Petrography and geochemistry of target rocks and impactites from the Ilyinets Crater,Ukraine

Abstract— The ～400 Ma old Ilyinets impact structure was formed in the Precambrian basement of the Ukrainian Shield and is now mostly covered by Quaternary sediments. Various impact breccias and melts are exposed in its southern section. The crater is a complex structure with a central uplift that is surrounded by an annular deposit of breccias and melt rocks. In the annulus, brecciated basement rocks are overlain by up to 80 m of glass-poor suevitic breccia, which is overlain (and partly intercalated) by glass-rich suevite with a thickness of up to 130 m. Impact-melt rocks occur within and on top of the suevites—in some cases in the form of devitrified bomb-shaped impact-glass fragments. We have studied the petrographic and geochemical characteristics of 31, mostly shocked, target rock samples (granites, gneisses, and one amphibolite) obtained from drill cores within the structure, and impact breccias and melt rock samples from drill cores and surface exposures. Multiple sets of planar deformation features (PDFs) are common in quartz, potassium feldspar, and plagioclase of the shocked target rocks. The breccias comprise more or less devitrified impact melt with shocked clasts. The impact-melt rocks (“bombs”) show abundant vesicles and, in some cases, glass is still present as brownish patches and schlieren. All impact breccias (including the melt rocks) are strongly altered and have significantly elevated K contents and lower Na contents than the target rocks. The alteration could have occurred in an impact-induced hydrothermal system. The bomb-shaped melt rocks have lower Mg and Ca contents than other rock types at the crater. Compared to target rocks, only minor enrichments of siderophile element contents (e.g., Ni, Co, Ir) in impact-melt rocks were found.     

Suevite at the Roter Kamm impact crater,Namibia

Abstract— A small area littered with loose decimeter-sized fragments of glass and melt fragment-bearing suevite has been discovered on the western rim of the Roter Kamm impact crater in southern Namibia. The clast population and results of major and trace element chemical analyses are consistent with this breccia having been formed from granitoid basement lithologies only, without contribution from the metasedimentary Gariep and Cenozoic cover sequences. It is assumed that the limited amount of impact melt observed in the Roter Kamm structure could be the result of melt dissipation due to explosive shock-induced devolatilization of the significant marble component of the Gariep supracrustal cover. Preservation of very limited remnants of impact breccia on the rim of the Roter Kamm crater suggests a relatively deep level of erosion of the crater rim.     

Geology,petrography, shock petrography,and geochemistry of impactites and target rocks from the Kärdla crater,Estonia

Abstract— The Kärdla crater is a 4 km‐wide impact structure of Late Ordovician age located on Hiiumaa Island, Estonia. The 455 Ma‐old buried crater was formed in shallow seawater in Precambrian crystalline target rocks that were covered with sedimentary rocks. Basement and breccia samples from 13 drill cores were studied mineralogically, petrographically, and geochemically. Geochemical analyses of major and trace elements were performed on 90 samples from allochthonous breccias, sub‐crater and surrounding basement rocks. The breccia units do not include any melt rocks or suevites. The remarkably poorly mixed sedimentary and crystalline rocks were deposited separately within the allochthonous breccia suites of the crater. The most intensely shockmetamorphosed allochthonous granitoid crystalline‐derived breccia layers contain planar deformation features (PDFs) in quartz, indicating shock pressures of 20–35 GPa. An apparent K‐enrichment and Ca‐Na‐depletion of feldspar‐ and hornblende‐bearing rocks in the allochthonous breccia units and sub‐crater basement is interpreted to be the result of early stage alteration in an impact‐induced hydrothermal system. The chemical composition of the breccias shows no definite sign of an extraterrestrial contamination. By modeling of the different breccia units with HMX‐mixing, the indigenous component was determined. From the abundances of the siderophile elements (Cr, Co, Ni, Ir, and Au) in the breccia samples, no unambiguous evidence for the incorporation of a meteoritic component above about 0.1 wt% chondrite‐equivalent was found.     

