Incremental growth of a large volume,chemically zoned magma body: a study of the tephra sequence beneath the Rainier Mesa ash flow sheet of the Timber Mountain Tuff

The Rainier Mesa ash-flow is a large (1200 km³), 11.6 My old, chemically zoned unit that ranges in composition from 55 to 76% SiO₂ — one of the largest chemical ranges ever observed in a large volume ash-flow sheet. Two chemical trends occur in this sheet, a low silica (55–66% SiO₂) and a high silica (>66% SiO₂) trend. Ninety per cent of the Rainier Mesa sheet occurs in the high silica trend. Immediately beneath the Rainier Mesa sheet is a thick tephra sequence. The chemical variation of this sequence is nearly equivalent to the high silica portion of the Rainier Mesa ash-flow sheet (about 66–78% SiO₂). Throughout the tephra sequence numerous small ash-flow layers occur, and each ash-flow layer is chemically zoned from more evolved at the base to less evolved at the top. This is consistent with having been erupted from a zoned magma body. The lowest silica tephra units are at the base of the sequence and the highest silica units are at the top — that is, the large-scale chemical trend of the entire sequence is opposite to that of the individual ash-flow layers. These ash-flow layers are of very small volume. The tephra sequence provides a unique record of the incremental development of the zoned, high silica portion of the Rainier Mesa magma body.     

Evidence for magma hybridization for the voluminous 29.5 Ma Wah Wah Springs Formation, Utah and Nevada, U.S.A.

The 29.5 Ma Wah Wah Springs Formation which erupted from the Indian Peak Caldera has an estimated volume of > 3900 km³ making it one of the largest ignimbrites on earth. The magma was calc-alkaline, dacitic (68 wt. % SiO₂) and phenocryst-rich (38 vol.%). Phenocrysts include plagioclase (An 47), magnesio-hornblende, Mg-biotite, quartz, Fe-Ti oxides, diopsidic-augite, and rare Ca-poor pyroxene, in order of decreasing abundance. Apatite, zircon and pyrrhotite occurs as inclusions within phenocrysts. Atmospheric glass losses (1040 km³) account for bulk-rock compositions that have SiO₂ contents ranging from 63 to 67 wt.%. Glass compositions are high-silica rhyolite.Phenocrysts equilibrated at temperatures ranging from about 790 to 850°C and oxygen fugacities approximately 2.6 log units above the QFM buffer. Confining pressure estimates using the aluminum-in-hornblende geobarometer calibrated for calc-alkaline volcanic rocks suggest a mean pressure of 230±50 MPa corresponding to 7.5±1.5 km depth. These estimates are consistent with caldera formation accompanying emplacement.Crystal compositions for phenocrysts and mineral inclusions within phenocrysts are remarkably homogeneous throughout the outflow tuff, although minor zoning does occur. Given the dacitic composition of the magma, the weakly zoned phenocryst population cannot be modeled to produce the observed high-silica glass (melt) indicating open-system behavior for the magma. The high-silica rhyolite glass is interpreted to be an artifact of efficient magma mixing accompanying addition of highly evolved magma, or melt to intermediate composition magma. Mixing was followed by magma hybridization. Additional support for this hybridization model includes: (1) physically and chemically distinct populations of augite; (2) minor but unbiquitous resorbed plagioclase, biotite and hornblende phenocrysts; and (3) reverse zoning in some of the plagioclase euhedra within pumice lapilli.     

Origin of silicic volcanic rocks in Central Costa Rica: a study of a chemically variable ash-flow sheet in the Tiribí Tuff

