Spatial characters of nutrients in Wujiangdu Reservoir in karst river,SW China

A preliminary assessment of the Wujiangdu Reservoir examined nutrient distribution and transport.Water samples were collected in the summer(July) of 2004, during the high-flow season. Inorganic nutrients(N,P, Si) and chlorophyll a(chl a) concentrations of the Wujiangdu Reservoir and its inflow rivers were analyzed.Other water parameters(dissolved oxygen, p H, temperature, and electrical conductivity) were measured as well.The results show gradually decreasing concentrations of NO_3~--N and dissolved silicate in the surface water moving downstream to the dam of the Wujiangdu Reservoir.Additionally, soluble reactive phosphorus concentrations measured very low, with most falling below the sensitivity threshold of the method used in surface waters. Particulate phosphorus and NO_3~--N were the predominant species of phosphorus and nitrogen in the reservoir, respectively. The concentration of nutrients in the Yeji River was the largest of all inflow rivers. The maximum concentration of chl a was found near the dam. These results reflect upstream conditions similar to that of a river, and reservoir conditions near the dam similar to that of a natural lake system.     

广东长潭水库富营养化与浮游植物分布特征

为掌握梅州市长潭水库富营养化状态与浮游植物分布特征,为控制藻类水华暴发提供科学依据,2011年10月至2012年7月,在长潭水库关键断面选取10个监测点,测定水体理化特征、浮游植物种类、丰度等指标,采用营养状态指数(TLI)和Shannon-Wiener多样性指数法对水质污染现状进行评价,并分析浮游植物类群分布特征.结果表明:长潭水库水体富营养状态在4、10和12月处于中营养级,7月份处于富营养级,营养指数从库区中游上游逐渐降低;观测期间共检出浮游植物4门11科16属,通过丰度比较,发现长潭水库以蓝绿藻为优势种,并且季节变化明显,总体表现为7月 >4月 >10月 >12月;藻类多样性指数分析显示,水库水体污染水平为中度,中游和库区(除7月)为轻度污染,与综合营养指数结果一致;长潭水库污染源调查分析结果表明,该水库主要为氮、磷污染,污染源主要为上游禽畜养殖废水.     

辽宁省大伙房水库及入库河流水质空间特征与河库水质关系

入库河流与水库存在空间上的连续性,河流污染物输入是水库水质恶化的主要原因,对大伙房水库及其入库支流61个采样点的水质状况进行调查,并运用聚类分析和主成分分析对大伙房水库及入库支流的水质空间特性和主要污染物进行分析.聚类分析显示,按照水质相似性将大伙房水库及入库支流水质可分为上游区、下游区和库区3个典型空间区域.分别对3个区域进行主成分分析,结果显示:入库支流上游区和下游区水质主要影响因素为氨氮、总氮和化学需氧量,库区影响水质的主要因素为温度、p H值、浊度、溶解氧、电导率、氨氮和总氮.对上游、下游和库区水质均有显著影响的因子为氨氮和总氮,上游区、下游区和库区氨氮浓度均值分别为0.06、0.10和0.19 mg/L,总氮浓度均值分别为0.13、0.16和0.26 mg/L.入库河流下游区对水库水质影响较大,受社河和浑河污染物输入的影响,大伙房水库水质在空间上呈现社河入库区水质优于浑河入库区水质.并且库区氨氮和总氮浓度均与距岸边距离呈负相关,溶解氧和p H值均与距入库口距离呈负相关,表明入库河流污染物输入和环库区面源污染均对大伙房水库水质产生一定影响.     

中国东南丘陵山区水质良好水库现状与天目湖保护实践

东南丘陵山区是我国水库分布最为集中的区域之一,这些水库在保障区域供水安全方面具有极其重要的作用,应该优先保护.然而,水库水环境保护正面临丘陵山区开发强度持续增加,开发方式和空间布局不合理,氮、磷污染及富营养化趋势严峻,缺乏完善监测和管理体系等众多问题.本文以2000年以来天目湖水库保护实践过程为例,从库体水环境治理、流域污染物削减和综合管理3个方面介绍天目湖沙河水库保护的措施和成效,在此基础上提出良好湖库优先保护的建议:建立具有部门协调能力的水库管理机构,实行基于湖库水生态目标的水质目标管理,治理丘陵山区茶果园的面源污染,注重流域生态系统整体的恢复,禁止上游水源涵养区和临湖地带的开发,划定生态保护红线,明确禁止和限制的开发类型与规模,加强湖库及流域的监测和预警,开展必要的水库水体治理工程,并针对性地制定湖库管理条例.天目湖十几年的保护实践中有效地解决了流域开发与水库水质保护之间的矛盾,使天目湖水质由快速恶化转为稳步好转,为东南丘陵山区经济发展过程中水库的环境保护探索了一条道路.     