The Obolon impact structure,Ukraine, and its ejecta deposits

Abstract— The Obolon impact structure, 18 km in diameter, is situated at the northeastern slope of the Ukrainian Shield near its margin with the Dnieper‐Donets Depression. The crater was formed in crystalline rocks of the Precambrian basement that are overlain by marine Carboniferous and continental Lower Triassic deposits. The post‐impact sediments comprise marine Middle Jurassic (Bajocian and Bathonian) and younger Mesozoic and Cenozoic deposits. Today the impact structure is buried beneath an about 300‐meter‐thick sedimentary rock sequence. Most information on the Obolon structure is derived from two boreholes in the western part of the crater. The lowest part of the section in the deepest borehole is composed by allogenic breccia of crystalline basement rocks overlain by clast‐rich impact melt rocks and suevites. Abundant shock metamorphic effects are planar deformation features (PDFs) in quartz and feldspars, kink bands in biotite, etc. Coesite and impact diamonds were found in clast‐rich impact melt rocks. Crater‐fill deposits are a series of sandstones and breccias with blocks of sedimentary rocks that are covered by a layer of crystalline rock breccia. Crystalline rock breccias, conglomeratic breccias, and sandstones with crystalline rock debris have been found in some boreholes around the Obolon impact structure to a distance of about 50 km from its center. Those deposits are always underlain by Lower Triassic continental red clay and overlain by Middle Jurassic marine clay. The K‐Ar age of impact melt glasses is 169 Ma, which corresponds to the Middle Jurassic (Bajocian) age. The composition of crater‐fill rocks within the crater and sediments outside the Obolon structure testify to its formation under submarine conditions.     

The geology of the Målingen structure: A probable doublet to the Lockne marine‐target impact crater,central Sweden

The Målingen structure is an approximately 700 m wide, rimmed, sediment‐filled, circular depression in Precambrian crystalline basement approximately 16.2 km from the concentric, marine‐target Lockne crater (inner, basement crater diameter approximately 7.5 km, total diameter in sedimentary strata approximately 13.5 km). We present here results from geologic mapping, a 148.8 m deep core drilling from the center of the structure, detailed biostratigraphic dating of the structure's formation and its age correlation with Lockne, chemostratigraphy of the sedimentary infill, and indication for shock metamorphism in quartz from breccias below the crater infill. The drill core reveals, from bottom to the top, approximately 33 m of basement rocks with increased fracturing upward, approximately 10 m of polymict crystalline breccia with shock features, approximately 97 m of slumped Cambrian mudstone, approximately 4.7 m of a normally graded, polymict sedimentary breccia that in its uppermost part grades into sandstone and siltstone (cf. resurge deposits), and approximately 1.6 m of secular sediments. The combined data set shows that the Målingen structure formed in conjunction with the Lockne crater in the same marine setting. The shape and depth of the basement crater and the cored sequence of crystalline breccias with shocked quartz, slumped sediments, and resurge deposits support an impact origin. The stratigraphic and geographic relationship with Lockne suggests the Lockne and Målingen craters to be the first described doublet impact structure by a binary asteroid into a marine‐target setting.     

Woodleigh impact structure,Australia: Shock petrography and geochemical studies

Abstract— The large, complex Woodleigh structure in the Carnarvon basin of Western Australia has recently been added to the terrestrial impact crater record. Many aspects of this structure are, however, still uncertain. This work provides a detailed petrographic assessment of a suite of representative drill core samples from the borehole Woodleigh 1 that penetrated uplifted basement rocks of the central part of this structure. Fundamental rock and mineral deformation data and high‐precision chemical data, including results of PGE and oxygen isotopic analysis, are presented. The sampled interval displays likely impact‐produced macrodeformation in the form of fracturing and breccia veining at the microscopic scale. Contrary to earlier reports that these breccias represent pseudotachylite (friction melt) or even shock/shear‐produced pseudotachylitic melt breccia cannot be confirmed due to pervasive post‐impact alteration. Abundant planar deformation features (PDFs) in quartz, in addition to diaplectic glass and partial isotropization, are the main shock deformation effects observed, confirming that Woodleigh is of impact origin. Over the investigated depth interval, the statistics of quartz grains with a variable number of sets of PDFs does not change significantly, and the patterns of crystallographic orientations of PDFs in randomly selected quartz grains does not indicate a change in absolute shock pressure with depth either. The value of oxygen isotopes for the recognition of meteoritic contamination, as proposed by earlier Woodleigh workers, is critically assessed. Neither INA nor PGE analyses of our samples support the presence of a meteoritic component within this basement section, as had been claimed in earlier work.     