Chemical heterogeneities of pumice clasts in an ash-flow sheet can be used to determine processes that occur in the magma chamber because they represent samples of magma that were erupted at the same time. The dominant ash-flow sheet in the Tiribí Tuff contains pumice clasts that range in composition from 55.1 to 69.2 wt% SiO₂. It covers about 820 km² and has a volume of about 25 km³ dense-rock equivalent (DRE). Based on pumice clast compositions, the sheet can be divided into three distinct chemical groupings: a low-silica group (55.1-65.6 wt% SiO₂), a silicic group (66.2-69.2 wt% SiO₂), and a mingled group (58.6-67.7 wt% SiO₂; all compositions calculated 100% anhydrous). Major and trace element modeling indicates that the low-silica magma represents a mantle melt that has undergone fractional crystallization, creating a continuous range of silica content from 55.1-65.6 wt% SiO₂. Eu/Eu*, MREE, and HREE differences between the two groups are not consistent with crystal fractionation of the low-silica magma to produce the silicic magma. The low-silica group and the silicic group represent two distinct magmas, which did not evolve in the same magma chamber. We suggest that the silicic melts resulted from partial melting of relatively hot, evolved calc-alkaline rocks that were previously emplaced and ponded at the base of an over-thickened basaltic crust. The mingled group represents mingling of the two magmas shortly before eruption. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-001-0188-8.     

Roof-rock contamination of magma along the top of the reservoir for the Bishop Tuff

The Bishop Tuff, a well known Quaternary high-silica rhyolite in east-central California, is widely considered the type example of a vertically and monotonically zoned pyroclastic deposit that represents zoning in the source magma reservoir, inverted during the process of pyroclastic emplacement. However, the deposit of plinian pumice, which forms the base of the Bishop Tuff and represents the initial 10% or so of all magma erupted during the event that produced the Bishop Tuff, contains features at odds with monotonie zoning for the reservoir. Relative to overlying ignimbrite, the plinian deposit contains a reversal in trace-element zoning. Moreover, the ⁸⁷Sr/⁸⁶Sr is significantly higher than that in overlying ignimbrite (about 0.7084 vs 0.7064), and melt inclusions trapped in quartz phenocrysts exhibit notable variability of trace-element concentrations, even within a single host crystal (e.g., U: 10.77 to 8.91 ppm).These data have been previously interpreted as due to processes of chemical fractionation and evolution operating within a magma system closed to chemical interactions with its roof rocks. For example, the reversal in trace-element zoning has been explained by the first-erupted magma being erupted from somewhat below the top of a monotonically zoned reservoir. However, we submit that the reversed zoning and other above-noted features can be explained equally well as consequences of minor assimilation of roof rocks into a magma reservoir that was erupted from the top down.The basal part of the Bishop Tuff exhibits extreme concentrations and depletions of trace elements, relative to the average composition of crustal rocks. For example, the upward decrease of Sr in the Bishop magma reservoir (downward decrease in the ignimbrite) results in concentrations as low as 2–4 ppm. Because of the attendant ‘chemical leverage’, assimilation of < 1 wt.% of Sierra Nevada batholith rocks typical of the area could readily reverse an ‘uncontaminated’ Sr (and other trace elements) trend of zoning and could also substantially raise ⁸⁷Sr/⁸⁶Sr. Small-scale trace-element variability in the uppermost part of the Bishop magma reservoir, as recorded by the above-mentioned melt inclusions, may simply reflect melt heterogeneity produced by the process of assimilation.     

Heterogeneous pumice populations in the 2.08-Ma Cerro Gal��n Ignimbrite: implications for magma recharge and ascent preceding a large-volume silicic eruption

