北山造山带南部早古生代构造演化：来自花岗岩的约束

北山造山带是中亚造山带的重要组成部分,处于天山造山带和索仑缝合带之间的关键构造位置,对认识中亚造山带的构造演化和古亚洲洋的最终闭合具有重要意义。本文选择北山造山带南部早古生代桥湾糜棱岩化花岗岩和金塔钾长花岗岩进行了LA-ICP-MS锆石U-Pb年代学、LA-MC-ICP-MS锆石Hf同位素和地球化学研究。结果表明,桥湾糜棱岩化花岗岩和金塔钾长花岗岩均形成于~430Ma,岩浆结晶锆石的二阶段Hf模式年龄分别为2.14~2.37Ga和1.32~1.72Ga。样品中含有少量继承锆石,继承锆石的Hf同位素特征与北山南部新元古代花岗质片麻岩类似。在地球化学组成上,两者均具有高的SiO2含量(73.18%~75.00%),弱过铝质,富集Rb、U、K等元素,亏损Ba、Nb、Ta、和Sr、P、Ti等元素的特点,类似于北山南部其它早古生代钾长花岗岩。它们的岩浆均起源于北山南部古老地壳基底的部分熔融,金塔钾长花岗岩可能还有幔源岩浆或新生下地壳的贡献。这同时也暗示了北山南部石板山地块与敦煌地块具有显著不同的地壳基底组成。结合敦煌地块早古生代高压麻粒岩的研究结果,我们认为北山南部早古生代岩浆活动可能与敦煌地块向北山南部石板山地块的碰撞、俯冲作用有关,反映了中亚造山带南缘的北山造山带在早古生代经历了造山带中微陆块与周缘克拉通碰撞拼贴的造山事件。     

东昆仑小灶火软玉中热液锆石U-Pb年龄及Hf同位素特征:对成矿时代的制约

小灶火软玉矿床位于东昆仑造山带西段,同新疆和田玉处于昆仑山脉同一条成矿带上。该矿床软玉种类主要为青玉,其中透闪石含量达99%以上,为特殊的镁矽卡岩矿床。对该矿区青玉及其相关的黑云二长花岗岩进行了系统的LA-MC-ICP-MS锆石微量元素、U-Pb及Lu-Hf同位素研究。结果显示,黑云二长花岗岩中均为具典型韵律振荡环带的岩浆成因锆石,锆石U-Pb定年得到其成岩年龄为415.8±1.7 Ma;锆石ε_(Hf)(t)值为1.5~6.6,亏损地幔Hf模式年龄(tDM)为779~965 Ma,指示黑云二长花岗岩为东昆仑原特提斯造山带后碰撞阶段新生的新元古代地壳物质熔融的产物。青玉中的锆石可分为两类,其中主要锆石群——I类锆石呈补丁状环带、面状环带或无环带,且具有与黑云二长花岗岩中的岩浆锆石明显不同的稀土元素及Hf同位素特征,显示典型的热液锆石特点,其U-Pb年龄416.4±1.5 Ma代表了青玉的形成时间;II类锆石(416 Ma、471 Ma、818 Ma)呈韵律振荡环带,为热液流体从围岩中捕获的继承锆石。小灶火地区成岩-成矿作用的同时性(~416 Ma)表明岩浆岩侵入是软玉矿床形成的岩浆岩条件,软玉成矿作用方式为热液交代和充填作用。值得注意的是,用热液锆石的Hf同位素来示踪软玉成矿流体性质时应十分谨慎,因为成矿热液中的Hf元素在同时结晶的两种不同矿物(热液锆石和透闪石)间发生了重新分配。     

大兴安岭中段扎兰屯南部花岗质糜棱岩岩石成因及地质意义

大兴安岭扎兰屯南部位于中亚造山带东段,兴安地块(XB)与松嫩地块(SB)之间,是探究兴安地块与松嫩地块构造演化过程,乃至中亚造山带东段微地块聚合过程的关键地区.对该地区出露的花岗质糜棱岩进行地质学、地球化学、锆石U-Pb测年分析,以期查明板块俯冲过程中的岩浆作用特征,并尝试限定兴安地块与松嫩地块碰撞拼合时间.LA-ICP-MS锆石U-Pb测年结果表明,花岗质糜棱岩分为两期：Ⅰ期为早泥盆世(～398.8 Ma),Ⅱ期为晚泥盆世末-早石炭世(351.6～365.7 Ma).两期岩石均具有高SiO₂(68.20%～77.90%),富碱(K₂O+Na₂O=6.32%～9.67%),贫镁(MgO=0.22%～0.97%),偏铝质,高钾钙碱性系列的特征.稀土元素分布模式均为右倾[(La/Yb)_N=4.33～10.77],Eu负异常(δEu=0.03～0.13),富集LILE,亏损HFSE,具有I型花岗岩的特征.两期花岗质糜棱岩可能为俯冲背景下岛弧岩浆活动形成的I型-分异I型花岗岩.结合区域构造演化和岩石地球化学...     

