The electrical conductivity of Posidonia black shales — from magnetotelluric exploration to rock samples

We carried out a magnetotelluric field campaign in the South–East Lower Saxony Basin, Germany, with the main goal of testing this method for imaging regional Posidonia black shale sediments. Two‐dimensional inversion results of the magnetotelluric data show a series of conductive structures correlating with brine‐saturated sediments but also with deeper, anthracitic Westphalian/Namurian coals. None of these structures can be directly related with the Posidonia black shale, which appears to be generally resistive and therefore difficult to resolve with the magnetotelluric method. This assumption is supported by measurements of electrical resistivity on a set of Posidonia shale samples from the Hils syncline in the Lower Saxony basin. These rock samples were collected in shallow boreholes and show immature (0.53% Ro), oil (0.88% Ro), and gas (1.45% Ro) window thermal maturities. None of the black shale samples showed low electrical resistivity, particularly those with oil window maturity show resistivity exceeding 10⁴ Ωm. Moreover, we could not observe a direct correlation between maturity and electrical resistivity; the Harderode samples showed the highest resistivity, whereas the Haddessen samples showed the lowest. A similar trend has been seen for coals in different states of thermal maturation. Saturation of the samples with distilled and saline water solutions led to decreasing electrical resistivity. Moreover, a positive correlation of electrical resistivity with porosity is observed for the Wickensen and Harderode samples, which suggests that the electrical resistivity of the Posidonia black shale is mainly controlled by porosity.     

Increasing the effectiveness of electrical resistivity tomography using γ11n configurations

A new array type, i.e., the γ_11n arrays, is introduced in this paper, in which the sequence of the current (C) and potential (P) electrodes is CPCP, and the distance between the last two electrodes is n times the distance between the first two ones and that of the second one and the third one. These arrays are called quasinull arrays because they are—according to their array and behaviour—between the traditional and null arrays. It is shown by numerical modelling that, in detecting small‐effect inhomogeneity, these configurations may be more effective than the traditional ones, including the optimized Stummer configuration. Certain γ_11n configurations—especially the γ₁₁₂, γ_113, and γ₁₁₄—produced better results both in horizontal and vertical resolution investigations. Based on the numerical studies, the γ_11n configurations seem to be very promising in problems where the anomalies are similar to the numerically investigated ones, i.e., they can detect and characterize, e.g., tunnels, caves, cables, tubes, abandoned riverbeds, or discontinuity, in a clay layer with greater efficacy than those of the traditional configurations. γ_11n measurements need less data than traditional configurations; therefore, the time demand of electrical resistivity tomography measurements can be shortened by their use.     

W. A. Battaglin, ‘Chemical and isotopic evidence of nitrogen transformation in the Mississippi River, 1997‐98’ Hydrological Processes 15(7) 2001, 1285–1300.

The original article to which this Erratum refers was published in Hydrological Processes 15(7) 2001, 1285–1300