A discussion on the boundary between diagenesis and metamorphism with reference to zeolite facies

Abstract A Triassic formation in the Turpan-Hami and Ordos basin of China gives two typical examples of occurrence of laumontite belonging to diagenetic facies. Sandstones of the Upper Triassic Yanchang Formation in the eastern sector of the Ordos basin are formed at the mature stage of mesodiagenesis at temperatures in the range of 71-120°C, while the temperatures of the oil-bearing beds Chang-6 and Chang-7 where laumontite is present are about 81-88°C. The laumontite-bearing beds of the Middle Triassic in the Hami depression are presently at the supermature stage of organic matter, the corresponding diagenetic temperature being about 140 °C. The term zeolite facies should be rejected, and the features of metamorphic stage should be clearly denned, such as closely packed grains, absence of pores and cements, and characteristic mineral assemblages including sericite, epidote, muscovite, illite (2M₁), chlorite (IIb, β= 97°), dickite, pyrophyllite, graphite, chlorozeolite formed at temperatures of 200°C and Ro values of 2.5%; the stage is also characterized by schistosity and illite crystallinity of IC = 0.42°Δ 2θ. The anchimetamorphic zone is characterized by some characteristic minerals such as paragonite, rectorite, albite, laumontite, illite (1M), chlorite (Ib, P = 90°+ IIb, β= 97°) formed at temperatures of 130-200°C and Ro values of 1.3-2.5% as well as other quantitative parameters of organic matter.     

Capelinhos 1957–1958, Faial, Azores: deposits formed by an emergent surtseyan eruption

The 1957–1958 eruption of Capelinhos, Faial island, Azores, involved three periods of surtseyan, hydromagmatic activity: two in 1957 and one in 1958. Deposits from this eruption are exposed both in sea cliffs cut into the flanks of the tuff cone and more distally >1 km from the vent. Five lithofacies are identified: lithofacies I is composed of even thickness beds with laterally continuous internal stratigraphy and is interpreted to have been formed by fallout. Lithofacies II consists of beds with internally discontinuous lenses, and has sand-wave structures that increase in abundance toward the outer margins of the tuff cone. This lithofacies is interpreted as having been deposited from pyroclastic surges. Lithofacies III is composed of mantle-bedded deposits with laterally discontinuous internal stratigraphy. This lithofacies is interpreted to have been formed by hybrid processes where fallout of tephra occurred simultaneously with pyroclastic surges. In the outer flanks of the tuff cone, lithofacies III grades laterally into fallout beds of lithofacies I. Lithofacies IV consists of alternating beds of coarse ash aggregates and non-aggregated fine ash, and is particularly well developed in distal regions. Some of this facies was formed by fallout. Alternating beds also occur plastered against obstacles up to 2 km from the vent, indicating an origin from wet pyroclastic surges. The orientation of plastered tephra indicates that the surges were deflected by topography as they decelerated. The distinction between surge and fallout in distal regions is uncertain because wind-drifted fallout and decelerating surge clouds can generate similar deposits. Lithofacies V consists of scoria lapilli beds interpreted to be fallout from hawaiian-style fire-fountaining in the later stages of the eruption. Juvenile pyroclasts within hydromagmatic deposits are predominantly poorly vesicular (25–60% of clasts <30% vesicles). However, on both micro- and macroscopic scales, there is a wide range in clast vesicularity (up to 70% vesicles) indicating that, although fragmentation was predominantly hydromagmatic, vesiculation and magmatic-volatile-driven fragmentation operated simultaneously.     

