Dokhan volcanics of Gabal Monqul area,North Eastern Desert,Egypt: geochemistry and petrogenesis

The Dokhan volcanics are represented by a thick stratified lava flows succession of basalt, andesite, imperial porphyry, dacite, rhyodacite, rhyolite, ignimbrites, and tuffs. These lavas are interbanded with their pyroclastics in some places including banded ash flow tuffs, lithic tuffs, crystal lapilli tuffs, and agglomerates. They are typical calc–alkaline and developed within volcanic arc environment. All rocks show moderate enrichment of most large ion lithophile elements relative to high field strength elements (HFSE). The incompatible trace elements increase from basalt through andesite to rhyolite. The felsic volcanics are characterized by moderate total rare earth elements (REE) contents (162 to 392 ppm), less fractionated patterns {(Ce/Yb)_N = (1.24 to 10.93)}, and large negative Eu anomaly {(Eu/Eu*) = (0.15 to 0.92)}. The mafic volcanics have the lowest REE contents (61 to 192 ppm) and are relatively steep {(Ce/Yb)_N = (3.2 to 8.5)}, with no negative Eu anomalies {(Eu/Eu*) = (0.88 to 1)}. The rhyolite displays larger negative Eu anomaly (Eu/Eu* = 0.28) than those of other varieties, indicating that the plagioclase was an early major fractionating phase. The mineralogical and chemical variations within volcanics are consistent with their evolution by fractional crystallization of plagioclase and clinopyroxene.     

Mineral chemistry and geochemistry of ophiolitic metaultramafics from Um Halham and Fawakhir,Central Eastern Desert,Egypt

International Journal of Earth Sciences - This study is focused on ophiolitic metaultramafics from Um Halham and Fawakhir, Central Eastern Desert of Egypt. The rocks include serpentinized...     

Structural elements and incremental strain history of the basement rocks of Um Had area, central Eastern Desert, Egypt

The Um Had area, central Eastern Desert, Egypt shows a regional stretching in the NW–SE and a contraction in the NE–SW direction. Major NW–SE folds, small recumbent folds, and local thrusts and reverse faults were recognized. Complicated relation between folds and boudinage was identified. This stretching amount ranges from 1.282 to 1.309. Earlier coaxial and later non-coaxial strains were inferred. The change from axial to non-coaxial stress regime was gradual and the latter was associated with minor clockwise and anticlockwise rotation of structural elements. During the non-coaxial strain, strain fringes were formed as a consequence of the high circulation of fluids in low temperature and high pressure conditions. Superimposed strain fringes indicating right- and left-lateral senses of movement were recognized. At least three generations of fringes were recognized, implying three stages of non-coaxial stretching. Each generation has about 15 increments which show irregular strain gradient and intensity over the different increments. Eastwards, the strain increments became mature and westwards, the finite strain increases. The strongest finite strain was found in a narrow belt delimiting the basement rocks on the west and underlying the Phanerozoic sediments. Chocolate-tablet structure was recorded and indicates later multidirectional tension. Not all Nubia Sandstone exposures are overlying the basement rocks and some are separated by NW–SE normal faults. Major NW–SE normal faults are cutting basement rocks of different ages.     

Geochemistry and Radioactive Potentiality of Um Naggat Apogranite, Central Eastern Desert, Egypt

Abstract: The northern part of Um Naggat granite massif (UNGM) has suffered extensive post-magmatic metasomatic reworking which results into the development of (Zr, Hf, Nb, Ta, U, Th, F)– and albite-enriched and greisenized apogranite body (UNAP) of 600 m thick, and more than 3 km in the strike length.
Albitization produced an enrichment in Zr (av. 2384 ppm), Hf (61), Nb (419), and U (43). The Th/U ratio ranges between 1. 33 and 1. 90. Extreme albitization (i. e. the albitite rock) is characterized by sharp decrease in the rare metals contents. However, extreme greisenization (i. e. endogreisen bodies) is characterized by a considerable enrichment in Zr (av. 5464 ppm), Hf (143), Nb (2329), Ta (152), U (66) and Th (178). The Th/U ratio ranges between 1. 57 and 3. 60. In contrast to extreme greisenization, it seems that extreme albitization does not apparently change the fluid pH and therefore poor amounts of rare metals are localized in the albitites.
It is suggested that the presence of Na⁺, H⁺ and F^- in the ore fluids was essential to stablize complexes of Zr, Hf, Nb, Ta, U, Th, and HREE during extraction and transportation. In contrast, contemporaneous decrease of temperature and increasing pH due to decreasing pressure are considered the essential factors for localization of disseminated mineralization of Zr and Nb in the apical parts of the UNAP. The enhanced uranium content in the alteration facies of UNAP coupled with the absence of significant uranium mineralization may indicate the metalliferous rather than mineralized nature for the UNAP. The high uranium contents are stabilized in refractory accessory minerals. However, with repect to Zr and Nb, the UNAP especially the albitized and greisen facies, can be categorized as a mineralized productive granite.     

