Eclogitic metapelites in the western segment of the north Qaidam Mountains: Evidence on “in situ” relationship between eclogite and its country rock

In Yuka-Luofengpo area of the north Qaidam Mountains, eclogitic metapelites are recognized. The metapelites enclosed lenses of eclogites, and locally intercalated with eclogites. Their typical mineral assemblages are garnet+kyanite+chloritoid+phengite+quartz+rutile. Strong growth zoning is preserved in garnets of metapelites, and phengite contains up to 3.4 Si per formula units. The petrographic observations and textural relations testify to the following sequence of mineral assemblages connected to three metamorphic stage: (1) Grt+ChlI+CldI +PheI ± StI+Qtz; (2) Grt+Ky+PheII±CldII+Qtz; and (3) Grt+CldIII+ChlII+PheIII+StII ± ky+ Qtz. Applying THERMOCALC Program, Grt-Phe thermometer and Grt-Ky-Phe-Qtz barometry, P-T conditions for three metamorphic stages were obtained: P=1.07±0.31GPa, T=564±22? (prograde stage); P=2.3–3.1GPa, T=615–700°C-(peak stage); and P =1.22 ± 0.26GPa, T=581±20°C (retrograde stage). A hairpin shape P-T path similar to that of adjacent eclogite is inferred. In combination with eclogitic mineral relics in marbles and orthogneisses enclosing eclogites, we thought that the relationship between eclogites and country rocks is “in situ” rather than “tectonic emplacement”.     

Eclogites of southern Henan and northern Hubei Provinces, central China

Abstract According to field occurrence and P-T condition, eclogites of southern Henan and northern Hubei Provinces can be divided into two types: medium temperature (MT) and low temperature (LT) eclogites. MT eclogite occurs as layers or lenticular bodies within migmatized gneiss of the Dabie Group. This study is the first to report an occurrence of the assemblages coesite and kyanite + talc in this area. Garnet exhibits a distinct prograde compositional zoning and has mineral inclusions with rotational textures indicating syntectonic growth. Five evolutionary stages are outlined. (1) Pre-eclogite stage, determined by the inclusions of barroisite + zoisite + quartz in the cores of zoned garnets. (2) Eclogite stage, characterized by garnet + omphacite + kyanite ± talc + coesite + rutile, represents the peak metamorphism. The peak conditions are estimated to be T = 600-700°C, P >27 kb. (3) Glaucophane stage, without an appearance of plagioclase, is assigned to a transitional stage. Blades of glaucophane form rims around garnet grains as a result of the reaction talc + jadeite = glaucophane. This marks the beginning of retrograde metamorphism. (4) Symplectite stage, where eclogitic minerals break down, and Amp + Pl symplectite develops around garnet or omphacite; (5) Later retrograde stage is represented by epidote-amphibolite assemblages. Low temperature eclogite appears as blocks in the Qijiaoshan Formation (part of the Susong Group). Four stages can be identified: (1) Pre-eclogite stage, amphibole + epidote + sphene inclusions occur in garnet core; (2) Eclogite stage, consists of garnet + omphacite + rutile + quartz + phengite + glaucophane + zoisite. The peak conditions are T = 490-560°C, P <15 kb; (3) Symplectitic stage, is characterized by the breakdown of eclogitic minerals; (4) Greenschist facies stage, is recorded by a greenschist facies assemblage. The difference between the two types of eclogites suggests contrasting processes. A model is proposed whereby partial melting of continental crust and the emplacement of tonalite occurs during the exhumation of ultrahigh-pressure eclogite terrain.     