Geochemistry of drill core samples from Yaxcopoil‐1, Chicxulub impact crater,Mexico

Abstract— The chemical composition of suevites, displaced Cretaceous target rocks, and impact‐generated dikes within these rocks from the Yaxcopoil‐1 (Yax‐1) drill core, Chicxulub impact crater, Mexico, is reported and compared with the data from the Yucatán 6 (Y6) samples. Within the six suevite subunits of Yax‐1, four units with different chemical compositions can be distinguished: a) upper/lower sorted and upper suevite (depth of 795–846 m); b) middle suevite (depth of 846–861 m); c) brecciated impact melt rock (depth of 861–885 m); and d) lower suevite (depth of 885–895 m). The suevite sequence (a), (b), and (d) display an increase of the CaO content and a decrease of the silicate basement component from top to bottom. In contrast, the suevite of Y6 shows an inverse trend. The different distances of the Yax‐1 and Y6 drilling sites from the crater center (～60, and ～47 km, respectively) lead to different suevite sequences. Within the Cretaceous rocks of Yax‐1, a suevitic dike (depth of ～916 m) does not display chemical differences when compared with the suevite, while an impact melt rock dike (depth of ～1348 m) is significantly enriched in immobile elements. A clastic breccia dike (depth of ～1316 m) is dominated by material derived locally from the host rock, while the silicate‐rich component is similar to that found in the suevite. Significant enrichments of the K₂O content were observed in the Yax‐1 suevite and the impact‐generated dikes. All impactites of Yax‐1 and Y6 are mixtures of a crystalline basement and a carbonate component from the sedimentary cover. An anhydrite component in the impactites is missing (Yax‐1) or negligible (Y6).     

Geochemical studies of the SUBO 18 (Enkingen) drill core and other impact breccias from the Ries crater,Germany

Suevite and melt breccia compositions in the boreholes Enkingen and Polsingen are compared with compositions of suevites from other Ries boreholes and surface locations and discussed in terms of implications for impact breccia genesis. No significant differences in average chemical compositions for the various drill cores or surface samples are noted. Compositions of suevite and melt breccia from southern and northeastern sectors of the Ries crater do not significantly differ. This is in stark contrast to the published variations between within‐crater and out‐of‐crater suevites from northern and southern sectors of the Bosumtwi impact structure, Ghana. Locally occurring alteration overprint on drill cores—especially strong on the carbonate‐impregnated suevite specimens of the Enkingen borehole—does affect the average compositions. Overall, the composition of the analyzed impact breccias from Ries are characterized by very little macroscopically or microscopically recognized sediment‐clast component; the clast populations of suevite and impact melt breccia are dominated consistently by granitic and intermediate granitoid components. The Polsingen breccia is significantly enriched in a dioritic clast component. Overall, chemical compositions are of intermediate composition as well, with dioritic‐granodioritic silica contents, and relatively small contributions from mafic target components. Selected suevite samples from the Enkingen core have elevated Ni, Co, Cr, and Ir contents compared with previously analyzed suevites from the Ries crater, which suggest a small meteoritic component. Platinum‐group element (PGE) concentrations for some of the enriched samples indicate somewhat elevated concentrations and near‐chondritic ratios of the most immobile PGE, consistent with an extraterrestrial contribution of 0.1–0.2% chondrite‐equivalent.     

