Adsorption of Metal Ions onto the Chemically Modified Agricultural Waste

This paper discusses about the adsorption of metal ions such as Cu(II), Cd(II), Zn(II), and Ni(II) from aqueous solution by sulfuric acid treated cashew nut shell (STCNS). The adsorption process depends on the solution pH, adsorbent dose, contact time, initial metal ions concentration, and temperature. The adsorption kinetics was relatively fast and equilibrium was reached at 30 min. The adsorption equilibrium follows Langmuir adsorption isotherm model. The maximum adsorption capacity values of the modified cashew nut shell (CNS) for metal ions were 406.6 mg/g for Cu(II), 436.7 mg/g for Cd(II), 455.7 mg/g for Zn(II), and 456.3 mg/g for Ni(II). The thermodynamic study shows the adsorption of metal ions onto the STCNS was spontaneous and exothermic in nature. The kinetics of metal ions adsorption onto the STCNS followed a pseudo‐second‐order kinetic model. The external mass transfer controlled metal ions removal at the earlier stages and intraparticle diffusion at the later stages of adsorption. A Boyd kinetic plot confirms that the external mass transfer was the slowest step involved in the adsorption of metal ions onto the STCNS. A single‐stage batch adsorber was designed using the Langmuir adsorption isotherm equation.     

Modelling of sediment supply from torrent catchments in the Western Alps using the sediment contributing area (SCA) approach

The production of coarse sediment in mountain landscapes depends mainly on the type and activity of geomorphic processes and topographic and natural conditions (e.g. vegetation cover) of these catchments. The supply of sediment from these slopes to mountain streams and its subsequent transport lead to sediment connectivity, which describes the integrated coupled state of these systems. Studies from the Northern Calcareous Alps show that the size of the sediment contributing area (SCA), a subset of the drainage area that effectively delivers sediment to the channel network, can be used as a predictor of sediment delivery to mountain streams. The SCA concept is delineated on a digital elevation model (DEM) using a set of rules related to the steepness and length of slopes directly adjacent to the channel network, the gradient of the latter and the vegetation cover. The present study investigates the applicability of this concept to the Western Alps to identify geomorphologically active areas and to estimate mean annual sediment yield (SY) in mainly debris-flow-prone catchments. We use a statistical approach that shows a parameter optimisation and a linear regression of SY on SCA extent. We use a dataset of ~25 years of assessed coarse sediment accumulation in 35 sediment retention basins. In the investigated catchments, sediment transport is governed by several factors, mainly by the extent of vegetation-free areas with a minimum slope of 23° that is coupled to the channel network with a very low gradient of the latter. With our improved framework, we can show that the SCA approach can be applied to catchments that are widely distributed, in a large spatial scale (hectare area) and very heterogeneous in their properties. In general, the investigated catchments show high connectivity, resulting in significant correlations between long-term average yield and the size of the SCA.     

Basal sediment evacuation by subglacial meltwater: suspended sediment transport from Haut Glacier d'Arolla,Switzerland

Proglacial suspended sediment transport was monitored at Haut Glacier d'Arolla, Switzerland, during the 1998 melt season to investigate the mechanisms of basal sediment evacuation by subglacial meltwater. Sub‐seasonal changes in relationships between suspended sediment transport and discharge demonstrate that the structure and hydraulics of the subglacial drainage system critically influenced how basal sediment was accessed and entrained. Under hydraulically inefficient subglacial drainage at the start of the melt season, sediment availability was generally high but sediment transport increased relatively slowly with discharge. Later in the melt season, sediment transport increased more rapidly with discharge as subglacial meltwater became confined to a spatially limited network of channels following removal of the seasonal snowpack from the ablation area. Flow capacity is inferred to have increased more rapidly with discharge within subglacial channels because rapid changes in discharge during highly peaked diurnal runoff cycles are likely to have been accommodated largely by changes in flow velocity. Basal sediment availability declined during channelization but increased throughout the remainder of the monitored period, resulting in very efficient basal sediment evacuation over the peak of the melt season. Increased basal sediment availability during the summer appears to have been linked to high diurnal water pressure variation within subglacial channels inferred from the strong increase in flow velocity with discharge. Basal sediment availability therefore appears likely to have been increased by (1) enhanced local ice‐bed separation leading to extra‐channel flow excursions and[sol ]or (2) the deformation of basal sediment towards low‐pressure channels due to a strong diurnally reversing hydraulic gradient between channels and areas of hydraulically less‐efficient drainage. Copyright © 2005 John Wiley & Sons, Ltd.     