Thermodynamic modelling of the phengite geobarometry

Using the updated models of activity-composition relations for solid solutions,P-T pseudosections and Si isopleths of phengite in the system KFMASH (K2O-FeO-MgO-Al2O3-SiO2-H2O) are calculated with the software THERMOCALC 323 for three bulk compositions of the average,Al-rich and K-rich metapelites. The Si isopleths of phengite in the calculated pseudosections are highly dependent on mineral as-semblages. In the chlorite-and biotite-bearing di-and trivariant fields,and in the garnet kyanite-bearing trivariant fields,the phengite can be used as a good geobarometer. But in the carpho-lite-present and chlorite-absent fields,the Si contents of phengite mainly indicate variance of tem-perature. For a given Si value,the phengite in kyanite-bearing assemblages shows higher pressures than in the K-feldspar-bearing assemblages. Addition of Na2O into the KFMASH leads to reduction of stability of the AFM phases. The Si isopleths of phengite in the mineral assemblages containing only one Na-phase are similar to those in the corresponding KFMASH assemblages. But in the assemblages with two or more Na-phases,the phengite Si isopleths differ remarkably from those in the KFMASH.     

Mineral chemistry,P-T-t paths and exhumation processes of mafic granulites in Dinggye,Southern Tibet

Lower crustal high grade metamorphic rocks have been successively found at Pamirs nearby the western Himalayan syntaxis, Namjagbarwa and Dinggye nearby the eastern Himalayan syntaxis and the central segment of the Himalayan Orogenic Belt, respec-tively[1―4]. In particular, some researchers deduced that there were probably eclogites at some locations[5]. Moreover, some geochronological data of these lower crustal granulites also have been accumulated. For example, the high-pressure granulit…     

Ultrahigh-pressure metamorphic records hidden in zircons from amphibolites in Sulu Terrane, eastern China

Abstract The amphibolites occur sporadically as thin layers and blocks throughout the Sulu Terrane, eastern China. All analyzed amphibolite from outcrop and drill cores from prepilot drill hole CCSD‐PP1 and CCSD‐PP2, Chinese Continental Scientific Drilling Project in the Sulu Terrane, are retrograded eclogites overprinted by amphibolite‐facies retrograde metamorphism, with characteristic mineral assemblages of amphibole + plagioclase + epidote ± quartz ± biotite ± ilmenite ± titanite. However, coesite and coesite‐bearing ultrahigh‐pressure (UHP) mineral assemblages are identified by Raman spectroscopy and electron microprobe analysis as inclusions in zircons separated from these amphibolites. In general, coesite and other UHP mineral inclusions are preserved in the cores and mantles of zircons, whereas quartz inclusions occur in the rims of the same zircons. The UHP mineral assemblages consist mainly of coesite + garnet + omphacite + rutile, coesite + garnet + omphacite, coesite + garnet + omphacite + phengite + rutile + apatite, coesite + omphacite + rutile and coesite + magnesite. Compositions of analyzed mineral inclusions are very similar to those of matrix minerals from Sulu eclogites. These UHP mineral inclusion assemblages yield temperatures of 631–780°C and pressures of ≥2.8 × 10³ MPa, representing the P–T conditions of peak metamorphism of these rocks, which are consistent with those (T = 642–726°C; P ≥ 2.8 × 10³ MPa) deduced from adjacent eclogites. These data indicate that the amphibolites are the retrogressive products of UHP eclogites.     

Low temperature eclogite facies metamorphism in Western Tianshan, Xinjiang

According to the field occurrences and petrological study, the low temperature eclogite facies metamorphic rocks in Western Tianshan of Xinjiang can be divided into five types: (i) massive glaucophane-epidote eclogites and glaucophane-paragonite eclogites; (ii) schistose or gneissic mica eclogites; (iii) banded calcite eclogites; (iv) pillow glaucophane eclogites; (v) garnet-omphacite quartzites. Their eclogite facies metamorphism has undergone four stages of evolution: (i) pre-peak lawsonite-blueschist facies stage,T = 350–4000°C,P = 0.7–0.9 GPa; (ii) peak eclogite facies stage,T = 530 ± 20°C,P = 1.6–1.9 GPa; (iii) retrograde epidote-blueschist facies stage, T=500–530°C,P = 0.9–1.2 GPa and (iv) retrograde blueschist-greenschist facies stage,T= 450–550°C,P= 0.7–0.8 GPa. The metamorphic PT path of Western Tianshan eclogites is characterized by clockwise ITD resulting from the subduction of Tarim plate northward to Yili-Central Tianshan plate followed by fast uplift to the surface. But there were at least two stages of blueschist facies retrograde metamorphism overprinted during their uplift.     

