Isotopic composition of trapped and cosmogenic noble gases in several Martian meteorites

Abstract— Isotopic abundances of the noble gases were measured in the following Martian meteorites: two shock glass inclusions from Elephant Moraine (EET) 79001, shock vein glass from Shergotty and Yamato (Y) 793605, and whole-rock samples of Allan Hills (ALH) 84001 and Queen Alexandra Range (QUE) 94201. These glass samples, when combined with literature data on a separate single glass inclusion from EET 79001 and a glass vein from Zagami, permit examination in greater detail of the isotopic composition of Ne, Ar, Kr, and Xe trapped from the Martian atmosphere. The isotopic composition of Martian Ne, if actually present in these glasses, remains poorly defined. The ⁴⁰Ar/³⁶Ar ratio of trapped Martian atmospheric Ar is probably considerably lower than the nominal ratio of 3000 measured by Viking, and data on impact glasses suggest a value of ～1900. The atmospheric ³⁶Ar/³⁸Ar ratio is ≤4.0. Martian atmospheric Kr may be enriched in lighter isotopes by ～0.5%/amu compared to both solar-wind Kr and to the Martian composition previously reported. The isotopic composition of Xe in these glasses agrees with that previously reported in the literature. The Martian atmospheric ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are higher than those reported by Viking by factors of ～2.5–1.6 (depending on the ⁴⁰Ar/³⁶Ar ratio adopted) and ～1.8, respectively, and are discussed in a separate paper. Cosmogenic gases indicate space exposure ages of 2.7 ± 0.6 Ma for QUE 94201 and Shergotty and 14 ± 1 Ma for ALH 84001. Small amounts of ²¹Ne produced by energetic solar protons may be present in QUE 94201 but are not present in ALH 84001 or Y-793605. The space exposure age for Y-793605 is 4.9 ± 0.6 Ma and appears to be distinctly older than the ages for basaltic shergottites. However, uncertainties in cosmogenic production rates still makes somewhat uncertain the number of Martian impact events required to produce the exposure ages of Martian meteorites.     

Cosmogenic and trapped noble gases in individual chondrules: Clues to chondrule formation

Abstract— We studied the elemental and isotopic abundances of noble gases (He, Ne, Ar in most cases, and Kr, Xe also in some cases) in individual chondrules separated from six ordinary, two enstatite, and two carbonaceous chondrites. Most chondrules show detectable amounts of trapped ²⁰Ne and ³⁶Ar, and the ratio (³⁶Ar/²⁰Ne)_t (from ordinary and carbonaceous chondrites) suggests that HL and Q are the two major trapped components. A different trend between (³⁶Ar/²⁰Ne)_t and trapped ³⁶Ar is observed for chondrules in enstatite chondrites indicating a different environment and/or mechanism for their formation compared to chondrules in ordinary and carbonaceous chondrites. We found that a chondrule from Dhajala chondrite (DH‐11) shows the presence of solar‐type noble gases, as suggested by the (³⁶Ar/²⁰Ne)_t ratio, Ne‐isotopic composition, and excess of ⁴He. Cosmic‐ray exposure (CRE) ages of most chondrules are similar to their host chondrites. A few chondrules show higher CRE age compared to their host, suggesting that some chondrules and/or precursors of chondrules have received cosmic ray irradiation before accreting to their parent body. Among these chondrules, DH‐11 (with solar trapped gases) and a chondrule from Murray chondrite (MRY‐1) also have lower values of (²¹Ne/²²Ne)_c, indicative of SCR contribution. However, such evidences are sporadic and indicate that chondrule formation event may have erased such excess irradiation records by solar wind and SCR in most chondrules. These results support the nebular environment for chondrule formation.     