Hornblende gabbros of Wadi Az Zarib area,Central Eastern Desert,Egypt: opaque mineralogy,geochemistry, tectonic setting,and petrogenesis

A small intrusive fresh gabbroic mass intrudes the Neoproterozoic metasediments and Dokhan volcanics of Wadi Az Zarib area, Central Eastern Desert. It is composed of hornblende gabbros and leuco-hornblende gabbros. Their petrography, opaque mineralogy, and geochemistry are addressed to elucidate their tectonic setting and petrogenesis. They represent a subduction-related calc–alkaline magma that evolved in an island arc setting. In terms of maturity, the supposed arc represents an intermediate stage between continental arc and active continental margin. Thermobarometry and physical–chemical data of the parent magma as deduced from compositions of amphiboles, biotite, and plagioclase indicate crystallization temperatures of 931–825 °C at pressures of 6.16–4.01 kbar and H₂O_melt of 6.4–5.2 wt%. Data, as presented, argue in favor of fractional crystallization mechanism to be accounted to the present suite to interpret the observed variations. The evolution of the suite from hornblende gabbros to leuco-hornblende gabbros was accompanied by decreasing of MgO, CaO, Cr, and Ni with simultaneous increasing of Al₂O₃, TiO₂, Na₂O, K₂O, Ba, Rb, Sr, La, and Ce. Residuals calculated during mass balance fractional crystallization modeling suggest that brown and green hornblendes are the main fractionated phases which derived the melt composition towards the leuco-hornblende gabbros.     

Fluid Inclusions in the Gold—Bearing Quartz Veins at Um Rus Area,Eastern Desert,Egypt

Fluid inclusions in the gold-bearing quartz veins at the Um Rus area are of three types: H₂O, H₂O−CO₂ and CO₂ inclusions. H₂O inclusions are the most abundant, they include two phases which exhibit low and high homogenization temperatures ranging from 150 to 200°C and 175 to 250°C, respectively. The salinity of aqueous inclusions, based on ice melting, varies between 6.1 and 8 equiv. wt% NaCl. On the other hand, H₂O−CO₂ fluid inclusions include three phases. Their total homogenization temperatures range from 270 to 325°C, and their salinity, based on clathrate melting, ranges between 0.8 and 3.8 equiv. wt% NaCl. CO₂ fluid inclusions homogenize to a liquid phase and exhibit a low density range from 0.52 to 0.66 g/cm³. The partial mixing of H₂O−CO₂ and salt H₂O−NaCl fluid inclusions is the main source of fluids from which the other types of inclusions were derived. The gold-bearing quartz veins are believed to be of medium temperature hydrothermal convective origin.     

Uranium mineralized fault zone at Wadi Um Gir locality,Central Eastern Desert,Egypt

