Study of bond stress–slip relationship and radial dilation in prestressed concrete

This paper presents two test procedures for evaluating the bond stress–slip and the slip–radial dilation relationships when the prestressing force is transmitted by releasing the steel (wire or strand) in precast prestressed elements. The bond stress–slip relationship is obtained with short length specimens, to guarantee uniform bond stress, for three depths of the wire indentation (shallow, medium and deep). An analytical model for bond stress–slip relationship is proposed and compared with the experimental results. The model is also compared with the experimental results of other researchers. Since numerical models for studying bond‐splitting problems in prestressed concrete require experimental data about dilatancy angle (radial dilation), a test procedure is proposed to evaluate these parameters. The obtained values of the radial dilation are compared with the prior estimated by numerical modelling and good agreement is reached. Copyright © 2012 John Wiley & Sons, Ltd.     

A coupled chemo‐thermo‐hygro‐mechanical model of concrete at high temperature and failure analysis

A hierarchical mathematical model for analyses of coupled chemo‐thermo‐hygro‐mechanical behaviour in concretes at high temperature is presented. The concretes are modelled as unsaturated deforming reactive porous media filled with two immiscible pore fluids, i.e. the gas mixture and the liquid mixture, in immiscible–miscible levels. The thermo‐induced desalination process is particularly integrated into the model. The chemical effects of both the desalination and the dehydration processes on the material damage and the degradation of the material strength are taken into account. The mathematical model consists of a set of coupled, partial differential equations governing the mass balance of the dry air, the mass balance of the water species, the mass balance of the matrix components dissolved in the liquid phases, the enthalpy (energy) balance and momentum balance of the whole medium mixture. The governing equations, the state equations for the model and the constitutive laws used in the model are given. A mixed weak form for the finite element solution procedure is formulated for the numerical simulation of chemo‐thermo‐hygro‐mechanical behaviours. Special considerations are given to spatial discretization of hyperbolic equation with non‐self‐adjoint operator nature. Numerical results demonstrate the performance and the effectiveness of the proposed model and its numerical procedure in reproducing coupled chemo‐thermo‐hygro‐mechanical behaviour in concretes subjected to fire and thermal radiation. Copyright © 2005 John Wiley & Sons, Ltd.     

Influence of tectonic overpressure on P–T paths of HP–UHP rocks in continental collision zones: thermomechanical modelling

The principle of lithostatic pressure is habitually used in metamorphic geology to calculate burial/exhumation depth from pressure given by geobarometry. However, pressure deviation from lithostatic, i.e. tectonic overpressure/underpressure due to deviatoric stress and deformation, is an intrinsic property of flow and fracture in all materials, including rocks under geological conditions. In order to investigate the influences of tectonic overpressure on metamorphic P–T paths, 2D numerical simulations of continental subduction/collision zones were conducted with variable brittle and ductile rheologies of the crust and mantle. The experiments suggest that several regions of significant tectonic overpressure and underpressure may develop inside the slab, in the subduction channel and within the overriding plate during continental collision. The main overpressure region that may influence the P–T paths of HP–UHP rocks is located in the bottom corner of the wedge‐like confined channel with the characteristic magnitude of pressure deviation on the order of ～0.3 GPa and 10–20% from the lithostatic values. The degree of confinement of the subduction channel is the key factor controlling this magnitude. Our models also suggest that subducted crustal rocks, which may not necessarily be exhumed, can be classified into three different groups: (i) UHP‐rocks subjected to significant (≥0.3 GPa) overpressure at intermediate subduction depth (50–70 km, P = 1.5–2.5 GPa) then underpressured at depth ≥100 km (P ≥ 3 GPa); (ii) HP‐rocks subjected to ≥0.3 GPa overpressure at peak P–T conditions reached at 50–70 km depth in the bottom corner of the wedge‐like confined subduction channel (P = 1.5–2.5 GPa); (iii) lower‐pressure rocks formed at shallower depths (≤40 km depth, P ≤ 1 GPa), which are not subjected to significant overpressure and/or underpressure.     

Genesis of the Weiquan Ag–Polymetallic Deposit in East Tianshan, China: Evidence from Zircon U–Pb Geochronology and C–H–O–S–Pb Isotope Systematics

The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ~(13)C values of the calcite samples range from-2.5‰ to 2.3‰, the δ~(18)O_(H2 O) and δD_(VSMOW) values of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ~(13)C, δ~(18)O_(H2 O) and δD_(V-SMOW) values of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ~(34)S_(V-CDT) values of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields~(206)Pb/~(204)Pb,~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.     