A method for error analysis of sediment yields derived from estimates of lacustrine sediment accumulation

The logistical demands of coring lake sediments tend to preclude the replicate coring necessary to establish error estimates for measured sedimentary parameters. However, if such parameters are to be used to reconstruct sediment yield, and particularly to identify temporal variability of sediment yield, reasonable error estimates are required. In this paper data from a series of alpine lakes in British Columbia are applied to develop a new method for deriving such estimates. Regression surfaces fitted to point values of sediment mass are used to model the physically controlled spatial variability of sedimentation. Deviations from these surfaces are assumed to represent remaining unstructured variance, which constitutes a conservative error estimate. Application of the technique to the alpine lake dataset gives sediment yield estimates with error ranges of ±7–21 per cent. The potential error is minimized where the spatial variability of sedimentation is strongly predictable. The best fits were achieved for elongate lakes of simple basin morphology. The range of the error estimates is sufficiently low to allow detection of variability in Holocene sediment yield to one of the lakes. By using this technique, absolute sediment yields with associated error estimates may be derived. The associated gains in precision justify multicore approaches to lake sediment‐based reconstructions of sediment yield. Copyright © 2000 John Wiley & Sons, Ltd.     

三峡水库区间来沙量估算及水库排沙效果分析

三峡水库是控制和开发长江的重要工程,具有巨大的防洪、发电、航运等综合效益.水库排沙比是反映水库拦截泥沙程度的重要指标.针对目前三峡水库排沙比计算没有考虑三峡水库区间来沙,结果偏大的问题,依据三峡水库区间水文站2003-2016年实测水文资料,采用水文学法估算了三峡水库区间月、年入库输沙量,分析了三峡水库排沙效果及主要影响因素.结果表明：1）三峡水库区间年均来沙量约1775×10⁴ t,占总入库沙量的10.3%,近年来沙占比有所增大,其中2013-2016年来沙量占总入库沙量的26.9%;2）三峡水库年均排沙比为21.6%,其中围堰蓄水期为34.1%,初期蓄水期为17.0%,试验性蓄水期为15.4%;3）三峡水库采用"蓄清排浑"方式运行,主汛期7-9月的排沙比一般大于枯季,但2013年以后,出现了主汛期排沙比小于枯季的现象;4）入库细颗粒泥沙的排沙比大于粗颗粒泥沙,其中粒径d ≤ 0.062 mm的细颗粒泥沙排沙比为23.4%,0.062 mm0.125 mm的中粗沙排沙比分别为5.5%和11.1%;5）三峡水库排沙比汛期主要受V/Q影响,枯季主要受入库含沙量的影响;当V/Q约为170×10⁴ s时,水库排沙效果最差;分别建立了汛期和枯季排沙比经验计算式.本文的研究成果可为三峡水库水沙优化调度等提供参考.     

Relationship between texture and fractions of inorganic phosphorus in the surface sediment of a reservoir

Inorganic P was fractionated into three categories (NaOH-, BD- and HCI-extractable) for 30 surface sediment samples in La Minilla Reservoir (Sevilla, Spain). The amount of reactive P extracted with NaOH (NaOH-RP) and with HCI (HCI-RP) correlated in a multivariate regression with the clay and sand content of the sediment. This multivariate function should aid in predicting the amount of phosphorus available to the sediment organisms, and it can also contribute to the knowledge of the phosphorus budget of the reservoir.Supported by a Grant from CSIC-CONICET.     