The area of Wadi Um Gir, Central Eastern Desert of Egypt, is covered by Basement rocks of Late Precambrian age namely; the postgeosynclinal (Hammamat) sediments, intruded by a bostonite dyke of the younger postorogenic volcanics. The radioactive anomaly discovered at Wadi Urn Gir is a typical vein-type hydrothermal occurrence structurally controlled by a major fault which is among the youngest faults related to the formation of the Red Sea Rift Valley during Tertiary times. The net slip of this fault is determined by the orthographic projection method to be 260 m.Hydrothermal alteration is intense along the fault zone, and is represented by successive bands mainly of hematite, kaolinitic clays, carbonates, etc.The radioactivity is normally distributed in the fresh rocks with anomalous readings connected to the altered bostonite rock in the fault zone. The abnormal high radioactivity is found to be mainly due to secondary uranium mineralization, with a uranium content of 0.065%, and in a radioactive disequilibrium with slight deficiency of daughter elements which may be due to redistribution by the effect of ground water. The uranium mineralization is usually present as fracture-fillings or forming thin fissure veinlets mostly with hematitic alteration bands along the fault zone.Genetically; repeated movement along the major fault resulted in intense fracturing of the bostonite rocks and reopening of the tectonically related fissures. The fault provided an easy channel for the passage of the contemporaneous or immediately ascending uranium-bearing solutions. Subsequently, alteration of bostonite and radioactive mineralization took place in the secondary tension fractures. The physico-chemical conditions of the altered and sheared bostonite rocks afforded the favourable conditions for the deposition of uranium minerals carried by the hydrothermal fluids along the opened fractures.

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Zusammenfassung Das Gebiet »Wadi Um Gir« in der zentralarabischen Wüste Ägyptens besteht aus Basisgesteinen von Präkambrischem Alter. Es handelt sich um die postgeosynklinale »Hammamat«-Serie, deren Sedimentabfolge von einem Bostonitgang des jüngeren postorogenen Vulkanismus durchbrochen wird.Eine Radioaktivitätsanomalie wurde in »Wadi Um Gir« festgestellt. Sie bildet ein typisch-gangartiges hydrothermales Vorkommen und ist von einem Hauptbruch der mit der Entstehung des Rotmeergrabens verbundenen jungen Brüche bestimmt. Eine Berechnung der Sprunghöhe dieser Verwerfung mit der orthographischen Projektionsmethode ergab einen Wert von 260 m.Intensive hydrothermale Umwandlung der Muttergesteine kommt entlang der Bruchzone vor. Sie besteht unter anderem aus Successiven Streifen von hämatitischem, kaolinitischem und karbonatischem Material.Die Radioaktivität, deren Verteilung in den frischen Gesteinen normal ist, zeigt Anomalien nur noch im Zusammenhang mit dem umgewandelten Bostonit der Bruchzone, wobei die abnormal hohen Radioaktivitäts-Werte mit der sekundären Uran-Mineralisation (Urangehalt 0,065%) in Einklang stehen. Es besteht jedoch durch geringe Verarmung an gewissen Tochterelementen eine Gleichgewichtsstörung. Dies könnte auf die Umverteilung durch Grundwassereinflüsse zurückgeführt werden.Genetische Überlagerungen führen zu der Annahme, daß die wiederholte Bewegung entlang der Hauptbruchzone eine intensive Fraktur der Bostonitgesteine veranlaßt hat. Dies führte zur mehrfachen Öffnung der in Zusammenhang stehenden Spalten und damit bildeten sich Bahnen für die aufsteigenden, syngenetischen, uranhaltigen Lösungen.Die Anlagerung uranhaltiger Mineralien in den sekundären Spannungsbrüchen wurde durch die physiko-chemischen Verhältnisse des umgewandelten und abgescherten Bestonits gewährleistet.

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Silver and silver-bearing minerals at the Um Samiuki volcanogenic massive sulphide deposit, Eastern Desert, Egypt

The Um Samiuki Zn–Cu–Pb–Ag mineralisation, south Eastern Desert, Egypt is hosted by felsic volcanic rocks which form part of the 712-Ma-old, east-west-trending Shadli Volcanic Belt. Two major occurrences of massive sulphides are present at the top of rhyolitic breccia in the Western and Eastern mine areas. In each occurrence, a bornite-bearing zone is overlain by a pyrite-chalcopyrite-bearing zone and underlain by a disseminated, Cu-depleted zone. In the massive sulphide ore, sphalerite, chalcopyrite, pyrite, galena, bornite and tetrahedrite–tennantite are major minerals, whereas arsenopyrite, pyrrhotite, molybdenite and magnetite are accessory phases. Covellite and digenite are common secondary minerals. Bornite, tetrahedrite–tennantite and covellite contain high amounts of silver (averages of 1.97, 1.39 and 1.82 wt% respectively). Based on mineralogical balance calculations, bornite and covellite accommodate 80% of silver in the Um Samiuki deposit. Ag was incorporated in the crystal structure of the early-crystallised copper sulphides and sulphosalts and silver minerals. The temperature, sequential precipitation of the fluids and the structure of the crystallising phases control the distribution of silver. Post-depositional deformation and metamorphic processes caused liberation, remobilisation and redeposition of silver within the massive sulphides.Editorial handling: D. Lentz     