三峡水库蓄水后库区水沙变化及其生态环境响应特征

三峡水库举世瞩目,是长江保护与治理的关键性枢纽工程,水库自2003年蓄水运行后库区水沙条件均发生了显著改变,对库区水生态环境产生了深远影响。本文系统综述了三峡水库蓄水运行后库区的水流动力特性和泥沙淤积特性,总结了蓄水后水库的新水沙运动情况;从水库蓄水运行后水质参数特征,营养物质、重金属和典型有毒有机污染物的赋存特征等方面,分析了三峡水库库区新水沙变化条件下的水环境响应特征;基于水库蓄水前后浮游植物、底栖动物等重点生物群落的现存量和群落特征变化规律,探索了三峡水库新水沙变化条件下库区的水生态响应特征;最后对未来三峡水库运行下的水生态环境效应研究提出展望,本文可为三峡水库水生态环境保护科学研究和管理提供新的认识和决策参考。     

Water quality guidelines for the Great Barrier Reef World Heritage Area: a basis for development and preliminary values

The Australian and New Zealand Guidelines for Fresh and Marine Water Quality (ANZECC Guidelines) provide default national guideline values for a wide range of indicators of relevance to the protection of the ecological condition of natural waters. However, the ANZECC Guidelines also place a strong emphasis on the need to develop more locally relevant guidelines. Using a structured framework, this paper explores indicators and regional data sets that can be used to develop more locally relevant guidelines for the Great Barrier Reef World Heritage Area (GBRWHA). The paper focuses on the water quality impacts of adjacent catchments on the GBRWHA with the key stressors addressed being nutrients, sediments and agricultural chemicals. Indicators relevant to these stressors are discussed including both physico-chemical pressure indicators and biological condition indicators. Where adequate data sets are available, guideline values are proposed. Generally, data were much more readily available for physico-chemical pressure indicators than for biological condition indicators. Specifically, guideline values are proposed for the major nutrients nitrogen (N) and phosphorus (P) and for chlorophyll-a. More limited guidelines are proposed for sediment related indicators. For most agricultural chemicals, the ANZECC Guidelines are likely to remain the default of choice for some time but it is noted that there is data in the literature that could be used to develop more locally relevant guidelines.     

河道型水库水动力特征与气候条件的响应关系

气候条件(降雨、气温)的变化对流域内水资源、河道、湖库的径流影响较大.河道型水库由于具有河道和湖泊的双重特点,受气候条件的影响则更为显著.本文以广东省梅州的河道型水库——长潭水库为例,耦合流域分布式水文模型SWAT与环境流体动力学模型EFDC,研究了河道型水库水动力特征(以水龄表征)与气候条件的响应关系.根据梅县气象站1953-2010年共58年的年均降雨量资料的频率分析,选取降雨量保证率分别为20%(丰水年)、50%(平水年)和90%(枯水年)年份的气候条件作为3种气候方案,对应的典型年分别为1992、1988和2004年,并将各典型年的日均降雨量和气温作为SWAT水文模型的输入条件,模拟了进入长潭水库各主要支流的日均变化过程.并将该流量过程作为长潭水库库区水动力模型的入流边界,模拟了各种降雨典型年情景下长潭水库的水动力变化过程.结果表明,长潭水库库区水龄沿程逐渐增大,呈指数增长的趋势,且受气候条件的影响很大.与丰水年相比,平水年、枯水年年降雨量分别减少了14%和49%,入库径流分别减少了23%和62%,水库出库坝址附近水龄分别增大了66%和247%,支流区域水龄增幅可达81%和290%左右,可见水库水动力特征受气候条件影响很大,而支流区域受气候条件影响更显著.不同气候条件下,河道型水库分别呈现出河道和深水湖泊的双重特性.丰水年时,坝址附近垂向上水体交换频繁,水龄均匀,呈现出河道的特性;平水年与枯水年时,坝址附近水体垂向交换较弱,逐渐呈现出深水湖泊的垂向分层特性.另外,流域分布式水文模型SWAT与环境流体动力学模型EFDC的联用,为弥补历史长系列高频监测资料的缺失,提高湖库水动力模型模拟的精度提供了有效的方法.     

