰富,奥陶系油气藏集中赋存于上奥陶统礁滩体与下奥陶统风化壳储层中,缝洞系统控制了大型凝析气藏纵向多套叠置-横向准层状分布规律。多学科、动静态一体化研究表明,形成塔中海相碳酸盐岩大型凝析气田主力烃源岩为寒武-奥陶系两套碳酸盐岩,原油具有明显的混源特征,天然气主要来源于中-下寒武统高成熟度原油裂解气。奥陶系海相碳酸盐岩凝析气藏是古油藏在喜山期被寒武系来源的原油裂解气气侵的结果,经历了三期成藏过程,即中晚加里东期、晚海西期原油充注,喜山期注气。两套烃源岩长期供烃是形成塔中奥陶系海相碳酸盐岩大型凝析气田的物质基础,构造作用、岩溶作用是形成了塔中奥陶系多套优质碳酸盐岩储集体的主控因素,断裂、不整合面、缝洞发育带构建的网状油气输导体系是塔中海相碳酸盐岩复式聚集混源成藏的重要保障。塔中奥陶系海相碳酸盐岩具备10亿吨当量的油气资源潜力。