Influence of storm-related sediment storage on the sediment delivery from tributary catchments in the upper Waipaoa River,New Zealand

Although much is known about overall sediment delivery ratios for catchments as components of sediment production and sediment yield, little is known about the component of temporary sediment storage. Sediment delivery ratios focused on the influence of storm-related sediment storage are measured at Matakonekone and Oil Springs tributaries of the Waipaoa River basin, east coast of New Zealand. The terrace deposits of both tributaries show abundant evidence of storm-related sedimentation, especially sediment delivered from Cyclone Bola, a 50 year return rainfall event which occurred in 1988. The sediment delivery ratio is calculated by dividing the volume of sediment transported from a tributary to the main stream by the volume of sediment generated at erosion sites in the tributary catchment. Because the sediment delivery volume is unknown, it can be calculated as the difference between sediment generation volume and sediment storage volume in the channel reach of the tributary. The volume of sediment generated from erosion sites in each tributary catchment was calculated from measurements made on aerial photographs dating from 1960 (1:44 000) and 1988 (1:27 000). The volume of sediment stored in the tributary can be calculated from measurements of cross-sections located along the tributary channel, which are accompanied by terrace deposits dated by counting annual growth rings of trees on terrace surfaces. Sediment delivery ratios are 0·93 for both Matakonekone catchment and Oil Springs catchment. Results indicate that Oil Springs catchment has contributed more than twice the volume of sediment to the Waipaoa River than the Matakonekone catchment (2·75 × 10⁶ m³ vs 1·22 × 10⁶ m³). Although large volumes of sediment are initially deposited during floods, subsequent smaller flows scour away much of these deposits. The sediment scouring rate from storage is 1·25 × 10⁴ m³ a⁻¹ for Matakonekone stream and 0·83 × 10⁴ m³ a⁻¹ for Oil Springs stream. Matakonekone and Oil Springs channels respond to extreme storms by instantaneously aggrading, then gradually excavating the temporarily stored sediment. Results from Matakonekone and Oil Springs streams suggest a mechanism by which event recurrence interval can strongly influence the magnitude of a geomorphic change. Matakonekone stream with its higher stream power is expected to excavate sediment deposits more rapidly and allow more rapid re-establishment of storage capacity. Copyright © 1999 John Wiley & Sons, Ltd.     

博斯腾湖表层沉积物无机碳及其稳定同位素空间异质性

2012年8月,在新疆博斯腾湖13个站点进行表层沉积物采集,分析无机碳及其碳、氧稳定同位素的含量和空间分布特征,探讨该湖表层沉积物无机碳(TIC)的空间变化影响因素.结果表明:2012年,博斯腾湖表层沉积物TIC含量平均值为5.5%,变幅为3.8%~9.8%,而δ13Ccarb和δ18Ocarb平均值分别为0.71‰和-4.4‰,范围为-0.23‰~2.27‰和-5.53‰~-2.55‰.从空间来看,湖泊北岸TIC值明显高于南岸,最高值出现在湖泊西北部的黄水沟水域,而河口区和湖心区最低.总体上,博斯腾湖表层沉积物TIC主要是湖泊自生的,其空间分布主要受开都河、黄水沟等入湖河水的影响,导致水体矿化度和营养盐的空间差异,进而影响了碳酸盐的析出与沉淀.另外,湖泊局部的水动力条件也影响TIC的保存与分布.δ13Ccarb与δ18Ocarb的极显著正相关说明近几年博斯腾湖封闭程度较好,尤其是东部大湖区,属于封闭环境碳酸盐沉淀.     

Natural sediment at a dam and its inorganic materials as adsorbents of praseodymium(Pr(Ⅲ))

The sediment deposited behind a dam(DS) and its inorganic materials(IM-DS) were characterized and used for the removal of praseodymium(Pr) from aqueous solutions. Quartz, albite, and kaolinite were found in the sediment by X-ray diffraction. Kinetic data fit well to a pseudo second-order model, the equilibrium time for DS and IM-DS was 2 h and 3 min, respectively, and the adsorption capacity was higher for Pr/DS(q_e= 4.91 mg/g) than for Pr/IM-DS(q_e= 3.01 mg/g) in these condi...     

Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.     