Cover crops and precipitation influence soluble reactive phosphorus losses via tile drain discharge in an agricultural watershed

Subsurface tile drainage speeds water removal from agricultural fields that are historically prone to flooding. While managed drainage systems improve crop yields, they can also contribute tothe eutrophication of downstream ecosystems, as tile-drained systems are conduits for nutrients to adjacent waterways. The changing climate of the Midwestern US has already altered precipitation regimes which will likely continue into the future, with unknown effects on tile drain water and nutrient loss to waterways. Adding vegetative cover (i.e., as winter cover crops) is one approach that can retain water and nutrients on fields to minimize export via tile drains. In the current study, we evaluate the effect of cover crops on tile drain discharge and soluble reactive phosphorus (SRP) loads using bi-monthly measurements from 43 unique tile outlets draining fields with or without cover crops in two watersheds in northern Indiana. Using four water years of data (n = 844 measurements), we examined the role of short-term antecedent precipitation conditions and variation in soil biogeochemistry in mediating the effect of cover crops on tile drain flow and SRP loads. We observed significant effects of cover crops on both tile drain discharge and SRP loads, but these results were season and watershed specific. Cover crop effects were identified only in spring, where their presence reduced tile drain discharge in both watersheds and SRP loads in one watershed. Varying effects on SRP loads between watersheds were attributed to different soil biogeochemical characteristics, where soils with lower bioavailable P and higher P sorption capacity were less likely to have a cover crop effect. Antecedent precipitation was important in spring, and cover crop differences were still evident during periods of wet and dry antecedent precipitation conditions. Overall, we show that cover crops have the potential to significantly decrease spring tile drain P export, and these effects are resilient to a wide range of precipitation conditions.     

东巢湖沉积物水界面氮、磷、氧迁移特征及意义

以东巢湖近城市湖湾沉积物为研究对象,在沉积物氮、磷营养盐分析的基础上,采用沉积物柱状芯样静态释放模拟法定量评估研究区域沉积物—水界面氨氮、溶解性活性磷酸盐营养盐释放潜力,利用微电极非损伤测定技术获得沉积物—水微界面溶解氧(DO)剖面分布及微界面DO消耗和扩散特征.结果表明:东巢湖近城市湖湾沉积物氮、磷污染物蓄积量较高,受TN、TP污染程度较重.沉积物内源氨氮、磷酸盐释放明显,平均释放速率分别达到32.44 mg/(m~2·d)和1.25mg/(m~2·d),区域内沉积物已成为水柱中氮、磷营养盐的污染源.研究区域上覆水体处于好氧状态,沉积物—水微界面平均DO穿透深度(OPD)达到5.3 mm,平均DO扩散通量为4.56 mmol/(m~2·d),表现出良好的DO扩散能力.沉积物内源氨氮和磷酸盐释放能力与表层沉积物TN/TP物质含量及沉积物—水微界面DO穿透深度有关,在沉积物氮、磷污染较重的情况下,DO穿透深度越低越有利于氮、磷污染物从沉积物向上覆水体释放.     

Distribution and transportation of nitrogen in Miyun reservoir waters

The Miyun reservoir is an important water supply for Beijing city. The distribution laws of nitrogen in the Miyun reservoir waters and the transportation factors have been systematically analyzed in space and time by using water monitoring data sampled in the high-water and low-flow periods in 2001 and 2002. The nitrogen in east and west reservoir waters is distributed differently in space. It shows the change characteristics in high-water and low-flow periods and is affected by the source of nitrogen, runoff conditions, hydrodynamic conditions, precipitation and the control of bed mud, of which the source of nitrogen controls the change of concentration of nitrogen, the peripheral runoff controls the distribution law of nitrogen, bed mud controls the vertical distribution of nitrogen, and the contents of nitrogen and its change in the surrounding environment directly cause the change of concentration of total nitrogen in the waters. The improvement and protection of the waters in the Miyun reservoir basically rests with the amelioration of the peripheral environment.     

