Fallout radionuclide tracers identify a switch in sediment sources and transport-limited sediment yield following wildfire in a eucalypt forest

Fire can alter sediment sources and transport rates in river basins, changing landforms and aquatic habitats and degrading downstream water quality. Variability in the response between environments, between fires, and with time since fire makes predicting the catchment-scale effect of individual fires difficult. This study applies the fallout radionuclides ¹³⁷Cs and ²¹⁰Pb_xs to trace the sources and transport of fine sediment through a river network following a wildfire of moderate to extreme severity in the 629-km² eucalypt-forested Nattai River water-supply catchment near Sydney, Australia. The tracer analysis showed that post-fire erosion caused a switch in fine (< 10 µm) sediment sources from 80% subsoil derived from gully and river bank erosion to 86% topsoil derived from hillslope surface erosion. The fine sediment phosphorus content increased 4–10 fold over pre-fire levels. Annual post-fire sediment yields estimated from suspended solids rating curves were 109–250 times higher than they would have been without fire. A large additional amount of sediment remained stored within the river network for at least four years, particularly in lower-gradient reaches. Analysis of a sediment core showed that surface erosion following a previous fire had supplied at least 29% of total catchment sediment yield over the past 36 years. It is concluded that wildfire can alter catchment sediment budgets in two ways. Firstly, a spatially-diffuse pulse of elevated erosion is associated with moderate or intense rainfall events in post-fire years. Secondly, pulses of elevated catchment sediment yield are driven by the timing and river sediment transport capacity of runoff events. Severe post-fire erosion and high interannual hydrologic variability can result in large sediment stores persisting within the river network for many years. Fallout radionuclide tracers are shown to be useful in quantifying fine sediment sources and transport dynamics following wildfire, and the contribution of wildfire to catchment sediment yield.     

Historical change in lake sedimentation in Lake Takkobu, Kushiro Mire, northern Japan over the last 300 years

Environmental degradation, including shallowing, deterioration of aquatic habitat and water pollution, has arisen from the inflow of fine sediment to Lake Takkobu in northern Japan. The lake has experienced gradual environmental degradation due to agricultural development, which has introduced both fine sediment and sediment-associated nutrients into the lake. We have reconstructed the history of sediment yield to Lake Takkobu in Kushiro Mire over the last 300 years and have examined trends with reference to land-use development. Fifteen lake sediment core samples were obtained, and various physical variables of lake sediments were analyzed and dated using ¹³⁷Cs and tephrochronology. The physical variables showed that all points contained mainly silt, except for two points close to the river mouths, where the mean diameter was < 35 μm. The peaks were defined as a “signal” when the physical variables were synchronous in a profile. These were created by floods and engineering works constructing drainage systems. The signal of canal construction in 1898 was detected in all core points. Lake Takkobu core samples contained two tephra layers. From the refractive indices of dehydrated glasses, the lower tephra layer was identified as Ko-c2 (1694) and the upper tephra layer as Ta-a (1739). A clear peak in the ¹³⁷Cs concentration was detected at all the sampling points, except for the site close to the Takkobu River. This site showed two peaks in the ¹³⁷Cs concentration, which was attributed to perturbation from flood events and a drainage project. The maximum ¹³⁷Cs concentration was identified as the sediment surface from 1963, enveloped by the 1962 and 1964 signals. The sediment yield averaged over the last 300 years for Lake Takkobu was reconstructed for four periods using the signal, tephra and ¹³⁷Cs as marker layers. The sediment yield under the natural erosion condition for the first two periods was 226 tons/year from 1694 to 1739 and 196 tons/year from 1739 to 1898. The development of the Takkobu watershed started in 1880s with partial deforestation and channelization in 1898, 1959, and 1962 leading to an increased sedimentation yield of 1016 tons/year from 1898 to 1963. Continued deforestation, channelization works in 1964, road construction in 1980–1990s, as well as agriculture development caused a further increase to 1354 tons/year from 1963 to 2004. Compared to the averaged natural sedimentation yield of 206 tons/year until 1898, initial land-use development in a catchment accelerated lake sedimentation, indicated by the 5-fold sediment yield. With increasing agricultural development since 1960s, sedimentation yields were highest for 1963–2004; a 7-fold increase compared with pre-impact conditions. To reduce sediment yield, riparian buffers along the rivers should be preserved or rebuilt, and sluices may function effectively during short-term periods of flooding. Environmental management policy and laws restricting uncontrolled and inappropriate land-use might help in addition to ensure longer-term environmental health by reducing the sedimentation rate.     

