A Morphological Study of Greenschist Weathering on Dated Coastal Structures,South Devon,UK

Three dated structures up to 450 years in age display the effects of coastal weathering of the greenschist of which they are constructed. A variety of weathering forms is present. The various topographic surfaces of the structures create variation in weathering environments and consequent weathering processes and rates. Weathering is enhanced by direct exposure to salt-bearing spray and by humid conditions, and apparently limited by direct exposure to solar radiation. The maximum rates of weathering on the three surfaces approximate to 0·6 mm a⁻¹ over this period, consistent with measured contemporary weathering rates for a natural surface formed by this rock type in a nearby coastal location. © 1997 by John Wiley & Sons, Ltd.     

Sr isotope evolution during chemical weathering of granites -- impact of relative weathering rates of minerals

The Sr isotopic systematics in the weathering profiles of biotite granite and granite porphyry in southern Jiangxi Province were investigated. The results showed that during the chemical weathering of granites, remarked fractionation occurred between Rb and Sr. During the early stages of chemical weathering of granites, the released Sr/Si and Sr/Ca ratios are larger than those of the parent rocks, and the leaching rate of Sr is higher than those of Si, Ca, K, Rb, etc. Dynamic variations in relative weathering rates of the main Sr-contributing minerals led to fluctuation with time in 87Sr/86Sr ratios of inherent and released Sr in the weathering crust of granite. Successive weathering of biotite, plagioclase and K-feldspar made 87Sr/86Sr ratios in the weathering residues show such a fluctuation trend as to decrease first, increase, and then decrease again till they maintain stable. This work further indicates that when Sr isotopes are used to trace biogeochemical processes on both the catchment and global scales, one must seriously take account of the prefer-ential release of Sr from dissolving solid phase and the fluctuation of 87Sr/86Sr ratios caused by the variations of relative weathering rates of Sr-contributing minerals.     

Exploring an ‘ideal hill': how lithology and transport mechanisms affect the possibility of a steady state during weathering and erosion

We present a model of chemical reaction within hills to explore how evolving porosity (and by inference, permeability) affects flow pathways and weathering. The model consists of hydrologic and reactive-transport equations that describe alteration of ferrous minerals and feldspar. These reactions were chosen because previous work emphasized that oxygen- and acid-driven weathering affects porosity differently in felsic and mafic rocks. A parameter controlling the order of the fronts is presented. In the absence of erosion, the two reaction fronts move at different velocities and the relative depths depend on geochemical conditions and starting composition. In turn, the fronts and associated changes in porosity drastically affect both the vertical and lateral velocities of water flow. For these cases, estimates of weathering advance rates based on simple models that posit unidirectional constant-velocity advection do not apply. In the model hills, weathering advance rates diminish with time as the Darcy velocities decrease with depth. The system can thus attain a dynamical steady state at any erosion rate where the regolith thickness is constant in time and velocities of both fronts become equal to one another and to the erosion rate. The slower the advection velocities in a system, the faster it attains a steady state. For example, a massive rock with relatively fast-dissolving minerals such as diabase – where solute transport across the reaction front mainly occurs by diffusion – can reach a steady state more quickly than granitoid rocks in which advection contributes to solute transport. The attainment of a steady state is controlled by coupling between weathering and hydrologic processes that force water to flow horizontally above reaction fronts where permeability changes rapidly with depth and acts as a partial barrier to fluid flow. Published 2020. This article is a U.S. Government work and is in the public domain in the USA.     

