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1.
根据赣南会昌地区中基性火山岩高碱、富钾、低钛、贫铁,岩石中斜长石斑晶具钾长石环边,基质中存在大量钾长石微晶,以及富集轻稀土元素和大离子亲石元素等矿物岩石地球化学特征,确切厘定会昌地区的中基性火山岩为橄榄玄粗岩安粗岩组合,属典型的大陆板内橄榄玄粗岩系列火山岩。对会昌橄榄玄粗岩进行了RbSr同位素定年研究,确定其全岩RbSr等时线年龄为107.3±2.3Ma。 会昌橄榄玄粗岩系火山岩SrONdPb 同位素组成的特征为: 偏高的 ISr(0.7098~0.7115); 较低的δ18O值(5.3‰~7.0‰);中等的εNd(t)(-0.61~-3.60); 富放射性成因铅((206Pb/204Pb)i=17.32~18.29, (207Pb/204Pb)i=15.34~15.65, (208Pb/204Pb)i =37.51~38.60)。会昌橄榄玄粗岩的Δ7/4Pb值为-7.8~+16.8(平均值为+5.42), Δ8/4Pb值为27.3~97.3 (平均值为68.04), ΔSr值为96.2~114.1 (平均值为104.3),这表明存在典型的Dupal 同位素异常。根据SrO, SrNd, SrPb, NdPb, PbPb同位素相关特征, 判明会昌橄榄玄粗岩是由亏损地幔端元(DM)和岩石圈富集地幔端元(EM)在源区混合形成的。按SrNd双变量二元混合模型计算得出源区物质中亏损地幔端元和富集地幔端元所占份额各占50%左右。会昌早白垩世橄榄玄粗岩系火山岩带的形成反映了华南板块内部在燕山晚期发生的一起重要的伸展构造事件  相似文献   

2.
五大连池火山岩是我国东部新生代最典型的钾质玄武岩。以富Ti、Na、K为特点,结晶分异使岩浆向富Si、富碱方向演化。岩石中Rb、Sr、Sin、Nd丰度与熔岩的碱质同步增长。Pb、Sr、Nd同位素组成很特殊,富放射成因Sr和Nd,但贫放射成因Pb,^37Sr/^34Sr,高于全球未分异现代值,^143Nd/^144Nd为0.512381-0.512433,低于全球未分异现代值;^206Pb/^204Pb,^207Pb/^204Pb,^208Pb/^204Pb分别对16.712-16.992,115,371-15.407,36.315-36.948,比许多大洋玄武岩和大陆玄武岩偏低。上述数据表明,其源区为无明显地壳物质混染的,未遭改造的原始富集地幔,同大洋玄武岩明显不同,暗示地幔的物质组成有区域性和不均匀性。  相似文献   

3.
通过对比研究新生代玄武岩Pb,Sr,Nd同位素组成及前寒武纪基底Nd同位素组成,本文将扬子板块东段划归为四个构造-岩石-同位素地球化学省,即苏沪省、嘉山省,北扬子省和南扬子省。其中,喜山省位于庐江-灌云断裂和庐断裂之间,以高^87Sr/^86Sr比(0.70435-0.70490),低^143Ndxx (0.512395-0.512615)和低放射成因铅(^206Pb/^204Pb,^207Pb/^204Pb和^208Pb/^204Pb分别为16.594-17.266,15.317-15.437和37.352-37.782)为特点;苏沪省们于苏皖边界以东,以低^87Sr/^86Sr比(0.70341-0.70392),高^143Nd/^144Nd比(0.512838-0.513002)和较高放射成因铅(^206Pb/^204Pb,^207Pb/^204Pb^和208Pb/^204Pb分别为17.789-18.275,15.489-15.552和37.831-38.369)为特点;北扬子省位于庐江-灌云断裂以南,富含放射成因铅(^206Pb/^204Pb为18.021-18.150,^207Pb/^204Pb为15.546-15.574,^208Pb/^204Pb为38.154-38.469),而^87Sr/^86Sr比和^143Nd/^144Nd比(分别为0.70464-0.70468和0.512748-0.512774)介于嘉山省和苏沪省之间。  相似文献   