Planar deformation features in quartz from impact‐produced polymict breccia of the Xiuyan crater,China

Abstract– The 1.8 km‐diameter Xiuyan crater is an impact structure in northeastern China, exposed in a Proterozoic metamorphic rock complex. The major rocks of the crater are composed of granulite, hornblendite, gneiss, tremolite marble, and marble. The bottom at the center of the crater covers about 100 m thick lacustrine sediments underlain by 188 m thick crater‐fill breccia. A layer of polymict breccia composed of clasts of granulite, gneiss, hornblendite, and fragments of glass as well as clastic matrix, occurs near the base, in the depth interval from 260 to 295 m. An investigation in quartz from the polymict breccia in the crater‐fill units reveals abundant planar deformation features (PDFs). Quartz with multiple sets of PDFs is found in clasts of granulite that consist of mainly quartz and feldspar, and in fine‐grained matrix of the impact‐produced polymict breccia. A universal stage was used to measure the orientation of PDFs in 70 grains of quartz from five thin sections made from the clasts of granulite of polymict breccia recovered at the depth of 290 m. Forty‐four percent of the quartz grains contain three sets of PDFs, and another 40% contain two sets of PDFs. The most abundant PDFs are rhombohedron forms of , , and with frequency of 33.5, 22.3, and 9.6%, respectively. A predominant PDF form of in quartz suggests a shock pressure >20 GPa. The occurrence of PDFs in quartz from the polymict breccia provides crucial evidence for shock metamorphism of target rocks and confirms the impact origin of this crater, which thus appears to be the first confirmed impact crater in China.     

The Allochthonous Polymict Breccia Layer of the Haughton Impact Crater,Devon Island,Canada

Abstract— The central allochthonous polymict breccia of the Haughton impact structure is up to about 90 m thick and as much as 7.3 km in radial extent. It has been analyzed with respect to modal composition, grain-size characteristics, and degree of shock metamorphism for the grain-size ranges 10–～ 50, 1–10, 0.03–1, and <0.03 mm. The mineralogy of the breccia matrix is dominated by dolomite and calcite, with minor amounts of quartz, other silicate minerals, and rare melt particles. The following lithic clasts have been identified in the 1–10 mm size fraction (averages of vol.% given in parentheses): dolomitic rocks (51), limestones (29), crystalline rocks (10), sandstones and siltstones (3.7), chert (0.7), melt particles (1.9). The mineral clasts (1–0.03 mm) comprise (with decreasing frequency) dolomite, quartz, calcite, feldspar, biotite, amphibole, garnet, opaques, rounded quartz derived from sandstones and accessory minerals. Lithic and mineral clasts display various degrees of shock. Fragments of crystalline rocks are shocked in the 0–60 GPa range; whole rock melts from the crystalline basement are lacking and unshocked rocks are very rare. In contrast, shock-melted sandstones, shales, and chert were found in most samples. Large clasts of these melt rocks are highly concentrated near the center of the crater. Otherwise, no distinct change of the modal composition with radial range has been observed except that the frequency of limestone clasts increases slightly with radial range. The breccia near the center is more fine-grained than that beyond about 1 km radius and the sorting parameter increases somewhat with radial range. Except for the high concentration of shock-melted sedimentary rocks and highly shocked crystalline rocks near the center of the crater, the distribution of shock stages within the lithic clast population is quite uniform throughout the breccia formation. We conclude that the breccia constituents are derived from the lower part of the target stratigraphy (deeper than about 800 m) and that the total depth of excavation at Haughton is in the order of 2000 m. The mixing of sedimentary rocks of the Eleanor River Formation, Lower Ordovician, and Cambrian (～850 m thickness) with crystalline basement rocks is quite thorough and homogeneous throughout the breccia lens, at least for the analyzed part. This may require an air-borne mode of emplacement for the upper section of the breccia in analogy to the fall-back suevite in the Ries crater. A calculation of the excavation (Z-model) and of the shock pressure attenuation based on reasonable estimates of the energy and crater geometry of the Haughton impact confirms the observed maximum depth of excavation of about 2 km. Shock-melted crystalline basement rocks, if present at all, must be confined to the very center of the structure below the excavation cavity.     