Petrogenesis of the Wadi Dib alkaline ring complex, Eastern Desert of Egypt

Summary The Wadi Dib magmatic complex is the oldest known alkaline ring complex in the Egyptian part of the Pan-African orogenic belt. Rb-Sr isotope data for seven samples suggest a Vendian age of 578±16 Ma, and a⁸⁷Sr/⁸⁶Sr initial ratio of 0.7048±0.0010. The igneous complex has a diameter of 2 km and was emplaced within granodioritic Pan-African host rocks at the intersection of two faults. It shows distinct concentric compositional zoning with several syenitic outer ring sheets, a mainly trachytic intermediate ring sheet, and a quartz syenite inner ring sheet with a granitic core; relative ages decrease from margin to core. The mineralogical and chemical features are characteristic of within-plate (A-type) magmatic complexes. Major and trace element patterns underline the co-magmatic origin of the suite but indicate three stages of evolution with several pulses of emplacement. A common feature of element distribution patterns is the small systematic change in the early lithologies, but a distinct evolution trend in the late quartz-bearing rocks.We propose that an alkali-basaltic parent magma was emplaced within deep or middle levels of the juvenile Pan-African crust. Differentiation mainly occurred by fractional crystallization of olivine, clinopyroxene, plagioclase, and apatite. During the late stages of evolution, limited assimilation of island-arc magmatic rocks may have occurred. Emplacement took place along ring fractures at a subvolcanic level and was probably related with formation of a caldera during emplacement of the trachytic lithologies. The anorogenic character of the magmatic suite indicates consolidation of the Pan-African crust of NE Africa at the time of emplacement of the alkaline body.

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Petrogenese des alkalischen Wadi Dib ringkomplexes, Östiche Wüste Ägyptens

Zusammenfassung Der Wadi Dib-Komplex ist die älteste bekannte Ringstruktur im ägyptischen Teil des Panafrikanischen Orogengürtels. Rb-Sr Isotopendaten von sieben Proben ergeben ein vendisches Alter von 578±16 Ma and ein initiales⁸⁷Sr/⁸⁶Sr-Verhältnis von 0,7048±0,0010. Der magmatische Komplex besitzt einen Durchmesser von 2 km und hat am Schnittpunkt zweier Störungen innerhalb panafrikanischer Granodiorite Platz genommen. Er weist eine konzentrische Zonierung mit mehreren syenitischen äußeren Ringen, einem vorwiegend trachytischen mittleren Ring und einem quarzsyenitischen inneren Ring mit einem granitischen Kern auf; die relativen Alter der Gesteine nehmen vom Rand zurn Kern hin ab. Mineralogische and chemische Charakteristika sind die von Intraplatten- (A-Typ-) Komplexen. Haupt- and Spurenelementmuster weisen auf eine ko-magmatische Entstehung hin, zeigen aber eine Entwicklung in drei Stadien mit mehreren magmatischen Pulsen auf. Charakteristika der Elememverteilungen sind wenig systematische Änderung in den älteren Lithologien, aber ein gerichteter Entwicklungstrend in den späten, quarzführenden Lithologien.Wir schließen, daß ein alkali-basaltisches Magma in ein tiefes oder mittleres Niveau der jungen panafrikanischen Kruste intrudierte. Differentiation erfolgte im wesentlichen durch fraktionierte Kristallisation von Olivin, Klinopyroxen, Plagioklas und Apatit. Während später Entwicklungsstadien gab es vermutlich begrenzte Assimilation von Inselbogen-Kruste. Die Platznahme erfolgte entlang von Ringbrüchen in einem subvulkanischen Stockwerk und war vermutlich mit der Bildung einer Caldera während der Platznahme der trachytischen Lithologien verbunden. Der anorogene Charakter der magmatischen Folge zeigt an, daß die panafrikanische Kruste Nordost-Afrikas zur Zeit der Platznahme der alkalischen Intrusion bereits konsolidiert war.