Purely physical separation of a small fraction of the Allende meteorite that is highly enriched in noble gases

Abstract— Fine material that floats during freeze-thaw disaggregation of the Allende meteorite is greatly enriched in noble gases compared to the bulk meteorite. Not only the elemental concentrations, but also most isotopic ratios of the noble gases in this fraction, strongly suggest that this material is very similar to the gas-rich carbonaceous residue isolated from the bulk meteorite by chemical treatment. The only significant difference in noble gas signature between our separated fraction and the chemical residues is that the ¹²⁹Xe/¹³²Xe ratio in the former is significantly lower than that in the latter, which suggests readsorption of ¹²⁹Xe released from the dissolved minerals during the chemical treatment. This is the first time that a gas-rich residue of a meteorite has been separated by a purely physical method alone. We also show that noble gases in phase Q and presolar diamond may be separable physically, although both are closely associated.     

The effect of pyridine treatment on phase Q: Orgueil and Allende

Marrocchi et al. (2005) reported that low‐temperature fractions of heavy noble gases were largely removed upon pyridine treatment of the Orgueil CI meteorite. As pyridine is known to induce the swelling of the macromolecular network of organic matter, they concluded that the low‐temperature phase Q is macromolecular organic carbon. However, Busemann et al. (2008) showed that pyridine had no significant effect on the noble gas contents for other very primitive meteorites, such as CM and CR. Therefore, we prepared an HF–HCl residue and the pyridine‐treated residue of Orgueil, and re‐examined the results of Marrocchi et al. (2005) by analyzing all noble gases. We confirmed that heavy noble gases are surely removed by the pyridine treatment, but the degree of the loss of heavy noble gases is generally small, and is even smaller for the lighter noble gases. Furthermore, we could not observe the evidence of Xe isotopic ratios by removing only phase Q after the pyridine treatment. We further prepared the HF–HCl residue and the pyridine‐treated residue of the Allende CV3 meteorite and performed noble gas analyses. For Allende, there is no significant change in the elemental abundances after the pyridine treatment. These results suggest that only Orgueil is special, and it is likely that the gas loss of the Orgueil residue is due to the loss of some kind of organic matter that was formed and that adsorbed the fractionated Q and HL gases during the aqueous alteration within the parent body of Orgueil.     

A search for new objects in the transition phase between AGB-stars and planetary nebulae

We present the first results of a spectroscopy survey of iras sources with colours similar to those of planetary nebulae.Two new planetary nebulae, some H emission line stars, one peculiar source which is probably a pre-Main-Sequence object and a new Seyfert I galaxy have been found.Based on observations collected at the European Southern Observatory, La Silla, Chile.     

Comparison of cosmic‐ray exposure ages and trapped noble gases in chondrule and matrix samples of ordinary,enstatite, and carbonaceous chondrites

Abstract— We performed a comprehensive study of the He, Ne, and Ar isotopic abundances and of the chemical composition of bulk material and components of the H chondrites Dhajala, Bath, Cullison, Grove Mountains 98004, Nadiabondi, Ogi, and Zag, of the L chondrites Grassland, Northwest Africa 055, Pavlograd, and Ladder Creek, of the E chondrite Indarch, and of the C chondrites Hammadah al Hamra 288, Acfer 059, and Allende. We discuss a procedure and necessary assumptions for the partitioning of measured data into cosmogenic, radiogenic, implanted, and indigenous noble gas components. For stone meteorites, we derive a cosmogenic ratio ²⁰Ne/²²Ne of 0.80 ± 0.03 and a trapped solar ⁴He/³He ratio of 3310 ± 130 using our own and literature data. Chondrules and matrix from nine meteorites were analyzed. Data from Dhajala chondrules suggest that some of these may have experienced precompaction irradiation by cosmic rays. The other chondrules and matrix samples yield consistent cosmic‐ray exposure (CRE) ages within experimental errors. Some CRE ages of some of the investigated meteorites fall into clusters typically observed for the respective meteorite groups. Only Bath's CRE age falls on the 7 Ma double‐peak of H chondrites, while Ogi's fits the 22 Ma peak. The studied chondrules contain trapped ²⁰Ne and ³⁶Ar concentrations in the range of 10^?6–10^?9 cm³ STP/g. In most chondrules, trapped Ar is of type Q (ordinary chondritic Ar), which suggests that this component is indigenous to the chondrule precursor material. The history of the Cullison chondrite is special in several respects: large fractions of both CR‐produced ³He and of radiogenic ⁴He were lost during or after parent body breakup, in the latter case possibly by solar heating at small perihelion distances. Furthermore, one of the matrix samples contains constituents with a regolith history on the parent body before compaction. It also contains trapped Ne with a ²⁰Ne/²²Ne ratio of 15.5 ± 0.5, apparently fractionated solar Ne.     