Shock metamorphism investigations of quartz grains in clasts from impact breccia of the Eyreville B drill core,Chesapeake Bay impact structure,USA

Abstract– The Chesapeake Bay impact structure, approximately 85 km in diameter, has been drilled in 2005–2006 at Eyreville (Virginia, USA), to a total depth of 1766 m. In the drill cores, the abundance of shock metamorphosed material is very variable with depth. Shocked mineral and lithic clasts, as well as melt particles, are most abundant in suevitic impact breccia section (1397–1451 m depth). Shocked quartz (i.e., quartz grains with planar fractures and/or planar deformation features) and melt particles, although rare, are also dispersed in the Exmore Formation unit (444–867 m depth). Other lithologies in the Eyreville drill cores show no clear evidence of shock metamorphism. Here, we report on the investigations of 40 samples from the impact breccia section. A total of more than 27,000 quartz grains were examined in about 200 clasts. The abundance of highly shocked clasts tends to decrease with increasing depth. Crystalline clasts derived from the crystalline basement are commonly only slightly shocked (contain generally <10 rel% of shocked quartz grains). The clasts of metamorphosed sediments show a low proportion of shocked quartz grains (mostly <10 rel%). Sedimentary clasts show a wide range of proportions of shocked quartz grains, with several of them being highly shocked clasts (most values between 0 and 40 rel%). Conglomerates show the highest proportion of shocked quartz grains of all types of clasts (up to 83 rel%). Polycrystalline quartz clasts are also commonly highly shocked (contain mostly between 10 and 40 rel% of shocked quartz grains). These hard nonporous clasts are possibly more liable to show evidence of shock. The investigations suggest that the intensity of shock metamorphism is the result of several parameters, such as original position in the target (both horizontal and vertical) and the properties of each lithology (e.g., grain size, porosity, and amount of matrix). According to the universal‐stage investigations, the dominant orientations of planar deformation features in quartz are , , and also .     

Evidence for shock‐induced anhydrite recrystallization and decomposition at the UNAM‐7 drill core from the Chicxulub impact structure

Drill core UNAM‐7, obtained 126 km from the center of the Chicxulub impact structure, outside the crater rim, contains a sequence of 126.2 m suevitic, silicate melt‐rich breccia on top of a silicate melt‐poor breccia with anhydrite megablocks. Total reflection X‐ray fluorescence analysis of altered silicate melt particles of the suevitic breccia shows high concentrations of Br, Sr, Cl, and Cu, which may indicate hydrothermal reaction with sea water. Scanning electron microscopy and energy‐dispersive spectrometry reveal recrystallization of silicate components during annealing by superheated impact melt. At anhydrite clasts, recrystallization is represented by a sequence of comparatively large columnar, euhedral to subhedral anhydrite grains and smaller, polygonal to interlobate grains that progressively annealed deformation features. The presence of voids in anhydrite grains indicates SO_x gas release during anhydrite decomposition. The silicate melt‐poor breccia contains carbonate and sulfate particles cemented in a microcrystalline matrix. The matrix is dominated by anhydrite, dolomite, and calcite, with minor celestine and feldspars. Calcite‐dominated inclusions in silicate melt with flow textures between recrystallized anhydrite and silicate melt suggest a former liquid state of these components. Vesicular and spherulitic calcite particles may indicate quenching of carbonate melts in the atmosphere at high cooling rates, and partial decomposition during decompression at postshock conditions. Dolomite particles with a recrystallization sequence of interlobate, polygonal, subhedral to euhedral microstructures may have been formed at a low cooling rate. We conclude that UNAM‐7 provides evidence for solid‐state recrystallization or melting and dissociation of sulfates during the Chicxulub impact event. The lack of anhydrite in the K‐Pg ejecta deposits and rare presence of anhydrite in crater suevites may indicate that sulfates were completely dissociated at high temperature (T > 1465 °C)—whereas ejecta deposited near the outer crater rim experienced postshock conditions that were less effective at dissociation.     