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With 13 Figures     

Geochemical and geochronological characteristics of the Um Rus granite intrusion and associated gold deposit,Eastern Desert,Egypt

The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.     

3-D magnetic inversion and satellite imagery for the Um Salatit gold occurrence,Central Eastern Desert,Egypt

The Um Salatit is a gold occurrence situated in the Central Eastern Desert of Egypt. The studied area is characterized by an intensive imbrication zone of serpentinites and metavolcanic rocks. The integrated use of aeromagnetic and spectral reflectance remote sensing data has proved effective for mapping geology related to ore deposits. Spectral reflectance maps have been produced to discriminate various rocks, such as serpentinites, gabbros, and metavolcanic rocks. 3-D inversion of aeromagnetic data acquired over the Um Salatit study area produced a 3-D magnetic susceptibility model showing magnetic bodies surrounded by less magnetic host rock. The magnetic features are elongated ENE-WSW parallel to the major thrust fault and mapped the Um Salatit serpentinized rocks. Remote sensing data allow investigating surficial geological features and mapping the mineralized areas. Remote results, in conjunction with 3-D inversion of aeromagnetic data, demonstrate that gold occurrence in the study area was effectively restricted to the highly magnetic zone interpreted as host rocks.     

Geochemistry, petrogenesis and radioactivity of El Hudi I-type younger granites, South Eastern Desert, Egypt

The present study deals with geochemical characteristics and petrogenesis of three younger granite varieties (coarse-grained biotite-muscovite granites (CBG), garnetiferous muscovite granites (GMG) and Abu Aggag biotite granites (AAG)) in El-Hudi area, east of Aswan, southeastern desert of Egypt. Mineral chemistry and whole rock chemistry data revealed that all granites have high SiO₂ (70.8-74.7 wt.%), Al₂O₃ (12.8-14.3 wt.%), Na₂O and K₂O (>3.2 wt.%) contents with high Na₂O/K₂O ratios (～>1). Plagioclase feldspars range in composition from albite to oligoclase (An_9-27) in CBG, oligoclase (An_13-18) in GMG and albite (An_2-6) in AAG. Potash feldspars are mainly perthitic microcline and exhibit chemical formulae as (Or_93-96 Ab_7-4 An₀) in CBG, (Or_95-98 Ab_5-2 An₀) in GMG and (Or_82-98 Ab_18-2 An₀) in AAG. Biotites from CBG and GMG are enriched in (Mg and Ti) and depleted in (Al, Fe, Mn and K) compared with those of AAG. Biotites from CBG and GMG had been derived from calc-alkaline magma, whereas those from AAG had been derived from peraluminous magma. Chlorites from CBG and GMG are Mg-Fe bearing, while that from AAG is Fe-rich chlorite (chamosite). The CBG and GMG are Mg-rich monzogranites originated from high-K calc-alkaline magma with metaluminous to mildly peraluminous nature. The AAG are Fe-rich monzogranites to syenogranites generated from high-K calc-alkaline peraluminous magma. Both CBG and GMG are late- to post-orogenic granites, while the AAG are post-orogenic granites. All three granite varieties are considered as evolved I-type granites, formed under low to moderate water pressures (～ 0.5-7 kbars) and relatively high ranges of crystallization temperatures (～700-890°C). They were generated from partial melting of crustal materials at lower (CBG >30 km depth) and intermediate (GMG & AAG ～20-30 km depth) levels. The crystal fractionation was the predominant process during differentiation of parent magmas of these granites. Geochemical characteristics manifest that AAG represent the highly fractionated member of magma cycle differs from that produced CBG and GMG. The CBG are relatively enriched in both U and Th existing only within the accessory minerals such as zircon, sphene, and allanite.     

