Revisiting the deforestation-induced EKC hypothesis: the role of democracy in Bangladesh

GeoJournal - This paper aimed at evaluating the validity of the deforestation-induced Environmental Kuznets Curve hypothesis controlling for the democracy between 1971 and 2018 in Bangladesh. The...     

Review: the environmental status and implications of the nitrate time lag in Europe and North America

The efficacy of water quality policies aiming to reduce or prevent nitrate contamination of waterbodies may be constrained by the inherent delay or “time lag” of water and solute transport through unsaturated (soil) and saturated (groundwater) pathways. These delays must be quantified in order to establish realistic deadlines, thresholds and policy expectations, and to design effective best management practices. The objective of this review is to synthesise the current state of research on nitrate-related time lags in both the European and North American environmental and legislative contexts. The durations of time lags have been found to differ according to climatic, pedological, landscape and management scenarios. Elucidation of these driving factors at a watershed scale is essential where water quality is impaired or at risk. Finally, the existence of time lags is increasingly being acknowledged at a policy level and incorporated into the development of environmental legislation. However, the full impact of these time lags is not yet fully understood or appreciated, and continued outreach and education in scientific, public and policy venues is still required.     

Variations of the Effective Temperature Index (ET) in Kenya

Using the Effective Temperature Index (ET) as a measure of climatic comfort conditions in Kenya, this study analyses its spatial, seasonal and diurnal variations. This index is computed using data collected from 57 weather stations spread throughout the country. Isarithmic mapping technique and the conditioning square method are used in this analysis. The results indicate that there exists in Kenya marked spatial, seasonal and diurnal variations of climatic comfort conditions. A classification of the country using this index and the Terjung (1968) system of climatic classification yields six climatic comfort zones. This type of physio-climatic studies has significant implications for Kenya in aspects such as building, clothing, recreation and sporting. This revised version was published online in July 2006 with corrections to the Cover Date.     

Estimating groundwater recharge using GIS-based distributed water balance model in an environmental protection area in the city of Sete Lagoas (MG), Brazil

Improvement in modern water resource management has become increasingly reliant on better characterizing of the spatial variability of groundwater recharge mechanisms. Due to the flexibility and reliability of GIS-based index models, they have become an alternative for mapping and interpreting recharge systems. For this reason, an index model by integrating water balance parameters (surface runoff, actual evapotranspiration, and percolation) calculated by Thornthwaite and Mather’s method, with maps of soil texture, land cover, and terrain slope, was developed for a sustainable use of the groundwater resources. The Serra de Santa Helena Environmental Protection Area, next to the urbanized area of Sete Lagoas (MG), Brazil, was selected as the study area. Rapid economic growth has led to the subsequent expansion of the nearby urban area. Large variability in soil type, land use, and slope in this region resulted in spatially complex relationships between recharge areas. Due to these conditions, the study area was divided into four zones, according to the amount of recharge: high (>?100 mm/year), moderate (50–100 mm/year), low (25–50 mm/year), and incipient (>?25 mm/year). The technique proved to be a viable method to estimate the spatial variability of recharge, especially in areas with little to no in situ data. The success of the tool indicates it can be used for a variety of groundwater resource management applications.     

Assessment of suspended particulate pollution in the Bhadra River catchment,Southern India: an environmental magnetic approach

Open-cast mining generates sediment in river systems at globally significant scales. One of the challenges in attributing measured sediment loads to upstream mining activities is establishing the source of sediments that are a mixture of natural and mining-based materials. The environmental magnetic data (mass-specific magnetic susceptibility, anhysteretic remanent magnetisation, isothermal remanent magnetisation and inter-parametric ratios) on 57 samples of suspended sediment from the Bhadra River in the Sahyadri (the Western Ghat) of India have been used in this study. Samples were collected upstream, adjacent to and downstream of Kudremukh, a mountainous and high rainfall site where the largest mechanised open-cast mine in south Asia was located. Graphical and multivariate analyses and modelling of the data show that on average ~29% of the river suspended load downstream of the mine is derived from mining and allied activities at Kudremukh although the mine occupies less than 5% of the catchment. The contribution of primary ore is the maximum (18%), followed by transitional hard weathered ore (7%) and weathered ore (4%). The model has done a fairly good job of unmixing; the sum of errors is <1 for 40 samples, 1–4,254 for five samples and >71,000 for four samples. Modelling of samples with small mass seems to produce large errors. This investigation demonstrates the utility of environmental magnetic data, which can be obtained in a simple and rapid manner, and the unmixing of such data in identifying the contribution of mining activities to the total suspended sediment load.     