Constitutive description of interface behavior including cyclic loading and particle breakage within the framework of critical state soil mechanics

The cyclic behavior of soil–structure interface can be very important in dynamic problems. The cyclic behavior of soil–structure interface may be nonlinear, which includes hysteresis, hardening, degradation, and particle breakage. The breakage of granular soil particles during shearing of granular soil–structure interface is associated with cyclic degradation and can be critical to the dynamic behavior of soil–structure system. The critical state soil mechanics concept formerly used to simulate the nonlinear monotonic behavior of granular soil–structure interface was modified and extended to describe the cyclic behavior, especially soil‐particle breakage and degradation during cyclic shearing. Soil‐particle breakage was assumed to relate to the energy consumption during cyclic shearing and the critical state line of the soil–structure interface was assumed to translate with the consumption of shearing energy during cyclic shearing as the threshold value is attained. The model was formulated in the framework of generalized plasticity and is capable of describing the salient features of granular soil–structure interface under cyclic loading. Most of the model parameters have straightforward physical meanings and are calibrated using monotonic or cyclic interface test results. The proposed model was calibrated and validated against published test results. The dependency of interface behavior on stress path and cyclic degradation can be successfully described by the proposed model. Copyright © 2008 John Wiley & Sons, Ltd.     

The Late Triassic I–Type Granites from the Longmu Co–Shuanghu Suture Zone in the interior of Tibetan Plateau, China: Petrogenesis and Implication for Slab Break–Off

The Jiangaidarina granitic mass(JM) is an important part of the magmatic belt in Longmu CoShuanghu Suture Zone(LSSZ) in the central Tibetan Plateau. An integrated research involving wholerock geochemistry, zircon LA-ICP-MS U-Pb ages and Hf isotopic compositions was carried out to define the timing, genesis and tectonic setting of the JM. Zircon LA-ICP-MS U-Pb ages have been obtained ranging from 210 to 215 Ma, rather than the Early Jurassic as previously thought. Fifteen granite samples contain hornblendes and show a negative correlation between P_2 O_5 and SiO_2, indicating that the JM is an I-type granite. All the granites are enriched in LREE relative to HREE, with negative Eu anomalies(Eu/Eu*=0.56-0.81), and have similar trace elements patterns, with depletion of Ba, Nb, Sr and P. These suggest that the JM was fractionated, and this is also proved by the characteristic of negative correlations between oxide elements(TiO_2, MgO, FeOt, MnO, CaO) and SiO_2. Almost all ε_(Hf)(t) values of the granites are between-10.3 and-5.8, implying that the JM has a crustal source intimately related with the South Qiangtang Block(SQB), except for one(+10.2), showing a minor contribution from mantle source.Moreover, relatively low Na_2 O/K_2 O ratios(0.42-0.93) and high A/CNK values(0.91-1.50) reflect that the JM was predominately derived from the medium-high potassium basaltic crust, interacted with greywacke. Our new geochemical data and geochronological results imply that the Late Triassic magmas were generated in a post-collisional tectonic setting, probably caused by slab break-off of the Longmu Co-Shuanghu Tethyan Ocean(LSTO). This mechanism caused the asthenosphere upwelling, formed extension setting, offered an enormous amount of heat, and provided favorable conditions for emplacement of voluminous felsic magmas. Furthermore, the LSTO could be completely closed during the Middle Triassic, succeed by continental collision and later the slab broke off in the Late Triassic.     

Age and P–T conditions of the Gridino‐type eclogite in the Belomorian Province,Russia

Although eclogites in the Belomorian Province have been regarded as Archean in age and among the oldest in the world, there are also multiple studies that have proposed a Paleoproterozoic age. Here, we present new data for the Gridino‐type eclogites, which occur as boudins and metamorphosed dykes within tonalite–trondhjemite–granodiorite gneisses. Zircon from these eclogites has core and rim structures. The cores display high Th/U ratios (0.18–0.45), negative Eu anomalies and strong enrichment in HREE, and have Neoarchean U–Pb ages of c. 2.70 Ga; they are interpreted to be magmatic in origin. Zircon cores have δ¹⁸O of 5.64–6.07‰ suggesting the possibility of crystallization from evolved mantle‐derived magmas. In contrast, the rims, which include the eclogite facies minerals omphacite and garnet, are characterized by low Th/U ratios (<0.035) and flat HREE patterns, and yield U–Pb ages of c. 1.90 Ga; they are interpreted to be metamorphic in origin. Zircon rims have elevated δ¹⁸O of 6.23–6.80‰, which was acquired during eclogite facies metamorphism. Based on petrography and phase equilibria modelling, we recognize a prograde epidote amphibolite facies mineral assemblage, the peak eclogite facies mineral assemblage and a retrograde high‐P amphibolite facies mineral assemblage. The peak metamorphic conditions of 695–755°C at >18 kbar for the Gridino‐type eclogites suggest an apparent thermal gradient of <39–42°C/kbar for the Lapland–Kola collisional orogeny.     