High and low temperature alteration of uranium and thorium minerals, Um Ara granites, south Eastern Desert, Egypt

The Um Ara area, in the south Eastern Desert of Egypt contains a number of uranium occurrences related to granitic rocks. U-rich thorite, thorite and zircon are the main primary uranium- and thorium-bearing minerals found in mineralized zones of the Um Ara alkali-feldspar granites; uranophane is the most common secondary uranium mineral. U-rich thorite contains blebs of galena, has rims of uranophane and contains inclusions of Zr-rich thorite. Electron probe microanalysis (EPMA) provides an indication of a range of solid solution between thorite and zircon, in which intermediate phases, such as Th-rich zircon and Zr-rich thorite, were formed. These phases have higher sum of all cations per formula (2.05 to 2.06 apfu, for 4 oxygen atoms) than that of ideal thorite and zircon. This is attributed to the presence of substantial amount of interstitial cations such as Ca, U and Al in these phases. Some zircon grains are stoichiometric in composition, other altered grains display lower SiO₂ and ZrO₂ contents. Enrichment of Th and U in altered zircon preferentially involves coupled substitution (Ca²⁺ + (Th,U)⁴⁺ ↔ 2Zr⁴⁺ + 2Si⁴⁺), implying that significant U and Th may enter the Zr and Si position in zircon. Negative correlation of Zr vs. Hf and Al may indicate that Hf and Al have been introduced to the zircon during later fluid alteration rather than during the primary magmatic event. A two-stage metallogenetic model is proposed for the alteration processes and origin of U- and Th-bearing minerals in the Um Ara alkali-feldspar granite: 1) the first stage was dominated by hydrothermal alteration and accompanied by albitization, k-feldspathization, desilicification, chloritization, hematitization, silicification, argillization, fluoritization and corrosion of primary U-bearing minerals. Solid-solution between thorite and zircon occurred during this stage. The second stage occurred at the near-surface profile where circulating meteoric water played an important role in mobilizing the early formed primary U-bearing minerals. Uranium was likely transported as a calcium uranyl carbonate complexes. When these complexes lost their stabilities by precipitation of calcite, they decomposed in the presence of silica to form uranophane.     

Geology and geochemistry of Tertiary basalt in south Wadi Hodein area, South Eastern Desert, Egypt

Tertiary basalt is widespread in the area south of Wadi Hodein, south Eastern Desert, Egypt. It is the youngest unit in the basement rocks of the Central Eastern Desert classification of El Shazly (Proc 22nd Intl Geol Congr, New Delhi 10:88–101, 1964) and El Ramly (Ann Geol Surv Egypt II:1–17, 1972), traversed all the previous succession of the basement rocks as well as the Nubia Sandstone of Cretaceous age, forming sheets, small hills, ridges, and dikes. This Tertiary basalt is strongly associated with the opening of the Red Sea. Geologic, petrographic, and petrochemical studies as well as microprobe and X-ray analyses were performed on samples from Wadi Hodein Tertiary basalt. Field and petrographic studies classified the Tertiary basalt in south Wadi Hodein into porphyritic olivine basalt, plagiophyric basalt, and doleritic basalt. Opaque minerals (magnetite and ilmenite) constitute 6–7.5% of this basalt. Petrochemical studies and microprobe analyses reveal that they are low-TiO₂ basalt with low uranium and thorium contents, classified as being basaltic andesite to andesite, originated from calc-alkaline magma, and developed in within-plate tectonic environment. Scanning electron microscopy shows that magnetite and ilmenite are the prevalent opaque minerals in this Tertiary basalt. Field radiometric measurements of the Tertiary basalt in south Wadi Hodein reveals low uranium and thorium contents. Uranium contents range from 0.5 to 0.9 ppm, while thorium contents range from 1.2 to 3.2 ppm. Fractional crystallization and mass balance modeling indicate that the most-silica low-TiO₂ Tertiary basalt in south Wadi Hodein can be derived from the relatively less-silica low-TiO₂ Tertiary basalt of south Quseir and Gabal Qatrani through fractional crystallization of plagioclase, olivine, augite, and titanomagnetite oxides. Tertiary basalts in south Wadi Hodein and south Quseir have nearly the same age, 25 Ma (Sherif, The Fifth International Conference on the Geology of Africa, 2007), 24 Ma (Meneisy and Abdel Aal, Ain Shams Sci Bull 25(24B): 163–176, 1984), and 27 Ma (El Shazly et al., Egypt J Geol 1975), respectively. Finally, the fractionation modeling and geochemical characteristics of these basalts suggested their origination from one basaltic magma emplaced in late Oligocene.     