Two examples of subaqueously welded ash-flow tuffs: the Visean of southern Vosges (France) and the Upper Cretaceous of northern Anatolia (Turkey)

Pyroclastic deposits interpreted as subaqueous ash-flow tuff have been recognized within Archean to Recent marine and lacustrine sequences. Several authors proposed a high-temperature emplacement for some of these tuffs. However, the subaqueous welding of pyroclastic deposits remains controversial.The Visean marine volcaniclastic formations of southern Vosges (France) contain several layers of rhyolitic and rhyodacitic ash-flow tuff. These deposits include, from proximal to distal settings, breccia, lapilli and fine-ash tuff. The breccia and lapilli tuff are partly welded, as indicated by the presence of fiamme, fluidal and axiolitic structures. The lapilli tuff form idealized sections with a lower, coarse and welded unit and an upper, bedded and unwelded fine-ash tuff. Sedimentary structures suggest that the fine-ash tuff units were deposited by turbidity currents. Welded breccias, interbedded in a thick submarine volcanic complex, indicate the close proximity of the volcanic source. The lapilli and fine-ash tuff are interbedded in a thick marine sequence composed of alternating sandstones and shales. Presence of a marine stenohaline fauna and sedimentary structures attest to a marine depositional environment below storm-wave base.In northern Anatolia, thick massive sequences of rhyodacitic crystal tuff are interbedded with the Upper Cretaceous marine turbidites of the Mudurnu basin. Some of these tuffs are welded. As in southern Vosges, partial welding is attested by the presence of fiamme and fluidal structures. The latter are frequent in the fresh vitric matrix. These tuff units contain a high proportion of vitroclasis, and were emplaced by ash flows. Welded tuff units are associated with non-welded crystal tuff, and contain abundant bioclasts which indicate mixing with water during flowage. At the base, basaltic breccia beds are associated with micritic beds containing a marine fauna. The welded and non-welded tuff sequences are interbedded in an alternation of limestones and marls. These limestones are rich in pelagic microfossils.The evidence above strongly suggest that in both examples, tuff beds are partly welded and were emplaced at high temperature by subaqueous ash flows in a permanent marine environment. The sources of the pyroclastic material are unknown in both cases. We propose that the ash flows were produced during submarine fissure eruptions. Such eruptions could produce non-turbulent flows which were insulated by a steam carapace before deposition and welding. The welded ash-flow tuff deposits of southern Vosges and northern Anatolia give strong evidence for existence of subaqueous welding.     

The origin of strata within the inner accretionary prism of Nankai Trough: Evidence from clay mineral assemblages along the NanTroSEIZE transect

One of the more prominent architectural elements of the Nankai subduction margin, offshore southwest Japan, is an out‐of‐sequence thrust fault (megasplay) that separates the inner accretionary prism from the outer prism. The inner prism (hanging wall of the megasplay) is dominated by mudstone, which is enigmatic when the sedimentary facies is compared to coeval deposits in the Shikoku Basin (i.e. inputs from the subducting Philippine Sea plate) and to coarser‐grained turbidite sequences from the Quaternary trench wedge. Clay mineral assemblages amplify the mismatches of sedimentary facies. Mudstones from the inner prism are uniformly depleted in smectite, with average bulk values of 23–24 wt%, whereas the Shikoku Basin deposits show progressive decreases in proportions of smectite over time, from averages of 46–48 wt% at 10 Ma to 17–21 wt% at 1 Ma. Plate‐boundary reconstructions for the Philippine Sea region provide one solution to the conundrum. Between 15 Ma and 10 Ma, the Pacific plate subducted near the NanTroSEIZE transect, and a trench‐trench‐trench triple junction migrated to the northeast. Accretion during that period involved sediments that had been deposited on the Pacific plate. Motion of the Philippine Sea plate changed from 10 Ma to 6 Ma, resulting in sinistral slip along the proto‐Nankai Trough. Sediments accreted during that period probably had been deposited near the triple junction, with a hybrid detrital provenance. Renewed subduction of the Philippine Sea plate at 6 Ma led to reorganization of watersheds near the Izu–Honshu collision zone and gradual incision of large submarine canyons on both sides of the colliding Izu arc. Accreted Pliocene mudstones share more of an affinity to the triple junction paleoenvironment than they do to Shikoku Basin. These differences between subducting Shikoku Basin strata and accreted Pacific plate sediments have important implications for interpretations of frictional properties, structural architecture, and diagenetic fluid production.     