内蒙古维拉斯托矿床花岗岩类SHRIMP年代学及Hf同位素研究

维拉斯托铜多金属矿床地处中亚造山带和大兴安岭造山带的叠加复合部位,该矿床花岗岩类锆石SHRIMP U-Pb测年结果显示为(298.0±2.5)Ma、(308.3±4.2)Ma、(313.9±3.4)Ma和(320.5±4.1)Ma,表明该矿区花岗岩类的成岩时代为晚石炭世。岩石地球化学特征表明它们为岩浆弧活动的产物。除花岗闪长岩样品锆石的εHf(t)为-4.1～+4.08外,其他3件黑云母花岗岩、黑云母二长花岗岩、石英闪长岩样品锆石ε_Hf(t)为正值,为+0.4～+9.9,锆石Hf模式年龄的峰值与古亚洲洋发育的时间较为一致,暗示矿区花岗岩类源区物质主要为俯冲的古亚洲洋壳以及少量前寒武纪地壳。矿区花岗岩类系统研究为探讨晚古生代兴蒙造山带的演化过程提供了基础资料,为该铜多金属矿床的成因研究提供了新的证据。     

西藏拉萨地块过铝质花岗岩中继承锆石的物源区示踪及其古地理意义

富含继承锆石的过铝质花岗岩一般来源于富铝质岩石(如变泥质岩)的部分熔融,因而分析这些继承锆石的U-Pb年龄可以像分析沉积岩碎屑锆石的U-Pb年龄一样,提供过铝质花岗岩源区物质中碎屑沉积物物源区的丰富信息。本文报道了中部拉萨地块早侏罗世过铝质花岗岩的全岩地球化学和锆石U-Pb年代学数据,结合拉萨地块已有二叠纪和晚三叠世过铝质花岗岩的继承锆石年代学数据,总结了目前已有的拉萨地块过铝质花岗岩的继承锆石U-Pb年龄特征(共199个谐和测点)。这些过铝质花岗岩属强过铝质S型花岗岩,其中的继承锆石定义了1250~1100Ma(峰值1181±14Ma)和550~450Ma(峰值494±7Ma)2个最突出的年龄群,分别可比于拉萨地块古生代沉积岩的碎屑锆石年龄峰值(约1170Ma)和寒武纪火山岩的侵位时代,明显不同于西羌塘、安多和特提斯喜马拉雅新元古代-古生代沉积岩中的碎屑锆石年龄频谱。拉萨地块过铝质花岗岩中约1181Ma的继承锆石,可能与拉萨地块古生代沉积岩中的同期碎屑锆石一样,都来自澳大利亚南西部Albany-Fraser造山带和东南极Wilkes等地,而约494的继承锆石,既可能来自澳大利亚西部,也可能来自拉萨地块本地。本文提供了拉萨地块与澳大利亚大陆北缘具有古地理联系的过铝质花岗岩继承锆石U-Pb年龄证据。拉萨地块的研究实践表明,采用过铝质花岗岩继承锆石和古生代沉积岩碎屑锆石相结合的锆石U-Pb年代学方法,可为重建冈瓦纳大陆北缘其它微陆块的古地理和构造岩浆演化提供重要约束。     

觉罗塔格造山带阿奇山花岗岩地球化学、锆石U-Pb定年、Lu-Hf同位素及构造意义

为确定觉罗塔格造山带阿奇山花岗岩的成因和构造背景,并为觉罗塔格造山带在海西期-印支期发生了由后碰撞向板内转化的过程提供证据,对阿奇山地区的正长花岗岩和黑云母二长花岗岩进行了锆石U-Pb定年、Hf同位素和岩石地球化学研究。结果表明,两类花岗岩的形成时代分别为(271.7±3.1) Ma和(251.0±3.7) Ma;锆石~(176)Hf/~(177)Hf值分别为0.282 785～0.282 952和0.282 761～0.282 918,ε_(Hf)(t)值分别为6.00～11.65和4.63～10.20;岩体属高钾钙碱性系列,准铝质-弱过铝质的I型花岗岩。综合分析认为,花岗岩体形成于板内构造环境,且觉罗塔格造山带在海西期-印支期发生了由后碰撞向板内转化,这对深入了解天山造山带碰撞后及陆内构造演化过程、板内岩浆活动起源以及区域动力学背景等具有重要意义。     