Talc-phengite-albite assemblage in piemontite-quartz schist of the Sanbagawa metamorphic belt, central Shikoku, Japan

Abstract The talc (Tlc) + phengite (Phn) + albite (Ab) assemblage is newly confirmed in MnO^total-rich (1.65 wt% in average) piemontite-quartz schists from the intermediate- and high-grade part of the Sanbagawa belt, central Shikoku, Japan. Talc is in direct contact with Phn, Ab and chlorite (Chl) with sharp boundaries, suggesting that these four phases mutually coexist. Other primary constituents of the Tlc-bearing piemontite-quartz schist are spessartine, braunite, hematite (Ht), crossite/barroisite and dolomite. Phlogopite (Phl) rarely occurs as a later stage mineral developing along the rim of Phn. The studied piemontite-quartz schist has mg# (= Mg/(Mg + Fe²⁺)) ~ 1.0, because of its high oxidation state. Schreinemakers' analysis in the KNMASH system and the mineral assemblage in the Sanbagawa belt propose a possible petrogenetic grid, in which the Tlc–Phn assemblage is stable in a P-T field surrounded by the following reactions: lower-pressure limit by Chl + Phl + quartz (Qtz) = Phn + Tlc + H₂O as proposed by previous workers; higher-pressure limit by glaucophane + Qtz = Tlc + Ab + H₂O; and higher-temperature limit by Tlc + Phn + Ab = Phl + paragonite + Qtz + H₂O. Thermodynamic calculation based on the database of Holland & Powell (1998) , however, suggests that the Tlc–Phn stability field defined by these reactions is unrealistically limited around 580–600 °C at 11.6–12.0 (± 0.7) kbar. Schreinemakers' analysis in the KNMA-Fe³⁺-SH system and the observed mineral assemblage predict that Chl + crossite = Tlc + Ab + Ht + H₂O is a preferable Tlc-forming reaction in the intermediate-grade part of the Sanbagawa belt and that excess Ab + hematite narrows the stability field of the Tlc–Phn assemblage.     

Eclogitic metapelites in the western segment of the north Qaidam Mountains: Evidence on “in situ” relationship between eclogite and its country rock

Science China Earth Sciences - In Yuka-Luofengpo area of the north Qaidam Mountains, eclogitic metapelites are recognized. The metapelites enclosed lenses of eclogites, and locally intercalated...     

Mineral inclusions in zircon domains and geological significance of SHRIMP U-Pb dating for coesite-bearing zircons of paragneiss in Sulu terrane,eastern China

Laser Raman spectroscopy and cathodoluminescence (CL) image reveal that zircons separated from paragneisses in the southwestern Sulu terrane (eastern China) preserve multi-stage mineral assemblages in different zircon domains. In the same paragneiss zircon sample, some zircon grains retain inherited (detrital) cores with abundant low-pressure mineral inclusions of Qtz + Phe + Ap + impurities and Qtz + Phe + impurities. The ultrahigh-pressure (UHP) metamorphic overgrowths mantles of these zircons preserve Coe, Coe + Phe and other UHP mineral inclusions, indicating that these inherited (detrital) zircons from protoliths experienced metamorphic recrystallization during the Sulu UHP metamorphic event. However, other zircon grains preserve UHP mineral inclusions of Coe, Coe + Ap and Coe + Phe in the cores and mantles, whereas the outmost rims contain quartz (Qtz) and other low-pressure mineral inclusions. These phenomena prove that the second group zircons were crystallized at UHP metamorphic stage and overpr     

Ultrahigh-pressure metamorphic rocks and the thermal evolution of continent collision belts