利用地球物理方法探测火山沉积型硼矿——在西藏阿里地区的应用

火山沉积型硼矿形成于新近纪特定的火山+湖相沉积环境条件下,含硼地层具有含硼湖相沉积岩与凝灰岩、安山岩等火山岩互层的多旋回二元沉积结构的特点.由于硼酸盐矿物的沉积发生多在沉积后期,通常与凝灰岩、粘土、灰岩等互层沉积,因此形成的硼矿层具有低密度、低电阻率的特征.针对硼矿层的这种特征,采用综合地球物理技术进行探测.在西藏雄巴地区,首先进行了1:5万高精度重力勘探,获得了研究区的布格重力异常,通过对重力资料的处理分析,获取了研究区的断裂构造发育和重力异常变化,推断了地下地层岩性空间变化特点并圈定出火山沉积型硼矿的发育有利区;在此基础上对有利区域进行了1:5000音频大地电磁测深,获得了研究区地下地层电性结构特征.通过对研究区电法数据的震电拟合及重力和大地电磁资料联合反演并与研究区地质资料相结合,进一步分析了该区地层构造、断裂体系、沉积单元与火山沉积型硼矿的形成关系,并对该区火山沉积型硼矿的分布进行了预测,最终钻探验证结果与预测结果基本一致.     

Geology and age model of the Lower Pleistocene Nojima,Ofuna, and Koshiba Formations of the middle Kazusa Group,a forearc basin‐fill sequence on the Miura Peninsula,the Pacific side of central Japan

We present field and core observations, nannofossil biostratigraphy, and stable oxygen isotope fluctuations in foraminiferal tests to describe the geology and to construct an age model of the Lower Pleistocene Nojima, Ofuna, and Koshiba Formations (in ascending order) of the middle Kazusa Group, a forearc basin‐fill succession, exposed on the northern Miura Peninsula on the Pacific side of central Japan. In the study area, the Nojima Formation is composed of sandy mudstone and alternating sandy mudstone and mudstone, the Ofuna Formation of massive mudstone, and the Koshiba Formation of sandy mudstone, muddy sandstone, and sandstone. The Kazusa Group contains many tuff beds that are characteristic of forearc deposits. Thirty‐six of those tuff beds have characteristic lithologies and stratigraphic positions that allow them to be traced over considerable distances. Examination of calcareous nannofossils revealed three nannofossil datum planes in the sequences: datum 10 (first appearance of large Gephyrocapsa), datum 11 (first appearance of Gephyrocapsa oceanica), and datum 12 (first appearance of Gephyrocapsa caribbeanica). Stable oxygen isotope data from the tests of the planktonic foraminifer Globorotalia inflata extracted from cores were measured to identify the stratigraphic fluctuations of oxygen isotope ratios that are controlled by glacial–interglacial cycles. The observed fluctuations were assigned to marine isotope stages (MISs) 49–61 on the basis of correlations of the fluctuations with nannofossil datum planes. Using the age model obtained, we estimated the ages of 24 tuff beds. Among these, the SKT‐11 and SKT‐12 tuff beds have been correlated with the Kd25 and Kd24 tuff beds, respectively, of the Kiwada Formation on the Boso Peninsula. The Kd25 and Kd24 tuff beds are widely recognized in Pleistocene strata in Japan. We used our age model to date SKT‐11 at 1573 ka and SKT‐12 at 1543 ka.     

Oxygen isotope evidence for submarine hydrothermal alteration of the Del Puerto ophiolite, California

The oxygen isotope compositions and metamorphic mineral assemblages of hydrothermally altered rocks from the Del Puerto ophiolite and overlying volcaniclastic sedimentary rocks at the base of the Great Valley sequence indicate that their alteration occurred in a submarine hydrothermal system. Whole rock δ¹⁸O compositions decrease progressively down section (with increasing metamorphic grade): +22.4‰ (SMOW) to +13.8 for zeolite-bearing volcaniclastic sedimentary rocks overlying the ophiolite; +19.6 to +11.6 for pumpellyite-bearing metavolcanic rocks in the upper part of the ophiolite's volcanic member; +12.3 to +8.1 for epidote-bearing metavolcanic rocks in the lower part of the volcanic member; +8.5 to +5.7 for greenschist facies rocks from the ophiolite's plutonic member; +7.6 to +5.8 for amphibolite facies or unmetamorphosed rocks from the plutonic member.