二连盆地巴彦乌拉铀矿区花岗岩锆石U-Pb年龄和Hf同位素特征及地质意义

二连盆地中部巴彦乌拉地区位于中亚造山带东段,发育有多个砂岩型铀矿床(点)。利用LA-ICP-MS锆石U-Pb同位素和Hf同位素分析对巴彦乌拉地区巴音宝力格隆起东部花岗岩开展了年代学研究。结果显示,2个样品的锆石U-Pb年龄在292±3～288±2 Ma之间,与巴彦乌拉地区巴音宝力格隆起中西部发育的早二叠世花岗岩及流纹岩的年龄范围基本一致。结合区域成岩年代学数据可知,巴彦乌拉地区巴音宝力格隆起发育一条主要由晚石炭世—早二叠世花岗岩及火山岩组成的岩浆岩带。锆石Hf同位素数据显示,2个花岗岩样品的εHf(t)值为+10.6～+18.2,表明其源区为新生下地壳物质。综合区域地质特征可知,中亚造山带东段显生宙的构造-岩浆活动与二连盆地中部及巴彦乌拉地区赛汉组上段砂岩型铀成矿作用关系密切,为砂岩型铀矿床的形成提供了一系列有利条件。     

内蒙古碾子沟钼矿床SHRIMP锆石U-Pb年龄、硫同位素组成及其地质意义

内蒙古碾子沟钼矿床位于中亚-蒙古巨型造山带东段,是一中型石英脉型钼矿床,矿体赋存于燕山期中粗粒黑云母二长花岗岩内的断裂带中,矿体与岩体空间关系密切.文章对赋矿围岩和主要金属硫化物分别开展了单颗粒SHRIMP锆石U-Pb定年和硫同位素测试.获得的黑云母二长花岗岩加权平均年龄为(152.4±1.6) Ma(MSWD=0.2...     

东昆仑东段古特提斯洋俯冲作用——乌妥花岗岩体锆石U-Pb年代学和地球化学证据

东昆仑东段发育了一条晚二叠世-中三叠世以花岗质岩石为主的巨型弧岩浆岩。本文对东昆仑东段的中三叠世乌妥花岗岩体开展了岩石学、LA-ICP-MS锆石U-Pb年代学及地球化学研究。结果表明,乌妥花岗岩体主要包括花岗闪长岩、斑状二长花岗岩和正长花岗岩三种岩石类型,对应的锆石U-Pb年龄分别为248Ma、247Ma和245Ma,形成时代为中三叠世。主量元素特征显示其具有高钾钙碱性、准铝质-弱过铝质的I型花岗岩的属性。球粒陨石标准化稀土元素配分图解具轻稀土明显富集、重稀土亏损和Eu弱负异常-强负异常特征。原始地幔标准化微量元素蛛网图显示富集大离子亲石元素(Cs、Rb、Th、Ba、U等)、亏损高场强元素(Nb、Ti、Ta等)、而Zr和Hf无明显异常的特点。乌妥岩体总体具有负的Hf同位素组成特征,花岗闪长岩εHf(t)为-1. 5～+3. 4、斑状二长花岗岩εHf(t)为-4. 1～-0. 6、正长花岗岩εHf(t)为-6. 9～-0. 9。多种微量元素构造环境判别图解表明其形成于类似安第斯型陆缘弧的构造环境。岩石成因研究表明洋壳俯冲带上部壳幔接触过渡部位多次岩浆MASH过程及分离结晶作用是形成乌妥花岗岩体的重要方式。综合前人东昆仑地区有关三叠纪沉积地层及岩浆岩资料,认为布青山-阿尼玛卿古特提斯洋于晚二叠世向北俯冲于东昆仑地块之下,弧岩浆岩记录的布青山古特提斯洋盆向北俯冲过程一直持续到中三叠世晚期。晚三叠世,东昆仑南缘古特提斯洋盆关闭,东昆仑造山带转换为碰撞及后碰撞造山阶段,并形成了区域上具碰撞构造属性的侵入岩。     

北山造山带南部晚古生代花岗岩?闪长岩的成因与构造意义

北山造山带位于中亚造山带南部,是中亚造山带的重要组成部分.为了进一步深入认识北山造山带晚古生代的构造?岩浆演化过程,选择北山造山带南部石板墩?白墩子地区的晚古生代花岗岩?闪长岩开展了岩石学、锆石U-Pb定年、Hf同位素、微量元素及岩石地球化学研究.LA-ICP-MS锆石U-Pb年代学研究限定了石板墩花岗岩形成于~304~ 302 Ma,石板墩闪长岩形成于~291 Ma,白墩子石英闪长岩形成于~270 Ma.它们的锆石Hf同位素均呈现较亏损的特征（ε_Hf（t）=-2.0~+15.7）,且由老到新,亏损程度依次增加.岩石学和地球化学特征暗示了亏损地幔来源岩浆在北山造山带晚古生代岩浆活动中的主导作用,亏损地幔来源岩浆与古老地壳部分熔融形成的岩浆以不同比例混合,形成了复杂的岩石组合.因此,晚石炭世?早二叠世花岗岩?闪长岩可能形成于后撤式增生造山作用导致的弧后伸展构造环境.      

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.