Estimating instantaneous concentration of suspended sediment using acoustic backscatter from an ADV

The measurement of instantaneous sediment concentration remains a challenging task. In this study, a three-step procedure is proposed to estimate instantaneous sediment concentration using acoustic backscatter from Acoustic Doppler Velocimeter (ADV). The influences of acoustic noise and particle diameter on an ADV's performance was first tested in the laboratory, then the three-step procedure was verified based on field measurements in the Zhongxian and Fengjie reaches in the Three Gorges Reservoir. The first step involves reconstructing the backscatter signal time series. Due to contamination from both the noise floor and spurious spikes, the denoising-despiking method was applied instead of the traditional velocity-despiking methods, and this approach performed well based on spectrum ana-lysis. The second step involves calibrating the sediment concentration against the backscatter signal. A linear relation, whose slope and intercept were calibrated to be dependent on particle diameter, is proposed in double logarithmic coordinates. The third step involves calculating the instantaneous sediment concentration using reconstructed instantaneous backscatter based on the proposed relation. The accuracy of the proposed method was evaluated through consideration of the concentration spec-trum and sediment flux, indicating that the proposed three-step procedure is effective for the mea-surement of instantaneous sediment concentration.     

Evaluation of the method of collecting suspended sediment from large rivers by discharge-weighted pumping and separation by continuous-flow centrifugation

A method for collecting suspended sediment samples has been developed that pumps a discharge-weighted volume of water from fixed depths at four to 40 locations across a river and separates the suspended sediment in the sample using a continuous-flow centrifuge. The efficacy of the method is evaluated by comparing the particle size distributions of sediment collected by the discharge-weighted pumping method with the particle size distributions of sediment collected by depth integration and separated by gravitational settling. The pumping method was found to undersample the suspended sand sized particles (> 63 μm) but to collect a representative sample of the suspended silt and clay sized particles (< 63 μm). The centrifuge separated the silt and clay sized particles (< 63 μm) into three fractions. Based on the average results of processing 17 samples from the Mississippi River and several of its large tributaries in 1990, about 10% of the silt and clay sized material was trapped in a centrifuge bowl-bottom sealing unit containing the nozzle and consisted of mostly medium and coarse silt from 16 to 63 μm. About 74% was retained on a Teflon liner in the centrifuge bowl and consisted of sizes from 0–1 to 63 μm. About 9% was discharged from the centrifuge in the effluent and was finer than 0–1 μm. About 7% was lost during the processes of removing the wet sediment fractions from the centrifuge, drying and weighing. The success of the discharge-weighted pumping method depends on how homogeneously the silt and clay sized particles (< 63 μm) are distributed in the vertical direction in the river. The degree of homogeneity depends on the composition and degree of aggregation of the suspended sediment particles.     

Channel morphodynamics and sediment budget of the Lower Ganga River using a hydrogeomorphological approach

The Ganga River is one of the largest river systems in the world that has built extensive alluvial plains in northern India. The stretch of the Lower Ganga River is vulnerable to siltation because of: (a) the naturally low slope in the alluvial stretch; (b) the confluence of several highly sediment-charged rivers such as the Ghaghra, Gandak, and Kosi; and (c) the reduction in non-monsoon flows because of upstream abstractions of both surface and groundwater. Additionally, the Farakka barrage has impacted the morphology of the Ganga River significantly, both upstream and downstream of the barrage. Large-scale siltation in several reaches has reduced the channel capacity, leading to catastrophic floods in this region even at low discharges. This work has utilized historical remote sensing data and UAV surveys to reconstruct channel morphodynamics and compute sediment volumes accumulated in the channel belt along the Lower Ganga River between Buxar and Farakka. The work was carried out by dividing the total length of the river into four continuous stretches: (a) Buxar–Gandhighat (GW1, 160 km); (b) Gandhighat–Hathidah (GW2, 106 km); (c) Hathidah–Azmabad (GW3, 182 km); and (d) Azmabad–Farakka (GW4, 132 km). We document that major ‘hotspots’ of siltation have developed in several reaches of the Lower Ganga during the last four to five decades. Sediment budgeting using planform maps provides estimates of ‘extractable’ volumes of sediment in GW1, GW2, GW3, and GW4 as 656 ± 48, 706 ± 52, 876 ± 71, and 200 ± 85 Mm³, respectively. These estimates are considerably lower than those computed from the hydrological approach using observed suspended sediment load data, which assumes uniform sedimentation between two stations. Further, our approach provides reach-scale hotspots of aggradation and estimates of extractable sediment volumes, and this can be very useful for river managers to develop a strategic sediment management plan for the given stretch of the Ganga River.     