The Manicouagan impact structure as a terrestrial analogue site for lunar and martian planetary science

The 90 km diameter, late Triassic Manicouagan impact structure of Québec, Canada, is a well-preserved, undeformed complex crater possessing an anorthositic central uplift and a 55 km diameter melt sheet. As such, it provides a valuable terrestrial analogue for impact structures developed on other planetary bodies, especially the Moon and Mars, which are currently the focus of exploration initiatives. The scientific value of Manicouagan has recently been enhanced due to the production, between 1994 and 2006, of ∼18 km of drill core from 38 holes by the mineral exploration industry. Three of these holes are in excess of 1.5 km deep, with the deepest reaching 1.8 km. Here we combine recent field work, sampling and the drill core data with previous knowledge to provide insight into processes occurring at Manicouagan and, by inference, within extraterrestrial impact structures. Four areas of comparative planetology are discussed: impact melt sheets, central uplifts, impact-generated hydrothermal regimes and footwall breccias. Human training and instrument testing opportunities are also considered. The drill core reveals that the impact melt and clast-bearing impact melts in the centre of the structure reach thicknesses of 1.4 km. The 1.1 km thick impact melt has undergone differentiation to yield a lower monzodiorite, a transitional quartz monzodiorite and an upper quartz monzonite sequence. This calls into question the previous citing of Manicouagan as an exemplar of a relatively large crater possessing an undifferentiated melt sheet, which was used as a rationale for assigning different composition lunar impact melts and clast-bearing impact melts to separate cratering events. The predominantly anorthositic central uplift at Manicouagan is comparable to certain lunar highlands material, with morphometric analogies to the King, Tycho, Pythagoras, Jackson, and Copernicus impact structures, which have similar diameters and uplift structure. Excellent exposure of the Manicouagan uplift facilitates mapping and an appraisal of its formation and collapse mechanisms, enhanced by drill core data from the centre of the structure. Recent field studies at the edge of the central island at Manicouagan, and multiple drill core sections through footwall lithologies, provide insight into allochthonous (clastic and suevitic) and autochthonous breccia formation, as well as shock effects. The hydrothermal regimes developed at Manicouagan are akin to systems proposed for Noachian (>3.5 Ga) Mars that involve alteration of impact melts via meteoritic and surface waters, with the generation of phyllosilicates, zeolites, hematite, sulfates and sulfides that can contribute to martian soil formation and sedimentation processes.     

The Dhala structure,Bundelkhand craton,Central India—Eroded remnant of a large Paleoproterozoic impact structure

Abstract— The newly discovered Dhala structure, Madhya Pradesh State, India, is the eroded remnant of an impact structure with an estimated present‐day apparent diameter of about 11 km. It is located in the northwestern part of the Archean Bundelkhand craton. The pre‐impact country rocks are predominantly granitoids of ?2.5 Ga age, with minor 2.0–2.15 Ga mafic intrusive rocks, and they are overlain by post‐impact sediments of the presumably >1.7 Ga Vindhyan Supergroup. Thus, the age for this impact event is currently bracketed by these two sequences. The Dhala structure is asymmetrically disposed with respect to a central elevated area (CEA) of Vindhyan sediments. The CEA is surrounded by two prominent morphological rings comprising pre‐Vindhyan arenaceous‐argillaceous and partially rudaceous metasediments and monomict granitoid breccia, respectively. There are also scattered outcrops of impact melt breccia exposed towards the inner edge of the monomict breccia zone, occurring over a nearly 6 km long trend and with a maximum outcrop width of ?170 m. Many lithic and mineral clasts within the melt breccia exhibit diagnostic shock metamorphic features, including multiple sets of planar deformation features (PDFs) in quartz and feldspar, ballen‐textured quartz, occurrences of coesite, and feldspar with checkerboard texture. In addition, various thermal alteration textures have been found in clasts of initially superheated impact melt. The impact melt breccia also contains numerous fragments composed of partially devitrified impact melt that is mixed with unshocked as well as shock deformed quartz and feldspar clasts. The chemical compositions of the impact melt rock and the regionally occurring granitoids are similar. The Ir contents of various impact melt breccia samples are close to the detection limit (1–1.5 ppb) and do not provide evidence for the presence of a meteoritic component in the melt breccia. The presence of diagnostic shock features in mineral and lithic clasts in impact melt breccia confirm Dhala as an impact structure. At 11 km, Dhala is the largest impact structure currently known in the region between the Mediterranean and southeast Asia.     