Mesozoic to Cenozoic tectono‐metamorphic history of the South Pamir–Hindu Kush (Chitral,NW Pakistan): Insights from phase equilibria modelling,and garnet–monazite petrochronology

The Karakoram–Hindu Kush–Pamir and adjacent Tibetan plateau belt comprise a series of Gondwana‐derived crustal fragments that successively accreted to the Eurasian margin in the Mesozoic as the result of the progressive Tethys ocean closure. These domains provide unique insights into the thermal and structural history of the Mesozoic to Cenozoic Eurasian plate margin, which are critical to inform the initial boundary conditions (e.g. crustal thickness, structure and thermo‐mechanical properties) for the subsequent development of the large and hot Tibetan–Himalaya orogen, and the associated crustal deformation processes. Using a combination of microstructural analyses, thermobarometry modelling and U–Th–Pb monazite and Lu–Hf garnet geochronology, the study reappraises the metamorphic history of exposed mid‐crustal metapelites in the Chitral region of the South Pamir–Hindu Kush (NW Pakistan). This study also demonstrates that trace elements in monazite (especially Y and Dy), combined with thermodynamical modelling and Lu–Hf garnet dating, provides a powerful integrated toolbox for constraining long‐lived and polyphased tectono‐metamorphic histories in all their spatial and temporal complexity. Rocks from the Chitral region were progressively deformed and metamorphosed at sub‐ and supra‐solidus conditions through at least four distinct episodes from the Mesozoic to the Cenozoic. Rocks were first metamorphosed at ~400–500°C and ~0.3 GPa in the Late Triassic–Early Jurassic (210–185 Ma), likely in response to the accretion of the Karakoram during the Cimmerian orogeny. Pressure and temperature subsequently increased by ~0.3 GPa and 100°C in the Early‐ to Mid Cretaceous (140–80 Ma), coinciding with the intrusion of calcalkaline granitic plutons across the Karakoram and Pamir regions. This event is interpreted as the record of crustal thickening and the development of a proto‐plateau within the Eurasian margin due to a long‐lived episode of slab flattening in an Andean‐type margin. Peak metamorphism was reached in the Late Eocene–Early Oligocene (40–30 Ma) at conditions of 580–600°C and ~0.6 GPa and 700–750°C and 0.7–0.8 GPa for the investigated staurolite schists and sillimanite migmatites respectively. This crustal heating up to moderate anatexis likely resulted in the underthrusting of the Indian plate after a NeoTethyan slab‐break off or to the Tethyan Himalaya–Lhasa microcontinent collision and subsequent oceanic slab flattening. Near‐isothermal decompression/exhumation followed in the Late Oligocene (28–23 Ma) as marked by a pressure decrease in excess of ~0.1 GPa. This event was coeval with the intrusion of the 24 Ma Garam Chasma leucogranite. This rapid exhumation is interpreted to be related to the reactivation of the South Pamir–Karakoram suture zone during the ongoing collision with India. The findings of this study confirm that significant crustal shortening and thickening of the south Eurasian margin occurred during the Mesozoic in an accretionary‐type tectonic setting through successive episodes of terrane accretions and probably slab flattening, transiently increasing the coupling at the plate interface. Moreover, they indicate that the south Eurasian margin was already hot and thickened prior to Cenozoic collision with India, which has important implications for orogen‐scale strain‐accommodation mechanisms.     