Assessment of erosion damage in Ndome and Ghazi, Taita Taveta, Kenya: Towards an integrated erosion management approach

Aerial photograph interpretation on erosion trends from 1961 to 1998 showed that by 1998, approximately 17 and 50% of agricultural land in Ndome and Ghazi respectively had been permanently lost due to the combined effect of rill, inter-rill, and gully erosion, and sand deposition. Although abnormally heavy rains received between 1996–98 caused much of the present land damage, the severity of the damage was enhanced by inappropriate and persistent human perturbations in the land-system notably through vegetative degradation and destruction of soil structure through inappropriate tillage practices. With soil organic matter contents of 1.6 and 1.9%, and clay ratios of 10.1 and 10.6 for Ndome and Ghazi, respectively, the areas inherent erodibility was considered as high thus pointing to the need for careful use and management of the soil resource. That farmers appreciated only land quality indicators that were visible to the naked eye and that directly affected their subsistence, revealed a knowledge gap that saw damages from intrinsic processes like rill and inter-rill erosion proceed unnoticed. This paper argues that the spread of erosion damage in rural agro-ecosystems is survival-driven. And as a remedy to this problem, there is need for the diversification of livelihood endeavours to alternative off-farm income sources to reduce pressure on the already fragile land resource. Further, being the ultimate implementers of conservation technologies and by virtue of the multiplicity and inter-relation of rural household needs, adoption of an integrated erosion management approach with food security as paramount presents the most practical entry point for sustainable land management in such rural agro-ecosystems. This revised version was published online in July 2006 with corrections to the Cover Date.     

Geometry and growth of an inner rift fault pattern: the Kino Sogo Fault Belt, Turkana Rift (North Kenya)

A quantitative analysis is presented of the scaling properties of faults within the exceptionally well-exposed Kino Sogo Fault Belt (KSFB) from the eastern part of the 200-km-wide Turkana rift, Northern Kenya. The KSFB comprises a series of horsts and grabens within an arcuate 40-km-wide zone that dissects Miocene–Pliocene lavas overlying an earlier asymmetric fault block. The fault belt is 150 km long and is bounded to the north and south by transverse (N50°E and N140°E) fault zones. An unusual feature of the fault system is that it accommodates very low strains (<1%) and since it is no older than 3 Ma, it could be characterised by extension rates and strain rates that are as low as 0.1 mm/yr and 10⁻¹⁶ s⁻¹, respectively. Despite its immaturity, the fault system comprises segmented fault arrays with lengths of up to 40 km, with individual fault segments ranging up to 9 km in length. Fault length distributions subscribe to a negative exponential scaling law, as opposed to the power law scaling typical of other fault systems. The relatively long faults and segments are, however, characterised by maximum throws of no more than 100 m, providing displacement/length ratios that are significantly below those of other fault systems. The under-displaced nature of the fault system is attributed to early stage rapid fault propagation possibly arising from reactivation of earlier underlying basement fabrics/faults or magmatic-related fractures. Combined with the structural control exercised by pre-existing transverse structures, the KSFB demonstrates the strong influence of older structures on rift fault system growth and the relatively rapid development of under-displaced fault geometries at low strains.     

Determination of the solubility products of sodium carbonate minerals and an application to trona deposition in Lake Magadi (Kenya)

The ion-interaction model of PITZER (1973), is very effective in deriving stability relationships at high concentrations for the system Na-Cl-HCO₃-CO₃-OH-H₂O. The solubility products of the main sodium carbonates have been calculated from solubility data between 5 and 50°C. The stability diagram in log p_co2 — temperature coordinates and the invariant points deduced from the newly determined data are in good agreement with the most recent measurements.These results are used to calculate the activities of the major dissolved species in Lake Magadi brines (Kenya). The thermodynamic treatment confirms the main conclusions reached earlier by Eugster (1970, 1980) mainly from field observations. Trona precipitation occurs at equilibrium while natron is likely to form when the temperature decreases below 25°C. After the salt deposition the CO₂ supply from the atmosphere is too slow to allow equilibrium between the atmosphere and the brines. In the next stages of evaporative concentration thermonatrite and halite precipitate. The deposition of the latter salts along with the observed HCO^?₃ depletion suggest that fractional crystallization is likely to control trona deposition.     