Biological and Geochemical Record of Anthropogenic Impacts in Recent Sediments from Lake Pupuke, Auckland City, New Zealand

Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS ¹⁴C and ²¹⁰Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO₄ addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the ²¹⁰Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.     

Carbon and nitrogen stable isotope ratios in surface sediments from lakes of western Ireland: implications for inferring past lake productivity and nitrogen loading

We used statistical analyses to determine which subset of 36 environmental variables best explained variations in surface sediment δ¹³C and δ¹⁵N from 50 lakes in western Ireland that span a human-impact gradient. The factors controlling lake sediment δ¹³C and δ¹⁵N depended on whether organics in the lake sediment were mostly derived from the lake catchment (allochthonous) or from productivity within the lake (autochthonous). Lake sediments with a dominantly allochthonous organic source (high C:N ratio sediments) produced δ¹³C and δ¹⁵N measurements similar to values from catchment vegetation. δ¹³C and δ¹⁵N measurements from lake sediments with a dominantly autochthonous organic source (low C:N ratio sediments) were influenced by fractionation in the lake and catchment leading up to assimilation of carbon and nitrogen by lacustrine biota. δ¹³C values from lake sediment samples in agricultural catchments were more negative than δ¹³C values from lake sediment samples in non-impacted, bogland catchments. Hypolimnetic oxygen concentrations and methane production had a greater influence on δ¹³C values than fractionation due to algal productivity. δ¹⁵N from lake sediment samples in agricultural catchments were more positive than δ¹⁵N in non-impacted bogland catchments. Lower δ¹⁵N values from non-impacted lake catchments reflected δ¹⁵N values of catchment vegetation, while higher δ¹⁵N values in agricultural catchments reflected the high δ¹⁵N values of cattle manure and inorganic fertilisers. The influence of changing nitrogen sources and lake/catchment fractionation processes were more important than early diagenesis for lake sediment δ¹⁵N values in this dataset. The results from this study suggest a possible influence of bound inorganic nitrogen on the bulk sediment δ¹⁵N values. We recommend using a suitable method to control for bound inorganic nitrogen in lake sediments, especially when working with clay-rich sediments. This study confirms the usefulness of δ¹³C and δ¹⁵N from bulk lake sediments, as long as we are mindful of the multiple factors that can influence these values. This study also highlights how stable isotope datasets from lake surface sediments can complement site-specific isotope source/process studies and help identify key processes controlling lake sediment δ¹³C and δ¹⁵N in a study area.     

The transport and mass balance of fallout radionuclides in Blelham Tarn, Cumbria (UK)