Mineralogy and petrography of amoeboid olivine aggregates from the reduced CV3 chondrites Efremovka,Leoville and Vigarano: Products of nebular condensation,accretion and annealing

Abstract— Amoeboid olivine aggregates (AOAs) from the reduced CV chondrites Efremovka, Leoville and Vigarano are irregularly‐shaped objects, up to 5 mm in size, composed of forsteritic olivine (Fa_<10) and a refractory, Ca, Al‐rich component. The AOAs are depleted in moderately volatile elements (Mn, Cr, Na, K), Fe, Ni‐metal and sulfides and contain no low‐Ca pyroxene. The refractory component consists of fine‐grained calcium‐aluminum‐rich inclusions (CAIs) composed of Al‐diopside, anorthite (An₁₀₀), and magnesium‐rich spinel (～1 wt% FeO) or fine‐grained intergrowths of these minerals; secondary nepheline and sodalite are very minor. This indicates that AOAs from the reduced CV chondrites are more pristine than those from the oxidized CV chondrites Allende and Mokoia. Although AOAs from the reduced CV chondrites show evidence for high‐temperature nebular annealing (e.g., forsterite grain boundaries form 120° triple junctions) and possibly a minor degree of melting of Al‐diopside‐anorthite materials, none of the AOAs studied appear to have experienced extensive (>50%) melting. We infer that AOAs are aggregates of high‐temperature nebular condensates, which formed in CAI‐forming regions, and that they were absent from chondrule‐forming regions at the time of chondrule formation. The absence of low‐Ca pyroxene and depletion in moderately volatile elements (Mn, Cr, Na, K) suggest that AOAs were either removed from CAI‐forming regions prior to condensation of these elements and low‐Ca pyroxene or gas‐solid condensation of low‐Ca‐pyroxene was kinetically inhibited.     

Noble gases in individual chondrules of the Allende CV3 chondrite

We analyzed noble gases in nine individual chondrules, an assemblage of small chondrules, and four whole‐rock samples of the Allende CV3 chondrite. Major elements were also determined for five chondrules. The cosmic ray exposure ages are calculated from cosmogenic ³He to be 5.17 ± 0.38 and 5.15 ± 0.25 Myr for the averages of the chondrules and whole rocks, respectively, showing no significant pre‐exposure evidence for the studied chondrules. Large amounts of ³⁶Ar, ^80,82Kr, and ¹²⁸Xe produced by neutron capture are observed in most samples; the abundances of these nuclides are correlated among the samples. The epithermal neutron flux and neutron slowing down density are calculated based on [⁸⁰Kr]_n, from which a sample depth of about 30 cm can be calculated. The measured chondrules contain variable amounts of radiogenic ¹²⁹Xe. The abundance ratios of radiogenic ¹²⁹Xe to neutron capture–produced ¹²⁸Xe are rather constant among the studied chondrules; four chondrules give more precise ratios at the high‐temperature fractions, ranging from 1920 ± 80 to 2280 ± 140, which corresponds to a time difference of 3.9 ± 2.4 Myr. It is noticeable that most chondrules also contain ²⁴⁴Pu‐derived fission Xe. The average ²⁴⁴Pu/²³⁸U ratio for nine chondrules is 0.0069 ± 0.0018, which agrees well with the preferred ratio reported for chondrites.     