Petrological constraints on the tectonic setting of the Kathmandu Nappe in the Langtang–Gosainkund–Helambu regions,Central Nepal Himalaya

The Gosainkund–Helambu region in central Nepal occupies a key area for the development of Himalayan kinematic models, connecting the well‐investigated Langtang area to the north with the Kathmandu Nappe (KN), whose interpretation is still debated, to the south. In order to understand the structural and metamorphic architecture of the Greater Himalayan Sequence (GHS) in this region, a detailed petrological study was performed, focusing on selected metapelite samples from both the Gosainkund–Helambu and Langtang transects. The structurally lowest sample investigated belongs to the Lesser Himalayan Sequence; its metamorphic evolution is characterized by a narrow hairpin P–T path with peak P–T conditions of 595 ± 25 °C, 7.5 ± 1 kbar. All of the other samples here investigated belong to the GHS. Along the Langtang section, two tectono‐metamorphic units have been distinguished within the GHS: the Lower Greater Himalayan Sequence (L‐GHS), characterized by peak P–T conditions at 728 ± 11 °C, 10 ± 0.5 kbar (corresponding to a T/depth ratio of 22 ± 1 °C km^?1), and the structurally higher Upper Greater Himalayan Sequence, with peak metamorphic conditions at 780 ± 20 °C, 7.8 ± 0.8 kbar (corresponding to a T/depth ratio of 31 ± 4 °C km^?1). This confirms the existence of a main tectono‐metamorphic discontinuity within the GHS, as previously suggested by other authors. The results of petrological modelling of the metapelites from the Gosainkund–Helambu section show that this region is entirely comprised within a sub‐horizontal and thin L‐GHS unit: the estimated peak metamorphic conditions of 734 ± 19 °C, 10 ± 0.8 kbar correspond to a uniform T/depth ratio of 23 ± 3 °C km^?1. The metamorphic discontinuity identified along the Langtang transect and dividing the GHS in two tectono‐metamorphic units is located at a structural level too high to be intersected along the Gosainkund–Helambu section. Our results have significant implications for the interpretation of the KN and provide a contribution to the more general discussion of the Himalayan kinematic models. We demonstrate that the structurally lower unit of the KN (known as Sheopuri Gneiss) can be correlated with the L‐GHS unit; this result strongly supports those models that correlate the KN to the Tethyan Sedimentary Sequence and that suggest the merging of the South Tibetan Detachment System and the Main Central Thrust on the northern side of the KN. Moreover we speculate that, in this sector of the Himalayan chain, the most appropriate kinematic model able to explain the observed tectono‐metamorphic architecture of the GHS is the duplexing model, or hybrid models which combine the duplexing model with another end‐member model.     

Modelling the flow of self‐compacting concrete

A Lagrangian particle‐based method, smooth particle hydrodynamics (SPH), is used in this paper to model the flow of self‐compacting concretes (SCC) with or without short steel fibres. An incompressible SPH method is presented to simulate the flow of such non‐Newtonian fluids whose behaviour is described by a Bingham‐type model, in which the kink in the shear stress vs shear strain rate diagram is first appropriately smoothed out. The viscosity of the SCC is predicted from the measured viscosity of the paste using micromechanical models in which the second phase aggregates are treated as rigid spheres and the short steel fibres as slender rigid bodies. The basic equations solved in the SPH are the incompressible mass conservation and Navier–Stokes equations. The solution procedure uses prediction–correction fractional steps with the temporal velocity field integrated forward in time without enforcing incompressibility in the prediction step. The resulting temporal velocity field is then implicitly projected on to a divergence‐free space to satisfy incompressibility through a pressure Poisson equation derived from an approximate pressure projection. The results of the numerical simulation are benchmarked against actual slump tests carried out in the laboratory. The numerical results are in excellent agreement with test results, thus demonstrating the capability of SPH and a proper rheological model to predict SCC flow and mould‐filling behaviour. Copyright © 2010 John Wiley & Sons, Ltd.     

Elasto‐plastic modelling of stress‐path‐dependent behaviour of interfaces

A single‐surface elasto‐plastic model developed by Desai and his coworkers is used to predict the behaviour of an interface between sand and a steel plate. The loading in the experiments and in their predictions followed various stress and displacement paths. The results of predictions of the two‐ and three‐dimensional behaviour of the interface under both constant normal stress and constant normal stiffness conditions are presented. The predictions are compared with their corresponding experimental results. The model parameters were determined on the basis of 2‐D conventional experiments under the condition of constant normal stress and they were used in the prediction of the interface behaviour in various stress paths. There is, in general, a good agreement between the predicted and experimental results. Copyright © 2000 John Wiley & Sons, Ltd.     