Although lake sediment archives are widely used for reconstructing historical records of atmospherically delivered pollutants, the quantitative relationship between fallout levels and their record in the sediments is complex and not well known. The original input signal from the atmosphere can be significantly distorted by mediating transport processes in the catchment, through the water column and within the sediments themselves. Since these processes also affect the fallout radionuclide ²¹⁰Pb commonly used to date sediments, a better understanding of their impact is also important to improving the accuracy and reliability of sediment dating. Blelham Tarn has been the subject of a number of palaeolimnological investigations using radiometric dating techniques since the early 1970s. More recently it was the site of a major study carried out within the EU Transuranics project concerning the long-term fate of fallout radionuclides in catchment/lake systems. This paper reviews the radiometric data from this study and uses the results to determine mass balances for fallout ²¹⁰Pb, ¹³⁷Cs and ^239+240Pu in Blelham Tarn, and their spatial distribution over the bed of the lake. Atmospheric fluxes were determined by measuring concentrations in rainwater and cumulative inventories in soil cores from non-eroding sites. Sediment records in a grid of 16 cores were used to determine the spatial distribution over the bed of the lake, and net inputs from the catchment. Mass balance calculations indicate that c. 47% of ²¹⁰Pb in the sediments derives from erosive inputs from the catchment. For ^239+240Pu the figure rises to 61%. Reduced amounts of ¹³⁷Cs in the sediments are attributed to greater losses of this radionuclide from the water column via the outflow due to its greater solubility. Inputs of radionuclides from the catchment are concentrated near one of the major input streams. Away from this part of the lake the sediment record is dominated by direct atmospheric fallout, though the detailed pattern is influenced by sediment focussing. A one parameter catchment/lake transport model is developed that incorporates the assumption that transport rates will decline with time as fallout on the catchment diffuses into the soil and becomes less available for removal. Values of the transport parameter were calculated for ²¹⁰Pb and ^239+240Pu and found to be comparable. The results suggest that it will take c. 11000 years to remove 50% of ^239+240Pu from the catchment to the lake.     

A model for inferring dissolved organic carbon (DOC) in lakewater from visible-near-infrared spectroscopy (VNIRS) measures in lake sediment

We developed an inference model to infer dissolved organic carbon (DOC) in lakewater from lake sediments using visible-near-infrared spectroscopy (VNIRS). The inference model used surface sediment samples collected from 160 Arctic Canada lakes, covering broad latitudinal (60–83°N), longitudinal (71–138°W) and environmental gradients, with a DOC range of 0.6–39.6 mg L⁻¹. The model was applied to Holocene lake sediment cores from Sweden and Canada and our inferences are compared to results from previous multiproxy paleolimnological investigations at these two sites. The inferred Swedish and Canadian DOC profiles are compared, respectively, to inferences from a Swedish-based VNIRS-total organic carbon (TOC) model and a Canadian-based diatom-inferred (Di-DOC) model from the same sediment records. The 5-component Partial Least Squares (PLS) model yields a cross-validated (CV) R_CV² R_{CV}^{2}  = 0.61 and a root mean squared error of prediction (RMSEP _CV ) = 4.4 mg L⁻¹ (11% of DOC gradient). The trends inferred for the two lakes were remarkably similar to the VNIRS-TOC and the Di-DOC inferred profiles and consistent with the other paleolimnological proxies, although absolute values differed. Differences in the calibration set gradients and lack of analogous VNIRS signatures in the modern datasets may explain this discrepancy. Our results corroborate previous geographically independent studies on the potential of using VNIRS to reconstruct past trends in lakewater DOC concentrations rapidly.     

Holocene environmental dynamics of south-eastern Brazil recorded in laminated sediments of Lago Aleixo

Environmental changes of the last 9,300 years were reconstructed by geochemical and pollen analyses of a 14-m-long, laminated sediment core from Lago Aleixo, south-eastern Brazil. Fossil pollen assemblages indicate open savannah vegetation (campo cerrado) and gallery forests until approximately 6,900 cal. BP. During that time, siderite laminae were deposited under anoxic conditions at the lake bottom. Then, increased rainfall and a shorter annual dry period allowed gallery forests and semi-deciduous forests to expand, leading to more closed cerrado vegetation. High-intensity rainfall events during this period are recorded as peaks in K and Ti concentrations. The sediment facies during this period consists of alternating layers of diatoms and minerogenic matter. C/N ratios imply that algae and perhaps soils, too, were the main contributors to sediment organic matter. Biogenic silica and δ¹³C_org variations indicate increasing primary productivity, which was related to higher nutrient flux from intensified leaching of soils, as shown by rising K/Al ratios. Around 800 cal. BP, a closed, semi-deciduous forest developed under present-day climate conditions. Slope stabilization diminished erosion processes in the catchment and caused reduced input of minerogenic matter into the basin. Human impact is evident in the topmost homogeneous sediments, as removal of the stabilizing forest cover amplified soil erosion. The continuous trend to more humid conditions during the Holocene probably reflects increased influence of the Amazon Basin as a moisture source. We conclude that the Lago Aleixo sediment archive was a sensitive recorder of environmental dynamics in tropical South America, which were mainly controlled by changes in precipitation patterns.     