Geology,geochemistry, and source characteristics of Neoproterozoic arc-related clastic metasediments,Central Eastern Desert,Egypt

The present work concerns two occurrences of Neoproterozoic volcaniclastic metasediments in the Central Eastern Desert (CED) of Egypt namely Alam occurrence and Atalla occurrence. They are mainly composed of bedded successions of feldspathic and feldspathic-lithic metagreywackes, arkosic metagreywackes, metasiltstones, and subordinate metaconglomerates. The rocks have been subjected mainly to various ductile deformational events (D₁ and D₂) due to NE–SW compression and later deformation (D₃). The D₁ deformation is synchronous with greenschist facies metamorphism (M₁). The Alam metagreywackes show oceanic arc tectonic setting. The greywackes have clasts of quartz, feldspar, and metamorphic amphibole after pyroxene and show variable abundances of Cr, Ni, and V. Their provenance components are mainly of evolved felsic and mafic (bimodal) island arcs. The rocks are suggested to be deposited in a localized “intra-arc basin.” The metagreywackes of Atalla show tectonic setting affinity similar to continental sland arc or active continental margin. Their geochemical characteristics reflect the presence of felsic rocks as the main sources, together with minor inputs of intermediate rocks and reworked mineral grains of quartz and feldspar. They are deposited in a localized “retro-arc basins” of an active continental margin. The whole sequences of both Atalla and Alam sediments have been subjected to deformation and contemporaneous regional metamorphism during arc-arc or arc-continent collision. Newproterozoic clastic metasedimentary rocks in the CED appear to have been deposited in arc-related basins, including interarc or back-arc basins, intra-arc basins, and retro-arc basin of active continental margin.     

Late Cryogenian arc-related volcaniclastic metasediment successions at Wadi Hammuda,Central Eastern Desert,Egypt: geology and geochemistry

Wadi Hammuda is dominated by a variety of low grade regionally metamorphosed volcaniclastic metasediments pertaining to two different geotectonic settings and intruded by arc and late collision granitic rocks. Thus, the volcaniclastic metasediments which form extensive outcrops are considered as a member of island arc assemblages. This paper deals with the petrography, geochemistry, and tectonic setting of the island arc volcaniclastic metasediment rock units. The volcaniclastic metasediments consist of interbedded metagreywackes, metasiltstones, metamudstones, and schists as well as metapyroclastics. They are well foliated, crenulated and tightly folded, metamorphosed, and intruded by granitic rocks. Geochemical data support the petrographic classification and reveal that these volcaniclastic metasediments are generally low-K, essentially tholeiitic in character, with the exception of some metasediments and metapyroclastics which exhibits calc-alkaline and tholeiitic affinities and represent the first stage of island arc volcanism. The overthrusted oceanic lithosphere blocks with fragments of the fore arc and/or back-arc marginal basins volcaniclastic metasediments were incorporated among the island arc volcanics which supported by tectonically relationship between the different rock units in the study area. Contemporaneous with this deformation event, Wadi Hammuda was subjected to low grade regional metamorphism and the rocks document an early phase of shearing and/or foliation. Occasionally minor folds were developed particularly in the metasediments and schists. The subsequent emplacement of the syn-tectonic granites (tonalites and granodiorites) resulted in minor local thrusts. During the regional thrusting event which preceded the emplacement of the late-tectonic granites (alkali feldspar granites) and affected the whole region, low grade successions cover the study area similar to the Meatiq volcaniclastic metasediments.     

Paleozoic glaciation in NE Africa: field and remote sensing-based evidence from the South Eastern Desert of Egypt

