Raindrop impact and water flow on the vegetative surfaces of trees and the effects on stemflow and throughfall generation

The physical processes of raindrop impact and water flow on the leaves and branches of selected tropical tree species were examined under laboratory conditions using simulated rainfall. Inclined branches were found to be particularly efficient in detaining impacting water droplets. This efficiency in raindrop detention increases linearly as a function of branch inclination on branches that are initially dry. On branches that have been thoroughly wetted, this increase in raindrop detention with branch inclination is best expressed as a logarithmic function. At branch inclinations of 60° above the horizontal, the quantity of branchflow was found to be > 80 per cent of the total quantity of impacting rainfall, indicating that < 20 per cent was lost to rainsplash. The strong positive relationship between branchflow and branch inclination explains why trees with large projected areas of steeply inclined upthrust branches have significant quantities of intercepted water draining from their branches and trunks under heavy rainfall conditions. This drainage from the woody frame of trees influences surficial processes by generating both stemflow and large throughfall droplets.     

MID-WINTER STEMFLOW DRAINAGE FROM BIGTOOTH ASPEN (POPULUS GRANDIDENTATA MICHX.) IN CENTRAL MASSACHUSETTS

Under winter conditions, stemflow drainage in forested ecosystems is often assumed to be a negligible component of the hydrological cycle. This paper reports on mid-winter stemflow drainage from the broadleaved deciduous tree species Populus grandidentata. Stemflow volumes from this species at air temperatures of < 0°C were found to be comparable to rainfall-generated stemflow during summer. Over the three-month period January–March 1993, stemflow ranged from 5.4 to 9.9% of the incident gross precipitation. Expressed as depth equivalents per unit trunk basal area, these stemflow inputs ranged from 1.8 to 4.9 m. These concentrated mid-winter inputs of liquid water to the bases of canopy trees were attributable to: (1) snow interception by the leafless woody frame of each tree; (2) snow retention by glazed ice precipitation associated with the snowfall event; (3) increased temperature at the bark/snow interface caused by the low albedo of the bark tissue; and (4) convergence of snowmelt drainage from steeply inclined upthrust primary branches. The hydrological and ecological significance of liquid water inputs to the forest floor under sub-zero conditions are discussed. © 1997 by John Wiley & Sons Ltd.     

Species differences in stomatal control of water loss at the canopy scale in a mature bottomland deciduous forest

In order to evaluate factors controlling transpiration of six common eastern deciduous species in North America, a model describing responses of canopy stomatal conductance (G_S) to net radiation (R_N), vapor pressure deficit (D) and relative extractable soil water (REW) was parameterized from sap flux data. Sap flux was measured in 24 mature trees consisting of the species Carya tomentosa, Quercus alba, Q. rubra, Fraxinus americana, Liriodendron tulipifera, and Liquidambar styraciflua in a bottomland oak-hickory forest in the Duke Forest, NC. Species differences in model coefficients were found during the 1997 growing season. All species showed a reduction in G_S with increasing D. R_N influenced G_S in the overstory shade intolerant L. styraciflua to a larger extent than the other species measured. In addition, despite a severe drought during the study period, only L. tulipifera showed a decline in G_S with decreasing REW. The primary effect of the drought for the other species appeared to be early autumn leaf senescence and abscission. As a result, despite the drought in this bottomland forest accustomed to ample water supply, maximum daily transpiration (1.6 mm) and growing season transpiration (264 mm) were similar to a nearby upland forest measured during a year of above average precipitation. These results may aid in assessing differences in water use and the ability of bottomland deciduous species to tolerate alterations in the frequency or amount of precipitation. Results also suggest little variation in water use among forests of similar composition and structure growing in different positions in the landscape and subjected to large interannual variation in water supply.     