Abstract Coesite-bearing eclogites exposed in the Alpine, Qinling-Dabie (China), Caledonian, and Ural orogenic belts provide insight into the time-dependent thermal structure of continent collision belts. Coesite-bearing eclogites record peak metamorphic temperatures of 550-900°C at pressures ≥ 2.5 GPa reflecting anomalously cool conditions at depths of 90 km or more. The low temperatures recorded by coesite-bearing eclogites strongly suggest formation in a convergent plate margin where the downward advection of cool lithosphere depresses isotherms on a regional scale. Subduction zone pressure-temperature (P-T) paths calculated using a two-dimensional finite-difference model predict steady-state temperatures of 450-650°C at 100 km depth at the slab-mantle interface for convergence rates of 10 to 100 mm/yr. Coesite-bearing eclogites record peak temperatures ~100-250°C higher, possibly reflecting (i) formation during the early stages of convergence prior to the achievement of thermal steady state; (ii) attainment of peak metamorphic temperatures during decompression (exhumation); (iii) formation during slow, <10 mm/yr, convergence; or (iv) uncertainties in the modeling parameters. Retrograde P-T paths determined for coesite-bearing eclogites from the western Alps and China indicate cooling during decompression from depths of ~100 km. Cooling of eclogite terrains during exhumation requires loss of heat downward into lithosphere that continues to subduct beneath the eclogites, loss of heat upward into the cooler hanging wall of a large-scale normal fault/shear zone, or a combination of the two scenarios.     

Prograde P–T path of kyanite eclogites from Junan in the Sulu ultrahigh-pressure province, eastern China

Kyanite-bearing ultrahigh-pressure (UHP) eclogites occur as blocks in orthogneisses at Yangzhuang, in the Junan area of the southwestern Sulu province, eastern China. Eclogites have variable bulk rock compositions, with Al₂O₃ = 16–27 wt%, FeO* + MgO = 6–22 wt% and CaO = 9–13 wt%. Major minerals are garnet, omphacite, phengitic white mica, zoisite, kyanite, rutile and an SiO₂ phase. Fe-rich staurolite (Mg ? Mg# = 0.24 ± 0.01) and paragonite–margarite aggregates are rarely included in the cores of prograde zoned garnet. Metamorphic conditions ranged from 520 to 650°C and <1.4 GPa at an early prograde stage, and mostly reached 660–830°C and 2.7–3.5 GPa at the peak UHP stage. The estimated dP/dT of the prograde P–T path is less than 0.25 GPa/100°C at earlier stages and increases to 0.7–1.4 GPa/100°C just before the UHP stage. The kink of the prograde P–T path closely resembles the steady-state P–T paths proposed, assuming a two-parameter brittle-plastic shear stress model. The estimated P–T path adequately explains the absence of prograde lawsonite and sodic amphibole and the common occurrence of coexisting zoisite, kyanite and sodic-calcic amphibole in the UHP eclogites throughout the Sulu province. Simple clockwise prograde P–T paths for Sulu UHP eclogites proposed in earlier studies should be carefully re-examined.     

Mineral parageneses and metamorphic P-T paths of ultrahigh-pressure eclogites from Kyrghyzstan Tien-Shan

Abstract Eclogites occur in three districts of the northern and southern parts of Tien-Shan. Three eclogites collected from the Aktyuz, Makbal and Atbashy districts were analyzed; the P-T paths of three eclogites were estimated by analyzing compositional growth zoning and retrograde reaction of garnet and omphacite. Aktyuz and Makbal eclogites have not preserved the prograde path. An Aktyuz eclogite that underwent a quartz eclogite facies metamorphism (about T = 600°C, P = 12 kbar) has recorded three stages of retrograde metamorphism. Four stages of retrograde metamorphism were recognized in a Makbal eclogite; the garnet-omphacite geothermometer gave about T = 560°C at 20 kbar as the highest metamorphic condition. Garnet from a garnetchloritoid-talc schist of the Makbal district includes quartz pseudomorphs after coesite; some units evidently underwent a low-temperature part of coesite eclogite fades metamorphism. Prograde and retrograde paths were recognized in an Atbashy eclogite; five stages of metamorphic reaction were observed in the Atbashy sample. The prograde path from stage I to stage III has been recorded in garnet and omphacite in which quartz pseudomorphs after coesite are included. The peak metamorphism of stage III took place at about 660°C at 25 kbar. The stages IV and V are retrograde. UHP eclogite facies metamorphism took place twice in Kyrghyzstan. The Aktyuz and Atbashy eclogites gave Rb-Sr mineral-isochron ages of about 750 Ma and 270 Ma, respectively. The K-Ar age of paragonite from the Makbal eclogite is about 480 Ma.     