Petrology,geochemistry and P–T–t path of lawsonite‐bearing retrograded eclogites in the Changning–Menglian orogenic belt,southeast Tibetan Plateau

The Changning–Menglian orogenic belt (CMOB) in the southeastern Tibetan Plateau, is considered as the main suture zone marking the closure of the Palaeo‐Tethys Ocean between the Indochina and Sibumasu blocks. Here, we investigate the recently discovered retrograded eclogites from this suture zone in terms of their petrological, geochemical and geochronological features, with the aim of constraining the metamorphic evolution and protolith signature. Two types of metabasites are identified: retrograded eclogites and mafic schists. The igneous precursors of the retrograded eclogites exhibit rare earth element distribution patterns and trace element abundance similar to those of ocean island basalts, and are inferred to have been derived from a basaltic seamount in an intra‐oceanic tectonic setting. In contrast, the mafic schists show geochemical affinity to arc‐related volcanics with the enrichment of Rb, Th and U, and depletion of Nb, Ta, Zr, Hf and Ti, and their protoliths possibly formed at an active continental margin tectonic setting. Retrograded eclogites are characterized by peak metamorphic mineral assemblages of garnet, omphacite, white mica, lawsonite and rutile, and underwent five‐stage metamorphic evolution, including pre‐peak prograde stage (M₁) at 18–19 kbar and 400–420°C, peak lawsonite‐eclogite facies (M₂) at 24–26 kbar and 520–530°C, post‐peak epidote–eclogite facies decompression stage (M₃) at 13–18 kbar and 530–560°C, subsequent amphibolite facies retrogressive stage (M₄) at 8–10 kbar and 530–600°C, and late greenschist facies cooling stage (M₅) at 5–8 kbar and 480–490°C. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) U–Pb spot analyses of zircon show two distinct age groups. The magmatic zircon from both the retrograded eclogite and mafic schist yielded protolith ages of 451 ± 3 Ma, which is consistent with the ages of Early Palaeozoic ophiolitic complexes and ocean island sequences in the CMOB reported in previous studies. In contrast, metamorphic zircon from the retrograded eclogite samples yielded consistent Triassic metamorphic ages of 246 ± 2 and 245 ± 2 Ma, which can be interpreted as the timing of closure of the Palaeo‐Tethys Ocean. The compatible peak metamorphic mineral assemblages, P–T–t paths and metamorphic ages, as well as the similar protolith signatures for the eclogites in the CMOB and Longmu Co–Shuanghu suture (LCSS) suggest that the two belts formed part of a cold oceanic subduction system in the Triassic. The main suture zone of the Palaeo‐Tethyan domain extends at least 1,500 km in length from the CMOB to the LCSS in the Tibetan Plateau. The identification of lawsonite‐bearing retrograded eclogites in the CMOB provides important insights into the tectonic framework and complex geological evolution of the Palaeo‐Tethys.     

Formation of sequential basins along a strike–slip fault–Geophysical observations from the Dead Sea basin

The Dead Sea basin is often cited as one of the classic examples for the evolution of pull-apart basins along strike–slip faults. Despite its significance, the internal structure of the northern Dead Sea basin has never been addressed conclusively. In order to produce the first comprehensive, high-resolution analysis of this area, all available seismic data from the northern Dead Sea (lake)–lower Jordan valley (land) were combined. Results show that the northern Dead Sea basin is comprised of a system of tectonically controlled sub-basins delimited by the converging Western and Eastern boundary faults of the Dead Sea fault valley. These sub-basins grow shallower and smaller to the north and are separated by structural saddles marking the location of active transverse faults. The sedimentary fill within the sub-basins was found to be relatively thicker than previously interpreted. As a result of the findings of this study, the “classic” model for the development of pull-aparts, based on the Dead Sea, is revised. The new comprehensive compilation of data produced here for the first time was used to improve upon existing conceptual models and may advance the understanding of similar basinal systems elsewhere.     