Spatial and Temporal Patterns of Plankton Assemblage Structure in a High Altitude Saline Lake,Namuka Co in Northern Tibet,China

The seasonal variations in biomass, abundance, and species composition of plankton in relation to hydrography were studied in saline lake Namuka Co, northern Tibet, China. The sampling was carried out at approximately monthly intervals from June 2001 to July 2002. The salinity ranged from 5.5 to 26 g/L. The mean annual air and water temperature showed a clear seasonal pattern, which was approximately 4.4 and 7.4°C, respectively, with the lowest water temperature in winter (from December to March, −1°C) and the highest in June and July (18°C). The results showed that 36 taxa of phytoplankton and 16 taxa of zooplankton were identified. Both the biomass and abundance of total phytoplankton were lower in the winter and peaked once or twice during the summer and spring in the early August (8.23 mg/L and 158.2 × 10⁶ ind./L). The seasonal variation in total zooplankton biomass and abundance was characterized by lower values in both winter and early spring, and one maximum (90.5 mg/L and 935 ind. L⁻¹) occurred in the late summer. Major phytoplankton species were Gloeothece linearis, Oscillatoria tenuis, Gloeocapsa punctata, Ctenocladus circinnatus, Ulothrix sp., and Spirogyra sp. And major zooplankton species included Vorticella campanula, Brachionus plicatilis, Daphniopsis tibetana, Cletocamptus dertersi, Arctodiaptomus stewartianus. The production of D. tibetana was 420.3 g m³ a⁻¹. The total number of plankton species has a significant negative correlation with the salinity.     

Increasing water losses from snow captured in the canopy of boreal forests: A case study using a 30 year data set

Water losses from snow intercepted by forest canopy can significantly influence the hydrological cycle in seasonally snow‐covered regions, yet how snow interception losses (SIL) are influenced by a changing climate are poorly understood. In this study, we used a unique 30 year record (1986–2015) of snow accumulation and snow water equivalent measurements in a mature mixed coniferous (Picea abies and Pinus sylvestris ) forest stand and an adjacent open area to assess how changes in weather conditions influence SIL. Given little change in canopy cover during this study, the 20% increase in SIL was likely the result of changes in winter weather conditions. However, there was no significant change in average wintertime precipitation and temperature during the study period. Instead, mean monthly temperature values increased during the early winter months (i.e., November and December), whereas there was a significant decrease in precipitation in March. We also assessed how daily variation in meteorological variables influenced SIL and found that about 50% of the variation in SIL was correlated to the amount of precipitation that occurred when temperatures were lower than ?3 °C and to the proportion of days with mean daily temperatures higher than +0.4 °C. Taken together, this study highlights the importance of understanding the appropriate time scale and thresholds in which weather conditions influence SIL in order to better predict how projected climate change will influence snow accumulation and hydrology in boreal forests in the future.     

Some aspects of the hydroclimatology of the Quesnel River Basin,British Columbia,Canada

In conjunction with available climate data, surface runoff is investigated at 12 gauges in the Quesnel watershed of British Columbia to develop its long‐term (1926–2004) hydroclimatology. At Quesnel itself, annual mean values of air temperature, precipitation and runoff are 4·6 °C, 517 and 648 mm, respectively. Climate data reveal increases in precipitation, no significant trend in mean annual air temperature, but an increasing trend in mean minimum temperatures that is greatest in winter. There is some evidence of decreases in winter snow depth. On the water year scale (October–September), a strong positive correlation is found between discharge and precipitation (r = 0·70, p < 0·01) and a weak negative correlation is found between precipitation and temperature (r = ? 0·36, p < 0·01). Long‐term trends using the Mann‐Kendall test indicate increasing annual discharge amounts that vary from 8 to 14% (12% for the Quesnel River, p = 0·03), and also a tendency toward an earlier spring freshet. River runoff increases at a rate of 1·26 mm yr^?1 m^?1 of elevation from west to east along the strong elevation gradient in the basin. Discharge, temperature and precipitation are correlated with the large‐scale climate indices of the Pacific Decadal Oscillation (PDO) and El‐Niño Southern Oscillation (ENSO). Copyright © 2009 John Wiley & Sons, Ltd.     

