Geochemistry and charge history of oils from the Yuqi area of Tarim Basin,NW China

The geochemistry, origin and charge history of oils from the Yuqi area of Tarim Basin have been investigated, through GC, GC-MS and fluid inclusion microthermometry analysis. The Yuqi oils accumulated mainly in three intervals: (1) in the Lower-Middle Ordovician Yingshan Formation (O_1-2y) carbonate reservoirs; (2) in the overlying Upper Triassic Halahatang Formation (T₃h); and (3) in the Lower Cretaceous Yageliemu Formation (K₁y) sandstones. Oils from different reservoirs have distinct physical properties, varying from extra-heavy (O_1-2y), heavy (T₃h), to light oils (T₃h and K₁y). However, their geochemical compositions show a high degree of similarity, which indicates that they derive from the same source rock. Abundant tricyclic terpanes, gammacerane, dibenzothiophene and C₂₁C₂₂steranes, together with a low level of diasteranes, indicate an anoxic marine source rock for oils in the Yuqi area. Oil-oil correlation shows that Yuqi oils derive from the same source bed as Tahe oils. The co-occurrence of intact n-alkanes and 25-norhopanes in all the samples supports the proposition that there is a mixture of an early filled severely biodegraded oil and a late filled fresh oil.In this study, charge history is examined on the basis of integration of fluid inclusion homogenization temperature data with 1D burial-thermal history models. Two episodes of oil charging are identified in the O_1-2y reservoir (well YQX1-1) at around 436-420 Ma (Middle-Late Silurian) and 10-3 Ma (Miocene to Pliocene), respectively. For the samples from the T₃h and K₁y intervals, only one episode of oil charge is indicated by the homogenization temperatures of coexisting aqueous inclusions with an inferred timing around 10-3 Ma. The T₃h heavy oil reservoir is assumed to be a secondary hydrocarbon pool, which accumulated by re-migration and re-distribution of hydrocarbons from O_1-2y hydrocarbon pools. The few early biodegraded oils in the K₁y light oils were probably picked up along the migration pathway during the late fresh oil charging.     

Constraining tectonic compression processes by reservoir pressure evolution: Overpressure generation and evolution in the Kelasu Thrust Belt of Kuqa Foreland Basin,NW China

The Kuqa Foreland Basin (KFB) immediately south of the South Tianshan Mountains is a major hydrocarbon producing basin in west China. The Kelasu Thrust Belt in the basin is the most favorable zone for hydrocarbon accumulations. Widespread overpressures are present in both the Cretaceous and Paleogene reservoirs with pressure coefficients up to 2.1. The tectonic compression process in KFB resulted from the South Tianshan Mountains uplift is examined from the viewpoint of the overpressure generation and evolution in the Kelasu Thrust Belt. The overpressure evolution in the reservoir sandstones were reconstructed through fluid inclusion analysis combined with PVT and basin modeling. Overpressures at present day in the mudstone units in the Kelasu Thrust Belt and reservoir sandstones of the Dabei Gas Field and the Keshen zone are believed to have been generated by horizontal tectonic compression. Both disequilibrium compaction and horizontal tectonic compression are thought to contribute to the overpressure development at present day in the reservoir of the Kela-2 Gas Field with the reservoir sandstones showing anomalously high primary porosities and low densities from wireline log and core data. The overpressure evolution for the Cretaceous reservoir sandstone in the Kelasu Thrust Belt evolved through four stages: a normal hydrostatic pressure (>12–5 Ma), a rapidly increasing overpressure (∼5–3 Ma), an overpressure release (∼3–1.64 Ma) and overpressure preservation (∼1.64–0 Ma). Overpressure developed in the second stage (∼5–3 Ma) was generated by disequilibrium compaction as tectonic compression due to the uplift of the Tianshan Mountains acted at the northern monocline of KFB from 5 Ma to 3 Ma, which provided abundant sediments for the KFB and caused the anomalously high sedimentation rate during the N₂k deposition. From 3 Ma to 1.64 Ma, the action of tectonic compression extended from the northern monocline to the Kelasu Thrust Belt and returned to the northern monocline of KFB from 1.64 Ma to present day. Therefore, the horizontal tectonic compression was the dominant overpressure mechanism for the overpressure generation in the third stage (∼3–1.64 Ma) and overpressure caused by disequilibrium compaction from 5 Ma to 3 Ma was only preserved in the Kela-2 Gas Field until present day.     