Genesis of Pb–Zn Mineralization Beneath the Xiangshan Uranium Orefield,South China: Constraints from H–O–S–Pb Isotopes and Rb–Sr Dating

The volcanic‐hosted Xiangshan uranium orefield is the largest uranium deposit in South China. Recent exploration has discovered extensive Pb–Zn mineralization beneath the uranium orebodies. Detailed geological investigation reveals that the major metallic minerals include pyrite, sphalerite, galena, and chalcopyrite, whilst the major non‐metallic minerals include quartz, sericite, and calcite. New δ¹⁸O_fluid and δD_fluid data indicate that the ore‐forming fluids were mainly derived from magmatic, and the sulfide δ³⁴S values (2.2–6.9‰) suggest a dominantly magmatic sulfur source. The Pb isotope compositions are homogeneous (²⁰⁶Pb/²⁰⁴Pb = 18.120–18.233, ²⁰⁷Pb/²⁰⁴Pb = 15.575–15.698, and ²⁰⁸Pb/²⁰⁴Pb = 37.047–38.446). The ⁸⁷Sr/⁸⁶Sr ratios of sulfide minerals range from 0.7197 to 0.7204, which is much higher than volcanic rocks and fall into the range of metamorphic basement. Lead and strontium isotopic compositions indicate that the metallogenic materials probably were derived from metamorphic basement. Pyrite Rb–Sr dating of the ores yielded 131.3 ± 4.0 Ma, indicating that the Pb–Zn mineralization occurred in the Early Cretaceous.     

Numerical modeling of three‐phase dissolution of underground cavities using a diffuse interface model

Natural evaporite dissolution in the subsurface can lead to cavities having critical dimensions in the sense of mechanical stability. Geomechanical effects may be significant for people and infrastructures because the underground dissolution may lead to subsidence or collapse (sinkholes). The knowledge of the cavity evolution in space and time is thus crucial in many cases. In this paper, we describe the use of a local nonequilibrium diffuse interface model for solving dissolution problems involving multimoving interfaces within three phases, that is, solid–liquid–gas as found in superficial aquifers and karsts. This paper generalizes developments achieved in the fluid–solid case, that is, the saturated case [1]. On one hand, a local nonequilibrium dissolution porous medium theory allows to describe the solid–liquid interface as a diffuse layer characterized by the evolution of a phase indicator (e.g., porosity). On the other hand, the liquid–gas interface evolution is computed using a classical porous medium two‐phase flow model involving a phase saturation, that is, generalized Darcy's laws. Such a diffuse interface model formulation is suitable for the implementation of a finite element or finite volume numerical model on a fixed grid without an explicit treatment of the interface movement. A numerical model has been implemented using a finite volume formulation with adaptive meshing (e.g., adaptive mesh refinement), which improves significantly the computational efficiency and accuracy because fine gridding may be attached to the dissolution front. Finally, some examples of three‐phase dissolution problems including density effects are also provided to illustrate the interest of the proposed theoretical and numerical framework. Copyright © 2014 John Wiley & Sons, Ltd.     

Sm–Nd and Ar–Ar Isotopic Dating of the Nuri Cu–W–Mo Deposit in the Southern Gangdese,Tibet: Implications for the Porphyry‐Skarn Metallogenic System and Metallogenetic Epochs of the Eastern Gangdese

The Nuri Cu–W–Mo deposit is a large newly explored deposit located at the southern margin of the Gangdese metallogenic belt. There are skarn and porphyry mineralizations in the deposit, but the formation age of the skarn and the relationship between the skarn and porphyry mineralizations are controversial. Constraints on the precise chronology are of fundamental importance for understanding the ore genesis of the Nuri deposit. To determine the formation age of the skarn, we chose garnets and whole rock skarn samples for Sm–Nd dating. We also selected biotite associated with potassic alteration for Ar–Ar dating to confirm the ore formation age of the porphyry mineralizations. The Sm–Nd ages of the skarn are 25.73 ± 0.92 – 25.2 ± 3.9 Ma, and the age of the potassic alteration is 24.37 ± 0.32 Ma. The results indicate that the skarn and porphyry mineralization are coeval and belong to a unified magmatic hydrothermal system. Combined with a previous molybdenite Re–Os age, we think that the hydrothermal activity of the Nuri deposit lasted for 1.2 – 2.1 Myr, which indicates that the mineralization formed rapidly. The chronologic results indicate that the Nuri deposit formed in the period of transformation from compression to extension in the late collisional stage of the collision between the Indian and Eurasian continents.     