Investigating the redox sensitivity of para-toluenesulfonamide (p-TSA) in groundwater

The groundwater downstream of a former sewage irrigation farm in Berlin is contaminated with ammonium (NH₄ ⁺) and para-toluenesulfonamide (p-TSA), besides other anthropogenic pollutants. In the field, in situ removal of NH₄ ⁺ by gaseous oxygen (O₂) and air injection is currently being tested. A laboratory column experiment using aquifer material and groundwater from the site was performed to determine whether this remediation technology is also feasible to reduce high p-TSA concentrations in the anoxic groundwater. First, the column was operated under anoxic conditions. Later, compressed air was introduced into the system to simulate oxic conditions. Samples were collected from the column outlet before and after the addition of compressed air. The experiment revealed that whereas p-TSA was not removed under anoxic conditions, it was almost fully eliminated under oxic conditions. Results were modelled using a transient one-dimensional solute transport model. The degradation rate constants for p-TSA increased from 2.8E−06 to 7.5E−05 s^–1 as a result of microbial adaption to the change of redox conditions. Results show that O₂ injection into an anoxic aquifer is a successful strategy for p-TSA remediation.     

On the presence of hydrous defects in differently coloured wulfenites (PbMoO4): an infrared and optical spectroscopic study

Several samples of wulfenite, PbMoO₄, varying in colour from colourless to yellow, orange and red, have been characterised by means of IR and optical absorption spectroscopy and by microprobe analyses. A distinct pleochroic band group with absorption maxima centred at 3,380 and 3,150 cm^?1 can be seen in the IR spectra of wulfenite single-crystals, indicating the presence of hydroxyl groups. The pleochroic and thermal behaviour of the OH stretching bands along with deuteration experiments, as well as results obtained from synthetic flux-grown samples, exclude the presence of submicroscopic hydrous mineral inclusions as their primary origin. The pleochroic scheme and the band positions were used to postulate a model for the OH incorporation mode, based on the assumption of vacancies on Mo and Pb sites in the structure of this ‘nominally anhydrous mineral’. Optical absorption spectra of coloured natural samples show a broad and polarised band around 23,000–24,000 cm^?1, preceding the fundamental UV absorption edge, which has been identified as the reason for the colour of the mineral. The comparison with synthetic PbMoO₄ single-crystals, doped with variable amounts of Cr⁶⁺, yielded conclusive evidence that trace amounts of the CrO₄ ^2? anion group, substituting for MoO₄ ^2?, determine the variable colour. Besides, in one sample, trace amounts of Nd³⁺ have been spectroscopically identified.     

New evidence for the presence of reindeer (Rangifer tarandus) on the Iberian Peninsula in the Pleistocene: an archaeopalaeontological and chronological reassessment

Reindeer (Rangifer tarandus) populations reached the Iberian Peninsula during the end of the Middle Pleistocene and there are numerous examples of this species from Late Pleistocene Mousterian and Upper Palaeolithic sites. In this paper, new evidence of reindeer in the east Cantabrian region is presented that further supports the timing of this species’ first appearance, and previous assessments are updated. To date, the presence of this species has been identified at 55 sites in the Iberian Peninsula, nearly as many as those of mammoth (Mammuthus primigenius) and woolly rhinoceros (Coelodonta antiquitatis) combined. Most of the sites with presence of reindeer (50) are located in the Cantabrian region with a clear increase in the density of sites and remains towards the Pyrenees. The remaining five sites with evidence of reindeer are located on the other side of the Pyrenees in the NW corner of Catalonia. In contrast, archaeological evidence of reindeer in the form of art (both parietal and portable) is more scarce and scattered. Evidence for the representation of these animals has been found outside the northern fringe of the Iberian Peninsula, which could reflect either long‐distance cultural communication or the movement of human groups.     

Contained (reflected) turbidity currents from the Middle Ordovician Cloridorme Formation, Quebec, Canada: an alternative to the antidune hypothesis