Triggering mechanisms of large silicic eruptions remain a critical unsolved problem. We address this question for the ~2.08-Ma caldera-forming eruption of Cerro Galán volcano, Argentina, which produced distinct pumice populations of two colors: grey (5%) and white (95%) that we believe may hold clues to the onset of eruptive activity. We demonstrate that the color variations correspond to both textural and compositional variations between the clast types. Both pumice types have bulk compositions of high-K, high-silica dacite to low-silica rhyolite, but there are sufficient compositional differences (e.g., ~150?ppm lower Ba at equivalent SiO₂ content and 0.03?wt.% higher TiO₂ in white pumice than grey) to suggest that the two pumice populations are not related by simple fractionation. Trace element concentrations in crystals mimic bulk variations between clast types, with grey pumice containing elevated Ba, Cu, Pb, and Zn concentrations in both bulk samples (average Cu, Pb, and Zn concentrations are 27, 35, and 82 in grey pumice vs. 11, 19, and 60 in white pumice) and biotite phenocrysts and white pumice showing elevated Li concentrations in biotite and plagioclase phenocrysts. White and grey clasts are also texturally distinct: White pumice clasts contain abundant phenocrysts (44?C57%), lack microlites, and have highly evolved groundmass glass compositions (76.4?C79.6?wt.% SiO₂), whereas grey pumice clasts contain a lower percentage of phenocrysts/microphenocrysts (35?C49%), have abundant microlites, and have less evolved groundmass glass compositions (69.4?C73.8?wt.% SiO₂). There is also evidence for crystal transfer between magma producing white and grey pumice. Thin highly evolved melt rims surround some fragmental crystals in grey pumice clasts and appear to have come from magma that produced white pumice. Furthermore, based on crystal compositions, white bands within banded pumice contain crystals originating in grey magma. Finally, only grey pumice clasts form breadcrusted surface textures. We interpret these compositional and textural variations to indicate distinct magma batches, where grey pumice originated from an originally deeper, more volatile-rich dacite recharge magma that ascended through and mingled with the volumetrically dominant, more highly crystalline chamber that produced white pumice. Shortly before eruption, the grey pumice magma stalled within shallow fractures, forming a vanguard magma phase whose ascent may have provided a trigger for eruption of the highly crystalline rhyodacite magma. We suggest that in the case of the Cerro Galán eruption, grey pumice provides evidence not only for cryptic silicic recharge in a large caldera system but also a probable trigger for the eruption.     

The Oligocene Lund Tuff, Great Basin, USA: a very large volume monotonous intermediate

Unusual monotonous intermediate ignimbrites consist of phenocryst-rich dacite that occurs as very large volume (>1000 km³) deposits that lack systematic compositional zonation, comagmatic rhyolite precursors, and underlying plinian beds. They are distinct from countless, usually smaller volume, zoned rhyolite–dacite–andesite deposits that are conventionally believed to have erupted from magma chambers in which thermal and compositional gradients were established because of sidewall crystallization and associated convective fractionation. Despite their great volume, or because of it, monotonous intermediates have received little attention. Documentation of the stratigraphy, composition, and geologic setting of the Lund Tuff – one of four monotonous intermediate tuffs in the middle-Tertiary Great Basin ignimbrite province – provides insight into its unusual origin and, by implication, the origin of other similar monotonous intermediates.The Lund Tuff is a single cooling unit with normal magnetic polarity whose volume likely exceeded 3000 km³. It was emplaced 29.02±0.04 Ma in and around the coeval White Rock caldera which has an unextended north–south diameter of about 50 km. The tuff is monotonous in that its phenocryst assemblage is virtually uniform throughout the deposit: plagioclase>quartz≈hornblende>biotite>Fe–Ti oxides≈sanidine>titanite, zircon, and apatite. However, ratios of phenocrysts vary by as much as an order of magnitude in a manner consistent with progressive crystallization in the pre-eruption chamber. A significant range in whole-rock chemical composition (e.g., 63–71 wt% SiO₂) is poorly correlated with phenocryst abundance.These compositional attributes cannot have been caused wholly by winnowing of glass from phenocrysts during eruption, as has been suggested for the monotonous intermediate Fish Canyon Tuff. Pumice fragments are also crystal-rich, and chemically and mineralogically indistinguishable from bulk tuff. We postulate that convective mixing in a sill-like magma chamber precluded development of a zoned chamber with a rhyolitic top or of a zoned pyroclastic deposit. Chemical variations in the Lund Tuff are consistent with equilibrium crystallization of a parental dacitic magma followed by eruptive mixing of compositionally diverse crystals and high-silica rhyolite vitroclasts during evacuation and emplacement. This model contrasts with the more systematic withdrawal from a bottle-shaped chamber in which sidewall crystallization creates a marked vertical compositional gradient and a substantial volume of capping-evolved rhyolite magma. Eruption at exceptionally high discharge rates precluded development of an underlying plinian deposit.The generation of the monotonous intermediate Lund magma and others like it in the middle Tertiary of the western USA reflects an unusually high flux of mantle-derived mafic magma into unusually thick and warm crust above a subducting slab of oceanic lithosphere.     