Modelling of fluid-rock interaction in the Del Puerto ophiolite indicates that the observed pattern of upward enrichment in whole rock δ¹⁸O can be best explained by isotopic exchange with discharging¹⁸O-shifted seawater at fluid/rock mass ratios near 2 and temperatures below 500°C.¹⁸O-depleted plutonic rocks necessarily produced during hydrothermal circulation were later removed as a result of tectonism. Submarine weathering and later burial metamorphism at the base of the Great Valley sequence cannot by itself have produced the zonation of hydrothermal minerals and the corresponding variations in oxygen isotope compositions. The pervasive zeolite and prehnite-pumpellyite facies mineral assemblages found in the Del Puerto ophiolite may reflect its origin near an island arc rather than deep ocean spreading center.     

青藏高原盐湖类沉积及盐湖矿物

上新世盐类沉积仅分布于柴达木盆地两部、昆仑山和唐古拉山北坡;晚更新世-全新世盐类沉积广布于羌塘和柴达木盆地。盐湖沉积只有蒸发岩和碎屑沉积物互层特点, 系干湿交替的内陆气候和动荡浅水环境下的湖相沉积。迄今已发现62种盐类矿物, 其析出具有阶段性特征, 青藏更新世-全新世盐湖自析阶段的起始时间分别为¹⁴C 24000和9000a B.P., 钾盐和硼酸盐各有两种典型的矿物共生组合。丰富的盐湖矿物资源是该区走向繁荣的物质基础之一。     

Large phreatomagmatic vent complex at Coombs Hills, Antarctica: Wet, explosive initiation of flood basalt volcanism in the Ferrar-Karoo LIP

The Mawson Formation and correlatives in the Transantarctic Mountains and South Africa record an early eruption episode related to the onset of Ferrar-Karoo flood basalt volcanism. Mawson Formation rocks at Coombs Hills comprise mainly (≥80% vol) structureless tuff breccia and coarse lapilli tuff cut by irregular dikes and sills, within a large vent complex (>30 km²). Quenched juvenile fragments of generally low but variable vesicularity, accretionary lapilli and country rock clasts within vent-fill, and pyroclastic density current deposits point to explosive interaction of basalt with groundwater in porous country rock and wet vent filling debris. Metre-scale dikes and pods of coherent basalt in places merge imperceptibly into peperite and then into surrounding breccia. Steeply dipping to sub-vertical depositional contacts juxtapose volcaniclastic rocks of contrasting componentry and grainsize. These sub-vertical tuff breccia zones are inferred to have formed when jets of debris + steam + water passed through unconsolidated vent-filling deposits. These jets of debris may have sometimes breached the surface to form subaerial tephra jets which fed subaerial pyroclastic density currents and fall deposits. Others, however, probably died out within vent fill before reaching the surface, allowing mixing and recycling of clasts which never reached the atmosphere. Most of the ejecta that did escape the debris-filled vents was rapidly recycled as vents broadened via lateral quarrying of country rock and bedded pyroclastic vent-rim deposits, which collapsed along the margins into individual vents. The unstratified, poorly sorted deposits comprising most of the complex are capped by tuff, lapilli tuff and tuff breccia beds inferred to have been deposited on the floor of the vent complex by pyroclastic density currents. Development of the extensive Coombs Hills vent-complex involved interaction of large volumes of magma and water. We infer that recycling of water, as well as recycling of pyroclasts, was important in maintaining water supply for phreatomagmatic interactions even when aquifer rock in the vent walls lay far from eruption sites as a consequence of vent-complex widening. The proportion of recycled water increased with vent-complex size in the same way that the proportion of recycled tephra did. Though water recycling leaves no direct rock record, the volcaniclastic deposits within the vent complex show through their lithofacies/structural architecture, lithofacies characteristics, and particle properties clear evidence for extensive and varied recycling of material as the complex evolved. Editorial responsibility: J. Donnelly-Nolan     