基于BSA及固定碘速率探讨不同浓度对比剂对肝静脉CT成像效果的影响

目的：探讨基于体表面积（BSA）和固定碘速率给药,不同浓度对比剂对CT肝静脉成像质量的影响。方法：选取2020年1月至11月符合纳入标准,行上腹部增强CT扫描的患者130例,根据所用对比剂浓度不同,分为高浓度组（62例）和低浓度组（68例）,高浓度组对比剂为碘帕醇（含碘370mg/mL）,低浓度组对比剂为碘佛醇（含碘320mg/mL）;根据BSA计算患者所用对比剂的总量,固定碘速率注射,进行分期动态扫描。选取肝静脉期数据行肝静脉血管重建,对图像质量进行评价,测量两组图像肝静脉和肝实质的CT值及其标准差值,计算信噪比和对比噪声比,并对图像质量进行主观评分;采用独立样本t检验比较两组间客观评价指标的差异,采用Mann-Whitney U检验比较主观评分的差异。结果：高、低浓度组图像评分分别为（3.74±0.47）分和（3.77±0.53）分,差异无统计学意义;两组间肝静脉左、中、右三支主干和同层面肝实质的CT值、SD值、SNR及肝静脉相对于肝实质的CNR,差异无统计学意义。结论：基于BSA及固定碘速率注射对比剂,两种不同浓度对比剂在肝静脉CT成像中的效果同样清晰利于诊断。     

Isotopic characteristics of groundwater in Changzhou,Wuxi and Suzhou area and their implications

Based on the study of groundwater isotope(2H and 18O, 34S, 15N, 3H, 14C) in Changzhou, Wuxi and Suzhou area, it is found that the deep confined groundwater has no pollution on the whole, whereas the shallow groundwater is polluted to a different degree in the area. The deep confined aquifers (main exploitation aquifers) in Changzhou area and in Wuxi and Suzhou area likely belong to two different aquifers. The main exploitation aquifers in Changzhou area are not connected with those in Wuxi and Suzhou area, or they are connected but not expedited. The lateral run-off of groundwater is at present directed to the exploitation center because of overexploitation of the deep groundwater for a long time, but the flowing speed of groundwater is still extremely slow. The deep confined groundwater is in a close to half close state. The 14C age of groundwater varies from 10000 a BP to 38000 a BP, with the oldest groundwater found at the nearest exploitation center (along the line of three cities of Changzhou, Wuxi and Suzhou) and the youngest at the furthest exploitation center.     

Temporal variation of chemical and mechanical weathering in NE Iceland: Evaluation of a steady-state model of erosion

This study critically assesses the temporal sensitivity of the steady-state model of erosion that has been applied to chemical and mechanical weathering studies of volcanic islands and the continents, using only one sample from each catchment. The model assumes a geochemical mass balance between the initially unweathered rock of a drainage basin and the dissolved and solid loads of the river.Chemical composition of 178 samples of suspended and dissolved inorganic river constituents, collected in 1998–2002, were studied from five basaltic river catchments in NE Iceland. The Hydrological Service in Iceland has monitored the discharge and the total suspended inorganic matter concentration (SIM) of the glacial rivers for ~ four decades, making it possible to compare modelled and measured SIM fluxes.Concentration of SIM and grain size increased with discharge. As proportion of clay size particles in the SIM samples increased, concentrations of insoluble elements increased and of soluble decreased. The highest proportion of altered basaltic glass was in the clay size particles.The concentration ratio of insoluble elements in the SIM was used along with data on chemical composition of unweathered rocks (high-Mg basalts, tholeiites, rhyolites) to calculate the pristine composition of the original catchment rocks. The calculated rhyolite proportions compare nicely with area-weighted average proportions, from geological maps of these catchments.The calculated composition of the unweathered bedrock was used in the steady-state model, together with the chemical composition of the suspended and dissolved constituents of the river. Seasonal changes in dissolved constituent concentrations resulted in too low modelled concentrations of SIM_mod at high discharge (and too high SIM_mod at low discharge). Samples collected at annual average river dissolved load yielded SIM_mod concentrations close to the measured ones. According to the model, the studied rivers had specific mechanical denudation rates of 1.3–3.0 kg/m²/yr whereas the average measured rates were 0.8–3.5 kg/m²/yr which are among the highest on Earth.This study validates the use of a steady-state model of erosion to estimate mechanical weathering rates at the scale of a river catchment when the collected riverine dissolved load represents the average chemical composition over a mean hydrological year.