Primordial and cosmogenic noble gases in the Sutter's Mill CM chondrite

The Sutter's Mill (SM) CM chondrite fell in California in 2012. The CM chondrite group is one of the most primitive, consisting of unequilibrated minerals, but some of them have experienced complex processes occurring on their parent body, such as aqueous alteration, thermal metamorphism, brecciation, and solar wind implantation. We have determined noble gas concentrations and isotopic compositions for SM samples using a stepped heating gas extraction method, in addition to mineralogical observation of the specimens. The primordial noble gas abundances, especially the P3 component trapped in presolar diamonds, confirm the classification of SM as a CM chondrite. The mineralogical features of SM indicate that it experienced mild thermal alteration after aqueous alteration. The heating temperature is estimated to be <350 °C based on the release profile of primordial ³⁶Ar. The presence of a Ni‐rich Fe‐Ni metal suggests that a minor part of SM has experienced heating at >500 °C. The variation in the heating temperature of thermal alteration is consistent with the texture as a breccia. The heterogeneous distribution of solar wind noble gases is also consistent with it. The cosmic‐ray exposure (CRE) age for SM is calculated to be 0.059 ± 0.023 Myr based on cosmogenic ²¹Ne by considering trapped noble gases as solar wind, the terrestrial atmosphere, P1 (or Q), P3, A2, and G components. The CRE age lies at the shorter end of the CRE age distribution of the CM chondrite group.     

Noble gases in planetary atmospheres: Implications for the origin and evolution of atmospheres

The radiogenic and primordial noble gas content of the atmospheres of Venus, Earth, and Mars are compared with one another and with the noble gas content of other extraterrestial samples, especially meteorites. The fourfold depletion of ⁴⁰Ar for Venus relative to the Earth is attributed to the outgassing rates and associated tectonics and volcanic styles for the two planets diverging significantly within the first billion or so years of their history, with the outgassing rate for Venus becoming much less than that for the Earth at subsequent times. This early divergence in the tectonic style of the two planets may be due to a corresponding early onset of the runaway greenhouse on Venus. The 16-fold depletion of ⁴⁰Ar for Mars relative to the Earth may be due to a combination of a mild K depletion for Mars, a smaller fraction of its interior being outgassed, and to an early reduction in its outgassing rate. Venus has lost virtually all of its primordial He and some of its radiogenic He. The escape flux of He may have been quite substantial in Venus' early history, but much diminished at later times, with this time variation being perhaps strongly influenced by massive losses of H₂ resulting from efficient H₂O loss processes.Key trends in the primordial noble gas content of terrestial planetary atmospheres include (1) a several orders of magnitude decrease in ²⁰Ne and ³⁶Ar from Venus to Earth to Mars; (2) a nearly constant ²⁰Ne/³⁶Ar ratio which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, although the degree of fractionation, especially for ³⁶Ar/¹³²Xe, seems to decrease systematically from carbonaceous chondrites to Mars to Earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among Earth, meteorites, and the Sun. Explaining trends (2), (2) and (4), and (1) pose the biggest problems for the solar-wind implantation, primitive atmosphere, and late veneer hypotheses, respectively. It is suggested that the grain-accretion hypothesis can explain all four trends, although the assumptions needed to achieve this agreement are far from proven. In particular, trends (1), (2), (3), and (4) are attributed to large pressure but small temperature differences in various regions of the inner solar system at the times of noble gas incorporation by host phases; similar proportions of the host phases that incorporated most of the He and Ne on the one hand (X) and Ar, Kr, and Xe on the other hand (Q); a decrease in the degree of fractionation with increasing noble-gas partial pressure; and the presence of interstellar carriers containing isotopically anomalous noble gases.Our analysis also suggests that primordial noble gases were incorporated throughout the interior of the outer terrestial planets, i.e., homogeneous accretion is favored over inhomogeneous accretion. In accord with meteorite data, we propose that carbonaceous materials were key hosts for the primordial noble gases incorporated into planets and that they provided a major source of the planets' CO₂ and N₂.     