4.
岩石学、地球化学和Nd、Sr、Pb同位素研究表明,西藏冈底斯铜矿带雄村特大型铜金矿床的容矿火山岩为一套具超浅成侵入特点的英安斑岩,SiO2含量集中在61.97%~64.31%之间,富Na2O、低K2O,Na2O/K2O比值平均为5.25。地球化学上明显富集大离子不相容元素Rb、Ba、K、Sr、Pb,同时高场强元素Nb、Ta、Ti处于亏损状态。Sr、Nd同位素组成变化范围小(87Sr/86Sr=0.705154~0.708267,ISr=0.704299~0.705357;143Nd/144Nd=0.512730~0.512931),具有富集地幔特征;Pb同位素组成显示出地幔铅与造山带铅的双重特性(206Pb/204Pb=18.170~18.432,207Pb/204Pb=15.485~15.546,208Pb/207Pb=37.993~38.392)。研究指出它们是早侏罗世(195Ma)由雅鲁藏布江洋壳向欧亚大陆之下俯冲形成的岛弧火山岩,岩浆源区具有EM1型原始地幔富集特征,同时有一定数量的俯冲沉积物加入了地幔源区的部分熔融。根据雄村矿床的成矿时代和矿化特征,笔者认为该矿床的成因类型与胶东焦家式金矿一致,为破碎带蚀变岩型。旦狮庭组容矿火山岩对成矿的贡献在于作为矿源层为矿床提供了成矿金属元素。  相似文献   

5.
相山火山—侵入杂岩Nd—Sr—Pb同位素地球化学特征   总被引:8,自引:6,他引:8  
对相山火山-侵入杂岩Nd,Sr,Pb同位素组成及其底变质岩Pb同位素组成的研究表明,相山两旋回火山岩及火山期后的次火山岩具有较低的εNd(t)值(-7.46-9.40),较高的Isr值(0.70801-0.71201)和较古老的Nd模式年龄(1.54-1.70Ga),且相对富集放射成因铅(^206Pb/^204Pb,^207Pb/^204Pb,^208Pb/^204Pb分别为17.686-18.323,15.523-15.730,38.143-38.936)。相山火山-侵入杂岩与该区出露的基底变质沉积岩在Nd,Pb同位素组成上既有明显的相似性,又有一定差别,因此,相山火山-侵入杂岩的源区主要为地壳岩石,但并不排除有部分幔源组分介入。ε  相似文献   

6.
华夏古板块与扬子古板块结合带内的广丰、玉山红色碎屑沉积盆地均有橄榄玄粗岩产出,SHRIMP锆石UPb年代学研究表明,橄榄玄粗岩锆石U-Pb年龄为93±1 Ma,属晚白垩世早期的产物。广丰盆地橄榄玄粗岩(~(87)Sr/~(86)Sr)_i值为0.706 191~0.706 352,εNd(t)值为0.27~0.55,(~(206)Pb/~(204)Pb)_i值为18.045~18.080,(~(207)Pb/~(204)Pb)_i值为15.503~15.543,(~(208)Pb/~(204)Pb)_i值为38.240~38.256;玉山盆地橄榄玄粗岩(~(87)Sr/~(86)Sr)_i值为0.705 856~0.706 024,εNd(t)值为1.74~1.93,(~(206)Pb/~(204)Pb)_i值为17.956~18.063,(~(207)Pb/~(204)Pb)_i值为15.456~15.498,(~(208)Pb/~(204)Pb)_i值为38.195~38.232。在(~(87)Sr/~(86)Sr)_i-(~(206)Pb/~(204)Pb)_i、(~(143)Nd/~(144)Nd)_i-(~(206)Pb/~(204)Pb)_i和(~(143)Nd/~(144)Nd)_i-(~(87)Sr/~(86)Sr)i图解中,广丰、玉山盆地橄榄玄粗岩均位于亏损地幔(DMM)和EMⅡ型富集地幔之间,而且(~(87)Sr/~(86)Sr)_i和(~(206)Pb/~(204)Pb)_i呈正相关,(~(143)Nd/~(144)Nd)_i和(~(206)Pb/~(204)Pb)_i呈负相关,指示其源区中可能均有DMM和EMⅡ型地幔的贡献;玉山盆地橄榄玄粗岩更偏向DMM端员,指示其DMM端员所占的比例更高。广丰、玉山盆地橄榄玄粗岩具有EMⅡ型地幔的贡献,说明华夏古板块与扬子古板块结合带的岩石圈地幔与华夏古板块的岩石圈地幔属相同类型,为华夏古板块俯冲于扬子古板块之下提供了新的证据。  相似文献   

7.
牙克石地区出露一套早白垩世玄武质火山岩,其SiO2含量为52.81%-53.39%,K2O含量为1.86%-2.87%,岩性为玄武质粗面安山岩。富集大离子亲石元素Rb和Ba,高场强元素Nb和Ta亏损明显,Zr和H阮明显异常,8Eu为0.77-0.82。从同住素的特点看,(^87Sr/^86Sr),变化于0.704762-0.704941之间,εNd(t)为2.00~2.54;在εNd(t)-(^87Sr/^86Sr)闺解上,样品投影点落入洋岛玄武岩(OIB)和美国盆岭省范围内。^206Pb/^204pb为18.3288-18.4225,^207b/^204Pb为15、4566-15.4893,^208Pb/^204Pb为37.9401-38.0523:在。^207Pb/^24Pb-^206Pb.^204pb和,^208b/^304pb-^306Pb/^204pb图解上.样品投影点都落在亏损洋中脊玄武岩地幔附近。综合考虑本区火山岩的地质、地球化学特点,认为其来源于被俯冲洋壳交代的岩石圈地幔。  相似文献   