Interaction of a Dynamic Rupture on a Fault Plane with Short Frictionless Fault Branches

Spontaneous bilateral mode II shear ruptures were nucleated on faults in photoelastic Homalite plates loaded in uniaxial compression. Rupture velocities were measured and the interaction between the rupture front and short fault branches was observed using high-speed digital photography. Fault branches were formed by machining slits of varying lengths that intersected the fault plane over a range of angles. These branches were frictionless because they did not close under static loading prior to shear rupture nucleation. Three types of behavior were observed. First, the velocity of both rupture fronts was unaffected when the fault branches were oriented 45° to the main slip surface and the length of the branches were less than or equal to ~0.75 R₀* (where R₀* is the slip-weakening distance in the limit of low rupture speed and an infinitely long slip-pulse). Second, rupture propagation stopped at the branch on the compressive side of the rupture tip but was unaffected by the branch on the tensile side when the branches were ~1.5 R₀* in length and remained oriented 45° to the principle slip surface. Third, branches on the tensile side of the rupture tip nucleated tensile ``wing tip' extensions when the branches were oriented at 70° to the interface. Third, when the branches were oriented at 70° to the interface, branches on the tensile side of the rupture tip nucleated tensile ``wing-crack' extensions. We explain these observations using a model in which the initial uniaxial load produces stress concentrations at the tips of the branches, which perturb the initial stress field on the rupture plane. These stress perturbations affect both the resolved shear stress driving the rupture and the fault-normal stress that controls the fault strength, and together they explain the observed changes in rupture speed.     

Factors controlling spatial and seasonal distributions of precipitation δ18O in China

Utilising datasets from the Global Network of Isotopes in Precipitation of the International Atomic Energy Agency, and previous isotopic studies, we investigated δ¹⁸O spatial and temporal patterns in Chinese precipitation. Significantly positive relationships existed between precipitation δ¹⁸O and air temperature above the north of 35°N and in high altitude regions above 32°N. Significantly negative relationships between precipitation δ¹⁸O and the precipitation amount existed below south of 35°N. These temperature and precipitation effects became stronger with increasing altitude except in high altitude regions between 32°N and 35°N. The NCEP/NCAR reanalysis data from 1980 to 2004 showed that variations in spatial and seasonal wind fields at 700 hpa and total precipitable water from the ground to the top of the atmosphere were correlated with the monthly spatial distribution of precipitation δ¹⁸O. Basing on this relationship, we established quantitative correlations between the mean monthly precipitation δ¹⁸O and both latitude and temperature in different seasons. We found that spatial variations in precipitation δ¹⁸O could be described well using the Bowen–Wilkinson model and second‐order equations developed during the present study only in winter (from December to February). During the rest of the year, patterns were too complex to predict using simple models. The results suggest that it is difficult to demonstrate variations of precipitation δ¹⁸O throughout the year and for all regions of China using a single model. Moreover, the new models for the relationships among precipitation, latitude, and temperature were better able to depict the variations in precipitation δ¹⁸O than the Bowen–Wilkinson model. Copyright © 2011 John Wiley & Sons, Ltd.     

Moisture origin and stable isotope characteristics of precipitation in southeast Siberia

The paper presents oxygen and hydrogen isotopes of 284 precipitation event samples systematically collected in Irkutsk, in the Baikal region (southeast Siberia), between June 2011 and April 2017. This is the first high-resolution dataset of stable isotopes of precipitation from this poorly studied region of continental Asia, which has a high potential for isotope-based palaeoclimate research. The dataset revealed distinct seasonal variations: relatively high δ¹⁸O (up to −4‰) and δD (up to −40‰) values characterize summer air masses, and lighter isotope composition (−41‰ for δ¹⁸O and −322‰ for δD) is characteristic of winter precipitation. Our results show that air temperature mainly affects the isotope composition of precipitation, and no significant correlations were obtained for precipitation amount and relative humidity. A new temperature dependence was established for weighted mean monthly precipitation: +0.50‰/°C (r² = 0.83; p <.01; n = 55) for δ¹⁸O and +3.8‰/°C (r² = 0.83, p < 0.01; n = 55) for δD. Secondary fractionation processes (e.g., contribution of recycled moisture) were identified mainly in summer from low d excess. Backward trajectories assessed with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model indicate that precipitation with the lowest mean δ¹⁸O and δD values reaches Irkutsk in winter related to moisture transport from the Arctic. Precipitation originating from the west/southwest with the heaviest mean isotope composition reaches Irkutsk in summer, thus representing moisture transport across Eurasia. Generally, moisture transport from the west, that is, the Atlantic Ocean predominates throughout the year. A comparison of our new isotope dataset with simulation results using the European Centre/Hamburg version 5 (ECHAM5)-wiso climate model reveals a good agreement of variations in δ¹⁸O (r² = 0.87; p <.01; n = 55) and air temperature (r² = 0.99; p <.01; n = 71). However, the ECHAM5-wiso model fails to capture observed variations in d excess (r² = 0.14; p < 0.01; n = 55). This disagreement can be partly explained by a model deficit of capturing regional hydrological processes associated with secondary moisture supply in summer.     