Scanning reflectance spectroscopy (380–730 nm): a novel method for quantitative high-resolution climate reconstructions from minerogenic lake sediments

High-resolution (annual to sub-decadal) quantitative reconstructions of climate variables are needed from a variety of paleoclimate archives across the world to place current climate change in the context of long-term natural climate variability. Rapid, high-resolution, non-destructive scanning techniques are required to produce such high-resolution records from lake sediments. In this study we explored the potential of scanning reflectance spectroscopy (VIS-RS; 380–730 nm) to produce quantitative summer temperature reconstructions from minerogenic sediments of proglacial, annually laminated Lake Silvaplana, in the eastern Swiss Alps. The scanning resolution was 2 mm, which corresponded to sediment deposition over 1–2 years. We found correlations up to r = 0.84 (p < 0.05) for the calibration period 1864–1950, between six reflectance-dependent variables and summer (JJAS) temperature. These reflectance-dependent variables (e.g. slope of the reflectance 570/630 nm, indicative of illite, biotite and chlorite; minimum reflectance at 690 nm indicative of chlorite) indicate the mineralogical composition of the clastic sediments, which is, in turn, related to climate in the catchment of this particular proglacial lake. We used multiple linear regression (MLR) to establish a calibration model that explains 84% of the variance of summer (JJAS) temperature during the calibration period 1864–1950. We then applied the calibration model downcore to develop a quantitative summer temperature reconstruction extending back to AD 1177. This temperature reconstruction is in good agreement with two independent temperature reconstructions based on documentary data that extend back to AD 1500 and tree ring data that extend back to AD 1177. This study confirms the great potential of in situ scanning reflectance spectroscopy as a novel non-destructive technique to rapidly acquire high-resolution quantitative paleoclimate information from minerogenic lake sediments.     

Sediment geochemical records of environmental change in Lake Wuliangsu, Yellow River Basin, north China

We present a paleolimnological record from shallow Lake Wuliangsu in the Yellow River Basin, north China, using a short (56 cm) sediment core. Our objective was to investigate environmental changes in this semi-arid region over the past ~150 years. The sediment core was dated using ¹³⁷Cs and ²¹⁰Pb. We examined stratigraphic trends in core lithology, nutrients, stable isotopes (δ¹³C and δ¹⁵N) and trace element concentrations in the Lake Wuliangsu core to discern between natural sediments and those affected by human agency. A lithologic transition from yellow, coarse-grained sediment to grey, fined-grained sediment marked the lake’s formation about 1860. Until ~1950, sediments displayed relatively low and constant heavy metal concentrations, indicating little human influence. In the 1950s, enrichment factors (EFs) increased, reflecting greater impact of human activities. Carbon and nitrogen stable isotopes in organic matter (OM), along with heavy metal concentrations, were used to infer past shifts in trophic state and identify pollutants that came from agriculture, industry and urbanization. In the late 1950s, the first evidence for environmental change is recorded by increases in total organic carbon (TOC), total organic nitrogen (TN), TOC/TN, EFs, δ¹³C and a decrease in δ¹⁵N. After about year 2000, a more rapid increase in trophic status occurred, as indicated by greater total phosphorus (TP), EFs, δ¹⁵N and lower δ¹³C values. Changes in isotope and TOC/TN values in the lake sediments may reflect a shift in lake ecology during this period. The first increase in trophic status during the late 1950s was mainly a result of agricultural development in the catchment. In contrast, the change after ca. AD 2000 was driven largely by urban and industrial development. Agreement between paleolimnologic data from Lake Wuliangsu, and both instrumental and written records, indicates that the lake sediments provide a reliable archive for investigating the formation and environmental history of the lake.     