密云水库内湖富营养化现状分析

2001年的调研结果显示,由于网箱养鱼的影响,密云水库内湖已成为富营养水体,库区水体处于中营养水平,但有向富营养化发展的趋势;内湖水体通过侧渗、扩散等途径与库区水体进行物质交换,当水位达到150m以上时,水漫过相隔的窄坝,内湖与库区连为一体,内湖对库区的污染加重,内湖是库区的内污染源,应取消内湖的网箱养鱼,减少内源污染,稳定密云水库水质。     

Dynamics of algae growth and nutrients in experimental enclosures culturing bighead carp and common carp:Phosphorus dynamics

This is the third paper of the series about “Dynamics of algae growth and nutrients in experimental enclosures culturing bighead carp and common carp”. In this paper, phosphorus dynamics were inves-tigated under the condition of culturing bighead carp and common carp with added fish food (nitrogen dynamics is discussed in the second paper because their behaviors are so different from each other). Nearly fifty days’ observation results indicated that the reservoir water was typical of “phosphorus limited” water, and soluble reactive phosphorus (SRP) was the main constituent of measured total phosphorus (TP). The presence of fish food resulted in significantly higher SRP, dissolved total phos-phorus (DTP) and TP concentrations in contrast with the reservoir water. Moreover, continuous supply of fish food led to the decline of total nitrogen to total phosphorus (TN:TP) from more than 100 to less than 5. Variations in the ratio of TN to TP favored the growth of blue-green algae. Fish species affected phosphorus concentrations, and culturing bait-eating common carp contributed more to reducing the SRP, DTP and TP concentrations than culturing planktivorous bighead carp. 0.5%, 4.1%and 3.1%TP can be removed in enclosures with culturing bighead carp, common carp and mixed bighead carp and common carp, respectively. Abundant phosphorus in the fish culturing activities may be present as the uneaten food, algae cells, and within the water column and sediment, which should be taken into serious con-sideration for the target of future water eutrophication prevention and safety of the drinking water supply.     

寡-中营养型水体偶发性蓝藻水华的驱动因素分析——以南京方便水库为例

寡-中营养型水体中,虽然营养盐水平偏低,但仍会偶发性出现较为严重的蓝藻水华现象,其具体机制仍有待深入探索研究.本研究以偶发水华水体方便水库为例,通过历史数据分析和调查研究,探讨了其水华蓝藻的优势类群,并分析了蓝藻水华形成的主要驱动因素.研究发现:方便水库优势的水华蓝藻为浮丝藻和长孢藻,这两种丝状蓝藻是发生偶发性蓝藻水华的潜在风险物种,其中浮丝藻的发生风险最高,风险时段为7-9月.方便水库多年来营养盐浓度呈现下降的趋势,其中总氮浓度的下降趋势快于总磷浓度,整体有利于蓝藻水华的防控,但是营养盐的波动,尤其是随着降雨导致的地表径流入库对水体总磷的脉冲式补充,降低了水体氮磷比,增加了水库偶发蓝藻水华的风险;在营养盐满足的条件下,水温、高锰酸盐指数和氧化还原电位是发生浮丝藻水华的主要驱动因素,氧化还原电位、水温和透明度是发生长孢藻水华的主要驱动因素.本研究结果有助于提升对偶发性蓝藻水华机制的认识和应急处置工作的精准性.     

Potential eutrophication assessment in rivers; relationship between produced and exported loads

In contrast with biological processes in lacustrine environments, the physical characteristics of river waters greatly complicate the relationship between nutrient input and primary productivity. In this paper a new approach to quantify this relationship is developed, linking land use within the watershed to the bioavailability of nutrients in the receiving waters. It estimates by two different ways an enrichment index derived from N/P ratios. A load model links land-use within the watershed area to nutrient export, and allows the estimation of the potential enrichment index from the ratio of calculated annual exports of nitrogen and phosphorus. This index value correlates well with the real enrichment index representing the annual mean value of the corresponding measured ratios in running waters. The latter index can then be related to nutrient availability expressed by chl-a and the algal growth potential. This model, established from 7 sampling stations on the Yamaska-North river, allowed assessment of nutrient bioavailability in the river water as a function of hydrological (low or high water flow) as well as of seasonal (summer or winter) events.     

太湖草源性"湖泛"水域沉积物营养盐释放估算

于太湖草源性"湖泛"暴发期,采集柱状沉积物并应用peeper被动采样装置获得"湖泛"区原位沉积物间隙水.泥水样品分析表明:"湖泛"发生水域表层(0~7 cm)沉积物的含水率、孔隙度和有机质含量均明显高于对照区,其中有机质含量更是对照区样品的4倍左右,沉水植物残体促使表层沉积物物化性质改变的作用明显;"湖泛"发生水域表层沉积物间隙水中铵态氮(NH+4-N)、溶解性反应磷(SRP)及Fe2+含量远高于未发生区,植物残体降解对沉积物厌氧环境的营造显著.运用分子扩散模型对沉积物释放通量估算:"湖泛"发生区沉积物NH+4-N、SRP和Fe2+的释放速率分别是对照区的49.8、15.3和123.1倍.研究认为,草源性"湖泛"水体氮、磷等营养物含量升高的主要原因是沉积物的释放,而"湖泛"所营造的厌氧环境是氮、磷释放急剧增加的主要驱动因素.     