Effect of Pinus radiata plantations on water balance in Chile

The effect of Pinus radiata (D. Don) plantations on water resources at different Chilean sites located between 33 and 40 south was determined. Incoming precipitation, canopy interception loss, evapotranspiration, net evapotranspiration (transpiration and evaporation from the soil), percolation and soil water content were measured in each site, where Pinus radiata plantations were 12 to 17 years old and between 700 and 830 trees ha^?1 dense. The results were compared with those obtained from areas covered with perennial grasses and shrubs at the same sites. The pine canopies intercepted on average 36–40% of the annual rainfall at all sites where rainfall was less then 1200 mm, while only 15% of the mean rainfall was intercepted in the southernmost and rainy (2081 mm year^?1) site. Annual net evapotranspiration increased from south to north from 32% of the incoming precipitation for the southernmost site to 55% for the one located at the lower latitude. In this northernmost site almost the entire incoming precipitation was evapotranspired. Annual percolation registered its minimum value in the northern site (5% of incoming precipitation) and its maxima in the southern one (53%). The values of net evapotranspiration and percolation were regulated by the pluviometric regime and the soil moisture retention capacity in each site. Compared with the shrub or grass covers, sites under Pinus radiata plantations registered higher water consumption by evapotranspiration and reduced percolation. Copyright © 2007 John Wiley & Sons, Ltd.     

Temperature in lowland Danish streams: contemporary patterns,empirical models and future scenarios

Continuous temperature measurements at 11 stream sites in small lowland streams of North Zealand, Denmark over a year showed much higher summer temperatures and lower winter temperatures along the course of the stream with artificial lakes than in the stream without lakes. The influence of lakes was even more prominent in the comparisons of colder lake inlets and warmer outlets and led to the decline of cold‐water and oxygen‐demanding brown trout. Seasonal and daily temperature variations were, as anticipated, dampened by forest cover, groundwater input, input from sewage plants and high downstream discharges. Seasonal variations in daily water temperature could be predicted with high accuracy at all sites by a linear air‐water regression model (r²: 0·903–0·947). The predictions improved in all instances (r²: 0·927–0·964) by a non‐linear logistic regression according to which water temperatures do not fall below freezing and they increase less steeply than air temperatures at high temperatures because of enhanced heat loss from the stream by evaporation and back radiation. The predictions improved slightly (r²: 0·933–0·969) by a multiple regression model which, in addition to air temperature as the main predictor, included solar radiation at un‐shaded sites, relative humidity, precipitation and discharge. Application of the non‐linear logistic model for a warming scenario of 4–5 °C higher air temperatures in Denmark in 2070‐2100 yielded predictions of temperatures rising 1·6–3·0 °C during winter and summer and 4·4–6·0 °C during spring in un‐shaded streams with low groundwater input. Groundwater‐fed springs are expected to follow the increase of mean air temperatures for the region. Great caution should be exercised in these temperature projections because global and regional climate scenarios remain open to discussion. Copyright © 2006 John Wiley & Sons, Ltd.     

Impact of climatic change on river discharge in the driest region of Poland

Abstract

Discharge in the Warta River in Poland has been analysed based on long series of measurements at the Gorzów Wielkopolski gauge station (covering the whole catchment area) and at Poznań (middle and upper catchment area), and the Note? River is characterized by the gauge station at Nowe Drezdenko. The annual mean discharge of the Warta River for the period 1981–2010 was equal to the average value for the last 163 years (209 m³ s^-1), and there was no significant change in comparison with the ratio of runoff in the summer and winter half-years. In the driest region of Poland, the climate has been described on the basis of precipitation and air temperature. The annual mean precipitation for 1981–2010 (544 mm) in the Warta River catchment area was the same as that for the period 1848–2010. The precipitation has been increasing in spring and winter, and decreasing in summer. There is a positive and very significant correlation (r = 0.705) between the annual discharge and annual precipitation totals. The annual mean air temperature has risen by 0.6°C between the periods 1848–1980 and 1981–2010.