Ultrahigh-pressure metamorphism and decompressional P-T paths of eclogites and country rocks from Weihai, eastern China

Abstract Altered quartz-rich and nearly quartz-free eclogitic rocks and completely retrograde quartz-rich garnet amphibolites occur as blocks or lenses in gneisses at Weihai, northeastern tip of the Sulu ultrahigh-P belt. Eclogitic rocks with assemblage garnet ± clinopyroxene ± coesite + rutile have experienced three-stage metamorphic events including ultrahigh-pressure eclogite, granulite and amphibolite facies. Granulite metamorphic event is characterized by formation of the hypersthene + salite + plagioclase ± hornblende corona between garnet and quartz + clinopyroxene. P-T conditions for the three-stage recrystallization sequence are 840 ± 50°C, >28 kbar, about 760±50°C, 9 kbar, and ~650°C, <8 kbar respectively. Most country rock gneisses contain dominant amphibolite-facies assemblages; some garnet-bearing clinopyroxene gneisses recrystallized under granulite-facies conditions at about 740±50°C and 8.5 kbar; similar to granulite-facies retrograde metamorphism of the enclosed eclogitic blocks. Minor cale-silicate lenses within gneisses containing an assemblage grossular + salite + titanite + quartz with secondary zoisite and plagioclase may have formed within a large pressure range of 14-35 kbar. Eclogitic boudins and quartzo-feldspathic country rocks may have experienced coeval in situ UHP and subsequent retrograde metamorphism. The established nearly isothermal decompression P-T path suggests that this area may represent the interior portion of a relatively large subducted sialic block. The recognized UHP terrane may extend eastward across the Yellow Sea to the Korean Peninsula.     

Eclogites from the Chinese continental scientific drilling borehole, their petrology and different P-T evolutions

Abstract Four phengite‐bearing eclogites, taken from different depths of the Chinese continental scientific drilling (CCSD) borehole in the Sulu ultrahigh pressure terrane, eastern China, were studied with the electron microprobe. The compositional zonations of garnet and omphacite are moderate, whereas phengite compositions generally vary significantly in a single sample from core to rim by decrease of the Si content. Various geothermobarometric methods were applied to constrain the P‐T conditions of these eclogites on the basis of the compositional variability of the above minerals. The constrained P‐T path for sample B218 is characterized by pressure decrease from ca 3.0 GPa (ca 600°C) to 1.3 GPa (ca 550°C). Eclogite B310 yielded P‐T conditions of 3.0 GPa and 750°C. The path for eclogite B1008 starts at about 650°C and 3.6–3.9 GPa (stage I) followed by a pressure decrease to 2.8–3.0 GPa and a significant temperature rise (stages II and IIIa, 750–810°C). Afterwards, this rock cooled down to 620–660°C at still high pressures (2.5–2.7 GPa, stage IIIb). Retrograde conditions were about 670°C and 1.3 GPa (stage IV). Eclogite B1039 yielded a P‐T path starting at ca 600°C and 3.3–3.9 GPa (stage I). A pressure decrease to about 3.0 GPa (stage II, 590–610°C) and then a moderate isobaric temperature increase to ca 630°C (stage III) followed. Stage IV is characterized by temperatures of 650°C at pressures close to 1.3 GPa. During and after this stage (hydrous) fluids partially rich in potassium penetrated the rocks causing minor changes. Relatively high oxygen fugacities led to andradite and magnetite among the newly formed minerals. We think that the above findings can be best explained by mass flow in a subduction channel. Thus, we conclude that the assembly of UHP rocks of the CCSD site, eclogites, quartzofeldspathic rocks, and peridotites, cannot represent a crustal section that was already coherent at UHP conditions as it is the common belief currently. The coherency was attained after significant exhumation of these UHP rocks.     