Cohesive‐frictional model for bond and splitting action of prestressing wire

This paper presents a numerical procedure for bond between indented wires and concrete, and the coupled splitting process of the surrounding concrete. The bond model is an interface, non‐associative, plasticity model. It is coupled with a cohesive fracture model for concrete to take into account the splitting of such concrete. Bond between steel and concrete is fundamental for the transmission of stresses between both materials in precast prestressed concrete. Indented wires are used to improve the bond in these structural elements. The radial component of the prestressing force, increased by Poisson's effect, may split the surrounding concrete, decreasing the wire confinement and diminishing the bonding. The combined action of the bond and the splitting is studied with the proposed model. The results of the numerical model are compared with the results of a series of tests, such as those which showed splitting induced by the bond between wire and concrete. Tests with different steel indentation depths were performed. The numerical procedure accurately reproduces the experimental records and improves knowledge of this complex process. Copyright © 2010 John Wiley & Sons, Ltd.     

Geochemistry,and zircon U–Pb and molybdenite Re–Os geochronology of Jilongshan Cu–Au deposit,southeastern Hubei Province,China

The Jilongshan skarn Cu–Au deposit is located at the Jiurui ore cluster region in the southwestern part of the Middle–Lower Yangtze River valley metallogenic belt. The region is characterized by NW‐, NNW‐ and EW‐trending faults and the mineralization occurs at the contact of lower Triassic carbonate rocks and Jurassic granodiorite porphyry intrusions. The intrusives are characterized by SiO₂, K₂O, and Na₂O concentrations ranging from 61.66 to 67.8 wt.%, 3.29 to 5.65 wt.%, and 2.83 to 3.9 wt.%, respectively. Their A/CNK (A/CNK = n(Al₂O₃)/[n(CaO) + n(Na₂O) + n(K₂O)]) ratio, δEu, and δCe vary from 0.77 to 1.17, 0.86 to 1, and 0.88 to 0.96, respectively. The rocks show enrichment in light rare earth elements ((La/Yb)_N = 7.61–12.94) and large ion lithophile elements (LILE), and depletion in high field strength elements (HFSE), such as Zr, Ti. They also display a peraluminous, high‐K calc‐alkaline signature typical of intrusives associated with skarn and porphyry Cu–Au–Mo polymetallic deposits. Laser ablation inductively coupled plasma spectrometry (LA‐ICP‐MS) zircon U–Pb age indicates that the granodiorite porphyry formed at 151.75 ± 0.70 Ma. A few inherited zircons with older ages (677 ± 10 Ma, 848 ± 11 Ma, 2645 ± 38 Ma, and 3411 ± 36 Ma) suggest the existence of an Archaean basement beneath the Middle–Lower Yangtze River region. The temperature of crystallization of the porphyry estimated from zircon thermometer ranges from 744.3 °C to 751.5 °C, and 634.04 °C to 823.8 °C. Molybdenite Re–Os dating shows that the Jilongshan deposit formed at 150.79 ± 0.82 Ma. The metallogeny and magmatism are correlated to mantle–crust interaction, associated with the subduction of the Pacific Plate from the east. Copyright © 2013 John Wiley & Sons, Ltd.     

The P–T–t evolution of the exhumed Himalayan metamorphic core in the Likhu Khola region,East Central Nepal

The recent identification of multiple strike‐parallel discontinuities within the exhumed Himalayan metamorphic core has helped revise the understanding of convergence accommodation processes within the former mid‐crust exposed in the Himalaya. Whilst the significance of these discontinuities to the overall development of the mountain belt is still being investigated, their identification and characterization has become important for potential correlations across regions, and for constraining the kinematic framework of the mid‐crust. The result of new phase equilibria modelling, trace element analysis and high‐precision Lu–Hf garnet dating of the metapelites from the Likhu Khola region in east central Nepal, combined with the previously published monazite petrochronology data confirms the presence of one of such cryptic thrust‐sense tectonometamorphic discontinuities within the lower portion of the exhumed metamorphic core and provides new constraints on the P–T estimates for that region. The location of the discontinuity is marked by an abrupt change in the nature of P–T–t paths of the rocks across it. The rocks in the footwall are characterized by a prograde burial P–T path with peak metamorphic conditions of ~660°C and ~9.5 kbar likely in the mid‐to‐late Miocene, which are overlain by the hanging wall rocks, that preserve retrograde P–T paths with P–T conditions of >700°C and ~7 kbar in the early Miocene. The occurrence of this thrust‐sense structure that separates rock units with unique metamorphic histories is compatible with orogenic models that identify a spatial and temporal transition from early midcrustal deformation and metamorphism in the deeper hinterland to later deformation and metamorphism towards the shallower foreland of the orogen. Moreover, these observations are comparable with those made across other discontinuities at similar structural levels along the Himalaya, confirming their importance as important orogen‐scale structures.