Characterization of suspended sediment in Meltwater from Glaciers of Garhwal Himalaya

Glacierised basins are significant sources of sediments generated by glacial retreat. Estimation of suspended sediment transfer from glacierised basins is very important in reservoir planning for hydropower projects in Himalaya. The present study indicates that storage and release of sediment in proglacial streams may categorise the pattern of suspended sediment transfer from these basins. Assessment of suspended sediment concentration (SSC), suspended sediment load (SSL) and yield has been undertaken for Dunagiri Glacier basin located in Garhwal Himalaya (30^o33'20”N, 79^o53'36”E), and its results are compared with the Gangotri and Dokriani glaciers sharing close proximity. Out of the total drainage basin area, about 14.3 % of the area is glacierised. Data were collected for five ablation seasons (1984–1989, barring 1986). The mean daily SSCs for July, August and September were 333.9, 286.0 and 147.15 mg/l, respectively, indicating highest concentration of mean daily suspended sediment in July followed by August. SSL trends were estimated to be 93.0, 57.0 and 21.3 tonnes. About 59% of the total SSL of the melt period was transported during the months of August and September. Sediment yield for the study basin was computed to be 296.3 t km^?2 yr ^?1. It is observed that the cumulative proportion of SSC precedes the discharge throughout the melt season except in the year 1987. Release of SSL in terms of total load is less in the early part of melt season than in the later stage as compared to that of discharge. Diurnal variations in SSC reach their maximum at 2400 h, and therefore, SSC was found to be high during night (2000–0400 h). There was a good relationship between SSC and SSL with discharge for the ablation seasons (1988 and 1989). Mean monthly SSC and mean monthly SSL provide a good exponentional relationship with mean monthly temperature. Copyright © 2012 John Wiley & Sons, Ltd.     

The accumulation of radiocesium in coarse marine sediment: effects of mineralogy and organic matter

The controlling factors affecting the accumulation of (137)Cs in marine sediment have not been investigated in detail, especially in coarse grained sediment. Eighty eight coarse marine sediment samples near Wuljin, Korea, were characterized by quantitative X-ray-diffraction (XRD), gamma-ray, and total organic carbon (TOC) analysis. Those factors were then compared. The grain size was in the range of -0.48 to 3.6Mdphi corresponding to sand grains. TOC content was in the range of 0.06-1.75%, and the concentration of (137)Cs was 相似文献   

PAH-degrading microbial consortium and its pyrene-degrading plasmids from mangrove sediment samples in Huian, China

PAH-degrading microbial consortium and its pyrene-degrading plasmids were enriched from the sediment samples of Huian mangroves. The consortium YL showed degrading abilities of 92.1%, 87.6%, 92.3%, and 95.8% for pyrene, fluoranthene, phenanthrene, and fluoene at 50 mg l(-1) after 21 days incubation, respectively. The dynamics of pH changes in the cultures was consistent with that of PAH concentration change. Bacillus cereus Py5 and Bacillus megaterium Py6 were isolated from the consortium and observed consuming 65.8% and 33.7% of pyrene (50 mg l(-1)) within three weeks, respectively. The enriched Escherichia coli DH5alpha cells containing the plasmids of YL were demonstrated to degrade 85.7% of the original pyrene concentration at the 21st day.     