In situ LA-ICP-MS zircon U-Pb age of ultrahigh-pressure eclogites in the Yukahe area,northern Qaidam Basin

Zircon grains were selected from two types of ultrahigh-pressure (UHP) eclogites, coarse-grained phengite eclogite and fine-grained massive eclogite, in the Yukahe area, the western part of the North Qaidam UHP metamorphic belt. Most zircon grains show typical metamorphic origin with residual cores in some irregular grains and sector, planar or misty internal textures on the cathodoluminescence (CL) images. The contents of REE and HREE of the core parts of grains range from 173 to 1680 μg/g and 170 to 1634 μg/g, respectively, in phengite eclogite, and from 37 to 2640 μg/g and 25.7 to 1824 μg/g, respectively, in massive eclogite. The core parts exhibit HREE-enriched patterns, representing the residual zircons of protolith of the Yukahe eclogite. The contents of REE and HREE of the rim parts and the grains free of residual cores are much lower than those for the core parts. They vary from 13.1 to 89.5 μg/g and 12.5 to 85.7 μg/g, respectively, in phengite eclogite, and from 9.92 to 45.8 μg/g and 9.18 to 43.8 μg/g, respectively, in massive eclogite. Negative Eu anomalies and Th/U ratios decrease from core to rim. Positive Eu anomalies are shown in some grains. These indicate that the presence of garnet and the absence of plagioclase in the peak metamorphic mineral assemblage, and the zircons formed under eclogite facies conditions. LA-ICP-MS zircon U-Pb age data indicate that phengite eclogite and massive eclogite have similar metamorphic age of 436±3Ma and 431±4Ma in the early Paleozoic and magmatic protolith age of 783–793 Ma and 748–759 Ma in the Neo-proterozoic. The weighted mean age of the metamorphic ages (434±2 Ma) may represent the UHP metamorphic age of the Yukahe eclogites. The metamorphic age is well consistent with their direct country rocks of gneisses (431±3 Ma and 432±19 Ma) and coesite-bearing pelitic schist in the Yematan UHP eclogite section (423–440 Ma). These age data together with field observation and lithology, allow us to conclude that the Yukahe eclogites were Neo-proterozoic igneous rocks and may have experienced subduction and UHP metamorphism with continental crust at deep mantle during the early Paleozoic, therefore the metamorphic age of 434±2 Ma of the Yukahe eclogites probably represents the continental deep subduction time in this area.

     