The parautochthonous Cloridorme Formation is a syn-orogenic flysch succession that was deposited in an elongate foredeep basin as mainly lower middle-fan, outer-fan, and basin-floor deposits. The basin-floor deposits (about 1.5 km thick) are confined to members β1, β2 and γ1, and are characterized by graded, thick (1–10 m) mud-rich calcareous greywacke beds previously interpreted as deposits of concentrated, muddy, unidirectional turbidity currents that locally generated backset (antidune) lamination in internally stratified flows. The dominant flow directions were from east to west, but west to east transport also occurred, as seen in the orientation of ripples, climbing ripples, flutes, consistently overturned flames, and grain imbrication. We believe that the flows that deposited these thick calcareous greywacke beds reversed by roughly 180° one or more times during deposition of the lower sandy part of the beds. Flow reversals are consistent with the sharp grain-size breaks and mud partings within sandy divisions. Measurement of grain fabric relative to stratification in the most celebrated ‘antidune’ bedforms indicates flow from west to east; thus, the bedforms were produced by west-to-east migration of megaripples, not by the upcurrent migration of antidunes. The thick muddy beds were deposited by large-volume, muddy flows that were deflected and reflected from the side slopes and internal topographic highs of a confined basin floor, much like the ‘Contessa’ and similar beds of the Italian Apennines. Large quantities of suspended mud were ponded above the irregular basin floor and settled to produce the thick silty mudstone caps seen on each bed. Because of their mode of emplacement, we propose that these beds be called contained turbidites.     

Hydrochemistry of superficial waters in the Adoria mine area (Northern Portugal): environmental implications

The purpose of this work is to characterize the hydrochemical behavior of acid mine drainages (AMD) and superficial waters from the Adoria mine area (Northern Portugal). Samples of superficial and mine drainage water were collected for one year, bi-monthly, with pH, temperature, Eh, conductivity and HCO₃ determined in situ with chemical analyses of SO₄, Ca, K, Mg, Na, Cl, Ag, As, Bi, Co, Cu, Fe, Mn, Ni, Pb, Zn and Cd. In the mine, there are acidic waters, with low pH and significant concentrations of SO₄, and metals (Fe, Mn, Zn, Cu, Pb, Cd and Ni), while in the superficial natural stream waters outside the mine, the pH is close to neutral, with low conductivity and lower metal concentrations. The stream waters inside the mine influence are intermediate in composition between AMD and natural stream waters outside the mine influence. Principal Component Analysis (PCA) shows a clear separation between AMD galleries and AMD tailings, with tailings having a greater level of contamination.     

Dissolution of cinnabar (HgS) in the presence of natural organic matter

Cinnabar (HgS) dissolution rates were measured in the presence of 12 different natural dissolved organic matter (DOM) isolates including humic, fulvic, and hydrophobic acid fractions. Initial dissolution rates varied by 1.3 orders of magnitude, from 2.31 × 10⁻¹³ to 7.16 × 10⁻¹² mol Hg (mg C)⁻¹ m⁻²s⁻¹. Rates correlate positively with three DOM characteristics: specific ultraviolet absorbance (R² = 0.88), aromaticity (R² = 0.80), and molecular weight (R² = 0.76). Three experimental observations demonstrate that dissolution was controlled by the interaction of DOM with the cinnabar surface: (1) linear rates of Hg release with time, (2) significantly reduced rates when DOM was physically separated from the surface by dialysis membranes, and (3) rates that approached constant values at a specific ratio of DOM concentration to cinnabar surface area, suggesting a maximum surface coverage by dissolution-reactive DOM. Dissolution rates for the hydrophobic acid fractions correlate negatively with sorbed DOM concentrations, indicating the presence of a DOM component that reduced the surface area of cinnabar that can be dissolved. When two hydrophobic acid isolates that enhanced dissolution to different extents were mixed equally, a 20% reduction in rate occurred compared to the rate with the more dissolution-enhancing isolate alone. Rates in the presence of the more dissolution-enhancing isolate were reduced by as much as 60% when cinnabar was prereacted with the isolate that enhanced dissolution to a lesser extent. The data, taken together, imply that the property of DOM that enhances cinnabar dissolution is distinct from the property that causes it to sorb irreversibly to the cinnabar surface.     

A multi-method approach for the characterization of landslides in an intramontane basin in the Andes (Loja,Ecuador)

In the last several decades, population growth in the cities of the Andes has caused urban areas to expand into landslide-prone areas. Fatal landslides affecting urban settlements are especially frequent in cities located in the Neogene intramontane basins of the Andes. These basins have similar situations and include geographical and geological features that frequently generate ground instabilities. We studied the characteristics of the mass movements observed in these basins by carrying out a detailed analysis of four landslides that have occurred in the Loja Basin (Ecuador). This multi-method study integrated geophysical, geotechnical methods, mineralogical studies and analyses of precipitation time series. Our study characterizes the slope movements as active, slow-moving, complex earthslide earthflows. According to Differential GPS measurements, these landslides move at velocities of up to several metres per year. Electrical resistivity tomography profiles show that most of the landslides are mainly surficial. Time-series analyses of precipitation reveal that rainfall events that are not exceptionally intensive can reactivate these landslides. This characteristic and the development of these landslides on low-gradient slopes are explained using the results obtained from the geotechnical and mineralogical analyses. We find that the smectite clay minerals detected in the mobilized geological formations, combined with the tropical climate of the northern Andean region, induce the observed weak slope stability conditions. The conceptual model for the studied landslides may aid in assessing landslide-prone areas in Loja and other Neogene intramontane basins of the Andes and can help to mitigate the associated risks.     