Magma chamber evolution prior to the Campanian Ignimbrite and Neapolitan Yellow Tuff eruptions (Campi Flegrei,Italy)

The Campi Flegrei (Campanian Region, Italy) experienced two cataclysmic caldera-forming eruptions which produced the Campanian Ignimbrite (39 ka, CI) and the Neapolitan Yellow Tuff (15 ka, NYT). We studied the minor eruptions before both these large events to understand magma chamber evolution leading towards such catastrophic eruptions. Major, trace element, and Sr and Nd isotope compositions of pre-Campanian Ignimbrite and pre-Neapolitan Yellow Tuff products define distinct geochemical groups, which are here interpreted as distinct magma batches. These batches do not show any transitional trend towards the CI and NYT eruptions. The CI and NYT systems are decoupled geochemically and isotopically. At least one of the pre-CI and one of the pre-NYT erupted magma batches qualifies as mixing endmembers for the large CI and NYT eruptions, and thus, must have been stored in reservoirs for some time to remain available for the CI and NYT eruptions. The least evolved, isotopically distinct magma compositions that are typical of the last phases of the NYT and CI eruptions did not occur before caldera-forming events. Based on the new data, we propose the following scenario: Multiple magma chambers with distinct compositions existed below the Campi Flegrei before the CI and NYT eruptions and remained generally separated for some time unless new magma was recharged. In each case, one of the residing magma reservoirs was recharged by a new large-volume magma input of intermediate composition from a deeper differentiating magma reservoir. This may have triggered the coalescence of the previously separated reservoirs into one large chamber which fed the cataclysmic caldera-forming eruption. Large magma chambers in the Campi Flegrei may therefore be ephemeral features, interrupted by periods of evolution in individual, separated magma reservoirs.     

40Ar/39Ar Ages and stratigraphy of the Latera caldera,Italy

The Latera caldera is a well-exposed volcano where more than 8 km³ of mafic silica-undersaturated potassic lavas, scoria and felsic ignimbrites were emplaced between 380 and 150 ka. Isotopic ages obtained by ⁴⁰Ar/³⁹Ar analysis of single sanidine crystals indicate at least four periods of explosive eruptions from the caldera. The initial period of caldera eruptions began at 232 ka with emplacement of trachytic pumice fallout and ignimbrite. They were closely followed by eruption of evolved phonolitic magma. After roughly 25 ky, several phonolitic ignimbrites were deposited, and they were followed by phreatomagmatic eruptions that produced trachytic ignimbrites and several smaller ash-flow units at 191 ka. Compositionally zoned magma then erupted from the northern caldera rim to produce widespread phonolitic tuffs, tephriphonolitic spatter, and scoria-bearing ignimbrites. After 40 ky of mafic surge deposit and scoria cone development around the caldera rim, a compositionally zoned pumice sequence was emplaced around a vent immediately northwest of the Latera caldera. This activity marks the end of large-scale explosive eruptions from the Latera volcano at 156 ka.     

Formation of the Green Tuff,Pantelleria

The strongly peralkaline Green Tuff, Pantelleria, is an example of a thin, densely welded air-fall tuff which mantles an area of at least 85 km². Offshore the tuff is correlated with the Y-6 ash layer in the central Mediterranean Sea, and the total volume of the eruption is estimated at 7 km³ D.R.E. New petrological data suggests that the tuff was erupted from a zoned magma chamber containing a cooler, more fractionated upper zone relative to be bulk of the magma. Analysis of the distribution of accessory lithic fragments in terms of existing models of eruption dynamics indicates emplacement by a plinian-type eruption. It is shown that, due to the low viscosity of pantelleritic ejecta, dense welding can occur at moderate tephra accumulation rates and a rate of the order of 1 cm/minute is suggested for the Green Tuff; this yields an estimate for the eruption duration of rather less than one day. It is predicted that welded tuff should be formed during large plinian eruptions of pantelleritic magma, and therefore that welded airfall tuffs should be common in areas of peralkaline volcanism.     