Diagenetic history of tight sandstones and gas entrapment in the Yulin Gas Field in the central area of the Ordos Basin,China

The Ordos Basin is a large cratonic basin with an area of 250,000 km² in central China. Upper Paleozoic coals and shales serve as gas source rocks with peak generation and migration at the end of the early Cretaceous. Recent exploration has verified the huge gas potential in the “basin-centered gas accumulation system” (BCGAS). However, the mechanism for the gas accumulation is controversial. With an integrated approach of thin-section petrography, ultra-violet fluorescence microscopy, fluid inclusion microthermometry, Raman microspectrometry, scanning electron microscopy, and X-ray diffractometry, we identified diagenetic trapping and evaluated the diagenetic history of sandstone reservoirs in the Yulin Gas Field in the central area, where structural, stratigraphic and/or sedimentary lithologic traps have not been found. It was revealed that three phases of diagenesis and hydrocarbon charging occurred, respectively, in the late Triassic, late Jurassic and at the end of the early Cretaceous. In the first two phases, acidic water entered the reservoir and caused dissolution and cementation, resulting in porosity increase. However, further subsidence and diagenesis, including compaction and cementation, markedly reduced the pore space. At the end of the early Cretaceous, the bulk of the gas migrated into the tight reservoirs, and the BCGAS trap was formed. In the updip portion of this system, cementation continued to occur due to low gas saturation and has provided effective seals to retain gas for a longer period of time than water block in the BCGAS. The mechanism for the gas entrapment was changed from water block by capillary pressure in the BCGAS to diagenetic sealing. The diagenetic seals in the updip portion of the sand body were formed after gas charging, which indicates that there is a large hydrocarbon exploration potential at the basin-centered area.     

Alteration and multi-stage accumulation of oil and gas in the Ordovician of the Tabei Uplift,Tarim Basin,NW China: Implications for genetic origin of the diverse hydrocarbons

The Ordovician is the most important exploration target in the Tabei Uplift of the Tarim Basin, which contains a range of petroleum types including solid bitumen, heavy oil, light oil, condensate, wet gas and dry gas. The density of the black oils ranges from 0.81 g/cm³ to 1.01 g/cm³ (20 °C) and gas oil ratio (GOR) ranges from 4 m³/m³ to 9300 m³/m³. Oil-source correlations established that most of the oils were derived from the Mid-Upper Ordovician marine shale and carbonate and that the difference in oil properties is mainly attributed to hydrocarbon alteration and multi-stage accumulation. In the Tabei Uplift, there were three main periods of hydrocarbon accumulation in the late Caledonian stage (ca. 450–430 Ma), late Hercynian stage (ca. 293–255 Ma) and the late Himalayan stage (ca. 12–2 Ma). The oil charging events mainly occurred in the late Caledonian and late Hercynian stage, while gas charging occurred in the late Hercynian stage. During the late Caledonian stage, petroleum charged the reservoirs lying east of the uplift. However, due to a crustal uplifting episode in the early Hercynian (ca. 386–372 Ma), most of the hydrocarbons were transformed by processes such as biodegradation, resulting in residual solid bitumen in the fractures of the reservoirs. During the late Hercynian Stage, a major episode of oil charging into Ordovician reservoirs took place. Subsequent crustal uplift and severe alteration by biodegradation in the west-central Basin resulted in heavy oil formation. Since the late Himalayan stage when rapid subsidence of the crust occurred, the oil residing in reservoirs was exposed to high temperature cracking conditions resulting in the production of gas and charged from the southeast further altering the pre-existing oils in the eastern reservoirs. A suite of representative samples of various crude oils including condensates, lights oils and heavy oils have been collected for detailed analysis to investigate the mechanism of formation. Based on the research it was concluded that the diversity of hydrocarbon physical and chemical properties in the Tabei Uplift was mainly attributable to the processes of biodegradation and gas washing. The understanding of the processes is very helpful to predict the spatial distribution of hydrocarbon in the Tabei Uplift and provides a reference case study for other areas.     

Molecular and isotopic compositions of bitumens in Silurian tar sands from the Tarim Basin,NW China: Characterizing biodegradation and hydrocarbon charging in an old composite basin

Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in ¹³C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C₂₈ regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.     

Formation of low permeability reservoirs and gas accumulation process in the Daniudi Gas Field,Northeast Ordos Basin,China

The Daniudi Gas Field is a typical large-scale coal-generated wet gas field located in the northeastern Ordos Basin that contains multiple Upper Paleozoic gas-bearing layers and considerable reserves of gas. Based on integrated analysis of reservoir petrology, carbonate cement C–O isotope, geochemistry of source rocks and HC gas and numerical basin modeling, a comprehensive study focusing on the formation of low permeability reservoirs and gas generation process uncovers a different gas accumulation scene in Daniudi Gas Field. The gas accumulation discovered was controlled by the reservoir permeability reduction and gas generation process, and can be divided into two distinct stages by the low permeability reservoir formation time: before the low permeability reservoir formation, the less matured gas was driven by buoyancy, migrated laterally towards NE and then accumulated in NE favorable traps during Late Triassic to early Early Cretaceous; after the low permeability reservoir formation, highly matured gas was driven by excessive pressure, migrated vertically and accumulated in-situ or near the gas-generating centers during early to late Early Cretaceous. The coupling relationship between reservoir diagenetic evolution and gas generation process controlled on gas accumulation of the Daniudi Gas Field. This study will aid in understanding the gas accumulation process and planning further E&D of the Upper Paleozoic super-imposed gas layers in the whole Ordos Basin and other similar super-imposed low permeability gas layer basins.