Editor D. Koutsoyiannis

Citation Ilnicki, P., Farat, R., Górecki, K., and Lewandowski, P., 2014. Impact of climatic change on river discharge in the driest region of Poland. Hydrological Sciences Journal, 59 (6), 1117–1134. http://dx.doi.org/10.1080/02626667.2013.831979     

Estimation of tree water stress from stem and soil water monitoring with time‐domain reflectometry in two small forested basins in Spain

Soil‐tree water relationships were studied using time domain reflectometry (TDR) in two small forested basins in Spain. The stem water content of two Mediterranean Quercus species (Quercus pyrenaica and Quercus rotundifolia) was measured using previously constructed species‐specific equations. To monitor soil moisture, a TDR station network was used in both cases. Sixteen Q. pyrenaica and six Q. rotundifolia individuals were selected to install two TDR probes in their trunks (at 20 and 120 cm above the ground) to monitor stem water content. Stem and soil water contents were measured fortnightly. The stem water content of both species showed a similar temporal trend for the period studied. A spring maximum (0·654 cm³ cm^?3 for Q. pyrenaica and 0·568 cm³ cm^?3 for Q. rotundifolia) was found to be associated with high transpiration and no soil moisture deficit, and a late‐summer minimum (0·520 cm³ cm^?3 for Q. pyrenaica and 0·426 cm³ cm^?3 for Q. rotundifolia) was associated with the end of the dry season. This drop in stem water content occurs when the available water in the soil decreases. This seasonal difference presumably reflects water withdrawn from stem storage to support the transpirational demands of the tree. Since plant water stress results in reduced stem water content and since this drop can be measured by TDR, it may be concluded that this technology offers a suitable tool for detecting plant water stress. Copyright © 2007 John Wiley & Sons, Ltd.     

Modelling the regional climate and isotopic composition of Svalbard precipitation using REMOiso: a comparison with available GNIP and ice core data

Simulations of a regional (approx. 50 km resolution) circulation model REMO_iso with embedded stable water isotope module covering the period 1958‐2001 are compared with the two instrumental climate and four isotope series (δ¹⁸O) from western Svalbard. We examine the data from ice cores drilled on Svalbard ice caps in 1997 (Lomonosovfonna, 1250 m asl) and 2005 (Holtedahlfonna, 1150 m asl) and the GNIP series from Ny‐Ålesund and Isfjord Radio. The surface air temperature (SAT) and precipitation data from Longyearbyen and Ny‐Ålesund are used to assess the skill of the model in reproducing the local climate. The model successfully captures the climate variations on the daily to multidecadal times scales although it tends to systematically underestimate the winter SAT. Analysis suggests that REMO_iso performs better at simulating isotope compositions of precipitation in the winter than summer. The simulated and measured Holtedahlfonna δ¹⁸O series agree reasonably well, whereas no significant correlation has been observed between the modelled and measured Lomonosovfonna ice core isotopic series. It is shown that sporadic nature as well as variability in the amount inherent in precipitation process potentially limits the accuracy of the past SAT reconstruction from the ice core data. This effect in the study area is, however, diminished by the role of other factors controlling δ¹⁸O in precipitation, most likely sea ice extent, which is directly related with the SAT anomalies. Copyright © 2011 John Wiley & Sons, Ltd.     

A remote sensing contribution to hydrologic modelling in arid and inaccessible watersheds,Pishin Lora basin,Pakistan