Recurrent magma mingling in successive ignimbrites from Amealco caldera, central Mexico

The Amealco Tuff is a widespread (>2880 km²), trachyandesitic to rhyolitic pyroclastic deposit in the central Mexican Volcanic Belt that was erupted from the Amealco caldera at 4.7ǂ.1 Ma. It includes three major ignimbrites, each showing complex mingling of pumice fragments and matrix glass with andesitic to rhyolitic compositions. The different glasses are well mingled throughout each of the pyroclastic-flow deposits. Mingling of glasses may have occurred just before and during the explosive eruptions that produced the pyroclastic flows, as the distinct melts had insufficient time to homogenize. Mingling of glasses is evident in each of the three separate major ignimbrites of the Amealco Tuff; thus, the processes that caused it were repetitive. It is infered that the repetitive mingling of melts was due to repeated mafic magma inputs to an evolved magma chamber.     

Origin and emplacement of the andesite of Burroughs Mountain,a zoned,large-volume lava flow at Mount Rainier,Washington, USA

Burroughs Mountain, situated at the northeast foot of Mount Rainier, WA, exposes a large-volume (3.4 km³) andesitic lava flow, up to 350 m thick and extending 11 km in length. Two sampling traverses from flow base to eroded top, over vertical sections of 245 and 300 m, show that the flow consists of a felsic lower unit (100 m thick) overlain sharply by a more mafic upper unit. The mafic upper unit is chemically zoned, becoming slightly more evolved upward; the lower unit is heterogeneous and unzoned. The lower unit is also more phenocryst-rich and locally contains inclusions of quenched basaltic andesite magma that are absent from the upper unit. Widespread, vuggy, gabbronorite-to-diorite inclusions may be fragments of shallow cumulates, exhumed from the Mount Rainier magmatic system. Chemically heterogeneous block-and-ash-flow deposits that conformably underlie the lava flow were the earliest products of the eruptive episode. The felsic–mafic–felsic progression in lava composition resulted from partial evacuation of a vertically-zoned magma reservoir, in which either (1) average depth of withdrawal increased, then decreased, during eruption, perhaps due to variations in effusion rate, or (2) magmatic recharge stimulated ascent of a plume that brought less evolved magma to shallow levels at an intermediate stage of the eruption. Pre-eruptive zonation resulted from combined crystallization–differentiation and intrusion(s) of less evolved magma into the partly crystallized resident magma body. The zoned lava flow at Burroughs Mountain shows that, at times, Mount Rainier’s magmatic system has developed relatively large, shallow reservoirs that, despite complex recharge events, were capable of developing a felsic-upward compositional zonation similar to that inferred from large ash-flow sheets and other zoned lava flows.     

Pyroclastic deposits of the November 13, 1985 eruption of Nevado del Ruiz volcano, Colombia

The November 13, 1985 eruption of Nevado del Ruiz produced a series of pyroclastic flows and surges that eroded channels on the surface of the summit glacier and generated lahars which descended down most of the rivers that drain the volcano. The stratigraphy of the proximal pyroclastic deposits indicates that there were at least four episodes to the eruption. Episode I, deposited an unusual surge consisting of small pieces of ice mixed with ash and exhibiting planar stratification. Ballistically emplaced fragments are also intercalated with this unit. During Episode II, at least two pyroclastic flows were erupted. Their deposits contain the most evolved pumice of the entire eruption; SiO₂ content of matrix glass ranges between 74.5 and 74.9%. Episode III is marked by the emplacement of a welded tuff with an average SiO₂ content of about 66% in the matrix glass. The final Episode IV was characterized by the development of a high-altitude eruption column and the emplacement of several nonwelded pyroclastic flows. Banded pumice are common in the pyroclastic flow as well as in the pumice fall deposits. Co-existing dark and light pumice bands differ in SiO₂ content by 3.5% and in general are similar to the composition of the welded pumice from Episode III.The compositional zonation of the pyroclastic deposits from Episode I to IV suggests that a nearsurface compositionally-stratified portion of the magma body was tapped during Episode II. During Episodes III and IV the main body of magma was involved although the coexistence of the compositionally distinct pumice clasts at similar stratigraphic levels argues for mixing of magma from different levels in the chamber during the eruptive process.     