Geochemical and petrographic characteristics of impactites and Cretaceous target rocks from the Yaxcopoil‐1 borehole,Chicxulub impact structure,Mexico: Implications for target composition

Abstract— We present major and trace element data as well as petrographic observations for impactites (suevitic groundmass, bulk suevite, and melt rock particles) and target lithologies, including Cretaceous anhydrite, dolomite, argillaceous limestone, and oil shale, from the Yaxcopoil‐1 borehole, Chixculub impact structure. The suevitic groundmass and bulk suevite have similar compositions, largely representing mixtures of carbonate and silicate components. The latter are dominated by melt rock particles. Trace element data indicate that dolomitic rocks represented a significant target component that became incorporated into the suevites; in contrast, major elements indicate a strong calcitic component in the impactites. The siliceous end‐member requires a mafic component in order to explain the low SiO₂ content. Multicomponent mixing of various target rocks, the high alteration state, and dilution by carbonate complicate the determination of primary melt particle compositions. However, two overlapping compositional groups can be discerned—a high‐Ba, low‐Ta group and a high‐Fe, high‐Zn, and high‐Hf group. Cretaceous dolomitic rocks, argillaceous limestone, and shale are typically enriched in U, As, Br, and Sb, whereas anhydrite contains high Sr contents. The oil shale samples have abundances that are similar to the North American Shale Composite (NASC), but with a comparatively high U content. Clastic sedimentary rocks are characterized by relatively high Th, Hf, Zr, As, and Sb abundances. Petrographic observations indicate that the Cretaceous rocks in the Yaxcopoil‐1 drill core likely register a multistage deformation history that spans the period from pre‐ to post‐impact. Contrary to previous studies that claimed evidence for the presence of impact melt breccia injection veins, we have found no evidence in our samples from a depth of 1347–1348 m for the presence of melt breccia. We favor that clastic veinlets occur in a sheared and altered zone that underwent intense diagenetic overprint prior to the impact event.     

Combining shock barometry with numerical modeling: Insights into complex crater formation—The example of the Siljan impact structure (Sweden)

Siljan, central Sweden, is the largest known impact structure in Europe. It was formed at about 380 Ma, in the late Devonian period. The structure has been heavily eroded to a level originally located underneath the crater floor, and to date, important questions about the original size and morphology of Siljan remain unanswered. Here we present the results of a shock barometry study of quartz‐bearing surface and drill core samples combined with numerical modeling using iSALE. The investigated 13 bedrock granitoid samples show that the recorded shock pressure decreases with increasing depth from 15 to 20 GPa near the (present) surface, to 10–15 GPa at 600 m depth. A best‐fit model that is consistent with observational constraints relating to the present size of the structure, the location of the downfaulted sediments, and the observed surface and vertical shock barometry profiles is presented. The best‐fit model results in a final crater (rim‐to‐rim) diameter of ~65 km. According to our simulations, the original Siljan impact structure would have been a peak‐ring crater. Siljan was formed in a mixed target of Paleozoic sedimentary rocks overlaying crystalline basement. Our modeling suggests that, at the time of impact, the sedimentary sequence was approximately 3 km thick. Since then, there has been around 4 km of erosion of the structure.     

The suevite of drill hole Yucatàn 6 in the Chicxulub impact crater

Abstract— The suevite breccia of the Chicxulub impact crater, Yucatàn, Mexico, is more variable and complex in terms of composition and stratigraphy than suevites observed at other craters. Detailed studies (microscope, electron microprobe, SEM, XRF) have been carried out on a noncontinuous set of samples from the drill hole Yucatàn 6 (Y6) located 50 km SW from the center of the impact structure. Three subunits can be distinguished in the suevite: the upper unit is a fine‐grained carbonate‐rich suevite breccia with few shocked basement clasts, mostly altered melt fragments, and formerly melted carbonate material; the middle suevite is a coarse‐grained suevite with shocked basement clasts and altered silicate melt fragments; the lower suevite unit is composed of shocked basement and melt fragments and large evaporite clasts. The matrix of the suevite is not clastic but recrystallized and composed mainly of feldspar and pyroxene. The composition of the upper members of the suevite is dominated by the sedimentary cover of the Yucatàn target rock. With depth in well Y6, the amount of carbonate decreases and the proportion of evaporite and silicate basement rocks increases significantly. Even at the thin section scale, melt phases of different chemistry can be identified, showing that no widespread homogenization of the melt took place. The melt compositions also reflect the heterogeneity of the deep Yucatàn basement. Calcite with characteristic feathery texture indicates the existence of formerly pure carbonate melt. The proportion of carbonate to evaporite clasts is less than 5:1, except in the lower suevite where large evaporite clasts are present. This proportion constrains the amount of CO₂ and SO_X released by the impact event.     