A 42-yr soil erosion record inferred from mineral magnetism of reservoir sediments in a small carbonate-rock catchment,Guizhou Plateau,southwest China

Shibanqiao Reservoir (25°56′56.5′′ N, 105°26′44.5′′ E and ∼1400 m a.s.l.), southwest Guizhou Plateau, SW China, was built in 1958. It lies in an area of sub-tropical monsoon humid climate in a carbonate-rock-dominated catchment of 6 km². Two sediment cores (24 and 23 cm long) were retrieved from the reservoir, and four soil profiles were sampled in the catchment. Mineral magnetism was measured on all sediment and soil samples. Soil and sediment magnetic measurements together with analyses of sediment ¹³⁷Cs activity, particle-size, TOC, and C/N revealed changes in soil erosion between 1960 and 2002. During some phases, erosion (probably as splashing and/or sheeting) was relatively low and tended to take place only in the topsoil as indicated by high ARM/SIRM of the sediments. During other phases, erosion (probably as rilling and/or initial gullying) was relatively intense and thus disturbed the deeper soils, as expressed by high IRM_−100mT/SIRM. Most of the changes in relative intensity of erosion can be ascribed to fluctuations in precipitation. Changes in land use/land cover or human activities may account, in part, for changes in soil erosion inferred for four more roughly identified periods.     

A whole-basin stratigraphic record of sediment and phosphorus loading to the St. Croix River,USA

Lake St. Croix is a natural impoundment of the lowermost 37 km of the St. Croix River in Minnesota and Wisconsin, making this one of a few large river systems in the world possessing a long-term depositional basin at its terminus. The river’s relatively pristine condition led to its designation as a National Scenic Riverway in 1968, but increasing urbanization in its lower reaches has raised concerns about impacts on water quality. This study was initiated to reconstruct historical loadings of suspended sediment and phosphorus (P) from the sediment record in Lake St. Croix. Twenty-four piston cores, with an average length of 2 m, were collected along eight transects of the lake. Dated chronologies from ²¹⁰Pb, ¹³⁷Cs and ¹⁴C were used to calculate the rate of sediment accumulation in the lake over the past 100+ years. Diatom microfossil analysis was used to reconstruct historical lakewater P concentrations over the same time period, and sediment P analysis quantified the amount of P trapped in lake sediments. Using a whole-lake mass balance approach, the loading of sediment and P to Lake St. Croix over the last 100+ years was calculated. Beginning in 1850, sediment accumulation increased dramatically to a peak in 1950–1960 of eight times background rates prior to European settlement. The peak is driven largely by sediment contributions from small side-valley catchment tributaries to the downstream half of the lake. The total P load to the lake increased sharply after 1940 and remains high, at around four times the level of pre-European settlement conditions. The timing of peak sediment and P loading to the lake shows that early settlement activities, such as logging and the conversion of forest and prairie to agricultural land between 1850 and 1890, had only modest impacts on the lake. By contrast, the mid-1900s brought major increases in sediment and P loading to the lake, suggesting that relatively recent activities on the landscape and changes to nutrient balances in the watershed have caused the current eutrophic condition of this important recreational and natural resource. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

Devensian Late-glacial environmental change in the Gordano Valley, North Somerset, England: a rare archive for southwest Britain

The Late-glacial and Holocene environmental history of the Gordano Valley, North Somerset, UK has been reconstructed using pollen, sediment particle size and mineralogical analyses and radiocarbon dating. A Devensian sediment ridge across the valley confined the waters of a small lake, within which the initial sedimentation was minerogenic. Radiocarbon dating of overlying organic-rich deposits suggests that this began late in the Dimlington Stadial c. 18,000–15,000 Cal. BP. Petrographic analyses indicate the minerogenic sediments were partly wind-blown in origin. Climatic amelioration during the Windermere Interstadial c. 15,000 Cal. BP encouraged a shift from minerogenic to biogenic sedimentation. A brief return to minerogenic sedimentation between c. 10,400 and c. 9,520 Cal. BP was followed by uninterrupted fen peat accumulation throughout the Holocene. The later minerogenic horizon appears to represent the Loch Lomond Stadial. Few stratigraphic sequences preserving the complete Devensian Late-glacial–Holocene transition exist in southwest Britain, making the sedimentary archive of the Gordano Valley valuable regionally for reconstructing Late-glacial climate change.     