On magma fragmentation by conduit shear stress: Evidence from the Kos Plateau Tuff,Aegean Volcanic Arc

Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas–pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones that dominated in the inner column portions. The plate tube pumice proportion decreased abruptly up to disappearance during the emplacement of the main pyroclastic currents and lithic-rich breccias related to extensive caldera collapse at the eruption climax, as a consequence of an overall widening of the magma feeder system through the opening of multiple conduits and eruptive vents, along with fissure erosion, concomitant to the disruption of the collapsing block.     

The basaltic to trachydacitic upper Diliman Tuff in Manila: Petrogenesis and comparison with deposits from Taal and Laguna Calderas

The basaltic to trachydacitic (50–65 wt.% SiO₂) upper Diliman Tuff is the youngest deposit of a sequence of tuffaceous deposits in Metro Manila. The deposit is located north of Taal Caldera and northwest of Laguna Caldera, which are both within the Southwest Luzon Volcanic Field. Chemical variations in the pumice fragments within the upper Diliman Tuff include medium-K basalt to basaltic andesite, high-K basaltic andesite to andesite and trachyandesite to trachydacite. Magma mixing/mingling is ubiquitous and is shown by banding textures in some pumice fragments, considerable range in groundmass glass composition (54 to 65 wt.% SiO₂) in a single pumice fragment, and zoning in plagioclase phenocrysts. Simple binary mixing modeling and polytopic vector analysis were used to further evaluate magma mixing. Trace-element variations are inconsistent with the medium-K and high-K magmas being related by crystal fractionation. The medium-K basalts represent hotter intrusions, which induced small degrees of partial melting in older crystallized medium-K basaltic material within the crust to produce the high-K magmas. All melts likely differentiated in the crust but the emplaced and new basaltic intrusions originated from the mantle wedge and were generated by subduction zone processes. The volcanic source vent for the upper Diliman Tuff has not been identified. In comparisons with the deposits from adjacent Taal and Laguna Calderas it is chemically distinct with respect to both major- and trace-element concentrations.     

Precursory activity of the 161 ka Kos Plateau Tuff eruption, Aegean Sea (Greece)

The Kos Plateau Tuff (KPT) eruption of 161 ka was the largest explosive Quaternary eruption in the eastern Mediterranean. We have discovered an uplifted beach deposit of abraded pumice cobbles, directly overlain by the KPT. The pumice cobbles resemble pumice from the KPT in petrography and composition and differ from Plio-Pleistocene rhyolites on the nearby Kefalos Peninsula. The pumice contains enclaves of basaltic andesite showing chilled lobate margins, suggesting co-existence of two magmas. The deposit provides evidence that the precursory phase of the KPT eruption produced pumice rafts, and defines the paleoshoreline for the KPT, which elsewhere was deposited on land. The beach deposit has been uplifted about 120 m since the KPT eruption, whereas the present marine area south of Kos has subsided several hundred metres, as a result of regional neotectonics. The basaltic andesite is more primitive than other mafic rocks known from the Kos–Nisyros volcanic centre and contains phenocrysts of Fo₈₉ olivine, bytownite, enstatite and diopside. Groundmass amphibole suggests availability of water in the final stages of magma evolution. Geochemical and mineralogical variation in the mafic products of the KPT eruption indicate that fractionation of basaltic magma in a base-of-crust magma chamber was followed by mixing with rhyolitic magma during eruption. Low eruption rates during the precursory activity may have minimised the extent of mixing and preserved the end-member magma types.     

Compositional variation in three Cascade stratovolcanoes: Jefferson,Rainier, and Shasta