基于贝叶斯方法的贵州高原百花水库水体营养盐变化及评价(2014—2018年)

为了确定百花水库营养盐变化特征,选取百花水库5个监测点2014年1月-2018年7月共28个月份的水质实测数据,分析溶解氧、高锰酸盐指数、氨氮、总磷和总氮的年际变化特征.采用基于熵权法赋权的贝叶斯理论对5个监测点的水质综合状况进行评价,并结合水库的实际状况,从生态修复、工业污染源、沉积物中营养盐、水库季节性热分层及农业与生活污染源5个方面对其水质变化的影响因素进行分析.结果表明:2014-2018年水体环境波动较大;除总氮外,各污染指标浓度均有不同程度的下降;综合水质后验概率表明百花水库水质有逐渐变差的趋势;总氮和总磷治理应成为百花水库污染治理的主要方面;生态修复工程的开展和工业污染源的削减是百花水库水质转好的主要影响因素,农业与生活污染源的增加是百花水库水质转差的主要影响因素.     

福建省富营养化水库沉积物磷形态及对水体的贡献

采用 SMT 法结合 X 射线荧光和 X 射线衍射分析了福建省发生富营养化的山仔深水库表层沉积物的磷赋存形态 及对水体的贡献．分析结果表明，山仔水库表层沉积物总磷含量在400-750 mg/kg 之间，铁/铝结合态磷和有机磷是沉积 物磷的主要赋存形态，分别占总磷含量的47%和37%左右．沉积物水-土界面存在明显的活性磷梯度，在一定条件下活 性磷可以从沉积物间隙水扩散到上覆水体，从而一定程度上影响山仔水库水体的营养水平．     

福建省富营养化水库沉积物磷形态及对水体的贡献

2003年7月至2004年4月,每季度对武汉市南湖大型底栖动物进行定量和定性的采样分析,共发现大型底栖动 物30种;优势种为霍甫水丝蚓和刺铗长足摇蚊,均呈聚集分布;大型底栖动物的年均密度和生物量分别为4437 ind/m~2和 17．79 g/m~2,其密度和生物量春季最高,Shannon-Wiener 多样性指数和 Margalef 多样性指数的年均值分别为1．515和 1．123．比较分析了南湖大型底栖动物组成的历史变化,对水环境进行了生物学评价,并提出了南湖大型底栖动物合理利 用的建议．     

Temporal and spatial distributions of nutrients under the influence of human activities in Sishili Bay,northern Yellow Sea of China

The temporal and spatial distributions of dissolved inorganic nitrogen (DIN), dissolved organic nitrogen (DON), soluble reactive phosphorus (SRP) and dissolved reactive silica (DRSi) together with chlorophyll-a, temperature and salinity were analyzed monthly from December 2008 to March 2010 at four zones in Sishili Bay located in the northern Yellow Sea. The nutrient distribution was impacted by seasonal factors (biotic factors, temperature and wet deposition), physical factors (water exchange) and anthropogenic loadings. The seasonal variations of nutrients were mainly determined by the seasonal factors and the spatial distribution of nutrients was mainly related to water exchange. Anthropogenic loadings for DIN, SRP and DRSi were mainly from point sources, but for DON, non-point sources were also important. Nutrient limitation has changed from DIN in 1997 to SRP and DRSi in 2010, and this has resulted in changes in the dominant red tide species from diatom to dinoflagellates.     

Prediction of Water Temperature as Affected by a Pre‐Constructed Reservoir Project Based on MIKE11

Reservoir construction can lead to much more water stored in front of the dam and significantly increase heat storage capacity of the reservoir waters, thus resulting in different distribution pattern of water temperature in reservoir area compared to river. Especially for large reservoir, the obvious stratification of water temperature will appear in the reservoir with deeper water levels. Meanwhile, the low water temperature will be observed in the downstream river due to the operation of the reservoir. The vertical numerical simulation model for reservoir from MIKE 11 was used to predict the changes of water temperature of Wuxikou Reservoir to check the effects of the reservoir construction on water temperature. The water temperature prediction model was developed to simulate the water temperature of the reservoir and the discharged outflow water. The predicted results can contribute to assessing the feasibility of the pre‐constructed project based on the environmental influence of water temperature.