Holocene sediment budgets in two river catchments in the Southern Upper Rhine Valley, Germany

The Holocene sediments of two catchments in the southern Upper Rhine valley have been quantified as part of the German LUCIFS Programme (RheinLUCIFS), which aims to quantify sediment fluxes in the Rhine catchment since the onset of agriculture in the Neolithic about 7500 years ago.The spatial distribution of the alluvial and colluvial sediments was derived using geological maps, with information on the thickness of these sediments from various sources including auger profiles and data from excavations. The sediments were subdivided into characteristic sedimentary storage types according to the different types of landscapes. For each of the sedimentary storage types an average thickness was assessed so that an integral sediment balance for the Holocene could be derived.For the different types of landscapes in the study area, 32 Holocene sedimentary storage types were determined, 21 in the Elz catchment (1500 km²) and 11 in the Möhlin catchment (230 km²). By adding up the sediment volumes of all single sedimentary storage types the total Holocene sediment volumes for the two catchments were calculated. Erosion depths were determined by dividing the sediment volumes through the potential erosion areas (slope > 2%) and by assuming a sediment delivery ratio (SDR) between 0 and 0.4. The total erosion for the potential erosion areas during the Holocene was calculated as 31–61 cm in the Elz catchment and 44–79 cm in the Möhlin catchment.     

Radiometric dating of recent lake sediments from a highly eroded area in semiarid Tanzania

Semiarid regions are vulnerable environments with a series of important and often discussed problems such as land degradation, water scarcity and desertification. These regions are dynamic and respond quickly to climatic and environmental changes. Unlike lakes in temperate zones, lakes in semiarid regions are yet poorly utilized as climatic and environmental indicators. In this study aquatic deposits are used to uncover the environmental history of a severely degraded area in central Tanzania. The ²¹⁰Pb and ¹³⁷Cs chronologies date a 360 cm long sediment sequence to 155 years. The sediments show that lake Haubi basin changed from a seasonally waterlogged depression to a lake at the turn of the century. Calculated sedimentation rates show that the catchment of the lake has been subject to varied and enhanced soil erosion during the last 155 years.     

A test of the integrity of metal records in sediment cores based on the documented history of metal contamination in Lac Dufault (Québec, Canada)

There is an important volume of published information on Lac Dufault (Québec) which describes the history of metal inputs over 70 years and the changes that occurred in the lake as a result of this contamination. We used this abundant source of chronological markers to test the hypothesis that lake sediments can provide true historical records of trace metal loading from metal mining. Sediment cores were obtained from the deepest zone of the lake (19 m). The sediments were dated using ²¹⁰Pb and ¹³⁷Cs and they were analyzed for total elemental concentrations (Ca, Cd, Cu, Fe, P, Pb, S, Zn). Metal profiles in the sediment core preserved the distinct signatures of different mine exploitations documented in the lake watershed. In particular, the core recorded: the beginning of industrialization in 1926; increasing sedimentation rates associated with perturbations in the lake watershed; the maximum of sediment [Cu] and the contemporary exploitation of ore bodies rich in Cu; the maximum of sediment [Fe] and the contemporary production of pyrite by a mining operation; the low sediment [Cu] and [Zn] in the 1950s and the low contemporary production of these metals by mining operations; the maximum of sediment [Cd] and the contemporary production of Cd by a subsequent mining operation. Anomalies in the distribution of ²¹⁴Pb activities in sediments reflected the intensity of acid mine drainage (AMD). There is good evidence that the lake resisted acidification from this AMD for the last thirty years. Overall, our results support the thesis that profiles of sedimentary Cd, Cu, Zn, Pb and Fe levels reflect the past history of metal input to Lac Dufault.     