Detailed major and trace element studies of volcanic rocks from Jefferson, Rainier, and Shasta stratovolcanoes in the Cascade Range indicate that each volcano has distinct geochemical distribution patterns. Silica variation diagrams are not smooth nor, in general, continuous for any volcano. Portions of stratigraphic sections within the volcanoes exhibit compositional coherency and are interpreted as eruptive groups which were extruded over time intervals which are short compared to the lifetimes of the volcanoes. The results of this investigation indicate the leasibility of geochemically mapping eruptive groups within stratovolcanoes. Systematic compositional trends are not observed within thick (500–1000 m) eruptive groups but may occur over thicknesses of <200 m. Compositional variations within eruptive groups are commonly non-systematic and show ranges similar to the ranges observed in individual flows. Correlations between the amounts or kinds of phenocryst phases present and intra-group compositional variation is not observed. Inter-group compositional differences are sometimes accompanied by mineralogical differences. Late andesites and dacites at Rainier and Shasta are characterized by decreases in K and Rb while at Jefferson increases in these elements and other compositional changes occur in the late eruptives. Progressive fractional crystallization models do not seem capable of explaining the element distributions observed in the three volcanoes. Existing data are consistent with a model involving varying degrees of melting of some combination of amphibolite, eclogite or peridotite in or above a subduction zone with varying water contents. Segregation and sequential eruption of small batches of magma may produce the eruptive groups characterizing the volcanoes. Late mafic magmas erupted at satellite vents appear to be produced in different (deeper?) mantle source areas.     

Geology of the peralkaline volcano at Pantelleria,Strait of Sicily

Situated in a submerged continental rift, Pantelleria is a volcanic island with a subaerial eruptive history longer than 300 Ka. Its eruptive behavior, edifice morphologies, and complex, multiunit geologic history are representative of strongly peralkaline centers. It is dominated by the 6-km-wide Cinque Denti caldera, which formed ca. 45 Ka ago during eruption of the Green Tuff, a strongly rheomorphic unit zoned from pantellerite to trachyte and consisting of falls, surges, and pyroclastic flows. Soon after collapse, trachyte lava flows from an intracaldera central vent built a broad cone that compensated isostatically for the volume of the caldera and nearly filled it. Progressive chemical evolution of the chamber between 45 and 18 Ka ago is recorded in the increasing peralkalinity of the youngest lava of the intracaldera trachyte cone and the few lavas erupted northwest of the caldera. Beginning about 18 Ka ago, inflation of the chamber opened old ring fractures and new radial fractures, along which recently differentiated pantellerite constructed more than 25 pumice cones and shields. Continued uplift raised the northwest half of the intracaldera trachyte cone 275 m, creating the island's present summit, Montagna Grande, by trapdoor uplift. Pantellerite erupted along the trapdoor faults and their hingeline, forming numerous pumice cones and agglutinate sheets as well as five lava domes. Degassing and drawdown of the upper pantelleritic part of a compositionally and thermally stratified magma chamber during this 18-3-Ka episode led to entrainment of subjacent, crystal-rich, pantelleritic trachyte magma as crenulate inclusions. Progressive mixing between host and inclusions resulted in a secular decrease in the degree of evolution of the 0.82 km³ of magma erupted during the episode.The 45-Ka-old caldera is nested within the La Vecchia caldera, which is thought to have formed around 114 Ka ago. This older caldera was filled by three widespread welded units erupted 106, 94, and 79 Ka ago. Reactivation of the ring fracture ca. 67 Ka ago is indicated by venting of a large pantellerite centero and a chain of small shields along the ring fault. For each of the two nested calderas, the onset of postcaldera ring-fracture volcanism coincides with a low stand of sea level.Rates of chemical regeneration within the chamber are rapid, the 3% crystallization/Ka of the post-Green Tuff period being typical. Highly evolved pantellerites are rare, however, because intervals between major eruptions (averaging 13–6 Ka during the last 190 Ka) are short. Benmoreites and mugearites are entirely lacking. Fe-Ti-rich alkalic basalts have erupted peripherally along NW-trending lineaments parallel to the enclosing rift but not within the nested calderas, suggesting that felsic magma persists beneath them. The most recent basaltic eruption (in 1891) took place 4 km northwest of Pantelleria, manifesting the long-term northwestward migration of the volcanic focus. These strongly differentiated basalts reflect low-pressure fractional crystallization of partial melts of garnet peridotite that coalesce in small magma reservoirs replenished only infrequently in this continental rift environment.     