Measuring the accessibility of critical facilities in the presence of hurricane-related roadway closures and an approach for predicting future roadway disruptions

Natural Hazards - Roadway closures magnify the adverse effects of disasters on people since any type of such disruption increases the emergency response travel time (ERTT), which is of central...     

Uranium(VI) sorption to hematite in the presence of humic acid

A long-standing problem in aquatic geochemistry has been the incorporation of natural organic matter (NOM) into speciation models. The general effect of NOM on metal ion sorption by particles has been understood for some time, and significant progress has been made in elucidating some of the details of the role of NOM through the use of surrogate organic acids such as citric acid. However, a gap exists between the general observations that have been made of NOM behavior and the inclusion of NOM in surface chemical models for metal ion sorption. In this paper, we report on the results of a study on the sorption of U(VI) by hematite in the absence and presence of Suwannee river humic acid (HA) and over a range of other system conditions (e.g., pH, I). Essential HA characteristics (e.g., its acid/base, metal binding, and surface chemical properties) were “captured” by representing the HA as an assembly of monoprotic acids with assumed pK values and without explicit correction for electrostatic effects. The ternary system (hematite/HA/U(VI)) was simulated through the combination of the binary submodels (i.e., CO₃²⁻/hematite, U(VI)/HA, U(VI)/hematite, and HA/hematite) with model constants fixed at the values determined from simulations of the respective experimental systems. However, the “summed-binary” approach undersimulated experimental results, and the ternary system model required the postulation of two ternary surface (Type A) complexes composed of the uranyl ion, hematite surface sites, and the model ligands comprising the HA. Consideration of the HA in this manner permitted the simulation of HA effects on U(VI) sorption by hematite over a range of solution conditions using a general speciation model.     

Mediation agreement to resolve an environmental conflict and its social implications: the case of Wadi Zalmon (Israel National Park)

Mediation refers to an informal process in which a neutral third party helps parties in conflict attain an agreement which they were unable to reach on their own. It is mainly used to solve social, economic and political problems, but its characteristics allow using it to resolve also environmental disputes. The purpose of this article is to examine over a period of time the different attitudes of some groups of populations (communities, municipalities and governmental authorities) toward mediation agreement and its implications. The agreement was signed for an area which was declared a National Park due to its unique landscape—characterized as a cultural landscape (a landscape which represents a combined works of nature and of man). Examination over time is intended to expose whether changes have taken place in the populations in respect to the agreement and its social and cultural influences on them. The paper is dealing with Wadi Zalmon, a stream flowing from east to west in Western Galilee, in the north part of Israel and its environs. In this declaration are involved many populations, which represent the multicultural distinctiveness of Israeli society: Christians, Moslems, Bedouins and Jews.     

Stratigraphy of the Koobi Fora Formation (Pliocene and Pleistocene) in the Ileret region of northern Kenya

Exposures of Pliocene and Pleistocene deposits in the Ileret region include all eight members of the Koobi Fora Formation and represent at least 533 m of section from the base of the Lonyumun Member to the top of the Chari Mb. This thickness is more than twice that reported by earlier workers (∼260 m) and compares well with the composite section of the Koobi Fora Formation (525 m). Thus the Ileret region provides a very complete and representative outcrop of the Koobi Fora Formation. As Koobi Fora Formation member boundaries are placed at the base of specified tuffs, not all member boundaries can be recognized in the Ileret region. For this reason, the stratigraphy is described in terms of the following members (thicknesses in parentheses): Lonyumun (110 m), undifferentiated Moiti and Lokochot (104 m), Tulu Bor (54 m), Burgi (55 m), KBS (74 m), Okote (45 m), and Chari (93 m). Moreover, the boundary between the Okote Member and the KBS Member in the Ileret region is placed at a prominent caliche which must closely approximate the age of the Okote Tuff in its type section.