The lack of adequate field measurements often hampers the construction and calibration of rainfall‐runoff models over many of the world's watersheds. We adopted methodologies that rely heavily on readily available remote sensing datasets as viable alternatives for assessing, managing, and modelling of such remote and inadequately gauged regions. The Soil and Water Assessment Tool was selected for continuous (1998–2005) rainfall‐runoff modelling of one such area, the northeast part of the Pishin Lora basin (NEPL). Input to the model included satellite‐based Tropical Rainfall Measuring Mission precipitation data, and modelled runoff was calibrated against satellite‐based observations, the latter included: (i) monthly estimates of the water volumes impounded by the Khushdil Khan (latitude 30°40′N, longitude 67°40′E), and the Kara Lora (latitude 30°34′N, longitude 66°52′E) reservoirs, and (ii) inferred wet versus dry conditions in streams across the NEPL. Calibrations were also conducted against observed flow reported from the Burj Aziz Khan station at the NEPL outlet (latitude 30°20′N; longitude 66°35′E). Model simulations indicate that (i) average annual precipitation (1998–2005), runoff and recharge in the NEPL are 1300 × 10⁶ m³, 148 × 10⁶ m³, and 361 × 10⁶ m³, respectively; (ii) within the NEPL watershed, precipitation and runoff are high for the northeast (precipitation: 194 mm/year; runoff: 38 × 10⁶ m³/year) and northwest (134 mm/year; 26 × 10⁶ m³/year) basins compared to the southern basin (124 mm/year; 8 × 10⁶ m³/year); and (3) construction of delay action dams in the northeast and northwest basins could increase recharge from 361 × 10⁶ m³/year up to 432 × 10⁶ m³/year and achieve sustainable extraction. The adopted methodologies are not a substitute for traditional approaches, but they could provide first‐order estimates for rainfall, runoff, and recharge in the arid and semi‐arid parts of the world that are inaccessible and/or lack adequate coverage with field data. Copyright © 2011 John Wiley & Sons, Ltd.     

Seasonal and annual throughfall and stemflow in Andean temperate rainforests

The partitioning of gross rainfall into throughfall, stemflow, and interception loss and their relationships with forest structure was studied for a period of four years (October 2002–September 2006) and two years (October 2005–September 2007) in seven experimental catchments of temperate rainforest ecosystems located in the Andes of south‐central Chile (39°37′S, 600–925 m a.s.l.). The amount of throughfall, stemflow, and interception loss was correlated with forest structure characteristics such as basal area, canopy cover, mean quadratic diameter (MQD), and tree species characteristics in evergreen and deciduous forests. Annual rainfall ranged from 4061 to 5308 mm at 815 m a.s.l. and from 3453 to 4660 mm at 714 m a.s.l. Throughfall ranged from 64 to 89% of gross rainfall. Stemflow contributed 0·3–3·4% of net precipitation. Interception losses ranged from 11 to 36% of gross rainfall and depended on the amount of rainfall and characteristics as well as on forest structure, particularly the MQD. For evergreen forests, strong correlations were found between stemflow per tree and tree characteristics such as diameter at breast height (R² = 0·92, P < 0·01) and crown projection area (R² = 0·65, P < 0·01). Stemflow per tree was also significantly correlated with epiphyte cover of trunks in the old‐growth evergreen forests (R² = 0·29, P < 0·05). The difference in the proportion of throughfall and interception loss among stands was significant only during winter. The reported relationships between rainfall partitioning and forest structure and composition provide valuable information for management practices, which aimed at producing other ecosystem services in addition to timber in native rainforests of southern Chile. Copyright © 2010 John Wiley & Sons, Ltd.     

Evolution of forest precipitation water storage measurement methods

Precipitation intercepted by forests plays a major role in more than one‐fourth of the global land area's hydrologic cycle. Direct in situ measurement of intercepted precipitation is challenging, and thus, it is typically indirectly estimated through comparing precipitation under forest cover and in the open. We discuss/compare measurement methods for forest precipitation interception beyond classical budgeting and then recommend future directions for improving water storage estimation. Comparison of techniques shows that methods submerging tree components produce the largest water storage capacity values. Whole‐tree lysimeters have been used with great success at quantifying water storage for the integrated system yet are unable to separate trunk versus canopy storage. Remote sensing, particularly signal attenuation, may permit this separation. Mechanical displacement methods show great promise and variety of techniques: pulley/spring system, branch strain sensors, trunk compression sensors and photography. Relating wind sway to water storage also shows great promise with negligible environmental disruption yet is currently at the proof‐of‐concept stage. Suggested future directions focus on development of common features regarding all discussed methods: (i) measurement uncertainties or processes beyond interception influencing the observed signal, (ii) scaling approaches to move from single tree components to the single‐tree and forest scales and (iii) temporal scaling to estimate the relevance of single‐interception components over longer timescales. Through addressing these research needs, we hope the scientific community can develop an ‘integrated’ monitoring plan incorporating multiple measurement techniques to characterize forest‐scale water storage dynamics while simultaneously investigating underlying (smaller‐scale) components driving those dynamics across the spectrum of precipitation and forest conditions. Copyright © 2014 John Wiley & Sons, Ltd.     