The 322 ka Tiribí Tuff: stratigraphy, geochronology and mechanisms of deposition of the largest and most recent ignimbrite in the Valle Central, Costa Rica

The Tiribí Tuff covered much of the Valle Central of Costa Rica, currently the most densely populated area in the country (∼2.4 million inhabitants). Underlying the tuff, there is a related well-sorted pumice deposit, the Tibás Pumice Layer. Based on macroscopic characteristics of the rocks, we distinguish two main facies in the Tiribí Tuff in correlation to the differences in welding, devitrification, grain size, and abundance of pumice and lithic fragments. The Valle Central facies consists of an ignimbritic plateau of non-welded to welded deposits within the Valle Central basin and the Orotina facies is a gray to light-bluish gray, densely to partially welded rock, with yellowish and black pumice fragments cropping out mainly at the Grande de Tárcoles River Gorge and Orotina plain. This high-aspect ratio ignimbrite (1:920 or 1.1×10⁻³) covered an area of at least 820 km² with a long runout of 80 km and a minimum volume outflow of 25 km³ (15 km³ DRE). Geochemically, the tuff shows a wide range of compositions from basaltic-andesites to rhyolites, but trachyandesites are predominant. Replicate new ⁴⁰Ar/³⁹Ar age determinations indicate that widespread exposures of this tuff represent a single ignimbrite that was erupted 322±2 ka. The inferred source is the Barva Caldera, as interpreted from isopach and isopleth maps, contours of the ignimbrite top and geochemical correlation (∼10 km in diameter). The Tiribí Tuff caldera-forming eruption is interpreted as having evolved from a plinian eruption, during which the widespread basal pumice fall was deposited, followed by fountaining pyroclastic flows. In the SW part of the Valle Central, the ignimbrite flowed into a narrow canyon, which might have acted as a pseudo-barrier, reflecting the flow back towards the source and thus thickening the deposits that were filling the Valle Central depression. The variable welding patterns are interpreted to be a result of the lithostatic load and the influence of the content and size of lithic fragments.     

Origin of some bedded welded tuffs

Well defined, laterally continuous welded tuff beds from <1 cm to 2 m thick are more common than has previously been recognized. Examples ranging in composition from rhyolitic to basaltic are described from Ordovician volcanic areas in Britain and Norway, and from the Miocene of the Canary Islands. Bedded welded tuffs are most common in areas of alkaline and peralkaline acidic pyroclastics. They generally occur within successions of massive, welded ash-flow tuff, or within non-welded air-fall tuff successions. Sequences consisting entirely of bedded welded tuff range from <1 m up to 75 m thick. Bedded welded tuffs are thought to originate in three ways. Poorly sorted, thick-bedded welded tuffs are interpreted as the deposits of pyroclastic flows, in which case the beds represent either individual flows units or the layers within flow units. Better sorted, thin-bedded welded tuffs are thought to be of air-fall origin. Thirdly, welding may be produced by the effects of an external heat source on non-welded bedded tuffs.     

Eruption processes and deposit characteristics at the monogenetic Mt. Gambier Volcanic Complex, SE Australia: implications for alternating magmatic and phreatomagmatic activity