Sedimentological and petrographic analysis of drill core FC77-1 from the flank of the central uplift,Flynn Creek impact structure,Tennessee

Drill core FC77-1 on the flank of the central uplift, Flynn Creek impact structure, Tennessee, contains 175 m of impact breccia lying upon uplifted Lower Paleozoic carbonate target stratigraphy. Sedimentological analysis of this 175-m interval carbonate breccia shows that there are three distinct sedimentological units. In stratigraphic order, unit 1 (175–109 m) is an overall coarsening-upward section, whereas the overlying unit 2 (109–32 m) is overall fining-upward. Unit 3 (32–0 m) is a coarsening-upward sequence that is truncated at the top by postimpact erosion. Units 1 and 3 are interpreted as debris or rock avalanches into finer sedimentary deposits within intracrater marine waters, thus producing progressively coarser, coarsening-upward sequences. Unit 2 is interpreted to have formed by debris or rock avalanches into standing marine waters, thus forming sequential fining-upward deposits. Line-logging of clasts ranging from 5 mm to 1.6 m, and thin-section analysis of selected drill core samples (including clasts < 5 mm), both show that the Flynn Creek impact breccia consists almost entirely of dolostone clasts (90%), with minor components of cryptocrystalline melt clasts, chert and shale fragments, and clastic grains. Cryptocrystalline melt clasts, which appear isotropic in thin section, are in fact made of exceedingly fine quartz crystals that exhibit micro-Fourier transform infrared (FTIR) and micro-Raman spectra consistent with crystalline quartz. These cryptocrystalline melt clasts are the first melt clasts of any kind to be reported from Flynn Creek impact structure.     

Composition of impact melt particles and the effects of post‐impact alteration in suevitic rocks at the Yaxcopoil‐1 drill core,Chicxulub crater,Mexico

Abstract Petrographical and chemical analysis of melt particles and alteration minerals of the about 100 m‐thick suevitic sequence at the Chicxulub Yax‐1 drill core was performed. The aim of this study is to determine the composition of the impact melt, the variation between different types of melt particles, and the effects of post‐impact hydrothermal alteration. We demonstrate that the compositional variation between melt particles of the suevitic rocks is the result of both incomplete homogenization of the target lithologies during impact and subsequent post‐impact hydrothermal alteration. Most melt particles are andesitic in composition. Clinopyroxene‐rich melt particles possess lower SiO₂ and higher CaO contents. These are interpreted by mixing of melts from the silicate basement with overlying carbonate rocks. Multi‐stage post‐impact hydrothermal alteration involved significant mass transfer of most major elements and caused further compositional heterogeneity between melt particles. Following backwash of seawater into the crater, palagonitization of glassy melt particles likely caused depletion of SiO₂, Al₂O₃, CaO, Na₂O, and enrichment of K₂O and FeO_tot during an early alteration stage. Since glass is very susceptible to fluid‐rock interaction, the state of primary crystallization of the melt particles had a significant influence on the intensity of the post‐impact hydrothermal mass transfer and was more pronounced in glassy melt particles than in well‐crystallized particles. In contrast to other occurrences of Chicxulub impactites, the Yax‐1 suevitic rocks show strong potassium metasomatism with hydrothermal K‐feldspar formation and whole rock K₂0 enrichment, especially in the lower unit of the suevitic sequence. A late stage of hydrothermal alteration is characterized by precipitation of silica, analcime, and Na‐bearing Mg‐rich smectite, among other minerals. This indicates a general evolution from a silica‐undersaturated fluid at relatively high potassium activities at an early stage toward a silica‐oversaturated fluid at relatively high sodium activities at later stages in the course of fluid rock interaction.