Production of noble gases near the surface of Europa and the prospects for in situ chronology

The age of the surface of Europa is probably tens of Myr or less, but is poorly constrained. Two different geochronology schemes could potentially be applied to near-surface samples to provide far more precise ages. First, the surface salts apparently contain enough potassium to make potassium-argon dating feasible. Second, the bombardment of the surface with both galactic cosmic rays and protons trapped within the jovian magnetosphere will cause nuclear reactions that can lead to measurable buildups of cosmogenic noble gases, which can be used to determine both cosmic-ray exposure ages and erosion, deposition, or mixing rates for surface modification. The major differences between Europa's salt-rich ice and the rocks (meteorites, lunar samples and terrestrial rocks) in which cosmogenic noble gases are normally measured are that the abundance of target elements for nuclear reactions creating neon and argon are lower (because of the high water content), but neutron-capture reactions, particularly ³⁵Cl(n,γ)³⁶Cl(β⁻)³⁶Ar, are enhanced because of the thermalizing effects of the water. As well as presenting calculations of noble gas production near the surface of Europa, we also show that the measurements required to determine ages are within reach of technology in the near future, if an instrument can be landed on the surface of Europa.     

Light noble gases in Jilin: More of the same and something new

Abstract— Results are reported for documented samples from two drill cores and for specimens from the strewn field of the largest known stone meteorite, the H chondrite Jilin. Core B was found to have been parallel to the surface of Jilin during its first stage of irradiation, in 2π geometry. Core A was normal to the 2π surface; in it the mean attenuation length for the production by galactic cosmic rays of ³⁸Ar from metal and of ²¹Ne from Mg, Al, Si in silicates was found to be the same. A numerical value for the mean attenuation length of (71 ± 4) cm or (246 ± 14) g × cm^?2 follows if corrections for the contribution from the second stage of exposure are based on T₂ = 0.32 Ma; agreement with the lower values of ～180 g × cm^?2 obtained from lunar studies and target data requires T₂ to be about twice as long. Previous results are confirmed that in specimens with high contents of stable spallogenic gases the ratio ²¹Ne_bulk/³⁸Ar_metal is low. The suggestion had been, and is, mat this is a transition effect in near-surface samples where the secondary cascade of nuclear-active particles, and hence the production of ²¹Ne, was not yet fully developed. This suggestion is borne out by the present results on two samples that, based on cosmic-ray tracks and ⁶⁰Co content, are certified near-surface samples (although, strictly speaking, this is true only for the depth of burial during the second stage of irradiation). Cosmic-ray produced ⁶⁰Co is positively correlated with ⁴He content, indicating that significant losses of ⁴He occurred when the Jilin meteoroid had acquired already its final size and shape and that the losses were more severe for near-surface samples than for such from the 4π interior. Presumably, the losses were caused by a thermal spike associated with the excavation of Jilin from its parent body. The same event caused losses of part of the ³He produced during the first irradiation stage. From the systematics of the ³He/²¹Ne vs. ⁴He correlation, we derive for the second 4π irradiation a production ratio ³He/²¹Ne = 3.2 ± 0.4.     

Light noble gases in 12 meteorites from the Omani desert,Australia, Mauritania,Canada, and Sweden