Metamorphism, partial preservation, and exhumation of ultrahigh-pressure belts

The Dabie-Sulu belt of east-central China, the Kokchetav Complex of northern Kazakhstan, the Maksyutov Complex of the South Urals, the Dora Maira Massif of the Western Alps, and the Western Gneiss Region of southwestern Norway lie astride intracontinental suture zones. All represent collisional mountain belts. Adjoining Eurasian regions exhibit little or no evidence of a coeval calc-alkaline arc. Each metamorphic complex contains mineralogic and textural relics of the presence or former existence of coesite ± diamond. Other ultrahigh-P, moderate-T metamorphic phases, including K-rich clinopyroxene, Mg-rich garnet, ellenbergerite, lawsonite, Al-rutile, glaucophane, high-Si phengite, and associations such as coesite + dolomite, magnesite + diopside, and talc + kyanite, diopside, jadeite, or phengite also testify to pressures approaching or exceeding 2.8 GPa. Each of the five well-studied Eurasian ultrahigh-pressure complexes consists chiefly of old, cool continental crust. Deep-seated recrystallization took place during the Phanerozoic. Subduction zones constitute the only known plate-tectonic environment where such high-P, low-T conditions exist. A model involving underflow of a salient of continental crust imbedded in oceanic crust-capped lithosphere explains the ultrahigh- pressure metamorphism. Partly exhumed ultrahigh-pressure terranes consist of relatively thin sheets 7 ± 5 km thick. During early stages of plate descent, hydration of relatively anhydrous units occurs, and volatiles are expelled from hydrous rocks. If present, aqueous fluids markedly catalyze reactions. Experimental studies on MORB bulk compositions demonstrate that, for common subduction-zone P–T trajectories, amphibole (the major hydrous phase in metabasaltic rocks) dehydrates at less than ~ 2.0 GPa; accordingly, mafic blueschists and amphibolites expel H₂O at great depth and, except for some coarse-grained, dry metagabbros, tend to recrystallize to eclogite. Serpentinized mantle beneath the oceanic crust devolatilizes at comparable pressures. In contrast, phengite and biotite remain stable to pressures exceeding 3.5 GPa in associated quartzofeldspathic rocks. So, under ultrahigh-pressure conditions, the micaceous lithologies that dominate the continental crust fail to evolve significant H₂O, and may transform incompletely to eclogitic assemblages. Although hydrous rocks expel volatiles during compaction and shallow burial, very deep underflow of partly hydrated oceanic crust + mantle generates most of the volatile flux along and above a subduction zone prior to continental collision. As large masses of sialic crust enter the convergent plate junction, fluid evolution at deep levels severely diminishes, and both convergence and dehydration terminate. After cessation of ultrahigh-pressure recrystallization, tectonic slices of sialic massifs return to shallow depths along the subduction channel, propelled by buoyancy; collisional sheets that retain ultrahigh-pressure effects lose heat efficiently across both upper (extensional, normal fault) and lower (subduction, reverse fault) tectonic contacts. These sheets ascend to midcrustal levels rapidly at average exhumation rates of 2–12 mm/year. Surviving ultrahigh-pressure relics occur as micro-inclusions encased in dense, strong, impermeable, unreactive mineralogic hosts, and are shielded during return towards conditions characteristic of midcrustal levels. Rehydration attending decompression is incomplete; its limited extent reflects the coarse grain size and relative impermeability of the rocks undergoing retrogression, as well as declining temperature and lack of aqueous fluids.     

Prograde pressure-temperature path of jadeite-bearing eclogites and associated high-pressure/low-temperature rocks from western Tianshan, northwest China

Abstract Jadeite‐bearing eclogites and associated blueschists locally crop out in a greenschist facies area at Kuldkourla, near the Akeyazhi River in the western Chinese Tianshan region, northwestern China. Garnet in these metamorphic rocks shows prograde zoning with increasing Mg and decreasing Mn from the crystal center towards the rim, and is divided into Ca‐poor/Fe‐rich core and Ca‐rich/Fe‐poor mantle parts. The garnet cores include the assemblages of (i) jadeite/omphacite (X_jd = 0.34–0.96) + barroisite/taramite; and (ii) omphacite + barroisite/pargasite, with paragonite, epidote, rutile and quartz as major phases with rare albite. The garnet mantles rarely contain inclusions of omphacite, glaucophane, epidote, rutile and quartz. Major matrix phases of the pre‐exhumation stage are omphacite, glaucophane, paragonite, rutile and quartz. These mineral parageneses give pressure (P)‐temperature (T) conditions of 0.9 GPa/390°C?1.4 GPa/560°C for the stage of the garnet core formation, 1.8 GPa/520°C for the stage of the garnet mantle formation, and 2.2 GPa/495°C‐2.4 GPa/535°C for the peak eclogite facies assemblage in the matrix. The estimated P‐T conditions and continuous changes of mineral parageneses imply a counterclockwise P‐T path which is a combination of (i) an early prograde stage of high‐pressure/low‐temperature (HP/LT) blueschist facies and/or LP/LT eclogite facies; (ii) a later prograde stage involving compression with minimal heating; and (iii) a climax‐of‐subduction stage characterized by a slight decrease of temperature with increasing pressure. The negative dP/dT of the latest subduction stage is possibly a record of the following events after a continuous subduction and ridge approach: (i) material migration within the upper part of the subducting slab, which has an inverse thermal gradient caused by ductile flow and/or slab break during subduction; and/or (ii) temporary cooling of the wedge mantle–slab interface by continuous subduction of a relatively cold slab following subduction of a hotter ridge.     