8.
牙克石地区出露一套早白垩世玄武质火山岩,其SiO2含量为52.81%-53.39%,K2O含量为1.86%-2.87%,岩性为玄武质粗面安山岩。富集大离子亲石元素Rb和Ba,高场强元素Nb和Ta亏损明显,Zr和H阮明显异常,8Eu为0.77-0.82。从同住素的特点看,(^87Sr/^86Sr),变化于0.704762-0.704941之间,εNd(t)为2.00~2.54;在εNd(t)-(^87Sr/^86Sr)闺解上,样品投影点落入洋岛玄武岩(OIB)和美国盆岭省范围内。^206Pb/^204pb为18.3288-18.4225,^207b/^204Pb为15、4566-15.4893,^208Pb/^204Pb为37.9401-38.0523:在。^207Pb/^24Pb-^206Pb.^204pb和,^208b/^304pb-^306Pb/^204pb图解上.样品投影点都落在亏损洋中脊玄武岩地幔附近。综合考虑本区火山岩的地质、地球化学特点,认为其来源于被俯冲洋壳交代的岩石圈地幔。  相似文献   

9.
对赣中地区打鼓顶组第四岩性段中基性火山岩的岩石-地球化学特征系统研究表明,这一岩性段的火山岩具有高碱、 富钾、低钛、贫铁以及富集轻稀土和大离子亲石元素等特征,据此厘定其为橄榄玄粗岩-安粗岩组合,属典型的大陆板内橄 榄玄粗岩系列火山岩。这套火山岩的全岩Rb-Sr等时年龄为(138±8.8) Ma, I Sr偏高,中等的εN(d t),富放射性成因铅。盛 源盆地及邻区橄榄玄粗岩系列火山岩的△7/4Pb值为14~19.6( 平均值为16),△8/4Pb值为70.5~97( 平均值为89.2),△Sr值为 121.5~161.8( 平均值为136.3),显示存在典型的Dupal同位素异常。根据Sr-Nd,Sr-Pb,Nd-Pb,Pb-Pb同位素相关性分析,判 明赣中地区橄榄玄粗岩是由亏损地幔端元(DM)和岩石圈富集地幔端元(LEM)在源区混合形成的。按Nd,Sr双变量二元 混合方程式计算,得出源区物质中亏损地幔端元(DM)和岩石圈富集地幔端元(LEM)所占份额分别为37%(平均值)和 63%( 平均值)。赣中地区早白垩世橄榄玄粗岩系火山岩的形成反映了华南板块内部在燕山晚期发生的一起重要的伸展构造 事件。  相似文献   

10.
赵磊  吴泰然  罗红玲 《岩石学报》2011,27(10):3071-3082
内蒙古乌拉特中旗温更地区北七哥陶辉长岩岩体由橄榄辉长岩和角闪辉长岩组成,主要造岩矿物为橄榄石、辉石、斜长石及角闪石等.锆石SHRIMP U-Pb同位素定年结果表明,橄榄辉长岩形成于269±8Ma,为晚古生代华北板块北缘岩浆活动的产物.橄榄辉长岩和角闪辉长岩具有相似的稀土元素、微量元素以及同位素特征,即:轻稀土元素( LREE)富集的右倾平滑配分模式;大离子亲石元素(LILE)K、Sr、Ba明显富集,高场强元素(HFSE) Nb、Ta、U、Th相对亏损,但Zr-Hf不亏损;87Sr/86Sr(t)平均值分别为0.706776和0.706960,εNd(t)平均值分别为-8.8和-8.9,206pb/204Pb、207pb/204Pb、208Pb/204Pb比值的平均值分别为17.2019和17.2277、15.4252和15.4524、37.3082和37.4724,在s7 Sr/86Sr(t)-143Nd/144 Nd (t)图解上,北七哥陶辉长岩都落在了EMI型富集地幔附近.根据以上事实,结合区域资料表明,橄榄辉长岩和角闪辉长岩产于后碰撞的构造环境,并且来自相同的岩浆源区,主要继承了华北陆块内部EMI型富集地幔,可能受到了古亚洲洋俯冲消减过程中再循环下地壳组分对岩石圈地幔的改造.  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

20.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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