The ～5 ka Mt. Gambier Volcanic Complex in the Newer Volcanics Province, Australia is an extremely complex monogenetic, volcanic system that preserves at least 14 eruption points aligned along a fissure system. The complex stratigraphy can be subdivided into six main facies that record alternations between magmatic and phreatomagmatic eruption styles in a random manner. The facies are (1) coherent to vesicular fragmental alkali basalt (effusive/Hawaiian spatter and lava flows); (2) massive scoriaceous fine lapilli with coarse ash (Strombolian fallout); (3) bedded scoriaceous fine lapilli tuff (violent Strombolian fallout); (4) thin–medium bedded, undulating very fine lapilli in coarse ash (dry phreatomagmatic surge-modified fallout); (5) palagonite-altered, cross-bedded, medium lapilli to fine ash (wet phreatomagmatic base surges); and (6) massive, palagonite-altered, very poorly sorted tuff breccia and lapilli tuff (phreato-Vulcanian pyroclastic flows). Since most deposits are lithified, to quantify the grain size distributions (GSDs), image analysis was performed. The facies are distinct based on their GSDs and the fine ash to coarse+fine ash ratios. These provide insights into the fragmentation intensities and water–magma interaction efficiencies for each facies. The eruption chronology indicates a random spatial and temporal sequence of occurrence of eruption styles, except for a “magmatic horizon” of effusive activity occurring at both ends of the volcanic complex simultaneously. The eruption foci are located along NW–SE trending lineaments, indicating that the complex was fed by multiple dykes following the subsurface structures related to the Tartwaup Fault System. Possible factors causing vent migration along these dykes and changes in eruption styles include differences in magma ascent rates, viscosity, crystallinity, degassing and magma discharge rate, as well as hydrological parameters.     

Growth of an emergent tuff cone: Fragmentation and depositional processes recorded in the Capelas tuff cone,São Miguel,Azores

The Capelas tuff cone is an emergent Surtseyan-type tuff cone that erupted in shallow seawater off the coast of São Miguel, Azores. In this paper, we present a detailed stratigraphic study which is used to infer depositional processes and modes of fragmentation for the Capelas tuff cone deposits. The growth of the tuff cone can be divided into three stages based on variations in depositional processes that are probably related to differences in water/magma (W/M) ratios. The first stage corresponds well to wet Surtseyan-type activity where wet fallout is the dominant depositional process, with only minor representation of pyroclastic surge deposits. The second stage of the eruption is suggested to be the result of alternating wet and slightly drier periods of Surtseyan activity, with an overall lower W/M-ratio compared to the first stage. The drier Surtseyan periods are characterized by the presence of minor grain-flow deposits and undulating pyroclastic surge deposits that occasionally display relatively dry structures such as strongly grain-segregated layers and brittle behavior when impacted by ballistic ejecta. The first deposits of the second stage show an intense activity of pyroclastic surges but fallout, commonly modified by surges, is still the dominant depositional process during the second stage. The third stage represents a final effusive period, with the build-up of a scoria cone and ponded lava flows inside the tuff cone crater.Phreatomagmatic fragmentation, as seen by studies of the fine ash fraction (< 64 μm), is dominant in the Capelas tuff cone. However, particles with shapes and vesicularities characteristic of magmatic fragmentation are abundant in proximal deposits and present in all investigated beds (in various amounts). Emergent Surtseyan-type tuff cones are characterized by a domination of fallout deposits, both wet and dry, where dry periods are characterized by the deposition of relatively dry falling tephra transforming into grain-flow deposits. However, this study of the Capelas tuff cone shows that drier Surtseyan periods may also be represented by an increased amount of thin surge deposits that occasionally display dry features.     

香港安山-英安质古火山颈群

香港中侏罗世屯门组火山岩主要由安山质熔岩、凝灰岩和凝灰角砾岩夹少量凝灰质砂岩组成。其中凝灰角砾岩初期曾误认为是沉积砾岩。1990年香港地质调查组重新研究后,确认是火山成因的凝灰角砾岩。按岩相分析,屯门组火山岩可分为火山通道相安山-英安质熔岩和爆发角砾岩,还有爆发空落相凝灰角砾岩。火山通道相又可分为火山颈相和岩墙相,分布在屯门组东西两侧。在青山东麓,出露一列NNW向呈断续、线状分布的火山颈群。近年来新出版的《香港地质考察指引》和《香港工程地质实践》等地质著作仍将该区爆发角砾岩误认为是沉积成因的砾岩,在地质勘探和工程设计上造成混乱,导致不应有的经济和时间上的损失。本文综合最新研究成果并与世界各地同类火山岩的特征进行对比,确证火山通道相爆发角砾岩的存在,并发现呈线状分布的古火山颈群。     

Strombolian and phreatomagmatic deposits of Ohakune craters, Ruapehu, New Zealand: A complex interaction between external water and rising basaltic magma