We measured the concentrations and isotopic compositions of He, Ne, and Ar in 14 fragments from 12 different meteorites: three carbonaceous chondrites, six L chondrites (three most likely paired), one H chondrite, one R chondrite, and one ungrouped chondrite. The data obtained for the CV3 chondrites Ramlat as Sahmah (RaS) 221 and RaS 251 support the hypothesis of exposure age peaks for CV chondrites at approximately 9 Ma and 27 Ma. The exposure age for Shi?r 033 (CR chondrite) of 7.3 Ma is also indicative of a possible CR chondrite exposure age peak. The three L chondrites Jiddat al Harasis (JaH) 091, JaH 230, and JaH 296, which are most likely paired, fall together with Hallingeberg into the L chondrite exposure age peak of approximately 15 Ma. The two L chondrites Shelburne and Lake Torrens fall into the peaks at approximately 40 Ma and 5 Ma, respectively. The ages for Bassikounou (H chondrite) and RaS 201 (R chondrite) are approximately 3.5 Ma and 5.8 Ma, respectively. Six of the studied meteorites show clear evidence for ³He diffusive losses, the deficits range from approximately 17% for one Lake Torrens aliquot to approximately 45% for RaS 211. The three carbonaceous chondrites RaS 221, RaS 251, and Shi?r 033 all have excess ⁴He, either of planetary or solar origin. However, very high ⁴He/²⁰Ne ratios occur at relatively low ²⁰Ne/²²Ne ratios, which is unexpected and needs further study. The measured ⁴⁰Ar ages fit well into established systematics. They are between 2.5 and 4.5 Ga for the carbonaceous chondrites, older than 3.6 Ga for the L and H chondrites, and about 2.4 Ga for the R chondrite as well as for the ungrouped chondrite. Interestingly, none of our studied L chondrites has been degassed in the 470 Ma break‐up event. Using the amount of trapped ³⁶Ar as a proxy for noble gas contamination due to terrestrial weathering we are able to demonstrate that the samples studied here are not or only very slightly affected by terrestrial weathering (at least in terms of their noble gas budget).     

Nitrogen and noble gases in a glass sample from the LEW88516 shergottite

Abstract— A glass separate from the LEW88516 shergottite was analyzed by step-wise combustion for N and noble gases to determine whether it contained trapped gas similar in composition to the martian atmosphere-like component previously observed in lithology C of EETA79001. Excesses of ⁴⁰Ar and ¹²⁹Xe were in fact observed in this glass, although the amounts of these excesses are ≤20% of those seen in the latter meteorite, and are comparable to the amounts seen in whole-rock analyses of LEW88516. The isotopic composition of N in LEW88516 does not show an enrichment in ¹⁵N commensurate with the amount of isotopically-heavy N expected from the noble gases excesses. One must posit some extreme assumptions about the nature of the N components present in LEW88516 in order to allow the presence of the trapped nitrogen component. Alternatively, the N has somehow been decoupled from the noble gases, and was either never present or has been lost.     

Active capture and anomalous adsorption: New mechanisms for the incorporation of heavy noble gases

Abstract— Active capture is a new process for the incorporation of large quantities of heavy noble gases into growing surfaces. Adsorption in the conventional sense involves surface bonding by polarization (Van der Waals forces). What is referred to as “anomalous adsorption” of heavy noble gases involves chemical bonds and can occur when other (more chemically active) species are not available to preempt sites with unfilled bonds. Anomalous adsorption has been observed under conditions of fracture, vacuum deposition and ionizing radiation. Active capture depends upon anomalous adsorption to retain noble gases on a surface long enough to be captured in a growing surface film as it is deposited. The fundamental principle may be the impingement onto the growing film with sufficient energy to liberate surface electrons (work function energy of a few electronvolts) so that they are retained by anomalous adsorption long enough to be entrapped in the growing surface. Trapping efficiencies of ?1% have been observed for Kr and Xe in laboratory experiments, implying a fundamentally new mechanism for the incorporation of heavy noble gases onto surfaces. It may play a role in explaining the large concentrations of planetary noble gases contained in phase‐Q.     

Orphan radiogenic noble gases in lunar breccias: evidence for planet pollution of the Sun?

Surface-correlated noble gases in lunar soils are primarily implanted SW (solar wind) noble gases. However, they also include apparently orphan radiogenic ⁴⁰Ar, ¹²⁹Xe, and ²⁴⁴Pu-derived fission Xe in excess of plausible primordial solar origin. These orphan radiogenic components are usually assigned a lunar origin, in a scenario in which radiogenic noble gases produced in the lunar interior were degassed into the transient atmosphere and then re-implanted to the lunar surface together with SW. There are some quantitative difficulties with this scenario, however, and it requires special constraints on the degassing history of the Moon that have not emerged from more general thermal history models. We therefore urge consideration of alternative hypotheses. As a possible source for the orphan radiogenic noble gases, we have examined planetary pollution of the Sun, as suggested by studies of extrasolar planetary systems (e.g., Murray et al., 2001, Astrophys. J. 555, 801-815; Israelian et al., 2001, Nature 411, 163-166). Pollution of the Sun by 2M_⊕ (two Earth mass) planetary materials (Murray et al., 2001, Astrophys. J. 555, 801-815) is likely not significant for Ar but could be important to account for orphan Xe in the Moon.     