ABSTRACT

Exhumed Paleozoic glacial deposits and landforms of the North Gondwana are reported here for the first time from the South Eastern Desert (SED) of Egypt. Using field observations and remote sensing datasets (Advanced Land Observing Satellite [ALOS], Phased Array L-band Synthetic Aperture Radar [PALSAR] radar, multispectral Landsat TM datasets, and digital elevation models [DEMs]), we mapped the distribution of Paleozoic glacial features (i.e. deposits and landforms) in the SED. Two main glaciogenic facies were identified in three locations in the SED: (1) massive, poorly sorted, matrix supported, boulder-rich diamictites in Wadi El-Naam and Korbiai, and (2) moderately-sorted, occasionally bedded outwash deposits in Betan area. Inspection of radar, DEMs, and Landsat Operational Land Imager (OLI) images revealed previously unrecognized ENE-WSW trending glacial megalineations (MLs) over the peneplained Neoproterozoic basement rocks in the central sections of the SED, whose trends align along their projected extension with those of glacial features (tunnel valleys and striation trends) reported from Saudi Arabia. The glaciogenic features in the SED are believed to be largely eroded during the uplift associated with the Red Sea opening, except for those preserved as basal units beneath the Nubia Sandstone Formation or as remnant isolated deposits within paleo-depressions within the basement complex. The apparent spatial correlation of the SED glacial features with well-defined Late Ordovician deposits in North Africa and in Saudi Arabia, and the reported thermochronometric analyses and fossil records are consistent with a Late Ordovician age for the SED glaciogenic features and support models that call on the continuation of the Late Ordovician (Hirnantian) ice sheet from the Sahara into Arabia through the SED of Egypt.     

Mineral Chemistry of Albite-Enriched Granitoids at Um Ara,Southeastern Desert,Egypt

Mineral chemistry and typomorphic characteristics are used to monitor the physicochemical evolution of late-magmatic to postmagmatic alteration processes that resulted in the development of a radioactive and albite-enriched microgranite stock. The mineral paragenesis indicates that postmagmatic fluids were enriched in Nb, Zn, Mn, U., Th, Zr, and Y, in addition to Rb, Li, and F Manganocolumbite with extremely high Nb/(Nb+Ta) (0.99), Mn/(Mn+Fe) (0.82), and zircon with high Zr/(Zr+Hf) (0.97) indicate crystallization under alkaline, relatively high-temperature conditions (>425° C). The close association of manganocolumbite, Nb-Mn-Zn- rich ilmenite (with 1.2 to 14.5 wt% ZnO), spessartine garnet (with 68.2-89.4 mol% spessartine), zircon, xenotime, zinnwaldite mica (up to 5.98 wt% F), and fluorite indicates the strong affinity of the elements of Nb, Y., Zr, Mn, and Zn for stable complexing by K⁺, Na⁺, Li⁺, and F^? rich supercritical fluids during the course of extraction and transportation.

The enrichment of the interacting fluid in U and Th is depicted by the presence of up to 1.6% UO₂ in manganocolumbite and Hf-bearing zircon, and up to 10.5% ThO₂ in monazite, in addition to locally abundant thorite and uranophane. It is suggested that the uranium mineralization, mainly as fracture fillings, formed during the waning stage of hydrothermal activity.     

Geology and geochemistry of the granitic rocks and associated dykes, East Gabal Nuqra, South Eastern Desert, Egypt

A crescent-shape granitic stock and associated dykes is located to the East Gabal Nuqra at the extreme western part of Wadi Natash,South Eastern Desert,Egypt.The examined granites are classified as alkali-feldspar granites and mainly consist of quartz,potash feldspars,plagioclases,and aegirine-augite.Xenotime,zircon,apatite and allanite are accessories representing the source of Y,U,Th and REEs in these rocks.These granites are characterized by high K2O,Na2O and Zn contents and Rb/Sr ratio.Also,they are highly enriched in high field strength elements(HFSE),especially Zr(1529×10-6),Nb(100×10-6),Hf(91×10-6) and Y(624×10-6) and light rare-earth elements(LREE,141×10-6) concentrations and strongly depleted in Ca,Mg,Sr and Eu contents.These features suggest that they are similar to A-type granites(type-2).The rhyolite dykes and granites have similar geochemical characteristics whereas the chondrite-normalized REE patterns show a LREE enriched feature with strong negative Eu-anomaly,whereas the REE pattern of trachydacites show slightly fractionated pattern with no Eu-anomaly.It is suggested that the trachydacites were generated by small degree of partial-melting deep-seated basic source.Such liquid,when subjected to fractional crystallization involving separation of plagioclases as residue,generated the alkali-feldspar granites.And further fractional crystallization gave rise to the alkali rhyolites.The igneous rock suite originated from metaluminous to alkaline trachytic magma,and was developed in a within-plate tectonic environment.The extension caused by NW-SE right-lateral shear in area led to the emplacement of the alkali-feldspar granites.The later extrusion of the alkali rhyolite and trachydacite dykes was due to cauldron subsidence.