Adsorption behaviour of dibutyl phthalate on marine sediments

Laboratory experiments were carried out to investigate the adsorption behaviour of dibutyl phthalate (DBP) on marine sediments collected from five different sites in Victoria Harbour, Hong Kong. DBP adsorption can be well described by the Langmuir isotherm. The maximum DBP adsorption capacity (Q(max)) of the marine sediments ranges from 53 to 79 mg g(-1), which has a positive correlation with their organic content. Around 90% of the organic can be removed from the sediments with treatment by H(2)O(2) oxidation, and the Q(max) then decreases to a range between 13 and 22 mg g(-1). The black carbon content of the sediments has a much greater DBP adsorption capacity than does the natural organic matter of the sediments. The amount of DBP adsorbed on the sediments increases as the salinity of the marine water increases.     

Prediction of sediment yield by coupling Kalman filter with instantaneous unit sediment graph

An instantaneous unit sediment graph (IUSG) model in conjunction with Kalman filter was investigated for prediction of sediment yield from an upland watershed in Northwestern Mississippi. The state vector of the watershed sediment yield system was constituted by the IUSG and then the sediment yield was estimated by the IUSG model using Kalman filter. The initial values of the state vector were assumed as the average of the IUSG values and the initial sediment yield estimated from the average IUSG. The IUSG model using Kalman filter with a recursive algorithm accurately predicted sediment yield from watershed W‐5, Mississippi. The filter allowed the IUSG to vary in time, increased the accuracy of the IUSG model, and reduced physical uncertainty of the sediment yield process in the watershed. Copyright © 1999 John Wiley & Sons, Ltd.     

Separation of Vanillin and Syringaldehyde from Oxygen Delignification Spent Liquor by Macroporous Resin Adsorption

This paper reports on an approach for separating vanillin and syringaldehyde (VSA) from oxygen delignification spent liquor using non‐polar macroporous resin. The effects of temperature and pH on the adsorption isotherms were studied. The adsorption capacity and adsorption equilibrium constant were obtained using the Langmuir adsorption model at pH<4.5, where the ionization of the VSA to ionic forms was negligible. The standard enthalpy change was calculated using the van't Hoff equation and clearly showed that the adsorption is an exothermic process. The effect of pH on the adsorption isotherm is well‐described by a modified Langmuir model and shows that the adsorption equilibrium constant decreases significantly with the increasing pH. The VSA adsorbed on macroporous resin was eluted by ethyl ether. The separated VSA contained 37.51% vanillin, 31.88% syringaldehyde. The recoveries of VSA were 96.2 and 94.7%, respectively.     

Challenges to the representation of suspended sediment transfer using a depth‐averaged flux

The sediment saturation recovery process (i.e. the adaptation of suspended sediment concentration [SSC] to local forcing) is the main feature of the non‐equilibrium suspended sediment transport (SST) frequently occurring in fluvial, estuarine and coastal waters. In order to quantitatively describe this phenomenon, a series solution is analytically derived, including the evolution of both vertical SSC profile and near‐bed sediment flux (NBSF), and is verified by net erosion and net deposition experiments, respectively. The results suggest that the sediment saturation recovery process involves vertically varying fluxes that are not represented correctly by depth‐averaging. Consequently, a vertical two‐dimensional (2D) combined scheme is established and applied respectively in to a dredged trench and to a sand wave feature to demonstrate this argument. By analyzing the variations of the calculated depth‐averaged SSC and NBSF we reveal that the equilibrium state presented by the sediment carrying capacity (SCC) form of the NBSF, which is usually applied in depth‐integrated SST models, lags behind the actual dynamic bed equilibrium state. Moreover, the key factor α, the so‐called saturation recovery coefficient within this form, is not only a function of local Rouse number but also is influenced by the local SSC profile. Finally, a three‐dimensional (3D) non‐orthogonal curvilinear body‐fitted SST model is developed and validated in the Yangtze estuary, China, combined with the in situ hourly hydrographic data from August 14–15, 2007 during spring tide in the wet season. Model results confirm that the vertically varying sediment saturation recovery process, the discrepancies between the actual and SCC form of NBSF and non‐constant value of α are significant in actual real geomorphic cases. The quantitative morphological change resulting from variations in environmental conditions may not be correctly represented by uncorrected depth‐integrated SST models if they do not treat the effects of vertical motion on the sediment saturation recovery process. Copyright © 2016 John Wiley & Sons, Ltd.