Isotopic fingerprints on lacustrine organic matter from Laguna Potrok Aike (southern Patagonia, Argentina) reflect environmental changes during the last 16,000 years

A combination of carbon-to-nitrogen ratios (TOC/TN), Rock Eval-analyses, and stable isotope values of bulk nitrogen (δ¹⁵N) and organic carbon (δ¹³C_org) was used to characterize bulk organic matter (OM) of a piston core from the Patagonian maar lake Laguna Potrok Aike (Argentina) for the purpose of palaeoenvironmental reconstruction. Sedimentary data were compared with geochemical signatures of potential OM sources from Laguna Potrok Aike and its catchment area to identify the sources of sedimentary OM. Correlation patterns between isotopic data and TOC/TN ratios allowed differentiation of five distinct phases with different OM composition. Before 8470 calibrated ¹⁴C years before present (cal. yrs BP) and after 7400 cal. yrs BP, isotopic and organo-geochemical fingerprints indicate that the sediments of Laguna Potrok Aike consist predominantly of soil and diatom OM with varying admixtures of cyanobacterial and aquatic macrophyte OM. For a short phase of the early Holocene (ca. 8470–7400 cal. yrs BP), however, extremely high input of soil OM is implied by isotopic fingerprints. Previous seismic and geochronological results indicate a severe lake-level drop of 33 m below present-day shortly before 6590 cal. yrs BP. It is suggested that this lake level drop was accompanied by increased erosion of shore banks and channel incision enhancing soil OM deposition in the lake basin. Thus, isotopic data can be linked to hydrological variations at Laguna Potrok Aike and allow a more precise dating of this extremely low lake level. An isotopic mixing model was used including four different sources (soil, cyanobacteria, diatom and aquatic macrophyte OM) to model OM variations and the model results were compared with quantitative microfossil data.     

Sediment source changes over the last 250 years in a dry-tropical catchment, central Queensland, Australia

Rivers draining to the Great Barrier Reef are receiving increased attention with the realisation that European land use changes over the last  150 years may have increased river sediment yields, and that these may have adversely affected the reef environment. Mitigation of the effects associated with such changes is only possible if information on the spatial provenance and dominant types of erosion is known. To date, very few field-based studies have attempted to provide this information. This study uses fallout radionuclide (¹³⁷Cs and ²¹⁰Pb_ex) and geochemical tracing of river bed and floodplain sediments to examine sources over the last  250 years for Theresa Creek, a subcatchment of the Fitzroy River basin, central Queensland, Australia. A Monte Carlo style mixing model is used to predict the relative contribution of both the spatial (geological) sources and erosion types. The results indicate that sheetwash and rill erosion from cultivated basaltic land and channel erosion from non-basaltic parts of the catchment are currently contributing most sediment to the river system. Evidence indicates that the dominant form of channel erosion is gully headcut and sidewall erosion. Sheetwash and rill erosion from uncultivated land (i.e., grazed pasture/woodland) is a comparatively minor contributor of sediment to the river network. Analysis of the spatial provenance of floodplain core sediments, in conjunction with optical dating and ¹³⁷Cs depth profile data, suggests that a phase of channel erosion was initiated in the late nineteenth century. With the development of land underlain by basalt in the mid-twentieth century the dominant source of erosion shifted to cultivated land, although improvements in land management practices have probably resulted in a decrease in sediment yield from cultivated areas in the later half of the twentieth century. On a basin-wide scale, because of the limited spatial extent of cultivation, channel sources are likely to be the largest contributor of sediment to the Fitzroy River. Accordingly, catchment management measures focused on reducing sediment delivery to the Great Barrier Reef should focus primarily on decreasing erosion from channel sources.     