Zur Konzentrationsabhängigkeit der Sorption von Co(II) an Titanschwamm

The sorption of Co(II) from aqueous solutions on granulated titanium dioxide was investigated in dependence on pH-value (pH = 6 … 10) and solution concentration (c_L = 10^?7 … 10^?2 mol/kg) at 83 °C. The precipitation in the solution occurred at high pH-values and solution concentrations was determined by control experiments without the adsorber. The adsorption isotherms are S-shaped. This can be interpreted as transition from chemisorption at the basic material to surface precipitation.     

Effect of leaf distribution pattern on the interception storage capacity of leaf litter under simulated rainfall conditions

Rainwater interception by leaf litter is an important part of forest hydrological processes. The objective of this study was to investigate the interception storage capacity (ISC) of woodland leaf litter for three leaf distribution patterns, one flow path, two flow paths, and three flow paths, manually simulated via one-by-one leaf connection in the top leaf litter layer. A random pattern served as the control. Three different slopes (0°, 5° and 25°, representing flat, gentle and steep slopes, respectively) and two contrasting leaf litters (needle-leaf litter, represented by P. massoniana leaves, and broad-leaf litter, represented by C. camphora leaves) with a biomass of 0.5 kg/m² per unit area were applied, at a rainfall intensity of 50 mm/h. Results suggested that leaf distribution pattern greatly impacts litter drainage and hence affects leaf litter ISC. The delaying capacity of litter drainage initiation and ISC of broad-leaf litter were higher than those of needle-leaf litter under the same slope conditions. The maximum ISC (C_max) and minimum ISC (C_min) of leaf litter at flat and gentle slopes were higher than those at steep slope. C_min of the broad-leaf litter was two times higher than that of needle-leaf litter on average. When raindrops reached the litter layer, some were temporarily intercepted by the top litter layer while others infiltrated leaf litter sublayer along leaf edges, and in the process, some rainwater flowed through litter layer and contributed to lateral litter drainage along the potential flow path formed by leaves. The lateral litter drainage of broad-leaf litter was higher than that of needle-leaf litter, and the partitioning of rainwater into lateral litter drainage increased with increases in slope. The difference in leaf litter C_max among different slopes and leaf shapes decreased with flow path increasing. Therefore, leaf distribution pattern notably impact leaf litter ISC, which is similar to leaf shape and slope impacts. On inclined slopes, avoiding leaf accumulation to form flow path is helpful for improving ISC.     

Solute movement through intact columns of cryoturbated Upper Chalk

Cryoturbated Upper Chalk is a dichotomous porous medium wherein the intra‐fragment porosity provides water storage and the inter‐fragment porosity provides potential pathways for relatively rapid flow near saturation. Chloride tracer movement through 43 cm long and 45 cm diameter undisturbed chalk columns was studied at water application rates of 0·3, 1·0, and 1·5 cm h^?1. Microscale heterogeneity in effluent was recorded using a grid collection system consisting of 98 funnel‐shaped cells each 3·5 cm in diameter. The total porosity of the columns was 0·47 ± 0·02 m³ m^?3, approximately 13% of pores were ≥ 15 µm diameter, and the saturated hydraulic conductivity was 12·66 ± 1·31 m day^?1. Although the column remained unsaturated during the leaching even at all application rates, proportionate flow through macropores increased as the application rate decreased. The number of dry cells (with 0 ml of effluent) increased as application rate decreased. Half of the leachate was collected from 15, 19 and 22 cells at 0·3, 1·0, 1·5 cm h^?1 application rates respectively. Similar breakthrough curves (BTCs) were obtained at all three application rates when plotted as a function of cumulative drainage, but they were distinctly different when plotted as a function of time. The BTCs indicate that the columns have similar drainage requirement irrespective of application rates, as the rise to the maxima (C/C_o) is almost similar. However, the time required to achieve that leaching requirement varies with application rates, and residence time was less in the case of a higher application rate. A two‐region convection–dispersion model was used to describe the BTCs and fitted well (r² = 0·97–0·99). There was a linear relationship between dispersion coefficient and pore water velocity (correlation coefficient r = 0·95). The results demonstrate the microscale heterogeneity of hydrodynamic properties in the Upper Chalk. Copyright © 2007 John Wiley & Sons, Ltd.