Diamond-bearing and diamond-free metacarbonate rocks from Kumdy–Kol in the Kokchetav Massif, northern Kazakhstan

Abstract Dolomite marble from the Kumdy–Kol area of the Kokchetav Massif contains abundant microdiamond, mainly in garnet and a few in diopside. The mineral assemblage at peak metamorphic condition consists of dolomite + diopside + garnet (+ aragonite) ± diamond. Inclusions of very low MgCO₃ calcite and almost pure calcite occur in diopside and are interpreted as aragonite and/or aragonite + dolomite. Single-phase Mg–calcite in diopside with a very high MgCO₃ component (up to 21.7 mol%) was also found in diamond-free dolomitic marble, and is interpreted as a retrograde product from aragonite + dolomite to Mg–calcite. The dolomite stability constrains the maximum pressure (P) at < 7 GPa using previous experimental data, whereas the occurrence of diamond yields the minimum peak pressure–temperature (P–T) condition at 4.2 GPa and 980 °C at X co ₂ = 0.1. The highest MgCO₃ in Mg–calcite constrains the minimum P–T condition higher than 2.5 GPa and 800 °C for the exhumation stage. As these marbles were subjected to nearly identical P–T metamorphic conditions, the appearance of diamond in some carbonate rocks was explained by high X co ₂. A low X co ₂ condition refers to high oxidized conditions and diamond (and/or graphite) becomes unstable. Difference in X co ₂ for marble from the same area suggests local heterogeneity of fluid compositions during ultrahigh-pressure metamorphism.     

Ultra-high pressure metamorphism of granitic gneiss in the Yinggelisayi area, Altun Mountains, NW China

With the discovery and further studies of high- pressure (HP) to ultra-high-pressure (UHP) eclogites and UHP garnet lherzolite in the Altun Mountains[19], it becomes interesting if the country rocks of these HP-UHP metamorphic rocks also underwent HP-UHP metamorphism, which will be crucial for understand-ing the relationship of HP-UHP metamorphic rocks and their country rocks, the mechanism of their forma-tion and uplifting and the existence of continental deep subduction in the are…     

Petrology of the diamond-grade eclogite in the Kokchetav Massif, northern Kazakhstan

Abstract The Kokchetav Massif of northern Kazakhstan is unique because of the abundant occurrence of microdiamond inclusions in garnet, zircon and clinopyroxene of metasediments. In order to determine precise pressure–temperature (P–T) conditions, we have systematically investigated mineral inclusions and the compositions of major silicates in Ti–clinohumite–garnet peridotite and diamond-grade eclogite from Kumdy–Kol. It was found that garnet peridotites from Kumdy–Kol contain assemblages of garnet, olivine, Ti–clinohumite and ilmenite. The garnet contains inclusions that are indicative of both ultrahigh pressure (UHP) and retrograde conditions. Inclusions of hydrous phases such as chlorite, amphibole and zoisite were formed at the post-UHP stage. The study also found that eclogite from Kumdy–Kol contains albite–augite symplectites after omphacitic pyroxene. The core of pyroxene (sodic augite) contains high K₂O (up to 1wt%; average 0.24wt%). Phengite is included in the core. Applying the K₂O-in-augite geobarometry, which is based on recent experiments, and the garnet–clinopyroxene (Grt–Cpx) geothermometer for peak metamorphism, the eclogites yield P–T estimates of > 6 GPa and > 1000 °C, and the diamond-grade eclogites yield lower temperature estimates at 900–1000 °C and 5 GPa.