Kos Plateau Tuff (KPT) on Kalymnos island, Aegean volcanic arc: A geochemical approach

Thirteen pumice samples from the D and E ignimbrite units of Kalymnos Tuff have been analyzed for their biotite and feldspar phenocryst mineral chemistry and for bulk major and 20 trace, including 14 Rare Earth elements, to define and compare their petrochemistry with the Kos Plateau Tuff (KPT). For the same purpose major element analyses were obtained from Kalymnos Tuff and KPT glasses. Both KPT and Kalymnos pumice lapilli are rhyolites characterized by a well-developed ‘silky’ texture and roundish quartz. Phenocrysts of biotite and feldspars (sanidine, oligoclase) from both tuffs display compositional overlap. Crystals are charac-terized by undulatory extinction (quartz), fractures (sanidine, oligoclase) and bent cleavages (biotite) due to the explosive origin of their host. Both tuffs show well-defined petrogenetic trends and extensive compositional overlaps on major and trace element variation diagrams suggesting that they are consanguineous. However, D ignimbrite samples are more evolved than those obtained from E ignimbrite as indicated from major elements, alkali earths (Ba, Rb, Sr), immobile (Zr, Y), compatible (V) and hygromagmatophile trace element (Th) distributions. This evidence indicates a stratified magma chamber under a ～16 Km caldera superstructure which is mostly submarine.     

Stratigraphy of the Toba Tuffs and the evolution of the Toba Caldera Complex,Sumatra, Indonesia

During the past 1.2 m.y., a magma chamber of batholithic proportions has developed under the 100 by 30 km Toba Caldera Complex. Four separate eruptions have occurred from vents within the present collapse structure, which formed from eruption of the 2800 km³ Youngest Toba Tuff (YTT) at 74 ka. Eruption of the three older Toba Tuffs alternated from calderas situated in northern and southern portions of the present caldera. The northern caldera apparently developed upon a large andesitic stratovolcano. The calderas associated with the three older tuffs are obscured by caldera collapse and resurgence resulting from eruption of the YTT. Samosir Island and the Uluan Block are two sides of a single resurgent dome that has resurged since eruption of the YTT. Samosir Island is composed of thick YTT caldera fill, whereas the Uluan Block consists mainly of the Oldest Toba Tuff (OTT). In the past 74000 years lava domes have been extruded on Samosir Island and along the caldera's western ring fracture. This part of the ring fracture is the site of the only current activity at Toba: updoming and fumarolic activity. The Toba eruptions document the growth of the laterally continuous magma body which eventually erupted the YTT. Repose periods between the four Toba Tuffs range between 0.34 and 0.43 m.y. and give insights into pluton emplacement and magmatic evolution at Toba.     

The color of pumice: case study on a trachytic fall deposit, Meidob volcanic field, Sudan

 This paper examines the cause of color variations of trachytic pumices which are essentially uniform in chemical composition and proposes a geological model for their formation. A pyroclastic sequence of distinct subunits with brown, buff, and black pumices was deposited during the 5000-B.P. eruption of a tuff ring in the central Meidob volcanic field (Sudan). Subunits of buff pumices locally contain minor amounts of streaky pumice with pale-gray and dark-gray domains. The combined evidence of petrographic studies, chemical analyses of whole pumices and groundmass separates, electron microprobe analyses, optical spectroscopy, transmission electron microscopy, and magnetic susceptibility measurements show that color variations of the pumice clasts are related to the size and distribution of Fe³⁺-rich oxide microcrysts. Buff pumice and light-gray domains of streaky pumice have a colorless, transparent groundmass with very few microcrysts. Dark-gray domains of streaky pumice contain abundant hematite and/or magnetite microcrysts visible in thin section within a transparent, colorless glass groundmass. The groundmass of the black pumice clasts is brown in thin section which is most likely caused by submicroscopic magnetite microcrysts. Brown pumice clasts have a mixed groundmass consisting of brown domains and domains with opaque microcrysts in transparent glass. Variations in the eruption dynamics have been inferred from lithological observations. Subunits of black pumices are related to eruption pulses with low magma discharge and high water/magma mass ratio, whereas subunits of buff pumice were deposited during eruption pulses with high magma discharge and low water/magma mass ratio. Brown pumices represent the top part of the magma body, and the initial stage of the eruption probably had a low magma discharge. Streaky pumices are interpreted as the product of syn-eruptive mixing of Fe³⁺-rich oxide microcryst-bearing magma and microcryst-free magma. Received: 3 February 1997 / Accepted: 28 July 1997