The Ohakune Craters form one of several parasitic centres surrounding Ruapehu volcano, at the southern end of the Taupo Volcanic Zone. An inner scoria cone and an outer, probably older, tuff ring are the principal structures in a nested cluster of four vents.The scoria cone consists of alternating lava flows and coarse, welded and unwelded, strombolian block and bomb beds. The strombolian beds consist of principally two discrete types of essential clast, vesicular bombs and dense angular blocks. Rare finer-grained beds are unusually block-rich. The tuff ring consists of alternating strombolian and phreatomagmatic units. Strombolian beds have similar grain size characteristics to scoria cone units, but contain more highly vesicular unoxidised bombs and few blocks. Phreatomagmatic deposits, which contain clasts with variable degrees of palagonitisation, consist of less well-sorted airfall deposits and very poorly sorted, crystal-rich pyroclastic surge deposits.Disruption by expanding magmatic gas bubbles was a major but relatively constant influence on both strombolian and phreatomagmatic eruptions at Ohakune. Instead, the nature of deposits was principally controlled by two other variables, vent geometry and the relative influence of external water during volcanism. During tuff-ring construction, magma is considered to have risen rapidly to the surface, and to have been ejected without sufficient residence time in the vent for non-explosive degassing. Availability of external water principally governed the eruption mechanism and hence the nature of the deposits. Essentials clasts of the scoria cone are, by comparison, dense, degassed and oxidised. It is suggested that a change in vent geometry, possibly the construction of the tuff ring itself, permitted lava ponding and degassing during scoria cone growth. During strombolian eruptions, magma remaining in the vent probably became depleted in gas, leading to the formation of an inert zone, or crust, above actively degassing magma. Subsequent explosions had therefore to disrupt both this passive crust and underlying, vesiculating magma “driving” the eruption. Cycles of strombolian eruption are thought to have stopped when the thickness of the inert crust precluded explosive eruption and only recommenced when some of this material was removed, either as a lava flow or during phreatomagmatic explosions when external water entered the vent. Such explosions probably formed the unusually fine-grained and block-rich beds in the strombolian sequence.The Ohakune deposits are an excellent example of the products of explosive eruption of fluid, gas-rich basic magma vesiculating under very near-surface conditions. A complex interplay of rate of magma rise, rate and depth of formation of gas bubbles, vent geometry, abundance of shallow external water, wind velocity and accumulation rate of ejecta determines the nature of deposits of such eruptions.     

Block‐and‐ash flow deposit of the Narcondam Volcano: Product of dacite–andesite dome collapse in the Burma–Java subduction complex

Narcondam Island in the Andaman Sea represents a dacite–andesite dome volcano in the volcanic chain of the Burma–Java subduction complex. The pyroclasts of andesitic composition are restricted to the periphery of the dome predominantly in the form of block‐and‐ash deposits and minor base surge deposits. Besides pyroclastic deposits, andesitic lava occurs dominantly at the basal part of the dome whereas dacitic lava occupies the central part of the dome. The pyroclasts are represented by non‐vesiculated to poorly vesiculated blocks of andesite, lapilli, and ash. The hot debris derived from dome collapse was deposited initially as massive to reversely‐graded beds with the grain support at the lower part and matrix support at the upper part. This sequence is overlain by repetitive beds of lapilli breccia to tuff breccia. These deposits are recognized as a basal avalanche rather than lahar deposit. This basal avalanche was punctuated by an ash‐cloud surge deposit representing a sequence of thinly bedded units of normal graded unit to parallel laminated beds.     