Noble gases in chondrules and associated metal‐sulfide‐rich samples: Clues on chondrule formation and the behavior of noble gas carrier phases

Abstract— Chondrules are generally believed to have lost most or all of their trapped noble gases during their formation. We tested this assumption by measuring He, Ne, and Ar in chondrules of the carbonaceous chondrites Allende (CV3), Leoville (CV3), Renazzo (CR2), and the ordinary chondrites Semarkona (LL3.0), Bishunpur (LL3.1), and Krymka (LL3.1). Additionally, metalsulfide‐rich chondrule coatings were measured that probably formed from chondrule metal. Low primordial ²⁰Ne concentrations are present in some chondrules, while even most of them contain small amounts of primordial ³⁶Ar. Our preferred interpretation is that‐in contrast to CAIs‐the heating of the chondrule precursor during chondrule formation was not intense enough to expel primordial noble gases quantitatively. Those chondrules containing both primordial ²⁰Ne and ³⁶Ar show low presolar‐diamond‐like ³⁶Ar/²⁰Ne ratios. In contrast, the metal‐sulfide‐rich coatings generally show higher gas concentrations and Q‐like ³⁶Ar/²⁰Ne ratios. We propose that during metalsilicate fractionation in the course of chondrule formation, the Ar‐carrying phase Q became enriched in the metal‐sulfide‐rich chondrule coatings. In the silicate chondrule interior, only the most stable Ne‐carrying presolar diamonds survived the melting event leading to the low observed ³⁶Ar/²⁰Ne ratios. The chondrules studied here do not show evidence for substantial amounts of fractionated solar‐type noble gases from a strong solar wind irradiation of the chondrule precursor material as postulated by others for the chondrules of an enstatite chondrite.     

Light noble gases and cosmogenic radionuclides in Estherville,Budulan, and other mesosiderites: Implications for exposure histories and production rates

Abstract— We report measurements of ²⁶AI, ¹⁰Be, ⁴¹Ca, and ³⁶Cl in the silicate and metal phases of 11 mesosiderites, including several specimens each of Budulan and Estherville, of the brecciated meteorite Bencubbin, and of the iron meteorite Udei Station. Average production rate ratios (atom/atom) for metal phase samples from Estherville and Budulan are ²⁶Al/¹⁰Be = 0.77 ± 0.02; ³⁶Cl/¹⁰Be = 5.3 ± 0.2. For a larger set of meteorites that includes iron meteorites and other mesosiderites, we find ²⁶Al/¹⁰Be = 0.72 ± 0.01 and ³⁶Cl/¹⁰Be = 4.5 ± 0.2. The average ⁴¹Ca/³⁶Cl production rate ratio is 1.10 ± 0.04 for metal separates from Estherville and four small iron falls. The ⁴¹Ca activities in dpm/(kg Ca) of various silicate separates from Budulan and Estherville span nearly a factor of 4, from <400 to >1600, indicating preatmospheric radii of >30 cm. After allowance for composition, the activities of ²⁶Al and ¹⁰Be (dpm/kg silicate) are similar to values measured in most ordinary chondrites and appear to depend only weakly on bulk Fe content. Unless shielding effects are larger than suggested by the ³⁶Cl and ⁴¹Ca activities of the metal phases, matrix effects are unimportant for ¹⁰Be and minor for ²⁶Al. Noble gas concentrations and isotopic abundances are reported for samples of Barea, Emery, Mincy, Morristown, and Marjalahti. New estimates of ³⁶Cl/³⁶Ar exposure ages for the metal phases agree well with published values. Neon‐21 production rates for mesosiderite silicates calculated from these ages and from measured ²¹Ne contents are consistently higher than predicted for L chondrites despite the fact that the mesosiderite silicates have lower Mg contents than L chondrites. We suggest that the elevation of the ²¹Ne production rate in mesosiderite silicates reflects a “matrix effect,” that is, the influence of the higher Fe content of mesosiderites, which acts to enhance the flux of low‐energy secondary particles and hence the ²¹Ne production from Mg. As ¹⁰Be production is relatively insensitive to this matrix effect, ¹⁰Be/²¹Ne ages give erroneously low production rates and high exposure ages. By coincidence, standard ²²Ne/²¹Ne based “shielding” corrections give fairly reliable ²¹Ne production rates in the mesosiderite silicates.     