Chernobyl radiocaesium in upland watershed-lake systems,Galloway, south west Scotland

Levels of Chernobyl radiocaesium found in the upland region of Galloway, south west Scotland were relatively high e.g. catchment mean¹³⁴Cs inventories ranged from 5.72±2.64 kBq m² to 8.72±1.46 kBq m². The nuclear weapons test¹³⁷Cs content of soils and peats was significantly augmented. Accurate assessment of spatial variations and temporal changes in the levels of contamination, however, are inhibited by its marked, short-range heterogeneity. No significant change in mean catchment inventories was detected over a twelve month period. Lake sediment inventories, however, were consistently enhanced from initially lower levels of contamination than their catchments' surfaces. Pre Chernobyl catchment and lake sediment¹³⁷Cs inventories, however, show no such contrast. Both are substantially lower than rainfall based predictions. These observations of the relative levels of Chernobyl and pre-existing radiocaesium in watersheds and their waterbodies have important implications for both the assessment of the catchment and lake residence times of particle-associated contaminants and the use of lake sediment records as monitors of such pollutants.     

Mechanisms for Organic Matter and Phosphorus Burial in Sedimentsof a Shallow, Subtropical, Macrophyte-Dominated Lake

We studied the role that submersed aquatic vegetation (SAV) plays in the sedimentation of organic matter (OM) and phosphorus (P) in Lake Panasoffkee, Florida (USA), a shallow, hard-water, macrophyte-dominated water body. Carbon/Nitrogen ratios (C/N) and stable isotope signatures (δ¹³C and δ¹⁵N) in algae, higher plants, and surface sediments were measured to identify sources of OM to the lake mud. Pollen, plant macrofossils, and geochemistry in sediment cores indicated that primary productivity and SAV abundance in Lake Panasoffkee increased in the late 1800s, probably as a response to increased P loading from human settlement and forest clearance. SAV and associated periphyton served as temporary sinks for soluble P, maintaining relatively clear-water, low-nutrient conditions in the lake. P accumulation in Lake Panasoffkee sediments increased together with indicators for greater SAV presence. This suggests that SAV and associated epiphytes promote P burial and retention in sediments. Although it might be assumed that rooted submersed macrophytes are directly responsible for P uptake from water and transfer to sediments, C/N and stable carbon isotope results argue for the importance of other macrophyte growth forms, and perhaps epiphytic algae, in permanent OM and P sequestration. For instance, high rates of photosynthesis by epiphytes in hard-water systems consume CO₂ and promote CaCO₃ precipitation. Sloughing of accumulated carbonates from macrophyte leaves transfers epiphytes and associated P to the sediment. Our paleolimnological findings are relevant to restoration efforts in the Florida Everglades and support the claim that constructed SAV wetlands remove P from waters effectively.     

Unexpected post-settlement freshening and increase in charophytes in Bombah Broadwater (Myall Lakes,New South Wales,Australia)

Bombah Broadwater is a shallow coastal lake within the Ramsar-listed Myall Lakes system on the mid-north coast of New South Wales, Australia. Increased nutrient and sediment loads resulting from catchment modification are thought to have instigated the loss of aquatic plants in the lake, causing it to “switch” from a clear, macrophyte dominated system (similar to the conditions in present day Myall Lake) to a turbid, phytoplankton dominated system. To assess this hypothesis, charophytes, foraminifera and aquatic fauna remains from an 800 year sediment record were examined. The sediment chronology was established using ¹⁴C, ²¹⁰Pb and ¹³⁷Cs radiometric dating and sediment composition. Interestingly, a clear increase in charophytes since European arrival conflicted with the hypothesised aquatic plant loss. Hence, it appears Bombah Broadwater has not undergone a change in stable state since European arrival. An additional and unexpected finding in the patterns of the foraminifera and testate amoeba suggest that Bombah Broadwater has freshened substantially since European arrival. This freshening may have resulted from increased catchment run off as a result of the clearance of catchment vegetation. Since catchment vegetation clearance is widespread in Australia, this finding raises the possibility that post-settlement freshening of coastal lakes may be a common occurrence.