Mineral chemistry,P-T-t paths and exhumation processes of mafic granulites in Dinggye,Southern Tibet

Lower crustal high grade metamorphic rocks have been successively found at Pamirs nearby the western Himalayan syntaxis, Namjagbarwa and Dinggye nearby the eastern Himalayan syntaxis and the central segment of the Himalayan Orogenic Belt, respec-tively[1―4]. In particular, some researchers deduced that there were probably eclogites at some locations[5]. Moreover, some geochronological data of these lower crustal granulites also have been accumulated. For example, the high-pressure granulit…     

金属矿产勘查技术发展现状与思考

近年来，以寻找金属矿产为目的发愤卢业的勘查新技术可概括为：（1）以寻找隐伏矿为目标的覆盖区地球物理勘查技术，其中包括“三维地震”和“高光谱遥感”技术；（2）地球化学勘查新技术，其中包括“深穿透地球化学技术”、“地球化学信息的综合解释和地球化学填图技术”；（3）“找矿信息提取和综合”技术等。限于篇幅，本文仅对地球化学勘查新技术的研究现状进行了分析，同时对下列问题进行了思考：（1）在一个地区开展地球化学找矿工作首先要确立合适的取样介质，取样介质的立应以查明成矿成晕元素的形成机制和赋存状态为基础；（2）加强不同景观条件下不同矿种和不同矿床类型的异常特征和异常模式研究，建立区分矿异常和非矿异常的模式识别模型；（3）加强不同景观地质条件下，不同勘查尺度的地球化学填图技术研究，以实现迅速掌握全局，逐步缩小靶区的找矿战略；（4）加强地球化学信息与地质、地球物理和遥感信息相结合的信息综合技术的研究，应用综合信息定量圈定和评价找矿靶区，减少矿产勘查的不确定性。     

Alteration and mass transfer inferred from the Hirabayashi GSJ drill penetrating the Nojima Fault, Japan

Abstract Mineralogical and geochemical studies on the fault rocks from the Nojima–Hirabayashi borehole, south-west Japan, are performed to clarify the alteration and mass transfer in the Nojima Fault Zone at shallow depths. A complete sequence from the hornblende–biotite granodiorite protolith to the fault core can be observed without serious disorganization by surface weathering. The parts deeper than 426.2 m are in the fault zone where rocks have suffered fault-related deformation and alteration. Characteristic alteration minerals in the fault zone are smectite, zeolites (laumontite, stilbite), and carbonate minerals (calcite and siderite). It is inferred that laumontite veins formed at temperatures higher than approximately 100°C during the fault activity. A reverse component in the movement of the Nojima Fault influences the distribution of zeolites. Zeolite is the main sealing mineral in relatively deep parts, whereas carbonate is the main sealing mineral at shallower depths. Several shear zones are recognized in the fault zone. Intense alteration is localized in the gouge zones. Rock chemistry changes in a different manner between different shear zones in the fault zone. The main shear zone (MSZ), which corresponds to the core of the Nojima Fault, shows increased concentration of most elements except Si, Al, Na, and K. However, a lower shear zone (LSZ-2), which is characterized by intense alteration rather than cataclastic deformation, shows a decreased concentration of most elements including Ti and Zr. A simple volume change analysis based on Ti and Zr immobility, commonly used to examine the changes in fault rock chemistry, cannot account fully for the different behaviors of Ti and Zr among the two gouge zones.     

Characterization of distal turbidites in marine sedimentary sequences using magnetic mineral data and factor analysis of microfossils assemblages

Results of a study of turbiditic deposits in a sequence of middle to late Holocene marine sediments from Alfonso Basin in the southern Gulf of California are presented. Turbidites are identified from analyses of core sections, X-ray images, texture and granulometry. Characterization of distal turbidites could be difficult, particularly for thin fine-grained deposits with little contrast in grain size, mineralogy and texture. We have here included analyses of microfossil and magnetic mineral data. Turbiditic currents transport material from various depths in the continental slope into the basin and it can be expected that turbiditic deposits are characterized by re-worked material, lack of microfossils or mixed assemblages with no content of paleoceanographic and paleoclimatic record. This may show in lack of internal coherence as quantified by factor analysis of microfossil assemblages. Turbidites in some cases may also show distinct magnetic properties as compared with those in the sediment sequence. In Alfonso Basin, turbidites show increased contents of detrital magnetic minerals volcanic-derived and transported from the basin slope. We identify twelve turbiditic layers through the sequence that present high magnetic susceptibility and low communalities from factor model to the microfossils data providing characterization of the turbidites.