Distribution of noble gases in Chinese tektites: Implication for neon solubility in natural glasses

Abstract— Five indochinites from Hainan Island and the Leizhou Peninsula, China were analyzed for noble gas abundances and isotopic ratios. These splash‐form tektites show vesiculation ranging from 0.4 vol% to 8 vol%, as determined by digital image analysis (software SXM®) on thin section photographs. To study the distribution of noble gases in vesicles and in glass, the gases were extracted by heating and by crushing, respectively, on 2 aliquots of the same sample. The results show that 5 to 53% of the total measured ²⁰Ne resides in vesicles. The calculated concentration of neon dissolved in the glass is higher (0.7‐1 times 10^?7 cm³STP/g) than that expected from solubility equilibrium (1 times 10^?8 cm³STP/g), assuming solubility data from MORB glasses. The neon concentration of splash‐form tektites, those analyzed in this work and those from other strewn‐fields worldwide, is correlated with the SiO₂ content of glass and with the nonbridging oxygen per tetrahedral cation in the melt (hereafter NBO/T ratio), the latter being an index of the free‐volume in the silica network where neon could be dissolved. These correlations suggest that the glass structure of tektite has a larger free‐volume available for dissolving noble gases than MORB glasses.     

Cosmic-ray produced,radiogenic, and solar noble gases in lunar meteorites Queen Alexandra Range 94269 and 94281

Abstract— We measured the noble gas isotopic abundances in lunar meteorite QUE 94269 and in bulk-, glass-, and crystal-phases of lunar meteorite QUE 94281. Our results confirm that QUE 94269 originated from the same meteorite fall as QUE 93069: both specimens yield the same signature of solar-particle irradiation and also the cosmogenic noble gases are in agreement within their uncertainities. Queen Alexandra Range 93069/94269 was exposed to cosmic rays in the lunar regolith for ～1000 Ma, and it trapped 3.5 × 10^?4 cm³STP/g solar ³⁶Ar, the other solar noble gases being present in proportions typical for the solar-particle irradiation. The bulk material of QUE 94281 contains about three times less cosmogenic and trapped noble gases than QUE 93069/94269 and the lunar regolith residence time corresponds to 400 ± 60 Ma. We show that in lunar meteorites the trapped solar ²⁰Ne/²²Ne ratio is correlated with the trapped ratio ⁴⁰Ar/³⁶Ar, that is, trapped ²⁰Ne/²²Ne may also serve as an antiquity indicator. The upper limits of the breccia compaction ages, as derived from the trapped ratio ⁴⁰Ar/³⁶Ar for QUE 93069/94269 and QUE 94281 are ～400 Ma and 800 Ma, respectively. We found very different regolith histories for the glass phase and the crystals separated from QUE 94281. The glass phase contains much less cosmogenic and solar noble gases than the crystals, in contrast to the glasses of lunar meteorite EET 87521, that were enriched in noble gases relative to the crystalline material. The QUE 94281 phases yield a ⁴⁰K-⁴⁰Ar gas retention age of 3770 Ma, which is in the range of that for lunar mare rocks.